Nautile DG SPECIMEN

PEEL Nautile DG PCS No. 04540 HERE A water-dispersible granule containing 5% w/w cymoxanil and 68% mancozeb for use against potato blight. For use as an agricultural fungicide. FOR PROFESSIONAL USE ONLY.

SAFETY INFORMATION

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WARNING May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. date Wear protective gloves/protective clothing. Use personal protective equipment as required. IF ON SKIN: Wash with soap and water. IF exposed or concerned: Get medical advice/attention. to IF skin irritation or a rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/container to SPECIMENa licensed hazardous waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste. To avoid risks to human health and the environment, comply with the instructions for use. UN 3082 2016 PCS No. 04540 Do not contaminate water with the product or its container. (Do not clean application equipment near surface water / Avoid contamination via drains from farmyards and roads). To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. BATCH NO. & EXPIRY DATE: SHAKE WELL BEFORE USE. see packaging Marketing company and Authorisation holder: UPL Europe Ltd CONTENTS: The Centre, Birchwood Park, Warrington, WA3 6YN Telephone: 01925 819999 Fax: 01925 817425 For 24 hour emergency information contact: CARECHEM24 : +44 (0) 1235 239670 10 KG A2.0 NAUTILE DG IRE 060516 PCS 04540 NAU/IE/10kg/F/0516/UPL May 2016 DIRECTIONS FOR USE Spray tank clean-out SAFETY DATA SHEET Hazard statements Inhalation: Move to fresh air. Immediately after application, completely drain spray equipment. H317 - May cause an allergic skin reaction 4.2 Most Important Symptoms and Effects, Both Acute and Delayed Crop Max single Max. no. of Max. total Latest time of Thoroughly rinse sprayer and flush the hoses, boom nozzles with clean water. 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child No information available. dose applications dose application H410 - Very toxic to aquatic life with long lasting effects 4.3 Indication of immediate medical attention and special treatment needed Loosen and physically remove visible deposits. 1.1 Identification of the product Precautionary Statements - EU (§28, 1272/2008) Treat symptomatically. Potatoes 2.3 kg/ha 6 per crop 13.8 kg/ha 14 days Remove and clean nozzles, screens and strainers. Product code: FAZ02 P201 - Obtain special instructions before use (seed and ware) before harvest Flush the entire system with clean water. Product Description: NAUTILE DG P202 - Do not handle until all safety precautions have been read and understood 5. FIRE-FIGHTING MEASURES Take all necessary safety precautions when cleaning equipment. Synonyms: Cymoxanil/Mancozeb 5/68% WG P280 - Wear eye protection/face protection Disease control: Do not clean near wells or water sources. Pure substance/preparation: Preparation P281 - Use personal protective equipment as required 5.1 Extinguishing media Successful control of potato blight requires a season-long disease prevention policy that integrates cultural measures such as the Dispose of waste water in accordance with local regulations. 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against P302 + P352 - IF ON SKIN: Wash with plenty of water and soap Suitable extinguishing media: Use water spray or fog; do not use straight streams. Recommended use: Fungicide P308 + P313 - IF exposed or concerned: Get medical advice/attention Use water only in case of important fire. destruction of ground keepers and potato dumps and commencing the spray before blight infection. Uses advised against: Non labeled activities P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire. FIRST AID INFORMATION 1.3 Details of the Supplier of the Safety Data Sheet P363 - Wash contaminated clothing before reuse 5.2 Special hazards arising from the substance or mixture Nautile DG contains the active ingredient cymoxanil which is locally systemic, and mancozeb which has a contact activity. Obtain special instructions before use. Supplier: UPL Europe Ltd P391 - Collect spillage Special Hazard: Thermal decomposition giving flammable and toxic products. Do not handle until all safety precautions have been read and understood. The Centre P501 - Dispose of contents/ container in accordance with national regulation Carbon disulphide. The combination of two active ingredients will also help to reduce the selection and build-up of resistance strains of fungi. Wear protective gloves / protective clothing. Birchwood Park EU Specific Hazard Statements Hydrogen sulphide. Potato fungicides may not give complete protection of blight when the incidence of disease is severe. Use personal protective equipment as required. Warrington EUH208 - May produce an allergic reaction Hydrogen cyanide (hydrocyanic acid). IF ON SKIN: Wash with soap and water. WA3 6YN EUH401 - To avoid risks to human health and the environment, comply with the instructions for use Nitrogen oxides (NOx). IF exposed or concerned: Get medical advice/attention. Cheshire, UK 2.3 Other Hazards Carbon oxides. Varieties: Tel. : +44 (0) 1925 819999 - No information available 5.3 Advice for Firefighters All varieties of early and maincrop potatoes may be treated. On crops grown for processing consult your processor before use. IF skin irritation or a rash occurs: Get medical advice/attention. Fax : +44 (0) 1925 856075 Use personal protective equipment. Wash contaminated clothing before reuse. E-mail address: [email protected] 3. COMPOSITION / INFORMATION ON INGREDIENTS Avoid runoff to waterways and sewers. Timing: 1.4 Emergency Telephone Number Timing of spray applications should take into account the normal prevalence of the disease in the area and conditions of the Operator Protection Emergency telephone number: (CARECHEM 24): +44 (0) 1235 239670 3.2. Mixtures 6. ACCIDENTAL RELEASE MEASURES particular season. The first spray should be applied as soon as there is a risk of blight infection or an official warning is issued. Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal United Kingdom: NHS no. 111 protective equipment: Chemical name EC No CAS-No Weight % Classification EU - GHS Substance REACH No. 6.1 Personal precautions, protective equipment and emergency procedures In the absence of warning, spraying should begin just before the crop meets along the rows. 2. HAZARDS IDENTIFICATION (Dir.67/548) Classification Avoid contact with the skin and the eyes. Wear protective gloves/clothing and eye/face protection. Wear suitable protective gloves and suitable respiratory protective equipment* when handling the product. *Disposable filtering Mancozeb - 8018-01-7 60 - 70 - Skin Sens. 1 no data Applications should be repeated every 10-14 day intervals depending on the prevalence of the disease and on whether the 2.1 Classification of the mixture (H317) available 6.2 Environmental Precautions conditions are favorable for infection. A 7 day spray interval may be used under exceptional circumstances e.g. when the potato face piece respirator to at least EN149 FFP3 or equivalent. R-code(s): Repr. cat.3;R63 - Xi;R36/38 - Xn;R43 - N;R50/53 Repr. 2 Do not flush into surface water or sanitary sewer system. blight risk is high and rain is forecast at the time that the next 10 day spray is due. The longer interval is recommended under dry Classification according to Regulation (EC) No. 1272/2008 [CLP] (H361d) Do not allow material to contaminate ground water system. conditions. Irrigation of crops increases the risk of blight and crops should always be sprayed with NAUTILE DG as soon as possible Wear suitable protective gloves when handling contaminated surfaces. Human Health Aquatic Acute 1 6.3 Methods and materials for containment and cleaning up Skin sensitization Category 1 - (H317) date (H400) Sweep up and shovel into suitable containers for disposal. after irrigation, subject to the minimum spray interval. Reproductive toxicity Category 2 - (H361fd) However, if engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal Environment Cymoxanil 261-043-0 57966-95-7 5 - 10 - STOT RE 2 no data 7. HANDLING AND STORAGE Water volumes: or higher standard of protection. Acute aquatic toxicity Category 1 - (H400) (H373) available Apply NAUTILE DG in 200 to 600 l/ha, the higher volumes may be used in thick or dense crops to improve coverage. Chronic aquatic toxicity Category 1 - (H410) Skin Sens. 1 7.1 Precautions for Safe Handling CONDITIONS OF SUPPLY For the full text of the H-Statements mentioned in this Section, see Sectionto 16 (H317) Handling RESTRICTIONS All goods supplied by us are of high grade and we believe them to be suitable but, as we cannot exercise control over their 2.2 Label elements Repr. 2 Provide appropriate exhaust ventilation at places where dust is formed. R -phrase(s) (H361fd) Avoid dust formation in confined areas. To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. storage, handling, mixing or use, or the weather conditions before, during and after application which may affect the performance Acute Tox. 4 of the goods, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are R43 - May cause sensitization by skin contact Avoid contact with skin and eyes. R63 - Possible risk of harm to the unborn child (H302) Hygiene Measures Directions for the safe disposal of the plant protection product and of the packaging excluded, and no responsibility will be accepted by us or re-sellers for any failure in performance, damage or injury whatsoever R36/38 - Irritating to eyesSPECIMEN and skin Aquatic Acute 1 Use only outdoors or in a well-ventilated area. Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for triple rinsed empty arising from their storage, handling, application or use. Our staff or agents cannot vary these conditions whether or not they R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment (H400) 7.2 Conditions for safe storage, including any incompatibilities containers which can be disposed of as non-hazardous waste. supervise or assist in the use of such goods. S -phrase(s) Aquatic Chronic Maintain air gap between stacks/pallets. S35 - This material and its container must be disposed of in a safe way 1 (H410) Decomposes by reaction with strong acids. Resistance management S57 - Use appropriate container to avoid environmental contamination Keep away from food, drink and animal feeding stuffs. S24/25 - Avoid contact with skin and eyes For the full text of the R phrases mentioned in this Section, see Section 16 7.3 Specific end uses When fungicides with the same mode of action are used repeatedly over several years in the same field, naturally occurring less 2016 For the full text of the H-Statements mentioned in this Section, see Section 16 S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection No information available. sensitive strains may survive, propagate and become dominant in that field. It is therefore advised that spray programs should Labelling according Regulation (EC) No 1272/2008 (CLP) include fungicides with differing modes of action. 4. FIRST AID MEASURES 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 4.1 Description of first-aid measures 8.1 Control Parameters FOLLOWING CROPS General advice: Show this safety data sheet to the doctor in attendance. Exposure Limits: Apply technical measures to comply with the occupational exposure limits. Any crop may be sown after a crop treated with NAUTILE DG. Eye contact: Wash off with plenty of water. Rinse thoroughly with plenty of water, also under the eyelids. Chemical name Eu United Kingdom France Spain Germany

MIXING AND SPRAYING If eye irritation persists, consult a specialist. 3 Spraying equipment should be thoroughly cleaned before spraying. NAUTILE DG mixes easily with water and should be added directly Skin contact: Wash off immediately with soap and plenty of water. Mancozeb 5 mg/m Remove and wash contaminated clothing before re-use. to the spray tank during filling. Wash out container and add washing to the spray tank. Continue agitation until spraying is complete. Derived No Effect Level (DNEL): No information available Signal word: WARNING If skin irritation persists, call a physician. Ingestion: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. 1 2 3 4 5 Predicted No Effect Concentration No information available Hydrogen sulfide. 13. DISPOSAL CONSIDERATIONS 15.2 Chemical safety assessment (PNEC): Oxides of sulfur. A chemical safety assessment has not been carried out. 8.2 Exposure Controls Carbon disulfide. 13.1 Waste Treatment Methods Engineering controls: Ensure adequate ventilation, especially in confined areas. Ethylenethiourea. Waste from Residues / Unused Dispose of in accordance with local regulations. 16. OTHER INFORMATION PCS No. 04540 Personal Protective Equipment Nautile DG Products: Eye protection: Safety glasses with side-shields. 11. TOXICOLOGICAL INFORMATION Contaminated packaging: Empty containers should be taken for local recycling, recovery or waste disposal. Full text of H-Statements referred to under sections 2 and 3 A water-dispersible granule containing 5% w/w cymoxanil and 68% mancozeb for use against potato blight. Skin protection: Lightweight protective clothing. Boots. Apron. EWC waste disposal No: 020108 - agrochemical waste containing dangerous substances. H302 - Harmful if swallowed For use as an agricultural fungicide. Hand protection: Protective gloves. 11.1 Information on Toxicological Effects Other information: According to the European Waste Catalogue, Waste Codes are not product specific, but application H317 - May cause an allergic skin reaction FOR PROFESSIONAL USE ONLY. Respiratory protection: Effective dust mask Acute toxicity specific. Waste codes should be assigned by the user based on the application for which the H361d - Suspected of damaging the unborn child When workers are facing concentrations above the exposure limit they must use appropriate Local effects product was used. H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child certified respirators Inhalation: . H373 - May cause damage to organs through prolonged or repeated exposure SAFETY INFORMATION Environmental exposure controls: Local authorities should be advised if significant spillages cannot be contained. Eye contact: Irritating to eyes. (rabbit). 14. TRANSPORT INFORMATION H400 - Very toxic to aquatic life Do not allow material to contaminate ground water system. Skin contact: Irritating to skin. H410 - Very toxic to aquatic life with long lasting effects Prevent product from entering drains. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. ADR/RID H411 - Toxic to aquatic life with long lasting effects Ingestion: . 14.1 UN-No: UN3077 Revision date: 12-Dec-2014 9. PHYSICAL AND CHEMICAL PROPERTIES LD50 Oral: > 2000 (rat) mg/kg 14.2 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. ( (Mancozeb) (Cymoxanil) Mixture ) Revision note: Sections updated: 1.4 Emergency Telephone Number LD50 Dermal: > 2000 (rat) mg/kg 14.3 Hazard class: 9 This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 9.1 Information on basic physical and chemical properties LC50 Inhalation: > 5 mg/l 14.4 Packing group: III Disclaimer Appearance: Olive to brown-yellow Chronic toxicity 14.5 Environmental Hazard: DANGEROUS FOR THE ENVIRONMENT The information contained is based on our knowledge of the product at the date of publishing. Physical state: solid, granular Skin Corrosion/Irritation: May cause irritation. 14.6 Special Provisions: 274, 335, 375, 601 - It applies to the PRODUCT AS SUCH. In case of formulation or mixture, make sure that a new danger will not appear. Users are advised of possible Odor: Woody Eye damage/irritation: MAY CAUSE EYE IRRITATION. Tunnel restriction code: (E) additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and duplicated for Property VALUES Remarks/Method Sensitization: Skin Sensitization. IMDG/IMO prevention and Safety purposes. pH: approx 6.5 CIPAC MT 75 (1% aq) Carcinogenic effects: No information available. 14.1 UN-No: UN3077 For rates and use recommendations, refer to the information displayed on the packaging. Melting point/freezing point: No information available Decomposes without melting. Mutagenic effects: No information available. 14.2 Proper shipping name: Environmentally hazardous substances, solid n.o.s. ( (Mancozeb) , (Cymoxanil) , Mixture ) It is the responsability of the handlers of the product to pass on this safety data sheet to any subsequent persons who will come into contact Boiling Point/Range: No information available Reproductive effects: No information available. 14.3 Hazard class: 9 with the product. WARNING Flash Point: No information available STOT - Single Exposure: No information available. 14.4 Packing group: III May cause an allergic skin reaction. Flammability (solid, gas): Not highly flammable CE A.10 STOT - repeated exposure: No information available. 14.5 Environmental Hazard: Marine pollutant Bulk density: 0.7 kg/l Tap density / Pour density 0.68kg/l / 0.72 kg Suspected of damaging fertility or the unborn child. 14.6 Special Provisions: 274, 335, 966, 967, 969 May cause damage to organs through prolonged or repeated exposure. Water solubility: Dispersible 12. ECOLOGICAL INFORMATION IATA/ICAO Solubility in Other Solvents: Practically insoluble 14.1 UN-No: UN3077 Very toxic to aquatic life with long lasting effects. Partition coefficient: n-octanol/water: No information available 12.1 Toxicity 14.2 Proper shipping name: Environmentally hazardous substances, solid n.o.s. ( (Mancozeb) , (Cymoxanil) , Mixture ) Autoignition temperature: 165 °C CE A.16 EC50/72h/algae = 0.100 (mg/l) 14.3 Hazard class: 9 Obtain special instructions before use. Decomposition temperature: No information available LC50/48h/daphnia = 1.68 (mg/l) 14.4 Packing group: III date Do not handle until all safety precautions have been read and understood. Viscosity: No information available LC50/fish/96 h = 0.41 (mg/l) 14.5 Environmental Hazard: DANGEROUS FOR THE ENVIRONMENT Wear protective gloves/protective clothing. Oxidizing properties: Non oxidizing (according to A17 test) Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 14.6 Special Provisions: A97, A158, A179, A197 Use personal protective equipment as required. Explosive properties: According to the chemical structure no explosion reaction is expected. 12.2 Persistence and Degradability IF ON SKIN: Wash with soap and water. 9.2 Other information No information available. 15. REGULATORY INFORMATION VOC Content: Not applicable 12.3 Bioaccumulative Potential to IF exposed or concerned: Get medical advice/attention. IF skin irritation or a rash occurs: Get medical advice/attention. No information available. 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture 10. STABILITY AND REACTIVITY Registration n°: PCS number 04540 Wash contaminated clothing before reuse. Chemical name Log Pow - To avoid risks to man and the environment, comply with the instructions for use 10.1 Reactivity Mancozeb 1.38 International Inventories Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for triple rinsed empty None under normal use. TSCA: SPECIMENComplies containers which can be disposed of as non-hazardous waste. Cymoxanil log Pow = 0.59-0.67 @ 20°C 10.2 Chemical stability EINECS/ELINCS: Complies To avoid risks to human health and the environment, comply with the instructions for use. Stable under normal conditions. 12.4 Mobility in Soil DSL/NDSL: Complies 10.3 Possibility of hazardous reactions No information available. PICCS: Complies UN 3082 PCS No. 04540 None under normal processing. 12.5 Results of PBT and vPvB Assessment ENCS: Complies 10.4 Conditions to avoid No information available. China: - 2016 Do not contaminate water with the product or its container. Do not store near strong acids. 12.6 Other Adverse Effects AICS: Complies Do not expose to extreme temperatures. No information available. KECL: Complies (Do not clean application equipment near surface water / Avoid contamination via drains from farmyards and roads). 10.5 Incompatible Materials Legend To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. Alkaline. Chemical name EU - Endocrine Disrupters EU - Endocrine Disruptors - TSCA - United States Toxic Substances Control Act Section 8(b) Inventory. BATCH NO. & EXPIRY DATE: Strong acids. Candidate List Evaluated Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List. SHAKE WELL BEFORE USE. see packaging Strong oxidizing agents Mancozeb Group III Chemical EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances. Quaternary ammonium salts. PICCS - Philippines Inventory of Chemicals and Chemical Substances. Marketing company and Authorisation holder: Sequestring agents. ENCS - Japan Existing and New Chemical Substances. UPL Europe Ltd CONTENTS: 10.6 Hazardous Decomposition Products IECSC - China Inventory of Existing Chemical Substances. The Centre, Birchwood Park, Warrington, WA3 6YN Hydrogen cyanide. AICS - Australian Inventory of Chemical Substances. Telephone: 01925 819999 Fax: 01925 817425 Nitrogen oxides (NOx). KECL - Korean Existing and Evaluated Chemical Substances. For 24 hour emergency information contact: CARECHEM24 : +44 (0) 1235 239670 10 KG

Carbon oxides. A2.0 NAUTILE DG IRE 060516 PCS 04540 NAU/IE/10kg/F/0516/UPL May 2016 6 7 8 9