SAFETY DATA SHEET According to EC 1907/2006 (REACH)

Date last verification : 2016-06-16 Version number : 2.0 Revision date : 2016-06-15 Publication date : 2016-06-15

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier SDS : 32374 Supplier : DISCUS DENTAL, LLC. DISCUS DENTAL, LLC. DISCUS DENTAL EUROPE (COMPANY) (IMPORTER) 1700 A South Baker Avenue Van Nelle Ontwerpfabriek-Hal 1 91761 Ontario Van Nelleweg 1 California 3044 BC Rotterdam United States of America The Netherlands TEL:(800) 817-3636 TEL:+31(0)10-7503760 Tradename : PHILIPS ZOOM! DAY WHITE 9.5% WITH SODIUM FLUORIDE (POST HULA)

1.2. Relevant identified uses of the substance or mixture and uses advised against General description : DENTAL WHITENING GEL Use : Various Uses advised against : Data not available.

1.3. Details of the supplier of the safety data sheet Supplier safety data sheet : Philips Electronics Nederland B.V., P.O. Box 218, 5600 MD Eindhoven, Tel. +31 (0)40 2747588 Responsible department : [email protected]

1.4. Emergency telephone number Emergency telephone number : +31 (0)497-598315

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS: (EC) No 1272/2008 Serious eye damage Category 1 H318 Hazardous to the aquatic environment - chronic Category 3 H412 EC: (EC) No 67/548 or 1999/45 Harmful if swallowed. Risk of serious damage to eyes. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2.2. Label elements GHS: (EC) No 1272/2008 Hazard pictogram(s)

Signal word : Danger !

Date of request : 2016-06-20 SDS 32374 - Page 1 / 10 Hazard statements H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. EUH208 May produce an allergic reaction. Precautionary statements P273 Avoid release to the environment. P280.3 Wear eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P501 Dispose of contents/container to a hazardous or special waste collection point. Hazardous component(s) HYDROGEN PEROXIDE EUGENOL Remarks on GHS-labelling none EC: (EC) No 67/548 or 1999/45 Hazard pictogram(s)

HARMFUL R-phrases 22 Harmful if swallowed. 41 Risk of serious damage to eyes. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 39 Wear eye/face protection. 61 Avoid release to the environment. Refer to special instructions/Safety data sheets. P 83 May produce an allergic reaction. Hazardous component(s) HYDROGEN PEROXIDE EUGENOL Remarks on EC-labelling none

2.3. Other hazards If applicable: see section 6.1 and section 7.1.

SECTION 3: Composition/information on ingredients CAS-no. Index No. GHS-Label Component Percentage(%) EC-no. Registration no. EC-Label

ETHYLENE OXIDE/PROPYLENE OXIDE COPOLYMER 9003-11-6 ≥25.0 - <30.0 H412 Aquatic chronic 3 611-024-1 R: 52/53

GLYCEROL 56-81-5 ≥10.0 - <20.0 200-289-5 01-2119471987-18

1,2-PROPANEDIOL 57-55-6 ≥5.0 - <10.0 200-338-0 01-2119456809-23

HYDROGEN PEROXIDE 7722-84-1 008-003-00-9 ≥8.0 - <15.0 GHS03 231-765-0 01-2119485845-22 GHS05 GHS07 H271 Ox. liq. 1 H302 Acute tox. 4 H314 Skin corr. 1A H332 Acute tox. 4 O,C;R: 5 8 20/22 35

POTASSIUM NITRATE 7757-79-1 ≥1.0 - <5.0 GHS03 231-818-8 01-2119488224-35 H271 Ox. sol. 1 O;R: 8

EUGENOL 97-53-0 ≥0.1 - <0.5 GHS07

Date of request : 2016-06-20 SDS 32374 - Page 2 / 10 CAS-no. Index No. GHS-Label Component Percentage(%) EC-no. Registration no. EC-Label 202-589-1 01-2119971802-33 H302 Acute tox. 4 H315 Skin irrit. 2 H317 Skin sens. 1 H319 Eye irrit. 2 H335 STOT SE 3 Xn;R: 22 36/37/38 43

SODIUM FLUORIDE 7681-49-4 009-004-00-7 ≥0.1 - <0.5 GHS06 231-667-8 01-2119539420-47 H301 Acute tox. 3 H315 Skin irrit. 2 H319 Eye irrit. 2 EUH032 T;R: 25 32 36/38

PEPPERMINT OIL 8006-90-4 <1.0 616-900-7

WATER 7732-18-5 231-791-2

For the full text of the H-sentences, hazard statements and R-sentences mentioned in this section, see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures Skin : Remove contaminated clothes as soon as possible. Remove residue substance as soon as possible (e.g. rinse with plenty of water). In case of a serious exposure call for a doctor. Ingestion : If the victim is conscious let him rinse the mouth with water. Do NOT let him drink. In case of general disorders call for a doctor. Inhalation : Bring victim into the fresh air as soon as possible and let rest. In case of severe exposure call for a doctor. In case of breathing problems, loose squeezing clothes and if victim is conscious bring victim in high sitting position. In case of stagnation of breathing give IMMEDIATELY oxygen and transport to hospital as soon as possible. Eyes : Rinse for a long time with plenty of water. In case of eye-sight disturbances bring victim immediately into the hospital, in other cases call for a doctor

4.2. Most important symptoms and effects, both acute and delayed Skin local : The substance is irritating: redness, pain. general : The substance may be absorbed via the skin. Ingestion local : The substance is irritating: sore throat, abdominal pain. : Large concentrations may cause: vomiting, diarrhoea. general : The substance may be absorbed after ingestion. : May cause asphyxiation due to formation of foam. : Large concentrations may cause: coordination disturbances. : Serious cases may cause: fatal end. Inhalation local : The substance is with atomising irritating: sore throat, coughing. : Chance of pulmonary oedema: coughing and tightness of the chest, possibly after several hours. : Serious cases may cause fatal end. general : The substance may be absorbed after inhalation. Eyes local : The substance is corrosive: redness, pain, poor vision. Remarks symptoms : The substance has an effect on: the nervous system, the lungs, the blood (embolization).

4.3. Indication of any immediate medical attention and special treatment needed Administer oxygen in the event of shortness of breath. Use 2.5% calcium gluconate gel as an antidote if the skin is damaged. First flush the affected skin with running water for a lengthy period. Then apply the gel as quickly as possible with a spatula (about 5 mm thick!). Rinse the gel off 5 minutes after applying it. Apply a new layer and again rinse off after 5 minutes. Repeat until the pain is relieved. Allow the final layer of gel to dry and leave on the skin for at least several hours. The 2.5% calcium gluconate gel must be replaced every year. Always alert an ambulance. In the event of gas embolism, consider administering hyperbaric oxygen therapy. For advice on further treatment contact a (national) poison center.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable fire-extinguisher carbon dioxide, extinguishing powder, water spray, alcohol resistant foam

Date of request : 2016-06-20 SDS 32374 - Page 3 / 10 Unsuitable fire-extinguisher not traceable

5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in fire : carbon monoxide, nitrous oxides, potassium oxide, sodium oxide, hydrogen fluoride

5.3. Advice for firefighters In the event of fire, wear protective clothing and use breathing apparatus that is independent of the ambient air.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Precautions Use protective equipment. See section 8. Read label before use. Emergency procedure Is not to be expected.

6.2. Environmental precautions Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

6.3. Methods and material for containment and cleaning up Spillage procedure Dependent on quantity spilt paste, one has the choice between: - remove with cleaning rag or paper, or - cover paste with Powersorb, sand, diatomite, vermiculite and suchlike. Shovel the material into plastic bag or other suitable packaging and remove to the central depot for hazardous waste.

6.4. Reference to other sections See section 8 for appropriate personal protection. See section 13 for additional information on waste treatment.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Observe label precautions. Do not eat, drink or smoke in work areas. Remove contaminated clothing and protective equipment. Wash hands after leaving the work area. Local exhausting : Depends on processing circumstances, but at least good room ventilation. Storage code (on behalf of PGS : none 15)

7.2. Conditions for safe storage, including any incompatibilities Storage conditions : See also any precautionary statements and S-phrases in section 2.2. Store product protected from the sun, in a closed packaging, in a well ventilated area. Storage temperature : ≥15 ºC - ≤30 ºC

7.3. Specific end use(s) Data not available.

SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits : applicable to: The Netherlands (20 ºC; 1013 mbar) No TWA has been laid down. ETHYLENE OXIDE/PROPYLENE OXIDE COPOLYMER TWA(8 hours): 10 mg/m3 GLYCEROL(as aerosol) TWA(8 hours): 50 mg/m3 1,2-PROPANEDIOL(proposal Health Council) TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE(as hydrogen peroxide 90%) No TWA has been laid down. POTASSIUM NITRATE No TWA has been laid down. EUGENOL TWA(15 minutes): 2 mg/m3 SODIUM FLUORIDE(as fluorine) (Statutory threshold limit value) No TWA has been laid down. PEPPERMINT OIL No TWA has been laid down. WATER

Date of request : 2016-06-20 SDS 32374 - Page 4 / 10 applicable to: Belgium (20 ºC; 1013 mbar) TWA(8 hours): 10 mg/m3 GLYCEROL(as aerosol) TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE TWA(8 hours): 2.5 mg/m3 SODIUM FLUORIDE(as fluorine) TWA(8 hours): 10 mg/m3 PEPPERMINT OIL(as aerosol) applicable to: Germany (20 ºC; 1013 mbar) TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE TWA(8 hours): 1 mg/m3 S SODIUM FLUORIDE(as fluorine, inhalable dust) TWA(15 minutes): 4 mg/m3 S SODIUM FLUORIDE(as fluorine, inhalable dust) applicable to: United States of America (25 ºC; 1013 mbar) TWA(8 hours): 10 mg/m3 GLYCEROL(as aerosol) - [according to ACGIH] TWA(8 hours): 15 mg/m3 GLYCEROL(as dust) - [according to OSHA] TWA(8 hours): 5 mg/m3 GLYCEROL(as respirable dust) - [according to OSHA] TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE- [according to ACGIH] TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE- [according to OSHA] TWA(8 hours): 2.5 mg/m3 SODIUM FLUORIDE(as fluorine) - [according to ACGIH] TWA(8 hours): 2.5 mg/m3 SODIUM FLUORIDE(as fluorine) - [according to OSHA] applicable to: Sweden (20 ºC; 1013 mbar) TWA(8 hours): 1.4 mg/m3 HYDROGEN PEROXIDE TWA(8 hours): 3 mg/m3 C HYDROGEN PEROXIDE TWA(8 hours): 2 mg/m3 SODIUM FLUORIDE(as fluorine) applicable to: Switzerland (20 ºC; 1013 mbar) TWA(8 hours): 50 mg/m3 GLYCEROL(as inhalable dust) TWA(15 minutes): 100 mg/m3 GLYCEROL(as inhalable dust) TWA(8 hours): 0.71 mg/m3 HYDROGEN PEROXIDE TWA(15 minutes): 0.71 mg/m3 HYDROGEN PEROXIDE TWA(8 hours): 1 mg/m3 S SODIUM FLUORIDE(as fluorine, inhalable dust) TWA(15 minutes): 4 mg/m3 S SODIUM FLUORIDE(as fluorine, inhalable dust) applicable to: China (20 ºC; 1013 mbar) TWA(8 hours): 1.5 mg/m3 HYDROGEN PEROXIDE TWA(8 hours): 2 mg/m3 SODIUM FLUORIDE(as fluorine) applicable to: European Union (20 ºC; 1013 mbar) TWA(8 hours): 2.5 mg/m3 SODIUM FLUORIDE(as fluorine) C=Ceiling; S=Skin Remarks exposure limits : none DNEL (Derived No Effect Level) Worker - Inhalation - Long term exposure - Local effects: 56 mg/m3 GLYCEROL Source : Supplier Worker - Inhalation - Long term exposure - Systemic effects: 168 mg/m3 1,2-PROPANEDIOL Source : ECHA Worker - Inhalation - Long term exposure - Local effects: 10 mg/m3 1,2-PROPANEDIOL Source : ECHA Consumer - Inhalation - Long term exposure - Systemic effects: 50 mg/m3 1,2-PROPANEDIOL Source : ECHA Consumer - Inhalation - Long term exposure - Local effects: 10 mg/m3 1,2-PROPANEDIOL Source : ECHA Worker - Inhalation - Long term exposure - Local effects: 1.4 mg/m3 HYDROGEN PEROXIDE Source : ECHA Worker - Inhalation - Short term exposure - Local effects: 3 mg/m3 HYDROGEN PEROXIDE Source : ECHA Consumer - Inhalation - Long term exposure - Local effects: 0.210 mg/m3 HYDROGEN PEROXIDE Source : ECHA Consumer - Inhalation - Short term exposure - Local effects: 1.93 mg/m3 HYDROGEN PEROXIDE Source : ECHA Worker - Dermal - Long term exposure - Systemic effects: 20.8 mg/kg bw/day POTASSIUM NITRATE Source : Supplier Worker - Inhalation - Long term exposure - Systemic effects: 36.7 mg/m3 POTASSIUM NITRATE Source : Supplier Consumer - Dermal - Long term exposure - Systemic effects: 12.5 mg/kg bw/day POTASSIUM NITRATE Source : Supplier Consumer - Inhalation - Long term exposure - Systemic effects: 10.9 mg/m3 POTASSIUM NITRATE Source : Supplier Consumer - Oral - Long term exposure - Systemic effects: 12.5 mg/kg bw/day POTASSIUM NITRATE Source : Supplier Worker - Inhalation - Short term exposure - Systemic effects: 2.5 mg/m3 SODIUM FLUORIDE Source : Chemicalcards Worker - Dermal - Long term exposure - Systemic effects: 0.36 mg/kg bw/day SODIUM FLUORIDE Source : Chemicalcards Worker - Dermal - Short term exposure - Systemic effects: 0.36 mg/kg bw/day SODIUM FLUORIDE Source : Chemicalcards PNEC (Predicted No Effect Concentration) Soil: 0.141 mg/kg GLYCEROL Source : Supplier Sewage Treatment Plant (STP): 1000 mg/l GLYCEROL Source : Supplier Marine water: 0.0885 mg/l GLYCEROL Source : Supplier Marine water sediment: 0.33 mg/kg GLYCEROL Source : Supplier Fresh water sediment: 3.3 mg/kg GLYCEROL Source : Supplier Fresh water: 0.885 mg/l GLYCEROL Source : Supplier

Date of request : 2016-06-20 SDS 32374 - Page 5 / 10 Intermittent releases: 8.85 mg/l GLYCEROL Source : Supplier Fresh water: 260 mg/l 1,2-PROPANEDIOL Source : ECHA Marine water: 26 mg/l 1,2-PROPANEDIOL Source : ECHA Intermittent releases: 183 mg/l 1,2-PROPANEDIOL Source : ECHA Sewage Treatment Plant (STP): 20000 mg/l 1,2-PROPANEDIOL Source : ECHA Fresh water sediment: 572 mg/kg 1,2-PROPANEDIOL Source : ECHA Marine water sediment: 57.2 mg/kg 1,2-PROPANEDIOL Source : ECHA Soil: 50 mg/kg 1,2-PROPANEDIOL Source : ECHA Fresh water: 12.6 µg/l HYDROGEN PEROXIDE Source : ECHA Marine water: 12.6 µg/l HYDROGEN PEROXIDE Source : ECHA Intermittent releases: 13.8 µg/l HYDROGEN PEROXIDE Source : ECHA Sewage Treatment Plant (STP): 4.66 mg/l HYDROGEN PEROXIDE Source : ECHA Fresh water sediment: 47 µg/kg HYDROGEN PEROXIDE Source : ECHA Marine water sediment: 47 µg/kg HYDROGEN PEROXIDE Source : ECHA Soil: 2.3 µg/kg HYDROGEN PEROXIDE Source : ECHA Fresh water: 0.45 mg/l POTASSIUM NITRATE Source : Supplier Marine water: 0.045 mg/l POTASSIUM NITRATE Source : Supplier Intermittent releases: 4.5 mg/l POTASSIUM NITRATE Source : Supplier Sewage Treatment Plant (STP): 18 mg/l POTASSIUM NITRATE Source : Supplier Fresh water: 0.9 mg/l SODIUM FLUORIDE Source : Chemicalcards

8.2. Exposure controls Advised personal protection : Hands : butyl rubber gloves neoprene gloves Breakthrough time : For information: consult the supplier of the gloves. Eyes : acid goggles Inhalation : none (when sufficient exhausting) Skin : protective clothing (such as: apron, coverall, boots)

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : gel Colour : type dependent Odour : mint Odour threshold (20ºC; 1013 mbar) : not traceable pH : not traceable Melting point/range : not traceable Boiling point/range : >100 ºC (1013 mbar) Flash point/range : not traceable Vapor rate/range : not traceable Flammability (solid, gas) : data not available Explosive limits : not traceable Vapour pressure : not traceable Relative density : ≥1.0 - ≤1.3 (water=1) (20 ºC) Solubility in water : partial Log Po/w : -2.6 GLYCEROL Source : IUCLID -1.4 1,2-PROPANEDIOL Source : IUCLID -1.1 HYDROGEN PEROXIDE 2.73 EUGENOL Source : Easi View Autoignition temperature : not traceable Decomposition temperature : not traceable Viscosity : ≥200 - ≤950 Pa.s (20 ºC) Dust explosions possible in air : not applicable Oxidising properties : no

9.2. Other information Solubility in fat : not traceable Electrostatic chargement : no

SECTION 10: Stability and reactivity 10.1. Reactivity See section 10.2 - 10.6.

10.2. Chemical stability The substance or mixture is stable under normal conditions. See also section 10.4.

10.3. Possibility of hazardous reactions

Date of request : 2016-06-20 SDS 32374 - Page 6 / 10 Reactions with water : no Other hazardous conditions : Data not available.

10.4. Conditions to avoid Avoid heat and direct sunrays.

10.5. Incompatible materials Hazardous reactions with : oxidizing substances, halogens, potassium permanganate, phosphorus oxide, strong alkaline solutions, perchlorates, reducing substances, inflammable substances, metal salt, strong acids

10.6. Hazardous decomposition products Hazardous decomposition products at heating : none

SECTION 11: Toxicological information 11.1. Information on toxicological effects

Acute oral toxicity LD-50: >2.0 g/kg (ORL-RAT) ETHYLENE OXIDE/PROPYLENE OXIDE COPOLYMER Source : Supplier LD-50: 12.6 g/kg (ORL-RAT) GLYCEROL Source : IUCLID LD-50: 20 g/kg (ORL-RAT) 1,2-PROPANEDIOL Source : IUCLID LD-50: 801 mg/kg (ORL-RAT) HYDROGEN PEROXIDE Source : Supplier LD-50: 1.901 g/kg (ORL-RBT) POTASSIUM NITRATE Source : Easi View LD-50: >2 g/kg (ORL-RAT) POTASSIUM NITRATE Method : OECD 425 Source : Supplier LD-50: 1.93 g/kg (ORL-RAT) EUGENOL Source : Easi View LD-50: 3 g/kg (ORL-MUS) EUGENOL Source : Easi View LD-50: 52 mg/kg (ORL-RAT) SODIUM FLUORIDE LD-50: 2.426 g/kg (ORL-RAT) PEPPERMINT OIL Source : Easi View Acute dermal toxicity LD-50: >10 g/kg (SKN-RBT) GLYCEROL Source : ACROS LD-50: 20.8 g/kg (SKN-RBT) 1,2-PROPANEDIOL Source : IUCLID LD-50: 4.06 g/kg (SKN-RAT) HYDROGEN PEROXIDE Source : IUCLID LD-50: >2 g/kg (SKN-RAT) POTASSIUM NITRATE Method : OECD 402 Source : Supplier Acute inhalation toxicity There are no data available. Ames test negative GLYCEROL Source : ChemDat (Merck) negative 1,2-PROPANEDIOL Source : ChemDat (Merck) negative POTASSIUM NITRATE Source : IUCLID negative EUGENOL Source : ChemDat (Merck) Skin corrosion/irritation The substance or mixture is not classified for skin corrosion/-irritation. Serious eye damage/irritation Causes serious eye damage. Respiratory or skin sensitisation The substance or mixture is not classified for respiratory or skin sensitisation. Germ cell mutagenicity The substance or mixture is not classified for germ cell mutagenicity. Carcinogenicity The substance or mixture is not classified for carcinogenicity. Additional information regarding carcinogenicity (NTP, IARC, OSHA) NTP: no IARC: no OSHA: no ETHYLENE OXIDE/PROPYLENE OXIDE COPOLYMER NTP: no IARC: no OSHA: no GLYCEROL NTP: no IARC: no OSHA: no 1,2-PROPANEDIOL NTP: no IARC: 3 OSHA: no HYDROGEN PEROXIDE NTP: no IARC: no OSHA: no POTASSIUM NITRATE NTP: no IARC: 3 OSHA: no EUGENOL NTP: no IARC: no OSHA: no SODIUM FLUORIDE NTP: no IARC: no OSHA: no PEPPERMINT OIL NTP: no IARC: no OSHA: no WATER Reproductive toxicity The substance or mixture is not classified for reproductive toxicity. Specific target organ toxicity-single exposure

Date of request : 2016-06-20 SDS 32374 - Page 7 / 10 The substance or mixture is not classified for specific target organ toxicity-single exposure. Specific target organ toxicity-repeated exposure The substance or mixture is not classified for specific target organ toxicity-repeated exposure. Aspiration hazard The substance or mixture is not classified for aspiration hazard. Symptoms Skin local : The substance is irritating: redness, pain. general : The substance may be absorbed via the skin. Ingestion local : The substance is irritating: sore throat, abdominal pain. : Large concentrations may cause: vomiting, diarrhoea. general : The substance may be absorbed after ingestion. : May cause asphyxiation due to formation of foam. : Large concentrations may cause: coordination disturbances. : Serious cases may cause: fatal end. Inhalation local : The substance is with atomising irritating: sore throat, coughing. : Chance of pulmonary oedema: coughing and tightness of the chest, possibly after several hours. : Serious cases may cause fatal end. general : The substance may be absorbed after inhalation. Eyes local : The substance is corrosive: redness, pain, poor vision. Remarks symptoms : The substance has an effect on: the nervous system, the lungs, the blood (embolization).

SECTION 12: Ecological information 12.1. Toxicity Ecotoxicity LC-50: >10000 mg/l/96H (Fish) GLYCEROL Source : IUCLID LC-50: 23800 mg/l/96H (Fish) 1,2-PROPANEDIOL Method : OECD 203 Source : IUCLID EC-50: 34400 mg/l/48H (Daphnia) 1,2-PROPANEDIOL Source : IUCLID IC-50: 19000 mg/l/96H (Algae) 1,2-PROPANEDIOL Source : ChemDat (Merck) LC-50: 16.4 mg/l/96H (Fish) HYDROGEN PEROXIDE Source : IUCLID EC-50: 2.4 mg/l/48H (Daphnia) HYDROGEN PEROXIDE Source : IUCLID IC-50: 2.5 mg/l/72H (Algae) HYDROGEN PEROXIDE Source : IUCLID NOEC-Fish: 5 mg/l/96H HYDROGEN PEROXIDE Source : IUCLID NOEC-Daphnia: 1 mg/l/48H HYDROGEN PEROXIDE Source : IUCLID NOEC-Algae: 0.1 mg/l/72H HYDROGEN PEROXIDE Source : IUCLID LC-50: 1378 mg/l/96H (Fish) POTASSIUM NITRATE Source : IUCLID EC-50: 490 mg/l/48H (Daphnia) POTASSIUM NITRATE Source : ChemDat (Merck) LC-50: 24 mg/l/96H (Fish) EUGENOL Source : Easi View LC-50: 51 mg/l/96H (Fish) SODIUM FLUORIDE EC-50: 98 mg/l/48H (Daphnia) SODIUM FLUORIDE IC-50: 850 mg/l/72H (Algae) SODIUM FLUORIDE

12.2. Persistence and degradability

Biological oxygen demand (5) : 0.86 g/g GLYCEROL Source : IUCLID 1.17 g/g 1,2-PROPANEDIOL Source : IUCLID Chemical oxygen demand : 1.16 g/g GLYCEROL Source : IUCLID 2.60 g/g 1,2-PROPANEDIOL Source : IUCLID Biological(5)/chemical oxygen : 0.741 GLYCEROL demand ratio 0.45 1,2-PROPANEDIOL Degradability : readily GLYCEROL Source : ChemDat (Merck) readily 1,2-PROPANEDIOL Source : ChemDat (Merck) readily EUGENOL

12.3. Bioaccumulative potential

Bioconcentration factor : <1.0 1,2-PROPANEDIOL Source : ChemDat (Merck) (BCF) 2.27 EUGENOL Source : ChemDat (Merck) Log Po/w : -2.6 GLYCEROL Source : IUCLID -1.4 1,2-PROPANEDIOL Source : IUCLID -1.1 HYDROGEN PEROXIDE 2.73 EUGENOL Source : Easi View

12.4. Mobility in soil

Henry Constant : 6.06E-7 atm m3/mol ETHYLENE OXIDE/PROPYLENE OXIDE COPOLYMER Source : Easi View 1.18E-8 atm m3/mol 1,2-PROPANEDIOL Source : ChemDat (Merck) 4.81E-8 atm m3/mol EUGENOL Source : Easi View

Date of request : 2016-06-20 SDS 32374 - Page 8 / 10 12.5. Results of PBT and vPvB assessment Data not available.

12.6. Other adverse effects Remarks on ecotoxicity : none

SECTION 13: Disposal considerations 13.1. Waste treatment methods Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

SECTION 14: Transport information 14.1. UN number Not subject to Transport-regulation Dangerous Substances

14.2. UN proper shipping name Not subject to Transport-regulation Dangerous Substances

14.3. Transport hazard class(es) Not subject to Transport-regulation Dangerous Substances

14.4. Packing group Not subject to Transport-regulation Dangerous Substances

14.5. Environmental hazards Marine pollutant : no

14.6. Special precautions for user Not subject to Transport-regulation Dangerous Substances

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Data not available.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- The component(s), as mentioned in section 3, are registered in the Toxic Substances Control Act Inventory (TSCA-USA).

15.2. Chemical safety assessment

- Data not available.

SECTION 16: Other information

Remarks on SDS : none

Overview relevant H-sentences from all components in section 3 H271 May cause fire or explosion; strong oxidiser. H301 Toxic if swallowed. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. EUH032 Contact with acids liberates very toxic gas. Overview relevant hazard statements from all components in section 3 C CORROSIVE O OXIDIZING

Date of request : 2016-06-20 SDS 32374 - Page 9 / 10 T TOXIC Xn HARMFUL Overview relevant R-sentences from all components in section 3 20/22 Harmful by inhalation and if swallowed. 22 Harmful if swallowed. 25 Toxic if swallowed. 32 Contact with acids liberates very toxic gas. 35 Causes severe burns. 36/37/38 Irritating to eyes, respiratory system and skin. 36/38 Irritating to eyes and skin. 43 May cause sensitization by skin contact. 5 Heating may cause an explosion. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 8 Contact with combustible material may cause fire.

Training advice Provide adequate information, instruction and training for operators.

A key or legend to abbreviations and acronyms used in the safety data sheet REACH Registration, Evaluation and Authorisation of CHemicals GHS Globally Harmonised System of Classification and Labelling of Chemicals CAS Chemical Abstracts Service TGG = TWA Time Weighted Average LEL Lower Explosive Limit UEL Upper Explosive Limit NTP National Toxicology Program KHC Known Human Carcinogen RAHC Reasonably Anticipated Human Carcinogen IARC International Agency for Research on Cancer OSHA Occupational Safety & Health Administration ADR Accord européen relatif au transport international des marchandises Dangereuses par Route RID Règlement concernant le transport international ferroviaire des marchandises dangereuses UN United Nations IMDG International Maritime Dangerous Goods IMO International Maritime Organization IATA International Air Transport Association ICAO International Civil Aviation Organization EmS Emergency Schedule

* Point to alterations with regard to the previous version. The information provided in this Safety Data Sheet is believed to be correct as of the date issued. Philips Electronics Nederland B.V. makes no warranty as to its contents, nor as to its fitness for any particular purpose or use.

Date of request : 2016-06-20 SDS 32374 - Page 10 / 10