Safety Reports Series No.78
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T1-Kovler-Purification-Of-Phosphogypsum-Israel.Pdf
Prof. Konstantin Kovler is Head of the Department “Building Materials, Performance and Technology”, National Building Research Institute (NBRI), Faculty of Civil & Environmental Engineering, Technion - Israel Institute of Technology. His research focuses on recycling industrial by-products in construction, PURIFICATION OF PHOSPHOGYPSUM FROM high-performance cementitious materials, radioactivity of building materials, and radon mitigation. Fellow of RILEM, Editor of Materials & Structures, Cement & Concrete Composites. Chairs committees “Ecological Aspects of Construction”, “Radioactivity of Building Products,” Israeli Standards Institution. 226Ra AND HEAVY METALS FOR ITS FURTHER Director of Technion Recycling Initiative. UTILIZATION IN CONSTRUCTION: Eng. Boris Dashevsky is Research Fellow, the Department “Building Materials, Performance and TECHNOLOGICAL UTOPIA OR REALITY? Technology”, NBRI. His research interests are in technologies of manufacturing building materials using mechano-chemical activation, recycling industrial by-products (phosphogypsum, coal ash, copper slag, carbonate rock waste of dimension stone factories and quarries, construction and demolition waste – including asbestos-cement, acid tar, sulfur- and sulfonate-containing wastes) in construction. Konstantin Kovler1 , Boris Dashevsky1, David S. Kosson2 1National Building Research Institute – Prof. David S. Kosson is Cornelius Vanderbilt Professor of Engineering at Vanderbilt University, Nashville, Tennessee, US, where he has appointments as Professor of Civil and Environmental -
Safety Data Sheet TSP - TRISODIUM PHOSPHATE
Safety Data Sheet TSP - TRISODIUM PHOSPHATE Date of Revision: 2/11/2015 Section 1 – Chemical Product and Company Identification Product/Chemical Name: Trisodium Phosphate dodecahydrate Chemical Formula: Na3PO4*12H2O CAS Number: 10101-89-0 Other Designations: TSP; trisodium orthophosphate; tribasic; tertiary sodium phosphate; trisodium phosphate Derivation: Prepared by combining proper proportions of phosphoric acid and soda to form disodium phosphate, then adding a caustic soda Supplied by: PRO Chemical & Dye 126 Shove Street Fall River, MA 02724 Emergency Telephone Numbers: 800-255-3924 ChemTel. (United States) + 1 01 813-248-0585 (Outside the United States) 1. Section 2 - Hazards Identification HMIS ***** Emergency Overview ***** H 3 MAY CAUSE EYE INJURY. CAUSES SKIN IRRITATlON. MAYBE HARMFUL IF SWALLOWED. F 0 Potential Health Effects R 0 PPE Primary Entry Routes: Inhalation, ingestion or skin contact. Sec. 8 Target Organs: Skin, digestive tract. HAZARDS IDENTIFICATION Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA DCS) Skin corrosion (Category I B). H314 Serious eye damage (Category I). H318 GHS Label elements, including precautionary statements Pictogram Signal word Danger Hazard statement(s) H314 Causes severe skin burns and eye damage. Precautionary Statement(s) P260 Do not breathe dust or mist. P264 Wash skin thoroughly after handling. P280 Wear protective gloves protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: rinse mouth. DO NOT induce vomiting. P303 + P36l + P353 IF ON SKIN (or hair): Remove. Take off immediately all contaminated clothing. Rinse skin with water / shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. -
PHOSBRITE® 156 Page: 1 / 8
SAFETY DATA SHEET PHOSBRITE® 156 Page: 1 / 8 Date: 24/08/2004 Version: 1 Cancels and replaces version: 1 Product and company identification. PRODUCT NAME : PHOSBRITE® 156 Use : Treating the surfaces of metals. (For further information, refer to the product technical data sheet). SUPPLIER : Manufacturer : Name : Thermphos International B.V. Address : Haven 9890 4389 PD Vlissingen P.O.Box 406 4380 AK Vlissingen The Netherlands Telephone number : ++31(0)113 689 500 Telefax number : ++31(0)113 689 501. 2 Composition / information on ingredients >> PREPARATION Components contributing to the : Phosphoric acid (CAS : 7664-38-2) : 50 - 90% - EC Classification hazard : C - R34 Sulphuric acid (CAS : 7664-93-9) : 10 - 50 %. - EC Classification : C - R 35 3 Hazards identification MOST IMPORTANT HAZARDS Adverse human health effects : Corrosive. Causes severe burns. Severely irritating to respiratory system and eyes. Risk of serious damage to eyes. Extremely irritating to the digestive tract. Risk of burns. Environmental effects : If the product is not neutralised, it may have harmful effects on the aquatic environment. Physical and chemical hazards - Fire or explosion : Certain reactions may cause a fire or an explosion. SAFETY DATA SHEET PHOSBRITE® 156 Page: 2/8 Date: 24/08/2004 Version: 1 Cancels and replaces version: - Further hazards : Violent reactions may occur on contact with certain chemicals. (Refer to the list of incompatible materials section 10: "Stability-Reactivity"). Very corrosive to metals. Releases hydrogen which forms explosive mixtures in air. On heating : corrosive vapours are released. Specific hazards : According to EC criteria, this product is classified as : - CORROSIVE. 4 First-aid measures Inhalation : Move the affected person away from the contaminated area and into the fresh air. -
Phosphate Recycling in the Phosphorus Industry
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Wageningen University & Research Publications Phosphorus Research Bulletin Vol. 15 (2004) p. 47-51 Phosphate Recycling in the Phosphorus Industry W.J. SCHIPPER*1, A. KLAPWIJK2, B. POTJER3, W.H. RULKENS2, B.G. TEMMINK2, F.D.G. KIESTRA4 and A.C.M. LIJMBACH1 *corresponding author 1 Thermphos International B.V., PO Box 406, 4380 AK Vlissingen, The Netherlands; [email protected] 2 Wageningen University, Subdepartment Environmental Technology, P.O. Box 8129, 6700 EV Wageningen, the Netherlands 3 CE (solutions for environment, economy and technology), Oude Delft 180, 2611 HH Delft, The Netherlands 4 Haskoning Consultants, Barbarossastraat 35, Postbus 151, NL 6500 AD Nijmegen, The Netherlands INTRODUCTION Interest in phosphate recycling is increasing in the industrialized world. There are large amounts of phosphate available in waste streams from e.g. agriculture, sewage treatment and from industrial side streams which pose an increasing problem. To avoid wasting these in e.g. landfills, and to counteract the depletion of natural phosphate sources, routes for re-use are explored. One possibility is to replace phosphate rock by recycled materials in the production of white phosphorus. Worldwide, P production is limited to China, Kazakhstan, the USA and The Netherlands. The -1 latter producer, Thermphos International, has decided to replace 40 kt a of their P2O5 intake (17.5 kt P) by recovered materials. LIMITATIONS FOR PHOSPHATE RECYCLING IN THE PHOSPHORUS PROCESS The phosphorus process The phosphorus process consists of two parts. The first part is a wet granulation and sintering of phosphate rock, producing hard pellets of 1-2 cm. -
US Schedule for Internet V2
Draft as of March 23, 2007 Subject to legal review for accuracy, clarity and consistency. Annex 3.3 - - Industrial/Textile Schedule for the United States Tariff Elimination US 8 digit Description MFN RATE Schedule 03011000 Live ornamental fish Free I 03019100 Live trout Free I 03019200 Live eels Free I 03019300 Live carp Free I 03019900 Live fish, other than trout, eel, carp or ornamental fish Free I 03021100 Trout, fresh or chilled, excluding fillets, other meat portions, livers and roes Free I Pacific, Atlantic and Danube salmon, fresh or chilled, excluding fillets, other 03021200 meat portions, livers and roes Free I Salmonidae other than trout or Pacific, Atlantic & Danube salmon, fresh or 03021900 chilled, excluding fillets, other meat portions, livers & roes Free I Halibut and Greenland turbot, fresh or chilled, excluding fillets, other meat 03022100 portions, livers and roes Free I 03022200 Plaice, fresh or chilled, excluding fillets, other meat portions, livers and roes Free I 03022300 Sole, fresh or chilled, excluding fillets, other meat portions, livers and roes 1.1 cents/kg A Flat fish, nesi, fresh or chilled, excluding fillets, other meat portions, livers 03022900 and roes Free I Albacore or longfinned tunas, fresh or chilled, excluding fillets, other meat 03023100 portions, livers and roes Free I Yellowfin tunas, fresh or chilled, excluding fillets, other meat portions, livers 03023200 and roes Free I Skipjack or stripe-bellied bonito, fresh or chilled, excluding fillets, other meat 03023300 portions, livers and roes Free -
Brochure-Product-Range.Pdf
PRODUCT RANGE 2015 edition ANSI Standard 60 NSF® CERTIFIED HALAL M ISLAMIC FOOD AND NUTRITION ® COUNCIL OF AMERICA Rue Joseph Wauters, 144 ISO 9001:2008 (Quality) / OHSAS 18001:2007 (Health/ B-4480 Engis Safety) / ISO 14001:2004 (Environment) / ISO 22000:2005 www.globulebleu.com (Food Safety) / FSSC 22000:2013 (Food Safety). Tel. +32 (0) 4 273 93 58 Our food grade phosphates are allergen free, GMO free, Fax. +32 (0) 4 275 68 36 BSE/TSE free. www.prayon.com mail. [email protected] Design by www.prayon.com PRODUCT RANGE | 11 TABLE OF CONTENTS HORTICULTURE APPLICATIONS HORTIPRAY® RANGE FOR HORTICULTURE* FOOD AND INDUSTRIAL APPLICATIONS PRODUCT NAME Bulk density P O pH N-NH Made 2 5 4 MONOAMMONIUM PHOSPHATE - NH4H2PO4 in 3 3 % 1% % Sodium orthophosphates ................................................................................... 03 g/cm lbs/ft indicative indicative indicative Water-soluble fertilisers. Sodium pyrophosphates .................................................................................... 04 HORTIPRAY® MAP Horticultural Grade 0.9 56 61 4.5 12 Sodium tripolyphosphates ................................................................................. 05 HORTIPRAY® MAP 12.60 Horticultural Grade 0.9 56 60 5 12.1 Water-soluble fertilisers; Sodium polyphosphates ..................................................................................... 06 HORTIPRAY® MAP anticalc Horticultural Grade 0.9 56 61 4.5 12 preventive action against clogging. Potassium orthophosphates ............................................................................. -
Ionic Liquid + Biomolecule
Sónia Isabel Pereira Branco Licenciatura em Ciências da Engenharia Química e Bioquímica Aqueous Biphasic System based on Cholinium Ionic Liquids: Extraction of Biologically Active Phenolic Acids Dissertação para obtenção do Grau de Mestre em Engenharia Química e Bioquímica Orientador: Doutora Isabel Maria Delgado Jana Marrucho Ferreira, Investigadora Coordenadora, Laboratório de Termodinâmica Molecular, ITQB-UNL Presidente: Doutora Susana Filipe Barreiros Arguente: Doutor Alexandre Babo de Almeida Paiva Vogal: Doutora Isabel Maria Delgado Jana Marrucho Ferreira Setembro 2014 II UNIVERSIDADE NOVA DE LISBOA Faculdade de Ciências e Tecnologia Departamento de Química Aqueous Biphasic System based on Cholinium Ionic Liquids: Extraction of Biologically Active Phenolic Acids Sónia Isabel Pereira Branco Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para obtenção do grau Mestre em Engenharia Química e Bioquímica Orientadores: Doutora Isabel Maria Delgado Jana Marrucho Ferreira 2014 III IV Aqueous Biphasic Systems based on Cholinium Ionic Liquids: Extraction of Biologically Active Phenolic Acids COPYRIGHT Sónia Isabel Pereira Branco Faculdade de Ciências e Tecnologia Universidade Nova de Lisboa A Faculdade de Ciências e Tecnologia e a Universidade Nova de Lisboa têm o direito, perpétuo e sem limites geográficos, de arquivar e publicar esta dissertação através de exemplares impressos reproduzidos em papel ou de forma digital, ou por qualquer outro meio conhecido ou que venha a ser inventado, e de a divulgar através de repositórios científicos e de admitir a sua cópia e distribuição com objectivos educacionais ou de investigação, não comerciais, desde que seja dado crédito ao autor e editor. V VI Agradecimentos Durante a realização desta tese, contei com o apoio de várias pessoas sem as quais não teria concluído esta etapa. -
Vaccine Excipient Table
Vaccine Excipient Summary Excipients Included in U.S. Vaccines, by Vaccine In addition to weakened or killed disease antigens (viruses or bacteria), vaccines contain very small amounts of other ingredients – excipients. Some excipients are added to a vaccine for a specific purpose. These include: Preservatives, to prevent contamination. For example, thimerosal. Adjuvants, to help stimulate a stronger immune response. For example, aluminum salts. Stabilizers, to keep the vaccine potent during transportation and storage. For example, sugars or gelatin. Others are residual trace amounts of materials that were used during the manufacturing process and removed. These can include: Cell culture materials, used to grow the vaccine antigens. For example, egg protein, various culture media. Inactivating ingredients, used to kill viruses or inactivate toxins. For example, formaldehyde. Antibiotics, used to prevent contamination by bacteria. For example, neomycin. The following table lists substances, other than active ingredients (i.e., antigens), shown in the manufacturers’ package insert (PI) as being contained in the final formulation of each vaccine. Note: Substances used in the manufacture of a vaccine but not listed as contained in the final product (e.g., culture media) can be found in each PI, but are not shown on this table. Each PI, which can be found on the FDA’s website (see below) contains a description of that vaccine’s manufacturing process, including the amount and purpose of each substance. In most PIs, this information is found -
General Properties of the Alkaline Phosphates: - Major Food and Technical Applications
Phosphorus Research Bulletin Vol. 15 (2004) p. 85-94 General Properties of the Alkaline Phosphates: - Major Food and Technical Applications P.HOURANT Deputy Business Line Manager, Prayon S.A., Business Unit Phosphates, Rue Joseph Wauters, 144 4480 Engis, Belgium; E-mail: [email protected] INTRODUCTION The alkaline phosphates are used for many food and technical applications. Phosphates have two characteristics that explain their four main properties: buffer agent, sequestering power, dispersing power and water holding capability. Those properties allow phosphates to be used in many food and technical applications. The main food applications are meat and seafood processing, baking and processed cheese, but others such as cereals, French fries, fruits and vegetables, beverages, noodles and so on also may need the use of phosphates. On the technical side, the main applications are the detergent products, the water treatment and the metal treatment. As for the food, many other applications require phosphates such as ceramics, bone china, paper and paints,... In meat products, phosphates salts interact in a unique way to bind water with proteins and improve the tenderness in meats. Treated products will maintain their juicy appearance as well as their natural nutritional properties texture and colour. In fish and seafood products, phosphates salts allow the retention of the natural juices of frozen fish fillets, prawns, shrimps, scallops and other seafood. Phosphates also help prevent the build-up of struvite crystals in tinned tuna and crabmeat. In processed cheese, phosphates are crucially important in the production of processed cheese. These products ensure a homogeneous and uniform melt of raw cheese and product stability. -
Study of Phosphorus Behaviour in Levitated Silicon-Iron Droplets
STUDY OF PHOSPHORUS BEHAVIOUR IN LEVITATED SILICON-IRON DROPLETS by Katherine Le A thesis submitted in conformity with the requirements for the degree of Master of Applied Science Department of Materials Science and Engineering University of Toronto © Copyright by Katherine Le 2016 ii Study of Phosphorus Behaviour in Levitated Si-Fe Droplets Katherine Le Master of Applied Science Department of Materials Science and Engineering University of Toronto 2016 Abstract While the treatment of relatively inexpensive ferrosilicon alloys is a potential refining route in order to generate solar grade silicon, phosphorus is one of the more difficult impurities to remove by conventional processing. In this project, electromagnetic levitation was used to investigate the dephosphorization of ferrosilicon alloy droplets exposed to H2-Ar gas mixtures under various experimental conditions including, refining time, temperature (1450°C-1720°C), H2-Ar gas concentrations and flow rate, iron alloying content, and initial phosphorus concentration. Reaction rates increased with higher refining times, temperatures, and H2 gas concentrations. With unknown parameters associated with the kinetics of gas phase reactions, the approach involved comparison of apparent activation energies derived for the chemical reaction and gas diffusion steps of the dephosphorization process. The phosphorus removal rate is thought to be controlled by the interfacial reaction step; further work is required to confirm this conclusion. iii Acknowledgements I would like to express my gratitude and respect to my supervisor, Prof. Alex McLean for the opportunity to work on this research. I am thankful for his guidance, wisdom and encouragement throughout the course of my studies. He is a truly inspiring person, and a great enabler of new learning opportunities. -
IFAC Summary of Phosphate Citations the International Food Additives
IFAC Summary of Phosphate Citations The International Food Additives Council (IFAC) is a global association representing manufacturers of food ingredients, including phosphates used as food additives. IFAC strives for the harmonization of food additive standards and specifications worldwide, and supports regulatory processes to identify, categorize and document the safety of food additives. Phosphorus is an essential element critical for several key biochemical processes in the body, including development of cell membranes, growth of bones and teeth, maintenance of acid-base balance, and cellular energetics. Phosphorus is naturally occurring in various types of foods, including meat, grains, and dairy. Additionally, inorganic phosphates can be added to foods to improve texture, flavor, shelf life, and other technological functions. Inorganic phosphates are salts or esters of phosphoric acid. Phosphoric acid is produced starting with naturally-occurring phosphate ore mined around the world. As phosphoric acid, it can be combined with other elements such as calcium, potassium, and sodium into "salts." Phosphate additives are contained in a large number of processed foods and beverages and help contribute to the vast food supply while also minimizing food waste. Following is a comprehensive list of phosphates that are approved for use in food. All of these phosphates have either been approved by the US Food and Drug Administration (FDA) as a direct food additive or reviewed by FDA and determined to be generally recognized as safe (GRAS). Also included are the CAS numbers, International Numbering System (INS) numbers, Food Chemicals Codex (FCC) references and Joint FAO/WHO Expert Committee on Food Additives (JECFA) evaluations, as available. -
Binary and Ternary Transition-Metal Phosphides As Hydrodenitrogenation Catalysts
Research Collection Doctoral Thesis Binary and ternary transition-metal phosphides as hydrodenitrogenation catalysts Author(s): Stinner, Christoph Publication Date: 2001 Permanent Link: https://doi.org/10.3929/ethz-a-004378279 Rights / License: In Copyright - Non-Commercial Use Permitted This page was generated automatically upon download from the ETH Zurich Research Collection. For more information please consult the Terms of use. ETH Library Diss. ETH No. 14422 Binary and Ternary Transition-Metal Phosphides as Hydrodenitrogenation Catalysts A dissertation submitted to the Swiss Federal Institute of Technology Zurich for the degree of Doctor of Natural Sciences Presented by Christoph Stinner Dipl.-Chem. University of Bonn born February 27, 1969 in Troisdorf (NRW), Germany Accepted on the recommendation of Prof. Dr. Roel Prins, examiner Prof. Dr. Reinhard Nesper, co-examiner Dr. Thomas Weber, co-examiner Zurich 2001 I Contents Zusammenfassung V Abstract IX 1 Introduction 1 1.1 Motivation 1 1.2 Phosphides 4 1.2.1 General 4 1.2.2 Classification 4 1.2.3 Preparation 5 1.2.4 Properties 12 1.2.5 Applications and Uses 13 1.3 Scope of the Thesis 14 1.4 References 16 2 Characterization Methods 1 2.1 FT Raman Spectroscopy 21 2.2 Thermogravimetric Analysis 24 2.3 Temperature-Programmed Reduction 25 2.4 X-Ray Powder Diffractometry 26 2.5 Nitrogen Adsorption 28 2.6 Solid State Nuclear Magnetic Resonance Spectroscopy 28 2.7 Catalytic Test 33 2.8 References 36 3 Formation, Structure, and HDN Activity of Unsupported Molybdenum Phosphide 37 3.1 Introduction