Development of Scenarios for Drinking Water Produced from Groundwater and Surface Water for Use in the Pesticide Registration Procedure of Ethiopia
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Alterra Wageningen UR Alterra Wageningen UR is the research institute for our green living environment. P.O. Box 47 We offer a combination of practical and scientific research in a multitude of Development of scenarios for drinking 6700 AA Wageningen disciplines related to the green world around us and the sustainable use of our living The Netherlands environment, such as flora and fauna, soil, water, the environment, geo-information T +31 (0) 317 48 07 00 and remote sensing, landscape and spatial planning, man and society. water produced from groundwater and www.wageningenUR.nl/en/alterra The mission of Wageningen UR (University & Research centre) is ‘To explore surface water for use in the pesticide Alterra Report 2674 the potential of nature to improve the quality of life’. Within Wageningen UR, ISSN 1566-7197 nine specialised research institutes of the DLO Foundation have joined forces with Wageningen University to help answer the most important questions in the registration procedure of Ethiopia domain of healthy food and living environment. With approximately 30 locations, 6,000 members of staff and 9,000 students, Wageningen UR is one of the leading P.I. Adriaanse, M.M.S. Ter Horst, B.M. Teklu, J.W. Deneer, A. Woldeamanuel and J.J.T.I. Boesten organisations in its domain worldwide. The integral approach to problems and the cooperation between the various disciplines are at the heart of the unique Wageningen Approach. Development of scenarios for drinking water produced from groundwater and surface water for use in the pesticide registration procedure of Ethiopia P.I. Adriaanse, M.M.S. Ter Horst, B.M. Teklu, J.W. Deneer, A. Woldeamanuel and J.J.T.I. Boesten This research was partly funded by the Dutch Ministry for Foreign Affairs/Development Cooperation (project 5237663-03). Alterra Wageningen UR Wageningen, May 2015 Alterra report 2674 ISSN 1566-7197 Adriaanse, P.I., M.M.S. Ter Horst, B.M. Teklu, J.W. Deneer, A. Woldeamanuel and J.J.T.I. Boesten, 2015. Development of scenarios for drinking water produced from groundwater and surface water for use in the pesticide registration procedure of Ethiopia. Wageningen, Alterra Wageningen UR (University & Research centre), Alterra report 2674. 310 pp.; 42 fig.; 40 tab.; 24 ref. In the Pesticide Risk Reduction Programme Ethiopia the evaluation of risks of pesticides present in drinking water for man and cattle was selected as a priority protection goal. In cooperation with the Plant Health Regulatory Department of the Ministry of Agriculture of Ethiopia and other Ethiopian stakeholders Alterra developed a procedure to assess the risks for drinking water caused by pesticides, used according to Good Agricultural Practices (GAP). To do so, ‘realistic worst case’ scenarios were developed, that intend to protect man and cattle in 99% of all possible situations in Ethiopia. For groundwater three scenarios representing wells in aquifers in the Ethiopian highlands or Rift Valley margins were developed and for surface water three scenarios representing small rivers in the highlands or temporay stagnant ponds were developed. The scenarios were linked to crops on which pesticides are used that score high on acute, chronic or local chronic risk for man. In addition other agro-environmental conditions were defined, such as precipitation, soil, and land use management. The groundwater scenarios were parameterised in the EuroPEARL metamodel to calculate leaching concentrations to groundwater, whereas the surface water scenarios make use of the runoff model PRZM, the EU-FOCUS spray drift deposition table and the surface water model TOXSWA to calculate the concentration in the small river or pond scenarios. The concentration calculations use 33 years of meteorological data for the selected scenario sites of both groundwater and surface water. Example calculations for seven high risk compounds (dimethoate, endosulfan, deltamethrin, 2,4-D, malathion, atrazine and chlorothalonil) on e.g. barley, wheat, teff, maize, cotton, potatoes (Irish and sweet) and faba beans indicated that for the considered application schemes risks exist for drinking water produced from groundwater for atrazine. For surface water no acute toxicity risks exist, but for dimethoate used on barley and faba beans chronic toxicity risks exist. Keywords: pesticide registration, Ethiopia, risks for drinking water, groundwater scenarios, surface water scenarios, EuroPEARL metamodel, FOCUS_PRZM model, FOCUS_TOXSWA model The pdf file is free of charge and can be downloaded via the website www.wageningenUR.nl/en/alterra (scroll down to Publications - Alterra reports). Alterra does not deliver printed versions of the Alterra reports. 2015 Alterra (an institute under the auspices of the Stichting Dienst Landbouwkundig Onderzoek), P.O. Box 47, 6700 AA Wageningen, The Netherlands, T +31 (0)317 48 07 00, E [email protected], www.wageningenUR.nl/en/alterra. Alterra is part of Wageningen UR (University & Research centre). • Acquisition, duplication and transmission of this publication is permitted with clear acknowledgement of the source. • Acquisition, duplication and transmission is not permitted for commercial purposes and/or monetary gain. • Acquisition, duplication and transmission is not permitted of any parts of this publication for which the copyrights clearly rest with other parties and/or are reserved. Alterra assumes no liability for any losses resulting from the use of the research results or recommendations in this report. Alterra report 2674 | ISSN 1566-7197 Photo cover: Shutterstock Contents List of abbreviations 7 Preface 9 Summary 11 1 Introduction 15 1.1 Country of Ethiopia 15 1.2 Pesticide registration in Ethiopia 16 1.3 Structure of the report 17 2 Outline of the exposure scenario development procedure 18 2.1 Roadmap for developing scenarios for drinking water produced from groundwater and surface water 18 2.2 Target variables of the exposure assessments 21 2.2.1 Protection goals 21 2.2.2 Risk management decisions 22 2.2.3 Operational decisions 23 2.3 Position in the tiered assessment scheme 24 3 Approach to estimate risks for drinking water produced from surface water and groundwater 25 3.1 Introduction and general principles 25 3.2 Acute and chronic risks for drinking water produced from groundwater and surface water 27 3.3 Definition of exposure scenarios and probability in time and space 28 4 Agro-environmental characteristics and identification of the most relevant pesticides and crops 31 4.1 Geography, crops, soils, meteorology and agro-ecological zones in Ethiopia 31 4.2 Ranking of pesticide risk for surface water 40 4.3 Ranking of pestide risk for groundwater 44 5 Identification of scenario zones and drinking water protection goals 47 5.1 Choice for scenario zones 47 5.2 Groundwater 49 5.2.1 Options for protection goals and selection 49 5.2.2 Conceptual models for protection goals and association to scenario zones 50 5.3 Surface water 52 5.3.1 Options for protection goals, selection and association to scenario zones 52 5.3.2 Conceptual models for protection goals 53 6 Selected models/modules 56 6.1 EuroPEARL metamodel for leaching to groundwater 56 6.2 Models and modules for calculation of concentrations in surface water 57 6.2.1 Spray drift deposition: EU_FOCUS tables 57 6.2.2 Runoff, erosion and subsurface drainage: FOCUS_PRZM_SW model 58 6.2.3 Behaviour in streams: FOCUS_stream metamodel 58 6.2.4 Behaviour in ponds: slightly adapted FOCUS_TOXSWA model 59 7 Design of scenario selection procedure 60 7.1 Drinking water produced from groundwater 60 7.2 Drinking water produced from surface water 62 8 Selection of scenarios for specific protection goals in Ethiopia 67 8.1 Groundwater scenarios for Ethiopia 67 8.1.1 Introduction 67 8.1.2 Input for the EuroPEARL metamodel 67 8.1.3 Application of the scenario location selection procedure 68 8.1.4 Results for the groundwater protection goals 69 8.2 Surface water scenarios for Ethiopia 72 8.2.1 Introduction 72 8.2.2 Application of the scenario selection procedure 72 8.2.3 Results of the scenario selection procedure for the surface water protection goals 73 9 Calculation of concentrations in groundwater and surface water 76 9.1 Groundwater 76 9.2 Surface water 76 9.2.1 Type of concentration and percentiles 76 9.2.2 Procedure for small streams 78 9.2.3 Procedure for temporary ponds 78 10 Ground water scenarios: Parameterisation of the EuroPEARL model 80 11 Surface water scenarios: Parameterisation of the FOCUS_PRZM model 82 11.1 Introduction 82 11.2 Soil and Runoff Curve Numbers (FOCUS R4 scenario) 82 11.3 Meteorological data 83 11.4 Crop data 84 11.5 Irrigation 87 11.6 Remaining PRZM input 88 11.7 PRZM example input file 88 12 Surface water scenarios: Parameterisation of the FOCUS_stream metamodel and the adapted FOCUS_TOXSWA model 89 12.1 FOCUS_stream metamodel 89 12.1.1 Variable water and pesticide fluxes 89 12.1.2 Base flow 89 12.2 The adapted FOCUS_TOXSWA model 89 12.2.1 Introduction 89 12.2.2 The EU FOCUS R1 pond 89 12.2.3 Water temperatures 90 12.2.4 Base flow 91 12.2.5 Spray drift deposition 91 12.2.6 Pesticide properties 91 12.2.7 Sediment segmentation 91 13 Example calculations 93 13.1 Selection of compounds 93 13.2 Groundwater: exposure and risks for drinking water 95 13.3 Surface water: exposure and risks for drinking water 98 14 Calculation of risks using the PRIMET_Registration_Ethiopia_1.1 software 114 15 Conclusions and recommendations 116 15.1 General conclusions 116 15.2 Recommendations 117 References 119 Appendix 4.1 Background information on the