Dyes & Pigments

Total Page:16

File Type:pdf, Size:1020Kb

Dyes & Pigments Dyes & Pigments with forecasts to 2005 and 2010 New study finds: • The US market for dyes and organic pigments (organic colorants) is expected to increase 2.8 percent per year to $3.1 billion in 2005, with volume over the same period forecast to reach 675 million pounds • Positive growth opportunities are to be found in the rapidly growing market for dyes used in digital printing inks and high-tech imaging • The six leading suppliers -- Ciba Specialty Chemicals, DyStar, Clariant, Sun Chemical, Bayer and BASF -- accounted for nearly two-thirds of the total market in 2000 Freedonia Industry Study #1439 Study Publication Date: June 2001 Price: $3,700 Dyes & Organic Pigments Pages: 237 Dyes & Organic Pigments, a new study from The Freedonia Group, provides you with an in-depth analysis of major trends in the industry and the outlook for product seg- ments and major markets -- critical information to help you with strategic planning. This brochure gives you an indication of the scope, depth and value of Freedonia's new study, Dyes & Organic Pigments. Ordering information is included on the back page of the brochure. Brochure Table of Contents Study Highlights ............................................................................... 2 Table of Contents and List of Tables and Charts ............................. 4 Sample Pages and Sample Tables from: Market Environment .................................................... 6 Products ....................................................................... 7 Markets........................................................................ 8 Industry Structure ........................................................ 9 Company Profiles ...................................................... 10 List of Companies Profiled ........................................ 11 Forecasting Methodology ............................................................... 12 About the Company ....................................................................... 13 Advantages of Freedonia Reports ................................................... 13 About Our Customers .................................................................... 14 Other Titles From Freedonia ......................................................... 15 Ordering Information..................................................................... 16 Study Highlights • The US market for dyes and organic pigments (organic colorants) is expected to increase 2.8 percent per year to $3.1 billion in 2005, with volume over the same period forecast to reach 675 million pounds. • Organic pigments, having overtaken dyes during the latter half of the 1990s to become the predominant segment in 2000, will continue to lead growth, while demand for dyes will remain weak due to heavy reliance on the sluggish textile industry. • While development of high performance and other specialty pigments for water-based inks, powder coatings and radiation-curable inks and coatings will spur value gains, volume advances will be restrained by the lofty prices of these specialty pigments. • Positive growth opportunities are to be found in the rapidly growing market for dyes used in digital printing inks and high-tech imaging. • Disperse dyes will record the best performance among textile dyes, based on the resurgence in popularity of polyester and polyester blends in apparel and home furnishings, and the development of higher-value specialty disperse dyes, which face less competition from low-cost imports than do lower-performance types. • The six leading suppliers -- Ciba Specialty Chemicals, DyStar, Clariant, Sun Chemical, Bayer and BASF -- accounted for nearly two-thirds of the total market in 2000. Dyes & Organic Pigments #1439 Freedonia Industry Study 2 Study Highlights Dye & Organic Pigments Demand by Market, 2000 Textiles 32.7% Printing Inks 24.2% Other Paints & Coatings 20.6% 13.6% Plastics 8.9% Dye & Organic Pigment Demand (million dollars) % Annual Growth Item 1995 2000 2005 2010 95/00 00/05 Nondurable Goods Shpts (bil 1996$) 1632 1775 1940 2120 1.7 1.8 lb dye & pigment/000$ nondurable 0.34 0.33 0.35 0.37 -- -- Dye & Organic Pigment (mil lb) 548 590SUMMARY 675 775 TABLE 1.5 2.7 $/lb 4.71 4.51 4.53 4.69 -0.9 0.1 Dye & Organic Pigment Demand 2580 2660 3060 3635 0.6 2.8 By Type: Dye 1585 1320 1305 1345 -3.6 -0.2 Organic Pigment 995 1340 1755 2290 6.1 5.5 By Market: Textiles 1105 870 865 877 -4.7 -0.1 Printing Inks 485 643 838 1095 5.8 5.4 Paints & Coatings 258 361 472 615 6.9 5.5 Plastics 189 238 302 397 4.7 4.9 Other 543 548 583 651 0.2 1.2 © Copyright by The Freedonia Group, Inc. Dyes & Organic Pigments #1439 Order form on last page 3 IV. DYES General ...............................................................................38 Table - Dye Demand by Type .......................................39 List of Contents, Chart - Dye Demand by Type, 2000.............................40 Fiber-Reactive .....................................................................40 Tables and Charts Table - Fiber-Reactive Dye Demand by Market .............42 Production & Foreign Trade ..........................................42 Table - Fiber-Reactive Dye Supply & Demand ..........44 Markets...........................................................................44 Suppliers .........................................................................45 I. EXECUTIVE SUMMARY Disperse Dyes .....................................................................46 Table - Disperse Dye Demand by Market 47 Summary Table ................................................................ 3 ...................... Production & Foreign Trade ..........................................47 II. MARKET ENVIRONMENT Table - Disperse Dye Supply & Demand ...................49 Markets 49 General ................................................................................. 4 ........................................................................... Suppliers 50 Macroeconomic Outlook ...................................................... 4 ......................................................................... Acid Dyes 51 Table - Macroeconomic Outlook ...................................... 6 ........................................................................... Table - Acid Dye Demand by Market 52 Consumer Spending............................................................. 6 ............................ Production & Foreign Trade 52 Table - Consumer Income & Spending Trends................ 8 .......................................... Table - Acid Dye Supply & Demand 53 Nondurable Goods Manufacturing Outlook ........................ 8 ......................... Markets 53 Table - Nondurable Goods Shipments ............................. 9 ........................................................................... Suppliers 54 Historical Market Trends ....................................................10 ......................................................................... Table - Dyes & Organic Pigments Vat Dyes ............................................................................55 Table - Vat Dye Demand by Type 56 Market Trends, 1990-2000 .........................................11 ................................. Production & Foreign Trade 56 Chart - Dyes & Organic Pigments Market Trends..........11 .......................................... Table - Vat Dye Supply & Demand 57 Technology & Competitive Products .................................12 ........................... Markets 58 Regulatory Environment ....................................................13 ........................................................................... Suppliers 58 Pollution Control Issues ..................................................14 ......................................................................... Direct Dyes 59 Consumer & Worker Safety Concerns ............................15 ........................................................................ Table - Direct Dye Demand by Market ..........................60 III. OVERVIEW Production & Foreign Trade ..........................................60 Table - Direct Dye Supply & Demand 61 General ...............................................................................17 ....................... Markets 62 Table - Dyes & Organic Pigment Demand.....................20 ........................................................................... Chart - Dye & Organic Pigment Demand Suppliers .........................................................................62 Solvent Dyes 63 by Type, 1990-2000 ...................................................20 ....................................................................... Pricing21 Table - Solvent Dye Demand by Market ........................64 Production & Foreign Trade 64 Dyes ...............................................................................22 .......................................... Table - Solvent Dye Supply & Demand 65 Table - Dye Pricing Trends.........................................23 ..................... Markets 65 Organic Pigments ...........................................................23 ........................................................................... Suppliers 66 Table - Organic Pigment Pricing Trends.....................24 ......................................................................... Basic Dyes 67 International Activity ..........................................................25 .........................................................................
Recommended publications
  • Wool Fiber Dyeing Machine Operator Course Code: TC WOOL 04
    Government of India Ministry of Textiles Textiles Committee Course Name: Wool Fiber Dyeing Machine Operator Course Code: TC WOOL 04 Version: 01 Developed by: Resource Support Agency (RSA), Textiles Committee, Ministry of Textiles, Government of India TABLE OF CONTENTS 1. Basic Textile Wet Processing Terms . 01 2. Brief of all Wet Processing Stages . 06 2.1. Grey Fabric Inspection . 07 2.2. Stitching . 07 2.3. Brushing . 07 2.4. Shearing/Cropping . 07 2.5. Singeing . 07 2.6. Desizing . 08 2.7. Scouring . 08 2.8. Bleaching . 09 2.10. Heat Setting . 09 2.11. Dyeing . 09 2.12. Printing . 11 2.13. Finishing . 11 2.14. Quality Assurance Laboratory . 12 2.15. Effluent Treatment Plant . 12 3. Introduction to Wool . 13 3.1. What is Wool? . 13 3.2. Types of Wool . 13 4. Composition of Wool . 15 4.1. Chemical Structure of Wool . 15 4.2. Morphological Structure of Wool . 16 5. Properties of Wool . 18 5.1. Physical properties of wool . 18 5.2. Chemical Properties of Wool . 19 5.3. End-Use Properties of Wool . 20 5.3.1 Uses and Application of Wool Fibres . 21 5.3.2 End Uses of Wool Fibres . 21 6. Wool Manufacturing Process . 22 Course: Wool Fiber Dyeing Machine Operator Developed by: Textiles Committee, Ministry of Textiles, Govt. of India 6.1. Flow Chart of Wool Processing . 22 6.2. Wool Manufacturing Processes . 22 6.2.1. Shearing . 23 6.2.2. Grading and Sorting . 23 6.2.3. Cleaning and Scouring . 24 6.2.4. Carding . 24 6.2.5.
    [Show full text]
  • Innovation Spotlight the Sustainable Revolution in Jeans Manufacture
    Innovation Spotlight ADVANCED DENIM The sustainable revolution Issue: Spring 2012 in jeans manufacture Innovative dyeing process spares the environment, offers greater color variety and higher quality Whether elegant or artificially aged, worn with a jacket or a T-shirt: jeans go well with almost anything. They are simultaneously a lifestyle statement, worldwide cult classic and long-selling fashion garment – with no end to the success story in sight. The statistics tell us that a US American has eight pairs of jeans, while a European comes a close second with five to six pairs. The immense number of almost two billion pairs of jeans are produced each year, claiming about 10 percent of the worldwide cotton harvest. The conventional indigo dyeing process, however, is environmentally polluting, and so Clariant has now developed, under its innovative Advanced Denim concept, a groundbreaking new dyeing process adapted to current needs that operates completely without indigo. It also needs much less water and energy, greatly reduces cotton waste and produces no effluents. Furthermore it offers a greater variety of colors, better color quality and new fashion effects. Experts are convinced: Advanced Denim will revolutionize jeans production. Denim is the name given to the typical, tough jeans material which is produced from cotton yarn and in the conventional process is dyed blue with indigo. In its natural agglomerated CLARIANT INTERNATIONAL LTD form, this dye isn’t soluble in water. The dye molecules first have to be separated before BUSINESS UNIT TEXTILE CHEMICALS Rothausstrasse 61 dyeing – this is done by reduction using the strong reducing agent sodium hydrosulfite.
    [Show full text]
  • Thin-Layer (Planar) Chromatography 2619
    III / DYES / Thin-Layer (Planar) Chromatography 2619 Thin-Layer (Planar) Chromatography P. E. Wall, Merck Limited, Poole, Dorset, UK that dyes are easily visualized on a chromatographic Copyright ^ 2000 Academic Press layer by their colour. Often slight differences in hue are more clearly seen on the layer than in solution and hence are easily distinguishable. It is therefore rarely Introduction necessary to employ detection reagents unless the area of interest is dye intermediates which may lack Synthetic dyes comprise a large group of organic, the conjugation needed in their molecular structure to organic salt and organometallic compounds which be coloured in visible light. Of course, there are number in the thousands. Most individual dyes are a large number of dyes which either exhibit Suores- assigned colour index (CI) numbers which helps to cence quenching in short wavelength ultraviolet (UV) identify structure and properties as well as identity light (254 nm) or naturally Suoresce by excitation in where a series of names have been used by the manu- long wavelength UV light (usually 366 nm). Where facturers for the same dye. Pigments are also listed separated dyes on the chromatographic layer do Su- and can be either organic or inorganic in nature. The oresce, the limit of sensitivity of detection is often in value of planar chromatography in the identiRcation the low nanogram or high picogram level. In the of dyes and separation of impurities and their quan- commercial environment, as dye quality can vary tiRcation is the main subject of this article. Synthetic from batch to batch and colour can be matched by dyes will be split into nine groups, the Rrst three being using different dyes, the planar chromatographic the major ones.
    [Show full text]
  • Imports of Benzenoid Chemicals and Products
    co p Z UNITED STATES TARIFF COMMISSION Washington IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS 1 9 7 3 United States General Imports of Intermediates, Dyes, Medicinals, Flavor and Perfume Materials, and Other Finished Benzenoid Products Entered in 1973 Under Schedule 4, Part 1, of The Tariff Schedules of the United States TC Publication 688 United States Tariff Commission September 1 9 7 4 UNITED STATES TARIFF COMMISSION Catherine Bedell Chairman Joseph 0. Parker Vice Chairman Will E. Leonard, Jr. George M. Moore Italo H. Ablondi Kenneth R. Mason Secretary to the Commission Please address all communications to UNITED STATES TARIFF COMMISSION Washington, D.C. 20436 ERRATA SHEET Imports of Benzenoid Chemicals And'Produets, 1973 P. 94-- The 1973 data ascribed to Acrylonitrile-butadiene- styrene (ABS) resins actually included 8,216,040 pounds of Methyl- methacrylate-butadiene-styrene (MBS) resins. The revised figure for ABS resins alone is 23,823,791 pounds. CONTENTS (Imports under TSUS, Schedule 4, Parts 1B and 1C) Table No. Page 1. Benzenoid intermediates: Summary of U.S. general imports entered under Part 1B, TSUS, by competitive status, 1973___ 6 2. Benzenoid intermediates: U.S. general imports entered under Part 1B, TSUS, by country of origin, 1973 and 1972___ 6 3. Benzenoid intermediates: U.S. general imports entered under Part 1B, TSUS, showing competitive status,. 1973, 8 4. Finished benzenoid products: Summary of U.S. general im- ports entered under Part 1C, TSUS, by competitive status, 1973- 28 S. Finished benzenoid products: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1973 and 1972--- 29 6.
    [Show full text]
  • USE and ASSESSMENT of MARKER DYES USED with HERBICIDES
    SERA TR 96-21-07-03b USE and ASSESSMENT OF MARKER DYES USED WITH HERBICIDES Submitted to: Leslie Rubin, COTR Animal and Plant Health Inspection Service (APHIS) Policy and Program Development Environmental Analysis and Documentation United States Department of Agriculture Suite 5A44, Unit 149 4700 River Road Riverdale, MD 20737 Task No. 10 USDA Order Nos. 43-3187-7-0408 USDA Contract No. 53-3187-5-12 Submitted by: Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., 42C Fayetteville, New York 13066-0950 Telephone: (315) 637-9560 Fax: (315) 637-0445 Internet: [email protected] December 21, 1997 USE and ASSESSMENT OF MARKER DYES USED WITH HERBICIDES Prepared by: Michelle Pepling1, Phillip H. Howard1, Patrick R. Durkin2, 1Syracuse Research Corporation 6225 Running Ridge Road North Syracuse, New York 13212-2509 2Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., Building 42C Fayetteville, New York 13066-0950 Submitted to: Leslie Rubin, COTR Animal and Plant Health Inspection Service (APHIS) Policy and Program Development Environmental Analysis and Documentation United States Department of Agriculture Suite 5A44, Unit 149 4700 River Road Riverdale, MD 20737 Task No. 10 USDA Order Nos. 43-3187-7-0408 USDA Contract No. 53-3187-5-12 Submitted by: Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., 42C Fayetteville, New York 13066-0950 Telephone: (315) 637-9560 Fax: (315) 637-0445 Internet: [email protected] December 21, 1997 TABLE OF CONTENTS TABLE OF CONTENTS .....................................................ii ACRONYMS, ABBREVIATIONS, AND SYMBOLS .............................. iii 1. INTRODUCTION .....................................................1 2. CURRENT PRACTICE .................................................2 3. GENERAL CONSIDERATIONS .........................................3 3.1. DEFINITIONS .................................................3 3.2. CLASSES OF DYES .............................................4 3.3.
    [Show full text]
  • United States Patent 19 11 Patent Number: 5,749,923 Olip Et Al
    USOO5749923A United States Patent 19 11 Patent Number: 5,749,923 Olip et al. 45) Date of Patent: May 12, 1998 54 METHOD FOR BLEACHING DENIM OTHER PUBLICATIONS TEXT LE MATERIAL Federal Law Gazette, No. 612, Sep. 24, 1992, "Limitation of Waste Water Emissions from Textile Finishing and Process 75 Inventors: Winzenz Olip. Schächtestrasse, ing Plants". Austria; Norbert Steiner. Upper Saddle Peter, M., et al. Grundlagen der Textilveredelung Basics of River, N.J. Textile Finishing, 13th ed., Deutscher Fachverlag, 1989, pp. 73 Assignee: Degussa Aktiengelschaft, Frankfurt am 80 to 81. (Month Unknown). Main, Germany Derwent Acc. No. 80-24863C, 1980 (month unknown). Derwent Acc. No. 86-268586, 1986 (Month Unknown). Derwent Acc. No. 89-155166, 1989 (Month Unknown). 21 Appl. No.: 651,785 Das, T.K., et al., “Thiourea Dioxide: A Powerful And Safe 22 Filed: May 24, 1996 Reducing Agent For Textile Applications”. Colourage, vol. 31, No. 26, 1984, pp. 15-20. (Month Unknown). Related U.S. Application Data Weiss, M., "Thiourea Dioxide: A Safe AlternativeTo Hydro sulfite Reduction”. Part 1. American Dyestuff Reporter; vol. 63 Continuation of Ser. No. 347,146, Nov. 22, 1994, Pat. No. 67. No. 8, Aug. 1978, pp. 35-38. 5,549,715. Weiss, M., "Thiourea Dioxide: A Safe Alternative to Hydro 30 Foreign Application Priority Data sulfite Reduction, Part II", American Dyestuff Reporter, vol. 67, No. 9, Sep. 1978, pp. 72-74. Nov. 23, 1993 AT Austria .............................. AT 2378/93 Primary Examiner-Alan Diamond (51 int. Cl. ... D06L 3/10 Attorney, Agent, or Firm-Spencer & Frank 52 U.S. Cl. ........................... 8/102; 8/107; 8/110; 8/111; 510/302; 510/303; 5101494; 510/367; 510/370; 57 ABSTRACT 510/470 Amethod for chlorine-free bleaching of denim textile mate 58 Field of Search ...............................
    [Show full text]
  • Chromatographic and Mass Spectral Analyses of Oligosaccharides and Indigo Dye Extracted from Cotton Textiles with Manova and Ano
    University of Central Florida STARS Electronic Theses and Dissertations, 2004-2019 2008 Chromatographic And Mass Spectral Analyses Of Oligosaccharides And Indigo Dye Extracted From Cotton Textiles With Manova And Ano Jessica Frisch University of Central Florida Part of the Chemistry Commons, and the Forensic Science and Technology Commons Find similar works at: https://stars.library.ucf.edu/etd University of Central Florida Libraries http://library.ucf.edu This Masters Thesis (Open Access) is brought to you for free and open access by STARS. It has been accepted for inclusion in Electronic Theses and Dissertations, 2004-2019 by an authorized administrator of STARS. For more information, please contact [email protected]. STARS Citation Frisch, Jessica, "Chromatographic And Mass Spectral Analyses Of Oligosaccharides And Indigo Dye Extracted From Cotton Textiles With Manova And Ano" (2008). Electronic Theses and Dissertations, 2004-2019. 3625. https://stars.library.ucf.edu/etd/3625 CHROMATOGRAPHIC AND MASS SPECTRAL ANALYSES OF OLIGOSACCHARIDES AND INDIGO DYE EXTRACTED FROM COTTON TEXTILES WITH MANOVA AND ANOVA STATISTICAL DATA ANALYSES by JESSICA LYNNE FRISCH B.S. University of Central Florida, 2005 A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science in the Department of Chemistry in the College of Sciences at the University of Central Florida Orlando, Florida Spring Term 2008 © 2008 Jessica Lynne Frisch ii ABSTRACT Research was conducted on thirteen 100% cotton denim samples using an acid wash, established by Murray, to extract oligosaccharides from the cellulosic material. The oligosaccharide ion + + + groups ([M+H] , [M+NH4] , and [M-OH] ) for molecules with degrees of polymerization between two and seven (DP2-DP7) were analyzed using liquid chromatography coupled to mass spectrometry with an electrospray ionization interface (LC-ESI-MS).
    [Show full text]
  • What Is Sera® Fil SBS Based On?
    REVISTADE ORGANO OFICIAL DE LA ASOCIACIÓN ESPAÑOLA DE QUÍMICOS Y COLORISTAS TEXTILES Nº214 / NOVIEMBRE 2015 www.aeqct.org Miembro de la FIAQCT Miembro Adherido a la FLAQT Con la colaboración de TEXFOR Les esperamos en / NOVIEMBRE 2015 Nº214 - AEQCT SUMALLA S.L. Plaza Joaquin Folguera, 5, Entlo. 6ª | |08022 - Barcelona - España Tel: (+34) 93 2 09 99 57 | Fax: (+34) 93 2 02 03 90 [email protected] www.gruposumalla.com Denim 2015_Revista_FullPage 20.05.15 11:29 Seite 1 Competence in Denim Finishing Excellence in Dyeing & Finishing ITMA Hall 10 / E101 Aguilar & Pineda Asociados, S.L. Tel.: 0034-93-4876667 C/Mallorca, 279, principal 3° Fax: 0034-93-4880375 08037 Barcelona [email protected] A. Monforts Textilmaschinen GmbH & Co. KG Germany | A Member of CHTC Fong’s Industries www.monforts.com Sumario Revista de Química e Industria Textil • Núm. 214 • Noviembre 2015 5 Editorial 7 Determinación rápida de la degradación de lanas y pelos. F. Marsal 12 Estudio de la capacidad de desintegración de agrotextiles obtenidos a partir de fibras biodegra- dables. M. Ferrándiz, L.Capablanca, D.García, E. Bou- Belda, O. Gutiérrez 20 Los materiales augéticos y su potencial en el sector textil. E. Bou-Belda, P. Díaz-García, I. Montava, M. Bonet-Aracil 27 Denim Book by Archroma. Capítulos 5 y 6. La Revista de Química e Industria Textil con cuatro números anuales, pretende informar sobre las 44 ¿Cómo resolvería Sherlock Holmes los problemas novedades tanto nacionales como internacionales relacionadas con el sector textil. Se distribuye de en la empresal. forma gratuita a los asociados de la AEQCT.
    [Show full text]
  • Lexique-Anglais-Francais.Pdf
    Description Terme anglais Terme français Description française anglaise Laine entière, pure, non 100% wool Only wool, pure. laine 100% mélangée. 4 box loom métier à 4 boîtes métier à tisser à 4-box loom quatre boîtes above the knee au dessus du genou Action d’user. Enlèvement The act of polishing, abrasion abrasion par raclage superficiel de grinding. certains tissus. The ability of a fabric to withstand loss of appearance, utility, La solidité d’un tissu, abrasion résistance à pile or surface through comment il conserve ou perd resistance l’abrasion the destructive action ses propriétés face à l’usure. of surface wear and rubbing. A mechanical instrument that tests a Instrument pour mesurer la fabric’s resistance to abrasion tester abrasimètre résistance à l’usure et au the destructive actions temps des tissus. of surface wear and rubbing. coton hydrophile absorbant cotton (ouate) Qui absorbe les liquides, les absorbent Able to absorb. absorbant gaz, les radiations. absorbent cotton- ouate hydrophile wool This fabric don’t permit Tissu qui n’est pas absorbent fabric the passage of a fluid tissu absorbant imperméable, qui absorbe through its substance. les liquides. Qui ne représente pas le monde sensible (réel ou Having only intrinsic imaginaire); qui utilise la abstract form with little or no abstrait (dessin) matière, la ligne et la pictural representation. couleur pour elles-mêmes. Dessin sans référence à la réalité concrète. abstract design dessin abstrait Motif sans référence à la Motif without pictural abstract motif motif abstrait réalité concrète. Motif non- representation. figuratif. Substance qui accélère une réaction. Substance chimique Something that utilisée pour augmenter la accelerant accélérateur accelerate a reaction.
    [Show full text]
  • Institute of Chemistry University of the Punjab, Lahore
    SYNTHESIS OF ECO-FRIENDLY DYES A THESIS SUBMITTED TO THE UNIVERSITY OF THE PUNJAB FOR THE AWARD OF DEGREE OF DOCTOR OF PHILOSOPHY IN CHEMISTRY Session 2010 SUBMITTED BY: RANA AMJAD AYUB BHATTI RESEARCH SUPERVISOR PROF. DR. MUNAWAR ALI MUNAWAR INSTITUTE OF CHEMISTRY UNIVERSITY OF THE PUNJAB, LAHORE. DEDICATDEDICATEDEDEDED To My Loving Family Prof. Munawar Ali Munawar Prof. Robert M. Christie Mr. Shehzad ...H.HHHassanassanassan.. Pervaiz, The prayers and guidance of all helped and enabled me to accomplish this project. Declaration I hereby declare that the work described in this thesis was carried out by me under the supervision of Prof. Dr. Munawar Ali Munawar at the Institute of Chemistry, University of the Punjab, Lahore. I also hereby declare that the substance of this thesis has neither been submitted elsewhere for any other degree. I further declare that the thesis embodies the results of my own research work or advanced studies and that it has been composed by my self. Where appropriate, I have made acknowledgement of the work of others. Rana Amjad Ayub Bhatti APPROVAL CERTIFICATE I hereby certify that Mr Rana Amjad Ayub Bhatti s/o M. Ayub Bhatti has conducted research work under my supervision, has fulfilled the condition and is qualified to submit the thesis entitled “Synthesis of Eco-friendly Dyes” in application for the degree of Doctor of Philosophy. Dr. Munawar Ali Munawar (Supervisor) Professor of Organic Chemistry. Institute of Chemistry, University of The Punjab. Lahore, Pakistan. ACKNOWLEDGEMENT All praises to the Al-Mighty “Allah ” who provided us with knowledge, sight to observe and brain to think.
    [Show full text]
  • The Use of Glucose As Ecological Reducing Agent for Sulphur Dyes: Optimization of Experimental Conditions
    European Scientific Journal June 2014 edition vol.10, No.18 ISSN: 1857 – 7881 (Print) e - ISSN 1857- 7431 THE USE OF GLUCOSE AS ECOLOGICAL REDUCING AGENT FOR SULPHUR DYES: OPTIMIZATION OF EXPERIMENTAL CONDITIONS Romdhani Zouhaier Dhouib Sofiène Sakli Faouzi Laboratory of Textile Research, ISET of Ksar, Hellal, Monastir, Tunisia Abstract At the present time, dyeing of textile material requires the use of various auxiliaries. These used agents have adverse effects on the environment. In general, for the dyeing with sulphur dyes, a reducing agent is used to transform the dye molecule to a water soluble leuco form that can diffuse into the fibre. In this study, three reducing agents were used : the sodium sulphide, sodium dithionite and glucose as an environmentally friendly reducer. To compare their effect on the reduction of the sullphur dyestuff, the redox potential, pH and the colour yield (K/S) were measured according to the concentration of reducing agent and caustic soda concentration. Results of leuco sulphur black B reduction by the different reducing agents were evaluated by measuring the colour yield (K/S) and the brightness variation after the washing process. The obtained results showed that glucose can offer some scientifically results similar to those done with sodium sulphide which can give for the reduction of sulphur dyestuff Keywords: Sulphur dye, Dyeing, Reduction, Reducing Agent, Glucose Introduction Cellulosic substrates especially cotton, rayon, and paper, are very hydrophilic and, therefore, require hydrophilic soluble dyes for their coloration from a dye bath. Current dyes designed for cellulosic polymers are direct, vat, sulfur, and reactive dyes. Sulphur dyes are one of the less costs of all dye classes used on cellulosic fibres and their blends (Senior & Clarke, 1986).
    [Show full text]
  • ABSTRACT YI, DING. a Comparison of Mordant and Natural Dyes In
    ABSTRACT YI, DING. A Comparison of Mordant and Natural Dyes in Dyeing Cotton Fabrics. (Under the direction of Dr. Harold S. Freeman and Dr. Peter J. Hauser). Mordant dyes constitute a class of synthetic colorants that are applied to textile fibers mainly through the aid of transition metal ions such as Cr3+. The resultant dye-metal complexes are key to the fastness properties produced on wool. In the same way, most natural dyes require the use of a mordant to have coloring power on textiles such as cotton. Unlike mordant dyes on wool, the fastness properties of natural dyes on cotton are generally quite low. Consequently, they have largely been replaced by synthetic dyes that are more cost effective, brighter, and more durable under end-use applications. Interest in green technologies has led to renewed consideration of natural dyes for textile coloration because they are biodegradable and do not involve manufacturing processes requiring genotoxic aromatic amines. Interestingly, such a shift would bring dyeing technology full circle to a family of colorants lacking the vibrancy and technical properties of most synthetic dyes. However, similarities between the dyeing method for mordant and natural dyes brought to mind the potential for reducing the level of synthetic dyes used commercially by combining suitable dyes from these two classes for dyeing textiles. This thesis research was devoted to stage 1 of this idea, namely the evaluation of mordant dyes as colorants for cotton fabric. With this in mind, dyes such as Mordant Blue 13, Mordant Brown 40, Mordant Orange 6 and Mordant Yellow 8 were applied to cotton using various dyeing times, temperatures, dye bath concentrations and mordants.
    [Show full text]