SCANNED
t (fc u T Mo Trd b x h /set Ilx Mac( FOSTER WHEELER ENVIRONMENTAL CORPORATION SCOPE OF WORK for PHASE IIA GROUNDWATER INVESTIGATION FIREWORKS I (FORMER NATIONAL FIREWORKS FACILITY) HANOVER, MA RTN: 4-0090 October 1998 (Rev. 0) Prepared for: The Fireworks Site Joint Defense Group Prepared by: Foster Wheeler Environmental Corporation 470 Atlantic Avenue Boston, MA 02210 0198-236 1onJ93 FOSTER WHEELER ENVIRONMENTAL CORPORATION October 2, 1998 OT98-238 Mr. Jonathan Hobill Bureau of Waste Site Cleanup Massachusetts Department of Environmental Protection Southeast Regional Office 20 Riverside Drive Lakeville, MA 02347 Subject: FIREWORKS I SITE, HANOVER, MA, RTN #4-0090 PHASE IIA SCOPE OF WORK Dear Mr. Hobill: On behalf of the Cooperating Parties and pursuant to 310 CMR 40.0834(a), Foster Wheeler Environmental Corporation (Foster Wheeler) is submitting this Phase IIA Scope of Work for the Fireworks I Site, Release Tracking Number 4-0900. Included as appendices to this Scope of Work are the Quality Assurance Plan and Health and Safety Plan that will be followed for all Phase IIA activities. The LSP of Record overseeing the Phase IIA investigation will be Mr. David Austin (License No. 2062). Foster Wheeler's submission of these documents, including the Tier IA Permit Application, does not constitute an acknowledgment of liability by any or all of the Cooperating Parties, and the Cooperating Parties each reserves it rights to dispute such liability in the future. Furthermore, these documents contain no admissions of any kind, and should not be construed to contain any admissions. If you have any questions, please call the undersigned at (617) 457-8253. Sincerely, Boyd Allen III, CPG Project Manager Enclosures cc: R. Jones C. Davis J. Beling W. Lahey Hanover Board of Health Hanson Board of Health File: FRX 16.1 FRX 2.1.2 470 ATLANTic AvENUE, BOSTON, MA 02210 TEL: 617-457-8200 FAx: 617-457-8498 FOSTER WHEELER ENVIRONMENTAL CORPORATION SCOPE OF WORK for PHASE IIA GROUNDWATER INVESTIGATION FIREWORKS I (FORMER NATIONAL FIREWORKS FACILITY) HANOVER, MA RTN: 4-0090 October 1998 (Rev. 0) Prepared for: The Fireworks Site Joint Defense Group Prepared by: Foster Wheeler Environmental Corporation 470 Atlantic Avenue Boston, MA 02210 OT98-236 10/2/98 TABLE OF CONTENTS 1.0 INTRODUCTION...... -...... -...... -- 1 2.0 MCP INVESTIGATION HISTORY AND PROCESS..---...... I 2.1 Phase I Investigation and Tier Classification...... 1 2.2 Phase II Comprehensive Site Assessment ...... 3 3.0 FIELD INVESTIGATION PROGRAM ...... 4 3.1 M obilization A ctivities ...... - -..... -... - -...... 4 3.2 Field A ctivities...... - ...... -- -...... -- - - - ...... -...... 4 4.0 PREPARATION OF THE PHASE IIA GROUNDWATER INVESTIGATION REPORT ..... 5 5.0 PUBLIC INVOLVEM ENT...... __...... 5 6.0 PRO JECT TEA M ...... __...... 6 7.0 SC H ED U LE ...... _...... 6 8.0 R EFER EN C E S ...... _...... _...... 6 LIST OF FIGURES Figure 1 Site L ocation M ap ...... __...... 2 Figure 2 Phase I Sampling Locations...... - -...... _...... Attached Plate Figure 3 Project Organizational Chart...... 7 LIST OF APPENDICES Appendix A Quality Assurance Plan Appendix B Health and Safety Plan o3s-26 wIs 1.0 INTRODUCTION Foster Wheeler Environmental Corporation (Foster Wheeler) prepared this Phase IIA Scope of Work (SOW) on behalf of the Fireworks Site Joint Defense Group to support Phase II - Comprehensive Site Assessment activities at the Fireworks Site (RTN #4-0090), located in Hanover, Massachusetts. In accordance with the requirements of the Massachusetts Contingency Plan (MCP) in 310 CMR 40.0834, this Phase IIA SOW describes Foster Wheeler and the Joint Defense Group's approach to the proposed environmental investigation and is being submitted to the Massachusetts Department of Environmental Protection (DEP) for approval. The Phase IIA SOW is the first task of a Phase II investigation and is intended to collect initial groundwater information and additional site data to partially fulfill the requirements in 310 CMR 40.0835. The property known as the Fireworks Site (Site) is comprised of approximately 240 acres, portions of which have a history of the use, storage, and disposal of potentially hazardous materials associated with the manufacture and research of munitions and pyrotechnics. A USGS map showing the location of the Site is included as Figure 1. This Phase IIA SOW was developed to address the technical complexities associated with this Site, its large size, and various historical uses in a phased investigation, ultimately leading to completion of a Phase II Comprehensive Site Assessment. The technical approach is designed to develop an understanding of groundwater flow and quality on site and provide more specific hydrogeochemical data at several areas of interest identified by the DEP and in the Phase I Initial Site Investigation Report completed by Foster Wheeler (Foster Wheeler, 1997). Based on the foregoing, the intent of this investigation is to provide groundwater data that can be used in conjunction with data obtained from previous investigations to further determine or evaluate Site Hydrogeological Characteristics, Environmental Fate and Transport of Oil and/or Hazardous Material (OHM) and the Nature and Extent of Contamination pursuant to the requirements of a Phase II Report (310 CMR 40.0835[d-fj). Subsequent to this work, additional environmental investigations may be defined and conducted during one or more successive phases of the Phase II process. The format of this Phase IIA SOW includes Section 1.0 (this section), which describes the objectives of and general approach to this investigation as well as the organization of this Phase IIA SOW. Section 2.0 summarizes current site conditions and site history, and provides an overview of previous site assessment work under the MCP and the intended purpose of the Phase IIA investigation. Section 3.0 describes the field investigation for the groundwater monitoring program. Section 4.0 briefly discusses the format and content of the Phase IIA report or data submittal (the work products of this investigation). Section 5.0 briefly discusses public involvement. Sections 6.0 and 7.0 describe the Foster Wheeler project organization and the anticipated schedule for completion of project activities, respectively. Specific quality assurance (QA) procedures to be implemented during data collection activities are described in the QA Plan (QAP), included in Appendix A. Site specific health and safety procedures are included in the Health and Safety Plan (HASP) in Appendix B. 2.0 MCP INVESTIGATION HISTORY AND PROCESS 2.1 Phase I Investigation and Tier Classification In October 1995, after conducting surface water, sediment, and fish tissue sampling for mercury, lead, and other metals, DEP issued Notices of Responsibility (NORs) to Kerr-McGee Chemical Corporation, Massachusetts Institute of Technology, National Coating Corporation, Susquehanna Corporation and the U.S. Department of Defense based on their alleged status as either owners, operators, generators, 0198.236 I 10/2/8 IsI --- £ OFSIT so I FAREA ____S__ TEBOUNDARY-,; my SIT- L-C--I---A- - 7 n F SRWORSST 1000 0 2000 2000 3000 4000 SCALE IN FEET - SCALE: AS SHOWN Sourc: USGS 7.5 Miln Topographic Maps; Whitman, MA, 1977, and Hanover. MA 1978. RTI operators, generators, transporters or disposers or successors to former Fireworks Site owners, Parties) while not admitting transporters or disposers. The first three entities (termed the Cooperating association, to respond to liability, formed the Fireworks Site Joint Defense Group, an unincorporated by the Fireworks Site Joint the NOR issued by DEP. A Phase I investigation was undertaken and funded Corporation or the Defense Group and no support or assistance was provided by either Susquehanna of concern identified by DEP Department of Defense. The Phase I investigation focused on several areas investigations to Tier to provide sufficient data to be used in conjunction with data from previous Classify the Site under the MCP. of Work. Soil borings were A field investigation was performed in accordance with the July 1997 Scope interest: Fox Island, Building advanced on site and a monitoring well installed in each of the five areas of and groundwater samples were 80, Building 307, Waste Bum Pit and Demolition Area Pit. Soil collected and analyzed. - - contaminants at the Fireworks Five principal migration pathways of potential concern were identified for and air. Several potential Site in the following media: soil, groundwater, surface water, sediments in the Demolition Pit exposure points have been identified and include: surface soils present primarily and surface waters, including and Waste Bum Pit areas, sediments in the Drinkwater River system, wetland areas adjacent to the Demolition Pit. from the July 1997 field The Site was numerically ranked using the soil and groundwater data 1995 sampling. Based on investigation and historic sediment and surface water data from DEP's January Key points from the ranking these data, the Site scored 681 points and was classified as a Tier IA site. score sheet are summarized below: by DEP * Mercury levels (840 mg/kg) in one of the Factory Pond sediment samples collected (RCS-2) of 60 in 1995 were greater than the DEP S-2 Reportable Concentration for soil mg/kg. This comparison was made for scoring purposes only. Pit area were greater - * Mercury concentrations (0.0026 mg/I) in groundwater at the Demolition than the DEP GW-2 Reportable Concentration (RCGW-2) of 0.001 mg/I). soil * Mercury (70 mg/kg) and lead (1200 mg/kg) levels were detected in the top six inches of at concentrations greater than the DEP S-1 soil standards of 20 mg/kg and 300 mg/kg, respectively. by DEP * Neither mercury nor lead were detected in surface water based on samples collected in 1995. * No Oil or Hazardous Material (OHM) was identified in air based on PID readings collected during the Phase I investigation field work. * A fish consumption advisory based on mercury levels in fish tissue was issued for Factory Pond by the Massachusetts Department of Public Health on June 24, 1994. Permit Application were The Phase I Report (Foster Wheeler, 1997), Tier Classification and Tier IA was issued to the submitted to DEP on October 20, 1997. A Tier IA permit (Permit No. 100223) Cooperating Parties with an effective date of July 27, 1998. 2.2 Phase H Comprehensive Site Assessment to develop and complete a The Cooperating Parties have five years from the effective date of the permit DEP approval. The remedy at the Site consistent with the MCP and subject to possible extension with is a systematic Phase II Comprehensive Site Assessment is the next step in the MCP process and oT9-236 3 10/2/98 investigation and assessment of the entire disposal site to be used in developing remedial response alternatives. Elements of the Phase Il investigation include: * Physical characteristics of the site including site hydrogeology * Identification of source and extent of any releases * Characterization of OHM at the site including environmental fate and transport * Identification of exposure points and exposure point concentrations * Identification of background levels of OHM * Characterization of risk and harm to human health and the environment The Cooperating Parties are adopting a phased approach to Phase II, and this SOW represents the first task in that Comprehensive Site Assessment. The purpose of the Phase IIA groundwater investigation is to develop an understanding of groundwater flow in the upper surficial -aquifer and determine groundwater quality in selected areas of the Site. The investigation will consist of measuring groundwater and stream elevations from well points and staff gages installed across the Site and collection of groundwater samples for geochemical analyses from the newly installed well points. Following completion of the Phase IIA investigation, either a Phase IIA Report or Data Package/Submittal will be completed and submitted for DEP review and public review as applicable. Prior to initiating any subsequent Phase II work, a SOW would be prepared for DEP approval, incorporating the information collected to date at the Site and any comments received on the Phase IIA data. 3.0 FIELD INVESTIGATION PROGRAM 3.1 Mobilization Activities Following DEP's approval of the SOW, Foster Wheeler will finalize procurements and subcontracts with the driller, laboratory and surveyor and prepare field equipment and personnel for mobilization to the Site. Concurrent with this activity, the seven day notification describing the personal protective gear and methods of investigation will be submitted to the Town of Hanover and the Hanover Health Department. Because of the potential for sampling activities to occur within 100 feet of the Drinkwater River and Factory Pond, Foster Wheeler contacted the Hanover Conservation Commission with respect to the Massachusetts Wetlands Protection Act. At its direction, Foster Wheeler will submit a copy of the Plan of Well Point Locations for review by the Commission to confirm that changes in activities are not significant enough to require a new filing for a Negative Determination of Applicability. The project has already received a Negative Determination of Applicability from the Phase I investigation. In addition, access agreements must be obtained from landowners prior to entry for any field activities. 3.2 Field Activities Prior to commencement of the Phase IIA field activities, Foster Wheeler staff will walk the Site and stake potential well point locations for Digsafe clearance. All on-site work will be performed in accordance with the HASP which is included as Appendix B of this SOW. The field effort includes the installation of eight (8) staff gages in the Drinkwater River system and thirty (30) one-inch diameter carbon steel driven well points with five-foot stainless steel screens to an average depth of ten (10) feet below grade. These locations are shown on Figure 2 and will be leveled by a surveyor working off the established survey baselines on site. The well points will be installed by a soft OT98-236 4 10/1J98 tire mobile drilling rig. Each well point will be completed with a three foot stick up above the ground surface and fitted with locking caps. These well points are considered "temporary", although they can be used for several years. The well points will be developed and allowed to equilibrate with the aquifer before sampling. All development and sampling water will be disposed on the ground adjacent to the well points per 310 CMR 40.0045. One round of analytical samples will be collected from the well points using low flow sampling methods and analyzed for volatile organic compounds with an instrument data library search of ten (10) Tentatively Identified Compounds (TICs), freon, nitrate, mercury, and lead. At seven selected locations, full Target Analyte List (TAL) metals will be analyzed. No petroleum analyses are included. This program will provide an indication of the extent of potential volatile organic and mercury and lead groundwater impacts on the Site and be beneficial in assessing overall groundwater environmental concerns at the Site as well as planning any necessary environmental investigations in the future. The nitrate analysis will serve as a proxy indicator of dissolved explosives residues. In addition, one surface water sample near the Factory Pond Dam will be collected and analyzed for mercury and lead. All sample collection and analysis will be conducted in accordance with the Quality Assurance Plan (see Appendix B). Two rounds of water level elevations will be measured in the newly installed well points, the five existing monitoring wells (from 1997) and at the river staff gages. The first round will coincide with the analytical sampling effort and the second round will be collected four to six weeks later depending on precipitation or seasonal fluctuations. Groundwater elevations for the two rounds will be calculated using the surveyed elevations,-tabulated and presented as potentiometric contours on the Site base map. 4.0 PREPARATION OF THE PHASE IIA GROUNDWATER INVESTIGATION REPORT Following completion of field activities and receipt of laboratory data, a Phase IIA report will be prepared. The Phase IIA report will present the data collected from the. field investigation program discussed in Section 3.0. The report will summarize the field efforts and data collection activities, and present the tabulated hydrogeological and chemical data. Figures will include the Site base map showing well point and staff gage locations and the potentiometric contour maps. The analytical data reports from the laboratory will be included as an Appendix. The Phase IIA report will also include an evaluation to determine if an Immediate Response Action is necessary, as described in 310 CMR 40.0412. The conclusions section will include a summary of findings and a statement of conclusions with respect to groundwater at the Site and suggested followup activities for continuing the Phase II Comprehensive Site Assessment. 5.0 PUBLIC INVOLVEMENT All applicable public involvement requirements will be followed pursuant to the MCP in 310 CMR 40.0839. At this time, public involvement is being handled by the Cooperating Parties, in coordination with DEP. Foster Wheeler and the Cooperating Parties will attend a DEP sponsored public meeting to discuss the proposed groundwater investigation (Phase IIA) in Hanover, Massachusetts on October-5, 1998. In addition, Foster Wheeler and the Cooperating Parties may be asked to attend public meetings or otherwise provide support for public involvement activities at the completion of the Phase IIA site work and/or subsequent site activities. OT98-236 10/2/98 5 6.0 PROJECT TEAM The project team is illustrated in Figure 3. Three subcontractors will be utilized to provide off-site analytical laboratory services, well point installation and surveying services. Foster Wheeler has worked with all three firms on previous assignments. Severn Trent Laboratories (formerly ITS/Aquatec) of Burlington, Vermont will serve as the off-site analytical laboratory. Severn Trent is well qualified to support the Fireworks project based on existing certifications with MADEP and the USACE, its reputation for performing quality work including metals analyses, and its demonstrated ability to provide high quality data from the Phase I investigation. Pine and Swallow, Inc. of Groton, Massachusetts will serve as the drilling subcontractor. Pine & Swallow is highly experienced in the performance of geologic investigations and pioneered much of the driven well technology utilized throughout the New England region. Norfolk/SNB of Raynham, Massachusetts will serve as the surveying subcontractor. They are Registered Land Surveyors and performed the surveying to support Phase I activities. 7.0 SCHEDULE The current project schedule assumes DEP approval of the SOW in mid-October 1998 and mobilization to the field by the end of the month, contingent upon receiving access from property owners. Well point installation and groundwater sampling would be completed by November with analytical results received by late December. The second round of water levels would be collected during data reduction in January and report preparation will take place in February 1999, with a final report scheduled for submission to DEP by February-March 1999. 8.0 REFERENCES USGS, Topographic Maps, Whitman, MA Quadrangle, 1977 and Hanover, MA Quadrangle, 1978. Foster Wheeler Environmental Corporation, 1997. Phase I Initial Site Investigation Report and Tier Classification, Fireworks I, Hanover, MA, RTN:4-0090, October 1997. OT98-2366 WW//9 Figure 3 Fireworks Site Project Organizational Chart R. Jones I B.Aljeanager B. Allen, CPG D. Austin, LSP P. Woodman, PhD Risk Assessment L. Horzempa, PhD Geochemistry P. Vernon, CSP J. Ehret, P.G. I Geology and Field Sperations Sampling K. Carpenter T. Lee I I | Severn Trent Norfolk/SNB I Pine & Swallow Laboratories ig 3.ppt APPENDIX A QUALITY ASSURANCE PLAN O198-236 10/2/98 QUALITY ASSURANCE PLAN 1.0 INTRODUCTION measures This Quality Assurance Plan describes the quality control (QC) and quality assurance (QA) IIA that will be conducted for the Fireworks Site to ensure that the data generated from the Phase sampling program are of known quality and are acceptable for project objectives. Data generated for the Fireworks Site will be used to determine the following: * presence and/or absence of contamination in selected areas of the Site; * nature of the contaminants, if present; and * provide a preliminary indication of the distribution of contaminants. 2.0 FIELD QA/QC PROCEDURES 2.1 Sample Designation System The following system will be used to identify samples collected during the Phase IIA sampling program: Location: MWxx Monitoring Well, where xx designates the well ID PZxx Well Point, where xx designated the well point ID Each well point location will be recorded sequentially. Sample Type: MW Groundwater samples from monitoring wells PZ Groundwater samples from well points QC Identifier: D Field duplicate TB Trip blank EB Equipment blank MS/MSD Sample to be used as the MS/MSD or spike and duplicate for inorganics QC samples which are not associated with physical locations will be referenced by the data collected (i.e., TB103198 would be a trip blank collected on October 31, 1998). For example, PZ05D would be a duplicate groundwater sample collected from well point #5. 2.2 Quality Control Sampling Requirements Specific quality control steps which will be taken to ensure that the data collected are representative, defensible, and accurate for the purposes of this project are described in this section and in the following subsections. Quality control (QC) samples that will be collected for the purpose of quantitatively assessing the quality of the sampling effort and the laboratory analysis are discussed in this subsection. Other quality control requirements, including field documentation, sample handling and shipping requirements, and decontamination procedures, are also discussed in this section. o09s-236 A-] 10/2/98 2.2.1 Quality Control Samples The number and type of quality control samples that will be collected are summarized in the Work Plan. A general summary of how the samples will be collected and the frequency of collection is summarized below. 2.2.2 Field Duplicate Samples Field duplicate samples are multiple grab or composite samples, collected separately, that equally represent a medium at a given location and time. Field duplicates will be collected at a frequency of 5% per sample matrix for most key project parameters. However, field duplicates have not been included in the instance where only one sample is anticipated for the analysis, given that this sample is scheduled only to provide an indication of potential contaminants of concern (i.e., not intended to be representative). Should conclusive data regarding the absence of these constituents, further sampling and analysis will be recommended. 2.2.3 Equipment Blanks Equipment blanks are samples consisting of a reagent (analyte-free) water collected during a sampling event from a final rinse of sampling equipment after the decontamination procedure has been performed. The purpose of equipment blanks is to determine whether the sampling equipment is causing cross contamination of samples. Equipment blanks will not be collected for the groundwater samples, as these samples are obtained using disposable sampling equipment. 2.2.4 Trip Blanks Trip blanks are samples consisting of reagent free (VOC free) water prepared and shipped with each cooler containing samples for VOC analysis. The purpose of these samples is to monitor the amount of contamination introduced to samples during the handling, packaging, and shipping process. Trip blanks will be analyzed for VOCs only. 2.2.5 Matrix Spike/Matrix Spike Duplicate Matrix spike/matrix spike duplicate (MS/MSD) samples are laboratory QC samples used to assess the precision and accuracy of the laboratory analytical methods. Note that MS/MSD samples are analyzed for organic analyses; inorganic analyses require a spike and duplicate. Although, these are not actually field QC samples, additional volume of sample is required for the additional laboratory analyses. For this project, laboratory batch QC will be reported and additional site specific MS/MSDs are nt proposed for collection. 2.3 Equipment Decontamination Procedures - Sampling equipment will be decontaminated using the following procedures: * Wash equipment with non-phosphate detergent solution. * Rinse with tap water. * Rinse with 9.9% nitric acid (HNO 3) solution. * Rinse with deionized water. " Rinse with methanol. 008-236 A-2 I0/2/98 I Repeat entire procedure or any parts of the procedure if necessary. * Allow the equipment or material to air dry before re-using. * Dispose of any soiled materials in a designated disposal container. Drilling equipment or other large equipment or vehicles may be decontaminated using steam cleaning. 2.4 Documentation Procedures A bound, weatherproof field notebook will be maintained by the sampling crew to record all information related to sampling activities. Information will document the following: * Date and time of site visit. * Key personnel on-site. * Description of activities being performed. * Sample identification and time of collection. QA/QC samples. Decontamination procedures. * Sampling sequence and time of sample collection. * Types of sample bottles and sample identifiers used. * Preservatives used (if required). * Parameters requested for analysis. Field observations, including sample conditions (sample matrix, sample volume, color, consistency, odor, evidence of contamination, etc.). * Description of equipment used, including trade names, model numbers, diameters, material compositions, etc. * Calibration data for field instruments (if required). * Description of any problems encountered in the field. Photographs may be taken to document site conditions, appearance, or specific samples. Photographs will be recorded in the site logbook. 2.5 Sample Chain of Custody, Packaging, and Shipping Procedures 2.5.1 Chain of Custody To maintain and document sample possession, chain of custody (COC) procedures will be implemented. These procedures are necessary to insure the integrity of samples from the time of collection to data reporting. The COC protocol provides the ability to trace possession and handling of samples. A sample is considered under custody if: I It is in a person's possession; * It is in a person's view after being in your possession; * It is in a person's possession and then locked up; or * It is in a designated secure area. Personnel collecting samples are responsible for the care and integrity of those samples until they are properly transferred or dispatched. Therefore, the number of people handling samples will be kept to a minimum. oT98-236 A-3 10/2/98 A Chain of Custody form will be completed by the sampler for all samples to be shipped off-site and shall accompany the samples at all times. The following information shall be indicated on the COC record: r Project identification; * Signature of samplers; * Sample identification, sample matrix, date and time of collection, grab or composite sample designation, number of containers corresponding to that sample identification, analyses required, remarks or sample location (if applicable), and preservation method(s); * Signature of the individual relinquishing the samples; and * Name of the individual(s) receiving the samples and air bill number, if applicable. The COC preparer will then check the sample label and COC record for accuracy and completeness. When transferring custody of samples, individuals relinquishing custody and individuals receiving custody will sign, date, and record the time on the COC. When samples are being shipped to the laboratory via courier or shipping company (Federal Express), the shipping company will be indicated as receiving custody. Upon receipt of shipment at the laboratory, a designated sample custodian will accept custody of the samples and verify that information on the sample labels match the COC record. Pertinent information on shipment, air bill number, pickup, courier, date, and time will be recorded on the COC. It is then the laboratory's responsibility to maintain logbooks and custody records throughout sample preparation and analysis. 2.5.2 Sample Packing and Shipping Samples for off-site laboratory analysis will be shipped via Federal Express or by courier for overnight delivery in waterproof coolers using the procedures outlined below. The samples taken for this project shall be considered low-level or environmental samples for packaging and shipping purposes. The sample packing procedures are as follows: * Fill out the pertinent information on the sample label, and ensure agreement with the COC. * Place about 3 inches of cushioning material, such as vermiculite or bubblepack, in the bottom of the cooler. * Wrap the sample containers in bubblepack. Place containers in the cooler in such as way that they will not touch during shipment. * Put in additional packing material to partially cover sample containers (more than halfway). * Place ice, sealed in plastic bags, around and on top of the containers. The temperature of the samples must be maintained at or below 4C during shipment to the laboratory. * Fill cooler with cushioning material. If the cooler will be picked up by a laboratory courier, the cooler may be closed and transferred to the courier. The courier will sign the COC as a record of receipt, returning one signed copy to the sampler. If samples are to be shipped via Federal Express or other delivery service, the following steps will be taken: * Put COC record in a waterproof plastic bag and tape it to the inside lid of the cooler. * Tape the drain shut. * Affix two signed and dated custody seals on opposite corners of the cooler so that the cooler cannot be opened without breaking the seals. onT8-236 A-4 10/2/98 * Secure the lid by wrapping the cooler completely with nylon strapping tape or duct tape at a minimum of two locations. * Attach completed shipping label to top of the cooler. From the time of sample collection, samples for off-site analysis will be stored on ice. 2.6 Sample Containers, Preservatives and Holding Times Table A-1 summarizes the sample containers, preservation and holding times required for this sampling program: Table A-1 Sample Containers, Preservatives, and Holding Times Container Analysis__ Oontainer (sol (quenus) Preservative Holding Tm VOC, freon 40 ml VOC vial (or 40 ml VOC vial HCI pH <2, 14 days I equiv. wide mouth) Cool 4"C metals 8 oz (or larger)glass I L HDPE HNO 3 pH <2, Hg - 28 days, others 6 months nitrate/nitrite include with metals I L HDPE Cool 4*C, H2SO4 28 days pH <2 Chemical preservative (acid or base) will not be used for soil samples. Preservatives for aqueous QC samples (trip and equipment blanks) will be the same as for aqueous samples. 2 Holding times are from time of sample collection HDPE = high density polyethylene L = liter HCl = Hydrochloric acid (1:1) HNO 3 = Nitric acid H2SO 4 = Sulfuric acid 3.0 ANALYTICAL METHODS 3.1 Laboratory Analytical Methods The following off-site methods will be used to analyze the samples from the Fireworks Site. Analysis EPA Reference Method Analvte Lists and Renortino limits Lead 6010 Table 2 Mercury 7471/7470 Table 2 TAL metals 6010/7000 series Table 2 Volatile Organics 8260B Table 3 Nitrate/nitrite 353.1 Table 2 O198-236 A-5 I0/2/98 In addition, VOC analysis will include a library search of unknown peaks for ten highest Tentatively Identified Compounds (TICs). TICs are a qualitative indication that a compound is present although the actual concentration cannot be determined without additional analysis. The TCL/TAL analyte lists comprise a significant majority of the Appendix IX (40 CFR 264) list and include contaminants commonly used in industries and typically identified on hazardous waste sites. These analyte lists with the TICs were chosen as a cost effective alternative to the complete Appendix IX list. Should TICs be identified that may be considered contaminants of concern, qualitative analysis for those compounds will be added during future phases of work. Analyte lists and reporting limits for the off-site analytical methods are provided in Tables A-2 and A-3. 3.2 Laboratory Reporting Requirements Laboratory reports submitted to Foster Wheeler will include, but not be limited to, the following: * The name, address, and phone number of the analytical laboratory. * Signature of an authorized laboratory individual, indicating the acceptability of the data. * A copy of signed COC records, indicating the condition of samples at the time of receipt by the laboratory. * Sample results reported in units of microgram or milligram per kilogram or liter. * Sample results will include a summary of pertinent COC and tracking information (i.e., dates of preparation and analyses, analytical instrumentation, associated QC samples, etc.). * Quality control results reported are to include spiking concentrations and acceptable limits. QC results that exceeded criteria and corrective actions should be discussed by the laboratory. Copies of chromatograms, quantitation reports, other instrument output data, and relevant logbooks, including instrument injection logs, standard preparation logs, and sample preparation logs, must remain on file at the laboratory and be made available for review by Foster Wheeler upon request. 3.3 Quality Control Review Following receipt of data from the laboratory, the Foster Wheeler Project Chemist will review the data and associated quality control results prior to being used in support of the hydrogeologic investigation. The data will be evaluated with respect to project objectives. Should the use of data be found limited due to QC exceedances, its use in future site characterization will be monitored accordingly. Similarly, should data be lost due to sample volume restrictions or breakage or found otherwise unacceptable due to severe QC exceedances, additional sampling and/or analysis may be recommended. 0T98-236 A-6 10/2/98 Table A-2 TAL Metals and Nitrate Target Analyte List and Reporting Limits Aqeous Reportig Analyte Limit (pg/L) Aluminum 200 Antimony 60 Arsenic 10 Barium 200 . Beryllium 5 Cadmium 5 Calcium 5,000 Chromium 10 Cobalt 50 Copper 25 Cyanide 10 Iron 100 Lead 3 Magnesium 5,000 Manganese 15 Mercury 0.2 Nickel 40 Potassium 5,000 Selenium 5 Silver 10 Sodium 5,000 Thallium 10 Vanadium 50 Zinc 20 Nitrate/nitrite 10 oT98-236 A-7 0/2/98 I Table A-3 I TCL Volatile Organic Compounds Analyte List and Reporting Limits - EPA Method 8260B Water or Sei. I Copound (pg Ior pg/kfr) Freon-TF 1.0 Dichlorodifluoromethane 1.0 Trichlorofluoromethane 1.0 Vinyl chloride 1.0 Chloromethane 1.0 Bromomethane 1.0 Chloroethane 1.0 2-Butanone 1.0 2-Hexanone 1.0 4-Methyl-2-pentanone 1.0 Acetone 1.0 1,1-Dichloroethane 1.0 Methylene chloride 1.0 Trans 1,2-dichloroethene * 1.0 Carbon disulfide 1.0 1,1-Dichloroethene 1.0 Chloroform 1.0 1,1,1-Trichloroethane 1.0 Carbon tetrachloride 1.0 1,2-Dichloroethane 1.0 Benzene 1.0 Trichloroethene 1.0 1,2-Dichloropropane 1.0 Bromodichloromethane 1.0 Trans-I ,3-dichloropropene 1.0 Toluene 1.0 Cis- 1,3-dichloropropene 1.0 1,1,2-Trichloroethane 1.0 Tetrachloroethene 1.0 Dibromochloromethane 1.0 Chlorobenzene 1.0 I Ethyl benzene 1.0 Xylenes (total) 1.0 Styrene 1.0 Bromoform 1.0 I 1,1,2,2,-Tetrachloroethane 1.0 * = May Be Reported As Total I I I I OT98-236 A-8 10/2/98 I APPENDIX B HEALTH AND SAFETY PLAN OT98-236 10/2/98 FOSTER WHEELER ENVIRONMENTAL CORPORATION SITE-SPECIFIC ENVIRONMENTAL HEALTH AND SAFETY PLAN SITE NAME: Fireworks Site LOCATION: Street No.: King Street City: Hanover State: Massachusetts DATE PREPARED: September 30, 1998 REVISION / DATE: Rev. I PROJECT NUMBER: 1780.0004.0000.00001 PROJECT The Fireworks site is a 250 acre OEW (ordnance and explosive waste) DESCRIPTION: site with lead, mercury and VOC contamination and possibly small amounts of radioactive waste. The site was as a manufacturing facility for fireworks and later for munitions for the US Government and alledgedly used for hazardous waste disposal. The factory was in operation from the early 1900s to 1972 and closed in 1972. The Phase I investigation evaluated the presence of wastes in five areas that may be contributing contamination to the Drinkwater River and Torrey Brook waters, sediment and biota. The Phase IIA investigation will focus on the presence of lead, mercury, metals, and VOCs, in groundwater WASTE TYPE: mercury, lead, OEW, volatile organics, metals and possibly small amounts of radioactive waste WASTE CHARACTERISTICS: UNUSUAL SITE FEATURES: Wooded site with surface water bodies. Primarily inactive, some business activity at the northern STATUS (Active, Inactive, or Unknown): portion of the site. LOCATION CLASS: Industrial X Commercial Urban/Residential Rural Other (specify): OVERALL HAZARD: = Serious = Moderate X Low Q Unknown BACKGROUND REVIEW: [ Complete = Preliminary O98-233 10/1/98 I DOCUMENTS USED AS REFERENCES FOR THIS PLAN: I 1) Request for Proposal - Goodwin, Proctor & Hoar 2) Draft Site Inspection Report - NUS Corporation 12/8/86 3) Proposal for Work - Foster Wheeler Environmental Corporation I 4) Draft Scope of Work for Phase I Investigation and Tier Classification (Rev. 0) Fireworks Site, Hanover, MA RTN #4-0090, July 1997 I 5) Phase I Initial Site Investigation Report and Tier Classification, Foster Wheeler Environmental Corporation, October 1997 I I PROJECT ORGANIZATION: I Project Manager: Boyd Allen Field Operations Lead: Jay Ehret Project Health and Safety Manager: Peter Vernon I Site Safety and Health Officer: Jay Ehret & Ken Carpenter Other (specify title/position): LSP - David Austin Site Investigative Lead - Jay Ehret I Radioactive Waste Evaluation - Dr. Les Skoski UXO Technical Consultant - Bud Eason I FOSTER WHEELER : ENVIRONMENTAL CORPORATION, FOSTER WHEELER SUBCONTRACTORS, AND FOSTER WHEELER'S CLIENT DO NOT GUARANTEE THE HEALTH OR SAFETY OF ANY PERSON ENTERING THIS SITE. DUE TO THE NATURE OF THIS SITE AND THE ACTIVITY OCCURRING THEREON, IT IS NOT POSSIBLE TO DISCOVER, EVALUATE, AND PROVIDE PROTECTION FOR ALL I POSSIBLE HAZARDS WHICH MAY BE ENCOUNTERED. STRICT ADHERENCE TO THE HEALTH AND SAFETY GUIDELINES SET FORTH HEREIN WILL REDUCE, BUT NOT ELIMINATE, THE POTENTIAL FOR INJURY AT THIS SITE. THE ENVIRONMENTAL HEALTH AND SAFETY GUIDELINES IN THIS PLAN WERE PREPARED SPECIFICALLY FOR THIS SITE AND SHOULD NOT BE USED ON ANY OTHER SITE WITHOUT I PRIOR RESEARCH AND EVALUATION BY TRAINED HEALTH AND SAFETY SPECIALISTS. PROJECT TASKS, POTENTIAL HAZARDS, AND CONTROL MEASURES: I I I I I I oT98-233 2 10/1/98 I flYr~ - I POTENTIAL SAFETY, HEALTH,. TASKS AND ENVIRONMENTAL HAZARDS CONTROL MEASURES Well point installation * personal exposure Surface clearing by HSO, * contact with OEW monitoring an OVM, PPE, * contact with below ground utilities contact Digsafe Stream gage e personal exposure Waders or hip boots, carefull use installation * struck by object of hammer Surface soil sampling 0 personal exposure, contact with UXO Surface clearing by an UXO (Phase I only) and OEW specialist, PPE On-site chemical e personal exposure to potential PPE and appropriate ventilation screening contaminants (Phase I only) e exposure to reagents used in field screening samples Soil boring and * personal exposure Surface clearing by an UXO monitoring well * contact with UXO and OEW specialist, monitoring with a installation * contact with below ground utilities magnetometer and an OVM, (Phase I only) PPE, contact Digsafe oT98-233 3 10/1/98 PHYSICAL SAFETY HAZARDS TO PERSONNEL: W- Hot Work O Line Breaking 7 Boating [ Drill Rigs [ Excavation W Heat = Cold 5 Precipitation = Confined Space W Terrain 11111 Walking/Working Surfaces T Fire and Explosion = Oxygen Deficiency Underground Utilities W Overhead Utilities W Heavy Equipment Unknowns in Drums, Tanks, Containers [ Ponds, Lagoons, Impoundments W Rivers, Streams FIIJ Pressurized Containers, Systems M Noise W Illumination = Nonionizing T Ionizing Radiation (potential, not confirmed) BIOLOGICAL HAZARDS TO PERSONNEL: Infectious/Medical/Hospital Waste Non-domesticated Animals Insects E Poisonous Plants/Vegetation Raw Sewage TRAINING REQUIREMENTS: 40-Hour General Site Worker Course with three days supervised experience 24-Hour Course for limited, specific tasks with one day supervised experience 24-Hour Course forLevel D Site with one day supervised experience 8-Hour Annual Refresher Health and Safety Training 8-Hour Management/Supervisor Training in addition to basic training course ~flF Site-Specific Health and Safety Training Pre-entry training for emergency response skilled support personnel 4-Hour DOT Training 4-Hour Waste Management Training - required for any personnel handling or labeling drums. Other (specify): MEDICAL SURVEILLANCE REQUIREMENTS: 3 X Baseline initial physical examination with physician certification Annual medical examination with physician certification Site-specific medical monitoring protocol (Radiation, Pesticide, PCB, Metals) Asbestos Worker medical protocol Exempt from medical surveillance (specify): Examination required in event of chemical exposure or trauma I 098-233 4 1011/98 I M o9 on o on I CoC I co o o o o~ - .ooo.or~ -Z 'a .. -Z 0 0 0 . m 0 o zo z 0 ~0 a t %. oo0 In 2 0 F-0 . ~ 2200 400 000 0 0 I-- -- oon 0 ra ~ 'Cc.* ~ E.. . ' .O-. -- -E 43 0-0 -0 0 o. o O O -4 1 AIR MONITORING: I ACTION TASK INSTRUMENT FREQUENCY LEVEL ACTION 1 Surface soil CGI/0 2 sampling X PID Before and >1 unit Stop work, during sample sustained in notify PHSM, collection breathing investigate zone source Detector tube(s) During sampling >.05 Stop work, notify PHSM, investigate source Type: Mercury Each location Radiation meter During sampling each location 2 Soil borings and X CGI/0 2 Continuous > 10% LEL Stop work, monitoring well withdraw, installation investigate cause PID Every 2 feet > 1 unit Stop work, sustained in notify PHSM, breathing investigate zone source FID Aerosol monitor X Detector tube(s) Every 2 feet > 0.05 Investigate Type: Mercury mg/m3 source, notify PHSM Radiation meter Every 2 feet > 3X bkgrd Notify PHSM, Phase I only & < Imr/hr proceed with caution, > 1 mr/hr leave area, call PHSM 3 On-site chemical CGI/0 2 U screening PID None Required Probe: eV FID I Aerosol monitor Detector tube(s) U Type: Radiation meter I CALIBRATION: ALL INSTRUMENTS WILL BE CALIBRATED ACCORDING TO MANUFACTURERS' INSTRUCTIONS BEFORE AND AFTER USE (DAILY). THE RESULTS WILL BE DOCUMENTED IN THE SSHO LOGBOOK OR CALIBRATION SHEETS. I OT98-233 6 10/198 I U U DECONTAMINATION: D_ Dry Decon: I W-Wet Decon: DESCRIPTION OF SITE-SPECIFIC DECONTAMINATION PLAN: Boot wash/rinse, wash /rinse outer gloves, remove tyvek, remove inner gloves ADEQUACY OF DECONTAMINATION DETERMINED BY: Visual observation SITE WORK ZONES: See Attachment 1. HAZARDOUS WASTE SITE AND ENVIRONMENTAL SAMPLING ACTIVITIES: Off-site: Yes x No On-site: x Yes No .. Description of types of sampling and methods used to obtain samples: Surface soil samples will be collected by field personnel using a hand auger. Subsurface soil samples will be collected by a drilling subcontractor using a drill rig with hollow stem augers and split spoons. Wells and well points installed by driller; groundwater samples collected with low-flow techniques 0T98-233 7 10/1/98 I I U I I 0) 0 I r O Lno Cy t I to I t oz - 0 bl o o o Z I - -oo to Ct -- .a8 o (ov 001 e -p C40)C x 'G o oo I O~pi T es a .~ I z Qo 9 > " - I I - a t b - v. 0o) tco - e m~e o.c . I Uz I 0)1 -bDotd o-a com 'fl. V04 m In on e .o U C Q m o *1Fr~ cc U 0- I CHEMICAL DATA: See Attachment 6 : MSDSs COMMUNICATION: List communication method/system to be used for each task and work zone. WORK OM ICATIO SPECIAL TASK ZONE METHOD INSTRUCTIONS Soil/Ground Exclusion Verbal None Wtr. Sampling Zone Soil Boring Exclusion Verbal None Zone Chemical Support Zone Verbal None Analysis EMERGENCY INFORMATION: Emergency Coordinator: Jay Ehret First Aid/CPR Trained Personnel: Jay Ehret, Bianca Hebbel, Ken Carpenter Emergency Signals/Communication: Three blasts of air horn Cellular telephone - support zone Emergency Response Procedures: See Attachment 2 Emergency Equipment: Fire extinguisher, portable eye wash, air horn, first-aid kit EMERGENCY PHONE CONTACT LOCATION I NUMBER NOTIFIED Hospital: South Shore Hospital South Shore Hospital 55 Fogg Road 617-337-7011 NA Weymouth, MA Ambulance Hanover Fire Department 911 NA Hanover Police Dept. 911 Police 550 Hanover St. non-emergency NA Hanover, MA 781-826-3231 Hanover Fire Dept. 911 Fire Department 32 Center St. non-emergency NA Hanover, MA 781-826-3151 019-233 10/1l99 9 I DIRECTIONS TO HOSPITAL: I e Leaving site, turn Right on King Street and go 0.2 mile. U 0 Bear Left onto Circuit Street and go 0.8 mile. * Turn Left onto Route 139 (West) and follow for 3.3 miles. I * Turn Right onto Route 58 (North) and follow for 1.5 miles. I * Take a Right at the end of the road onto Route 18 (North) and go 1.5 miles. - e Take a Left at Lights (3rd set) onto Fogg Road - Entrance to Hospital on your immediate Right (Emergency Entrance). I Route verified by: Date: I I I ADDITIONAL EMERGENCY PHONE CONTACTS: I CONTACT |,PHONE NUMBER Peter Vernon (Health and Safety Manager) (617) 457-8218 11(508) 429-4500 I Mike McSherry (Director, Health and Safety Programs) (215) 702-4021 H (215) 538-0471 Lee Dixon (Environmental Compliance Specialist) (617) 457-8258 H (617) 749-7279 Karen Raffa (Director, Environmental Programs) (206) 688-3768 I Chemtrec. (800) 424-9300 ATSDR (404)639-0615 ATF (explosives information) (800) 424-9555 I National Response Center (800) 424-8802 National Poison Control Center (800) 942-5969 Medical Consultant (Dr. Greaney) (800) 455-6155 I UXO and OE Programs) (303) 289-0827 H (706) 866-8890 Bud Eason (Manager, I I I I oT98-233 10 10/1/98 I NOTE: THE NATURE OF THE WORK ASSIGNMENT MAY REQUIRE THE USE OF THE FOLLOWING PROCEDURES/PROGRAMS WHICH MAY BE INCLUDED AS ATTACH- MENTS TO THIS PLAN AS APPLICABLE: CHECK IF APPLICABLE: FOSTER HEALTH OSHA WHEELER AND SAFETY STANDARD - PROGRAM OTHER Activity Hazard Analysis EHS 3-5 wT Boating EHS 6-6 Chemical Hygiene Plan 1910.1450 Confined Space Entry 1910.146 EHS 6-1 wTDemolition Safety 1926, Subpart T Drill Rig Safety . EHS 6-2 Drum and Container Handling EHS 6-7 Excavation and Trenching 1926.651 EHS 6-3 Fall Protection 1926, Subpart M EHS 3-8 Hazard Communication Program 1910.1200 EHS 4-2 Lockout/Tagout 1910.147 EHS 6-4 IwF- Temperature Extremes 1910.120 EHS 4-6 UXO Operations EHS 7-1 to 7-5 Welding/Hot Work 1910.252 EHS 6-5 ENVIRONMENTAL COMPLIANCE Transportation of Hazardous Mat. RC-3 - Signing Waste Documentation RC-4 Permit Exceedance Reporting RC-5 Reporting Spills and Releases RC-6 O -233 I I 10/1/98 I THIS PLAN WAS PREPARED FOR WORK TO BE CONDUCTED BY FOSTER WHEELER I ENVIRONMENTAL CORPORATION. USE OF THIS PLAN BY FOSTER WHEELER AND ITS SUBCONTRACTORS IS INTENDED TO FULFILL THE OSHA REQUIREMENTS FOUND IN 29 CFR 1910.120. I THE SIGNATURES BELOW INDICATE THAT THE INDIVIDUALS HAVE READ AND ^UNDER- U STOOD THE SITE-SPECIFIC SAFETY AND HEALTH PLAN. S|PRINTED NAME SIGNATURE AFFILIATION DATE I I I U I 01'98-233 12 10/1/98 I PLAN APPROVAL: By their signature, the undersigned hereby certify that this plan has been reviewed and approved for use at the Fireworks site. Project ana Date caI Fi d Oirerations Leader Date Project Health and Safety Mana er Date Site af tyandHealth fic Date 0T98-233 9/3019R 13 1 ATTACHMENT 1 SITE WORK ZONES 0198-233 10/1/98 m m iNo = m ATTACHMENT 2 EMERGENCY RESPONSE PROCEDURES OT98-233 10/1/98 Foster Wheeler RC 6 Environmental Regulatory REPORTING SPILLS AND Revised: 08/18/95 Page 1 of 5 I Compliance Program Manual RELEASES 1.0 PURPOSE The purpose of this procedure is to implement Foster Wheeler Environmental Corporation's policy of strict compliance with all reporting requirements. This procedure describes the four categories of spills that Foster Wheeler Environmental employees must report, and identifies the specific reporting process to follow for each category. Numerous federal, state, and local regulatory requirements govern spill/release reporting and response activities. Depending upon the circumstances, reporting may be necessary under federal (CWA, CERCLA, SARA Title III, RCRA, TSCA), state, and/or local spill reporting programs. Some programs specify minimum quantities, others do not. Some programs apply to virtually any spill, others are very specific. Spill/release reporting can be complex. Outside contractor employees have been indicted and convicted of criminal violations of federal spill/release reporting requirements. This obligation may hold even though the spill was made by the client and not the contractor. In the absence of such requirements, money damages may still be imposed by a court for failure to disclose knowledge of spills that present a hazard to human health. 2.0 SCOPE This procedure applies to all Foster Wheeler Environmental employees who learn of the existence of a spill or release during the course of a project. The procedure is to be implemented immediately once a Foster Wheeler Environmental employee learns of the existence of a spill or release, regardless of who may have caused the spill or when the spill may have occurred. As noted in the Project Regulatory Compliance Procedure (RC 1), it is critical that spill reporting procedures be coordinated with the client prior to initiation of the project. If the procedures are modified and a mutually agreeable criteria to responding to spills are developed with the client, the Regulatory Compliance Manager must be advised of and must approve of these modified procedures. 3.0 DEFINITIONS None. 4.0 RESPONSIBILITIES 6- PLL-PRO I. ,1.19 Foster Wheeler Environmental Regulatory RC 6 REPORTING SPILLS AND Revised: 08/18/95 Compliance Program Manual RELEASES Page 2 of 5 4.1 PROJECT PERSONNEL The Project Manager shall present these procedures to the client prior to beginning the project. The Project Manager shall assign an On-Site Spill/Release Coordinator to each remediation and waste management project. The On-Site coordinator shall be identified in the project Regulatory Compliance Plan or Waste Management Plan, and shall be trained in these procedures by the assigned Regulatory Affairs Advisor. 4.2 REGULATORY COMPLIANCE PERSONNEL The Regulatory Affairs Advisors must train the assigned On-Site Coordinators in these procedures and document that training. Any client questions or concerns regarding these procedures be shall referred to the Regulatory Affairs Advisor or the Regulatory Compliance Manager. 5.0 PROCEDURE The On-Site Coordinator, in conjunction with the assigned Regulatory Affairs Advisor and the Regulatory Compliance Manager, must determine the following: * Who caused the spill/release; * Whether it is reportable; * Who must report; * How to report, if required. The following steps must be followed to determine the answer to these questions and determine the appropriate reporting requirements. STEP 1: DETERMINE WHO CAUSED THE SPILL - FOSTER WHEELER ENVIRONMENTAL OR CLIENT Foster Wheeler EnvironmentalSpill/Release A spill/release is considered a "Foster Wheeler Environmental spill/release" if the following conditions are met: * The spill/release is physically caused by, or is suspected to have been a Foster caused by, Wheeler Environmental or Foster Wheeler Environmental subcontractor employee. 6-Sf'I Lb PRO August 1S. 1995 Foster Wheeler RC 6 Environmental Regulatory REPORTING SPILLS AND Revised: 08/18/95 Compliance Program Manual RELEASES Page 3.of 5 * The spill/release is from, or is suspected to have been from, a facility or equipment that meets one of the following criteria: - owned by Foster Wheeler Environmental or a Foster Wheeler Environmental subcontractor - operated by Foster Wheeler Environmental or a Foster Wheeler Environmental subcontractor - under Foster Wheeler Environmental's direct or indirect control as a construction manager, oversight contractor, or similar capacity. Client Spill/Release All. other spills/releases are considered "client spills/releases" for purposes of this procedure. STEP 2: DETERMINE IF THE SPILL OR RELEASE IS REPORTABLE After responding to the spill as directed in the Foster Wheeler Environmental Health and Safety procedures, the On-Site Coordinator assigned to the project must contact the Regulatory Affairs Advisor to determine if the spill or release is subject to any federal, state, or local reporting requirements. The on-site coordinator must provide an estimate of quantity and concentration of the material spilled or released, and other details of the spill/release. The Regulatory Affairs Advisor will identify what agencies need to be notified and the type of notification (i.e., written or verbal) required. STEP 3: DETERMINE IF THE SPILL OR RELEASE POSES A THREAT TO HUMAN HEALTH If no reporting requirement is identified in Step 2, the Regulatory Affairs Advisor will contact the Regulatory Compliance Manager. The Regulatory Compliance Manager will determine if the spill or release poses a threat to human health. For purposes of this procedure a spill/release is considered to present a hazard to human health if the following criteria are met: * The spill or release results, or may result, in downgradient groundwater contamination that has entered, or is about to enter, known drinking water sources (wells or surface water bodies) * The spill or release has caused, or is about to cause, contamination of surface soils or other materials in areas accessible to the general public 6-SPILL. PRO Augus IS. 1995 Foster Wheeler RC 6 U Environmental Regulatory REPORTING SPILLS AND Revised: 08/18/95 Compliance Program Manual RELEASES Page 4 of 5 U * The spill or release has caused, or is about to cause, odors/air contamination detectable in areas accessible to the general public. I STEP 4: REPORT THE SPILL OR RELEASE I Spills or releases that are either "reportable" (Step 2) or determined to pose a "hazard" (Step 3) must be reported as specified in Table I below. Spills or releases which are not "reportable" (Step 2) or determined not to pose a "hazard" (Step 3) need not be reported I to an agency, but response information should be provided to the client and retained in the project file. These determinations and how the release was reported, if applicable, must be documented in the project file. I I I I I I I I I I I I 6-SPILL. PRO Augus IS. 1995 I I Foster Wheeler RC Environmental Regulatory REPORTING 6 SPILLS AND Revised: 08/18/95 Compliance Program Manual RELEASES Page 5 of S TABE -CAiTEGOIES AND ACTIONS FOR'REPORTING SPILIB OR RELEASES PARTY WHO REPORTABLE NOTREPO CAUSEDSPL TO AGENCYTHREATTO HUMAN HEALTH (' Immediately report to the client and a The Project Manager and Regulatory Foster Wheeler regulatory agencies. Compliance Manager will report to client Environmental a Regulatory Affairs Advisor must provide a Regulatory Compliance Regulatory Compliance Manager with verbal Manager and client will determine whether to report to and written notification of the spill, agencies. Real-Time SpillRelease. IfFoster Wheeler a The Project Environmental Manager and Regulatory personnel observe the occurrence Compliance of the Manager will report to client. spill or release or learn of it immediately 2 Regulatory after it happens: Compliance Manager and client will determine whether to report to agencies. * Project Manager shall immediately contact the client to give the client a "right of first Client refusal" to report the spill/release, and notify the Regulatory Compliance Manager. * If the client cannot be reached or declines to report, Project Manager shall report to the regulatory agencies as specified in Step 2 above. Historic Spill or Release. If Foster Wheeler Environmental personnel observe or-learn of evidence that aspill or release has occurred in the past: " Regulatory Affairs Advisor will immediately notify the Regulatory Compliance Manager. " The Regulatory Compliance Manager along with Project Manager will notify the client and evaluate whether the spill or release has been reported or whether to report to regulatory agencies. 6.0 TRAINING All project personnel must I be trained in this and other Regulatory Compliance Procedures Policies. The assigned and project Spill/Release Coordinator may contact the Advisor if Regulatory Affairs I additional training is required in order to implement this procedure. 7.0 REFERENCES I None. I ---End of Section--- I 6-SPILL.PRO I Augu 18. 1995 I ATTACHMENT 3 ACTIVITY HAZARD ANALYSES OT98-233 10/1/98 I U FOSTER WHEELER ENVIRONMENTAL CORPORATION I ACTIVITY HAZARD ANALYSIS I Project Identification: Location: Estimated Start Date: Fireworks Site Hanover, MA. July 14, 1997 I Phase of Work Phase I Analysis Performed by: Analysis Approved by: and Tier Classification Ken Carpenter Peter Vernon, CSP TAS POyENTIAL HAZARDS CNRLMAUE avoidance. Soil Sampling Exposure to Chemical e Practice contamination Hazards * Follow proper personal and sample decontamination procedures. * Wash hands/face immediately after decontamination. * Wear chemical safety goggles when handling chemical sample preservatives and samples. * Wear nitrile gloves when collecting or handling samples. * Disposable booties will be worn when walking in areas of potential contamination. * Contaminated sampling materials, decontamination solutions, and PPE will be properly disposed. * Material Safety Data Sheets (MSDSs) for decon solutions and field test kit chemicals will be reviewed and attached to the HASP. Chemical Data Sheets for site contaminants will be reviewed and attached to the HASP. Manual Lifting and Material o Use proper lifting techniques. Handling e Team lifting will be used for heavy loads. Sampling Tools e Daily inspections will be performed. * Remove broken or damaged tools from service. * Use in accordance with manufacturers instructions. * Use the tool for its intended purpose. OT98-233 3.] 10/1/98 I FOSTER WHEELER ENVIRONMENTAL CORPORATION I ACTIVITY HAZARD ANALYSIS I Project Identification: Location: Estimated Start Date: Fireworks Site Hanover, MA. July 14, 1997 Phase of Work Phase I Analysis Performed by: Analysis Approved by: and Tier Classification Ken Carpenter Peter Vernon, CSP SHAZARDS ONTROL MEA Soil Sampling Dropped objects * Steel toe boots meeting ANSI Z41 will be worn (exception for UXO Specialist to avoid interference with metal dececting equipment). * Hardhats will be worn if overhead hazards exist. Slip/Trip/Falls * Work areas and means of access shall be maintained neat and orderly. * Even terrain will be utilized as unloading areas. Eye Injury " Safety glasses meeting ANSI Z87 will be worn. Underground Hazards * Before advancing tools or probes into soil to depths greater than 1.5 feet, any underground utilities must be identified through plans or Digsafe". * Screening by UXO Specialist. * In areas where vehicular traffic is present, high Vehicular Traffic visibility vests will be worn. * Emergency telephone numbers will be verified. Emergency Procedures " Directions to Hospital will be verified. * Eastern Edison's emergency procedures and notification systems will be reviewd by Foster Wheeler personnel prior to commencing work. 3-2 I - I I __ - 'a 'a 4) -ca C U a .- 'a 4) I-c *0-- 'ac a. 4) . CS to o 'a C too C N - C ~ o 'a .5 2 4) -o ons .- "S -' 25 E4) 4) ' o- io.; C.o 4)'a - 4 0wn C-l o0o -on 4)- .5-4. 'a '- a.2 C u' e. 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I~ 'a C I 1.~a 'a 4, ~ '4- 4, C C's 04 Co 4) "so C 4- --. 4- 4)1-. 0'- C's I t-4, 4, 00 <04 0404 '- 0 I Co .4-4 32 4- 1 I a ' 4,84 I Co -4) I Co o 4'>oa Co 1-4 o C 'a - .0 o) I Co - 0 '.43on Co 0 -Co 0.2 '- C C" Co to A-C's < 0 0 0 1 4, .a C' N 'C U 4) .- I ., Ct 1- 4) I- <4 0400 'La- .- 04 I-c 'cd I FOSTER WHEELER ENVIRONMENTAL CORPORATION ACTIVITY HAZARD ANALYSIS Project Identification: Location: Estimated Start Date: Fireworks Hanover, MA 10/98 Phase of Work: Analysis Performed by: Reviewed by: Phase IHA Assessment Peter Vernon Jay Ehret POTENTIAL. TAS HAZARDS CONTROL.MEURES Well Sampling Exposure to Chemical * Wear nitrile outer and inner gloves. Hazards " Follow proper personal and sample decontamination procedures. * Wash hands/face immediately after decontamination. " Wear safety glasses when handling chemical sample preservatives and samples. " Avoid splashing. If inevitable, personnel should stay out of splash radius and wear tyvek coveralls. * Air monitoring will be performed in accordance with SSHP. Manual Lifting and * Use proper lifting techniques. Material Handling e Team lifting will be used for heavy loads. Hand and Power Tool a Daily inspections will be performed. Usage e Remove broken or damaged tools from service. * PPE as required. * Use in accordance with manufacturer's instructions. * Use the tool for its intended purpose. e Use safety glasses when operating. Dropped Objects e Steel toe boots meeting ANSI Z41 will be worn. Slip/Trip/Falls e Work areas and means of access will be maintained neat and orderly. * Even terrain will be utilized as unloading areas. Eye Injury * Safety glasses meeting ANSI Z87 will be worn. * Portable eye wash station will be available. Cuts and Scrapes * First aid kit will be readily available. Spills e Spill absorbing materials will be readily available. Temperature Extremes " A heated area or vehicle will be available for warm up as necessary. * Proper clothing will be worn, suitable for the current conditions. " All personnel will be familiar with the symptoms of hypothermia/Heat Stress. OTs-233 3-11l 10/2/98 FOSTER WHEELER ENVIRONMENTAL CORPORATION I ACTIVITY HAZARD ANALYSIS I Project Identification: Location: Estimated Start Date: Fireworks Hanover, MA 10/98 I Phase of Work: Analysis Performed by: Reviewed by: Phase IIA Assessment Peter Vernon Jay Ehret POTENTIAL TASK HAZARDS CONTROL MEASURES Sample Shipping Shipping Samples to * Nitrile surgical gloves will be worn when Analytical Lab handling samples. * Foster Wheeler personnel will clean sample containers before packaging and shipping. Manual Lifting of Sample * All provisions of Foster Wheeler's SSHP Coolers will be observed. e Team lifting will be used with greater than 30 lbs. Generator Fueling Fire * Generator will not be refueled while operating. * Fuel cans will be approved by NFPA. * Fuel cans will be equipped with pouring spout or a funnel will be used. e Hot generator will not be stored near combustible or flammable materials. * Fuel caps will be secured before the generator is restarted. a Spilled fuel will be cleaned up immediately. * Smoking and open flames will not be permitted in refueling areas. e Fuel oil, lubricating oil, and dirt will be removed from the generator surface prior to fueling. * If a generator is hot, refueling will not I begin until the generator has cooled down sufficiently (approximately 10 to 15 minutes). I * The generator will be moved to another location prior to restarting (at least 3 meters from the fueling area). * 20-lb. ABC type approved fire I extinguishers will be readily available in fueling areas. I Fuel/Oil Exposure * Protective clothing (chemical gloves and safety glasses) will be worn during fueling operations. * Skin will be rinsed with water if contact I with hazardous materials occurs. oT98-233 3-12 I 10/2/98 I FOSTER WHEELER ENVIRONMENTAL CORPORATION ACTIVITY HAZARD ANALYSIS Project Identification: Location: Estimated Start Date: Fireworks Hanover, MA 9/98 Phase of Work: Analysis Performed by: Reviewed by: Phase llA Assessment Peter Vernon Jay Ehret POTENTIA L TASK. .HAZARDS CONTRQL MEAStURES Generator Oiling and Spills * Covers will be secured on equipment and Fueling (cont'd) containers after each use. * Spilled fuel or oil will be cleaned up immediately. * Spill and absorbent materials will be readily available near fueling and oiling areas. * Only approved fuel and oil cans will be used. a Generator will be placed on bare ground prior to fueling to minimize cleanup area if spills were to occur. Generator Startup Struck By e Startup areas will be free of obstructions. Operation of Gas Powered Fire * Generator will be used in accordance with Generator During manufacturer's instructions. Sampling * Fire extinguisher will be available on-site. * Generator will be operated only in well ventilated area. Explosion * Wells will be monitored for methane buildup prior to operation of the generator. * If air monitoring produces readings at or above 10% of the LEL, the work zone will be vented until the LEL drops below this level. Hazardous Materials o Generators will be run in well ventilated Exposure areas to prevent carbon monoxide accumulation. o Personnel will be informed of the potential chemical hazards of gasoline, bar oil, grease, and other hazardous materials. e Appropriate PPE (gloves, coveralls, etc.) will be provided. e Personnel will wash immediately after contact with hazardous materials. Generator Shutdown Fire e Hot generators will not be placed into storage until they have cooled down (approximately 30 minutes). Generator Cleaning Struck By * Generators will not be cleaned or adjusted with engine running. 0 8.233 3-13 10/298 I FOSTER WHEELER ENVIRONMENTAL CORPORATION ACTIVITY HAZARD ANALYSIS I Date: I Project Identification: Location: Estimated Start Fireworks Hanover, MA 10/98 Phase of Work: Analysis Performed by: Reviewed by: I Phase IIA Assessment Peter Vernon Jay Ehret POTENT...... IAL . M. TAKHAZARDS CONTROL MEASURES I Manual Handling of Slip/Trip/Falls * Site personnel will be informed of potential Generator poor footing. " Tripping and poor footing hazards will be repaired as they are discovered or will be I clearly identified. * Debris will not be allowed to accumulate to the point where it exacerbates slipping and I tripping potential. Back Injuries e Site personnel will be instructed on proper lifting techniques. I * Team lifting will be used in lieu of mechanical devices. * Mechanical devices will be utilized to I reduce manual material handling. Sharp Objects o Keep guards in place during use. * First aid kits will be available adjacent to I work areas. Installing Staff Gages Attaching Graduated * Use Drills and masonry bits per I Index to Structure manufacturers instructions " Daily tool inspections will be performed. * Remove broken or damaged tools from I service. * PPE as required. " Use the tool for its intended purpose. U * Use safety glasses when operating. " Tool will be double insulated or GFCI protected. I " Secure footing will be maintained. * Adequate protection from vehicles will be provided. I Driving Indexed Pole Into e Pole will be steadied while it is started Substrate. into substrate and will stand free.^ I * The pole will be held well below the striking area. * Leather Gloves will be worn. * Safety glasses will be worn. I I I OTs-233 3-14 10/2/98 I * ATTACHMENT 4 UIXO PROCEDURES I OT8-3 I019 UXO PROCEDURES Surface Clea-rance and Drilling Procedures Prior to soil sampling activities and/or monitoring well installation, the surface of each intended work area will be inspected for any potential UXO hazards to ensure worker safety. Any suspected UXO items when encountered will not be moved or recovered. The health and safety officer will mark its location with a red pin flag to warn personnel to stay clear. The immediate area surrounding the red pin flag will be evacuated and all work efforts will be shifted to a new location. The HSO will immediately contact Foster Wheeler's Project Manager and UXO coordinator. The Joint Defense Group Technical Manager will also be notified in accordance with the Emergency Response Plan. If during drilling advancement, any suspicious objects are encountered that could possibly UXO materials, borehole activity will be abandoned, tools withdrawn, the location marked with a red pin flag and work shifted to a new location as described above. The HSO will immediately contact Foster Wheeler's Project Manager and UXO coordinator. The Joint Defense Group Technical Manager will also be notified in accordance with the Emergency Response Plan. oT98-233 4.1 10/1/98 ATTACHMENT 5 HOSPITAL ROUTE MAP OT98-233 10//98 Mag 13.00 13:37 1997 i Jun 20 ;le 1:50,000 (at center) 5000 Feet 10 eters - -- - -r-' - - - - * ATTACHMENT 6 MSDSs O)8-233 10/1/98 3 ://siri.org/msds/h/qI 77/q38495 http://siri.org/msds/h/ql77/q38495 HYDROCHLOR FISHER SCIENTIFIC CHEMICAL DIV -- HYDROCHLORIC ACID,MURIATIC ACID,A-144 - MATERIAL SAFETY DATA SHEET NSN: 6810011458100 Manufacturer's CAGE: 1B464 Part No. Indicator: A Part Number/Trade Name: HYDROCHLORIC ACID,MURIATIC ACID,A-144 General Information Item Name: HYDROCHLORIC ACID,ACS Company's Name: FISHER SCIENTIFIC, CHEMICAL DIV. Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 Company's Emerg Ph #: 201-796-7100 OR 201-796-7523 Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 007 Status: SE Date MSDS Prepared: 10MAY91 Safety Data Review Date: 23DEC91 Supply Item Manager: CX MSDS Serial Number: BLMWK Specification Number: O-C-265 Hazard Characteristic Code: Cl Unit Of Issue: DR Unit Of Issue Container Qty: 6.500 GALLONS Type Of Container: DRUM Net Unit Weight: 65.0 LBS Ingredients/Identity Information Proprietary: NO Ingredient: HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA ITT) Ingredient Sequence Number: 01 Percent: 37 NIOSH (RTECS) Number: MW4025000 CAS Number: 7647-01-0 OSHA PEL: C 5 PPM ACGIH TLV: C 5 PPM; 9192 Other Recommended Limit: NONE SPECIFIED ------Proprietary: NO Ingredient: WATER Ingredient Sequence Number: 02 Percent: 63 NIOSH (RTECS) Number: ZC0110000 CAS Number: 7732-18-5 U OSHA PEL: NOT RELEVANT ACGIH TLV: NOT RELEVANT Other Recommended Limit: NONE SPECIFIED ------Physical/Chemical Characteristics Appearance And Odor: COLORLESS TO YELLOW LIQUID WITH A PUNGENT, IRRITATING ODOR. Boiling Point: UNKNOWN Melting Point: UNKNOWN Vapor Pressure (MM Eg/70 F): UNKNOWN Vapor Density (Air=1): 1.3 Specific Gravity: 1.2 Decomposition Temperature: UNKNOWN Evaporation Rate And Ref: UNKNOWN 6/4/97 10:49 AM http://si ri.org/msds/h/q177/q38495 . http://siri.org/msds/h/q177/q384 Solubility In Water: COMPLETE Viscosity: UNKNOWN pH: 1.1 Corrosion Rate (IPY): UNKNOWN Fire and Explosion Hazard Data5 Flash Point: NONE Extinguishing Media: USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL FOR SURROUNDING FIRE. DO NOT PUT WATER INTO THE ACID TANK. Special Fire Fighting Proc: WEAR A FULL FACE SELF-CONTAINED BREATHING APPARATUS AND IMPERVIOUS CLOTHING. PREVENT HUMAN EXPOSURE TO FIRE, FUMES/ PRODUCTS OF COMBUSTION. Unusual Fire And Expl Hazrds: EXCESSIVE HEAT MAY CAUSE THE TANK TO RUPTURE. TAKE CARE NOT TO IGNITE HYDROGEN GAS WHICH CAN ACCUMULATE INSIDE METAL TANKS CONTAINING HYDROCHLORIC ACID. Reactivity Data Stability: YES Cond To Avoid (Stability): STABLE AT NORMAL AMBIENT TEMPERATURES AND ATMOSPHERIC PRESSURE. RELEASES HYDROGEN CHLORIDE GAS WHEN HEATED. Materials To Avoid: ACETIC ANHYDRIDE,ALCOHOLIC HYDROGEN CYANIDE,AL,2- AMINOETHANOL, NH40H, BASES,WATER, BRASS,STRONG OXIDIZERS,METALS, FLUORINE Hazardous Decomp Products: WITH METALS GIVES HYDROGEN GAS,WHICH WHEN MIXED WITH AIR,MAY RESULT IN EXPLOSION OR FIRE.WITH OXIDIZER GIVES OFF CL2. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NONE Health Hazard Data LD50-LC50 Mixture: LC50 INHALATION-RAT 4701 PPM/30 MINUTES Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE-INHALATION:MAY CAUSE IRRITATION, BURNING,COUGHING,CHOKING,HEADACHE,PULMONARY EDEMA,LIVER DAMAGE & DEATH. EYES:CAN CAUSE SEVERE IRRITATION,BURNS,LOSS OF VISION.SKIN:SEVERE IRRITATION,NECROSIS & BURNS.INGESTION:MAY CAUSE SEVERE BURNS TO MOUTH, THROAT & STOMACH.DEATH MAY OCCUR.CHRONIC-BRONCHITIS,GASTRITIS,DERMATITIS Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Signs/Symptoms Of Overexp: INHALATION MAY CAUSE IRRITATION, BURNING, COUGHING, CHOKING, HEADACHE, PULMONARY EDEMA, LIVER DAMAGE & DEATH. CAN CAUSE SEVERE EYE IRRITATION, BURNS, LOSS OF VISION. MAY RESULT IN SEVERE IRRITATION, NECROSIS, ULCERATION & BURNS OF SKIN. INGESTION MAY CAUSE SEVERE BURNS TO MOUTH, THROAT & STOMACH. DEATH MAY OCCUR. Med Cond Aggravated By Exp: PRE-EXISTING SKIN DISORDERS IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.KEEP EYELIDS OPEN. INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NECESSARY.INGESTION:DO NOT USE GASTRIC LAVAGE/EMESIS.IF CONSCIOUS,DRINK LARGE AMOUNT OF WATER/ MILK.IF VOMITING OCCURS,DRINK FLUIDS REPEATEDLY.INGESTED ACID MUST BE DILUTED 100 FOLD TO RENDER IT HARMLESS TO TISSUE.TREAT SYMPTOMATICALLY. Precautions for Safe Handling and Use Steps If Matl Released/Spill: WEAR PROPER PROTECTIVE EQUIPMENT.EVACUATE AREA,KEEP UPWIND.WEAR SELF-CONTAINED BREATHING APPARATUS.DIKE LARGE SPILLS. COVER SPILLS WITH SODIUM BICARBONATE,SODA ASH, OR LIME.AVOID FOAMING. TRANSFER TO DOT APPROVED CONTAINERS.IF SMALL SPILLS, USE SAND. Neutralizing Agent: SODA ASH, LIME, SODIUM BICARBONATE Waste Disposal Method: CONTACT FEDERAL, COUNTY, AND LOCAL ENVIRONMENTAL REGULATORS FOR GUIDANCE REGARDING PROPER DISPOSAL. Precautions-Handling/Storing: STORAGE-STORE IN A COOL WELL VENTILATED 2 of 4 6/4/97 10:49 A j ://siri.org/msds/h/q I 77/q384 95 http://siri.org/msds/h/ql77/q3849 5 PLACE AWAY FROM SUN & HEAT.STORE IN AN UPRIGHT POSITION. E IF Precautions: DANGER! CORROSIVE; BURNS EYES AND SKIN.HARMFUL Other VAPORS. DO NOT GET IN EYES,ON SKIN,OR ON CLOTHING.DO NOT BREATH SWALLOWED. INTO WATER. KEEP CONTAINER CLOSED.DO NOT TAKE INTERNALLY.ALWAYS POUR ACID REPORTABLE QUANTITY IS 5000 POUNDS. Control Measures SAFETY AND Respiratory Protection: USE NATIONAL INSTITUTE OF OCCUPATIONAL (MSHA) APPROVED HEALTH (NIOSH) OR MINE SAFETY AND HEALTH ADMINISTRATION EXPOSURE LIMITS RESPIRATOR APPROPRIATE FOR THIS PRODUCT WHEN PERMISSIBLE DARE EXCEEDED. EXPOSURE Ventilation: PROVIDE GENERAL VENTILATION TO MEET OSHA PERMISSIBLE LIMITS (OSHA PEL). Protective Gloves: RUBBER OR NEOPRENE E Eye Protection: CHEMICAL SAFETY GOGGLES & FACE SHIELD AND RUBBER BOOTS. Other Protective Equipment: USE RUBBER SPLASH APRON EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Transportation Data Trans Data Review Date: 91357 DOT PSN Code: HJG SOLUTION DOT Proper Shipping Name: HYDROCHLORIC ACID, DOT Class: 8 DOT ID Number: UN1789 DOT Pack Group: II DOT Label: CORROSIVE IMO PSN Code: IEX IMO Proper Shipping Name: HYDROCHLORIC ACID,SOLUTION IMO Regulations Page Number: 8183 IMO UN Number: 1789 IMO UN Class: 8 IMO Subsidiary Risk Label: - IATA PSN Code: NPG IATA UN ID Number: 1789 IATA Proper Shipping Name: HYDROCHLORIC ACID SOLUTION I IATA UN Class: 8 IATA Label: CORROSIVE AFI PSN Code: NPG AFI Symbols: T AFI Prop. Shipping Name: HYDROCHLORIC ACID, SOLUTION AFI Class: 8 AFI ID Number: UN1789 AFI Pack Group: II AFI Label: CORROSIVE AFI Special Prov: A3,A6,N41 AFI Basic Pac Ref: 12-5 3 Disposal Data 3 Label Data Label Required: YES Technical Review Date: 23DEC91 MFR Label Number: UNKNOWN Label Status: F Common Name: HYDROCHLORIC ACID,MURIATIC ACID,A-144 Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Severe: X Fire Hazard-None: X Reactivity Hazard-Slight: X 6/4/97 10:49 AM ttp://siri.org/msds/h/qlI77/q3 8495 http://siri.org/msds/h/ql77/q38495 Special Hazard Precautions: ACUTE-INHALATION:-LAY CAUSE IRRITATION,BURNING, COUGHING,CHOKING, HEADACHE, PULMONARY EDEMA, LIVER DAMAGE & DEATH.EYES:CAN CAUSE SEVERE IRRITATION,BURNS,LOSS OF VISION.SKIN:SEVERE IRRITATION, I NECROSIS & BURNS.INGESTION:MAY CAUSE SEVERE EURNS TO MIOUTH,THROAT & STOMACH.DEATH MAY OCCUR.CHRONIC-BRONCHITIS,GASTRITIS, DERMATITIS.STORAGE- STORE IN A COOL WELL VENTILATED PLACE.FIRST AID-GET PEDICAL CARE IN ALL CASES.EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.KEEP I EYELIDS OPEN.INHALATION:REMOVE TO FRESH AIR.G-VE CPR/OXYGEN IF NECESSARY. INGESTION:DO NOT USE GASTRIC LAVAGE/EMESIS.IF CONSCIOUS,DRINK WATER/MILK. ACID SHOULD BE DILUTED 100 FOLDS Protect Eye: Y I Protect Skin: Y Protect Respiratory: Y Label Name: FISHER SCIENTIFIC, CHEMICAL DIV. Label Street: 1 REAGENT LANE I Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410 I Label Country: US Label Emergency Number: 201-796-7100 OR 201-76-7523 URL for this msds http://siri.org. If you wish to change, add to, or I delete information in this archive please send updates to [email protected]. I U I I I I I I U I I Ml ://siri.org/msds/h/q321/q110209 http://siri.org/msds/h/q321/ql 10209 I QUEMETCO -- PURE LEAD MATERIAL SAFETY DATA SHEET NSN: 965000N052418 Manufacturer's CAGE: 9N315 E Part No. Indicator: A Part Number/Trade Name: PURE LEAD General Information Company's Name: QUEMETCO INC Company's Street: 720 SOUTH SEVENTH AVE Company's City: CITY OF INDUSTRY Company's State: CA Company's Country: US Company's Zip Code: 91745 Company's Emerg Ph #: 214-631-6070 Company's Info Ph #: 214-631-6070 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 I Status: SMJ Date MSDS Prepared: 01DEC88 Safety Data Review Date: 25AUG94 MSDS Serial Number: BVMFX I Hazard Characteristic Code: NK ------Ingredients/Identity Information U Proprietary: NO Ingredient: LEAD (SARA III) Ingredient Sequence Number: 01 Percent: >99.9 I NIOSH (RTECS) Number: OF7525000 CAS Number: 7439-92-1 OSHA PEL: SEE 1910.1025 ACGIH TLV: 0.15 MG/M3,DUST ------Proprietary: NO Ingredient: OTHER PRECAUT:OR LAUNDERED W/PERSONAL CLTHG. LAUNDER CONTAMD CLTHG BEFORE REUSE. WASH HANDS, FACE, NECK & ARMS (ING 3) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 2:THORO BEFORE EATING, DRINKING/SMOKING. THIS PROD IS INTENDED FOR INDUS USE ONLY & SHOULD BE ISOLATED (ING 4) Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE U ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 3:FROM CHILDREN AND THEIR ENVIRONMENT. Ingredient Sequence Number:. 04 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: RESP PROT:LOCAL AND STATE REGULATIONS MAY ALSO APPLY. Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE 6/4/97 10:53 AM http://siri.org/msds/h/q321/ql 10209 http://siri.org/msds/h/q321/ql 1020 Proprietary: NO Ingredient: VENT:HYGIENISTS, SHALL BE PROVIDED IN AREAS WHERE EXPOS ARE ABOVE PEL/THRESHOLD LIM VALUES SPECIFIED BY OSHA (ING 7) Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 6:OR OTHER LOCAL, STATE AND FEDERAL REGULATIONS. Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: OTHER PROT EQUIP:DISPOS OF I/A/W LOCAL, STATE & FED REGS. HARD HAT, SFTY BOOTS & OTHER SFTY EQUIP SHOULD BE WORN (ING 9) Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO SHOULD Ingredient: ING 8:AS APPROP FOR INDUS ENVIRON. PERSON CLTHG & SHOES BE PROTECT FROM CONTAMINATION W/THIS PRODUCT. Ingredient Sequence Number: 09 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: HYGIENE PRAC:NON-CONTAMINATED AREAS. Ingredient Sequence Number: 10 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: SUPDAT:REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZARD LSIT INFO AND (ING 12) Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: N/K (FP N) ACGIH TLV: NK (FP N) Ingredient: ING ll:SAFE HANDLING & EXPOSURE INFORMATION (FP N). Ingredient Sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: FIRST AID PROC:OCCUP EXPOS.TO LEAD (29CFR 1910.1925). Ingredient Sequence Number: 13 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Physical/Chemical Characteristics ODOR Appearance And Odor: SILVER-GREY METAL, TARNISHES; NO APPARENT Boiling Point: 3164F,1740C 1 2 of5 6/4/97 10:53 AM - :/siri.org/msds/h/q321/ql10209 http://siri.org/msds/h/q321/ql10209 I Melting Point: 621F,327C Vapor Pressure (MM Hg/70 F): N/A Vapor Density (Air=1): N/A Specific Gravity: 11.3 (H+20=1) Evaporation Rate And Ref: NOT APPLICABLE Solubility In Water: NEGLIGIBLE Percent Volatiles By Volume: N/A ------Fire and Explosion Hazard Data Flash Point: N/A Lower Explosive Limit: N/A Upper Explosive Limit: N/A BE USED ON Extinguishing Media: DRY CHEMICAL/CARBON DIOXIDE SHOULD METAL IS PRESENT. SURROUNDING FIRE. DO NOT USE WATER ON FIRES WHEN MOLTEN SCBA OPERATED IN EsSpecial Fire Fighting Proc: USE NIOSH/MSHA APPROVED POSITIVE-PRESS MODE AND FULL BODY PROT CLOTHING. AND/OR Unusual Fire And Expl Hazrds: MOLTEN METALS PRODUCE FUME, VAPOR, OR ITS DUST, CAN DUST THAT MAY BE TOX AND/OR RESP IRRITANTS. THE PRODUCT, E REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS. ------Reactivity Data ------I Stability: YES Cond To Avoid (Stability): NOT APPLICABLE MAY LIBERATE Materials To Avoid: STRONG OXIDIZERS AND THIS PRODUCT HYDROGEN GAS. METAL FUME, Hazardous Decomp Products: HIGH TEMPERATURES MAY PRODUCE HEAVY VAPOR AND/OR DUST. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT. Health Hazard Data LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of.Entry - Ingestion: YES VOMIT, Health Haz Acute And Chronic: ACUTE:IF LEFT UNTREATED:WEAKNESS, STUPOR & LOSS OF APPETITE, UNCOORDINATED BODY MOVEMENTS, CONVULSIONS, TO RESP SYS & POSSIBLY COMA. INHAL:DUST, VAP AND/OR FUME MAY BE IRRITATING AND/OR FUME MAY CAN RSLT IN BOTH ACUTE & CHRONIC OVEREXP. SKIN:DUST, VAP I CAUSE IRRIT. SKIN ABSORP:DUST, VAP AND/OR (EFTS OF OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. ABSORBED THRU Signs/Symptoms Of Overexp: HLTH HAZ:FUME ARE NOT READILY VAP AND/OR SKIN. EYE:DUST, VAP AND/OR FUME MAY CAUSE IRRIT. INGEST:DUST, ACUTE & CHRONIC FUME MAY BE ABSORBED BY DIGESTIVE SYS & CAN RSLT IN BOTH SLIGHT IRRIT OVEREXP. CHRONIC:IF LEFT UNTREATED:WEAK, INSOM, HYPERTENSION, TO SKIN & EYES, METALLIC TASTE IN MOUTH, (SUPDAT) AND/ OR Med Cond Aggravated By Exp: CHRONIC FORMS OF KIDNEY, HEMATOPOEITIC DISORDERS MAY BE NEUROLOGIC DISEASES, PREEXISTING SKIN AND/OR RESPIRATORY AGGRAVATED BY EXPOSURE TO THIS PRODUCT. COOL WATER FOR AT Emergency/First Aid Proc: EYES:FLUSH W/COPIOUS QTYS OF OF OVEREXP. INGEST:GET REMOVE FROM EXPOS. GET MED ATTN IF EXPERIENCING EFTS ARE NEUROTOXINS IMMED MED ATTN. NOTES TO PHYS:LEAD & ITS INORGAN CMPDS OF EFTS OF LEAD WHICH MAY PRODUCE PERIPHERAL NEUROPATHY. FOR AN OVERVIEW EXPOS, CONSULT OCCUP SFTY & HLTH ADMIN APPENDIX A OF (ING 13) Precautions for Safe Handling and Use OR WET SWEPT Steps If Matl Released/Spill: DUST MATL SHOULD BE VACUUMED, SHOULD BE STORED IN DRY WHERE VACUUMING IS NOT FEASIBLE. PARTICULATE MATTER 6/4/97 10:53 AM http://siri.org/msds/h/q32 I/q 110209 http://siri.org/msds/h/q321/q l1020 CNTNRS FOR LATER DISP. DO NOT USE COMPRESSED AIR/DRY SWEEPING AS A MEANS OF CLEANING. Neutralizing Agent: NOT APPLICABLE Waste Disposal Method: DISPOSE OF TOX SUBSTANCES AND HAZARDOUS WASTES IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Precautions-Handling/Storing: STORE IN COOL, DRY AREA WHERE ACCIDENTAL CONT W/ACIDS IS NOT POSS. AVOID SKIN CONT. Other Precautions: ADHERE TO ALL PERS PROT EQUIP PROCEDURES WHEN HANDLING, & VENT REQUIREMENTS WHEN HEAVY METAL EXPOSURES ARE ABOVE PEL OR THRESHOLD LIM VALUES. WORK CLOTHES & EQUIP SHOULD REMAIN IN DESIGNATED LEAD CONTAMD AREAS, & NEVER TAKEN HOME (ING 2) Control Measures Respiratory Protection: NIOSH/MSHA APPRVD RESP APPROP FOR EXPOS OF CONCERN (FP N). AS SPECIFIED BY 29CFR1910.1025 SUBPART (F) OF THE FED OCCUP SFTY & HLTH ADMIN STD OCCUP EXPOS TO LEAD. OTHER (ING 5) Ventilation: VENT, AS DESCRIBED IN INDUS VENT, A MANUAL OF REC PRACTICE PRODUCED BY AMERICAN CONFERENCE OF GOVT INDUS (ING 6) Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: VENTED GOGG/FACE SHIELD. Other Protective Equipment: COVERALLS/OTHER FULL BODY CLTHG SHALL BE WORN DURING PROD USE & PROPERLY LAUNDERED AFTER USE, W/WASH WATER (ING 8) Work Hygienic Practices: NORMAL, GOOD PERS HYGIENE PRIOR TO SMOKING, EATING/DRINKING. SMOKING, EATING & DRINKING SHOULD BE CONFINED TO (ING 10) Suppl. Safety & Health Data: EFTS OF OVEREXP:ANEMIA, CONSTIP, HDCH, MUSCLE & JOINT PAINS, NEUROMUSCULAR DYSFUNCTION, POSS PARAL & ENCEPHALOPATHY. LEAD EXPOS CAN POSE RISK TO DEVELOPING FETUSES & MAY ALSO IMPAIR REPROD SYS IN BOTH MEN & WOMEN. DMG TO KIDNEYS, HEMATOPOEITIC AND/OR CNS MAY OCCUR. LEAD APPEARS ON NAVY LISTING OF OCCUP CHEM (ING 11) Transportation Data Disposal Data Label Data Label Required: YES Technical Review Date: 25AUG94 Label Date: 29AUG94 Label Status: G Common Name: PURE LEAD Chronic Hazard: YES Signal Word: CAUTION! Acute Health Hazard-Slight: X Contact Hazard-Slight: X Fire Hazard-None: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE:INHALATION:DUST, VAPOR AND/OR FUME MAY IRRITATE RESPIRATORY SYSTEM. INGESTION:DUST, VAPOR AND/OR FUME MAY BE DUST, VAPOR AND/OR FUME MAY CAUSE IRRITATION. EYE CONTACT:DUST, VAPOR AND/ OR FUME MAY CAUSE IRRITATION. IF ANY EXPOSURE LEFT UNTREATED, WEAKNESS, VOMITING, LOSS OF APPETITE, UNCOORDINATED BODY MOVEMENTS, CONVULSIONS, STUPOR AND POSSIBLY COMA. CHRONIC:LEAD APPEARS ON NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). CAN DAMAGE KIDNEYS, BLOOD FORMING SYSTEM OR CNS. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: QUEMETCO INC Label Street: 720 SOUTH SEVENTH AVE Label City: CITY OF INDUSTRY Label State: CA I of 5 6/4/97 10:53 AM - - ' - - r -. .~s - e. - http://siri.org/msds/h/q32 1/qI 10209 t://siri.org/msds/h/q321/ql 10209 Label Zip Code: 91745 Label Country: US Label Emergency Number: 214-631-6070 URL for this msds http://siri.org. If you wish to change, add to, or delete information in this archive please send updates to [email protected]. 5 6/4/97 10:53 AM 5 of 5 http://www.wco.com/jray...ds/other/leadazide.txt lttp://www.wco.com/jray-cgi/ssie/msds/other/lead -azide.t SUBSTANCE NAME: Lead azide CAS Number: 13424-46-9 UN Number: 0129 CLASSIFICATION OF PURE SUBSTANCE Risk Phrases: R3 Extreme risk of explosion by shock, fricticn:, fire or other sources of ignition. R20/22 Harmful by inhalation and if swallowed. R33 Danger of cumulative effects. Safety Phrases: S33 Take precautionary measures against static aischarges. S34 Avoid shock and friction. S35 This material and its container must be discosed of in a safe way. CLASSIFICATION OF SUBSTANCE AS AN INGREDIENT IN MIXTUkI Health Hazard Classification : Harmful , Concentration Cut-off level 25 % weight/weight Above this concentration ingredient to be classified with R20 and/or R21 and/or R22. When classifying a substance as an ingredient in a mixture at a particular concentration cut-off level take into account any risk phrases that apply at the lower concentration cut-off level. I of 1 6/4/97 11:07 A http://www.wco.com/jray-cgi/ssie/msds/msds/magnesium.txt Ittp://www.wco.com/jray ...msds/msds/magnesium.txt MSDS - MAGNESIUM 1 - PRODUCT IDENTIFICATION PRODUCT NAME: MAGNESIUM FORMULA: MG FORMULA WT: 24.30 CAS NO.: 7439-95-4 NIOSH/RTECS NO.: OM2100000 PRODUCT CODES: 2416 EFFECTIVE: 10/24/86 REVISION #03 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 1 SLIGHT FLAMMABILITY - 4 EXTREME (FLAMMABLE) REACTIVITY - 3 SEVERE (WATER REACTIVE) CONTACT - 1 SLIGHT HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT SAFETY GLASSES; LAB COAT; CLASS D EXTINGUISHER PRECAUTIONARY LABEL STATEMENTS WARNING CAUSES IRRITATION DUST MAY FORM FLAMMABLE AND EXPLOSIVE MIXTURE WITH AIR, ESPECIALLY WHEN DAMP. KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT BREATHE DUST. KEEP.IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL, SWEEP UP AND CAREFULLY REMOVE. SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY) 2 - HAZARDOUS COMPONENTS COMPONENT % CAS NO. MAGNESIUM 90-100 7439-95-4 3 - PHYSICAL DATA BOILING POINT: 1107 C ( 2025 F) VAPOR PRESSURE(MM HG): N/A MELTING POINT: 650 C ( 1202 F) VAPOR DENSITY(AIR=1): 0.84 SPECIFIC GRAVITY: 1.74 EVAPORATION RATE: N/A (H20=1) (BUTYL ACETATE=1) SOLUBILITY(H20): DECOMPOSES % VOLATILES BY VOLUME: 0 APPEARANCE & ODOR: SILVERY, WHITE METALLIC POWDER. of 4 6/4/97 11:08 AM http://www.wco.com/jray...msds/msds/magnesium.txt http://www.wco.com/jray-cgi/ssie/msds/msds/magnesium.t 4 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP 634 C ( 1175 F) NFPA 704M RATING: 0-1-2 w FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA SMOTHER WITH DRY SODA ASH. NEVER USE WATER OR CHEMICAL FIRE EXTINGUISHERS. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. BURNS WITH A VERY BRIGHT FLAME, FIRE GLASSES MUST BE WORN. UNUSUAL FIRE & EXPLOSION HAZARDS REACTS VIOLENTLY WITH WATER PRODUCING HIGHLY FLAMMABLE VAPORS. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION. DUST MAY FORM EXPLOSIVE MIXTURE WITH AIR. TOXIC GASES PRODUCED HYDROGEN GAS 5 - HEALTH HAZARD DATA TLV IS LISTED FOR MAGNESIUM OXIDE FUME. THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM) CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. INHALATION OF FUMES MAY RESULT IN LEUKOCYTOSIS. CONTACT MAY CAUSE IRRITATION OF SKIN, EYES, AND MUCOUS MEMBRANES. TARGET ORGANS RESPIRATORY SYSTEM, EYES MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY I INHALATION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT -LEAST------15 MINUTES. FLUSH SKIN WITH WATER. 6 - REACTIVITY DATA 2of4 6/4/97 11:08 AM nesium.txt http://www.wco.com/jray-cgi/ssie/msds/msds/magnesium.txt 1p://www.wco.com/jray...msds/msds/mag OCCUR U STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT CONDITIONS TO AVOID: MOISTURE, HEAT, FLAME, OTHER SOURCES OF IGNITION I INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, WATER, HALOGENS, CYANIDES DECOMPOSITION PRODUCTS: HYDROGEN 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE FLARES, WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO SMOKING, OR FLAMES IN AREA. DO NOT USE WATER. WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER. MOVE CONTAINER(S) FROM SPILL AREA. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D001, D003 (IGNITABLE, REACTIVE WASTE) 8 - PROTECTIVE EQUIPMENT VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE. RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK. ARE EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES RECOMMENDED. 9 - STORAGE AND HANDLING PRECAUTIONS SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM WATER OR LOCATIONS WHERE WATER MAY BE USED TO EXTINGUISH FIRE. OR STORE IN A COOL, WELL-VENTILATED AREA AWAY FROM SOURCES OF HEAT, FLAME, IGNITION. 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) PROPER SHIPPING NAME MAGNESIUM METAL (POWDERED) HAZARD CLASS FLAMMABLE SOLID UN/NA UN1869 LABELS FLAMMABLE SOLID, DANGEROUS WHEN WET INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME MAGNESIUM, POWDER, NON-PYROPHORIC 6/4/97 11:08 AM http://www.wco.com/jray ...msds/msds/magnesium.txt http://www.wco.com/jray-cgi/ssie/msds/msds/magnesium.txk HAZARD CLASS 4.3 UN/NA UN14 18 LABELS DANGEROUS WHEN WET r II II I U I I I I U I I U I I I I of 4 M3 http://siri.org/msds/h/ql31/q1 5336 lp://siri.org/msds/h/q131/q15336 MERCURY - MERCURY,ACS U FISHER SCIENTIFIC CHEMICAL DIV -- MERCURY;METALLIC MATERIAL SAFETY DATA SHEET NSN: 6810006021569 Manufacturer's CAGE: 1B464 Part No. Indicator: A MERCURY Part Number/Trade Name: MERCURY;METALLIC I General Information Item Name: MERCURY,ACS DIV. Company's Name: FISHER SCIENTIFIC, CHEMICAL I Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 201-796-7523 Company's Emerg Ph #: 201-796-7100 OR Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 001 I 001 - Tot Safety Entries This Stk#: Status: SM Date MSDS Prepared: 13JUL90 Safety Data Review Date: 030CT90 Supply Item Manager: 90 MSDS Preparer's Name: GASTON L.PILLORI MSDS Serial Number: BFHRF Hazard Characteristic Code: J6 Unit Of Issue: LB Unit Of Issue Container Qty: 6 POUNDS Type Of Container: BOTTLE I Net Unit Weight: 6 LB Ingredients/Identity Information I=Proprietary: NO Ingredient: MERCURY (SARA III) Ingredient Sequence Number: 01 Percent: 100.0 NIOSH (RTECS) Number: OV4550000 CAS Number: 7439-97-6 OSHA PEL: S, C, 0.1 MG/M3 I ACGIH TLV: S, 0.05 MG/M3; 9192 Other Recommended Limit: NONE SPECIFIED Physical/Chemical Characteristics LIQUID WITH METALLIC LUSTER Appearance And Odor: COLORLESS,SILVERY Boiling Point: 674F,357C Melting Point: -38F,-39C Vapor Pressure (MM Hg/70 F): 0.002 Vapor Density (Air=1): 7.0 Specific Gravity: 13.5939 Decomposition Temperature: UNKNOWN Solubility In Water: INSOLUBLE Corrosion Rate (IPY): UNKNOWN Fire and Explosion Hazard Data Flash Point: NONE DIOXIDE, FOAM, OR DRY CHEMICAL. Extinguishing Media: USE WATER FOG, CARBON SHOULD USE NIOSH APPROVED SCBA & Special Fire Fighting Proc: FIRE FIGHTERS CHEMICAL FIRE. USE WATER SPRAY TO FULL PROTECTIVE EQUIPMENT WHEN FIGHTING COOL NEARBY CONTAINERS EXPOSED TO FIRE. BREATHING CORROSIVE AND POISONOUS Unusual Fire And Expl Hazrds: AVOID VAPORS. KEEP UPWIND. 6/4/97 10:54 AM 1 of4 http://si ri.org/msds/h/q13 1/q 15336 http://sri.org/msds//q13 1/ql533 Reactivity Data Stability: YES Cond To Avoid (Stability): EXCESSIVE HEAT Materials To Avoid: AMMONIA,METALS,O*2,OXIDANTS,ACETYLINICS,BORON, DIIDOPHOSPHIDE Hazardous Decomp Products: THERMAL DECOMPOSITION PRODUCTS INCLUDE TOXIC MERCURY VAPORS AND OXYGEN. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT APPLICABLE Health Hazard Data LD50-LC50 Mixture: LD50 (ORAL RAT) IS UNKNOWN Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE: SKIN:IRRITATION. ABSORBED THROUGH IMMEDIATE NECROSIS IN MOUTH, THROAT, ESOPHAGUS & STOMACH. DEATH MAY OCCURE. INHALATION:DYSPNEA, COUGH, FEVER, NAUSEA & VOMITING, DIARRHEA, STOMATITIS, SALIVATION & METALLIC TASTE. CHRONIC: CNS DISTURBANCES. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: DATA PER MSDS Signs/Symptoms Of Overexp: TREMORS, CONVULSIONS & OTHER CNS DISTURBANCES, PNEUMONITIS, CHEST PAINS, DYSPNEA, COUGHING, STOMATITIS, GINGIVITIS AND LOOSENING OF TEETH, SALIVATION, LOSS OF MEMORY, METALLIC TASTE, DIZZINESS, CLUMSINESS, SLURRED SPEECH, DIARRHEA, PAIN & NUMBNESS IN EXTREMITIES, NEPHRITIS, ANXIETY, HEADACHE, WEIGHT LOSS, AND INSOMNIA. Med Cond Aggravated By Exp: PERSONS WITH A HISTORY OF ALCOHOLISM, CHRONIC RISK FROM KIDNEY DISEASE OR KNOWN ALLERGY TO MERCURY MAY BE AT INCREASED EXPOSURE. - Emergency/First Aid 'Proc: INHALATION: REMOVE TO FRESH AIR. IF NOT FLUSH BREATHING GIVE CPR/OXYGEN. GET MEDICAL ATTENTION. EYE: IMMEDIATELY EYES WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH PLENTY OF OF SOAP & WATER. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. A 5% SOLUTION SODIUM FORMALDEHYDE SULFOXYLATE MAY BE USED TO INDUCE VOMITING. Precautions for Safe Handling and Use EQUIPMENT Steps If Matl Released/Spill: SMALL SPILL: PICK UP WITH VACUUM SPECIFICALLY DESIGNED FOR MERCURY PICK UP OR USE MERCURY SPILL KIT. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP LEAK. DIKE TO RETAIN. VACUUM UP FREE LIQUID. DO NOT TOUCH SPILLED MATERIAL. Neutralizing Agent: NONE CENTER. Waste Disposal Method: DO NOT INCINERATE - RETURN TO RECLAMATION Precautions-Handling/Storing: STORE IN SEALED UNBREAKABLE POLYETHYLENE CONTAINERS IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions: THIS CHEMICAL IS SUBJECT TO SARA SECTION 313 REPORTING. PROVIDE PREPLACEMENT AND PERIODIC MEDICAL EXAMS FOR THOSE REGULARLY EXPOSED TO MERCURY, WITH EMPHASIS ON CNS, SKIN, LUNGS, LIVER, KIDNEYS AND G.I. TRACT. Control Measures Respiratory Protection: IF VENTILATION DOES NOT MAINTAIN INHALATION AS PER EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR DECISION LOGIC-PUBLICATION NUMBER 87.108. IN Ventilation: PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL. 6/4/97 10:54 A 2 of 4 1/q 15336 It://siri.org/msds/h/q 1 3 http://siri.org/msds/h/q13 1/ql15336 Protective Gloves: RUBBER Eye Protection: CHEMICAL SAFETY GOGGLES Other Protective Equipment: SEPARATE WORK AND STREET CLOTHING. STORE WORK CLOTHING IN SPECIAL LOCKERS. SHOWER BEFORE CHANGING TO STREET CLOTHES. Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Suppl. Safety & Health Data: DO NOT GET ON SKIN, IN EYES OR ON CLOTHING. DO NOT BREATHE VAPORS. Transportation Data Trans Data Review Date: 88165 DOT PSN Code: IWD DOT Symbol: A,W DOT Proper Shipping Name: MERCURY DOT Class: 8 DOT ID Number: UN2809 DOT Pack Group: III DOT Label: CORROSIVE IMO PSN Code: JKJ IMO Proper Shipping Name: MERCURY IMO Regulations Page Number: 8191 IMO UN Number: 2809 IMO UN Class: 8 IMO Subsidiary Risk Label: - IATA PSN Code: PYF IATA UN ID Number: 2809 IATA Proper Shipping Name: MERCURY IATA UN Class: 8 IATA Label: CORROSIVE AFI PSN Code: PYF AFI Prop. Shipping Name: MERCURY AFI Class: 8 AFI ID Number: UN2809 AFI Pack Group: I AFI Label: CORROSIVE AFI Basic Pac Ref: 12-13 Disposal Data Disposal Data Review Date: 88291 Rec # For This Disp Entry: 01 Tot Disp Entries Per NSN: 001 Landfill Ban Item: YES Disposal Supplemental Data: MSDS DATED 12-13-86/ IN CASE OF ACCIDENTAL EXPOSURE OR DISCHARGE, CONSULT HEALTH AND SAFETY FILE FOR PRECAUTIONS. 1st EPA Haz Wst Code New: U151 1st EPA Haz Wst Name New: MERCURY 1st EPA Haz Wst Char New: TOXIC (T) 1st EPA Acute Hazard New: NO Label Data Label Required: YES Technical Review Date: 030CT90 Label Status: F Common Name: MERCURY;METALLIC MERCURY Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Slight: X Fire Hazard-None: X Reactivity Hazard-None:.X Special Hazard Precautions: CONTACT CAUSES BURNS TO SKIN AND EYES. IF INHALED, MAY BE HARMFUL. FIRE MAY PRODUCE IRRITATING OR POISONOUS GASES. 6/4/97 10:54 AM http://siri.org/msds/h/ql31/ql5336 ttp://siri.org/msds/h/ql31I/ql15336 1 CORNEAL IRRITATION. ABSORBED THROUGH SKIN CAUSING ANURIA. EYE:IRRITATION, & M! INJURY OR BURNS. INGESTION:IMMEDIATE NECROSIS IN MOUTH, THROAT, ESOPHAGUS STOMACH. INHALATION:DYSPNEA, COUGH, FEVER, NAUSEA & VOMITING, DIARRHEA, I STOMATITIS, SALIVATION & METALLIC TASTE.FIRST AID:IF INHALED OR INGESTED, WITH REMOVE TO FRESH AIR AND CONSULT A PHYSICIAN.FOR EYES AND SKIN,FLUSH PLENTY OF WATER FOR ABOUT 15-20 MINUTES AND SEEK MEDICAL ATTENTION IMMEDIATELY. I Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: FISHER SCIENTIFIC, CHEMICAL DIV. I Label Street: 1 REAGENT LANE Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410 I Label Country: US Label Emergency Number: 201-796-7100 OR 201-796-7523 If you wish to change, add to, or I. URL for this msds http://siri.org. in this archive please send updates to [email protected]. delete information I U I I U U I I I I I I 6/4/97 1054AM1 4 of 4 811 MERCURY() IODIDE I and NO,. See also MERCURY FULMI- -To- MDCOOO CAS: 628-86-4 HR: 3 Hg MERCURY(II) FULMINATE (dry) NATE (dry). I ) DOT: UN 0135 mf: CHgN202 mvi: 284.63 MDC500 CAS: 63937-14-4 HR: 3 MERCURY(l) GLUCONATE PROP: White solid. Mp: explodes, d: 4.42. DOT: UN 1637 SYNS:FULMINATEOfMERCURY.DRY-(DOT) * MER. mf: 6H1 OgHg mw: 395.76 Poi- CURYFULMINATE(DOT) * RCRAWASTENUMBER l5. PROP: White solid. P065 I IIb- CONSENSUS REPORTS: Mercury and its SYNS: MERCUROUSOLUCONATE * MERCUROUS meal compounds are on the Community Right-To- GLUCONATE, solid (DOT) in EPA TSCA Inven- Know List. Reported REPORTS: Mercury and its in: CONSENSUS tory. compounds are on the Community Right-To- 3 ;itive OSHA PEL: (Transitional: CL 1 mg/10m ) Know List. mg(Hg)/m3 (skin) id CL 0.1 OSHA PEL: (Transitional: CL 1 mg/0mi3) 0.1 mfg(Hg)/m 3 (skin) ACGIH TLV: TWA CL 0.1 mg(Hg)/m 3 (skin) Mercury) TWA 0.05 en NIOSH REL (Inorganic ACGIH TLV: TWA 0. 1 mg(Hg)/n9 (skin) mg(Hg)/m 3 toxic NIOSH REL: (Inorganic Mercury) TWA 0.05 I DOT Classification: Forbidden. mg(Hg)/m 3K- SAFETY PROFILE: An explosive sensitive to DOT Classification: Poison B; Label: Poi- flame, heat, impact, friction, intense radia- son. or contact with sulfuric acid. Self-ex- tion, SAFETY PROFILE: A poison. When heated plodes. Dangerously flammable; should be to decomposition it emits toxic fumes of Hg. kept moist until used. Incompatible with sul- See also MERCURY COMPOUNDS, OR- furic acid. When heated to decomposition it emits very toxic fumes of Hg and NO,. See GANIC. also MERCURY COMPOUNDS and FUL- MINATES. MDC750 CAS: 7783-30-4 HR: 3 MERCURY(I) IODIDE MDC250 CAS: 628-86-4 HR: 3 MERCURY FULMINATE (wet) DOT: UN 1638 mf: Hgl mw: 327.49 DOT: UN 0135 odorless, yellow, tetragonal mf: CHgN O2 mw: 284.63 PROP: Heavy, 2 crystals or amorphous powder. D: 7.70, mp: SYNS:FULMINATEOfMERCURY, WET(DOT) * INI- 2900 when rapidly heated (partial decomp). hATING EXPLOSIVE FULMINATE of MERCURY (DOT) Insol in water, aIc, and ether; sol in soins of * RCRA WASTENUMBER P065 mercurous or mercuric nitrates. Protect from light. CONSENSUS REPORTS: Mercury and its compounds are on the Community Right-To- SYNS: IODURE de MERCURE (FRENCH) * MERCU- Know List. ROUS IODIDE * MERCUROUS IODIDE, solid (DOT) * MERCURY PROTOIODIDE * YELLOWMERCURY OSHA PEL: (Transitional: CL 1 mg/10m3 ) CLO.1 mg(Hg)/m 3 (skin) IODIDE ACGIH TLV: TWA 0.1 mg(Hg)/m 3 (skin) CONSENSUS REPORTS: Mercury and its NIOSH REL: (Inorganic Mercury) TWA 0.05 compounds are on the Community Right-To- tg(Hg)/n3 Know List. Cassification: Label: Explosive A. NIOSH REL (Inorganic Mercury) TWA 0.05 PROFILE: An explosive. It can be mg(Hg)/m ke!inoresafelyin wet form. When heated to DOT Classification: Poison B; Label: Poi- posion it emits very toxic fumes of son. http://siri.org/msds/h/ql71/q3522 up:/siri.org/msds/h/q17 1/q35222 FISHER SCIENTIFIC -- METHANOL - METHANOL,TECHNICAL MATERIAL SAFETY DATA SHEET NSN: 6810002756010 Manufacturer's CAGE: 1B464 Part No. Indicator: A Part Number/Trade Name: METHANOL General Information Item Name: METHANOL,TECHNICAL Company's Name: FISHER SCIENTIFIC Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 201-796-7523 Company's Emerg Ph #: 201-796-7100 OR Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 005 Tot Safety Entries This Stk#: 027. Status: SE Date MSDS Prepared: 14JAN91 Safety Data Review Date: 14NOV92 Supply Item Manager: CX MSDS Serial Number: BDSGR Specification Number: O-M-232 Hazard Characteristic Code: F3 Unit Of Issue: CN Unit Of Issue Container Qty: 5 GALLONS Type Of Container: CAN, METAL Net Unit Weight: 32.9 LBS Ingredients/Identity Information Proprietary: NO (SARA III) Ingredient: METHYL ALCOHOL (METHANOL) Ingredient Sequence Number: 01 Percent: >99 NIOSH (RTECS) Number: PC1400000 CAS Number: 67-56-1 OSHA PEL: S,200PPM/250STEL ACGIH TLV: S,200PPM/250STEL; 93 Physical/Chemical Characteristics LIQUID Appearance And Odor: CLEAR,COLORLESS Boiling Point: 149F,65C Vapor Pressure (MM Hg/70 F): 97MMHG@20C Vapor Density (Air=l): 1.11 Specific Gravity: 0.792 Decomposition Temperature: 725F,385C ACETAT=1 Evaporation Rate And Ref: <1.0 (BUT I Solubility In Water: COMPLETE Percent Volatiles By Volume: 100 Fire and Explosion Hazard Data Flash Point: 52.QF,11.lC Flash Point Method: TCC Lower Explosive Limit: 6.0 Limit: 36.5 Upper Explosive DIOXIDE, ALCOHOL-RESISTANT FOAM, Extinguishing Media: DRY CHEMICAL,CARBON WATER SPRAY APPROVED SCBA WITH FULL PROTECTION Special Fire Fighting Proc: USE NIOSH FIRE. APPLY COOLING WATER TO COOL DOWN FOR FIREFIGHTING. DO NOT SCATTER THE 6/4/97 10:32 AM iA ://siri.org/msds/h/q 17 1/q35 222 http://siri.org/msds/h/ql71/q35222 FIRE EXPOSED CONTAINERS. U GIVE TOXIC VAPORS. Unusual Fire And Expl Hazrds: NONE SPECIFIED.MAY i Reactivity Data Stability: YES Cond To Avoid (Stability): HEAT,SPARKS,FLAME. I Materials To Avoid: STRONG OXIDIZERS. Hazardous Decomp Products: CHLOROFORM,FORMALDEHYDE Hazardous Poly Occur: NO Conditions To Avoid (Poly): NONE SPECIFIED Health Hazard Data LD50-LC50 Mixture: 5628 MG/KG ORAL RAT. E Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES OR FATAL. ASPIRATION Health Haz Acute And Chronic: ACUTE-INGESTION:HARMFUL BE FATAL. INHALATION OF INTO LUNGS CAN CAUSE CHEMICAL PNEUMONIA AND CAN MAY CAUSE IRRITATION, IRRITATION. CHRONIC-PROLONGED/REPEATED SKIN CONTACT DERMATITIS. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Carcinogenicity: NONE STATED. Explanation OF VAPORS MAY Signs/Symptoms Of Overexp: INHHALTION: EXCESSIVE BREATHING SEVERE IRRITATION AND CAUSE NASAL AND RESPIRATORY IRRITATION. EYES: CAUSES HARMFUL IF ABSORBED THROUGH BLURRED VISION; SKIN: CAUSES IRRITATION. MAY BE PROLONGED AND REPEATED SKIN. MAY CAUSE AN ALLERGIC SKIN REACTION ON CONTACT; INGESTION: MAY BE HARMFUL.CAUSES GI IRRITATION U EYE; OR SKIN DISORDER Med Cond Aggravated By Exp: INDIVIDUALS WITH KIDNEY, BE AT INCREASED RISK FROM EXPOSURE OF THIS MATERIAL. MAY WITH SOAP Aid Proc: EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH Emergency/First OR OXYGEN & WATER. INHALED:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION LARGE QUANTITY OF MILK OR AS NEEDED. INGESTED:DO NOT INDUCE VOMITING. GIVE MEDICAL ATTENTION. WATER.(NOTHING BY MOUTH IF UNCONSCIOUS.) GET IMMEDIATE MEDICAL CARE. IF ANY IRRITATION PERSISTS OR IS SEVERE,GET PROMPT Precautions for Safe Handling and Use CONTAIN LIQUID. USE Steps If Matl Released/Spill: REMOVE IGNITION SOURCES. ABSORB ON PERSONAL PROTECTIVE EQUIPMENT. EVACUATE AREA IF POSSIBLE. KEEP PENDING VERMICULITE. SCOOP UP AND PLACE IN A SUITABLE CONTAINER. DISPOSAL INSTRUCTIONS. Neutralizing Agent: NONE U MUST BE IN Waste Disposal Method: CONSULT LOCAL AUTHORITIES.DISPOSAL SEE EPA DISPOSAL CODE ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. FOR DISPOSAL PROCEDURES. FOR METHANOL AREA. I Precautions-Handling/Storing: STORE IN COOL, DRY AND WELL-VENTILATED HANDLE AS CLASSIFIED FLAMMABLE LIQUIDS. EYES,SKIN & CLOTHINGS. Other Precautions: DO NOT SMOKE.AVOID CONTACT WITH DO NOT INHALE OR INGEST. Control Measures VAPORS RESPIRATOR OR Respiratory Protection: USE NIOSH APPROVED ORGANIC SCBA. TO MAINTN 6/4/97 10:32 AM 2 of4 ip://siri.org/msds/h/q 17 1/q35222 http://siri.org/msds/h/q17 1/q35222 Suppl. Safety & Health Data: MSDS DATED APRIL 8,1980 Transportation Data Trans Data Review Date: 96060 DOT PSN Code: JEZ DOT Proper Shipping Name: METHANOL, OR METHYL ALCOHOL DOT Class: 3 DOT ID Number: UN1230 DOT Pack Group: II DOT Label: FLAMMABLE LIQUID, POISON IMO PSN Code: JPB IMO Proper Shipping Name: METHANOL IMO Regulations Page Number: 3251 IMO UN Number: 1230- IMO UN Class: 3.2 IMO Subsidiary Risk Label: TOXIC IATA PSN Code: QHQ IATA UN ID Number: 1230 IATA Proper Shipping Name: METHANOL IATA UN Class: 3 IATA Subsidiary Risk Class: 6.1 IATA Label: FLAMMABLE LIQUID & TOXIC AFI PSN Code: QHQ AFI Prop. Shipping Name: METHANOL OR METHYL ALCOHOL AFI Class: 3 AFI ID Number: UN1230 AFI Pack Group: II AFI Label: FLAMMABLE LIQUID, POISON AFI Basic Pac Ref: 7-7 Disposal Data Disposal Data Review Date: 88231 Rec # For This Disp Entry: 02 Tot Disp Entries Per NSN: 012 Landfill Ban Item: YES IN CASE OF ACCIDENTAL Disposal Supplemental Data: MSDS DATED APRIL 8,1980 FILE FOR PRECAUTIONS. EXPOSURE OR DISCHARGE, CONSULT HEALTH AND SAFETY 1st EPA Haz Wst Code New: U154 1st EPA Haz Wst Name New: METHANOL; METHYL ALCOHOL 1st EPA Haz Wst Char New: IGNITABLE (I) 1st EPA Acute Hazard New: NO Label Data Label Required: YES Technical Review Date: 14NOV92 Label Status: F Common Name: METHANOL Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Severe: X Reactivity Hazard-None: X METHYL ALCOHOL. MAY BE Special Hazard Precautions: POISONOUS! CONTAIN SKIN. CONTACT MAY CAUSE FATAL IF INHALED, SWALLOWED OR ABSORBED THROUGH OR DILUTION WATER MAY BURNS TO SKIN AND EYES. RUNOFF FROM FIRE CONTROL SOAP AND WATER. FLUSH EYES CAUSE POLLUTION. IN CASE OF CONTACT, WASH WITH WITH LARGE QUANTITY OF WATER. IF SWALLOWED, DRINK LARGE AMOUNT OF WATER. CONTACT POISON CONTROL CENTER. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y 6/4/97 10:32 AM of4 ://siri.org/msds/h/q 171/q35222 http://siri.org/msds/h/ql71/q35222 U Label Name: FISHER SCIENTIFIC, CHEMICAL DIV. Label Street: 1 REAGENT LANE Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410 Label Country: US Label Emergency Number: 201-796-7100 OR 201-796-7523 I Year Procured: 1980 URL for this msds http://siri.org. If you wish to change, add to, or delete information in this archive please send updates to [email protected]. 6/4/97 10:32 AM http://siri.org/msds/h/ql32/q15651 http://siri.org/msds/h/qI32/q 15651 FISHER SCIENTIFIC -- NITRIC ACID (A-200) - NITRIC ACID, ACS MATERIAL SAFETY DATA SHEET NSN: 6810007534779 Manufacturer's CAGE: 94480 Part No. Indicator: A Part Number/Trade Name: NITRIC ACID (A-200) General Information Item Name: NITRIC ACID, ACS Company's Name: FISHER SCIENTIFIC Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 Company's Emerg Ph #: 201-796-7100;800-424-9300(CHEMTREC) Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 002 Tot Safety Entries This Stk#: 002 Status: SMJ Date MSDS Prepared: 14DEC90 Safety Data Review Date: 13FEB91 Supply Item Manager: S9M MSDS Serial Number: BKLJY Hazard Characteristic Code: N/ Ingredients/Identity Information Proprietary: NO Ingredient: NITRIC ACID (SARA III) Ingredient Sequence Number: 01 Percent: 70 NIOSH (RTECS) Number: QU5775000 CAS Number: 7697-37-2 OSHA PEL: 2 PPM/4 STEL ACGIH TLV: 2 PPM/4 STEL; 9192 Proprietary: NO Ingredient: WATER Ingredient Sequence Number: 02 Percent: 30 NIOSH (RTECS) Number: ZC0110000 CAS Number: 7732-18-5 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO INFORMATION Ingredient: MATLS TO AVOID:OXIDIZERS. FOR MORE SPECIFIC CONTACT FOCAL POINT (FP N). HLTH HAZ:HEAL SLOWLY. (SEE ING 4) Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 3:(CHRONIC) DERMATITIS OR EFTS SIMILAR TO ACUTE EXPOS. EYE:(ACUTE) PAIN & BURNS, POSS SEVERE. CORNEA DMG (SEE IN 5) Ingredient Sequence Number: 04 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 4:& POSS BLINDNESS. EYE MAY BE TOTALLY DESTROYED. YELLOW 6) DISCOLORATION. (CHRONIC) CONJUNCTIVITIS & EFTS (SEE ING Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 9999999ZZ 6/4/97 10:50 AM Iof5 3 :/siri.org/msds/h/q632/q15651 http://siri.org/msds/h/q l 2/q 15651 Proprietary: NO Ingredient: ING 5:SIMILAR TO ACUTE EXPOS. INGEST:(ACUTE) BURNS/ DISCOLORATION TO MOUTH, THROAT, ESOPHAGUS. EPIGLOTTAL (SEE ING 7) Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO IIngredient: ING 6:EDEMA WHICH MAY RESULT IN RESP DISTRESS & ASPHYXIA. PAIN & INABILITY TO SWALLOW OR SPEAK. EPIGASTRIC (SEE ING 8) Ingredient Sequence Number: 07 7 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 7:PAIN, SHOCK W/MARKED HYPOTENSION. CIRCULATORY COLLAPSE MAY ENSUE & IF UNCORRECTED, LEAD TO RENAL (SEE ING 9) Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ EProprietary: NO Ingredient: ING 8:FAILURE. POSS ESOPHAGEAL & GASTRIC PERFORATION RESULTING IN PERITONITIS. GASTRIC & PYLORIC STRICTURE (SEE ING 10) Ingredient Sequence Number: 09 I NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 9:MAY OCCUR WITHIN A FEW WEEKS/MAY BE DELAYED FOR MONTHS OR EVEN YEARS. DEATH MAY RESULT FROM ASPHYXIA, (SEE ING 11) Ingredient Sequence Number: 10 NIOSH (RTECS) Number: 9999999ZZ I .Proprietary: NO Ingredient: ING 10:CIRCULATORY COLLAPSE OR ASPIRATION. (CHRONIC) INFLAMM OR ULCERATIVE CHANGES OF THE MUCOUS MEMBRANES. (SEE ING 12) Ingredient Sequence Number: 11 3 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING ll:LATER DEATH MAY BE FROM PERITONITIS, SEVERE NEPHRITIS OR PNEUMONIA. FIRST AID PROC:COVER W/STERILE (SEE ING 13) Ingredient Sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ I Proprietary: NO Ingredient: ING 12:BANDAGES, GET MD IMMED. INGEST:DO NOT USE GASTRIC LAVAGE/EMESIS. DILUTE BY GIVING LG QTY OF WATER (SEE ING 14) Ingredient Sequence Number: 13 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO ACID Ingredient: ING 13:OR MILK. IF VOMITING PERSISTS, GIVE FLUIDS RPTDLY. MUST BE DILUTED 100 FOLD. MAINTAIN AIRWAY, (SEE ING 15) Ingredient Sequence Number: 14 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 14:TREAT FOR SHOCK. GET MD IMMED. KEEP HEAD BELOW HIPS WHEN VOMITING. HNDLG/STOR PREC:ORGANIC OR OTHER (SEE ING 16) Ingredient Sequence Number: 15 NIOSH (RTECS) Number: 9999999ZZ Proprietary: NO Ingredient: ING 15:READILY OXIDIZABLE MATLS. PROVIDE GOOD VENTILATION AND AVOID DIRECT SUNLIGHT. SPILL PROC:KEEP (SEE ING 17) Ingredient Sequence Number: 16 -m NIOSH (RTECS) Number: 9999999ZZ 6/4/97 10:50 AM http://siri.org/msds/h/ql32/q 15651 L ://siri.org/msds/h/q132/q15651 Proprietary: NO AWAY. ISOLATE HAZARD AREA & DENY Ingredient: ING 16:UNNECESSARY PEOPLE ENTERING. ENTRY. VENTILATE CLOSED SPACES BEFORE Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ 3 Physical/Chemical Characteristics YELLOW LIQUID WITH A SUFFOCATING Appearance And Odor: COLORLESS TO PALE ODOR. U Boiling Point: 181F,83C Melting Point: -44F,-42C Vapor Pressure (MM Hg/70 F): 47.9 Vapor Density (Air=l): 3.2 Specific Gravity: 1.5027 Solubility In Water: VERY SOLUBLE Fire and Explosion Hazard Data wFlashPoint: N/A Lower Explosive Limit: N/A Upper Explosive Limit: N/A OR SODA ASH. LARGER FIRES FLOOD Extinguishing Media: WATER, DRY CHEMICAL AREA WITH WATER FROM A DISTANCE. APPRVD SCBA & FULL PROT EQUIP Special Fire Fighting Proc: USE NIOSH/MSHA W/O RISK. APPLY COOLING WATER TO SIDES (FP N). MOVE CNTNR FROM FIRE AREA IF FLAMES UNTIL (SEE SUPP DATA) I EXPOSED TO BURN DECOMPOSE WHEN HEATED/INCR Unusual Fire And Expl Hazrds: OXIDIZERS OXIDIZABLE, ORG/OTHER COMBUST MATLS RATE OF COMBUST MATL. CNTCT W/EASILY MAY RESULT IN IGNIT, VIOLENT COMBUST/EXPLOS. Reactivity Data Stability: YES EXOTHERMICALLY WITH WATER. Cond To Avoid (Stability): REACTS WATER, AMMONIA, AMINES, NITROGEN Materials To Avoid: ACETYLENE, ORGANICS, STRONG (SEE INGRED 3) DIOXIDE, CARBOHYDRATES, ORGANIC ACID, EXOTHERMICALLY WITH WATER. Hazardous Decomp Products: REACTS Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT Health Hazard Data MANUFACTURER. LD50-LC50 Mixture: NONE SPECIFIED BY Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of Entry - Ingestion: NO SEVERE RESP IRRIT, W/POSS MUC Health Haz Acute And Chronic: INHAL:(ACUTE) IMMED OR DELAYED 5-72 HRS. (CHRONIC) MEMB BURNS. PULMONARY EDEMA MAY OCCUR ULCERS TO MOUTH & POSS JAW NECROSIS. EROSION OF TEETH, INFLAMMATION & POSS ASTHMA. SKIN:(ACUTE) SEVERE PAIN, BRONCHIAL INFLAMM & POTNTL BRONCHIAL MAY (SEE INGRED 3) BURNS & POSS YELLOW STAINS. BURNS Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO RELEVANT Explanation Carcinogenicity: NOT CHOKING, DIZZINESS, HEADACHE, Signs/Symptoms Of Overexp: INHAL:COUGHING, DYPSNEA, FROTHY SPUTUM & CYANOSIS, NAUSEA, WEAKNESS. TIGHTNESS IN CHEST, EYE:EXCESSIVE LACRIMATION, PAIN, HYPOTENSION. SKIN:PAIN & DISCOLORATION. TINGED NAUSEA, VOMITING, DIARRHEA, BLOOD PHOTOPHOBIA. INGEST:MARKED THIRST, VOMITUS, WEAK PULSE, SHALLOW RESPIRATION. PULMONARY FUNCTION, PRE-EXISTING EYE Med Cond Aggravated By.Exp: IMPAIRED AND SKIN DISORDERS. TO FRESH AIR. SUPPORT BRTHG Emergency/First Aid Proc: INHAL:REMOVE 10:50 AM Ir5'6/4/97 http://siri.org/msds/h/ql32/q 15651 ttp://siri.org/msds/h/ql32/q15651 WASH (0*2/ARTF RESP), GET MD IMMED. SKIN:REMOVE CONTAM CLTHG/SHOES IMMED. IN CASE OF CHEM W/MILD SOAP & LG QTY OF WATER FOR AT LEAST 15-20 MINS. IRRIGATION W/STERILE W/LG AMTS OF WATER FOR AT LEAST 15-20 MINS. CONTINUE (SEE INGRED 12) WATER UNTIL PH HAS RETURNED TO NORMAL (30-60 MINS) Precautions for Safe Handling and Use SPILLED MATL. DO NOT Steps If Matl Released/Spill: KEEP COMBUST AWAY FROM REDUCE VAPS. DO NOT TOUCH MATL. STOP LEAK IF W/O RISK. USE WATER SPRAY TO OF WATER. LG:DIKE GET WATER INSIDE CNTNR. SMALL:FLUSH AREA W/FLOODING AMTS 16) FAR AHEAD OF SPILL FOR LATER DISPOSAL. (SEE INGRED OR CRUSHED LIMESTONE. Neutralizing Agent: SLAKED LIME, SODIUM BICARBONATE APPLICABLE TO Waste Disposal Method: DISPOSAL MUST BE I/A/W STANDARDS HAZARDOUS WASTE NUMBER D002. GENERATORS OF HAZARDOUS WASTE, 40 CFR 262, EPA REPORTABLE QUANTITY:1000 POUNDS. DAMAGE. SEPARATE Precautions-Handling/Storing: PROTECT AGAINST PHYSICAL TURPENTINE, ORGANIC FROM METALLIC POWDERS, CARBIDES, HYDROGEN SULFIDE, ACIDS & ALL COMBUST, (SEE INGRED 15) MATLS. REACTS VIOLENTLY W/ Other Precautions: MAY IGNITE OTHER COMBUSTIBLE MAY ACCUMULATE IN TANKS & WATER AND FUELS. FLAMMABLE, POISONOUS GASES OR EXPLOSION HAZARD. HOPPER CARS. RUNOFF TO SEWER MAY CREATE FIRE Control Measures CONC:125 MG/M3; Protection: USE NIOSH/MSHA APPRVD RESP EQUIP. Respiratory 250 MG/M3; SCBA W/FULL SUPPLIED AIR RESP IN CONTINUOUS FLOW MODE. CHEMICAL CARTRIDGE W/ FACEPIECE, AIR PURIFYING, FULL FACEPIECE (GAS MASK), FULL FACEPIECE. SYSTEM TO MEET PUBLISHED Ventilation: PROVIDE LOCAL EXHAUST VENTILATION EXPOSURE LIMITS. (FP N). Protective Gloves: IMPERVIOUS GLOVES FULL(SEE SUPP) Eye Protection: CHEM WORKERS GOGG.MAY ADD EMERGENCY WASH FACILITIES, Other Protective Equipment: DELUGE SHOWER. IMPERVIOUS CLOTHING AND EQUIPMENT. AFTER USE AND BEFORE Work Hygienic Practices: WASH HANDS THOROUGHLY (FP N) . EATING, SMOKING OR USING SANITARY FACILITIES AFTER FIRE OUT.AVOID ENDS Suppl. Safety & Health Data: FIREFIGHT PROC:WELL UNMANNED HOSE HOLDER/MONITOR OF TANKS. FOR MASSIVE FIRE,CARGO AREA,USE USE FLOODING AMTS/WATER AS FOG. NOZZLES; IF IMPOSS,GET OUT/LET FIRE BURN. A FAR.AVOID BRTHG CORR VAP, COOL CNTNRS W/FLOODING AMTS/WATER, APPLY FROM N). KEEP UPWIND.EYE PROT:LENGTH FACE SHIELD TO GOGG(FP Transportation Data Trans Data Review Date: 91214 DOT PSN Code: KFD DOT Proper Shipping Name: NITRIC ACID DOT Class: 8 DOT ID Number: UN2031 DOT Pack Group: II DOT Label: CORROSIVE IMO PSN Code: KPF IMO Proper Shipping Name: NITRIC ACID IMO Regulations Page Number: 8195 IMO UN Number: 2031 IMO UN Class: 8 IMO Subsidiary Risk Label: - IATA PSN Code: RWF IATA UN ID Number: 2031 IATA Proper Shipping Name: NITRIC ACID IATA UN Class: 8 IATA Label: CORROSIVE AFI PSN Code: RWF AFI Symbols: 0 6/4/97 10:50 AM A f S http://siri.org/msds/h/q1 32/q15651 L ://siri.org/msds/h/ql32/q15651 AFI Prop. Shipping Name: NITRIC ACID AFI Class: 8 AFI ID Number: UN2031 AFI Pack Group: II AFI Label: CORROSIVE AFI Basic Pac Ref: 12-14 Data * Disposal Label Data Label Required: YES Technical Review Date: 10JUN91 Label Date: 10JUN91 Label Status: G Common Name: NITRIC ACID (A-200) Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Severe: X Fire Hazard-None: X Reactivity Hazard-Moderate: X TO ALL TISSUES. SKIN: MAY Special Hazard Precautions: ACUTE: CORROSIVE INGEST: MAY CAUSE CAUSE DEEP SEVERE BURNS. EYES: MAY CAUSE BLINDNESS. OF GI TRACT. MAY LEAD TO SEVERE GI BURNS/ULCERATION. MAY CAUSE PERFORATIONS MAY CAUSE SEVERE RESPIRATORY CIRCULATORY COLLAPSE AND/OR NEPHRITIS. INHAL: EROSION OF TEETH, IRRITATION AND PULMONARY EDEMA, PERHAPS FATAL. CHRONIC: PNEUMONIA, GI DISTURBANCES. JAW NECROSIS, FREQUENT ATTACKS OF BRONCHIAL Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: FISHER SCIENTIFIC Label Street: 1 REAGENT LANE Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410 Label Country: US 201-796-7100;800-424-9300(CHEMTREC) Label Emergency Number: to change, add to, or URL for this msds http://siri.org. If you wish send updates to [email protected]. delete information in this archive- please 6/4/97 10:50 AM 5 of 5 http://siri.org/msds/h/q l3 4/q 16791 http://siri.org/msds/h/qI 34/ql 6791 TECHNICAL FISHER SCIENTIFIC -- C182, TETRACHLOROETHYLENE - TETRACHLOROETHYLENE, MATERIAL SAFETY DATA SHEET NSN: 6810010319531 Manufacturer's CAGE: 1B464 Part No. Indicator: A Part Number/Trade Name: C182, TETRACHLOROETHYLENE General Information Item Name: TETRACHLOROETHYLENE, TECHNICAL Company's Name: FISHER SCIENTIFIC Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410-2802 Company's Emerg Ph #: 201-796-7523;800-424-9300(CHEMTREC) Company's Info Ph #: 201-796-7100; 201-796-7523 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 002 Status: SMJ Date MSDS Prepared: 13JUL90 Safety Data Review Date: 03JUN92 MSDS Serial Number: BNWBH Hazard Characteristic Code: NK Ingredients/Identity Information NO Proprietary: (SARA III) Ingredient: ETHYLENE, TETRACHLORO-; (PERCHLOROETHYLENE) Ingredient Sequence Number: 01 Percent: 100 NIOSH (RTECS) Number: KX3850000 CAS Number: 127-18-4 OSHA PEL: 100 PPM . ACGIH TLV: 25PPM/100,A3 STEL;94 Proprietary: NO HRS. SEV EXPOS MAY RESULT IN Ingredient: SUPDAT:SUBSIDED AFTER 1-2 OCCUR. EYE:VAPS MAY (ING 3) VESICULATION & POSS BURNS. ABSORP MAY Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO LEVELS/DIRECT CONT MAY CAUSE Ingredient: ING 2:CAUSE MILD IRRIT. HIGHER INJURY IS (ING 4) PAIN, LACRIM & BURNING, BUT SERIOUS Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO PPM, IRRIT IS ALMOST INTOLERABLE. Ingredient: ING 3:UNLIKELY. AT 1500 VOMIT, ABDOM (ING 5) INGEST:MAY CAUSE SEV GI IRRIT W/NAUS, 04 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO . W/BLOODY STOOLS. NARC EFTS MAY INCL Ingredient: ING 4:CRAMPS & DIARR, POSS CHRONIC: (ING 6) HDCH, DIZZ, EXHILARATION, INEBRIATION. 05 Ingredient Sequence Number: 6/4/97 11:03 A 1 of 6 4/q16791 ://siri.org/msds/h/q I 34/q 16791 http://siri.org/msds/h/q I 3 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO I YRS SHOWED Ingredient: ING 5:INHAL:WORKERS EXPOSED TO 1-40 PPM OVER 7.5 7) ALTERED ELECTRODIAGNOSTIC & NEUROLOGICAL RATING (ING Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO I RESP TRACT IRRIT, CNS Ingredient: ING 6:SCORES. RPTD EXPOS MAY ALSO CAUSE 8) DEPRESS W/OUT NARCOS, CONFUSN, HDCH, FATG, DIZZ, (ING Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO I ABDOM PAIN, Ingredient: INC 7:INEBRIATION, INSOMNIA, NAUS, ANOREXIA, (ING 9) CONSTIP, BLURRED VISION, MULTIPLE PREMATURE VENTRICULAR Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO W/NUMB IN FINGERS, Ingredient: ING 8:BEATS & PERIPHERAL NEUROPATHY DMG MAY (ING 10) TREMBLING, NEURITIS & MEMORY DEFECTS, HEPATIC Ingredient Sequence Number: 09 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------Proprietary: NO SCALY, Ingredient: ING 9:OCCUR. SKIN:RPTD/PRLNG CONT MAY PRDCE DERM W/DRY, (ING 11) FISSURED SKIN. EYE:RPTD/PRLNG EXPOS MAY CAUSE Ingredient Sequence Number: 10 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO INCR INCIDENCE OF LACRIMAL Ingredient: ING 10:CONJ. ONE STUDY REPORTED (ING 12) DUCT DISEASE IN EXPOSED WORKERS. INGEST:LONGTERM Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO & KIDNEY DMG IN MICE. Ingredient: ING 11:INGEST OF S0 MG/KG PRDCD LIVER TARGET (ING 13) HAS PRDCD HEPATOCELLULAR CARCINOMAS IN MICE. Ingredient Sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO MAY ALSO AFFECT LIVER & Ingredient: ING 12:EFTS:CNS DEPRESS. POISONING (ING 14) KIDNEYS. ALCOHOL MAY ENHANCE TOX EFTS. STIMULANTS 13 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ 6/4/97 11:03 AM 2 of 6 http://siri.org/msds/h/qI34/q 16791 ttp://si ri.org/msds/h/ql34/q 16791 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO MAY INDUCE VENTRICULAR Ingredient: ING 13:SUCH AS EPINEPHRINE MILK. ONE STUDY SHOWS (ING 15) FIBRILLATION, MAY BE EXCRETED IN BREAST 14 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO FOR CHILDREN WHOSE FATHERS HAD Ingredient: ING 14:INCR RISK OF LEUKEMIA BIRTH OF CHILD. OCCUP EXPOS TO CHLORINATED SOLVS AFTER 15 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO 15-20 MINS) . GET MD IMMED. EYE:WASH Ingredient: FIRST AID PROC: (APPROX SALINE, OCCAS LIFTING (ING 17) IMMED W/LG AMTS OF H*20/NORMAL Ingredient Sequence Number: 16 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO LIDS, UNTIL NO EVID OF CHEM REMAINS Ingredient: ING 16:UPPER & LOWER INGEST:REMOVE BY (ING 18) (APPROX 15-20 MINS). GET MD IMMED. Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO MAINTAIN BLOOD PRESS & AIRWiAY. Ingredient: ING 17:GASTRIC LAVAGE/EMESIS. PERFORM (ING 19) GIVE 0*2 IF RESP IS DEPRESSED. DO NOT Ingredient Sequence Number: 18 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE NO Proprietary: IF VICTIM IS UNCON. GET MD IMMED. Ingredient: ING 18:GASTRIC LAVAGE/EMESIS PERFORMED BY (ING 20) ADMIN OF GASTRIC LAVAGE/O*2 SHLD BE 19 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO TREAT MED PERS. NO SPECIFIC ANTIDOTE. Ingredient: ING 19:QUALIFIED SYMPTOMATICALLY & SUPPORTIVELY. Ingredient Sequence Number: 20 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Physical/Chemical Characteristics ETHER-LIKE COLORLESS, VOLATILE LIQUID W/MILD Appearance And Odor: CLEAR, ODOR. Boiling Point: 250F,121C Melting Point: -2F,-19C 6/4/97 11:03 AM 3 of 6 ://siri.org/msds/h/q134/q16791 http://siri.org/msds/h/qI34/q 16791 E Vapor Pressure (MM Hg/70 F): 14 @ 20C Vapor Density (Air=l): 5.83 Specific Gravity: 1.6227 Evaporation Rate And Ref: 2.8 (BUTYL ACETATE=1) Solubility In Water: 0.018% Fire and Explosion Hazard Data USE I Extinguishing Media: DRY CHEMICAL, CO*2 OR HALON. FOR LARGER FIRES, WATER SPRAY, FOG OR STANDARD FOAM. & FULL PROT EQUIP Special Fire Fighting Proc: WEAR NIOSH/MSHA APPRVD SCBA TO FLAMES W/H*20 (FP N). STAY AWAY FROM STOR TANK ENDS. COOL CNTNRS EXPOSED FROM SIDE UNTIL WELL AFTER (SUPDAT) EXPOSED TO HEAT Unusual Fire And Expl Hazrds: NEGLIGIBLE FIRE HAZARD WHEN OR FLAME. Reactivity Data Stability: YES Cond To Avoid (Stability): MAY BURN BUT DOES NOT IG-ITE READILY. CONTAINER MAY EXPLODE IN HEAT OF FIRE. Materials To Avoid: AL, BA, BASES, BE, N*20*4, METALS (LIGHT), O2, RUBBER, KOH & NAOH. PLASTICS, HIGHLY TOX U Hazardous Decomp Products: THERMAL DECOMP PRODS MAY INCLUDE & CO*X. FUMES OF PHOSGENE, TOX & CORROSIVE FUMES OF CHLORIDES Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT Health Hazard Data LD50-LC50 Mixture: LD50:(ORAL,RAT)2829.MG/KG. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES IRRIT OF NOSE, Health Haz Acute And Chronic: ACUTE:INHAL:VAP MAY CAUSE NASAL DISCHARGE, THROAT & MUC MEMBS, FLUSHED FACE & NECK, SINUS CONGESTION, MOUTH, SLURRED HDCH, DIZZ, LT HEAD, DROW, THICK TONGUE, TIGHTNESS AROUND CHANGES. OTHER SPEECH, CONFUSN, INCOORD, NAUS & REVERSIBLE LIVER & KIDNEY REPORTED SYMPS INCL WEAK, COUGH, CHEST (EFTS OF OVEREXP) Carcinogenicity - NTP: YES Carcinogenicity - IARC: YES Carcinogenicity - OSHA: NO TO BE A Explanation Carcinogenicity: TETRACHLOROETHYLENE:ANTICIPATED CARCINOGEN(NTP), GRP 2B(IARC). PULSE, BLURRED Signs/Symptoms Of Overexp: HLTH HAZ:PAINS, RAPID/WEAK DISTORTED VISION, IRRITABILITY, ANOREXIA, VOMIT, HALLUCINATIONS, FUNCS. MASSIVE EXPOS PERCEPTIONS, ACIDOSIS, LATENT JAUNDICE & ABNORM LIVER 40(SUPDAT) BRIEF IMMERSION CAUSES ONLY MILD IRRIT. LIQ ON SKIN FOR SKIN, EYE, LIVER, Med Cond Aggravated By Exp: PERSONS W/PRE-EXISTING RISK FROM EXPOSURE. KIDNEY, CVS OR NEUROLOGICAL DISORDERS ARE AT INCREASED IF BRTHG HAS Emergency/First Aid Proc: INHAL:REMOVE TO FRESH AIR IMMED. & ADMIN 0*2 IF STOPPED, PERFORM ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS SYMPTOMATICALLY & AVAIL. KEEP AFFECTED PERSON WARM & @ REST. TREAT PERS. GET MD SUPPORTIVELY. ADMIN OF 0*2 SHLD BE PERFORMED BY QUALIFIED AREA W/SOAP/ IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED MILD DETERGENT & LG AMTS OF H*20 UNTIL NO EVID OF CHEM REMAINS(ING 16) Precautions for Safe Handling and Use IF W/OUT Steps If Matl Released/Spill: SHUT OFF IGNIT SOURCES. STOP LEAK MATL. FOR LGR RISK. SM LIQ SPILLS, TAKE UP W/SAND, EARTH/OTHER ABSORB SMOKING, FLAMES/FLARES SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO IN HAZ AREA! KEEP UNNEC PEOPLE AWAY. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. APPLIC TO Waste Disposal Method: DISPOSAL MUST BE I/A/W STANDARDS 6/4/97 11:03 AM 4 of 6 http://siri.org/msds/hqI34/q1679fl ttp://siri.org/msds/h/q134/q16791 GENERATORS OF HAZ WASTE, 40 CFR 262. EPA HAZ WASTE# U210. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). ' Precautions-Handling/Storing: OBSERVE ALL FED, STATE & LOC REGS WHEN U ST6RING/DISP OF SUBSTANCE. FOR ASSISTANCE, CONT DISTRICT DIRECTOR OF EPA. Other Precautions: STORE IN COOL, DRY, WELL-VENTED LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ MAY BE ACUTE. STORE AWAY FROM INCOMPATIBLE MATERIALS. U Control Measures Respiratory Protection: SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIMITS OF I RESPIRATOR & BE JOINTLY APPROVED BY NIOSH/MSHA. FOR MORE SPECIFIC INFO CONTACT NEHC (FP N). Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PEL. U Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: CHEMICAL WORKERS GOGGLES (FP N). TO PVNT Other Protective Equipment: APPROP PROT (IMPERVIOUS) CLTHG & EQUIP WORK AREA. I RPTD/PRLNG SKIN CONT. EYE WASH FOUNTAIN W/IN IMMED Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. USING Suppl. Safety & Health Data: FIRE FIGHT PROC:FIRE IS OUT. EXTING H*20 SOURCES & AGENT(S) SUITABLE FOR TYPE OF SURROUND FIRE. AVOID CONTAM OF EFTS OF U SEWERS, BUILD DIKES TO CONTAIN FLOW. AVOID BRTHG VAPS, KEEP UPWIND. BEGINNING W/ OVEREXP:MINS RESULTED IN PROGRESSIVELY SEV BURNING SENSATION, IN 5-10 MINS & MARKED ERYTHEMA, WHICH (ING 2) I Transportation Data Trans Data Review Date: 92274 DOT PSN Code: NYB U DOT Proper Shipping Name: TETRACHLOROETHYLENE DOT Class: 6.1 DOT ID Number: UN1897 DOT Pack Group: III I DOT Label: KEEP AWAY FROM FOOD IMO PSN Code: OJV IMO Proper Shipping Name: TETRACHLOROETHYLENE IMO Regulations Page Number: 6264 I IMO UN Number: 1897 IMO UN Class: 6.1 IMO Subsidiary Risk Label: - U IATA PSN Code: XOW IATA UN ID Number: 1897 IATA Proper Shipping Name: TETRACHLOROETHYLENE IATA UN Class: 6.1 I IATA Label: TOXIC AFI PSN Code: XOW AFI Prop. Shipping Name: TETRACHLOROETHYLENE AFI Class: 6.1 I AFI ID Number: UN1897 AFI Pack Group: III AFI Label: KEEP AWAY FROM FOOD AFI Special Prov: N36 I AFI Basic Pac Ref: 10-10 Disposal Data I Label Data Label Required: YES I Technical Review Date: 03JUN92 Label Date: 28MAY92 Label Status: G U Common Name: C182, TETRACHLOROETHYLENE 6/4/97 1 1:03 AM3 16791a Ip/sr~rgmd/l- -69-tp/sr~r/sshq3/ 34/ http://siri.org/msds/h/q134/q16791 l://siri.org/msds/h/qlI34/ql16791 Chronic Hazard: YES Signal Word: WARNING! I Acute Health Hazard-Slight: X Contact Hazard-Moderate: X Fire Hazard-None: X Reactivity Hazard-None: X VAPORS MAY CAUSE I Special Hazard Precautions: ACUTE:INHALATION OF DIZZINESS, IRRITATION OF NOSE, THROAT & MUCOUS MEMBRANES, HEADACH4E, LIGHTHEADEDNESS, DROWSINESS, SLURRED SPEECH, CONFUSION, INCOORDINATION, EYE CONTACT MAY WEAKNESS, PULMONARY EDEMA, UNCONSCIOUSNESS, COMA & DEATH. U PAIN, LACRIMATION & BURNING. SKIN CONTACT MAY CAUSE CAUSE IRRITATION, IRRITATION, NAUSEA, IRRITATION, BURNING & ERYTHEMA. INGESTION MAY CAUSE GI CHRONIC:CANCER VOMITING, ABDOMINAL CRAMPS, DIARRHEA & NARCOTIC EFFECTS. CAUSE CNS HAZARD.TETRACHLOROETHYLENE IS LISTED AS A CARCINOGEN.MAY U DERMATITIS & DEPRESSION, LIVER & KIDNEY EFFECTS, PERIPHERAL NEUROPATHY, CONJUNCTIVITIS. Protect Eye: Y I Protect Skin: Y Protect Respiratory: Y Label Name: FISHER SCIENTIFIC Label Street: 1 REAGENT LANE Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410-2802 Label Country: US Number: 201-796-7523;800-424-9300(CHEMTREC) Label Emergency II add to, or URL for this msds http://siri.org. If you wish to change, to [email protected]. delete information in this archive please send updates 6/4/97 11:03 AM http://siri.org/msds/h/q209/q5439 ttp://siri.org/msds/h/q209/q54397 - TOLUENE, ACS FISHER SCIENTIFIC -- T-324,TOLUENE MATERIAL SAFETY DATA SHEET NSN: 6810002572487 Manufacturer's CAGE: 22527 Part No. Indicator: A Part Number/Trade Name: T-324,TOLUENE General Information Item Name: TOLUENE, ACS COMPANY Company's Name: FISHER SCIENTIFIC Company's Street: 1 REAGENT LANE Company's City: FAIRLAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 Company's Emerg Ph #: 201-796-7100;800-424-9300(CHEMTREC) Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 002 005 Tot Safety Entries This Stk#: Status: SMJ Date MSDS Prepared: 16JAN92 Safety Data Review Date: 27APR94 MSDS Serial Number: BDPHZ Specification Number: O-C-265 Hazard Characteristic Code: F3 NRC/State License Number: N/A Net Propellant Weight-Ammo: N/A Ingredients/Identity Information Proprietary: NO III) Ingredient: TOLUENE (SARA 01 Ingredient Sequence Number: Percent: 100 NIOSH (RTECS) Number: XS5250000 CAS Number: 108-88-3 OSHA PEL: 100 PPM; 150 STEL ACGIH TLV: 100 PPM; 150 STEL Proprietary: NO IF TANK, RAIL CAR/TANK TRUCK INVOLVED Ingredient: SUPDAT:IN ALL DIRECTIONS CAN BE STOPPED. USE (ING 3) IN FIRE. EXTING ONLY IF FLOW Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO STREAMS MAY SPREAD FLOODING QTYS AS FOG, SOLID Ingredient: ING 2: WATER IN DIST AS POSS. KEEP UPWIND. FIRE. APPLY FROM AS FAR A 03 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE 3 NO Proprietary: OF SUBSTANCE, FLOW/AGITATION Ingredient: EXPLO HAZ: ELECTROCONDUCTIVITY W/SPK & POSS IGNIT. MAY GENERATE ELECTROSTATIC CHARGES 04 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO 6/4/97 11:02 A I of6 ://siri.org/msds/h/q209/q54397 http://siri.org/msds/h/q209/q54397 U Ingredient: MATL TO AVOID:DIMETHYL-2,4-IMIDAZOLIDIDIONE, DINITROGEN TETRAFLUORIDE, NITRIC ACID, NITROGEN TETROXIDE, (ING 6) Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 9999999ZZ I OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 5:OXIDIZERS, PLASTICS, RUB & COATINGS, SILVER PERCHLORATE, SULFUR DICHLORIDE, SULFURIC ACID. Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE I Proprietary: NO Ingredient: EFTS OF OVEREXP:GAG, DISTRESS, ACUTE HEMORR PNEUM & PULM EDEMA. APPROX LETHAL DOSE 15-30ML. CHRONIC: TOLUENE (ING 8) Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE U Proprietary: NO Ingredient: ING 7:APPEARS ON NAVY LIST OF CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST (ING 9) Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE E Proprietary: NO MAY CAUSE MUC MEMB IRRIT, VOMIT, INSOM, NOSEBLEEDS, (ING 10) Ingredient Sequence Number: 09 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE I Proprietary: NO Ingredient: ING 9:CHEST PAIN, HDCH, VERTIGO, NAUS, ANOREXIA, MOMETARY MEMORY LOSS, TINNITUS,.IMPAIRED SPEECH, VISION &/OR (ING 11) Ingredient Sequence Number: 10 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE I Proprietary: NO Ingredient: ING 10:HEARING, ALCOHOL INTOLERANCE, ABNORM BLEED. SKIN:PRLNG/ RPTD CNTCT MAY CAUSE DEFAT W/DRY FISSURED DERM. (ING 12) Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE U Proprietary: NO Ingredient: ING 11: EYES: RPTD/PRLNG CNTCT W/IRRITANTS MAY CAUSE CONJ. Ingredient Sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: FIRST AID PROC: OF CHEM REMAINS (@ LEAST 15 MIN). GET MED ATTN IMMED. INGEST: EXTREME CARE MUST BE USED TO PVNT (ING 14) Ingredient Sequence Number: 13 6/4/97 11:02 AM http://siri.org/msds/h/q209/q54397 http://siri.org/msds/h/q209/q54397 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 13: ASPIR. GASTRIC LAVAGE W/CUFFED ENDOTRACHEAL TUBE IN PLACE TO PVNT ASPIR SHOULD BE DONE W/IN 15 MIN. IN (ING 15) Ingredient Sequence Number: 14 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 14:ABSENCE OF DEPRESS/CONVLS/IMPAIRED GAG REFLEX, EMESIS CAN ALSO BE INDUCED USING SYRUP OF IPECAC W/OUT (ING 16) Ingredient Sequence Number: 15 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO GASTRIC Ingredient: ING 15:INCR HAZ OF ASPIR. TREAT SYMP & SUPPORTIVELY. LAVAGE SHOULD BE PERFORMED BY QUALIFIED PERS. GET (ING 12) Ingredient Sequence Number: 16 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO TREAT SYMP & Ingredient: ING 16: MED ATTN IMMED. NO SPECIFIC ANTIDOTE. SUPPORTIVELY. Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: SPILL PROC: OR FLARES IN RAZ AREA. KEEP UNNEC PERS AWAY; ISOLATE HAZ AREA & RESTRICT ENTRY. RQ: 1000 LBS. Ingredient Sequence Number: 18 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: RESP PROT: CARTRIDGE, SCBA. 2000PPM: SUPPLIED-AIR RESP OPERATED IN CONTINUOUS FLOW MODE. SCBA W/FULL FACEPIECE. (ING 20) Ingredient Sequence Number: 19 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO FULL Ingredient: ING 19:SUPPLIED-AIR RESP W/FULL FACEPIECE. AIR-PURIFYING 21) FACEPIECE RESP (GAS MASK) W/CHIN-STYLE, FRONT- OR (ING Ingredient Sequence Number: 20 NTOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 20:BACK-MOUNTED ORG VAP CANISTER. ESCAPE:AIR-PURIFYING, (ING 22) FULL FACEPIECE RESP (GAS MASK) W/CHIN-STYLE, FRONT- Ingredient Sequence Number: 21 NIOSH (RTECS) Number: 9999999ZZ 6/4/97 11:02 AM3 of6 http://siri.org/msds/h/q209/q54397 :/siri.org/msds/h/q209/q54397 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO U CANISTER. APPROP ESCAPE-TYPE, Ingredient: ING 21:OR BACK-MOUNTED ORG VAP SCBA. Ingredient Sequence Number: 22 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE 3 Physical/Chemical Characteristics LIQUID; AROMATIC ODOR. Appearance And Odor: CLEAR, COLORLESS Boiling Point: 231F,111C Melting Point: -139F,-95C Vapor Pressure (MM Hg/70 F): 22 Vapor Density (Air=l): 3.1 Specific Gravity: 0.868 ACETATE=l) Evaporation Rate And Ref: 2.24 (BUTYL Solubility In Water: 0.05% Percent Volatiles By Volume: 100 Fire and Explosion Hazard Data Flash Point: 40F/4C Flash Point Method: CC Lower Explosive Limit: 1.2% Upper Explosive Limit: 7.1% DIOXIDE, WATER SPRAY OR REGULAR Extinguishing Media: DRY CHEMICAL, CARBON FOG OR REGULAR FOAM. FOAM. FOR LARGER FIRES USE WATER SPRAY, APPRVD SCBA & FULL PROT EQUIP(FP Special Fire Fighting Proc: NIOSH/MSHA BE DONE W/OUT RISK. APPLY COOLING N). MOVE CNTNR FROM FIRE AREA IF IT CAN TO SIDES OF CNTNRS EXPOS TO (SUPDAT) WATER HAZ WHEN EXPOS TO HEAT/FLAME. Unusual Fire And Expl Hazrds: DANGEROUS FIRE E DIST TO SOURCE OF IGNIT & FLASH VAPS HVR/AIR & MAY TRAVEL CONSIDERABLE (ING 4) BACK. VAP-AIR MIX EXPLO. DUE TO LOW Data * Reactivity Stability: YES BY MANUFACTURER. Cond To Avoid (Stability): NONE SPECIFIED DICHLOROETHYL ALUMINUM/ETHYLALUMINUM Materials To Avoid: ALLYL CHLORIDE + 1,3-DICHLORO-5,5- (ING 5) SESQUICHLORIDE, BROMINE TRIFLUORIDE, MAY RELEASE ACRID SMOKE & Hazardous Decomp Products: THERMAL DECOMPOSITION IRRITATING FUMES. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT. 3 Health Hazard Data MG/KG LD50-LC50 Mixture: LD50: (ORAL, RAT) 2250 Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Of Entry - Ingestion: YES Route DANGEROUS TO LIFE/HLTH. Haz Acute And Chronic: INHAL:2000PPM IMMED Health 100PPM:IRRIT. INSUFFICIENT WARNING DUE TO OLFACTORY FATG. ODOR DETECTION NAUS, IMPAIRED 200-60OPPM, UP TO 8 HRS:FATG, WEAK, CONFUSN, HDCH, SKIN, EUPHORIA, DIZZ, DILATED COORDINATION & RXN TIME, PARESTHESIAS OF METAL (EFTS OF OVEREXP) PUPILS. 80OPPM:IRRIT, NASAL MUC SECRETION, Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. DROW, IMPAIRED BALANCE W/ Signs/Symptoms Of Overexp: HLTH HAZ:TASTE, 6/4/97 11:02 AM I of 6 http://siri.org/msds/h/q209/q54397 http://siri.org/msds/h/q209/q5439 AFTEREFTS INCL NERVOUSNESS, MUSC FATG & INSOM. DEATH MAY BE DUE TO RESP FAILURE/VENTRICULAR FIBRILLATION. SKIN: IRRIT, DRYING. EYES: IRRIT & BURNING SENSATION & ABDOM SPASMS. ASPIR MAY CAUSE COUGH, (ING 7) Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED PERFORM ARTF RESP. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AREA W/ SOAP/MILD DETERGENT & LG AMTS WATER UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LG AMTS WATER/NORM SALINE, OCCAS LIFTING UPPER & LOWER LIDS UNTIL NO EVID (ING 13) Precautions for Safe Handling and Use Steps If Matl Released/Spill; SHUT OFF IGNIT SOURCES. STOP LEAK IF IT CAN W/ BE DONE W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SM SPILLS:TAKE UP SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. LG SPILLS:DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMKNG, FLAMES (ING 18) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS HAZARDOUS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA WASTE NUMBER U220. Precautions-Handling/Storing: STORE IN ACCORDANCE WITH 29 CFR 1910.106. MATERIALS. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. SEPARATE FROM OXIDIZING STORAGE Other Precautions: PROTECT AGAINST PHYSICAL DMG. OUTSIDE/DETACHED PREF. INSIDE STORAGE SHOULD BE IN STD FLAMM LIQ STORAGE ROOM/CABINET. MEET SUBSTANCES W/LOW ELECTROCONDUCTIVITY SHOULD BE STORED IN CNTNRS WHICH BONDING & GROUNDING GUIDELINES. Control Measures LEVELS Respiratory Protection: RESP SELECTED MUST BE BASED ON CONTAM RESP. 1000PPM: ANY CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE. SUPPLIED-AIR POWERED AIR-PURIFYING RESP W/ORG VAP (ING 19) Ventilation: LOCAL/MECHANICAL. Protective Gloves: IMPERVIOUS. GOGGLES. Eye Protection: SPLASH PROOF/SAFETY Other Protective Equipment: EMERGENCY EYEWASH. APPROP PROTECTIVE SKIN (IMPERVIOUS) CLOTHING & EQUIPMENT TO PREVENT REPEATED/PROLONGED CONTACT. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. AFTER FIRE & Health Data: FIRE FIGHT PROC:FLAMES UNTIL WELL Suppl. Safety USE OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, FIRE UNMANNED HOSE HOLDER/MONITOR NOZZ. IF IMPOSS, W/DRAW FROM AREA & LET BURN. W/DRAW IMMED IF RISING SOUND FROM VENTING SFTY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1/2 MILE (ING 2) Transportation Data Trans Data Review Date: 95163 DOT PSN Code: OJY DOT Proper Shipping Name: TOLUENE DOT Class: 3 DOT ID Number: UN1294 DOT Pack Group: II DOT Label: FLAMMABLE LIQUID IMO PSN Code: OSR IMO Proper Shipping Name: TOLUENE IMO Regulations Page Number: 3285 IMO UN Number: 1294 IMO UN Class: 3.2 IMO Subsidiary Risk Label: IATA PSN Code: YEL IATA UN ID Number: 1294 IATA Proper Shipping Name: TOLUENE IATA UN Class: 3 6/4/97 11:02 A 5 of 6 http://siri.org/msds/h/q209/q54397 j ://siri.org/msds/h/q209/q54397 E IATA Label: FLAMMABLE LIQUID AFI PSN Code: YEL AFI Prop. Shipping Name: TOLUENE IAFT Class: 3 AFI ID Number: UN1294 AFI Pack Group: II AFI Label: FLAMMABLE LIQUID U AFI Basic Pac Ref: 7-7 Disposal Data I Disposal Data Review Date: 88077 Rec # For This Disp Entry: 01 Tot Disp Entries Per NSN: 002 Ban Item: YES Landfill 4 CLASS,V TYPE. IN Supplemental Data: CONTAINER SIZE: 1 GAL CAN, U Disposal FILE. cONSULT HEALTH AND SAFETY CASE OF ACCIDENTAL EXPOSURE OR DISCHARGE, FOR PRECAUTIONS. 1st EPA Haz Wst Code New: U220 1st EPA Haz Wst Name New: TOLUENE; METHYLBENZENE 1st EPA Haz Wst Char New: TOXIC (T) 1st EPA Acute Hazard New: NO 2nd EPA Haz Wst Code New: D001 2nd EPA Haz Wst Name New: IGNITIBLE 2nd EPA Haz Wst Char New: IGNITABILITY 2nd EPA Acute Hazard New: NO Label Data Label Required: YES Technical Review Date: 27APR94 Label Date: 27APR94 Label Status: G Chronic Hazard: YES I Signal Word: DANGER!' Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Severe: X Reactivity Hazard-None: X I FLAMMABLE. ACUTE: EYES: IRRITATION, Special Hazard Precautions: EXTREMELY IRRITATION, FATIGUE, NAUSEA, WEAKNESS, BURNS. INGESTION/INHALATION: TOLUENE APPEARS ON THE IMPAIRED COORDINATION. SKIN: IRRITATION. CHRONIC: EYES: CONJUNCTIVITIS. IRRITATION, BLEEDING, SKIN: DEFATTING. Protect Eye: Y Protect Skin: Y ' Protect Respiratory: Y Label Name: FISHER SCIENTIFIC CO Label Street: 1 REAGENT LANE Label City: FAIRLAWN Label State: NJ Label Zip Code: 07410 Label Country: US Label Emergency Number: 201-796-7100;800-424-9300(CHEMTREC) to change, add to, or URL for this msds http://siri.org. If you wish send updates to [email protected]. delete information in this archive please 6/4/97 11:02 AM http://siri.org/msds/h/q233/q66187 http://siri.org/msds/h/q233/q66187 CHEM SERVICE -- TRICHLOROETHENE, 0-664 MATERIAL SAFETY DATA SHEET NSN: 681000N054678 Manufacturer's CAGE: 8Y898 Part No. Indicator: A Part Number/Trade Name: TRICHLOROETHENE, 0-664 General Information Company's Name: CHEM SERVICE INC Company's P. 0. Box: 3108 Company's City: WEST CHESTER Company's State: PA Company's Country: US Company's Zip Code: 19381 Company's Emerg Ph #: 215-692-3026 Company's Info Ph #: 215-692-3026 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 07JAN93 Safety Data Review Date: 03NOV94 MSDS Serial Number: BVYRM Hazard Characteristic Code: NK Ingredients/Identity Information Proprietary: NO Ingredient: ETHYLENE, TRICHLORO-; (TRICHLOROETHYLENE) (SARA III) Ingredient Sequence Number: 01 NIOSH (RTECS) Number: KX4550000 CAS Number: 79-01-6 OSHA PEL: 100 PPM ACGIH TLV: 50 PPM;100 PPM STEL Proprietary: NO Ingredient: SUPP DATA: BRTHG ADMIN ARTF RESPS.IF PATIENT IS IN CARD ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL(ING 3) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) Proprietary: NO Ingredient: ING 2: MEDICAL ASSISTANCE HAS ARRIVED. INGESTION: CALL MD IMMEDIATELY (FP N). Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) Proprietary: NO Ingredient: EYE PROTECTION: FULL LENGTH FACESHIELD (FP N). Ingredient Sequence Number: 04 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) Physical/Chemical Characteristics Appearance And Odor: COLORLESS LIQUID. Boiling Point: 189F,87C Melting Point: -125F,-87C Vapor Pressure (MM Hg/70 F): 58 @ 20C Specific Gravity: 1.462 6/4/97 11:04 AM 1 of 3 ://siri.org/msds/h/q233/q66187 http://siri.org/msds/h/q233/q66187 I Solubility In Water: INSOLUBLE Fire and Explosion Hazard Data Flash Point: NON-FLAMMABLE Lower Explosive Limit: 11% Upper Explosive Limit: 41% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR SPRAY. Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). INCLUDE Unusual Fire And Expl Hazrds: THERMAL DECOMPOSITION PRODUCTS MAY HCL AND PHOSGENE (FP N). Reactivity Data I Stability: YES Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG BASES, STRONG OXIDIZING AGENTS. FUMES Hazardous Decomp Products: DECOMPOSITION LIBERATES TOXIC DECOMPOSITION PRODUCTS ARE CORROSIVE. HCL, PHOSGENE (FP N). Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT. Health Hazard Data LD50-LC50 Mixture: LD50 (ORAL,RAT): 4920 MG/KG. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES IN LAB. ALL Health Haz Acute And Chronic: CONT LENSES SHOULD NOT BE WORN CARCIN-MAY CHEMS SHOULD BE CONSIDERED HAZ-AVOID DIRECT PHYS CONT! SUSPECTED IF PRDCE CANCER. MAY BE HARMFUL IF ABSORB THRU SKIN. MAY BE HARMFUL I SEV EYE IRRIT. INHALED. MAY BE HARMFUL IF SWALLOWED. LACHRYMATOR-CAUSES VAPS &/OR DIRECT EYE CONT CAN CAUSE SEV EYE (EFTS OF OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. IRRIT. CAN CAUSE Signs/Symptoms Of Overexp: HLTH HAZ: BURNS. CAN CAUSE EYE EXPOS CAN CAUSE SKIN IRRIT. CAN CAUSE SKIN BURNS. CAN CAUSE SEV SKIN BURNS. BE IRRIT LIVER DMG. EXPOS CAN CAUSE KIDNEY DMG. CAN CAUSE GI DISTURB. CAN DMG.CAN CAUSE TO MUC MEMBS. PRLNGD EXPOS MAY CAUSE NAUS/HDCH/DIZZ &/OR EYE U SENSIT BY SKIN CONT. CHLOROCARBON MATLS(SUPDAT) Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. TO COUNTERACT Emergency/First Aid Proc: AN ANTIDOTE IS SUBSTANCE INTENDED PERS. MED ADVICE EFT OF POIS. IT SHOULD BE ADMIN ONLY BY PHYS/TRAINED EMER W/ WATER FOR CAN BE OBTAINED FROM POIS CNTRL CNTR. EYE: FLUSH CONTINUOUSLY IF NOT BURNS HAVE AT LST 15-20 MINS. SKIN: FLUSH W/WATER FOR 15-20 MINS. TO FRESH OCCURED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE PATIENT AIR. ADMIN OXYGEN IF PATIENT IS HAVING DFCLTY (SUPDAT) Precautions for Safe Handling and Use OSHA Steps If Matl Released/Spill: EVACUATE AREA. WEAR APPROPRIATE SIMILAR REGULATED EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR I HOLD FOR MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. EQUIPPED WITH AN Waste Disposal Method: BURN IN A CHEMICAL INCINERATOR FEDERAL, STATE, AND AFTERBURNER AND SCRUBBER. DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS (FP N). AND CLOTHING. Precautions-Handling/Storing: AVOID CONTACT WITH SKIN, EYES KEEP TIGHTLY CLOSED IN COOL DRY PLACE. STORE ONLY WITH COMPATIBLE CHEMICALS. IN GENERAL Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE 6/4/97 11:04 AM of 3 http://siri.org/msds/h/q233/q66187 http://siri.org/msds/h/q233/q66187 VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY ------CAUSE FORMATION OF HCL AND/OR PHOSGENE (FP N). Control Measures APPROPRIATE Respiratory Protection: WEAR NIOSH/MSHA APPROVED RESPIRATOR FOR EXPOSURE OF CONCERN (FP N). Ventilation: CHEMICAL SHOULD BE HANDLED ONLY IN HOOD. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPRVD CHEM WORKERS GOGG & (ING 4) SAFETY Other Protective Equipment: USE APPROPRIATE OSHA/MSHA APPROVED STANDARDS(FP EQUIPMENT.EMER EYEWASH & DELUGE SHOWER WHICH MEET ANSI DESIGN N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. FRDCED SENSIT OF Safety & Health Data: EFTS OF OVEREXP: HAVE Suppl. SIMILAR EFT IN MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE EXCEPT HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED TO FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS 2) CHLOROCARBONS (FP N). FIRST AID PROC: BRTHG. IF PATIENT HAS STOPPED (ING Transportation Data Disposal Data Label Data Label Required: YES Technical Review Date: 03NOV94 Label Date: 260CT94 Label Status: G Common Name: TRICHLOROETHENE, 0-664 Chronic Hazard: YES Signal Word: DANGER!, Acute Health Hazard-Moderate: X Contact Hazard-Severe: X Fire Hazard-None: X Reactivity Hazard-None: X OF VAPORS MAY CONTRIBUTE TO Special Hazard Precautions: ACUTE: INHALATION BE HARMFUL IF ABSORB THRU THE OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). MAY DAMAGE, GASTROINTESTINAL SEVERE BURNS/IRRITATION MAY CAUSE LIVER/KIDNEY NAUSEA, DISTURBANCE. MAY CAUSE MUCOUS MEMBRANE IRRITATION. CHRONIC: HEADACHE, DIZZINESS AND/OR EYE DAMAGE. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: CHEM SERVICE INC Label P.O. Box: 3108 Label City: WEST CHESTER Label State: PA Label Zip Code: 19381 Label Country: US Label Emergency Number: 215-692-3026 add to, or URL for this msds http://siri.org. If you wish to change, delete information in this archive please send updates to [email protected]. 6/4/97 11:04 AM3 3 of 3 p://siri.org/msds/h/q376/q137601 http://siri.org/msds/h/q376/q137601 FISHER SCIENTIFIC -- T341500, TRICHLOROETHYLENE - TRICHLOROETHYLENE, ACS MATERIAL SAFETY DATA SHEET NSN: 6810013195400 Manufacturer's CAGE: 1B464 IPart No. Indicator: A Part Number/Trade Name: T341500, TRICHLOROETHYLENE General Information Item Name: TRICHLOROETHYLENE, ACS Company's Name: FISHER SCIENTIFIC Company's Street: 1 REAGENT LANE Company's City: FAIR LAWN Company's State: NJ Company's Country: US Company's Zip Code: 07410 Company's Emerq Ph #: 201-796-7100;800-424-9300(CHEMTREC) Company's Info Ph #: 201-796-7100 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 10MAR89 Safety Data Review Date: 25JUN92 MSDS Serial Number: BPKRC Hazard Characteristic Code: NK Ingredients/Identity Information Proprietary: NO Ingredient: TRICHLOROETHYLENE (SARA III) Ingredient Sequence Number: 01 U Percent: >99 NIOSH (RTECS) Number: KX4550000 CAS Number: 79-01-6 OSHA PEL: 100 PPM/100 STEL E ACGIH TLV: 50 PPM/100,A5STEL;93 Proprietary: NO Ingredient: ANTIOXIDANT (SUCH AS AMINES OR EPOXIDES & ESTERS TO STABILIZE) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 1000125AO OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------_------Proprietary: NO Ingredient: CNDTNS (POLYM):STABILIZER IS REQD TO PVNT POLYMERIZATION WHEN HEATED OR EXPOSED TO SUNLIGHT. Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: EFTS OF OVEREXP:WHEN IN CONT W/SOAKED CLTHG FOR LONG TIME, I BLISTERING MAY OCCUR. MAY BE ABSORBED THRU SKIN. (ING 5) Ingredient Sequence Number: 04 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO BURNS OF LIDS, CONJ & CORNEA W/REDNESS, TEARING & (ING 6) Ingredient Sequence Number: 05 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE 6/4/97 10:56 AM htt :/siri.org/msds/h/q376/q137601 http://siri.org/msds/h/q376/q3760 ACGIH TLV: NOT APPLICABLE Proprietary: NO IN MOUTH, Ingredient: ING 5:BLURRED VISION. INGEST:SEV BURNING SENSATION 7) THROAT & STOM, DIARR, CONFUSN, INEBRIATION & CNS (ING Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO & COMA), HDCH, Ingredient: ING 6:DEPRESS (DIZZ, NAUS, HCHD, CONVLS DEATH FROM (ING 8) AMNESIA, NUMB, WEAK OF EXTREMS & PSYCHOSIS, Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 7:RESP/CARDIAC/HEPATORNEAL FAILURE. CHRONIC:INHAL:NAUS, (ING 9) VOMIT, ABDOM CRAMPS, SLEEPINESS, DRUNKENNESS, Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO OF EYES, FACE & HANDS & MILD Ingredient: ING 8:FLUSHING, ANOREXIA, SWELL PARAL, (ING 10) CARDIAC ARRYTHMIA, WHEEZING, FACIAL NERVE 09 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO OF SMELL/TASTE, DOUBLE VISION, Ingredient: ING 9:LOSS OF COORD & SENSE & (ING 11) BLINDNESS, INTOLERANCE TO ALCOHOL, BRADYCARDIA 10 Ingredient Sequence Number: NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT-APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO & BRAIN DMG. REPRO EFTS REPORTED Ingredient: ING 10:ANXIETY, LIVER, KIDNEY (ING 12) IN ANIMALS. SKIN:DERM RESULTING IN ROUGHNESS, Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO & SECONDARY INFECTION, PARAL OF Ingredient: ING ll:CHAPPING, VESICULATION CAUSE (ING 13) FINGERS, SENSIT. CHRONIC LOW DOSE EXPOS MAY Ingredient Sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO & PERSONALITY CHANGES, NAUS, Ingredient: ING 12:INEBRIATION, IRRITABILITY PAIN & (ING 14) ANOREXIA, FATG, VISUAL IMPAIRMENT, JOINT Ingredient Sequence Number: 13 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE 6/4/97 10:56 AM 1 2 of6 http://siri.org/msds/h/q376/q 137601 1 ://siri.org/msds/h/q376/ql 37601 NO Proprietary: INGEST:IRRIT OF ING 13:WHEEZING. EYE:CONJ & CORNEAL INFLAMM. Ingredient: (ING 15) MUC MEMBS, HDCH, DROW, FATG, GIDD, EXCITABILITY, Ingredient Sequence Number: 14 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE I ACGIH TLV: NOT APPLICABLE Proprietary: NO OF SENSATIONS IN EXTREMS & Ingredient: ING 14:INDIGESTION, NAUS, DISTURBS EFTS, LIVER(ING 16) OTHER SYMPS AS IN CHRONIC INHAL. REPRO Ingredient Sequence Number: 15 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE NO Proprietary: EPINEPHRINE/OTHER ING 15:LUNG NEOPLASMS REPORTED IN ANIMALS. Ingredient: (ING 17) STIMULANTS MAY INDUCE VENTRICULAR ARRHYTHMIAS. Ingredient Sequence Number: 16 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO PRDCD SENSIT OF MYOCARDIUM TO Ingredient: ING 16:CHLOROCARBON MATLS HAVE SIM EFT IN (ING 18) EPINEPHRINE IN LAB ANIMALS & COULD HAVE Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ I OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO I (E.G., EPINEPHRINE) MAY BE Ingredient: ING 17:HUMANS. ADRENOMIMETICS USES IN (ING 19) CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING Ingredient Sequence Number: 18 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Other Recommended Limit: N/AE SPECIFIED NO Proprietary: EXPOSED TO CHLOROCARBONS (FP Ingredient: ING 18:HUMANS ACUTELY/CHRONICALLY NEHC (FP N). N). FOR MORE SPEC INFO ON HLTH EFTS, CONT Ingredient Sequence Number: 19 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO 15-20 MINS). GET MD FIRST AID PROC:NO CHEM REMAINS (APPROX Ingredient: MAINT (ING 21) IMMED. INGEST:REMOVE BY GASTRIC LAVAGE/EMESIS. Ingredient Sequence Number: 20 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary:NO -- GIVE 0*2 IF RESP IS DEPRESSED. DO Ingredient: ING 20:BLOOD PRESS & AIRWAY. IF VICTIM IS (ING 22) NOT PERFORM GASTRIC LAVAGE/EMESIS Ingredient Sequence Number: 21 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE 6/4/97 10:56 AM of 6 h / Lp: s iri.oLg/msdshuq3 6q 3760 1 http://siri.org/msds/h/q376/ql3760 Proprietary: NO Ingredient: ING 21:UNCON. GET MD IMMED. ADMIN OF GASTRIC LAVAGE/O*2 SHLD BE PERFORMED BY QUALIFIED MED PERSONNEL. NO SPEC (ING 23) Ingredient Sequence Number: 22 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 22:ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. Ingredient Sequence Number: 23 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: SPILL PROC:FOR MORE SPECIFIC INFORMATION, CONTACT NEHC (FP N). Ingredient Sequence Number: 24 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------===------====------Physical/Chemical Characteristics Appearance And Odor: COLORLESS, HEAVY, MOBILE LIQUID W/MILD CHLOROFORM- LIKE ODOR. Boiling Point: 188F,87C Melting Point: -99F,-73C Vapor Pressure (MM Hg/70 F): 58 @ 20C Vapor Density (Air=1): 4.5 Specific Gravity: 1.5 Evaporation Rate And Ref: 0.69 (CCL4 = 1) Solubility In Water: 0.1% Fire and Explosion Hazard Data Lower------Limit: 10.5% Explosiv Lower Explosive Limit: 10.5%@ 25C Upper Explosive Limit: 8% @ 25C Extinguishing Media: DRY CHEMICAL, CO*2 OR HALON. FOR LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD FOAM. Special Fire Fighting Proc: WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT EQUIP (FP N). STAY AWAY FROM STOR TANK ENDS. COOL CNTNRS EXPOSED TO FLAMES W/H*20 FROM SIDE UNTIL (SUPDAT) Unusual Fire And Expl Hazrds: SLIGHT FIRE HAZ WHEN EXPOS TO HEAT/FLAME. THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE (FP N). MAY BURN BUT DOES NOT IGNITE READILY. Reactivity Data Stability: YES Cond To Avoid (Stability) : HIGH TEMPERATURE, OPEN FLAME OR ULTRAVIOLET LIGHT. Materials To Avoid: ALKALI, AL, METALS (PWDRD), STRONG OXIDIZERS, EPOXIDES, 0*2.. FOR COMPLETE LIST OF MATLS TO AVOID, CONT NEHC (FP N). Hazardous Decomp Products: UPON CONT W/CERTAIN METALS, HIGH TEMPS, OPEN FLAME/ULTRAVIOLET LIGHT, DECOMPOSES INSTANTLY TO HIGHLY TOX & CORR (SUPDAT) Hazardous Poly Occur: YES Conditions To Avoid (Poly): MAY POLYMERIZE WHEN CATALYZED BY ALUM CHLORIDE IN SELF-SUSTAINING RXN WHICH MAY DEVEL TEMPS UP TO 1350C. (ING 3) Health Hazard Data LD50-LCS0 Mixture: LD50:(ORAL,MOUSE)2402 MG/KG. Route Of Entry - Inhalation: YES 4 of 6 6/4/97 10:56 AM http://siri.org/msds/h/q376/q 137601 ://siri.org/msds/h/q376/q 137601 Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES OF MEMORY, COMPLEX RXN TIME Health Haz Acute And Chronic: ACUTE:INHAL:LOSS DIZZ, HDCH, NAUS, VOMIT, CRAMPS & MANUAL DEXTERITY, MILD RESP IRRIT, DROW, PALLOR, PERSPIRATION, PULM EDEMA, & FLUSHED SKIN. HIGHER CONCS MAY CAUSE & COMA. NAUS & VOMIT MAY FOLLOW NARCOS, FACIAL NERVE DYSFUNC, ANESTH, UNCON OF OVEREXP) FOR SEVERAL HRS. ANEMIA & DMG TO (EFTS Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO NOT RELEVANT Explanation Carcinogenicity: & LUNGS MAY Of Overexp: HLTH HAZ:LIVER, KIDNEYS, SPLEEN Signs/Symptoms FIBRILLATION & PRIMARY OCCUR. DEATH MAY OCCUR FROM RESP ARREST/VENTRICULAR DELIB INHAL OF MOD AMTS WHICH CARDIAC FAILURE. ADDICTION OCCURRED FROM HALLUCINATIONS, DELUSIONS & OTHER CAUSE EUPHORIA, DISORIENTATION, VISUAL DERM. (ING 4) PSYCHOTIC SYMPS. SKIN:IRRIT & DERM. SENSIT BEVERAGES MAY ENHANCE TOXICITY. Med Cond Aggravated By Exp: ALCOHOLIC MAY INDUCE VENTRICULAR ARRHYTHMIAS. EPINEPHRINE/STIMULANTS EXPOS TO FRESH AIR IMMED. IF Emergency/First Aid Proc: INHAL:REMOVE FROM KEEP PERS WARM & @ REST. TREAT SYMP & BRTHG HAS STOPPED, PERFORM ARTF RESP. CONTAM CLTHG & SHOES IMMED. WASH SUPPORTIVELY. GET MD IMMED. SKIN:REMOVE OF H*20 UNTIL NO CHEM REMAINS AREA W/SOAP/MILD DETERGENT & LG AMTS AFFECTED W/LG AMTS OF H*20/NORM (APPROX 15-20 MINS). GET MD IMMED. EYE:WASH IMMED UNTIL(ING 20) SALINE, OCCAS LIFTING UPPER & LOWER LIDS, Precautions for Safe Handling and Use SOURCES. STOP LEAK IF YOU CAN Steps If Matl Released/Spill: SHUT OFF IGNIT UP W/SAND, EARTH/OTHER ABSORB DO IT W/OUT RISK. FOR SM LIQ SPILLS, TAKE FOR LATER DISP. NO SMOKING, FOR LGR SPILLS, DIKE FAR AHEAD OF SPILL MATL. AWAY. (ING 24) FLAMES/FLARES IN HAZ AREA! KEEP UNNEC PEOPLE MANUFACTURER. Neutralizing Agent: NONE SPECIFIED BY LBS. DISPOSAL MUST BE I/ Waste Disposal Method: REPORTABLE QUANTITY:1000 N). FEDERAL, STATE & LOCAL REGULATIONS (FP A/W DRY, WELL-VENTED LOCATION, Precautions-Handling/Storing: STORE IN COOL, MAY BE ACUTE. AWAY FROM ANY AREA WHERE FIRE HAZARD IGNITE READILY. CNTNR MAY EXPLODE Other Precautions: MAY BURN BUT DOES NOT DO NOT USE IN GEN VICIN OF ARC HEAT OF FIRE. NO SMOKING IN AREA OF USE. IN RADIA MAY CAUSE FORM OF HCL &/ WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV OR PHOSGENE (FP N). Control Measures BASED ON SPECIFIC RESPIRATOR SELECTED MUST BE Respiratory Protection: APPROVED. FOR SPECIFIC CONTAM LEVELS FOUND IN WORKPLACE & BE NIOSH/MSHA SELECTION, CONTACT NEHC (FP N). REPSIRATOR ENCLOSURE VENTILATION TO Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS MEET PELS. Protective Gloves: IMPERVIOUS GLOVES (FP N). WORKERS GOGGLES (FP N). Eye Protection: CHEMICAL TO PVNT Equipment: APPROP PROT (IMPERVIOUS) CLTHG & EQUIP Other Protective N). SKIN CONT. EMER EYEWASH & DELUGE SHOWER (FP RPTD/PRLNG BE WORN. Hygienic Practices: CONTACT LENSES SHOULD NOT Work FIRE IS OUT. USE AGENT Safety & Health Data: FIRE FIGHT:WELL AFTER Suppl. KEEP UPWIND. HAZ DECOMP FOR TYPE OF FIRE. AVOID BRTHG TOX VAPS, SUITABLE & DICHLOROACETYL CHLORIDE. >700C PROD:FUMES OF PHOSGENE &/OR HCL, CHLORINE TETRACHLORETHYLENE, CARBON VAPS DECOMPOSE TO MIXT OF DICHLOROETHYLENE, TETRACHLORIDE, CHLOROFORM & METHYLCHLORIDE. Transportation Data Trans Data Review Date: 93021 DOT PSN Code: OQK DOT Proper Shipping Name: TRICHLOROETHYLENE DOT Class: 6.1 6/4/97 10:56 AM 5 of 6 http://siri.org/msds/h/q376/q 137601 http://siri.org/msds/h/q376/q137601 DOT ID Number: UN1710 DOT Pack Group: III DOT Label: KEEP AWAY FROM FOOD IMO PSN Code: OVL IMO Proper Shipping Name: TRICHLOROETHYLENE IMO Regulations Page Number: 6273 IMO UN Number: 1710 IMO UN Class: 6.1 IMO Subsidiary Risk Label: - IATA PSN Code: YMD IATA UN ID Number: 1710 IATA Proper Shipping Name: TRICHLOROETHYLENE IATA UN Class: 6.1 IATA Label: TOXIC AFI PSN Code: YMD AFI Prop. Shipping Name: TRICHLOROETHYLENE AFI Class: 6.1 AFI ID Number: UN1710 AFI Pack Group: III AFI Label: KEEP AWAY FROM FOOD AFI Special Prov: N36 AFI Basic Pac Ref: 10-10 Disposal Data Label Data Label Required: YES Technical Review Date: 24JUN92 Label Date: 23JUN92 Label Status: G Common Name: T341500, TRICHLOROETHYLENE Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Slight: X Fire Hazard-None: X Reactivity Hazard-None: X AL/METAL PWDRS, Special Hazard Precautions: OSHA CLASS IC. AVOID ALKALI, CNS INHAL:ADDICTION, EUPHORIA, DISORIENTATION, DELUSIONS, RESP IRRIT, DERM & MAY BE EYE IRRIT, BURNS, REDNESS, BLURRED VISION, SKIN IRRIT, DIARR, ABSORBED IN TOX AMTS. INGEST:SEV BURNING SENSA IN MOUTH/THROAT/STOM, FAILURE. CONFUSN, INEBRIATION, CNS DEPRESS, DEATH FROM RESP/CARDIAC CRAMPS, CHRONIC:LIVER/KIDNEY/LUNG/BRAIN DMG, CARDIAC ARRHYTHMIA, VOMIT, CONJ, REPRO SLEEPINESS, BLINDNESS, PARAL OF FINGERS, PERSONALITY CHANGES, EFTS. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: FISHER SCIENTIFIC Label Street: 1 REAGENT LANE Label City: FAIR LAWN Label State: NJ Label Zip Code: 07410 Label Country: US Label Emergency Number: 201-796-7100;800-424-9300(CHEMTREC) add to, or URL for this msds http://siri.org. If you wish to change, delete information in this archive please send updates to [email protected]._3 6/4/97 10:56 A 6 of 6 06/09/97 10:32 '301 480 8056 NIH EPB - 002 I Page 1 OHS1A44 MERCURY FULMINATE - CTION 1 CNEMICAL PRODUCT AND COMPANY IDENTIFICATION INFORMATION SYSTE4S, INC. FOR EMERGENCY SOURCE INFORMATION tL USA 14600 CATALINA STREET CONTACT: 1-615-366-2000 *AN LEANDRO, CA 94577 -800-635-0064 OR 1-510-895-1313 CAS NUMBER: 628-86-4 RTECS NVUBER: OW4055000 EU NUMBER (EINECS): 211-057-8 $UBSTANCE: MERCURY FULMINATE RADE NAMES/SYNONYMiS: ThLMINIC ACID, MERCURY(2+) SALT; MERCURIC FULMINATE; MERCURY FULMINATE UN 0135; HG(ONC)2); MERCURIC CYANATE; MERCURY(II) FULMINATE; RCRA P065; .H2GN202; OHS14040 HE-MICAL FAMILY: talt CREATION. DATE: 09/09/87 REVISION DATE: 08/10/96 ECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS OMPONENT: MERCURY FULMINATE AS NUMBER: 628-86-4 PERCENTAGE: 100.0 ------I ------ NFPA RATINGS (SCALE 0-4): HFALTH=2 FIRE=3 REACTIVITY=4 I EU CLASSIFICATION:33 RE; R 3 06/09/97 10:32 /301 480 8056 NIE EPB (J003 DHS14040 MERCURY FULMINATE Page 2 T; R 23/24/25 EMERGENCY OVERVIEW: COLOR: white, brown or gray. PHYSICAL FORM: crystalline powder. MIAJOR HEALTH HAZARDS: skin irritation, eye irritation, allergic reactions. PHYSICAL HAZARDS: May explode if exposed to shock, friction or heating. POTENTIAL HEALTH EFFECTS; INHALATION; SHORT TERM EXPOSURE: allergic reactions, metallic tasto, nausea, vomiting, diarrhea, chest pain, difficulty breathing, headache, lung damage, kidney damage. LONG TERM EXPOSURE: blue lines on the gums, loosening of the teeth, nerve damage, reproductive effects. SKIN CONTACT: SlORT TERM EXPOSURE: irritation, allergic teacins.- LONU TERM EXPOSURE; same as effects reported in long term inhalation, kidney damage, nerve damage. EYE CONTACT: SHORT TERM EXPOSURE: irritation, itching. LONG TERM EXPOSURE: no information on significant adverse effects. INGESTION! SHORT TERM EXPOSURE: same as effect5 reported in long term inhalation, nausea, vomiting. LONG TERM EXPOSURE: same as effects reported in long term inhalation, kidney damage, nerve damage. CARCINOGEN STATUS: OSHA: N NTP: N IARC: N ------3 SECTION 4 FIRST AID MEASURES ------U INHALATION! Remove from exposurc immediately. Use a bag valve mask or similar device to perform artificial respiration (rescue breathing) if needed. Get medical attention. SKIN CONTACT: Remove contaminated clothing, jewelry, and shoes immediately. Wash with soap or mild detergent .and large amounts of water until no evidence of chemical remains (at least 15-20 minutes) . Get medical attention, if needed. EYE CONTACT: Wash eyes immediately with large amounts of water or normal3 - 004 06/09/97 10:32 301 480 8056 NIH EPB Page 3 OHS14040 MERCURY FULMINATE no evidence of upper and lower lids, until saline, occasionally lifting attention limediately. - chemical remains. Get medical control center or physician immediately. !4GESTION: Contact local poison vomit or drink fluids. When vomiting Never make an unconscious person If person is hips to help prevent aspiration. occurs, keep head lower than Get medical attention immediately. unconscious, turn head to side. penicillamine, oral; intramuscular; herodialysis; [TIDOTE: dimercapro/oil, chelating agent. catharsis. consider gastric lavage and 3 TE TO PHYSICIAN: For ingestion, ------*ECTION 5 FIRE FIGHTTNG MEASURES U------hazard. Severe fire hazard. Severe explosion IBE AND EXPLOSION RAZARDS: use dry water. If no water is available, EXTINGUISHING YEDIA; Flood with chemical or earth. Cool containers with water in cargo or storage area: IREFIGHTING: For fires well after fire is out. holder or monitor nozzles until from unmanned hose Keep take the following precautions: I If this is impossible then the fire hazard area and deny entry. Let unnecessary people away, isolate until Cool containers with watcr spray burn. Flood with water. Explosive. or from Apply water from a protected location well after the fire is out. are E gets out of control or containers safe distance. Evacuate if fire a radius; 500 feet. directly exposed to fire. Evacuation firefighting turn-out gear (bunker PROTECTIVE EQUIPMENT: Full a. IFIREFIGHTING full facepiece and operated in Any supplied-air respirator with gear). in combination with a or other positive-pressure mode E pressure-demand breathing apparatus with a full separate escape supply. Any self-cnntained tacepiece. ------MEASURES I------SECTION 6 ACCIDENTAL RELEASE ------ WATER RELEASE: of 1986 Water and Toxic Enforcement Act Subject to California Safe Drinking water supplies and sewers. (Proposition 65). Keep out of OCCUPATIONAL RELEASE: 06/09/97 10:33 Y301 480 8056 NIH EPB Z005 Page 4 OHS14040 MERCURY FULMINATE Do not touch Avoid heat, flames, sparks and other sources of ignition. spills; Wet down spilled material. Small spills: Flood with water. Large Keep area with water. Dike for later disposal. Remove sources of ignition. entry. Reportable unnecessary people away, isolate hazard area and deny Committee and Quantity (RQ); 10 pounds. Notify Local Emergency Planning to RQ State Emergency Response Commission for release greater than or equal is reportable (U.S. SARA Section 304) . If release occurs in the U.S. and a under CERCLA Section 103, notify the National Response Center (800)424-8802 (USA) or (202)426-2675 (USA). ------I SECTION 7 RANDLING AND STORAGE ------3 and standards. Store and handle in accordance with all current remilations Keep moist. Keep separated from incompatible substances. ------SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION ------U EXPOSURE LIMITS: MERCURY FULMINATE: MERCURY, ALL FORMS EXCEPT ALKYL (as Hg): 0.1 mg/m3 OSHA ceiling 30, 0.05 mg/m3 OSHA TWA (vapor) (skin) (vacated by 58 FR 35338, June 1993) 0.10 mg/m3 ACGIH TWA (aryl) (skin) 0.025 mg/m3 ACGIH TWA (metal and inorganic compounds) (skin) 0.05 mg/m 3 NIOSH recommended TWA 10 hour(s) (vapor) (skin) 0.1 mg/m3 NIOSH recommended ceiling (skin) 0.01 ppm (0.1 mg/m3) DFG MAK TWA 0.1 ppm (1.0 mg/m3) DFG MAK peak 30 minute average value 1 timee/shift MEASUREMENT METHOD; Hydrar(R) sorbent tube; Acid; Atomic absorption spectrometry (cold); NIOSH III # 6009, Mercury equipment VENTILATION: Provide local exhaust ventilation system. Ventilation of material are should be explosion-resistant if explosive concentrations present. Ensure compliance with applicable exposure limits. EYE PROTECTION: Wear splash resistant safety goggles. Provide an emergency work area. eye wash fountain and quick drench shower in the imnediate CLOTHING: Wear appropriate chemical resistant clothing. I 06/09/97 10:33 5301 480 8056 NIH EPB 0006 Page 5 =H514040 MERCURY FJLMINATE GLOVES: Wear appropriate chemical resistant gloves. use concentrations are SPIRATOR: The following respirators and maximum be certified by drawn from NIOSH and/or OSHA. Respiratory equipment must NIOSH/MSHA. Measurement Element: Hg ,00 mg/m3 providing protection Any chemical cartridge respirator with cartridge(s) * against this substance. End of service life indicator required (ESLI) - Any supplied-air respirator. 5 mg/m3 Any supplied-air respirator. Any powered, air-purifying respirator with cartridge(s) providing protection against this substance. End of service life indicator required (ESLI). mg/m3 and cartridge(s) Any chemical cartridge respirator with a full facepiece providing protection against this substance. End of service life indicator required (ESLI). I Any air-purifying respirator with a full facepiece and a canister providing protection against this substance- End of service life indicator required (ESLI). Any supplied-air respirator with a full facepiece. 3 facepiece and Any powered, air-purifying respirator with a full cartridge(s) providing protection against this substance. I Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 10 mg/m3 or other I Any supplied-air respirator operated in a pressure-demand positive-pressure mode. Escape - and a canister Any air-purifying respirator with a full facepiece providing protection against this substance. Any appropriate escape-type, self-contained breathing apparatus. Life or Health - or Unknown Concentrations or Immediately Dangerous to in a supplied-air respirator with full facepiece and operated Any with a pressure-demand or other positive-pressure mode in combination separate escape supply- full facepiece. [Any self-contained breathing apparatus with a SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES S------COLOR: white, brown or gray 06/09/97 NIH EB 10:40 Y301 480 8056 _ _NIH EPB I~0010 OHS14040 MERCURY FULMINATE Page 7 HEALTH EFFECTS: INHALATION: MERCURY FULMINATE: See information on inorganic mercury compounds. ACUTE EXPOSURE: TNORGANIC MERCURY COMPOUNDS: Inhalation of high compounds may cause levels of mercury almost immediate dyspnea, vomiting, diarrhea, cough, fever, nausea, headache, stomatitis, salivation, metallic taste, and cardiaC gingivitis, a abnormalities. Respiratory occur with chest pain irritation may and tightness. Symptoms progress to necrotizing may resolve or may bronchiolitis, pneumonitis, pneumothorax, and interstitial pulmonary edema, fibrosis. Acidosis, death may occur. Allergic renal damage and reactions that may occur persons include dermatitis, in previously exposed encephalitis, and death. CHRONIC EXPOSURE: INORGANIC MERCURY COMPOUNDS: Repeated may cause inhalation of mercury mercurialism, which is compounds erethism. characterized by fine tremors Tremors may affect the and evident hands first, but may in the face, arms, also become abnormal and legs. Erethism shyness, blushing, may be manifested by despondency, sclf-consciousness, depression resentment of criticism, or headache, irritability or excitability, fatigue, and insomnia. in severe cases, hallucinations, of memory and mental deterioration loss 0.03 may occur, Concentrations mg/m3 have induced psychiatric as low as Involvement symptoms in humans. Renal may be indicated by proteinuria, Other effects enzymuria, and may include salivation, anuria. of the teeth, gingivitis, stomatitis, blue lines on the gums, loosening speech and diarrhea, weight loss, sensory disorders, unsteady anorexia, chronic gait, constricted visual pneumonitis and mild anemia. tields, its compounds Repeated exposure to mercury may result in sensitization. and milk. Mercury is excreted I Several studies have revealed in breast reproductive that inorganic mercury effects such as chromosomal can cause animals; transplacental aberrations in humans and passage in 'female humans ovulation, lengthening and animals; decreased of the estrus cycle, and congenital increased infant mortality, malformation in rodents. Spontaneous weight and abnormal abortions, low birth development of the nervous reported. system have also been SKIN CONTACT: MERCURY FULMINATE: See information on inorganic have a vesicant mercury compounds. May action and may cause deriatitis and allergic reactions. ACUTE EXPOSURE: NIHEB 80568IHEPB - 06/09/97 10:40 I301 480 -- IQ002 0HS14040 MERCURY FULMINATE Page 8 INORGANIC MERCURY COMPOUNDS: Mercury compounds may cause irr~tation. Small skin amounts of mercury may'be I skin. Allergic absorbe-d through intact reactions that may occur include encephalitis, and death. dermatitis, * CHRONIC EXPOSURE; INORGANIC MERCURY COMPOUNDS! Prolonged or repeated exposure to mercury compounds may result in dermal sensitization and systemic effects detailed in chronic inhalation. as EYE CONTACT: MERCURY FUUNINATE: See information on inorganic mercury causes conjunctival irritation, compounds. Dust itching erythema and swellinq face and other exposed skin. of the l.ids, I ACUTE EXPOSURE: INORGANIC MERCURY COMPOUNDS: Mercury compounds may cause irritation. CHRONIC EXPOSURE: INORGANIC MERCURY COMPOUNDS: Mercury ingestion, exposure from inhalation, or skin contact may be I discoloration indicated by mercurialentis, of the crystalline lens, on eyes. slit lamp examination of the VNGESTION: MERCURY FUlTINATE: See information on inorganic mercury compounds. ACUTE EXPOSURE: INORGANIC MERCURY COMPOUNDS: Ingestion of mercury burning of the mouth compounds may cause and throat, thirst, nausea a signs and symptoms and vomiting. May cause as detailed in chronic inhalation. CHRONIC EXPOSURE: INORGANIC MERCURY COMPOUNDS: Repeated ingestion effects may result in toxic as detailed in chronic inhalation. ------ECTION 12 ECOLOGICAL U------INFORMRTION data available. ------CONSIDERATIONS --Ct-- CTTN -N 13-1 ------DISPOSAL ------..... 06/09/97 lu:33 %2301 480 6056 NIH EPB 16007 DH514040 MERCURY "ULMINATE Page 6 PHYSICAL FORM: crystalline powder 4OLECULAR WEIGHT: 284-62 MOLECULAR FOPMULA: HG- (C-N-0) 2 MELTING POINT: explodes VAPOR PRESSURE: not applicable VAPOR DENSITY: not applicable SPECIFIC GRAVITY (water=1): 4.42 WATER SOLUBTLITY: soluble in hot water DH: not applicable VOLATILITY; not applicable ODOR THRESHOLD: No data available. EVAPORATION RATE: not applicable SOLVENT SOLUBILITY: Soluble: alcohol, ammonium hydroxide ------U SECTION 10 STABILITY AND REACTIVITY ------I REACTIVITY: Explosive if dry. May explode if exposed to shock, friction or 1eating. I CONDITIONS TO AVOID: Avoid heat, flame5, sparks and other sources of sewers. ignition. Keep wet. Keep ut of water supplies and INCOMPATIBILITIES: acids. MERCURY FULMINATE: SULFURIC ACID: Explosive. of HAARDOTTS DECOMPOSITION: Thermal decomposition products; mercury, oxides nitrogen. Will not polymerize. POLYMERIZATIQN:------SECTION------11 TOXICOLOGICAL INFORMATION MERCURY FULMINATE: CARCINOGEN STATUS: None. LOCAL EFFECTS: Irritant: skin, eye. ACUTE TOXICITY LEVEL: No data available. TARGET ORGANS: immune system (sensitizer), nervous system, kidneys MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: kidney problems, nervous system problems, respiratory problems. 06/09/97 10:34 %Y301 480 8056 NIH EPB I008 514040 MERCURY FULMINATE Page 9 Ibject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): P065. Hazardous Waste Number(s); D009. Dispose of in accordance Iwith U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory level- 0.2 mg/L. Dispose in accordance with all applicable regulations. SECTION 14 TRANSPORT INFORMATION U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER: ercury fulminate, wetted-UN0135 S. DOT 49 CER 172.101 HAZARD CLASS OR DIVISION: jS DOT 49 CFR 172.101 PACKING GROUP: II I.S. OT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS: EXPLOSIVE 1.lA .S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS: EXCEPTIONS: None ON-BULK PACKAGING: 49 CFR 173.62 ULK PACKAGING: None .. DOT 49 CFR 172.101 QUANTITY LIMITATIONS: ASSENGER AIRCRAFT OR RAILCAR: Forbidden ARGO AIRCRAFT ONLY: Forbidden ECZTION 15 REGULATORY INFORMATION US. REGULATIONS: TSCA INVENTORY STATUS: Y TSCA 12(b) EXPORT NOTIFICATION: Not listed. CERCLA SECTION 103 (40CFR302.4): Y I MERCURY FULMINATE 10 LBS RQ SARA SECTION 302 (40CFR355.30): N SARA SECTION .304 (40CFR395.40) N SARA SECTION 313 (40CFR372.65): Y MERCURY, ALL FORMS EXCEPT ALKYL (as Hg) MERCURY FULMINATE U6/09/97 10.34 #&301 480 8056 NIH EPB Z009 Page 10 oHs14040 MERCURY FULMINATE 3 SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21): ACUTE; CHRONIC: Y FIRE: Y REACTIVE: SUDDEN RELEASE: N OSHA PROCESS SAFETY (29CFR1910.119): N STATE REGULATIONS: CALIFORNIA PROPOSITION 65: Y MERCURY, ALL FORMS EXCEPT ALKYL (as Hg) INTERNATIONAL REGULATIONS: EU NUMBER (EINECS) : 211-057-8 EU RISK AND SAFETY PHRASES: R: 3-23/24/25-33 Extreme risk of explosion by shock, friction, fire or other sources of ignition. Toxic by inhalation, in contact with skin and if swall2owed. Danger of cumulative effects. S: 1/2-3-35-45 Keep locked-up and out of reach of children. Keep in a cool place. This materia) and its container must be disposed of in a safe way. In case of accident or if you feel unwell, seek medical advice (show the label where possible) . ------immediately SECTION------16 OTHER INFORMATION U COPYRIGHT 1964-1997 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED. Licensed to: occupational Safety and Health Branch, DS To make unlimited paper copies for internal distribution and use only. PAGE 01 OF 05 U I*ACETONEEE EZACETONENI *ACETONERZ MATERIAL SAFETY DATA SHEET FISHER SCIENTIFIC EMERGENCY CONTACTS. DIVISION GASTON L. PILLORY. (201) 796-7100 CHEMICAL HOLIDAYS. 1 REAGENT LANE AFTER BUSINESS HOURS, (201) 796-7523 FAIR LAWN NJ 07*10 (800) -29-9300 (2012 796-7100 CHEMTREC ASSISTANCE, THE BEST THE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS MAKE NO WARRANTY OF INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED. WITH RESPECT TO MERCHANTABILITY ITS USE. USERS SUCH INFORMATION. AND WE ASSUME NO LIABILITY RESULTING FROM SUITABILITY OF THE SHOULD MAKE THEIR OWN INVESTIGATIONS, TO.DETERMINE THE INFORMATION FOR THEIR PARTICULAR PURPOSES. I --...... -....---..---...-----..----...----.------.------SUBSTANCE IDENTIFICATION CAS-NUMBER 67-64-1 SUBSTANCE: EZACETONESE NAMES/SYNONYMS TRADE BETA-KETOPROPANE DIMETHYLFORMALDEHYDE1 DIMETHYLKETAL, DIMETHYL KETONES 2-PROPANONEI PYROACETIC ETHER B-KETOPROPANE RCRA U002S PROPANONE A-la; STCC *908105; UN 10901 A-9*9, A-'t0; A-201 A.19; A-9461 A-16-SI C3H60 A-18-S; A-18-SK A-1il A-ll-Sy A-16-P CHEMICAL FAMILY: KETONE. ALIPHATIC MOLECULAR FORMULA: C-H3-C-O-C-H3 MOLECULAR WEIGHT: 58.08 PERSISTENCE:0 CERCLA RATINGS (SCALE 0-32, HEALTH1 FIRE=3 REACTIVITY=O NFPA RATINGS (SCALE 0-4), HEALTH=1 FIRE:3 REACTIVITY:0 COMPONENTS AND CONTAMINANTS PERCENT, 100 COMPONENT. ACETONE OTHER CONTAMINANTS: NONE EXPOSURE LIMITS. ACETONE: PPM (1780 MG/M3) OSHA TWA, 1000 PPM (2375 MG/M33 OSHA STEL 750 ACGIH STEL 750 PPM (1780 MG/M33 ACGIH TWA; 1000 PPM (2375 MG/M33 250 PPM (590 MG/M3) NIOSH RECOMMENDED 10 HOUR TWA 5000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING PHYSICAL DATA DESCRIPTION, CLEAR. COLORLESS. VOLATILE LIQUID WITH A CHARACTERISTIC. SWEETISH. FRAGRANT, MINT-LIKE ODOR AND PUNGENT, SWEETISH TASTE. BOILING POINT, 133 F C56 C) MELTING POINT: -139 F (-95 C) SPECIFIC GRAVITY: 0.7899 VOLATILITY, 100% 14.V VAPOR PRESSURES 180 MMHG a 20 C EVAPORATION RATE, CBUTYL ACETATE:1) PH: NEUTRAL IN SOLUTION SOLUBILITY IN WATERS VERY SOLUBLE ODOR THRESHOLDS 20 PPM VAPOR DENSITY: 2.0 BENZENE. MOST SOLVENT SOLUBILITY: SOLUBLE IN ETHANOL. ETHER, CHLOROFORM, OILS. DIMETHYLFORMAMIDE -- A------FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD, DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPOR-AIR MIXTURES ARE EXPLOSIVE. FLASH POINT -4 F C-20 C) CCC) UPPER EXPLOSIVE LIMIT 13% C(55 C) LOWER EXPLOSIVE LIMIT, 2. 5% AUTOIGNITION TEMP., 869 F FLAMMABILITY CLASSCOSHAli IB MEDIA FIREFIGHTING OR ALCOHOL FOAM DRY CHEMICAL, CARBON DIOXIDE. HALON. WATER SPRAY (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800. ). PACE 02 OF OS KNACETONEKS ALCOHOL FOAM FOR LARGER FIRES. USE WATER SPRAY. FOG OR P 50D.3). (1587 EMERGENCY RESPONSE GUIDEBOOK, DOT FIREFIGHTING WITH AREA IF POSSIBLE. COOL FIRE-EXPOSED CONTAINERS MOVE CONTAINER FROM FIRE TANK WELL AFTER FIRE IS OUT. STAY AWAY FROM STORAGE WATER FROM SIDE UNTIL HOLDER OR MONITOR FIRE IN STORAGE AREA, USE UNMANNED HOSE ENDS. FOR MASSIVE WITHDRAW IMMEDIATELY IN ELSE WITHDRAW FROM AREA AND LET FIRE BURN. NOZZLES. DEVICE OR ANY DISCOLORATION OF OF RISING SOUND FROM VENTING SAFETY CASE RESPONSE GUIDEBOOK. DOT P 5800.. STORAGE TANK DUE TO FIRE (1987 EMERGENCY GUIDE PAGE 26). AMOUNTS OF WATER AS A ONLY IF FLOW CAN BE STOPPED. USE FLOODING EXTINGUISH WITH FLOODING AMOUNTS STREAMS MAY BE INEFFECTIVE. COOL CONTAINERS FOG SOLID BREATHING VAPORS KEEP FROM AS FAR A DISTANCE AS POSSIBLE. AVOID 1 OF WATER ARE EXPOSED TO DIRECT FLAME, IF FIRE IS UNCONTROLLABLE OR CONTAINERS UPWIND. EVACUATION OF DOWNWIND AREA IF EVACUATE TO A RADIUS OF 1500 FEET. CONSIDER MATERIAL IS LEAKING. GUIDE ON HAZARDOUS MATERIALS,. WATER MAY HE INEFFECTIVE CNFPA FIRE PROTECTION EIGHTH EDITION). ON HAZARDOUS MATERIAL, EIGHTH ALCOHOL FOAM CNFPA FIRE PROTECTION GUIDE EDITION), TRANSPORTATION DATA +9CFR172.101. DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION FLAMMABLE LIQUID REQUIREMENTS *9CFR17Z.101 AND 172.02, DEPARTMENT OF TRANSPORTATION LABELING FLAMMABLE LIQUID REQUIREMENTS "9CFR173.119 DEPARTMENT OF TRANSPORTATION PACKAGING EXCEPTIONS, +SCFR173.118 TOXICITY ACETONE. MILD IRRITATION 3950 UG IRRITATIONj 395 MG OPEN SKIN-RABBIT 500 PPM EYE-HUMAN MODERATE IRRITATION SEVERE IRRITATION; 20 MG/2t HOURS EYE-RABBIT EVE-RABBIT 500 PPM INHALATION-HUMAN TCLO, 500 MG/V4- HOURS SKIN-RABBIT MILD IRRITATION TCLOL D MG/M3/6 HOURS INHALATION-MAN -TCLO) 12000 PPM/+ HOURS INHALATION-MAN TOLO, 1159 MG/KG INHALATION-MAN TCLO, 2857 MG/KG ORAL-MAN ++0 UG/M3/ MINUTES LOLOS 5800 MG/KG ORAL-RAT LOSOl 8 GM/KG ORAL-DOG UNREPORTED-MAN LDLO; LOSOI 20 GM/KG SKIN-RABBIT ORAL-MOUSE LDS0; S3+0 MG/KG ORAL-RABBIT 3000 MG/KG LCLO 1297 MG/KG INTRAPERITONEAL-MOUSE LOSO: 110 GM/M3/1 HOUR INHALATION-MOUSE LOLO, LDLO, 500 MG/KG INTRAPERITONEAL-RAT LDSO; B GM/KG INTRAPERITONEAL-DOG GM/KG LDLO 5500 MG/KG INTRAVENOUS-RAT LOSO, t 1576 MG/KG INTRAVENOUS-RABBIT PIG LDLO, 5 GM/KG LDLOg 5000 MG/KG SUBCUTANEOUS-GUINEA INTRAVENOUS-MOUSE CRTECS)I REPRODUCTIVE EFFECTS DATA SUBCUTANEOUS-DOG LDLOI MUTAGENIC DATA CRTECS), NONE. CARCINOGEN STATUS, AND CENTRAL NERVOUS IS A SKIN, EYE AND MUCOUS MEMBRANE IRRITANT ACETONE MAY ENHANCE THE TOXIC DEPRESSANT. THE USE OF ALCOHOLIC BEVERAGES SYSTEM OR SKIN DISEASES MAY BE AT AN EFFECTS. PERSONS WITH CHRONIC RESPIRATORY INCREASED RISK FROM EXPOSURE. HEALTH EFFECTS AND FIRST AID INHALATION:I ACETONE, HEALTH. PPM IMMEDIATELY DANGEROUS TO LIFE'OR IRRITANT/NARCOTIC. 20.000 MAY CAUSE SLIGHT VAPOR CONCENTRATIONS AROUND 1000 PPM ACUTE EXPOSURE- TRACT. EXPOSURE TO 12.000 TRANSIENT IRRITATION OF THE UPPER RESPIRATORY AND CENTRAL NERVOUS SYSTEM DEPRESSION PPM HAS CAUSED THROAT IRRITATION NAUSEA AND A THE LEGS, HEADACHE. DIZZINESS. DROWSINESS. WITH WEAKNESS OF FROM EXPOSURE TO HIGH FEELING OF MALAISE. OTHER POSSIBLE EFFECTS GENERAL MOUTH AND THROAT. INCOORDINATION OF CONCENTRATIONS INCLUDE DRYNESS OF THE BY ANOREXIA. VOMITING, SOMETIMES FOLLOWED MOTION AND SPEECH, RESTLESSNESS. SLOW. WEAK DYSPNEA. SLOW. IRREGULAR RESPIRATION. HEMATEMESIS. HYPOTHERMIA. CASES, COMA. LIVER COLLAPSE WITH STUPOR. AND IN SEVERE PULSE. PROGRESSIVE AND JAUNDICE. KIDNEY MAY BE INDICATED BY HIGH UROBILIN LEVELS DAMAGE AND RED AND WHITE BLOOD CELLS IN THE DAMAGE MAY BE INDICATED BY ALBUMIN IS POSSIBLE. LEVELS MAY BE AFFECTED AND FATAL KETOSIS URINE. BLOOD GLUCOSE DAYS EXPERIENCED WORKERS EXPOSED TO 500 PPM/6 HOURS/B CHRONIC EXPOSURE- HEAVY EYES. OVERNIGHT MEMBRANE IRRITATION, AN UNPLEASANT SMELL, MUCOUS BY HEMATOLOGIC CHANGES. HEADACHE. AND GENERAL WEAKNESS ACCOMPANIED DAYS. WORKERS EXPOSED TO 1000 PPM FOR RECOVERY OCCURRED IN SEVERAL THE YEARS REPORTED CHRONIC INFLAMMATION OF 3 HOURS/DAY FOR 7-15 OF STRENGTH. AND STOMACH AND DUODENUM. DIZZINESS, LOSS RESPIRATORY TRACT, AND COUGHING HAVE ALSO DROWSINESS, VERTIGO. SENSATION OF HEAT. ASTHENIA. CONCENTRATIONS. ANIMAL STUDIES REPORTED FROM CHRONIC EXPOSURE TO LOW BEEN FEMALES WERE EXPOSED CHRONICALLY SHOW ADVERSE EFFECTS ON FERTILITY WHEN DURING PREGNANCY. IF BREATHING EXPOSURE AREA TO FRESH AIR IMMEDIATELY. FIRST AID- REMOVE FROM PERSON WARM AND AT REST. PERFORM ARTIFICIAL RESPIRATION. KEEP HAS STOPPED. GET MEDICAL ATTENTION IMMEDIATELY. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. SKIN CONTACT. ACETONEt IRRITANT. PAGE 03 OF 05 ZZACETONEZZ CONTACT WITH THE LIQUID CAUSED MILD IRRITATION IN RABBITS. ACUTE EXPOSURE- EDEMA AND DAMAGE TO THE OUTER LAYERS OF THE EPITHELIUM WITH MILD CELLULAR REVERSIBLE. HYPEREMIA HAS BEEN DEMONSTRATED IN HUMANS. BUT WAS READILY AMOUNTS MAY BE ABSORBED THROUGH INTACT SKIN. SMALL DERMATITIS WITH CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE MAY CAUSE AND ERYTHEMA DUE TO THE DEFATTING ACTION. THE AMOUNT DRYING, CRACKING. EXTENT THROUGH THE SKIN INCREASES DIRECTLY. WITH THE FREQUENCY AND ABSORBED FOR 3 WEEKS OF THE EXPOSURE. 2 OF 3 GUINEA PIGS EXPOSED BY SKIN CONTACT DEVELOPED CATARACTS BY THE END OF THREE MONTHS. WASH AFFECTED AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. FIRST WATER UNTIL NO AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF MINUTES). GET MEDICAL EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 ATTENTION IMMEDIATELY. EYE CONTACT ACETONE IRRITANT. WHEN THE ACUTE EXPOSURE- IN HUMANS, VAPORS PRODUCE ONLY SLIGHT IRRITATION IS AT OR BELOW 1000 PPM. HOWEVER. HIGH VAPOR CONCENTRATIONS CONCENTRATION LIQUID CORNEAL EPITHELIAL AND CONJUNCTIVAL INJURY IN ANIMALS. HAVE CAUSED IF IN HUMAN EYES CAUSES AN IMMEDIATE STINGING SENSATION AND. SPLASHED BY PROMPTLY. DAMAGE ONLY TO THE CORNEAL EPITHELIUM CHARACTERIZED WASHED HEALS COMPLETELY MICROSCOPIC GRAY DOTS AND A FOREIGN BODY SENSATION. WHICH IN 1-2 DAYS. CHRONIC EXPOSURE- PROLONGED OR REPEATED EXPOSURE TO THE.VAPORS MAY CAUSE IRRITATION OR CONJUNCTIVITIS. SALINE. WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL FIRST AID- OF CHEMICAL OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE IMMEDIATELY. REMAINS CAPPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION INGESTION: ACETONE. NARCOTIC. AND MUCOUS MEMBRANE ACUTE EXPOSURE- MAY CAUSE A FRUITY ODOR OF THE BREATH IRRITATION. IN ACUTE CASES, A LATENT PERIOD MAY BE AND GASTROENTERIC AND FOLLOWED BY RESTLESSNESS AND VOMITING PROCEEDING TO HEMATEMESIS PROGRESSIVE COLLAPSE WITH STUPOR. HEPATORENAL LESIONS HAVE BEEN REPORTED. MAY BE AFFECTED AND KETOSIS MAY BE FATAL. 10-20 THE BLOOD GLUCOSE LEVEL HAVE HAVE BEEN TOLERATED WITHOUT ILL EFFECTS. 200 MILLILITERS MILLILITERS AND STUPOR WITHIN A HALF HOUR. FLUSHED CHEEKS. SHALLOW RESPIRATION, CAUSED FOR MONTHS. COMA WHICH LASTED FOR 12 HOURS. RENAL GLUCOSURIA PERSISTED 5 CHRONIC EXPOSURE- NO DATA AVAILABLE. FIRST AID- REMOVE BY GASTRIC LAVAGE OR EMESIS AND CONSIDER USING ACTIVATED NOT PERFORM GASTRIC LAVAGE OR EMESIS ON AN UNCONSCIOUS PERSON. CHARCOAL. DO IS MAINTAIN BLOOD PRESSURE AND RESPIRATION. GIVE OXYGEN IF RESPIRATION OR ANOXIA IS PRESENT. CDREISBACH. HANDBOOK OF POISONING, 12TH ED.) SHALLOW IMMEDIATELY. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION LAVAGE AND OXYGEN MUST BE ADMINISTERED BY QUALIFIED MEDICAL PERSONNEL. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ------REACTIVITY REACTIVITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. INCOMPATIBILITIES, ACETONE: ACIDS, INCOMPATIBLE. AMINES CALIPHATIC): INCOMPATIBLE. BROMINE: VIOLENT REACTION WITH EXCESS AMOUNTS OF BROMINE. BROMINE TRIFLUORIDE: EXPLOSION ON CONTACT. BROMOFORM VIOLENT REACTION IN PRESENCE OF BASES (E.G. POTASSIUM HYDROXIDE3. CHLOROFORM: VIOLENT REACTION IN PRESENCE OF A BASE. CHROMIUM TRIOXIDE IGNITION ON CONTACT AT AMBIENT TEMPERATURE. CHROMYL CHLORIDE: INCANDESCENT REACTION. DIOXYGEN DIFLUORIDE + SOLID CARBON DIOXIDE. EXPLOSION AT -7a C. HEXACHLOROMELAMINE: POSSIBLE EXPLOSION. HYDROGEN PEROXIDE: EXPLOSION. NITRIC ACID: IGNITION. NITRIC + ACETIC ACID MIXTURE. POSSIBLE EXPLOSION. NITRIC + SULFURIC ACID MIXTURE: VIOLENT OXIDATION. NITROSYL CHLORIDE: EXPLOSIVE REACTION. NITROSYL PERCHLORATE: IGNITION AND EXPLOSION. NITRYL PERCHLORATE. IGNITION AND EXPLOSION. OXIDIZERS (STRONG), FIRE AND EXPLOSION HAZARD. PERMONOSULFURIC ACID EXPLOSION. PLASTICS: INCOMPATIBLE. PLATINUM + NITROSYL CHLORIDE'POSSIBLE EXPLOSION. POTASSIUM-TERT-BUTOXIDE IGNITION. RAYON, INCOMPATIBLE. SODIUM HYPOBROMITE: EXPLOSION. SODIUM HYPOIODITE, POSSIBLE EXPLOSION. SULFUR DICHLORIDE: VIOLENT REACTION. SULFURIC ACID AND POTASSIUM BICHROMATE: IGNITION. THIODIGLYCOL + HYDROGEN PEROXIDE: POSSIBLE EXPLOSION. THIOTRIAZYL PERCHLORATE, POSSIBLE EXPLOSION. 1,1,1-TRICHLOROETHANE: EXOTHERMIC CONDENSATION BY A BASIC CATALYST. TRICHLOROMELAMINE. POSSIBLE EXPLOSION. SEE ALSO KETONES. KETONES, ' ACETALDEHYDE: VIOLENT CONDENSATION REACTION. PAGE 0i OF 05 PRODUCT. EXACETONEXI FORMATION OF EXPLOSIVE ACID + HYDROGEN PEROXIDE, NITRIC DECOMPOSITION. PERCHLORIC ACID, VIOLENT TOXIC OXIDES OF CARBON. DECOMPOSITION, PRODUCTS MAY INCLUDE THERMAL DECOMPOSITION TO OCCUR UNDER NORMAL POLYMERIZATION, HAS NOT BEEN REPORTED HAZARDOUS POLYMERIZATION TEMPERATURES AND PRESSURES. STORAGE AND DISPOSAL WHEN STORING OR DISPOSING STATE AND LOCAL REGULATIONS DIRECTOR OF THE OBSERVE ALL FEDERAL. CONTACT THE DISTRICT SUBSTANCE. FOR ASSISTANCE. OF THIS AGENCY. ENVIRONMENTAL PROTECTION SESTORAGES WITH 29 CFR 1910.106. STORE IN ACCORDANCE WHICH WITH LOW ELECTROCONDUCTIVITY. SUBSTANCES STORED IN CONTAINERS BONDING AND GROUNDING. SPARKS. SHOULD BE 77-1983. BY ELECTROSTATIC SPECIFIED IN NFPA MAY BE IGNITED GROUNDING GUIDELINES MEET THE BONDING AND WHICH ON STATIC ELECTRICITY. RECOMMENDED PRACTICE SUBSTANCES. STORE AWAY FROM INCOMPATIBLE XEDISPOSALEE TO GENERATORS OF WITH STANDARDS APPLICABLE BE IN ACCORDANCE NUMBER UG0. DISPOSAL MUST EPA HAZARDOUS WASTE WASTE, +0CFR 262. HAZARDOUS SIEE EEZEEZEZEZEZEEZEEEE SSZEEZEEEE IZEEEEEEZEEEE EEEEEEZEEEEEEEEEE*EEEZEEZEECONDITIONS TO AVOID OF MAY EXPLODE IN HEAT OR FLAMES. CONTAINER TO BY HEAT. SPARKS OR IN SEWERS. RUN-OFF MAY BE IGNITED INDOORS, OUTDOORS VAPOR EXPLOSION HAZARD FIRE. OR EXPLOSION HAZARD. SEWER MAY CREATE FIRE EEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEEESPILL AND LEAK PROCEDURES WATER WITHOUT RISK. USE OCCUPATIONAL SPILL: IF YOU CAN DO IT SOURCES. STOP LEAK SAND OR OTHER SHUT OFF IGNITION SPILLS, TAKE UP WITH LARGER VAPORS. FOR SMALL LATER DISPOSAL. FOR SPRAY TO REDUCE INTO CONTAINERS FOR FLAMES OR MATERIAL AND PLACE NO SMOKING, ABSORBENT SPILL FOR LATER DISPOSAL. HAZARD AREA AND DIKE FAR AHEAD OF AWAYI ISOLATE SPILLS, KEEP UNNECESSARY PEOPLE FLARES IN HAZARD AREAI DENY ENTRY. POUNDS 30- REQUIRES QUANTITY CR0), 5000 ACT (SARA) SECTION REPORTABLE AND REAUTHORIZATION FOR THIS SUPERFUND AMENDMENTS THE REPORTABLE QUANTITY THE TO OR GREATER THAN PLANNING COMMITTEE THAT A RELEASE EQUAL TO THE LOCAL EMERGENCY RELEASE OF BE IMMEDIATELY REPORTED (40 CFR 355.90). IF THE SUBSTANCE RESPONSE COMMISSION THE NATIONAL RESPONSE AND THE STATE EMERGENCY SECTION 103. IN THE REPORTABLE UNDER CERCLA OR C202) 26-2675 THIS SUBSTANCE IS AT C00) t24--8802 BE NOTIFIED IMMEDIATELY 302.63. CENTER MUST D.C. AREA ("0 CFR METROPOLITAN WASHINGTON. PROTECTIVE EQUIPMENT LIMITS. PUBLISHED EXPOSURE VENTILATION. VENTILATION TO MEET GENERAL DILUTION PROVIDE MUST BE EXPLOSION-PROOF. VENTILATION EQUIPMENT ARE RECOMMENDATIONS RESPIRATOR, AND MAXIMUM USE CONCENTRATIONS GUIDE TO RESPIRATORS SERVICES, NIOSH POCKET THE FOLLOWING OF HEALTH AND HUMAN OF LABOR. THE U.S. DEPARTMENT OR DEPARTMENT BY NIOSH CRITERIA DOCUMENTS, HAZARDS OR FOUND CHEMICAL Z. LEVELS 29CFR1910 SUBPART MUST BE BASED ON CONTAMINATION OF RESPIRATOR SELECTED BY THE NATIONAL INSTITUTE THE SPECIFIC BE JOINTLY APPROVED HEALTH ADMINISTRATION. THE WORK PLACE AND MINE SAFETY AND IN AND HEALTH AND THE OCCUPATIONAL SAFETY CARTRIDGECS). WITH ORGANIC VAPOR CARTRIDGE RESPIRATOR ORGANIC VAPOR - 1000 PPM- ANY CHEMICAL RESPIRATOR WITH ANY POWERED AIR-PURIFYING CARTRIDGE(S). ANY SUPPLIED-AIR RESPIRATOR. BREATHING APPARATUS. ANY SELF-CONTAINED MODE. IN A CONTINUOUS FLOW RESPIRATOR OPERATED 62S PPM- ANY SUPPLIED-AIR WITH A RESPIRATOR (GAS MASK) FULL FACEPIECE VAPOR CANISTER. 12.500 PPM- ANY AIR-PURIFYING OR BACK-MOUNTED ORGANIC CHIN-STYLE OR FRONT- A FULL FACEPIECE. RESPIRATOR WITH FACEPIECE. ANY SUPPLIED-AIR APPARATUS WITH A FULL SELF-CONTAINED BREATHING ANY AND OPERATED WITH A FULL FACEPIECE SUPPLIED-AIR RESPIRATOR PRESSURE MODE. 20,000 PPM- ANY OR OTHER POSITIVE IN A PRESSURE-DEMAND CGAS MASK) WITH A FULL FACEPIECE RESPIRATOR CANISTER. ANY AIR-PURIFYING ORGANIC VAPOR ESCAPE- OR FRONT- OR BACK-MOUNTED APPARATUS. CHIN-STYLE SELF-CONTAINED BREATHING ANY APPROPRIATE ESCAPE-TYPE I tZACETONE*E PACE 05 OF OS TO LIFE OR HEALTH CONDITIONS FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS IN PRESSURE USELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED DEMAND OR OTHER POSITIVE PRESSURE MODE. IN PRESSURE-DEMAND RESPIRATOR WITH FULL FACEPIECE AND OPERATED SUPPLIED-AIR WITH AN AUXILIARY POSITIVE PRESSURE MODE IN COMBINATION OR OTHER IN PRESSURE-DEMAND OR OTHER SELF-CONTAINED BREATHING APPARATUS OPERATED POSITIVE PRESSURE MODE. CLOTHING, CLOTHING AND EQUIPMENT MUST WEAR APPROPRIATE PROTECTIVE CIMPERVIOUS) EMPLOYEE WITH THIS SUBSTANCE. TO PREVENT REPEATED OR PROLONGED SKIN CONTACT GLOVES, -GLOVES TO PREVENT CONTACT WITH THIS EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE SUBSTANCE. EE PROTECTION. SAFETY GOGGLES TO PREVENT EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT LENSES SHOULD NOT BE WORN. EYE CONTACT WITH THIS SUBSTANCE. CONTACT AUTHORIZED - FISHER SCIENTIFIC GROUP, INC. DATE. 04/03/89 CREATION DATE, 09/0/84 REVISION -ADDITIONAL INFORMATION- TO BE ACCURATE AND REPRESENTS THE BEST THE INFORMATION BELOW IS BELIEVED OF AVAILABLE TO US. HOWEVER. WE MAKE NO WARRANTY INFORMATION CURRENTLY WITH RESPECT TO OR ANY OTHER WARRANTY. EXPRESS OR IMPLIED, MERCHANTABILITY RESULTING FROM ITS USE. USERS SUCH INFORMATION. AND WE ASSUME NO LIABILITY DETERMINE THE SUITABILITY OF THE SHOULD MAKE THEIR OWN INVESTIGATIONS TO INFORMATION FOR THEIR PARTICULAR PURPOSES. I1 I I I' I I MATERIAL SAFETY DATA SHEET I Trade Name: EnSys RDX Test of chemical test kit for the determination Description: An (RDX) in soil hexahydro-1,3,5-trinitro-1,3,5-triazine samples CAS Number Hazardous Ixigredients control 1. RDX 67-64-1 * Acetone 64-19-7 2. 77% Acetic Acid 7440-66-6 3. Zinc Dust Not Listed 4. HACH NitriVer 3 Nitrite Reagent Data Sheet for this particular *See attached Material Safety hazardous chemical. to be accurate presented in this MSDS is believed The information available to us. the best information currently and represents or any other we make no warranty of merchantability However, such information, and expressed or implied with respect to warranty, use. Users should make no liability resulting from its we assume the suitability of the their- own investigations to determine purposes. information for their particular Gerald Alvey, Manufacturing Director EnSys Incorporated 4/14/95 Part# 99987 Rev.1 Pg 1 of 14 Trade Name: EnSys RDX Test MATERIAL: RDX Control DESCRIPTION: 2ml amber glass flame sealed ampule containing iml liquid reagent HAZARDOUS INGREDIENTS Reagent weight % Nature of Hazard Acetone > 99.9 flamable, eye, skin,mucous membrane/respiratory tract irritant, respiratory depressent PHYSICAL DATA Appearance: Clear colorless solution Melting or freezing point: < -94* c Boiling point: > 56.5 0 c Solubility in water: Dilutable ------ FIRE AND EXPLOSION HAZARD DATA Flashpoint: 10 F Lower explosion level: 2% upper explosion level: 13% 3 Extinguishing media: Carbon dioxide, dry chemical powder or foam. Special fire-fighting procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire. and explosion hazards: Extremely flammable. Vapor may travel considerable distance to source of ignition and flashback. Part# 99987 Rev.1 Pg 2 of 14 4/14/95 Trade Name: EnSys RDX Test MATERIAL: RDX Control (continued) HEALTH HAZARD DATA Effects of Overexposure: Inhalation:. Adverse health effects from vapors and spray mists in poorly ventilated areas- may include irritation of the mucous membranes of- the nose,throat, respirator( - tract and symptoms of headache and nausea. May cause dermititis. Skin Contact: Prolonged and repeated contact with product may cause skin irritation. Eve Contact: Direct contact with product may result in eye irritation. Target organs: Brain and coverings, sense organs, lungs (respiritory depression), kidney and bladder (renal function), muscles (weakness, contraction, or spasticity) Emergency and First-Aid Procedures: Inhalation: Remove subject to fresh air. Seek medical attention if necessary. Ingestion : Wash out mouth with water and call a physician. Eye and Skin Contact: Flush eyes or skin with copious amounts of water. Wash contaminated clothing before reuse. Consult a physician if irritation persists. ------ REACTIVITY DATA: Stability: Stable conditions to avoid: N/A Hazardous decomposition products : Toxic fumes of carbon monoxide or carbon dioxide upon combustion Partf 99987 Rev.1 Pg 3 of 14 4/14/95 Trade Name: EnSys RDX Test MATERIAL: RDX Control (continued) Hazardous polymerization : Will not occur Incompatible materials to avoid: Oxidizing agents, reducing agents, bases, protect from moisture. LEAK/SPILL DISPOSAL INFORMATION: Steps to be taken in case of spill: Contain spill and then clean-up with copious amounts of water. Avoid contact with skin and clothing. Shut off all sources of ignition. Waste disposal methods: Dispose of in a manner consistent with all Federal, State, and local laws concerning disposal of waste material. SPECIAL PROTECTION INFORMATION: Avoid prolonged or repeated exposure, wash tbroughly after handling, do not breath vapor, do not get in eyes (severe eye irritant), on skin or clothing, keep away fron heat, sparks, and open flame. STORAGE: 0 Storage temperature: Store at 23 C (room temperature) This product is a mixture that may contain one or more hazardous chemicals. The hazardous ingredients listed are" 6nlf those as- required by 29 CFR 1910.1200. Part# 99987 Rev.1 Pg 4 of 14 4/14/95 5 of 14 4/14/95 P/N 99987 Rev. 1 Pg IMRCETIC ACID. GLACIALEX ZACETIC- ACID. GLACIALIX SEACETIC ACID. GLACIALEg SHEET MATERIAL SAFETY DATA CONTACTS, EMERGENCY (o) 796-7100 SCIENTIFIC GASTON L. PILLORI. FISHER HOURSg HOLIDAYS- CHEMICAL DIVISION AFTER BUSINESS REAGENT LANE (201) 796-75tX (800) *ZV-9300 IR LAWN NJ 071G CHEMTREC ASSISTANCE, 01) 796-7100 THE BEST TO BE ACCURATE AND REPRESENTS BELOW IS BELIEVED WE MAKE NO WARRANTY OF THE INFORMATION AVAILABLE TO US. HOWEVER. RESPECT TO CURRENTLY EXPRESS OR IMPLIED, WITH INFORMATION ANY OTHER WARRANTY,. FROM ITS USE. USERS ERCHANTABZLITY OR LIABILITY RESULTING THE I AND WE ASSUME NO THE SUITABILITY OF UCH INFORMATION, INVESTIGATIONS TO DETERMINE MOULD MAKE THEIR OWN PURPOSES. NFORMATXON FOR THEIR PARTICULAR SUBSTANCE IDENTIFICATION CAS-NUMBER 6'v-19-7 SUBSTANCE, ZEACETIC ACID, CLACIALIK ACIDS ETHYLIC ACIDS TRADE NAMES/SYNONYMS, ETHANOIC ACIDS VINEGAR ACETIC ACIDS. UN 27859 ACETIC ACID GLACVlL ACIDS STCC 931303, AOIO METHANECARBOXYLIC A-'fS, CZH'tO2; ACCOOI20 PYROLIGNEUS A-3B-SI A-35-Sj A-SO7T A-3T1 A-381 A-38C, A-Z8-Pg CHEMICAL FAMILY, ALIPHATIC ACID, C-H3-C-O2-H CARBOXYLIC FORMULA. I MOLECULAR WEIGHT, GO.Ss MOLECULAR PERSISTENCE:0 HEALTH:2 FIRE:2 REACTIVITY:1. RATINGS CSCALE 0-3), ICERCLA - HEALTH:2 FIRE=2 REACTIVITY=1 NFPA RATINGS (SCALE 0-t), - - COMPONENTS AND CONTAMINANTS PERCENT, 100 I'COMPONENT, ACETIC ACID. GLACIAL NONE OTHER CONTAMINANTS: EXPOSURE LIMITS ACETIC ACID. GLACIAL CPS MG/M3). OSHA TQA ACGIH STEL 10 PPM TWA 15 PPM (37 MG/M3) 10 PPM C25 MG/M3) ACGIH 103 REPORTABLE QUANTITY 5000 POUNDS CERCLA SECTION PHYSICAL DATA PUNGENT. CHARACTERISTIC LIQUID WITH A STRONG. OESCRIPTION, CLEAR, COLORLESS AN ACID TASTE. WELL DILUTED WITH WATER, ODOR OF VINEGAR AND WHEN F (17 C) 0) MELTING POINT 62 BOILING POINTS 2-- F (2.11. 20 C VAPOR PRESSURE, 11.5 MMHG a SPECIFIC GRAVITY, 1.049 0.97 PH 2. C1.0 M.SOL.) EVAPORATION RATE, .CBUTYL ACETATE:) 1.0 PPM SOLUBLE ODOR THRESHOLD, SOLUBILITY IN WATER. VERY VAPOR DENSITY 2.07 ETHER, ACETONE, BENZENE, SOLUBLE IN ETHANOL, GLYCEROL, DIMETHYL SOLVENT SOLUBILITY, CARBON DISULFIDE. CHLOROFORM. CARBON TETRACHLORIDES INSOLUBLE.IN SULFOXIDE - 1.22 CPS a 20 C VISCOSITY, ------. DATA------.------EXPLOSION ------AND FIRE - -FIREEXPOSED TO HEAT OR FLAME. MODERATE FIRE HAZARDHAARD WHEN AND EPLOSION POINT. EXPLOSIVE ABOVE FLASH VAPOR-AIR MIXTURES ARE DISTANCE TO A SOURCE MAY TRAVEL A CONSIDERABLE ARE HEAVIER THAN AIR AND VAPORS BACK. OF IGNITION AND FLASH LIMIT. 19.9% 0 200 F C) CCC) UPPER EXPLOSIVE FLASH POINT, 103 F C39 I Ia 4/14/95 P/N 99987 Rev. 1 Pg 6 of 14 a6 F (64 C) G. AUTOIGNITION TEMP.i LOWER EXPLOSIVE LIMITT. 3 II FLAMMABILITY CLASSCOSHA), MEDIA, STANDARD FOAM FIREFIGHTING HALON, WATER SPRAY OR CARBON DIOXIDE, 3. DRY CHEMICAL, GUIDEBOOK, DOT P 5500. (1587 EMERGENCY RESPONSE FOAM WATER SPRAY, FOG OR STANDARD FOR LARGER. FIRES, USE GUIDEBOOK, DOT P 5500.'t). (197 EMERGENCY RESPONSE CONTAINER. FIREFIGHTING, DO NOT GET WATER INSIDE FIRE AREA IF POSSIBLE. AFTER FIRE IS MOVE CONTAINER FROM FROM SIDE UNTIL WELL CONTAINERS WITH WATER IN CASE OF RISING COOL FIRE-EXPOSED ENDS. WITHDRAW IMMEDIATELY DUE TO AWAY FROM STORAGE TANK OF STORAGE TANK OUT. STAY DEVICE OR ANY DISCOLORATION 2S). FROM VENTING SAFETY P 5500.4, 'GUIDE PAGE SOUND RESPONSE GUIDEBOOK, DOT FIRE C19T7 EMERGENCY INEFFECTIVE. SOLID STREAMS MAY BE OF WATER AS A FOGS A DISTANCE AS USE FLOODING AMOUNTS OF WATER FROM AS FAR WITH FLOODING AMOUNTS BREATHING COOL CONTAINERS. CORROSIVE VAPORS. AVOID USE WATER SPRAY TO ABSORB POSSIBLE. UPWIND. CORROSIVE VAPORS, KEEP MATERIAL, EIGHTH PROTECTION GUIDE ON HAZARDOUS ALCOHOL FOAM CNFPA FIRE EDITION). OR CARBON CHEMICAL. ALCOHOL FOAM, USE WATER SPRAY. DRY LEAK OR SPILL FIRE FIGHTING PHASES, CONTAINERS COOL. IF A WATER'TO KEEP FIRE-EXPOSED AND TO PROTECT THE MEN DIOXIDE. USE TO DISPERSE THE VAPORS USE WATER SPRAY TO FLUSH SPILLS AWAY FROM HAS NOT IGNITED. WATER SPRAY MAY BE USED TO STOP A LEAK. MIXTURES CNFPA *9, HAZARDOUS ATTEMPTING SPILLS TO NONFLAMMABLE. EXPOSURES AND TO DILUTE CHEMICALS DATA. ieTS). TRANSPORTATION DATA *3CFR17Z.101, HAZARD CLASSIFICATION DEPARTMENT OF TRANSPORTATION CORROSIVE MATERIAL Et t-9CFR172.101 AND SUBPART LABELING REQUIREMENTS DEPARTMENT OF TRANSPORTATION CORROSIVE PACKAGING REQUIREMENTS, 9-9CFRL73.2%5. . DEPARTMENT OF TRANSPORTATION EXCEPTIONS ICFRIT3. P." TOXICITY .ACETIC ACID. GLACIALI MILD 525 MG OPEN SKIN-RABBIT MG/24 HOURS SKIN-HUMAN SEVERE, IRRITATION DATA, 50. MILDj 50 UG OPEN EYE-RABBIT 50 MG/2t HOURS SKIN-RABBIT RINSED EYE-$ABBIT MILD. SEVERE; MODERATE, 5 MG/30 SECONDS HOURS 20 MG/24 HOURS SKIN-RABBIT TOLO 16,000 PPMt DATA :SI1 PPM/3 MINUTES INHALATION-HUMAN LC50, 1050 MG/KG TOXICITY 5620 PPM/i HOUR INHALATION-MOUSE LOSO INHALATION-RAT LCLO TDLOI 3530 MG/KG ORAL-RAT LD50 1t7O UG/KG ORAL-HUMAN LDSO 308 MG/KG SKIN-RABBIT 1 LDLO; 525 MG/KG INTRAVENOUS-MOUSE 1200 MG/KG ORAL-RABBIT LOLO 1.200 MG/KG LDLOS £200 MG/KG SUBCUTANEOUS-MOUSE EFFECTS DATA UNREPORTED-MAN DATA CRTECS), REPRODUCTIVE RECTAL-RABBIT LDLO MUTAGENIC CRTECS). STATUS, NONE. CARCINOGEN SKIN. MUCOUS MEMBRANES. EFFECTS- CORROSIVE- EYE, DERMAL ABSORPTION, LOCAL MODERATELY TOXIC BY INHALATION. ACUTE TOXICITY LEVEL, KIDNEYS, AND CARDIOVRSCULAR INGESTION. MAY AFFECT THE LIVER, TARGET EFFECTS, POISONING SYSTEM. SKIN OR EYE DISEASE. WITH A HISTORY OF RESPIRATORY, AT INCREASED RISK, PERSONS AID HEALTH EFFECTS AND FIRST INHALATION, ACETIC ACID. GLACIAL, TO LIFE OR HEALTH. PPM IMMEDIATELY DANGEROUS TRACT. 50 PPM CORROSIVE. 1000 IRRITATION OF THE RESPIRATORY EXPOSURE- MAY CAUSE SEVERE IN PHARYNGEAL EDEMA ACUTE TO MOST PERSONS AND RESULTS OR MORE IS INTOLERABLE MAY INCLUDE COUGHING. DYSPNEA, BRONCHITIS. OTHER SYMPTOMS AND AND CHRONIC PULMONARY EDEMA. BRONCHOPNEUMONIA SHORTNESS' OF BREATH. LARYNGITIS. uP -TO HYPOTENSION.I EXPOSED TO CONCENTRATIONS EXPOSURE- WORKERS REPEATEDLY WITH HYPERTROPHY OF CHROC TO SUFFER FROM PALPEBRAL.EDEMA IN COME PPM HAVE BEEN FOUND CHRONIC BRONCHITIS AND NODES. CHRONIC PHARYNGITIS. THE TEETH. COMPLAINTS THE LYMPH AND TRACES OF EROSION OF ASTHMATIC BRONCHITIS HAVE ALSO BEEN - CASES. WITH PYROSIS AND CONSTIPATION OF DIGESTIVE DISORDERS REPORTED. IF BREATHING AREA TO FRESH AIR IMMEUrATELY. AID- REMOVE FROM EXPOSURE AIRWAY AND BLOOD FIRST RESPIRATION. MAINTAIN AND HAS STOPPED. GIVE ARTIFICIAL AFFECTED PERSON WARM OXYGEN IF AVAILABLE. KEEP OF OXYGEN PRESSURE AND- ADMINISTER ADMINISTRATION -SYMPTOMATICALLY AND SUrPORTIVELY. ATTENTION AT REST. TREAT PERSONNEL. GET MEDICAL SHOULD BE PERFORMED BY QUALIFIED I1 t P/N 99987 Rev. 1 Pg 7 of 14 . 4/14/95 I MMEDIATELY. SKIN CONTACT, UETIC ACID. GLACIAL, PAIN. RROSIVE. CAUSE SEVERE IRRITATION WITH DIREOT CONTACT MAY OF THE SKIN WITH ACUTE EXPOSURE- AND SUPERFICIAL DESTRUCTION ERYTHEMA. BLISTERS. BURNS AND FISSURED. BECOME BLACKENED, HYrERKERATOTIC SLOW HEALING. THE SKIN MAY CAUSE DARKENING OF THE AND PROLONGED CONTACT MAY CHRONIC EXPOSURE- REPEATED .SKIN. IRRITATION AND DERMATITIS. WASH AFFgCTED CLOTHING AND SHOES IMMEDIATELY. RST AID- REMOVE CONTAMINATED AMOUNTS OF WATER UNTIL NO MILD DETERGENT AND LARGE AREA WITH SOAP OR 1S-EO MINUTES). IN CASE OF CHEMICAL OF CHEMICAL REMAINS CAT LEAST BUT NOT EVIDENCE DRY DRESSING. BANDAGE SECURELY, BURNS. COVER AREA WITH STERILE, L GET MEDICAL ATTENTION IMMEDIATELY. TOO TIGHTLY. E CONTACT, ACETIC ACID, GLACIAL- CORROSIVE. SEVERE IRRITATION, LACRIMATION. DIRECT CONTACT CAUSES SIGHT IN ACUTE EXPOSURE- IRITIS AND POSSIBLY LOSS OF CORNEAL EROSION. OPACIFICATION. MONTHS, BUT CORNEAL THE EPITHELIUM MAY TAKE MANY HUMANS. REGENERATION OF IN LESS SEVERE CASES,. OPACITY WILL USUALLY BE PERMANENT. ANESTHESIA AND OF THE CONJUNCTIVA OCCURRED. THE PHOTOPHOBIA AND'HYPEREMIA AND SOMETIMES CONJUNCTIVITIS, CAUSE CONJUNCTIVAL HYPEREMIA VAPOR AND DILUTE SOLUTIONS MAY TO THE CORNEAL EPITHELIUM. OF EXPOSURE. IINJURY ON THE CONCENTRATION AND DURATION DEPENDING CHRONIC EXPOSURE- MAY OCCUR. EFFECTS SIMILAR TO ACUTE EXPOSURE AMOUNTS OF WATER. OCCASIONALLY EYES IMMEDIATELY'WITH LARGE CAT FIRST AID- WASH NO EVIDENCE OF CHEMICAL REMAINS UPPER AND LOWER LIDS. UNTIL UNTIL THE PH LIFTING IRRIGATING WITH NORMAL SALINE 15-20 INUTES). CONTINUE BANDAGES. GET LEAST MINUTES). COVER WITH STERILE HAS RETURNED TO NORMAL C3G-60 MEDICAL ATTENTION IMMEDIATELY. INGESTION, CETIC ACID, GLACIAL, ORROSIVE. SEVERE ULCERONECROTIC IN CASES OF ACCIDENTAL INGESTION, AND ACUTE EXPOXURE- TRACT. STRICTURE OF THE ESOPHAGUS, LESIONS OF THE UPPER DIGESTIVE OBSERVED WITH ESOPHAGUS AND PYLORUS HAVE BEEN PERFORATION OF THE FOLLOWED BY ANURIA AND DIARRHEA. SHOCK. HEMOGLOBINURIA HEMATEMESIS,- ABDOMINAL SPASMS. THIRST. OTHER. SYMPTOMS MAY INCLUDE VOMITING. UREMIA. HYPOTHERMIA, RAPID AND WEAK PULSE, SLOW'AND DIFFICULTY IN SWALLOWING. EDEMA, PNEUMONIA, LARYNGITIS. BRONCHITIS, PULMONARY SHALLOW BREATHING. CONVULSIONS, CARDIOVASCULAR. ALBUMINURIA. HEMATURIA, TWITCHING. IN HEMOLYSIS, THE NEWBORN HAVE BEEN REPORTED SHOCK AND DEATH. EFFECTS ON . COLLAPSE. la DAYS AFTER GESTATION. RATS FROM TOO MG/KG, ADMINISTERED AVAILABLE. CHRONIC EXPOSURE- NO DATA OR EMESIS. DILUTE THE ACID IMMEDIATELY FIRST AID- DO NOT USE GASTRIC LAVAGE OF WATER OR MILK. IF VOMITING PERSISTS, BY DRINKING LARGE QUANTITIES DILUTED APPROXIMATELY REPEATEDLY. INGESTED ACID MUST BE ADMINISTER FLUIDS AIRWAY AND TREAT SHOCK. RENDER IT HARMLESS TO TISSUES. MAINTAIN I 100 FOLD TO 12TH ED. ). GET MEDICAL ATTENTION CDREISBACH, HANDBOOK OF POISONING. KEEP HEAD BELOW HIPS TO HELP PREVENT IMMEDIATELY. IF VOMITING OCCURS, ASPIRATION. ANTIDOTE, AND SUPPORTIVELY. NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY REACTIVITY CREACTIVITY, REACTS EXOTHERMICALLY WITH WATER. INCOMPATISILITIES, GLACIAL, ACETIC ACID. REACTION. ACETALOEHYOE VIOLENT, EXOTHERMIC POLYMERIZATION + WATER VIOLENT, EXOTHERMIC REACTION. ACETIC ANHYDRIDE CLOSED CONTAINER. TEMPERATURE AND PRESSURE INCREASE IN 2-AMINOETHANOLt CONCENTRATED. NITRATE. IGNITES ON WARMING, ESPECIALLY IF AMMONIUM REACTION. S-AZIDOTETRAZOLE, POSSIBLE EXPLOSIVE BASES. EXOTHERMIC REACTION. BROMINE PENTAFLUORIDE, FIRE AND EXPLOSION.HAZARD. CARBONATES, INCOMPATIBLE. VIOLENT. POSSIBLY EXPLOSIVE REACTION, CHLORINE TRIFLUORIDE, INCREASE IN CLOSED CONTAINER CHLOROSULFONIC ACID. TEMPERATURE AD PRSSURE REACTION IF NOT KEPT COLD. CHROMIC ACIDC EXPLOSIVE HAZARD. TRIOXIDEt POSSIBLE FIRE AND EXPLOSION CHROMIUM REACTION. DIALLYL METHYL. CARBINOL AND OZONE, EXPLOSIVE AND PRESSURE. INCREASE IN CLOSED CONTAINER. , ETHYLENE DIAMINE, TEMPERATURE CONTAINER. TEMPERATURE AND PRESSURE INCREASE IN CLOSED ETHYLENEIMINE: WITH THE PRODUCTION OF PEROXIDE, EXOTHERMIC REACTION ON HEATING HYDROGEN AT 110 C. PERACETIC ACID WHICH WILL EXPLODE HYDROXIDES,- INCOMPATIBLE. -m LEAD: CORRODES. 'Ia - P/N 99987 Rev. 1 Pg 8 of 14 4/14/95 METALS, ATTACKS MOST METALS, INCLUDING ZINC. EXPLOSIVE REACTION IF NOT KEPT COLD. NITRIC ACID, CDELAYED) IN CLOSED CONTAINER. ACID AND ACETONE. EXPLOSIVE REACTION NITRIC IN CLOSED CONTAINER. OLEUM. TEMPERATURE AND PRtSSURE INCREASE OXIDIZERS, VIOLEN4T REACTION. ACID. EXPLOSIVE REACTION. PERCHLORIO COLD. rERMANGANATES, EXPLOSIVE REACTION IF NOT KEPT PHOSPHATES, .INCOMPATIBLE. PHOSPHORUS ISOCYANATE VIOLENT REACTION. PHOSPHORUS TROCHLORIDE, EXPLOSIVE REACTION. HYDROXIDE, VIOLENT REACTION. POTASSIUM IF INADEQUATELY COOLED. POTASSIUM PERMANGANATE, POSSIBLE EXPLOSION TERT-BUTOXIDEt IGNITION REACTION. POTASSIUM INCREASE IN CLOSED CONTAINER. SODIUM HYDROXIDE. TEMPERATURE AND PRESSURE EXPLOSIVE REACTION IF NOT KEPT COLD. SODIUM PEROXIDE, TERPHTHALIC ACID PRODUCTION, THE MAY FORM DETONABLE MIXTURES DURING XYLENE, HAZARD. PRESENCE OF WATER MAY DECREASE THE DECOMPOSITION, INCLUDE TOXIC OXIDES OF CARBON. THERMAL DECOMPOSITION PRODUCTS MAY POLYMERIZATION, BEEN REPORTED TO OCCUR UNDER NORMAL HAZARDOUS POLYMERIZATION HAS NOT TEMPERATURES AND PRESSURES. STORAGE AND DISPOSAL WHEN STORING OR DISPOSING ALL FEDERAL, STATE AND LOCAL REGULATIONS OBSERVE CONTACT THE DISTRICT DIRECTOR OF THE OF THIS SUBSTANCE. FOR ASSISTANCE, ENVIRONMENTAL PROTECTION AGENCY. EKSTORAGEXE IS PREFERRED. SEPARATE FROM PHYSICAL DAMAGE. DETACHED STORAGE PROTECT AGAINST MATERIALS. KEEP ABOVE MATERIALS AND AVOID STORAGE NEAR COMBUSTIBLE OXIDIZING OF CARBOYS AND GLASS CONTAINERS ITS FREEZING POINT C6Z F) TO AVOID RUPTURE CNFPA +5. HAZARDOUS CHEMICALS DATA, 1STS). WHICH AND GROUNDING SUBSTANCES WITH LOW ELECTROCONDUCTIVITY, BONDING BE STORED IN CONTAINERS BE IGNITED'BY ELECTROSTATIC SPARKS, SHOULD MAY GUIDELINES SPECIFIED IN NFPA 77-1-83, . WHICH *MEET THE BONDING AND GROUNDING RECOMMENDED PRACTICE ON STATIC ELECTRICITY. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. XXDISPOSALZZ TO GENERATORS OF MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE DISPOSAL WASTE- NUMBER DOOZ. HAZARDOUS WASTE, -O CFR 262. EPA HAZARDOUS QUANTITY. 100 POUND CERCLA SECTION 103 REPORTABLE CONDITIONS TO AVOID VAPORS MAY SPARKS. FLAMES OR OTHER IGNITION SOURCES. AVOID CONTACT WITH HEAT. OR EYES. DO NOT MATERIAL IS CORROSIVE, AVOID CONTACT WITH SKIN BE EXPLOSIVE. . 'ALLOW CONTAMINATION OF WATER SOURCES. SHIPPING CONTAINERS, USUAL POLYETHYLENE-LINED DRUMS, TANK BARGES -.. GLASS AND POLYETHYLENE CARBOYS AND CNFPA T. HAZARDOUS CHEMICALS DATA, 1975). SPILL AND LEAK PROCEDURES SOIL SPILL, TO CONTAIN SPILL AND DIKE A HOLDING AREA SUCH AS A FIT. POND 9R LAGOON DIG FOAMED POLYURETHANE OR FOAMED SURFACE FLOW USING' BARRIER OF SOIL. SANDBAGS, OR CEMENT POWDER. CONCRETE. ABSORB LIQUID MASS WITH FLY ASH SODA ASH CNAZCO3) NEUTRALIZE WITH CAUSTIC SODA CNAOH) OR SPILL. AIR UPWIND. KNOCK DOWN VAPORS WITH WATER SPRAY. KEEP CORROSIVE OR TOXIC AND SHOULD BE WATER USED TO KNOCK DOWN VAPORS MAY BECOME. CONTAINED PROPERLY FOR LATER DISPOSAL. WATER SPILL, NEUTRALIZE WITH CAUSTIC SODA. SPILL. OCCUPA.TIONAL STOP LEAK IF YOU OFF IGNITION SOURCES. DO NOT TOUCH SPILLED MATERIAL. SHUT VAPORS. DO NOT GET WATER 00 WITHOUT RISK. USE WATER SPRAY TO REDUCE CAN IT OR OTHER ABSORBENT CONTAINER. FOR SMALL SPILLS. TAKE UP WITH SAND INSIDE DISPOSAL. FOR LARGER SPILLS. MATERIAL AND PLACE INTO CONTAINERS FOR LATER I It - P/N 99987 Rev. 1 Pg 9 of 14 4/14/95: DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. NO SMOKING. FLAMES OR FLARES IN HAZARD AREA. KEEP UNNECESSARY PEOPLE AWAY, ISOLATE HAZARD AREA AND DENY ENTRY. PORTABLE QUANTITY CR), 5000 POUNDS E SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT CSARA) SECTION 30t REQUIRES AT A RELEASE EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING COMMITTEE AND THE STATE EMERGENCY RESPONSE COMMISSION CTO CFR 35S.0). IF THE RELEASE OF SIS SUBSTANCE IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL RESPONSE NTER MUST BE NOTIFIED IMMEDIATELY AT (aU) t2t-8aao OR .C202) NtZG-2S75 IN THE TROPOLITAN WASHINGTON. D.C. AREA CI-O CFR 302.63. PROTECTIVE EQUIPMENT NTILATION:, OVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET PUBLISHED EXPOSURE LIMITS. RESPIRATOR E FOLLOWING RESPIRATORS AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, NIOSH.POCKET GUIDE TO CHEMICAL HAZAROS, NIOSH CRITERIA DOCUMENTS OR BY THE U.S. DEPARTMENT OF LABOR, 29CFR1910 SUBPART Z. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUNrP' IN THE WORK. PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION CNIOSH-MSHA). ACETIC ACID, GLACIAL. 250 PPM- SUPPLIED-AIR RESPIRATOR OPERATED IN CONTINUOUS FLOW MODE. POWERED AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGECS). SOO PPM- CHEMICAL CARTRIDGE RESPIRATOR WITH.FULL FACEPIECE AND ORGANIC VAPOR CARTRIDGECS). SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE. AIR-PURIFYING FULL FACEPIECE RESPIRATOR CGAS MASK) WITH CHIN-STYLE OR FRONT- OR BACK-MOUNTED ORGANIC VAPOR CANISTER. POWERED AIR-PURIFYING RESPIRATOR WITH .TIGHT-FITTING FACEPIECE AND ORGANIC VAPOR CARTRIDGECS). 1000 PPM- SUPPLiED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ESCAPE- AIR-PURIFYING FULL FACEPIECE RESPIRATOR CGAS MASK) WITH CHIN-STYLE OR FRONT- OR BACK-MOUNTED -ORGANIC VAPOR CANISTER. ESCAPE-TYPE SELF-CONTAINED BREATHING APPARATUS. t R FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS, SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE- OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS: OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. CLOTHING, MPLOYEE MUST WEAR APPROPRIATE PROTECTIVE CIMPERVIOUS) CLOTHING AND EQUIPMENT I0 PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE. GLOVES, EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS UBSTANCE.I YE PROTECTION, EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. MERGENCY WASH FACILITIES, HERE THERE IS ANY POSSIBILITY THAT AN EM'PLOYEE'S EYES AND/OR SKIN MAY BE XPOSED TO'THIS SUBSTANCE. THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN AND QUICK-DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. AUTHORIZED - FISHER SCIENTIFIC GROUP. INC. CREATION DATE: 09/06/8R REVISION DATE, Q9/2S/89 -ADDITIONAL INFORMATION- HE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST NFORMATION CURRENTLY AVAILABLE TO US. HOWEVER. WE MAKE NO WARRANTY OF ERCHANTABILITY OR ANY OTHER WARRANTY. EXPRESS OR IMPLIED, WITH RESPECT TO UCH INFORMATION; AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. I l' P/N 99987 Rev. 1 4I Pg 10 of 14 4/14 /9 5 XXZINC POWDER OR DUST, NONPYROPHORICtx zxZINC POWDER OR DUST. NONPYROPHORICX. fXZXNC POWDER OR DUST, NONPYROPHORICxx xXZINC POWDER OR DUST, NONPYROPHORICZx I MATERIAL SAFETY DATA SHEET ------ EMERGENCY CONTACTS FISHER SCIENTIFIC 7 CHEMICAL DIVISION GASTON L. PILLORI: (201) 9G-7I00 I REAGENT LANE AFTER BUSINESS HOURS HOLIDAYSi I FAIR LAWN NJ 07-10 (201) 756-7523 (201) 796-7100 CHEMTREC ASSISTANCE. (800) +29-9300 THE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER. WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED. WITH RESPECT TO I SUCH INFORMATION. AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. SUBSTANCE IDENTIFICATION I CAS-NUMBER 79-90-66-6 SUBSTANCE, XXZINC POWDER OR DUST, NONPYROPHORICXx TRADE NAMES/SYNONYMS, 'I ZINC DUST; ZINC POWDER 2 BLUE POWDERj GRANULAR ZINC, C.I. 779-S, C.I. PIGMENT BLACK 16, C.I. PIGMENT METAL 6 UN 19-36w -2 Z-t: Z-Sj Z-111 Z-12, Z-1S, Z-1G, Z--6, Z-SG CHEMICAL FAMILY, METAL I MOLECULAR FORMULA: ZN MOLECULAR WEIGHT, GS.38 CERCLA RATINGS CSCALE -0-3): HEALTH=U FIRE=3 REACTIVITY:3 PERSISTENCE= I NFPA RATINGS CSCALE 0-T): HEALTH=O FIRE=l REACTIVITY=1 COMPONENTS AND CONTAMINANTS COMPONENT: ZINC PERCENT: 100 I OTHER CONTAMINANTS: NONE EXPOSURE LIMITS: NUISANCE PARTICULATES (NUISANCE DUST). 5 MG/M3 OSHA TWA (RESPIRABLE DUST); IS MG/M3 OSHA TWA (TOTAL DUST) I 10 MG/M3. ACGIH TWA (TOTAL DUST) CNO ASBESTOS AND < 1%. CRYSTALLINE SILICA) PHYSICAL DATA. DESCRIPTION: BLUISH-GRAY POWDER BOILING POINT 1669 F (07 C) I MELTING POINT. 787 F Ct20 C) SPECIFIC GRAVITY: 7.1 VAPOR PRESSURE: 1 MMHG . T-n7 C SOLUBILITY IN WATER: REACTS SOLVENT SOLUBILITY: SOLUBLE IN ACIDS. ALKALIS. ACETIC ACID I FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: I DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. DANGEROUS WHEN WETI MAY HEAT SPONTANEOUSLY AND IGNITE ON EXPOSURE TO AIR. DUST-AIR MIXTURES ARE EXPLOSIVE. EXPLOSION HAZARD WITH ACIDS, OXIDIZERS OR OTHER INCOMPATIBILITIES. EASILY IGNITED BY NAKED LIGHT, YITH POSSIBLE EXPLOSION. FLASH POINT, FLAMMABLE SOLID UPPER EXPLOSIVE LIMIT, NOT AVAILABLE I LOWER EXPLOSIVE LIMIT, SOD GM/M3Y AUTOIGNITION TEMP... 860 F (-GO C) FIREFIGHTING MEDIA: USE DRY CHEMICAL. SODA ASH. LIME OR SAND. DO NOT USE WATER OR FOAM. CS8 EMERGENCY RESPONSE GUIDEBOOK, DOT P sCU.). I FIREFIGHTING, DO NOT GET WATER INSIDE CONTAINER. MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. FOR MASSIVE FIRE IN STORAGE AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES: ELSE WITHDRAW FROM AREA AND LET FIRE BURN (1587 EMERGENCY RESPONSE GUIDEBOOK. DOT P Sa00.9. GUIDE PAGE 76). - I EXTINGUISH USING AGENT FOR TYPE OF FIRE. AVOID BREATHING FUMES FROM BURNING MATERIAL. I TRANSPORTATION DATA- DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION TSCFRITZ. 1019 FLAMMABLE SOLID DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS TSCFR172. 101 AND 172. "02 I FLAMMABLE SOLID no nnarmcnnc'JJC -'- P/N 99987 Rev. 1 Pg 11 of 14 4/14/95 EZINC POWDER OR OUST. NONIYROPHORICxx '9CFRIT3.15 EXCEPTIONS- TUCFR173.153 PACKAGING REQUIREMENTS, OF TRANSPORTATION ,DEPARTMENT TOXICITY SKIN-HUMAN MILD IRRITATION; 300 UG/3 DAYS-INTERMITTENT IZINC.TOXICITY12 MG/M3/SO DATA. MINUTES INHALATION-HUMAN TCLOI CARCINOGEN STATUS, NONE. LOCAL EFFECTS. IRRITANT- MUCOUS MEMBRANES. SKIN. ACUTE TOXICITY LEVEL, INSUFFICIENT DATA. TARGET EFFECTS POISONING MAY AFFECT THE BLOOD. ADDTIONAL DATA ZINC IS ESSENTIAL IN THE ACTIVITY OF NUMEROUS ENZYMES, AND METABOLIC PROCESSES. EXCESSIVE ZINC INTAKE HAS BEEN ASSOCIATED WITH A COPPER-DEFICIENCY ANEMIA. APPARENTLY. ZINC INTERFERES WITH COPPER AND IRON METABOLISM. TAX;------AID - -- 3 ------HEALTHL H - EFFECTS------AND FIRST INHALATION. ZINC- ACUTE EXPOSURE- PURE ZINC POWDER OR DUST IS NOT EXPECTED TO BE IRRITATING ON ACUTE EXPOSURE. HOWEVER. WHEN HEATED. IT EVOLVES A FUME OF ZINC OXIDE WHICH WHEN INHALED FRESH CAN CAUSE A DISEASE KNOWN AS ZINC METAL FUME FEVER.. MOST AUTHORITIES AGREE-THAT FRESH FUMES ARE NECESSARY TO PRODUCE THE DISEASE BUT THAT THE PARTICLE SIZE IS THE MOST IMPORTANT FACTOR IN THE GENESIS OF THE CONDITION. MOST OF THE RESPONSIBLE PARTICLES ARE IN THE RANGE OF 0. 02-0, 25 MICRONS. SYMPTOMS MAY BE DELAYED >-12 HOURS AND MAY INCLUDE A METALLIC OR FOUL TASTE. DRY THROAT. CHEST PAIN. DYSPNEA. DRY COUGH. CHILLS. LASSITUDE. MALAISE, FATIGUE. HEADACHE. MUSCLE CRAMPS. NAUSEA. FEVER. PERSPIRATION, VOMITING AND LEUKOCYTOSIS. TOLERANCE TO FUMES DEVELOPS RAPIOLY. BUT IS QUICKLY LOST. PRELIMINARY EXPOSURE TO ACETIC ACID MAY INCREASE SUSCEPTIBILITY TO ZINC FUME FEVER. RECOVERY USUALLY OCCURS WITHIN 2- TO 4t8 HOURS. CHRONIC EXPOSURE- ZINC FACTORY WORKERS EXPOSED FOR 2-3 YEARS REPORTED UPPER RESPIRATORY TRACT IRRITATION WITH NASOPHARYNGITIS AND LARYNGITIS. GASTROINTESTINAL DISTURBANCES AND CLINICALLY LATENT LIVER DYSFUNTION HAS ALSO BEEN REPORTED TO OCCUR IN WORKERS AFTER LONG-TERM EXPOSURE. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED. GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY AND BLOOD PRESSURE'ANOIADMINISTER OXYGEN IF AVAILABLE. KEEP AFFECTED PERSON.WARM AND AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT, ZINC, ACUTE EXPOSURE- PURE ZINC POWDER OR DUST IS NOT EXPECTED TO BE IRRITATING ON SINGLE EXPOSURE. I CHRONIC EXPOSURE- MAY CAUSE -DERMATITIS AFTER REPEATED OR PROLONGED EXPOSURE. 300 UG APPLIED 'TO HUMAN SKIN INTERMITTENTLY FOR THREE DAYS CAUSED MILD IRRITATION. ALLERGIC SENSITIZATION IS EXTREMELY RARE. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT ZINC, ACUTE EXPOSURE- NO DATA AVAILABLE. HOWEVER. IT IS EXPECTED TO CAUSE -- IRRITATION TO SOME DEGREE DUE TO A FOREIGN PARTICLE EFFECT. CHRONIC EXPOSURE- NO DATA AVAILABLE. FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, REMAINS (APPROXIMATELY 15-20 MINUTES).. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION. ZINC; ACUTE EXPOSURE- THE ZINC ION IS ORDINARILY TOO POORLY ABSORBED TO CAUSE ACUTE SYSTEMIC TOXICITY. AFTER LARGE DOSES HAVE BEEN INGESTED, FATAL COLLAPSE MAY OCCUR AS A RESULT OF SERIOUS DAMAGE TO THE BUCCAL AND - GASTROENTERIC. MUCOUS MEMBRANES. ACIDIC FOODS. OR BEVERAGES PREPARED OR STORED IN GALVANIZED ZINC CANS OR UTENSILS MAY DISSOLVE SUFFICIENT ZINC METAL INTO.ZINC SALTS. INGESTION OF THESE SOLUTIONS MAY CAUSE P.OISONIMG WITH FEVER. NAUSEA, VIOLENT VOMITING, STOMACH CRAMPS. AND DIARRHEA WITHIN 3 TO 12 HOURS. SHOCK, COLLAPSE AND DEATH MAY ALSO OCCUR. SURVIVORS MAY HAVE RESIDUAL NEPHRITIS AND STRICTURES OF THE ESOPHAGUS AND PYLORIC END OF THE STOMACH. CHRONIC EXPOSURE- PATIENTS TAKING ZINC IN AMOUNTS '10 TIMES THE RDA FOR MONTHS AND-YEARS HAVE NOT SHOWN ANY ADVERSE REACTIONS. EXCESSIVE ABSORPTION MAY CAUSE COPPER-DEFICIENCY ANEMIA. APPARENTLY, ZINC INTERFERES WITH COPPER AND IRON METABOLISM. THE TASTE THRESHOLD FORZINC IN WAlTER IS APPROXIMATELY 15 PPM.- DRINKING WATER CONTAMINATED WITH 4-0 PPM ZINC HAS CAUSED DROWSINESS. MENTAL FATIGUE. NAUSEA. MUSCLE PAIN AND STIFFNESS. INSOMNIA. ANOREXIA, LASSITUDE AND FATIGUE. ANIMAL STUDIES INDICATE THAT RATS TOLERATED 0.1% ZINC IN THEIR DIET. BUT MORE THAN 0..5% REDUCED THEIR CAPACITY TO REPRODUCE. AND 1% INHIBITED GROWTH AND CAUSED SEVERE ANEMIA AND OEATH 2% METALLIC ZINC IN THE DIET OF RATS RESULTED TN *40 INJURY. FIRST AID- TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY. IF VOMITING OCCURS. KEEP HEAD LOWER THAN HIPS TO PREVENT P/N 99987 Rev. 1 Pg 12 of 14 4/14/951 KKZINC POWDER OR DUST. NQNPYROPHORICxZ ASPIRATION. ANTIDOTE NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPOATIVELY. R-EAY------ECTIVITY REACTIVITY BASIC CARBONATE ON EXPOSURE TO MOIST AIR AND MAY BE EXPLOSIVE. ZINC POWDER OR DUST EVOLVES HIGHLY FLAMMABLE HYDROGEN GAS ON CONTACT WATER, WITH THE HEAT OF THE REACTION MAY BE SUFFICIENT TO IGNITE THEHYDROCEN. ZINC I FOIL MAY IGNITE IN THE PRESENCE OF MOISTURE. INCOMPATIBILITIES, ZINC, ACIDS, EVOLVES HYDROGEN GAS WHICH MAY BE IGNITED BY THE HEAT OF THE REACTION ALKALIES, EVOLVES HYDROGEN GAS WHICH MAY BE IGNITED BY THE HEAT OF THE REACTION. ALUMINUM, POSSIBLE IGNITION. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL, MAY SPARK ON IMPACT. AMMONIUM NITRATE. VIOLENT REACTION OR FORMATION OF EXPLOSIVE MIXTURE. AMMONIUM SULFIDE: MAY EXPLODE IN A CLOSED CONTAINER. ARSENIC, INCANDESCENT REACTION WHEN HEATED. ARSENIC TRIOXIDE, EXPLOSIVE REACTION ON HEATING. BROMOMETHANE: FORMS FLAMMABLE COMPOUNDS. CADMIUM, INCANDESCENT REACTION. CALCIUM CHLORIDE. EVOLVES HYDROGEN GAS WHICH MAY-BE IGNITED BY THE HEAT OF. THE REACTION. CARBON DISULFIDE: INCANDESCENT REACTION. CARBON TETRACHLORIDE + METHANOL: EXTREMELY VIGOROUS REACTION. CHLORATES, FORMS SHOCK-SENSITIVE MIXTURES. CHLORINATED RUBBER: VIOLENT OR EXPLOSIVE REACTION AT ELEVATED TEMPERATURES. CHROMIC ANHYDRIDE, VIOLENT REACTION AND POSSIBLE-IGNITION. HALOCARBONS: POSSIBLE VIOLENT REACTION. HALOGENS: POSSIBLE IGNITION. HYDRAZINE NITRATE: IGNITES ABOVE 70 C. HYDROXYLAMINE, MAY ItNITE OR EXPLODE WHEN HEATED. INTERHALOGENS: VIOLENT REACTION AND POSSIBLE IGNITION. LEAD AZIDE, FORMS EXPLOSIVE COMPOUND. MANGANESE DICHLORIDE:. EXP'LOSIVE REACTION WHEN HEATED. METAL HALIDES CTRANSITION) + IRON PENTACARBONYL: VIOLENT REACTION. METAL OXIDES, POSSIBLE IGNITION. NITRIC ACID. INCANDESCENT REACTION. Z-NITROANISOLE + SODIUM HYDROXIDE: EXOTHERMIC REACTION. NITRYL' FLUORIDE INCANCESCENT WHEN WARMED. OXIDIZERS CSTRONG). FIRE AND EXPLOSION HAZARD. PEROXYFORMIC ACID, VIOLENT EXPLOSION ON CONTACT. POTASSIUM NITRATE, EXPLOSIVE REACTION ON HEATING. POTASSIUM PEROXIDE: INCANDESCENT REACTION. SELENIUM: INCANDESCENT REACTION. SELENINYL BROMIDE: IGNITION. SILVER + ELECTROLYTES CBATTERIES): MAY SPONTANEOUSLY COMBUST. SULFUR, VIOLENT REACTION. TELLURIUM: INCANDESCENT REACTION. DECOMPOSITION: ZINC: THERMAL DECOMPOSITION RELEASES ACRID AND TOXIC FUMES OF ZINC OXIDE. .POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. STORAGE AND DISPOSAL OBSERVE ALL FEDERAL, STATE- AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,. CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. xKSTORAGEXX STORAGE PROTECT AGAINST PHYSICAL DAMAGE. STORE IN COOL, DRY. VENTILATED PLACE. SEPARATE FROM ACIDS. HALOGENATED HYDROCARBONS. AND STRONG ALKALI HYDROXIDES. PROTECT FROM MOISTURE CNFPA tS, HAZARDOUS CHEMICALS DATA, 1975). .. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. CONDITIONS TO AVOID MAY BE IGNITED BY HEAT. SPARKS OR FLAMES. MAY BURN RAPIDLY WITH FLARE-BURNING EFFECT. MAY IGNITE IN PRESENCE OF MOISTURE. VIOLENT REACTION WITH WATER. AVOID DISPERSION OF DUST IN AIR. FINELY DIVIDED PARTICLES, DUST. OR FUMES BE MAY FLAMMABLE OR EXPLOSIVE. KEEP AWAY FROM SPARKS OR IGNITION SOURCES. SXxxxxxx K KXExxxxxxxxxxxxxxxxxxr K KXXxxxxxxtxxxxxxxxxxx xxKKK SKKKxxxxxxxxx - SPILL AND LEAK PROCEDURES OCCUPATIONAL SPILL, DO NOT TOUCH SPILLED MATERIAL. SHUT OFF IGNITION SOURCES, NO FLARES. SMOKING P/N 99987 Rev. 1 Pg 13 of 14 4/14/95 EZINC POWDER OR DUST, NONPYROPHORIC. NO WATER . ON SPILLED MATERIAL, 00 NOT GET WATER INSIDE CONTAINER. DIKE SPILL OR LATER DISPOSAL. CLEAN UP ONLY UNDER SUPERVISION OF AN EXPERT. PROTECTIVE EQUIPMENT VENTILATION, IROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET THE PUBLISHED XPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF. ESPIRATOR. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON THE CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RRESPIRATORAND BE JOINTLY APPROVED DY THE NATIONAL XNSTITUTE FOR, OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION. E FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON THE DATA FOUND IN THE PHYSICAL DATA. HEALTH EFFECTS AND TOXICITY SECTIONS. THEY ARE RANKED IN ORDER FROM MINIMUM TO MAXIMUM RESPIRATORY PROTECTION, DUST, MIST. AND FUME RESPIRATOR. POWERED AIR-PURIFYING RESPIRATOR WITH A DUST, MIST. AND FUME FILTER. TYPE 'C' SUPPLIED-AIR I RESPIRATOR WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE OR WITH A FULL FACEPIECE. HELMET OR HOOD OPERATED IN CONTINUOUS-FLOW MODE. SELF-CONTAINED BRE 3 THING APPARATUS WITH A FULL FACE PIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. - fR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS.- SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESSURE - DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED..IN PRESSURE-DEMAND OR OTHER ULOTHING.POSITIVE PRESSURE MODE. MPLOYEE MUST WEAR APPROPRIATE PROTECTIVE CIMPERVIOUS) CLOTHING AND EQUIPMENT 0 PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE. LOVES, MPLOYEE MUST WEAR APPROPRIATE PROTECTIVE CLOVES TO PREVENT CONTACT WITH US TANCE. THIS EYE PROTECTION: MPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A ACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. CONTACT LENSES E WORN. SHOULD NOT EMERGENCY WASH FACILITIES, WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND/OR SKIN MAY BE TO DXPOSEDTHIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN ND QUICK DRENCH. SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. AUTHORIZED - FISHER SCIENTIFIC GROUP, INC. CREATION DATE. 12/ot8-8 REVISION DATE: 03/29/859 -ADDITIONAL INFORMATION- WHE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY MERCHANTABILITY OF OR ANY OTHER WARRANTY. EXPRESS OR IMPLIED. WITH RESPECT TO UCH INFORMATION. AND WE ASSUME NO LIABILITY RESULTING HOULD FROM ITS USE. USERS MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE NFORMATION FOR THEIR PARTICULAR PURPOSES. ) P/N 99987 Rev. I Pg 14 of 14 4 /14/951; II HSDS OATES [lst3 For Assistance. Contact, CANGC W. . 8745 Reuletory AffetraDet. HACH COMPANY Eoroncy Tet .S.one Recky Hogntain P-sta. Ctr. 'o Oo. 907 A..e, IA S.l PO BOX 907 CSl 227-422. AMES, IA 50010 533 L23-s.it I. PRODUCT IDENTIFICATION VII. FIRST AID PRODUCT NMEe Nitrivar So Nitlite R.a.et EYE AND SKIN CONtACT. Imdiatly 'fluh yv. with eter f i5 minutes. Cal uth of wat. CAS NO. i NA CICHLCAL NAMEi Net mscliscble physIon. Flugh Skin plenty rORMULA, Not eSpeiLible CIEMICAL AMtiYt Not ..sLicable INCESTION De NOT induce oeett.". Cive I - 2 ia.es. .f witer. Can physician ImmediAtely. Mever elve Ghthins by mouth to an Vhlncon..i.u II. INGREDIENTS parmen. IMeSLATLONI Rmoovo to Irooh '1r. 01iv artificial respiration f r potassium Ph..esphat.. nbes ic Call pTySiciMn. I PCTI 1,2-Cyelet.hxanedImeinetetre.Ct.O Asid. Tcisedium SaIt (CDTA1"eS Pft, FLASH PT.: Not applicable HETHOD: NA FLAMHIABILITY LIMITS - LONER: NA UPPER: NA SUSCEPTIBILITY TO SPOONTANOUS HEATING: None SHOCK SENSITIVITY: None AUTOIGNETION PT.: NA EXTINOUtSIING HEDIA, water. carbon diolide. or dry chemical FIRE/EXPLOSION HIAZARDSi Mey emit text f.ges in fire HAZARDOUS DECOMP. PRODUCTSt May cIt toxic fumes of phosphorus oxides in fire I OXIDIZERS No Nf-PA Codest Health: 2 Flaemebility: 0 ReactivIty, CONDITIONS TO AVOIDS Heat, moisture V.. HEALTH HAZARD DATA THIS PRODUCT MAY BE: corrosive to eyes, lrrLtatine to Skin and respiratory tract. ACUTE TOXICITY: Hoderately toxic ROUTES OF EXPOSURE: Ingestion TARGET ORGANS: Not determined CHRONIC TOXIOTTY: Not determined ROUTES OF EXPOSURE, Net determined TARGET ORGANS: Not determined CANCER INFORMATIONS Not epplicable ROUTES OF EXPOSURES Not asplIcebl. TARGET ORGANS! Not applicable OVEREXPOSUREj Caus.es burns to eyes; may irritating to skin and respiretory treot . HEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pro-axist in stlncondtlons VI. PRECAUTIONARY MEASURES AveId onta. t witih e and Skin. Do net broetthe dust. Wash thoroughly after handling. PROTECTIVE EQU1PHENTr adeuate ventilation. lea gad. oeTes,dispes e latex I.evo- iS EKPRESSED OR ePLIEO SET MCH Co.11 TIE INFORMATION CONTAINED HEREIN IS BASCOON DATA CONSIDEREO TO BE ACCURATE. OGWEVER,HO WiRRANTY RECAROING THE ACCUiSACYOF THESE DATA OR THE RESULTS To BE OBTAINED FROH TIE USE THEREOF. PAGE I OF I HachEla I p,e P 22..Z. 85e ... e.. r 1. ISEL(StUal Mach Coepany, WORLD NEAQUARTERS, PO Sox 3, Lovelend. CO 451 9e MlTF :Ii.:. TY: /TA 2IIEET Pq9.Ct I Trade Name: PCB RISc Test Kit Description: An immunoassay test kit for the determination of polychlorinated biphenyls (PCBs) in soil samples, in water camples, and on surfaces. ITT Hazardous Ingredients CAS Number 1. Polychlorinated biphenyl standard * Aroclor 1248 in methanol 11097-69-1 2. Extraction and dilution reagent * Methanol 67-56-L 3. Substrate A 68-12-2 * N,N-Dimethylformamide 4. Stop Solution 7664-93 -9 * Sulfuric acid, 1 M (6% v/v) 5. ENZYME (PCD Conjugate) NA * Polychlorinated biphenyl- Horseradish peroxidase conjugate 6. PCB Antibody NA * Monoclonal antibody to Polychlorinated biphenyls *See attached Material Safety Data Sheet for this particular hazardous chemical. The information presented in this MSDS is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied with respect to such information, and we assume no liability resulting from its use. Users should make their own investigationG to determine the suitability of the information for their particular purposes. Gerald Alvey, Manufacturing Director EnSys Incorporated I U 3 P/N 9 -- -, MATERIAL 2AFETY DATA SHEET Pg. 2 Trade Name : PCB RIScM Kit KATERIAL : Polychlorinated biphenyl otandard DESCRIPTION 2ML amber tlame sealed glass ampoule containing approximately I ml of liquid reagent ...... t HAZARDOUS INGREDIESrt Reagent weight % Nature ogfHazrd Aroclor 1248 < 00.1 Carc inogen '9' Methanol > 99.9 Flamable, eye & skin irritant PHYSICAL DATA Appearance r Clear colorless liquid Melting or freezing point - 98 c Boiling point : 65 c Solubility in water 100% FIRE AND EXPLOSION HAZARD DATA Extinguishing media alcohol foam, CO , dry chemical Special fire fighting procedures Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire and explosion hazards Fire hazard when exposed to heat, flame, or oxidizers. vapors are explosive. PIN 99996, Rev C(. : ATF.2I 1. .FETY DATA SHEET Pg. 3 rrade ::ame : PC1f RI1c :i MATERIAL: Polychlorinated biphenyl standard (continued) 1IEALTU RAZARD DATA: Effects of overexposure: Inhalation/Ingestion: narmful if inhaled, may be fatal Headache, nausea, blindness, if swallowed. gastrointestinal disturbance. low concentration of ContainA. material known to cause concentration is sufficiently cancer. such would below the OSRA threshold(s) require listing as which a component of this solution. Emergency First Aid Procedures Inhalation : Remove subject to fresh air. Seek medical if necessary. attention Eve and Skin Contact : Flush eyes or skin with copious amounts of water eyes for 15 minutes) (flush . Wash contaminated clothing reuse. Consult a physician before if irritation persists. REACTIVITY DATA: Stability: Stable Conditions U to avoid: N/A Hazardous decomposition products: Toxic fumes of carbon monoxide I and carbon dioxide Hazardous polymerization: Will not occur Incompatible U materials t:o avoid: Qxidizing agents, acids, acid chlorides, anhydrides, reducing acid I agents, alkali metals U SPILL OR LEAK PROCEDURE: Steps to be taken Ln case of spill: Contain spill I arn-, cake up with absorbant -liminate igniti- material. :ources. ventilate area. I P/N 99996, Rev - I MATERtAt\ .:AFETY DATA SHEET Pg. 4 I Trade Name : PCn RIc" Kit U MATERIAL: Polychlorinated biphenyl standard (continued) I Waste disposal methods: Observe all Federal, State, and local regulations. U SPECIAL PROTECTION INFORMATION: .-. I Respiratory protection: Hone required with good ventilation. Otherwise, wear MSHA/NIOSH approved respirator with organic vapor canister. ' U Storage and aandling: Store in sealed container in a codl, dry location. Keep away from oxidizers and/or ignition sources. I This product may contain one or more hazardous chemicals. The I hazardous ingredients listed are only those as required by 29 CPR 1910.1200. U I I It I I , I I I I 39996, Rev C I 4ATE.IAL. .AVETY DATA SHEET P9. 5 rade niame : PCD iscZ Kit MATERIAL: Extraction and dilution reagent DESCRIPTXON: Clear colorless liquid in a 30ml HDPE screw taOp, impulse sealed container (extraction reagent) or a 2 ml flAme qefled ampuole (dilution reagent) HAZARDOUS INGREfDIENTS: Reagent Weight % Nature of Hazard Methanol (CAS # 67-56-1) 100% Flnmah le. eye & skin irritan PHYSICAL DATA: 4 Appearance: Clear colorless liquid Melting or freezing point: 98 c Boiling po'lt: 65 c Solubility in water: 100% Specific gravity: 0.79 FIRE AND EXPLOSION IRAZARD DATA: Extinguishing media: alcohol foam, CO , dry chemical Special fire fighting procedures: None for small quantities (C 1 liter). For large quantities, wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire and explosion hazards: Fire hazard when exposed to heat, flame, or oxidizers. vapors are explosive. HEALTH HAZARD DATA: Effects of overexposure: Inhalation/Ingestion: Harmful if inhaled, may be fatal if swallowed. Headache, nausea, blindness, gastrointestinal disturbance. Contains low concentration of material known to cause cancer. Such I concentration- is sufficiently below the OSHA threshold(s) wh.ch would require listing as a component P/N 999 Rev C of this solution. . MATE iK L ::AFETY DATA SHEET Pg. 6 Trade Name :pcn ISce' Kit1 MATERIAL:Extraction and Dilution reagent(continued) Emergency First Aid Procedures Inhalation : Remove subject to fresh air. Seek medical attention U if necessary. Eye and Skin Contact : Flush eyes or skin with copious amount8 Of water (flush eyes for 15 minutes) . Wash contaminated clothing before reuse. Seek medical attention if irritation persists. REACTIVITY DATA: Stability: Stable Conditions to avoid: N/A Hazardous decomposition products: Toxic fumes of carbon monoxide and carbon dioxide Hazardous polymerization: Will not occur Incompatible materials to avoid: Qxidizing agents, acids, acid chlorides, acid anhydrides, reducing agents, alkali metals SPILL OR LEAK PROCEDURE: Steps to be taken in case of spill: Contain spill and take up with absorbant material. Eliminate ignition sources. Ventilate area. Waste disposal methods: Observe all Federal, State, and local regulations. SPECIAL PROTECTION INFORMATION: Respiratory protection: None required with good ventilation. Other-wise, wear MSEA/NIOSH approved respirator with organic vapor canister. Storage and Handling: Store in sealed container in a cool, dry location. Keep aw:', :--am oxidizers and/or ignition sources. -v------ I 99996, Rev M.ATi FFT Ol\TA hiEET P.2 T7rade 11are: pan nIc"mtit MATERIAL: SUBSTRATE DESCRIPTION: A polyethylene dropper bottle (yellow cap) containing SmL liquid reagent. HAZARDOUS INGREDIENTS: Reagent Weight % Nature of Hazard N,N-Dimethylformamide 26 Skin and eye irritant, Possible carcinogen PHYSICAL DATA: Appearance: Clear to slightly bluish colored solution Melting or freezing point: < 0 0 C/32 0 F (water) Boiling point: 100 k C/212 0 F (water) Solubility in water: Dilutable FIRE M EXPLOSION HAZARD DATA: Extinguishing media: Coam, alcohol foam, CO 2 , dry chemical, or water/fog Special fire-fighting procedures: Wear self-contained breathing apparatus and proteqtive clothing to prevent contact with skin and eyes. Unusual fire and explosion hazards: N/A HEALTH HAZARD DATA: Effects of Overexposure: Inhalation: Adverse health effects from vapors and spray mists in poorly ventilated areas may.include irritation of the mucous me:2CrAes of the nose, throat, respiratory trac &nd symptoms of headache and rausea. P/N 99996, Rev . I I MATERIAL :UAFETY DATA :;HEET Pg. 8 Trade Name: PCB RIScM Test Kit I MATERIAL: SUBSTRATE ;, (continued) Skin U Contact: , Prolonged and repeated contact with product may cause akin irritation. S - t Eye Contact: Direct contact with product may result in eye I irritation. Note: NN-Dimethyl Formamide is a possible carcinogen -r . 44 U (IARC class 2-B) Eergency and First-Aid Procedures: Inhalation: Remove subject to fresh air. Seek medical U attention if necessary. Eye and Skin Contact: Flush eyes or skin with copious amdunts I of water. Wash contaminated clothing before reuse. Consult a physician if irritation persists. -1 REACTIVITY DATA: U Stability: Stable Conditions to avoid: N/A U Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides I Hazardous polymerization: will not occur Conditions to avoid: N/A U Incompatible materials to avoid: Acid chlorides, oxidizing agents, chloroformates, I reducing agents, halogens I SPILL OR LEAK PROCEDURE: Steps to be taken in case of spill: Contain spill and then I clean-up with copious amounts of water. Avoid contact with skin and clothing. I Waste disposal methods: Observe all ' !ceral, State, and local laws concer - g health and pollution. I P/N 99996, Rev C 40 I MATF.r.:t. -:FETY DATA SHEET Pg. 9 rade tname: PCB RISC Teut' Kit MATERIAL: SUBSTRATE A (continued) SPECIAL PROTECTION INFORMATION: Respiratory protection: None required if good ventilation maintained. is otherwise, wear MSHA NIOSH /-- approved respirator suitable for vapor or mist concentrations encountered. STORAGE AND LABELING: Storage temperature: Store at 25 0C (room temperature) -- II ------. ,-- 3 I I I I I P I / N I"- Rev C I I MATERIAL AEF.TY DATA SHEET Pg. 10 rade 'ame: PC5 RISc lent t U MATflRIAXL: STOP SOLUTION *1 DESCRIPTION: 7z polyethylene ktropper bottle (red cap) containing 5 mL liquid reagent. I HAZARDOUS INGREDIENT: I Reagent Concentration Sulfuric Acid 6% v/v (1 M) I PRECAUTIONARY MEASUTES DangerI Corrosive. Liquid and mist cause severe burns to tissue. 'all body I May be fatal if swallowed. Harmful if inhaled. Inhalation may cause lung damage. Do not get in eyes, on skin, or on clothing. I Do not breathe mist. Keep container closed. Use only with adequate ventilation. I Wash thoroughly ifter handling. This substance is' classified as a POISON under the Federal CaustiC Poison Act. I EMERGENCY/FIRST AID In all cases call a physician. In case of contact, immediately flush 3 skin or eyes with plenty of water for at least 15 minutes. swallowed, If DO NOT INDUCE VOMITING! Give large quantiti es of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. I If breathing is difficult, give oxygen. DOT Hazard Class: Corrosive Material I PHYSICAL DATA: I Appearance: Colorless liquid Odor: Odorless U Solubility: Infinite o 20 0 C. Boiling point: 1 100 0 C. I I )9996, Rev C U MATERIAL 2AFETY DATA SHEET Pg. 11 Trade Name: PC1 RISC" Test Kit MATERIAL: STOP SOLUTION (continued) Melting point: < 0 0 c. Specific gravity: 1.05 - Vapor density: Not available Vapor pressure (mm Hg): < 760 Evaporation rate: No information found. FIRE AND EXPLOSION INFOR4ATION: Fire: Not combustible, but substance its heat is a strong oxidizer of reaction with reducing and combustibles may agents or cause ignition. Reacts metals releasing flanmahle, with most hydrogen gas. potentially explosive Explosion: Not combustible, but substance oxidizer and is a strong its heat of reaction agents or combustibles with reducing may cause ignition. Fire extinguishing media: Dry chemical, foam or carbon dioxide. Water spray may be used keep to fire exposed containers cool. Special information: In the event of a fire, protective wear full clothing and NIOSH-approved self-contained breathing full facepiece apparatus with operated in the pressure demand or other positive pressure mode. REACTIVITY DATA: Stability: Stable under ordinary storage. conditions of use and Hazardous decomposition products: Toxic fumes of oxides of sulfur. to generate Reacts with carbon dioxide gas, carbonates sulfides to and with cyanides form poisonous hydrogen and sulfide, respectively, cyanide and hydrogen P/N 99996, Rev C I .JieiAL.l, AFETY DATA SHEET Pg. 12 Trade I ::ame: PCB RISC ent Kit I MATERIAL: STOP SOLUTION (continued) Hazardous polymerization: will not occur. I Incompatibilities: Bases, organic material, halogens, metal I acetylides, oxides and hydrides, strong oxidizing and reducing agents and many other reactive substances. I LEA/SPILL DISPOSAL INFORMATION: Dike and cover I leaking or pilled liquid with dirt, vermiculite, kitty-litter or other inert absorbent. Cover spill with sodium bicarbonate or soda ash and mix. Clean-up personnel require protective clothing and respiratory protection from vapors and £ mists. Neutralized waste may be containerized and disposed in a RCRA approved waste disposal facility. Flush area of spill, dilute with soda ash solution and discard to sewer. I Reportable Quantity (RQ) (CWA/CERCLA): 1000 lbs. NFPA Ratings: Health: 3 I Flammability: 0 Reactivity: 2 Other: None I I I I I I I I P/N 99996, Rev I MATERIAL SAFETY DATA SHEET Pg. 13 Trade Name: PCB RISC"' Test Kit MATERIAL: ENZYME-PCB Conjugate DESCRIPTION: -A lOxSOm polyethylene dropper tube filled with buffer and containing a small flame sealed capsule of glass freeze dried powder with of PCB conjugate trace amounta HAZARDOUS INGREDIENTS: Reagent Coniugate weight/tube Nature of Hazard Polychlorinated biphenyl- < 5 micrograms No Horseradish peroxide conjugate known toxic effdcts PHYSICAL DATA: Appearance: White to slightly yellow powder Solubility in water: >16 grams/liter FIRE AND EXPLOSION INFORMiATION: FIRE: Not combustible EXPLOSION: Not combustible S------.--....-----...------...-...------..------REACTIVITY DATA: Stability: Stable at room temperature and under conditions ordinary of use and storage. Hazardous decomposition products: None known Hazardous polymerization: Will not occur 3 Conditions to avoid: None known Incompatibilities: None known rc9q96, Rev C I MATERlAIh !TFETY DATA :SHEET Pq. 14 I Trade Name: pCn RSc"^ test Eit I MATERIAL: ENZYME-PCB Conjugate (continued) U LEAK/SPILL DISPOSAL INFORMATION: I Steps to be taken in case of spill: Contain spill if po'sible. Clean up with absorbent material and/or water. I Waste disposal methods: Dispose of in a manner consistent with all Federal, State, and 3 -nl I regulations concerning dinpos"- -of waste material. I U I I I I I U U I I P/N 99996, R- .* I I .IATERIAL U iAFETY DATA SHEET Pg. 15 3T :ade Name: PCD RISc;M Test Kit jM ATERIAL: PCB-Antibody ESCRIPTION: A clear plastic 12x75m Trace amounts tube which appears of PCB antibody empty. I the inside have been *"2 walls of th' coated on not be seen tube. The PCB I by visual inspection. antibody can HAZARDOUS INGREDIENTS: I Reagent Antibody weight/Tube Nature of. Monoclonal antibody Hazard Polychlorinated to < 1 microgram biphenyl U No known toxic ------effects PHYSICAL I DATA: Appearance: Clear plastic tube. on'the The antibody I inside walls has been coated by of the tube and visual inspection. can not be seen Solubility in water: I Not determined ------ ------ PIRE AND I EXPLOSION INFORMATION: FIRE: Not combustible Explosion: I Not combustible I REACTIVITY DATA: Stability: Stable at room temperature I conditions and under ordinary of use and storage- Hazardous decomposition products: None known I Hazardous polymerization: Will not occur Conditions to avoid: I None known Incompatibilities: I None known P/N 99996, U Rev C I MATER IAL ;AVI:TY DATA :HEET P9. .6 I Trade Name: U MATERIAL: PCB Antibody (continued) U LEAK/SPILL DISPOSAL INFORMATTON: Steps to be taken in case of spill: N/A... this material is dried onto the plastic tube and cannot spill. I Waste disposal methods: Dispose of in a manner consistent with all Federal, State, and local I regulati ons concerning disposal of waste material. U I I While the information and recommendations are believed set forth in this document I to be accurate as of makes the revision date, EnSys Inc. no warranty with respect to liability such information,. and we assume resulting from its use. no investigations Users should make their to determine the own U suitability of the their particular purposes. information for I Ait .1 U I I I P/N 99996; Rev C I PROPERTY LINE 269 N040 262 260 249 N 2,8640 FIRST SRE AD D ,6400 0 259 2600 AN 231 353 - 260 -2 -2 32 -1410176E] WWOODS G49164A fl346 22 027 -186 D 13BLDG. NWA0STORAG-MWGRAFE N \ -- s-6 1 1 6 124r 2482 F327IAN 45D_ / - - 0 942 BU 307FNN OIL A. '0A307-O W1ER 209N021862z004 81/PPITN AA '000 000O43P3,WOODSHOU190 51 1 EDGEOAREAGE 20 A32.86,00BOUSo510464210 - AREANE SCUIT 115A 604 // OR IXHED - |SLANDA-K LANDFSTORAGE STRA22GRVE WOODS 17 WOODS PANLEN m ,, ,T -- WB MW Air Contaminents, FederaI Registor, Vol. 54, NO. 1t, 1969. pp. 2332-2S. information STATES solid APPEARANCE: White powder ODORSNot determined 3I In-hou.s Judrenet SOLUBILITY INS WATERS Soluble ACID: Not determined (0 Technical OTHER, Not determined BOILING POINT: NA hELTING Pf., ~224C SPEC GRAVITY, NO pHi of SX soin. - 5.2 VAPOR PRESSURE' Not oppictcble VAPOR DENSITY (airmle NA EVAPORATION RATE: NA METAL CORROSIVITY - ALUITIINUMI0.00 in/yr STEEL: 0.57 in/yr STAOILETYl Sea Conditions to Avoid STORAGE PRECAUTIONS, Storm ln . cool dry place. IV. FIRE, EXPLOSION HAZARD AND REACTIVITY DATA