Methyl Acrylate
Common Name: METHYL ACRYLATE
CAS Number: 96-33-3 DOT Number: UN 1919 RTK Substance number: 1219 DOT Hazard Class: 3 (Flammable Liquid) Date: May 1998 Revision: March 2006 ------
HAZARD SUMMARY * Methyl Acrylate can affect you when breathed in and by * Exposure to hazardous substances should be routinely passing through your skin. evaluated. This may include collecting personal and area * Contact can severely irritate and burn the skin and eyes air samples. You can obtain copies of sampling results with possible eye damage. from your employer. You have a legal right to this * Breathing Methyl Acrylate can irritate the nose and throat information under the OSHA Access to Employee causing coughing and wheezing. Exposure and Medical Records Standard (29 CFR * Breathing Methyl Acrylate can irritate the lungs causing 1910.1020). coughing and/or shortness of breath. Higher exposures * If you think you are experiencing any work-related health can cause a build-up of fluid in the lungs (pulmonary problems, see a doctor trained to recognize occupational edema), a medical emergency, with severe shortness of diseases. Take this Fact Sheet with you. breath. * ODOR THRESHOLD = 0.0048 to 0.263 ppm * Methyl Acrylate may cause a skin allergy. If allergy * The range of accepted odor threshold values is quite develops, very low future exposure can cause itching and a broad. Caution should be used in relying on odor alone as skin rash. a warning of potentially hazardous exposures. * Prolonged exposure to Methyl Acrylate may cause liver and kidney damage. WORKPLACE EXPOSURE LIMITS * Methyl Acrylate is a FLAMMABLE and REACTIVE OSHA: The legal airborne permissible exposure limit LIQUID and a FIRE and EXPLOSION HAZARD. (PEL) is 10 ppm averaged over an 8-hour workshift. IDENTIFICATION Methyl Acrylate is a clear, colorless liquid with a sharp, NIOSH: The recommended airborne exposure limit is fruity odor. It is used to manufacture polymers, and in leather 10 ppm averaged over a 10-hour workshift. finishing, resins, textile and paper coatings, and plastic films. ACGIH: The recommended airborne exposure limit is REASON FOR CITATION 2 ppm averaged over an 8-hour workshift. * Methyl Acrylate is on the Hazardous Substance List because it is regulated by OSHA and cited by ACGIH, * The above exposure limits are for air levels only. When DOT, NIOSH, DEP, IARC, IRIS, NFPA and EPA. skin contact also occurs, you may be overexposed, even * This chemical is on the Special Health Hazard Substance though air levels are less than the limits listed above.
List because it is FLAMMABLE and REACTIVE. * Definitions are provided on page 5. WAYS OF REDUCING EXPOSURE * Where possible, enclose operations and use local exhaust HOW TO DETERMINE IF YOU ARE BEING ventilation at the site of chemical release. If local exhaust EXPOSED ventilation or enclosure is not used, respirators should be worn. The New Jersey Right to Know Act requires most employers * Wear protective work clothing. to label chemicals in the workplace and requires public * Wash thoroughly immediately after exposure to Methyl employers to provide their employees with information and Acrylate and at the end of the workshift. training concerning chemical hazards and controls. The * Post hazard and warning information in the work area. In federal OSHA Hazard Communication Standard (29 CFR addition, as part of an ongoing education and training 1910.1200) requires private employers to provide similar effort, communicate all information on the health and training and information to their employees. safety hazards of Methyl Acrylate to potentially exposed workers. METHYL ACRYLATE page 2 of 6
This Fact Sheet is a summary source of information of all If symptoms develop or overexposure is suspected, the potential and most severe health hazards that may result from following are recommended: exposure. Duration of exposure, concentration of the substance and other factors will affect your susceptibility to any of the * Evaluation by a qualified allergist, including careful potential effects described below. exposure history and special testing, may help diagnose ------skin allergy. * Consider chest x-ray after acute overexposure HEALTH HAZARD INFORMATION Any evaluation should include a careful history of past and Acute Health Effects present symptoms with an exam. Medical tests that look for The following acute (short-term) health effects may occur damage already done are not a substitute for controlling immediately or shortly after exposure to Methyl Acrylate: exposure.
* Contact can severely irritate and burn the skin and eyes Request copies of your medical testing. You have a legal right with possible eye damage. to this information under the OSHA Access to Employee * Breathing Methyl Acrylate can irritate the nose and throat Exposure and Medical Records Standard (29 CFR 1910.1020). causing coughing and wheezing. * Breathing Methyl Acrylate can irritate the lungs causing Mixed Exposures coughing and/or shortness of breath. Higher exposures can * Because smoking can cause heart disease, as well as lung cause a build-up of fluid in the lungs (pulmonary edema), a cancer, emphysema, and other respiratory problems, it may medical emergency, with severe shortness of breath. worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will Chronic Health Effects reduce your risk of developing health problems. The following chronic (long-term) health effects can occur at * Because more than light alcohol consumption can cause some time after exposure to Methyl Acrylate and can last for liver damage, drinking alcohol can increase the liver months or years: damage caused by Methyl Acrylate.
Cancer Hazard WORKPLACE CONTROLS AND PRACTICES * While Methyl Acrylate has been tested, it is not classifiable as to its potential to cause cancer. Unless a less toxic chemical can be substituted for a hazardous substance, ENGINEERING CONTROLS are the most Reproductive Hazard effective way of reducing exposure. The best protection is to * According to the information presently available to the New enclose operations and/or provide local exhaust ventilation at Jersey Department of Health and Senior Services, Methyl the site of chemical release. Isolating operations can also Acrylate has not been tested for its ability to affect reduce exposure. Using respirators or protective equipment is reproduction. less effective than the controls mentioned above, but is sometimes necessary. Other Long-Term Effects * Methyl Acrylate may cause a skin allergy. If allergy In evaluating the controls present in your workplace, consider: develops, very low future exposure can cause itching and a (1) how hazardous the substance is, (2) how much of the skin rash. substance is released into the workplace and (3) whether * Prolonged exposure to Methyl Acrylate may cause liver harmful skin or eye contact could occur. Special controls and kidney damage. should be in place for highly toxic chemicals or when significant skin, eye, or breathing exposures are possible.
MEDICAL In addition, the following controls are recommended:
Medical Testing * Where possible, automatically pump liquid Methyl For those with frequent or potentially high exposure (half the Acrylate from drums or other storage containers to process TLV or greater), the following are recommended before containers. beginning work and at regular times after that: * Before entering a confined space where Methyl Acrylate may be present, check to make sure that an explosive * Liver and kidney function tests concentration does not exist.
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Good WORK PRACTICES can help to reduce hazardous Respiratory Protection exposures. The following work practices are recommended: IMPROPER USE OF RESPIRATORS IS DANGEROUS. Such equipment should only be used if the employer has a * Workers whose clothing has been contaminated by Methyl written program that takes into account workplace conditions, Acrylate should change into clean clothing promptly. requirements for worker training, respirator fit testing, and * Contaminated work clothes should be laundered by medical exams, as described in the OSHA Respiratory individuals who have been informed of the hazards of Protection Standard (29 CFR 1910.134). exposure to Methyl Acrylate. * Eye wash fountains should be provided in the immediate * Where the potential exists for exposure over 2 ppm, use a work area for emergency use. NIOSH approved full facepiece respirator with an organic * If there is the possibility of skin exposure, emergency vapor cartridge. Increased protection is obtained from full shower facilities should be provided. facepiece powered-air purifying respirators. * On skin contact with Methyl Acrylate, immediately wash * Where the potential exists for exposure over 20 ppm, use a or shower to remove the chemical. At the end of the NIOSH approved supplied-air respirator with a full workshift, wash any areas of the body that may have facepiece operated in a pressure-demand or other positive- contacted Methyl Acrylate, whether or not known skin pressure mode. For increased protection use in combination contact has occurred. with an auxiliary self-contained breathing apparatus * Do not eat, smoke, or drink where Methyl Acrylate is operated in a pressure-demand or other positive-pressure handled, processed, or stored, since the chemical can be mode. swallowed. Wash hands carefully before eating, drinking, * Exposure to 250 ppm is immediately dangerous to life and applying cosmetics, smoking, or using the toilet. health. If the possibility of exposure above 250 ppm exists, use a NIOSH approved self-contained breathing apparatus PERSONAL PROTECTIVE EQUIPMENT with a full facepiece operated in a pressure-demand or other positive-pressure mode. WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT. However, for HANDLING AND STORAGE some jobs (such as outside work, confined space entry, jobs done only once in a while, or jobs done while workplace * Prior to working with Methyl Acrylate you should be controls are being installed), personal protective equipment trained on its proper handling and storage. may be appropriate. * Methyl Acrylate must be stored to avoid contact with
OXIDIZING AGENTS (such as PERCHLORATES, The OSHA Personal Protective Equipment Standard (29 CFR PEROXIDES, PERMANGANATES, CHLORATES, 1910.132) requires employers to determine the appropriate NITRATES, CHLORINE, BROMINE and FLUORINE); personal protective equipment for each hazard and to train STRONG ACIDS (such as HYDROCHLORIC, employees on how and when to use protective equipment. SULFURIC and NITRIC); STRONG BASES (such as
SODIUM HYDROXIDE and POTASSIUM The following recommendations are only guidelines and may HYDROXIDE); and AMINES. not apply to every situation. * Store in tightly closed containers in a cool, well-ventilated
area away from HEAT, MOISTURE, METALS, and Clothing COMBUSTIBLES. * Avoid skin contact with Methyl Acrylate. Wear protective * At temperatures above 70oF (21oC), a violent reaction can gloves and clothing. Safety equipment take place. suppliers/manufacturers can provide recommendations on * Methyl Acrylate should always be used with an inhibitor the most protective glove/clothing material for your to prevent violent reactions or polymerization. operation. * Sources of ignition, such as smoking and open flames, are * Safety equipment manufacturers recommend Viton®/Butyl prohibited where Methyl Acrylate is used, handled, or Rubber, and Tychem® BR/LV and TK as protective stored. materials. * Metal containers involving the transfer of Methyl Acrylate * All protective clothing (suits, gloves, footwear, headgear) should be grounded and bonded. should be clean, available each day, and put on before * Use only non-sparking tools and equipment, especially work. when opening and closing containers of Methyl Acrylate. * Wherever Methyl Acrylate is used, handled, manufactured, Eye Protection or stored, use explosion-proof electrical equipment and * Wear indirect-vent, impact and splash resistant goggles fittings. when working with liquids.
* Wear a face shield along with goggles when working with corrosive, highly irritating or toxic substances.
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QUESTIONS AND ANSWERS ------The following information is available from: Q: If I have acute health effects, will I later get chronic health effects? New Jersey Department of Health and Senior Services A: Not always. Most chronic (long-term) effects result from Occupational Health Service repeated exposures to a chemical. PO Box 360 Trenton, NJ 08625-0360 Q: Can I get long-term effects without ever having short- (609) 984-1863 term effects? (609) 984-7407 (fax) A: Yes, because long-term effects can occur from repeated exposures to a chemical at levels not high enough to make Web address: http://www.state.nj.us/health/eoh/odisweb/
you immediately sick. Industrial Hygiene Information
Industrial hygienists are available to answer your questions Q: What are my chances of getting sick when I have been regarding the control of chemical exposures using exhaust exposed to chemicals? ventilation, special work practices, good housekeeping, good A: The likelihood of becoming sick from chemicals is hygiene practices, and personal protective equipment including increased as the amount of exposure increases. This is respirators. In addition, they can help to interpret the results of determined by the length of time and the amount of industrial hygiene survey data. material to which someone is exposed. Medical Evaluation Q: When are higher exposures more likely? If you think you are becoming sick because of exposure to A: Conditions which increase risk of exposure include chemicals at your workplace, you may call personnel at the physical and mechanical processes (heating, pouring, Department of Health and Senior Services, Occupational spraying, spills and evaporation from large surface areas Health Service, who can help you find the information you such as open containers), and "confined space" exposures need. (working inside vats, reactors, boilers, small rooms, etc.). Public Presentations Q: Is the risk of getting sick higher for workers than for Presentations and educational programs on occupational health community residents? or the Right to Know Act can be organized for labor unions, A: Yes. Exposures in the community, except possibly in trade associations and other groups. cases of fires or spills, are usually much lower than those found in the workplace. However, people in the Right to Know Information Resources community may be exposed to contaminated water as The Right to Know Infoline (609) 984-2202 can answer well as to chemicals in the air over long periods. This questions about the identity and potential health effects of may be a problem for children or people who are already chemicals, list of educational materials in occupational health, ill. references used to prepare the Fact Sheets, preparation of the Right to Know Survey, education and training programs, Q: Don't all chemicals cause cancer? labeling requirements, and general information regarding the A: No. Most chemicals tested by scientists are not cancer- Right to Know Act. Violations of the law should be reported to causing. (609) 984-2202. ------
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DEFINITIONS
ACGIH is the American Conference of Governmental NAERG is the North American Emergency Response Industrial Hygienists. It recommends upper limits (called Guidebook. It was jointly developed by Transport Canada, the TLVs) for exposure to workplace chemicals. United States Department of Transportation and the Secretariat of Communications and Transportation of Mexico. It is a A carcinogen is a substance that causes cancer. guide for first responders to quickly identify the specific or generic hazards of material involved in a transportation The CAS number is assigned by the Chemical Abstracts incident, and to protect themselves and the general public Service to identify a specific chemical. during the initial response phase of the incident.
CFR is the Code of Federal Regulations, which consists of the NFPA is the National Fire Protection Association. It classifies regulations of the United States government. substances according to their fire and explosion hazard.
A combustible substance is a solid, liquid or gas that will NIOSH is the National Institute for Occupational Safety and burn. Health. It tests equipment, evaluates and approves respirators, conducts studies of workplace hazards, and proposes standards A corrosive substance is a gas, liquid or solid that causes to OSHA. irreversible damage to human tissue or containers. NTP is the National Toxicology Program which tests DEP is the New Jersey Department of Environmental chemicals and reviews evidence for cancer. Protection. OSHA is the Occupational Safety and Health Administration, DOT is the Department of Transportation, the federal agency which adopts and enforces health and safety standards. that regulates the transportation of chemicals. PEL is the Permissible Exposure Limit which is enforceable EPA is the Environmental Protection Agency, the federal by the Occupational Safety and Health Administration. agency responsible for regulating environmental hazards. PIH is a DOT designation for chemicals which are Poison A fetus is an unborn human or animal. Inhalation Hazards.
A flammable substance is a solid, liquid, vapor or gas that will ppm means parts of a substance per million parts of air. It is a ignite easily and burn rapidly. measure of concentration by volume in air.
The flash point is the temperature at which a liquid or solid A reactive substance is a solid, liquid or gas that releases gives off vapor that can form a flammable mixture with air. energy under certain conditions.
IARC is the International Agency for Research on Cancer, a STEL is a Short Term Exposure Limit which is usually a 15- scientific group that classifies chemicals according to their minute exposure that should not be exceeded at any time cancer-causing potential. during a work day.
IRIS is the Integrated Risk Information System database of the A teratogen is a substance that causes birth defects by federal EPA. damaging the fetus.
A miscible substance is a liquid or gas that will evenly TLV is the Threshold Limit Value, the workplace exposure dissolve in another. limit recommended by ACGIH. mg/m3 means milligrams of a chemical in a cubic meter of air. The vapor pressure is a measure of how readily a liquid or a It is a measure of concentration (weight/volume). solid mixes with air at its surface. A higher vapor pressure indicates a higher concentration of the substance in air and A mutagen is a substance that causes mutations. A mutation therefore increases the likelihood of breathing it in. is a change in the genetic material in a body cell. Mutations can lead to birth defects, miscarriages, or cancer. page 6 of 6 >>>>>>>>>>>>>>>>> E M E R G E N C Y I N F O R M A T I O N <<<<<<<<<<<<<<<<<
Common Name: METHYL ACRYLATE ======DOT Number: UN 1919 FOR LARGE SPILLS AND FIRES immediately call your fire DOT Hazard Class: 3 (Flammable Liquid) department. You can request emergency information from the NAERG Code: 129P following: CAS Number: 96-33-3 CHEMTREC: (800) 424-9300 NJDEP HOTLINE: 1-877-WARN-DEP Hazard rating NJDHSS NFPA ======FLAMMABILITY - 3 HANDLING AND STORAGE (See page 3) - 2 REACTIVITY FLAMMABLE AND REACTIVE FIRST AID POISONOUS GASES ARE PRODUCED IN FIRE CONTAINERS MAY EXPLODE IN FIRE For POISON INFORMATION call 1-800-222-1222 Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; 4=severe Eye Contact * Immediately flush with large amounts of water. Continue FIRE HAZARDS without stopping for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention * Methyl Acrylate is a FLAMMABLE LIQUID. immediately. * Use dry chemical, CO2 or alcohol resistant foam extinguishers, as water may not be effective in fighting Skin Contact fires. * Quickly remove contaminated clothing. Immediately wash * POISONOUS GASES ARE PRODUCED IN FIRE. contaminated skin with large amounts of soap and water. * CONTAINERS MAY EXPLODE IN FIRE. * Use water spray to keep fire-exposed containers cool. Breathing * Vapors may travel to a source of ignition and flash back. * Remove the person from exposure. * Vapor is heavier than air and may travel a distance to cause * Begin rescue breathing (using universal precautions) if a fire or explosion far from the source. breathing has stopped and CPR if heart action has stopped. * If employees are expected to fight fires, they must be * Transfer promptly to a medical facility. trained and equipped as stated in the OSHA Fire Brigades * Medical observation is recommended for 24 to 48 hours Standard (29 CFR 1910.156). after breathing overexposure, as pulmonary edema may be delayed. SPILLS AND EMERGENCIES PHYSICAL DATA If Methyl Acrylate is spilled or leaked, take the following Vapor Pressure: 68.2 mm Hg at 68oF (20oC) steps: o o Flash Point: 27 F (-3 C) * Evacuate persons not wearing protective equipment from Water Solubility: Insoluble area of spill or leak until clean-up is complete. * Remove all ignition sources. OTHER COMMONLY USED NAMES * Cover with an activated charcoal adsorbent and place in Chemical Name: covered containers for disposal. 2-Propenoic Acid, Methyl Ester * Ventilate and wash area after clean-up is complete. Other Names: * Keep Methyl Acrylate out of a confined space, such as a Methyl Propenoate; Methoxycarbonylethylene; Acrylic Acid, sewer, because of the possibility of an explosion, unless the Methyl Ester sewer is designed to prevent the build-up of explosive ------concentrations. Not intended to be copied and sold for commercial * It may be necessary to contain and dispose of Methyl Acrylate as a HAZARDOUS WASTE. Contact your state purposes. Department of Environmental Protection (DEP) or your ------NEW JERSEY DEPARTMENT OF HEALTH AND regional office of the federal Environmental Protection SENIOR SERVICES Agency (EPA) for specific recommendations. Right to Know Program * If employees are required to clean-up spills, they must be PO Box 368, Trenton, NJ 08625-0368 properly trained and equipped. The OSHA Hazardous (609) 984-2202 Waste Operations and Emergency Response Standard ------(29 CFR 1910.120) may apply.