Metal Subgroups

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10/8/2015 Metal Subgroups Alkali, Alkaline Earth, Transition Today’s Goals ►►We will focus on the major subgroups of the periodic table. °° What is a subgroup? °° A subgroup is a small part of a larger group. °° Our larger group is the metals (yesterday), and our subgroups will be different types of metals. 1 10/8/2015 The Alkali Metals 2 10/8/2015 The Alkali Metals The Alkali Metals ►►Made up of all the Group 1 elements Characteristics ►►Shiny ►►Malleable ►►Ductile ►►Highly reactive with water ►►Each atom has one valence electron, meaning it can bond with only one other atom. 3 10/8/2015 Shiny (Sodium ––Na)Na) Malleable 4 10/8/2015 Ductile Highly reactive with water ►►Just watch the video… 5 10/8/2015 One valence electron ►► This means it can Common Alkali Compounds form only one bond! ►► NaCl (sodium chloride) ►► KBr (potassium bromide) ►► KCl (potassium chloride) ►► LiBr (lithium bromide) Uses of Alkali Metals 6 10/8/2015 Bipolar Disorder Sodium Chloride NaCl 7 10/8/2015 NaCl & KCl Deicing Roads % Salt Melts at: 0% 32 oF 10% 20 oF 20% 2oF The Alkaline Earth Metals 8 10/8/2015 The Alkaline Metals 9 10/8/2015 The Alkaline Earth Metals ►► Made up of all the Group 2 elements Characteristics ►► Shiny ►► Malleable ►► Ductile ►► Very reactive (but less than alkali metals) ►► Each atom has two valence electrons, meaning it can bond with two other atoms You know the properties of alkaline earth metals so let’s look at their uses… ►►Beryllium ––emeraldsemeralds (most valuable) ►►Magnesium ––burning,burning, white fireworks light, baseball bats, spaceships ►►Calcium ––milk,milk, bones, teeth, limestone (our water!) ►►Barium ––absorbsabsorbs x--raysx rays to diagnose digestive disorders 10 10/8/2015 Beryllium 11 10/8/2015 Magnesium 12 10/8/2015 Calcium 13 10/8/2015 Barium 14 10/8/2015 15 10/8/2015 Transition Metals Groups 33--1212 16 10/8/2015 Transition Metals ►►Properties ►►Same as alkali & alkaline earth metals, except they are less reactive on their own. ►►Examples: °° Copper, silver, gold, iron, aluminum, etc. ►►Magnets ––iron,iron, cobalt, nickel ►►Coinage ––copper,copper, silver, gold ►►Group 12 ––zinc,zinc, cadmium, mercury Iron, Cobalt, Nickel ►►The only known elements that generate a magnetic field (more on this later) 17 10/8/2015 Copper, Silver, Gold ►► Called “coinage” metals because of their historic use as coins. ►► These metals are very unreactive, so they are often found alone in nature 18 10/8/2015 Panning for Gold Gold Mine 19 10/8/2015 Zinc, Cadmium, Mercury (Group 12) ►►Zinc ––usedused to coat other metals because it forms an unreactive surface (protection) ►►Cadmium ––usedused in plating and rechargeable batteries ►►Mercury ––aa silvery liquid used in thermometers, thermostats, batteries, etc. °° Highly poisonous to humans, though common due to its accumulation in fish high in the food chain Zinc 20 10/8/2015 Cadmium Mercury 21 10/8/2015 The only metal liquid at room temperat ure 22 10/8/2015 The Aquatic Food Chain Effects of mercury on fetal development ►►Reduced shortshort--termterm memory ►►Lowered attention span ►►Reduced language skills ►►Don’t eat fish that are high up the food chain when pregnant! 23 10/8/2015 The End! 24.

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Promotion Effects and Mechanism of Alkali Metals and Alkaline Earth

Subscriber access provided by RES CENTER OF ECO ENVIR SCI Article Promotion Effects and Mechanism of Alkali Metals and Alkaline Earth Metals on Cobalt#Cerium Composite Oxide Catalysts for N2O Decomposition Li Xue, Hong He, Chang Liu, Changbin Zhang, and Bo Zhang Environ. Sci. Technol., 2009, 43 (3), 890-895 • DOI: 10.1021/es801867y • Publication Date (Web): 05 January 2009 Downloaded from http://pubs.acs.org on January 31, 2009 More About This Article Additional resources and features associated with this article are available within the HTML version: • Supporting Information • Access to high resolution figures • Links to articles and content related to this article • Copyright permission to reproduce figures and/or text from this article Environmental Science & Technology is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Environ. Sci. Technol. 2009, 43, 890–895 Promotion Effects and Mechanism such as Fe-ZSM-5 are more active in the selective catalytic reduction (SCR) of N2O by hydrocarbons than in the - ° of Alkali Metals and Alkaline Earth decomposition of N2O in a temperature range of 300 400 C (3). In recent years, it has been found that various mixed Metals on Cobalt-Cerium oxide catalysts, such as calcined hydrotalcite and spinel oxide, showed relatively high activities. Composite Oxide Catalysts for N2O One of the most active oxide catalysts is a mixed oxide containing cobalt spinel. Calcined hydrotalcites containing Decomposition cobalt, such as Co-Al-HT (9-12) and Co-Rh-Al-HT (9, 11), have been reported to be very efﬁcient for the decomposition 2+ LI XUE, HONG HE,* CHANG LIU, of N2O.
The Periodic Electronegativity Table

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Stable Isotopes of Cobalt Properties of Cobalt

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An Alternate Graphical Representation of Periodic Table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt

An Alternate Graphical Representation of Periodic table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt. Ltd, Hyderabad, India. [email protected] Abstract Periodic table of chemical elements symbolizes an elegant graphical representation of symmetry at atomic level and provides an overview on arrangement of electrons. It started merely as tabular representation of chemical elements, later got strengthened with quantum mechanical description of atomic structure and recent studies have revealed that periodic table can be formulated using SO(4,2) SU(2) group. IUPAC, the governing body in Chemistry, doesn‟t approve any periodic table as a standard periodic table. The only specific recommendation provided by IUPAC is that the periodic table should follow the 1 to 18 group numbering. In this technical paper, we describe a new graphical representation of periodic table, referred as „Circular form of Periodic table‟. The advantages of circular form of periodic table over other representations are discussed along with a brief discussion on history of periodic tables. 1. Introduction The profoundness of inherent symmetry in nature can be seen at different depths of atomic scales. Periodic table symbolizes one such elegant symmetry existing within the atomic structure of chemical elements. This so called „symmetry‟ within the atomic structures has been widely studied from different prospects and over the last hundreds years more than 700 different graphical representations of Periodic tables have emerged [1]. Each graphical representation of chemical elements attempted to portray certain symmetries in form of columns, rows, spirals, dimensions etc. Out of all the graphical representations, the rectangular form of periodic table (also referred as Long form of periodic table or Modern periodic table) has gained wide acceptance.
Cobalt Publications Rejected As Not Acceptable for Plants and Invertebrates

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The Development of the Periodic Table and Its Consequences Citation: J

Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1.
Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel

THESIS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM Department of Chemical and Biological Engineering CHALMERS UNIVERSITY OF TECHNOLOGY Gothenburg, Sweden, 2012 Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM ISBN 978-91-7385-751-2 © EMMA H. K. ANEHEIM, 2012. Doktorsavhandlingar vid Chalmers tekniska högskola Ny serie Nr 3432 ISSN 0346-718X Department of Chemical and Biological Engineering Chalmers University of Technology SE-412 96 Gothenburg Sweden Telephone + 46 (0)31-772 1000 Cover: Radiotoxicity as a function of time for the once through fuel cycle (left) compared to one P&T cycle using the GANEX process (right) (efficiencies: partitioning from Table 5.5.4, transmutation: 99.9%). Calculations performed using RadTox [HOL12]. Chalmers Reproservice Gothenburg, Sweden 2012 Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM Department of Chemical and Biological Engineering Chalmers University of Technology Abstract When uranium is used as fuel in nuclear reactors it both undergoes neutron induced fission as well as neutron capture. Through successive neutron capture and beta decay transuranic elements such as neptunium, plutonium, americium and curium are produced in substantial amounts. These radioactive elements are mostly long-lived and contribute to a large portion of the long term radiotoxicity of the used nuclear fuel. This radiotoxicity is what makes it necessary to isolate the used fuel for more than 100,000 years in a final repository in order to avoid harm to the biosphere.
The Periodic Table of Elements

The Periodic Table of Elements 1 2 6 Atomic Number = Number of Protons = Number of Electrons HYDROGENH HELIUMHe 1 Chemical Symbol NON-METALS 4 3 4 C 5 6 7 8 9 10 Li Be CARBON Chemical Name B C N O F Ne LITHIUM BERYLLIUM = Number of Protons + Number of Neutrons* BORON CARBON NITROGEN OXYGEN FLUORINE NEON 7 9 12 Atomic Weight 11 12 14 16 19 20 11 12 13 14 15 16 17 18 SODIUMNa MAGNESIUMMg ALUMINUMAl SILICONSi PHOSPHORUSP SULFURS CHLORINECl ARGONAr 23 24 METALS 27 28 31 32 35 40 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 POTASSIUMK CALCIUMCa SCANDIUMSc TITANIUMTi VANADIUMV CHROMIUMCr MANGANESEMn FeIRON COBALTCo NICKELNi CuCOPPER ZnZINC GALLIUMGa GERMANIUMGe ARSENICAs SELENIUMSe BROMINEBr KRYPTONKr 39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 RUBIDIUMRb STRONTIUMSr YTTRIUMY ZIRCONIUMZr NIOBIUMNb MOLYBDENUMMo TECHNETIUMTc RUTHENIUMRu RHODIUMRh PALLADIUMPd AgSILVER CADMIUMCd INDIUMIn SnTIN ANTIMONYSb TELLURIUMTe IODINEI XeXENON 85 88 89 91 93 96 98 101 103 106 108 112 115 119 122 128 127 131 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 CESIUMCs BARIUMBa HAFNIUMHf TANTALUMTa TUNGSTENW RHENIUMRe OSMIUMOs IRIDIUMIr PLATINUMPt AuGOLD MERCURYHg THALLIUMTl PbLEAD BISMUTHBi POLONIUMPo ASTATINEAt RnRADON 133 137 178 181 184 186 190 192 195 197 201 204 207 209 209 210 222 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 FRANCIUMFr RADIUMRa RUTHERFORDIUMRf DUBNIUMDb SEABORGIUMSg BOHRIUMBh HASSIUMHs MEITNERIUMMt DARMSTADTIUMDs ROENTGENIUMRg COPERNICIUMCn NIHONIUMNh
The Group 1A and Group 2A Elements

Cotton chapter 10,11 Group 1A Group 1A Qualitative alkali metal analysis Alkali Metals y The group 1A elements with their ns1 valence electron configurations are very active metals. They lose their valence electrons very readily. They have low ionization energies and react with nonmetals to form ionic solids. 2Na(s) +Cl2(g) Æ 2NaCl(s) y The expected trend in reducing ability, Cs>Rb>K>Na>Li y Alkali metals all react vigorously with water to release hydrogen gas. + ‐ 2M(s) +2H2O(l) Æ 2M (aq) +2OH(aq) +H2(g) y Observed reducing abilities: Li>K>Na First ionization energy Soda production Properties and Trends in Group 1A y The Group 1A metals exhibit regular trends for a number of properties. y Irregular trends suggest that factors are working against each other in determining a property (such as the density “discrepancy” between sodium and potassium). y The alkali metals have two notable physical properties: they are all soft and have low melting points. y When freshly cut, the alkali metals are bright and shiny—typical metallic properties. The metals quickly tarnish, however, as they react with oxygen in the air. Alkali Metal Oxides In the presence of ample oxygen, 4Li + O2 → 2Li2O(regularoxide) 2Na + O2 → Na2O2 (peroxide) K+O2 → KO2 (superoxide) Rb + O2 → RbO2 (superoxide) Cs + O2 → CsO2 (superoxide) The oxides of Group 1A Direct reaction of the alkali metals with O2 gives : Li ‐> oxide, peroxide (trace) Na ‐> peroxide , oxide (trace) K,Rb,Cs ‐> superoxide Diagonal Relationships: The Special Case of Lithium In some of its properties, lithium and its compounds resemble magnesium and its compounds.
TEK 8.5C: Periodic Table

Name: Teacher: Pd. Date: TEK 8.5C: Periodic Table TEK 8.5C: Interpret the arrangement of the Periodic Table, including groups and periods, to explain how properties are used to classify elements. Elements and the Periodic Table An element is a substance that cannot be separated into simpler substances by physical or chemical means. An element is already in its simplest form. The smallest piece of an element that still has the properties of that element is called an atom. An element is a pure substance, containing only one kind of atom. The Periodic Table of Elements is a list of all the elements that have been discovered and named, with each element listed in its own element square. Elements are represented on the Periodic Table by a one or two letter symbol, and its name, atomic number and atomic mass. The Periodic Table & Atomic Structure The elements are listed on the Periodic Table in atomic number order, starting at the upper left corner and then moving from the left to right and top to bottom, just as the words of a paragraph are read. The element’s atomic number is based on the number of protons in each atom of that element. In electrically neutral atoms, the atomic number also represents the number of electrons in each atom of that element. For example, the atomic number for neon (Ne) is 10, which means that each atom of neon has 10 protons and 10 electrons. Magnesium (Mg) has an atomic number of 12, which means it has 12 protons and 12 electrons.
Where Is Water on the Periodic Table

Where Is Water On The Periodic Table Grum Jess regrown some tirls and risk his creepies so ambrosially! Roderigo is edaphic: she libel ahold and budges her barm. Corrugate and percipient Ford never digitized lickerishly when Janos literalising his ultrafilter. Unsubscribe from rivers from three particles in marah was it is where water on the periodic table The periodic tables is where compounds is a question yourself. Periodic table organized his element does not the water where is on oxygen and silicon does the universe and the sight of concentration and. In the marine environment. The table is where it is generally halogens are. An appreciation of water resources, data for gym, make tungsten gets very sophisticated pieces of oxo anions. Tcp connection time is table is on the water periodic. In the 9th century BC a Spartan lawgiver invented a drinking cup that could go mud stick missing its turn Later on the posture of medicine Hippocrates developed a device called the Hippocrates Sleeve a cloth bag weight was used to strain boiled rain water eliminating hoarseness and even smell. His law that is an apartment building large version of a ratio of where water was given element in open a pond would accumulate at an outer shells need. On their properties? Free 2-day shipping Buy Chemistry Elements Pet Mat the Food make Water Periodic Table of Elements in Green Shades Education Themed Non-Slip Rubber. The wall of the cell is the plasma membrane that controls the rate and type of ions and molecules passing into and out of the cell.
Preparation of Barium Strontium Titanate Powder from Citrate

APPLIED ORGANOMETALLIC CHEMISTRY Appl. Organometal. Chem. 13, 383–397 (1999) Preparation of Barium Strontium Titanate Powder from Citrate Precursor Chen-Feng Kao* and Wein-Duo Yang Department of Chemical Engineering, National Cheng Kung University, Tainan, 70101, Taiwan TiCl4 or titanium isopropoxide reacted with INTRODUCTION citric acid to form a titanyl citrate precipitate. Barium strontium citrate solutions were then BaTiO3 is ferroelectric and piezoelectric and has added to the titanyl citrate reaction to form gels. extensive applications as an electronic material. It These gels were dried and calcined to (Ba,Sr)- can be used as a capacitor, thermistor, transducer, TiO3 powders. The gels and powders were accelerometer or degausser of colour television. characterized by DSC/TGA, IR, SEM and BaTiO3 doped with strontium retains its original XRD analyses. These results showed that, at characteristics but has a lower Curie temperature 500 °C, the gels decomposed to Ba,Sr carbonate for positive temperature coefﬁcient devices under and TiO2, followed by the formation of (Ba,Sr)- various conditions. TiO3. The onset of perovskite formation oc- Besides solid-state reactions, chemical reactions curred at 600 °C, and was nearly complete at have also been used to prepare BaTiO3 powder. 1 1000 °C. Traces of SrCO3 were still present. Among them the hydrolysis of metal alkoxide , The cation ratios of the titanate powder oxalate precipitation in ethanol2, and alcoholic prepared in the pH range 5–6 were closest to dehydration of citrate solution3 are among the more the original stoichiometry. Only 0.1 mol% of the attractive methods. In 1956 Clabaugh et al.4 free cations remained in solution.