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Safety Data Sheet SAFETY DATA SHEET Revision Date 27-Dec-2020 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Cadmium phosphide Cat No. : 87219 CAS-No 12014-28-7 EC-No. 234-595-5 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Thermo Fisher (Kandel) GmbH . Erlenbachweg 2 76870 Kandel Germany Tel: +49 (0) 721 84007 280 Fax: +49 (0) 721 84007 300 E-mail address [email protected] www.alfa.com Product safety Tel + +049 (0) 7275 988687-0 1.4. Emergency telephone number Carechem 24: +44 (0) 1235 239 670 (Multi-language emergency number) Poison Information Center Mainz www.giftinfo.uni-mainz.de Telephone: +49(0)6131/19240 Exclusively for customers in Austria: Poison Information Center (VIZ) Emergency call 0-24 clock: +43 1 406 43 43 Office hours: Monday to Friday, 8am to 4pm, tel: +43 1 406 68 98 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met ______________________________________________________________________________________________ ALFAA87219 Page 1 / 11 SAFETY DATA SHEET Cadmium phosphide Revision Date 27-Dec-2020 ______________________________________________________________________________________________ Health hazards Acute oral toxicity Category 4 (H302) Acute dermal toxicity Category 4 (H312) Acute Inhalation Toxicity - Dusts and Mists Category 4 (H332) Environmental hazards Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Warning Hazard Statements H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements P280 - Wear protective gloves/protective clothing P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Cadmium phosphide (Cd3P2) 12014-28-7 EEC No. 234-595-5 <=100 Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Component Concentration limits M-Factor Component notes Cadmium phosphide (Cd3P2) - - Note 1 ______________________________________________________________________________________________ ALFAA87219 Page 2 / 11 SAFETY DATA SHEET Cadmium phosphide Revision Date 27-Dec-2020 ______________________________________________________________________________________________ Note Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation (Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of the metallic element calculated with reference to the total weight of the mixture Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Ingestion Clean mouth with water and drink afterwards plenty of water. Inhalation Remove to fresh air. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire-fighting to enter drains or water courses. Hazardous Combustion Products Cadmium oxide, Oxides of phosphorus. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES ______________________________________________________________________________________________ ALFAA87219 Page 3 / 11 SAFETY DATA SHEET Cadmium phosphide Revision Date 27-Dec-2020 ______________________________________________________________________________________________ 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be released into the environment. 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Ensure adequate ventilation. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep under nitrogen. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Storage Class/LGK 13 (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. Component European Union The United Kingdom France Belgium Spain Cadmium phosphide STEL: 0.075 mg/m3 15 TWA / VME: 0.004 TWA / VLA-ED: 0.01 (Cd3P2) min mg/m3 (8 heures). mg/m3 (8 horas) TWA: 0.025 mg/m3 8 hr indicative limit TWA / VLA-ED: 0.002 mg/m3 (8 horas) Component Italy Germany Portugal The Netherlands Finland Cadmium phosphide Haut TWA: 0.002 mg/m3 8 (Cd3P2) horas TWA: 0.001 mg/m3 8 horas TWA: 0.004 mg/m3 8 ______________________________________________________________________________________________ ALFAA87219 Page 4 / 11 SAFETY DATA SHEET Cadmium phosphide Revision Date 27-Dec-2020 ______________________________________________________________________________________________ horas Component Austria Denmark Switzerland Poland Norway Cadmium phosphide Haut/Peau TWA: 0.05 mg/m3 8 (Cd3P2) TWA: 0.015 mg/m3 8 timer Stunden TWA: 0.004 mg/m3 8 Stunden Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Skin and body protection Long sleeved clothing Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves
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