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Supplementary Materials Supplementary Materials Table S1. Metals with stdev W1 W2 W3 W4 W5 W6 W7 W8 W9 W10 W11 W12 W13 As <LOD <LOD 19.84±0.03 <LOD <LOD <LOD <LOD <LOD <LOD <LOD <LOD <LOD <LOD Ba 32.6±0.3 33.8±0.4 26.1±0.2 123.3±0.9 79.8±0.8 79.1±0.7 83.3±0.6 239.7±0.8 58.1±0.4 77.7±0.3 32.1±0.3 31.7±0.5 122.1±0.8 Cd 0.365±0.004 1.553±0.002 0.939±0.002 1.254±0.003 0.386±0.005 1.367±0.008 0.733±0.004 0.050±0.002 0.976±0.002 1.644±0.006 <LOD 0.593±0.004 0.375±0.003 Co 3.64±0.04 2.09±0.02 0.98±0.03 4.40±0.06 2.77±0.02 1.83±0.02 2.42±0.02 2.68±0.03 7.34±0.09 7.78±0.07 2.12±0.04 1.61±0.02 2.60±0.03 Cr <LOD <LOD <LOD <LOD 4.322±0.005 3.030±0004 <LOD 6.417±0.006 15.41±0.02 14.82±0.05 11.12±0.04 9.15±0.02 3.111±0.004 Pb <LOD 56.0±0.8 <LOD 20.8±0.9 80±2 11.7±0.6 2.20±0.05 175±3 45.0±0.8 <LOD 0.830±0.007 0.538±0.006 14.9±0.3 Sb 32.8±0.5 8.59±0.09 19.1±0.2 18.±0.2 67.5±0.5 37.9±0.2 9.58±0.05 46.5±0.3 44.8±0.4 18.50±0.08 7.26±0.03 44.3±0.2 29.6±0.4 Se <LOD <LOD <LOD <LOD 1.45±0.09 0.30±0.05 0.23±0.08 25.7±0.4 2.87±0.2 2.06±0.04 2.91±0.8 2.38±0.07 2.99±0.06 Ni 4.17±0.05 46.0±0.2 0.569±0.005 30.9±0.3 15.3±0.2 5.77±0.02 35.2±0.3 13.86±0.04 50.6±0.7 17.9±0.2 9.99±0.03 0.197±0.007 5.00±0.02 Al 566±5 260.1±0.5 155.3±0.4 720±5 447±4 290.7±2 26.5±0.4 155.4±0.9 444±4 329±3 1027±10 567.7±8 236±3 Cu 97.5±0.8 469±3 36.3±0.9 10.07±0.05 <LOD <LOD <LOD <LOD 21.19±0.07 7.73±0.03 0.813±0.05 49.3±0.8 50.2±1.0 Mn 735±30 613±10 642±6 1016±6 762±3 743±5 839±8 1634±30 1732±20 1472±20 887±10 771±6 1299±10 V 4.18±0.02 1.894±0.007 0.574±0.002 <LOD 1.530±0.005 <LOD 1.948±0.006 3.179±0.004 3.235±0.007 2.304±0.003 0.810±0.002 0.729±0.002 <LOD Zn 468.4±0.7 1359±8 423.8±5 622.2±3 1356±10 607±7 298±3 969±8 1278±9 916±4 519±2 537±3 897±4 Caa 70.7±0.9 76.9±1.0 71.7±0.8 111.2±1.0 62.5±0.7 83.9±0.4 50.7±0.4 67.5±0.7 62.8±0.5 98.1±0.6 76.4±0.2 99.9±0.3 71.1±0.2 Fea 0.134±0.002 0.077±0.05 0.050±0.002 0.786±0.004 0.525±0.006 0.520±0.007 0.593±0.002 1.082±0.008 1.809±0.007 0.688±0.004 0.371±0.002 0.198±0.002 0.870±0.003 Ka 489±5 707±5 663±7 1152±10 609±3 719±4 965±8 1119±9 567±6 867±8 700±7 1174±10 1111±9 Mga 55.3±0.8 52.9±0.4 52.4±0.5 77.4±0.2 70.3±0.8 71.0±0.4 82.1±0.5 102.0±0.8 64.0±0.3 68.4±0.4 69.11±0.09 60.4±0.2 94.3±0.3 Naa 7.75±0.02 14.13±0.06 9.32±0.04 38.24±0.02 29.61±0.08 27.41±0.05 11.69±0.02 16.88±0.04 21.60±0.02 26.49±0.06 9.36±0.04 17.62±0.02 22.08±0.04 Rba 2.69±0.04 2.96±0.05 3.084±0.006 3.83±0.05 3.90±0.08 3.85±0.04 5.07±0.02 7.38±0.07 4.33±0.08 3.96±0.08 4.08±0.04 3.59±0.02 5.63±0.07 1 Table S2. Correlation coefficients among elements in analyzed wine samples. 2 Table S3. Polyphenols, TPC, and RSA stdev. Non-anthocyanins (mg/L) W1 W2 W3 W4 W5 W6 W7 W8 W9 W10 W11 W12 W13 Hydroxybenzoic acids Gallic acid 1.99±0.30 1.09±0.16 − 41.73±6.26 38.20±5.73 24.22±3.63 74.36±11.15 81.35±12.20 4.40±0.66 2.53±0.38 2.82±0.42 3.24±0.49 74.62±11.19 Protocatechuic acid 0.53±0.05 0.57±0.06 0.57±0.06 2.63±0.27 1.33±0.13 1.78±0.18 7.27±0.73 5.41±0.55 1.70±0.17 1.41±0.14 1.57±0.16 1.30±0.13 8.23±0.83 Gentisic acid 1.45±0.15 3.24±0.33 3.36±0.34 1.52±0.15 2.90±0.29 1.47±0.15 1.01±0.10 0.87±0.09 1.47±0.15 0.49±0.05 0.71±0.07 1.26±0.13 − Ellagic acid 0.71±0.11 0.51±0.08 0.65±0.10 1.17±0.18 0.81±0.12 1.01±0.15 25.24±3.79 24.41±3.66 1.36±0.20 0.74±0.11 0.49±0.07 0.61±0.09 29.02±4.35 Hydroxicinnamic acids Sinapic acid − − − − − − − − − − − 23.67±2.62 − Caffeic acid 0.59±0.07 0.67±0.08 1.36±0.16 8.79±1.04 9.16±1.09 5.47±0.65 4.58±0.54 7.18±0.85 5.78±0.69 2.58±0.31 1.01±0.12 0.95±0.11 5.44±0.65 Chlorogenic acid 0.040±0.004 0.030±0.003 0.040±0.004 0.040±0.004 0.07±0.01 0.10±0.01 − 0.07±0.01 0.030±0.003 0.19±0.02 0.12±0.01 0.10±0.01 0.20±0.02 p-Coumaric acid 1.12±0.07 2.03±0.12 1.46±0.09 2.64±0.16 3.02±0.18 2.99±0.18 10.34±0.62 4.63±0.28 1.80±0.11 1.65±0.10 1.60±0.10 4.30±0.26 5.61±0.34 Flavanols Gallocatechin − − − 1.34±0.13 3.29±0.33 5.37±0.54 − − − − − − 0.93±0.10 Epigallocatechin gallate − − 0.86±0.09 − − − 1.02±0.11 1.63±0.17 − 0.91±0.09 − 1.48±0.15 1.31±0.14 Catechin − − − 4.23±0.23 5.95±0.33 10.40±0.58 25.93±1.44 16.98±0.94 3.63±0.20 − 1.49±0.08 1.69±0.09 26.67±1.48 Gallocatechin gallate − − − − 0.52±0.05 − 2.48±0.24 − − − 1.10±0.10 0.35±0.03 1.94±0.19 Flavonols Myricetin − − − − − − 0.39±0.02 0.41±0.02 0.020±0.001 − − − 0.28±0.01 Rutin − − − 0.020±0.001 − 0.010±0.001 − − − 0.030±0.001 − − 0.020±0.001 Astragalin − − − 0.010±0.001 − − − 0.010±0.001 − 0.010±0.001 − − − Hyperoside − − − − − 0.010±0.001 0.20±0.01 0.26±0.01 − − − 0.010±0.001 0.47±0.02 Galangin 1.21±0.18 0.88±0.13 0.60±0.09 0.46±0.07 0.36±0.05 0.20±0.03 0.24±0.04 0.19±0.03 0.18±0.03 − − − − Flavones Chrysin 0.60±0.06 − − − − − − − − − − − − Luteolin − − − − − − − 0.10±0.01 − − − − − Cynaroside − − − 0.67±0.01 − − 0.48±0.01 0.53±0.01 0.50±0.01 0.57±0.01 − − 0.35±0.01 Apigetrin − − − 0.010±0.001 − − 0.010±0.001 0.010±0.001 0.010±0.001 0.010±0.001 − − 0.010±0.001 3 Apigenin 0.060±0.005 − 0.030±0.002 − − − − − − − − − − Hydroxycoumarins Aesculin − − 0.050±0.002 − − − 0.65±0.03 0.69±0.03 − − − 0.44±0.02 0.87±0.04 Stilbenes Resveratrol − − − − − − 4.00±0.17 − − − − − − Hesperetin − − 0.090±0.005 0.050±0.003 − − 0.71±0.04 0.44±0.03 − 0.10±0.01 − − 0.41±0.02 Dihydrochalcones Phlorizin − − − 0.080±0.002 0.130±0.004 0.180±0.006 1.03±0.03 0.98±0.03 0.130±0.004 0.060±0.002 0.050±0.002 0.070±0.002 0.98±0.03 Anthocyanins (mg/L) Myrtillin − − − 0.020±0.001 − − 0.47±0.03 0.050±0.003 − − − − 0.57±0.03 Malvin − − − 0.010±0.001 − − 0.040±0.004 − − − − − 0.060±0.006 Cyanidin 3-O-(2"-xylosyl)glucoside − − − − − − 0.040±0.006 0.020±0.003 − − − − 0.040±0.006 Chrysanthemin − − − − − − 0.15±0.01 0.020±0.001 − − − − 0.28±0.02 Peonidin 3-O-glucoside − − − 0.09±0.01 − − 0.61±0.07 0.06±0.01 − − − − 0.69±0.08 Oenin − − − 0.55±0.05 − − 3.4±0.3 0.64±0.06 − − − − 3.9±0.4 RSA (mmol TE/L) 0.39±0.03 0.44±0.01 0.42±0.02 1.97±0.03 3.17±0.01 2.68±0.04 16.09±0.02 18.71±0.02 1.86±0.01 1.64±0.02 1.26±0.03 0.82±0.01 12.03± TPC (g GAE/L) 1.15±0.02 1.44±0.02 1.41±0.01 1.44±0.02 1.51±0.03 1.67±0.01 2.24±0.00 2.36±0.01 1.35±0.02 1.31±0.02 0.81±0.01 1.17±0.01 1.71± 4 Table S4.
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