Redalyc.Composición Química Del Duramen De La Madera De Quercus

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Redalyc.Composición Química Del Duramen De La Madera De Quercus Madera y Bosques ISSN: 1405-0471 [email protected] Instituto de Ecología, A.C. México Rutiaga Quiñones, José Guadalupe; Weiderpass, E.; Strobel, C. Composición química del duramen de la madera de Quercus candicans Neé Madera y Bosques, vol. 6, núm. 2, 2000, pp. 73-80 Instituto de Ecología, A.C. Xalapa, México Disponible en: http://www.redalyc.org/articulo.oa?id=61760206 Cómo citar el artículo Número completo Sistema de Información Científica Más información del artículo Red de Revistas Científicas de América Latina, el Caribe, España y Portugal Página de la revista en redalyc.org Proyecto académico sin fines de lucro, desarrollado bajo la iniciativa de acceso abierto Madera y Bosques 6(2), 2000:73-80 73 Composición química del duramen de la madera de Quercus candicans Neé José G. Rutiaga Quiñones1 E. Windeisen2 C. Strobel2 RESUMEN ABSTRACT Harina tamizada del duramen de Sieved heartwood meal of Quercus Quercus candicans fue extraída candicans was extracted with petroleum sucesivamente con éter de petróleo, ether, acetone and methanol, then with acetona y metanol; posteriormente con agua cold water and, finally, with hot water. The fría y finalmente con agua caliente. El carbohydrates content was determined in análisis de carbohidratos se realizó en la extracted woodmeal, as well as in harina extraída y en los extractos metanólico methanolic and aqueous extracts. The y acuosos. Se determinó el contenido de content of Runkel lignin was determined. lignina Runkel. En la harina no extraída se The content of carbon, hydrogen, oxygen determinó el contenido de carbono, and ashes was also determined for non- hidrógeno, oxígeno y de cenizas. Las extracted wood. The ashes were analyzed cenizas fueron analizadas mediante energía by means of dispersive X Ray energy. The dispersiva de Rayos X. El valor del pH se pH value was determined. The heartwood determinó en la harina no extraída. El of Q. candicans contains 10.2 % duramen de Q. candicans contiene 10.2 % extractives, 66.9 % polysaccharides, 21.4 de extraíbles, 66.9 % de polisacáridos, 21.4 % Runkel lignin, 47.2 % carbon, 6.2 % % de lignina Runkel, 47.2 % de carbono, 6.2 hydrogen, 45.7 % oxygen and 0.9 % % de hidrógeno, 45.7 % de oxígeno y 0.9 % ashes. The ashes contain the following de cenizas. Las cenizas contienen los inorganic elements: K, Mg, Ca, P and S. siguientes elementos químicos: K, Mg, Ca, The pH value is 5.6. P y S. El pH es de 5.6. PALABRAS CLAVE: KEY WORDS: Quercus candicans, duramen, extraíbles, Quercus candicans, heartwood, polisacáridos, lignina, elementos extractives, polysaccharides, lignin, inorgánicos, química de la madera. inorganic elements, wood chemistry. 1 Facultad de Ingeniería en Tecnología de la Madera de la Universidad Michoacana de San Nicolás de Hidalgo. Apartado Postal 2-27. Morelia 58041, Mich. México. 2 Institut für Holzforschung der Technischen Universität München. Winzererstr. 45, D-80797. München. Manuscrito recibido el 2 de diciembre de1999. Aceptado el 3 de marzo del 2000. 74 Composición química de Quercus candicans. Rutiaga et al. INTRODUCCIÓN OBJETIVO El género Quercus es de suma Determinar el contenido de importancia en México, tanto por su extraíbles, polisacáridos, lignina, cenizas, abundancia, ya que incide en la mayor pH y la composición elemental del parte de los bosques de clima templado y duramen de Q. candicans, además, semi-húmedo, como por su utilidad como analizar sus cenizas mediante energía especie forestal. Martínez (1951) dispersiva de Rayos X. menciona que a pesar de no tener un arreglo sistemático definitivo pudieran existir alrededor de 300 especies en MATERIALES Y MÉTODOS México y Centroamérica, de cuya cifra corresponde a México un 80 %. Algunos El árbol de Q. candicans Neé se estudios alrededor de este género han colectó en Villa Madero, Michoacán, su abarcado temas como: características altura total fue de 28 m y su diámetro de anatómicas (De la Paz, 1974, 1976, 1982, 38 cm, medido a 1.3 m de altura. De una 1985; Corral, 1981; Bucio, 1985), físicas y rodaja de 30 cm de espesor, tomada a 1.3 anatómicas (Negrete, 1970; Guerrero, m del tocón, se obtuvieron muestras 1989; Borja, 1991), físicas y mecánicas representativas de la zona del duramen y (Herrera y Bocanegra, 1996), de fueron molidas, adicionando hielo seco, en maquinado (Flores, 1990; Flores, 1991; un equipo Retsch. La harina obtenida fue Martínez y Martínez-Pinillos, 1996), de tamizada de acuerdo a la norma DIN 4188 secado (Zavala y Hernández, 1995; Zavala (1977) y extraída sucesivamente 6 h con et al., 1998) y durabilidad natural (Herrera éter de petróleo, acetona y metanol en un et al., 1976; Herrera et al., 1980), pero aparato Soxhlet; después digerida 48 h en relativamente pocos sobre aspectos agua a temperatura ambiente (llamado químicos: cantidad de extraíbles en Q. comúnmente extracto acuoso frío) y resinosa, Q. laurina, Q. candicans y Q. finalmente extraída 6 h con agua caliente obtusata (Sandoval, 1979), análisis de bajo reflujo. Los solventes orgánicos carbohidratos de las mismas especies fueron destilados a vacío en un rotavapor y (Delgado, 1980), y otro sobre el efecto los extractos acuosos se secaron por fungicida de los extraíbles de Q. laurina sublimación en un aparato de liofilización. (Rutiaga et al., 1999). Quercus candicans (roble, encino blanco, encino de asta) se El contenido de polisacáridos en la localiza en los estados mexicanos de madera extraída y en los extractos Sinaloa, Durango, Jalisco, Colima, metanólico y acuosos se determinó Michoacán, Guerrero, Oaxaca, Chiapas, mediante hidrólisis con ácido Guanajuato, Edo. de México, Morelos, trifluoroacético bajo diferentes condiciones Hidalgo, Tlaxcala, Puebla, Veracruz y en el (Fengel et al., 1978; Fengel y Wegener, Distrito Federal formando parte de los 1979) en un analizador de azúcares bosques de pino-encino (Niembro, 1986). automático (LC 2000 Biotronik). La lignina Su madera se emplea como leña, en la se determinó cuantitativamente por el obtención de carbón, en la fabricación de método de Runkel y Wilke (1951). La muebles, artículos torneados, durmientes, cantidad de carbono e hidrógeno en la carrocerías, embarcaciones y para harina del duramen sin extraer se carpintería en general. También se usa determinó en un analizador elemental para parquet, duela y lambrín, puertas y (Heraeus, CHN-O-Rapid), el oxígeno fue ventanas, mangos para herramientas e calculado por diferencia. implementos agrícolas (Niembro, 1986). Madera y Bosques 6(2), 2000:73-80 75 Se determinó el contenido de (Fengel y Wegener, 1984); un valor similar cenizas en la harina no extraída de xilosa (19.2 %) ha sido calculado para gravimétricamente y su análisis cualitativo otra especie de encino, Q. falcata (Timell, se realizó en un espectrómetro de energía 1957). En la muestra de Q. candicans, dispersiva de Rayos X (Kevex 4000) colectada en el Estado de Jalisco, se acoplado a un microscópio electrónico de encontró un 28.1 % de xilosa (Delgado, barrido (Leitz AMR 1200 B), bajo las 1980). Estas diferencias pueden deberse a condiciones de operación: 15 – 20 kV y los métodos empleados. La cantidad de 300 s. El valor del pH (como “moisture pH“, polisacáridos en la harina del duramen MpH) del duramen se determinó según la extraída fue de 65.8 %. metodología de Sandermann y Rothkamm (1959). Todas las determinaciones se Los hidrolizados de los diferentes efectuaron por triplicado. extractos revelan distintas cantidades de monosacáridos (Fig. 3), lo que era de esperarse. De ahí se deduce que el RESULTADOS Y DISCUSIÓN extracto acuoso frío fue el que presentó la mayor cantidad de polisacáridos (24.0 %), El valor más bajo de extraíbles seguido por el acuoso caliente (16.0 %) y correspondió a la extracción con éter de finalmente el metanólico (8.9 %). Estos petróleo y los valores más altos a la resultados dejan de manifiesto el efecto de extracción con metanol y con agua (Fig. 1), la polaridad de los solventes en la lo que hace suponer que en la madera de ganancia de estos extractos. duramen estudiada se encuentran pocas sustancias no polares, como grasas y El contenido de lignina Runkel de ceras, y más sustancias polares, como 21.4 % es comparable con datos polisacáridos y flavonoides (Browning, presentados para otras especies de 1967). Mediante la secuencia de encinos (Fengel y Wegener, 1984). Por su extracción aquí empleada se ganaron más bajo contenido de lignina, esta madera extraíbles en agua fría que en agua pudiera emplearse en la obtención de caliente, pero no siempre sucede así, ya pulpa celulósica, p.e. en la fábrica "Crisoba que el tipo de madera desempeña un Industrial" de Morelia, actualmente se papel importante. La cantidad total de procesan por mes 15,800 m3 de madera extraíbles del duramen fue del 10.2 %. del género Quercus. El análisis elemental arrojó los siguientes resultados: 47.2 % de Para la misma especie, recolectada carbono, 6.2 % de hidrógeno y 45.7 % de en Tequila, Jalisco, se citan valores de 3.8 oxígeno, valores comparables con datos % y 5.3 % de extraíbles en alcohol- encontrados en la literatura (Nikitin, 1955). benceno y agua caliente, respectivamente El contenido de cenizas encontrado en el (Sandoval, 1979). El contenido duramen fue de 0.9 %, valor comprendido relativamente alto de sustancias extraíbles dentro del rango (0.1 - 1.0 %) mencionado presentes en el duramen de Q. candicans en la literatura para maderas latifoliadas de hace suponer que posee resistencia al clima templado (Fengel y Wegener, 1984) ataque de hongos, de hecho se califica de y ligeramente inferior al valor determinado moderada a altamente resistente (Herrera (1.2 %) para la misma especie colectada et al., 1976). Pero, una madera con alto en el Estado de Jalisco (Sandoval, 1979). contenido de extraíbles no siempre es resistente al biodeterioro. El análisis cualitativo de las cenizas, mediante energía dispersiva de Rayos X, El duramen extraído presentó 19.1 % revela la presencia de 5 elementos de xilosa (Fig.
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