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Section 2 - Hazardous Ingredients

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Section 2 - Hazardous Ingredients rev- OUR PRODUCTS HAVE NO OZONE DEPLETING SUBSTANCES. (ODS) SAFETY DATA SHEET - STAY-CLEAN* SOLDERING FLUXES SECTION 1 Address Manufacturer's Name Cincinnati, OH 45242 j. w. Harris Co., Inc. 10930 Deerfield Rd. 1-800-424-9300 ES 8/92 Emergency Telephone No. Date Prepared 6/93 SUP 1-513-891-2000 Telephone Mo. for Information Signature of Preparer: Section 2 - hazardous ingredients STAY-CLEAN LIQUID FLUX PEL MG/M3 TLV MG/M3 STEL MG/M3 INGREDIENT CAS NUMBER 1.0 Zinc Chloride* 7646-85-7 <40% 1.0 7.5 Not listed Hydrogen chloride* 7647-01-0 <15% 7.0 12125-02-9<25% 10.0 10.0 20 Ammonium chloride Not listed 7732-18-5 <70% Not listed Not listed Water 260.0 262.0 325 Methanol* 67-56-1 <5% STAY-CLEAN PASTE FLUX PEL MG/M3 TLV MG/M3 STEL MG/M3 INGREDIENT CAS NUMBER 1.0 Zinc Chloride* 7646-85-7 <40% 1.0 Not listed Not listed Not listed Petrolatum Not listed <80% 127 ceiling Not listed Ethylene Glycol 107-21-1 <15% 125 ceiling 10.0 20 Ammonium Chloride 12125-02-9 <10% 10.0 Not listed Not listed Not listed Water 7732-18-5 <10% STAY-CLEAN ALUMINUM FLUX PEL MG/M3 TLV MG/M3 STEL MG/M3 INGREDIENT CAS NUMBER 2.5 Not listed Ammonium Fluoborate 13826-83-0 2.5 Not listed Not listed Aminoethylethanolamine 111-41-1 Not listed Not listed 60 Triethanolamine 102-71-6 Not listed 2.0 Not listed Tin as Sn* 7440-31-5 <10% 2.0. Not listed 5.0 Not listed Zinc as Zn* 7440-66-6 <10% 5.0 10 Zinc Oxide* 1314-13-2 <15% 5.0 STAY-CLEAN ROSIN FLUX PEL MG/M3 TLV MG/M3 STEL MG/M3 INGREDIENT CAS NUMBER 985.0 1225 Isopropyl Alcohol 67-63-0 980.0 10.0 Not listed Adipic Acid 124-04-9 Not listed 30.0 Not listed Dimethylformamide 68-12-2 30.0 STAY-CLEAN HI-TEMP LIQUID FLUX PEL MG/M3 TLV MG/M3 STEL MG/M3 INGREDIENT CAS NUMBER 1 2 Zinc Chloride 7646-85-7 <50% 1 20 12125-02-9 10 10 Ammonium Chloride Not listed 7647-01-0 <40% 7 7 Hydrogen chloride Not listed 7732-18-5 Not listed Not listed Water Not listed Not listed Potassium Chloride 7447-40-7 Not listed Not listed Not listed Lithium Chloride 7447-41-8 Not listed Not listed Not listed Sodium Chloride 7647-14-5 Not listed *Upper bound concentration valve per SARA III 372.45.F, SECTION 2 - HAZARDOUS INGREDIENTS-continued SARA SECTION 313 SUPPLIER NOTIFICATION: Individual fluxes covered by this M may contain toxic chemicals subject to the reporting requirements of Sectior 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40CFR 372. Refer to Section 2 for the CAS number for each chemical ingredient NFPA HAZARD SIGNAL Health 1 * Flammability 1 Stability 0 Special 0 One recommended way to determine the composition and quantity of fumes and • gases to which workers are exposed is to take an air sample in the workers' breathing zone. See ANSI/AWS Fl.l available from the American Welding Society, P. 0. Box 351040, Miami, FL 33135. SPECIFIC HEALTH HAZARDS OF CHEMICALS Ammonium Chloride - Prolonged breathing of fumes may cause irritation of respiratory passages. Hydrogen Chloride - Causes eye and skin burns. Ingestion causes severe burns of mouth, esophagus and stomach. Vapor extremely irritating. Methanol - Ingestion may cause blindness; 100-250 ml may be fatal. Symptoms of overexposure include dizziness, visual impairment, nausea, respiratory failure, muscular incoordination and narcosis. Prolonged or repeated skin contact may cause dermatitis, erythmea, scaling, and possibly systemic effects. Petrolatum - May cause skin irritation upon continual use. Zinc Chloride - Fume or dust can cause dermatitis, and conjunctivitis. May cause rashes, boils, corneal burn, epigastric pain, nausea, vomiting, shock (internal). ^ Potassium Chloride - Dust may be irritating to the mucous membranes. Sodium Chloride - 40-60 grams intake of NaCL daily will elevate blood pressure. Lithium Chloride - May be irritating to eyes and slightly irritating to skin, nose and throat. Ipopropyl Alcohol - May be irritating to skin, eyes and mucous membranes. Ammonium Fluoborate - Chronic fluoride absorption can result in osseous fluorosis, increased radiographic density of the bones and mottling of the teeth. Aminoethylethanolamine - If inhaled, can cause irritation to the respiratory system. Triethanolamine - If inhaled, can cause irritation to the respiratory system. Tin - Tin fume may cause metal fume fever, characterized by fever, body ache, and chills. Zinc - Zinc fume may cause metal fume fever, characterized by fever, body ache, and chills. Zinc fume may also be an irritant to the skin and eyes. Zinc Oxide - Causes skin and eye burns. Harmful if inhaled or absorbed through the skin. Chronic effects are coughing, CNS effects, erythmea, and nausea. Adipic Acid - May cause dermatitis, chemical burns, irritation to the respiratory system, or if swallowed, chemical burns to the digestive system. Dimethylformamide - May cause liver or skin damage. It may also result in systemic toxicity. Chronic effects are liver, kidney, bone marrow effects, and CNS effects. SECTION 3 - PHYSICAL AND CHEMICAL DATA flBpeaiail,c - tan/gold color paste, no appreciable odor. pH 5.0 5.5; fe'&SlSW) ^0S70'F) 1'11 vapor Pressure <0.10 Pslg liquid with no appreciable odor. ^b,t,^->.~~ --'fi0' Ha°F^ 1944 H Vapor Pressure _/.:>i27.51 at ^u-20°C mm He STAY-CLEAN ALUMINUM FLUX ^eci??cPGrSvi?? ^2QF=2r 72°F) 1.245 Solubility in water - complete Appearance - viscous amber liquid with ammonia odor STAY-CLEAN HI-TEMP LIQUID FLUX --. _, ■ ^ ?-QOp Vapor Pressure 2.8 5 Ipeciric Gravity - 1.55 @ 70°F Solubility in Water - appreciable SECTION 4 - FIRE AND EXPLOSION DATA STAY-CLEAN PASTE AND LIQUID FLUX and STAY-CLEAN HI-TEMP LIQUID FLUX *NFPA Flammability rating 0. Stav-Clean Paste Flux - Flash Point - 490° F TOC. !£y-Clean LiquidLiqUlu FluxfJ.UX -— Flashrj.aa.ii PointruiJJi- - 221°*.«-j- F* TOC.*-_. _ Hi-Temp Liquid Flux - Flash Point not available. Nonflammable material. When heated the materials may release zinc chloride and zinS oxidefumes. The liquid flux may also release hydrogen chloride gas Ind SitSrSapSr! If large quantities are Involved in afire, firefighters Should use self-contained breathing apparatus and protective clothing. STAY-CLEAN ROSIN FLUX FlImSableniimitSOin air, % by volume - Lower 2.0 Upper 12.0 Extinguishing - Carbon Dioxide or Dry Chemical Explosion hazard - none STAY-CLEAN ALUMINUM FLUX ?i£5.llinuJiS*-> ULr 1.6 (est.) upper 10.0 (est.) In Air % by Vol. N/A Extinguishing - water spray, alcohol foam, CO2 Explosion hazard - none - ■ SECTION 5 - HEALTH HAZARD DATA If swallowed, give plenty of water or milk. Do not induce vomiting. Call Physician immediately. SXin - Flush with water ^halation - Irritates respiratory system - Move to fresh air Eyes - Eye irritant - Flush with water at least 15 min. Promptly get medical y y attention. CARCINOGENICITY NTP? NO IAHC MONOGRAPHS? NO OSHA REGULATED? NO SECTION 6 - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS STAY-CLEAN LIQUID AND PASTE FLUX AND STAY-CLEAN HI-TEMP LIQUID FLUX Flux is stable material in closed containers at room temperature under normal storage and handling conditions. This material can be considered a weak acid. It can be mildly corrosive to some metals, especially when hot. Incompatible with cyanides; may release HC1 gas when mixed with Zinc Chloride. If combined with sulfides, the liquid flux may release H2S gas. STAY-CLEAN ALUMINUM AND ROSIN FLUX Stable, avoid heat, sparks, open flame. _ Incompatibility - Avoid concentrated acids and oxidizers. Hazardous polymerization - will not occur. Hazardous decomposition products - carbon monoxide and/or dioxide. SECTION 7 - SPILL OR LEAK PROCEDURES Contain spill, absorb, sweep-up, dispose, flush area with water to chemical sewer. Dispose of in accordance with all federal, state, and local regulations. SECTION 8 AND 9 - SPECIAL PROTECTION INFORMATION AND PRECAUTIONS Read and understand the manufacturer's instructions and the precautionary label on the product. See"American National Standard Z49.1, Safety in Welding anr~% Cutting published by the American Welding Society, PO Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29CFR1910), U. S. Government Printing Office, Washington, D.C. 20402 for more details on many of the following. VENTILATION - Use enough ventilation to keep the fumes and gases below TLV's in the workers' breathing zone and the general area. Train the employee to keep his head out of the fumes. See ANSI/ASC Z49.1 Section 5. RESPIRATORY PROTECTION - Use respirable fume respirator or air supplied respirator when brazing in confined space or where local exhaust or ventilation does not keep exposure below TLV. EYE PROTECTION - Wear safety glasses, goggles or use face shield with filter lens of appropriate shade number (see ANSI/ASC Z49.1-Section 4.2). Provide protection-screens and flash goggles, if necessary, to shield others. Wear face shield if splashing is probable. PROTECTIVE CLOTHING - Wear head and body protection which help to prevent injury from splashing, sparks, and flame. See ANSI Z49.1. At a minimum this includes gloves and a protective face shield, and may include arm protectors, aprons, hats,- shoulder protection, as well as dark substantial clothing. The information and recommendations contained in this publication have been compiled from sources believed to be reliable and to represent the best information on the subject at the time of issue. No warranty, guarantee, or representation is made by J. W. Harris Co., Inc. as to the absolute correctness or sufficiency of any representation contained in this and othf"^ publications; J. W. Harris Co., Inc. assumes no responsibility in connectic. therewith; nor can it be assumed that all acceptable safety measures are contained in this (and other publications), or that other or additional measures may not be required under particular or exceptional conditions or circumstances..
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