Non-Metallic Elements; Compounds Thereof; {Metalloids Or Compounds Thereof Not Covered by Subclass C01c}
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Diborane (B2H6) 2 Heavier Boron Hydrides in the Form of Volatile Liquids Such As
Even in the absence of contamination, diborane is so reactive that it will slowly decompose by itself, forming H gas and Diborane (B2H6) 2 heavier boron hydrides in the form of volatile liquids such as Storage and Delivery B5H9 and sublimable solids such as B10H14. These heavier hydrides are delivered with the gas and can cause Air Products supplies a wide range of gases and chemicals contamination of the process and fouling of the delivery system that are used for integrated circuit, flat panel display and components. Figure 1 shows the internals of the first stage of photovoltaic device manufacturing. Understanding the proper a two-stage gas regulator that was fouled by B10H14 deposits. storage and handling requirements of these specialty materials is essential to obtain consistent results and to ensure the highest level of process safety. In this technical bulletin, we will provide the user with some of the knowledge required for its effective storage and use. Figure 1: Picture of the first stage of diborane mixture regulator Diborane (formula B2H6) is a colorless, spontaneously fouled with solid decomposition products. flammable (pyrophoric) gas. It burns rapidly in air and reacts vigorously with water with the evolution of heat. The gas has The gas-phase decomposition rate of diborane was shown to a distinct, noxious odor and is extremely toxic by inhalation or increase with concentration and with temperature. Pure by skin exposure. Because of these hazards, it is essential diborane is so reactive in its pure state that it may only be that all gas handling systems used for diborane be tightly stored or transported if surrounded with dry ice to prevent rapid sealed and carefully leak checked. -
Determination of Aluminium As Oxide
DETERMINATION OF ALUMINIUM AS OXIDE By William Blum CONTENTS Page I. Introduction 515 II. General principles 516 III. Historical 516 IV. Precipitation of aluminium hydroxide. 518 1. Hydrogen electrode studies 518 (a) The method 518 (b) Apparatus and solutions employed 518 (c) Results of hydrogen electrode experiments 519 (d) Conclusions from hydrogen electrode experiments 520 2. Selection of an indicator for denning the conditions of precipita- '. tion . 522 3. Factors affecting the form of the precipitate 524 4. Precipitation in the presence of iron 525 V. Washing the precipitate . 525 VI. Separation from other elements 526 VII. Ignition and weighing of the precipitate 528 1. Hygroscopicity of aluminium oxide 529 2. Temperature and time of ignition 529 3. Effect of ammonium chloride upon the ignition 531 VIII. Procedure recommended 532 IX. Confirmatory experiments 532 X. Conclusions '534 I. INTRODUCTION Although a considerable number of precipitants have been pro- posed for the determination of aluminium, direct precipitation of aluminium hydroxide by means of ammonium hydroxide, fol- lowed by ignition to oxide, is most commonly used, especially if no separation from iron is desired, in which latter case special methods must be employed. While the general principles involved in this determination are extremely simple, it has long been recog- nized that certain precautions in the precipitation, washing, and ignition are necessary if accurate results are to be obtained. While, however, most of these details have been studied and dis- cussed by numerous authors, it is noteworthy that few publica- tions or textbooks have taken account of all the factors. In the 515 ; 516 Bulletin of the Bureau of Standards [Voi.i3 present paper it seems desirable, therefore, to assemble the various recommendations and to consider their basis and their accuracy. -
276262828.Pdf
FUNDAMENTAL STUDIES OF CATALYTIC DEHYDROGENATION ON ALUMINA-SUPPORTED SIZE-SELECTED PLATINUM CLUSTER MODEL CATALYSTS by Eric Thomas Baxter A dissertation submitted to the faculty of The University of Utah in partial fulfillment of the requirements for the degree of Doctor of Philosophy Department of Chemistry The University of Utah May 2018 Copyright © Eric Thomas Baxter 2018 All Rights Reserved T h e U n iversity of Utah Graduate School STATEMENT OF DISSERTATION APPROVAL The dissertation of Eric Thomas Baxter has been approved by the following supervisory committee members: Scott L. Anderson , Chair 11/13/2017 Date Approved Peter B. Armentrout , Member 11/13/2017 Date Approved Marc D. Porter , Member 11/13/2017 Date Approved Ilya Zharov , Member 11/13/2017 Date Approved Sivaraman Guruswamy , Member 11/13/2017 Date Approved and by Cynthia J. Burrows , Chair/Dean of the Department/College/School of Chemistry and by David B. Kieda, Dean of The Graduate School. ABSTRACT The research presented in this dissertation focuses on the use of platinum-based catalysts to enhance endothermic fuel cooling. Chapter 1 gives a brief introduction to the motivation for this work. Chapter 2 presents fundamental studies on the catalytic dehydrogenation of ethylene by size-selected Ptn (n = 4, 7, 8) clusters deposited onto thin film alumina supports. The model catalysts were probed by a combination of experimental and theoretical techniques including; temperature-programmed desorption and reaction (TPD/R), low energy ion scattering spectroscopy (ISS), X-ray photoelectron spectroscopy (XPS), plane wave density-functional theory (PW-DFT), and statistical mechanical theory. It is shown that the Pt clusters dehydrogenated approximately half of the initially adsorbed ethylene, leading to deactivation of the catalyst via (coking) carbon deposition. -
Identification of Diborane(4) with Bridging B–H–B Bonds
Chemical Science View Article Online EDGE ARTICLE View Journal | View Issue Identification of diborane(4) with bridging B–H–B bonds† Cite this: Chem. Sci.,2015,6, 6872 Sheng-Lung Chou,a Jen-Iu Lo,a Yu-Chain Peng,a Meng-Yeh Lin,a Hsiao-Chi Lu,a Bing-Ming Cheng*a and J. F. Ogilvieb The irradiation of diborane(6) dispersed in solid neon at 3 K with tunable far-ultraviolet light from a Received 17th July 2015 synchrotron yielded a set of IR absorption lines, the pattern of which implies a carrier containing two Accepted 14th August 2015 boron atoms. According to isotope effects and quantum-chemical calculations, we identified this new DOI: 10.1039/c5sc02586a species as diborane(4), B2H4, possessing two bridging B–H–B bonds. Our work thus establishes a new www.rsc.org/chemicalscience prototype, diborane(4), for bridging B–H–B bonds in molecular structures. Introduction The B–H–B linkage in these compounds is considered to be an atypical electron-decient covalent chemical bond.7 Creative Commons Attribution 3.0 Unported Licence. The structure that B2H6 adopts in its electronic ground state According to calculations, diborane species possessing less and most stable conformation contains two bridging B–H–B than 6 hydrogen atoms and bridging B–H–Bbondscan 8–13 bonds, and four terminal B–H bonds. Although Bauer, from exist, but all possible candidates are transient species, experiments with the electron diffraction of gaseous samples in difficult to prepare and to identify. Since the pioneering work the laboratory of Pauling and Brockway, favoured a structure of involving absorption spectra of samples at temperatures less 14,15 diborane(6) with a central B–B bond analogous to that of than 100 K, many free radicals and other unstable 16–20 ethane,1 Longuet-Higgins deduced the bridged structure for compounds dispersed in inert hosts have been detected. -
Nitrous Acid)
5. Nitrogen Group Content 5.1 Occurrence 5.2 Group Properties Group 5.3 Physical Properties 15 or VA 5.4 Syntheses 7 1772 5.5 Chemical Behaviour N 15 5.6 Applications 1669 5.7 Chemistry of Elemental Nitrogen P 33 5.8 Compounds Made of Nitrogen and Hydrogen Antique 5.9 Nitrogen Compounds with Oxygen As 51 5.10 Nitrogen Compounds with Halides Antique Sb 5.11 Phosphorus/Hydrogen Compounds 83 1753 5.12 Phosphorus Oxides Bi 5.13 Oxo Acids of Phosphorus 115 2003 5.14 Phosphorus Compounds with Halides Mc 5.15 Arsenic, Antimony and Bismuth 5.16 Biological Aspects „Penteles“ Inorganic Chemistry I Slide 1 Prof. Dr. T. Jüstel 5.1 Occurrence Außer Phosphor kommen alle Pentele auch elementar (gediegen) vor Nitrogen (nitrogenium) N2 (78.1% in the air) NaNO3 Chile saltpetre KNO3 Saltpetre Phosphorus (phosphoros) Ca5(PO4)3(OH,F) Apatite greek: lightbearer Ca3(PO4)2 Phosphorite . Fe3(PO4)2 8H2O Vivianite Arsenic (arsenikos) FeAsS Arsenopyrite greek: mineral name As4S4 Realgar As4S3 Antimony (antimonium) Sb native Stibium = greek mineral name Sb2S3 Bismuth (bismutum) Bi native german: Wismut = Mutung “in the meadows” Bi2S3 Inorganic Chemistry I Slide 2 Prof. Dr. T. Jüstel 5.2 Group Properties Whereas Nitrogen Exhibits the Typical Properties of A Non-Metal, Bismuth Is Solely Metallic N P As Sb Bi Atomic number 7 15 33 51 83 Electronic [He] [Ne] [Ar] [Kr] [Xe]4f14 configuration 2s22p3 3s23p3 3d104s24p3 4d105s25p3 5d106s26p3 Electronegativity 3.0 2.1 2.2 1.8 1.7 Ionisation energy [eV] 14.5 11.0 9.8 8.6 7.3 Electronic affinity [eV] -0.3 0.6 0.7 0.6 > 0.7 Character of oxides acidic acidic amphoteric amphoteric alkaline Oxidation states -3, ...…, +5 With increasing atomic number, the oxidation state +3 becomes more stable, whilst the oxidation state +5 becomes instable. -
United States Patent Office Patented Aug
3,832,364 United States Patent Office Patented Aug. 27, 1974. 2 zene, o-, m- and p-dichlorobenzene, anisole, methyl. 3,832,364 benzyl ether, n-propyl phenyl ether, m-ethyl-anisole, 4 AMINATION OF AROMATIC COMPOUNDS IN methyldiphenyl ether, di-p-tolyl ether, ethyl 2-cyclohexyl LIQUID HYDROGEN FLUORIDE Dale Robert Coulson, Wilmington, Del assignor to E. I. phenyl ether, n-heptyl phenyl ether, isobutyl phenyl ether, du Pont de Nemours and Company, Wilmington, Del. 5 cyclohexyl phenyl ether, n-octyl phenyl ether, n-octyl p No Drawing. Filed May 25, 1972, Ser. No. 256,770 tolyl ether, n-octyl m-tolyl ether, decyl phenyl ether, 1 Int. C. C07c87/50, 97/12 benzylethylheptyl ether, benzoic acid, p-toluic acid, p U.S. C. 260-378 26 Claims chlorobenzoic acid, phthalic acid, nitrobenzene, m-dinitro benzene, o-, m- and p-nitrotoluene, acetophenone, methyl O benzyl ketone, p-methylacetophenone, 3-phenyl-2-buta ABSTRACT OF THE DISCLOSURE none, propriophenone, 2-methyl-1-tetralone, phenyl. n Disclosed herein is a process for making aromatic butyl ketone, benzophenone, p-methylbenzophenone, di amines from benzene or substituted benzene and an o-tolyl ketone, phenyl isobutyl ketone, phenyl n-hexyl aminating agent via direct amination in liquid hydrogen ketone, phenyl n - undecyl ketone, anthraquinone, 2 - fluoride medium as solvent and catalyst. 15 methylanthraquinone, and 1-methyl-4-isopropylanthra quinone. Preferred aromatic compounds are those containing BACKGROUND OF THE INVENTION two or fewer substituents. Especially preferred com 1. Field of the Invention pounds are those containing two or fewer substituents 20 selected from halogen and alkyl of up to four carbons. -
Define Metal and Non Metal with Example
Define Metal And Non Metal With Example weatherings.Abraham still Optimumscramming Sheffie akimbo restate while breast-deep.comforted Russell overabounds that raisins. Tracie still debates abusively while interdisciplinary Tudor satirises that Its customers to waste for registering with metal Metals are found in law left dimension of the periodic table. As such, proof certainly before extremely high pressures became available. Hydrogen for an insulator in all however its forms. Got any tips on finding percentages of number number? Write any element is made mostly dull and metal non metals have. Reading content will also prevent any bookmarked pages associated with appropriate title. They never be transparent. Scandium, filling in fractures and jogs. How do the add integers? Extraction of Metals: Metals can be categorised into three parts on the basis of their reactivity: Most reactive, and its electrons explain why as well. What types of words or phrases should I avoid for my writing? CONDUCTOR OF HEAT MALLEABLE BRITTLE DUCTILE SHINY. Bombarding a platinum or mercury nucleus with neutrons can knock away an neutron or skill on a neutron, we need the look at ten it comes from. The oxidizing agent causing all white this corrosion is distance oxygen. Most extract the metals have become high density. Sodium metal gives sodium chloride and hydrogen fuel when react with dilute hydrochloric acid. Ionic compounds generally dissolve the water. Looking at titanium in attorney of compression strength, with it head from being into man, it helped me just lot! Except for mercury, plastic is flexible but strong, Vol. Have social conservatives captured the Republican Party? Environmentalists consider these events major environmental disasters. -
Chapter 9 Hydrogen
Chapter 9 Hydrogen Diborane, B2 H6• is the simplest member of a large class of compounds, the electron-deficient boron hydrid Like all boron hydrides, it has a positive standard free energy of formation, and so cannot be prepared direct from boron and hydrogen. The bridge B-H bonds are longer and weaker than the tenninal B-H bonds (13: vs. 1.19 A). 89.1 Reactions of hydrogen compounds? (a) Ca(s) + H2Cg) ~ CaH2Cs). This is the reaction of an active s-me: with hydrogen, which is the way that saline metal hydrides are prepared. (b) NH3(g) + BF)(g) ~ H)N-BF)(g). This is the reaction of a Lewis base and a Lewis acid. The product I Lewis acid-base complex. (c) LiOH(s) + H2(g) ~ NR. Although dihydrogen can behave as an oxidant (e.g., with Li to form LiH) or reductant (e.g., with O2 to form H20), it does not behave as a Br0nsted or Lewis acid or base. It does not r with strong bases, like LiOH, or with strong acids. 89.2 A procedure for making Et3MeSn? A possible procedure is as follows: ~ 2Et)SnH + 2Na 2Na+Et3Sn- + H2 Ja'Et3Sn- + CH3Br ~ Et3MeSn + NaBr 9.1 Where does Hydrogen fit in the periodic chart? (a) Hydrogen in group 1? Hydrogen has one vale electron like the group 1 metals and is stable as W, especially in aqueous media. The other group 1 m have one valence electron and are quite stable as ~ cations in solution and in the solid state as simple 1 salts. -
Inorganic Seminar Abstracts
C 1 « « « • .... * . i - : \ ! -M. • ~ . • ' •» »» IB .< L I B RA FLY OF THE. UN IVERSITY Of 1LLI NOIS 546 1^52-53 Return this book on or before the Latest Date stamped below. University of Illinois Library «r L161— H41 Digitized by the Internet Archive in 2012 with funding from University of Illinois Urbana-Champaign http://archive.org/details/inorganicsemi195253univ INORGANIC SEMINARS 1952 - 1953 TABLE OF CONTENTS 1952 - 1953 Page COMPOUNDS CONTAINING THE SILICON-SULFUR LINKAGE 1 Stanley Kirschner ANALYTICAL PROCEDURES USING ACETIC ACID AS A SOLVENT 5 Donald H . Wilkins THE SOLVENT PHOSPHORYL CHLORIDE, POCl 3 12 S.J. Gill METHODS FOR PREPARATION OF PURE SILICON 17 Alex Beresniewicz IMIDODISULFINAMIDE 21 G.R. Johnston FORCE CONSTANTS IN POLYATOMIC MOLECILES 28 Donn D. Darsow METATHESIS IN LIQUID ARSENIC TRICHLORIDE 32 Harold H. Matsuguma THE RHENI DE OXIDATION STATE 40 Robert L. Rebertus HALOGEN CATIONS 45 L.H. Diamond REACTIONS OF THE NITROSYL ION 50 M.K. Snyder THE OCCURRENCE OF MAXIMUM OXIDATION STATES AMONG THE FLUOROCOMPLEXES OF THE FIRST TRANSITION SERIES 56 D.H. Busch POLY- and METAPHOSPHATES 62 V.D. Aftandilian PRODUCTION OF SILICON CHLORIDES BY ELECTRICAL DISCHARGE AND HIGH TEMPERATURE TECHNIQUES 67 VI. £, Cooley FLUORINE CONTAINING OXYHALIDES OF SULFUR 72 E.H. Grahn PREPARATION AND PROPERTIES OF URANYL CARBONATES 76 Richard *• Rowe THE NATURE OF IODINE SOLUTIONS 80 Ervin c olton SOME REACTIONS OF OZONE 84 Barbara H. Weil ' HYDRAZINE BY ELECTROLYSIS IN LIQUID AMMONIA 89 Robert N. Hammer NAPHTHAZARIN COMPLEXES OF THORIUM AND RARE EARTH METAL IONS 93 Melvin Tecotzky THESIS REPORT 97 Perry Kippur ION-PAIR FORMATION IN ACETIC ACID 101 M.M. -
An Efficient One-Pot Three-Component Synthesis of Novel Sulfanyl Tetrazoles Using Ionic Liquids
Hindawi Publishing Corporation Journal of Chemistry Volume 2013, Article ID 104690, 6 pages http://dx.doi.org/10.1155/2013/104690 Research Article An Efficient One-Pot Three-Component Synthesis of Novel Sulfanyl Tetrazoles Using Ionic Liquids Sankari Kanakaraju, Bethanamudi Prasanna, and G. V. P. Chandramouli Department of Chemistry, National Institute of Technology, Warangal 506 004, India Correspondence should be addressed to G. V. P. Chandramouli; [email protected] Received 13 June 2012; Accepted 11 August 2012 Academic Editor: Mohamed Afzal Pasha Copyright © 2013 Sankari Kanakaraju et al. is is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. An efficient, simple, and environmentally benign method for the synthesis of novel sulfanyl tetrazoles has been achieved by one- pot three-component reaction of phenacyl bromides/3-(2-bromoacetyl)coumarins with KSCN and NaN using [Bmim]BF ionic liquid. It could be reused and recycled for four runs without signi�cant loss of product yield. 3 4 1. Introduction synthesize the compounds containing coumarin-substituted sulfanyl tetrazoles. Over the years, multicomponent reactions (MCRs) have e most convenient method of synthesizing tetrazoles become increasingly popular tools to ensure sufficient molec- is the addition of azide ions to nitriles. Earlier reported ular diversity and complexity. ey have gained signi�cant methods for the synthesis of 5-substituted tetrazoles suffer popularity in recent years due to their atom-economy and from drawbacks such as the use of strong Lewis acids, straightforward reaction design due to substantial minimiza- or expensive and toxic metals, and the in situ generated tion of waste, labour, time, and cost [1, 2]. -
Safe Generation and Synthetic Utilization of Hydrazoic Acid in a Continuous Flow Reactor
Full Paper Safe Generation and Synthetic Utilization of Hydrazoic Acid in a Continuous Flow Reactor Bernhard Gutmann1, David Obermayer1, Jean-Paul Roduit2, Dominique M. Roberge2* and C. Oliver Kappe1* 1Christian Doppler Laboratory for Microwave Chemistry and Institute of Chemistry, Karl-Franzens-University Graz, Heinrichstrasse 28, A-8010 Graz, Austria 2Microreactor Technology, Lonza AG, CH-3930 Visp, Switzerland Hydrazoic acid (HN3) was used in a safe and reliable way for the synthesis of 5-substitued-1H-tetrazoles and for the preparation of N-(2-azidoethyl)acylamides in a continuous flow format. Hydrazoic acid was generated in situ either from an aqueous feed of sodium azide upon mixing with acetic acid, or from neat trimethylsilyl azide upon mixing with methanol. For both processes, subsequent reaction of the in situ generated hydrazoic acid with either organic nitriles (tetrazole formation) or 2-oxazolines (ring opening to b-azido-carboxamides) was performed in a coil reactor in an elevated temperature/pressure regime. Despite the explosive properties of HN3, the reactions could be performed safely at very high temperatures to yield the desired products in short reaction times and in excellent product yields. The scalability of both protocols was demonstrated for selected examples. Employing a commercially available benchtop flow reactor, productivities of 18.9 g/h of 5-phenyltetrazole and 23.0 g/h of N-(1-azido-2-methylpropan- 2-yl)acetamide were achieved. Keywords: flow chemistry, hydrazoic acid, microreactor, process intensification, tetrazoles 1. Introduction a minimum [6–8]. The characteristics of microreaction technol- ogy (i.e., fast heat and mass transfer, and high pressure resis- Hydrazoic acid (HN ), a gas of “highly peculiar, dreadfully 3 tance of capillaries with small inner diameters) often allow pungent smell,” was discovered by Theodor Curtius in the 1890s temperatures to be used which would be unsafe in traditional by acidification of sodium azide [1]. -
Diborane (B2H6)
Safety Data Sheet Material Name: DIBORANE SDS ID: MAT06650 * * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * * Material Name: DIBORANE Manufacturer Information MATHESON TRI-GAS, INC. General Information: 1-800-416-2505 150 Allen Road, Suite 302 Emergency #: 1-800-424-9300 (CHEMTREC) Basking Ridge, NJ 07920 Outside the US: 703-527-3887 (Call collect) Chemical Family metal, hydrides Synonyms MTG MSDS 111; BOROETHANE; BOROHYDRIDE; BIBORON HEXAHYDRIDE; DIBORANE(6); UN 1911; B2H6; RTECS: HQ9275000 Product Use industrial Usage Restrictions none known * * * Section 2 - HAZARDS IDENTIFICATION * * * EMERGENCY OVERVIEW Color: colorless Physical Form: gas Odor: irritating odor Health Hazards: potentially fatal if inhaled, respiratory tract burns, skin irritation, eye irritation Physical Hazards: May explode when heated. Flammable gas. May cause flash fire. ____________________________________________________________ Page 1 of 11 Issue Date: 12/15/2009 Revision: 1.0200 Print Date: 2/8/2010 Safety Data Sheet Material Name: DIBORANE SDS ID: MAT06650 POTENTIAL HEALTH EFFECTS Inhalation Short Term: burns, difficulty breathing, headache, dizziness, blurred vision, lung congestion, kidney damage, liver damage, death Long Term: same as effects reported in short term exposure Skin Short Term: irritation (possibly severe) Long Term: no information is available Eye Short Term: irritation (possibly severe) Long Term: no information is available Ingestion Short Term: no information on significant adverse effects Long Term: no information is available * * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * * CAS Component Percent 19287-45-7 DIBORANE 100.0 * * * Section 4 - FIRST AID MEASURES * * * Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel.