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Expanded Vapor Phase Library

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Expanded Vapor Phase Library Index Number Compound Name Index Number Compound Name 1 Methane 43 3-Methylheptane 2 Ethane 44 4-Methylheptane 3 Propane 45 2-Methyloctane 4 Butane 46 2-Methylnonane 5 Pentane 47 3-Methylnonane 6 Hexane 48 4-Methylnonane 7 Hexanes 49 3-Methylundecane 8 Heptane 50 2,2-Dimethylbutane 9 Octane 51 2,3-Dimethylbutane 10 Nonane 52 2,2-Dimethylpentane 11 Decane 53 2,3-Dimethylpentane 12 Undecane; Hendecane 54 3,3-Dimethylpentane 13 Dodecane 55 2,4-Dimethylpentane 14 Tridecane 56 2,2-Dimethylhexane 15 Tetradecane 57 2,4-Dimethylhexane 16 Pentadecane 58 2,5-Dimethylhexane 17 Hexadecane 59 2,2-Dimethylheptane 18 Heptadecane 60 3,3-Dimethylheptane 19 Octadecane 61 6,11- 20 Nonadecane Dipentylhexadecane 21 Eicosane 62 2,2,3-Trimethylbutane 22 Heneicosane 63 2,2,3-Trimethylpentane 23 Docosane 64 2,2,4-Trimethylpentane 24 Tricosane 65 2,3,3-Trimethylpentane 25 Tetracosane 66 2,3,4-Trimethylpentane 26 Pentacosane 67 2,2,4-Trimethylhexane 27 Hexacosane 68 2,2,5-Trimethylhexane 28 Heptacosane 69 6,9,12- 29 Octacosane Tripropylheptadecane 30 Nonacosane 70 6,12-Diethyl-9- 31 Triacontane pentylheptadecane 32 Dotriacontane 71 Hexamethylethane; 33 Petroleum ether 2,2,3,3- 34 Mineral spirits; Ligroin Tetramethylbutane 35 2-Methylpropane; 72 2,6,10,14- Isobutane Tetramethylpentadecane 36 2-Methylbutane; 73 2,2,4,6,6- Isopentane Pentamethylheptane 37 2-Methylpentane; 74 2,2,4,4,6,8,8- Isohexane Heptamethylnonane 38 3-Methylpentane 75 Squalane; 39 3-Ethylpentane 2,6,10,15,19,23- 40 2-Methylhexane Hexamethyltetracosane 41 3-Methylhexane 76 Ethylene; Ethene 42 2-Methylheptane 77 Propylene; Propene Expanded Vapor Phase Library, page 1 of 159 Index Number Compound Name Index Number Compound Name 78 1-Butene 131 4-Methyl-2-pentene 79 1-Pentene 132 (Z)-4-Methyl-2-pentene 80 1-Hexene 133 2-Methyl-1-hexene 81 1-Heptene 134 2-Ethyl-1-hexene 82 1-Octene 135 3-Methyl-1-hexene 83 1-Nonene 136 2-Methyl-2-hexene 84 1-Decene 137 (E)-2-Methyl-3-hexene 85 1-Undecene 138 2-Methyl-1-heptene 86 1-Dodecene 139 2-Methyl-2-heptene 87 1-Tridecene 140 2-Methyl-1-nonene 88 1-Tetradecene 141 2-Methyl-1-undecene 89 1-Pentadecene 142 2,3-Dimethyl-1-butene 90 1-Hexadecene 143 3,3-Dimethyl-1-butene 91 1-Heptadecene 144 2,3-Dimethyl-2-butene 92 1-Octadecene 145 2,4-Dimethyl-1-pentene 93 1-Nonadecene 146 4,4-Dimethyl-1-pentene 94 1-Eicosene 147 2,3-Dimethyl-2-pentene 95 1-Docosene 148 2,4-Dimethyl-2-pentene 96 (Z)-2-Butene 149 (Z)-4,4-Dimethyl-2- 97 (E)-2-Butene pentene 98 2-Pentene, (E) + (Z) 150 (E)-4,4-Dimethyl-2- 99 (E)-2-Pentene pentene 100 (Z)-2-Pentene 151 2,3-Dimethyl-1-hexene 101 2-Hexene, (E) + (Z) 152 2,5-Dimethyl-2-hexene 102 (E)-2-Hexene 153 (E)-2,2-Dimethyl-3- 103 (E)-3-Hexene hexene 104 (Z)-2-Heptene 154 (E)-2,5-Dimethyl-3- 105 (E)-2-Heptene hexene 106 (Z)-3-Heptene 155 (Z)-2,5-Dimethyl-3- 107 (E)-3-Heptene hexene 108 (Z)-2-Octene 156 (E)-2,2-Dimethyl-3- 109 (E)-2-Octene heptene 110 (E)-3-Octene 157 2,6-Dimethyl-3-heptene 111 (E)-4-Octene 158 3,5-Dimethyl-3-heptene 112 (E)-2-Nonene 159 2,3,3-Trimethyl-1-butene 113 (E)-3-Nonene 160 2,4,4-Trimethyl-1- 114 4-Nonene, (E) + (Z) pentene 115 (E)-2-Decene 161 1,1-Dineopentylethylene; 116 (E)-5-Decene 4-Methylene-2,2,6,6- 117 (E)-7-Tetradecene tetramethylheptane 118 (Z)-9-Tricosene 162 2,4,4-Trimethyl-2- 119 (Z)-9-Heneicosene pentene 120 Isobutene; 2- 163 3,5,5-Trimethyl-1-hexene Methylpropene 164 2,2,4,6,6-Pentamethyl-3- 121 2-Methyl-1-butene heptene 122 3-Methyl-1-butene 165 Allene; Propadiene 123 2-Ethyl-1-butene 166 1,3-Butadiene; Bivinyl 124 2-Methyl-2-butene 167 Piperylene, (E) + (Z); 125 2-Methyl-1-pentene 1,3-Pentadiene, (E) + (Z) 126 3-Methyl-1-pentene 168 (Z)-Piperylene; (Z)-1,3- 127 4-Methyl-1-pentene Pentadiene 128 2-Methyl-2-pentene 169 (E)-Piperylene; (E)-1,3- 129 3-Methyl-2-pentene, (E) Pentadiene + (Z) 170 1,4-Pentadiene 130 3-Ethyl-2-pentene 171 (E)-1,3-Hexadiene Expanded Vapor Phase Library, page 2 of 159 Index Number Compound Name Index Number Compound Name 172 1,4-Hexadiene, (E) + (Z) 207 Squalene; 173 2,4-Hexadiene, (E) + (Z) 2,6,10,15,19,23- 174 (E,E)-2,4-Hexadiene Hexamethyltetracosa- 175 (E,Z)-2,4-Hexadiene 2,6,10,14,18,22-hexaene 176 1,5-Hexadiene 208 Cyclopropane 177 1,5-Heptadiene 209 Cyclopentane 178 1,4-Octadiene 210 Cyclohexane 179 1,6-Heptadiene 211 Cycloheptane 180 1,7-Octadiene 212 Cyclooctane 181 1,8-Nonadiene 213 Cyclodecane 182 1,9-Decadiene 214 Cyclododecane 183 3-Methyl-1,2-butadiene 215 Methylcyclopentane 184 Isoprene; 2-Methyl-1,3- 216 Ethylcyclopentane butadiene 217 Butylcyclopentane 185 (E)-2-Methyl-1,3- 218 Methylcyclohexane pentadiene 219 Ethylcyclohexane 186 2-Methyl-1,3-pentadiene, 220 Propylcyclohexane (E) + (Z) 221 Isopropylcyclohexane 187 3-Methyl-1,3-pentadiene, 222 Butylcyclohexane (E) + (Z) 223 (2-Butyl)cyclohexane; 2- 188 3-Methyl-1,4-pentadiene Cyclohexylbutane 189 2-Methyl-1,4-pentadiene 224 Isobutylcyclohexane 190 3-Methyl-1,5-hexadiene 225 t-Butylcyclohexane 191 2-Methyl-1,5-hexadiene 226 Pentylcyclohexane 192 3-Methyl-1,5-heptadiene 227 1-Cyclohexylhexane; 193 2,3-Dimethyl-1,3- Hexylcyclohexane butadiene 228 1-Cyclohexylheptane; 194 2,4-Dimethyl-1,3- Heptylcyclohexane pentadiene 229 1,1-Dimethylcyclohexane 195 2,5-Dimethyl-1,5- 230 1,2- hexadiene Dimethylcyclohexane, cis 196 2,5-Dimethyl-2,4- + trans hexadiene 231 1,2- 197 (Z)-2,6-Dimethyl-2,6- Dimethylcyclohexane, octadiene cis- 198 (+)-b-Citronellene; 3,7- 232 1,2- Dimethyl-1,6-octadiene Dimethylcyclohexane, 199 (R)-(+)-5,7-Dimethyl-1,6- trans- octadiene 233 1,3- 200 7-Methyl-3-methylene- Dimethylcyclohexane, cis 1,6-octadiene; Myrcene + trans 201 1,3,5-Hexatriene 234 1,3- 202 5-Methyl-1,3,6- Dimethylcyclohexane, heptatriene cis- 203 3,7-Dimethyl-1,3,6- 235 1,3- octatriene; b-Ocimene Dimethylcyclohexane, 204 (2E,6Z)-2,6-Dimethyl- trans- 2,4,6-octatriene; 236 1,4- Neoalloocimene Dimethylcyclohexane, cis 205 (E,E)-2,6-Dimethyl-2,4,6- + trans octatriene; Alloocimene 237 1,4- 206 (E)-1,4,9-Decatriene Dimethylcyclohexane, cis- 238 1-Dodecyl-4- octylcyclohexane, trans- Expanded Vapor Phase Library, page 3 of 159 Index Number Compound Name Index Number Compound Name 239 1-Hexyl-4- 265 6,6-Dimethylfulvene tetradecylcyclohexane, 266 1-Methyl-1-cyclohexene trans- 267 3-Methyl-1-cyclohexene 240 1,3,5- 268 4-Methyl-1-cyclohexene Triisopropylcyclohexane 269 1-Isopropyl-1- 241 Dicyclohexyl cyclohexene 242 Hexahydroindane; 270 1-t-Butyl-1-cyclohexene Bicyclo[4.3.0]nonane 271 1,3-Dimethyl-1- 243 Decahydronaphthalene, cyclohexene cis + trans; Decalin, cis + 272 1,4-Dimethyl-1- trans cyclohexene 244 Decahydronaphthalene, 273 4,4-Dimethyl-1- cis-; Decalin, cis- cyclohexene 245 Decahydronaphthalene, 274 1,3,5-Trimethyl-1- trans-; Decalin, trans- cyclohexene, cis + trans 246 Perhydrofluorene 275 (+)-p-Menth-1-ene 247 Norbornane; 276 (+)-p-Menth-2-ene Bicyclo[2.2.1]heptane 277 1,4-Diisopropyl-1- 248 (1R)-(+)-Pinane, cis-; cyclohexene (1R,2S)-(+)-2,6,6- 278 Dipentene; p-Mentha- Trimethylbicyclo[3.1.1]he 1,8-diene; 4-Isopropenyl- ptane 1-methylcyclohexene 249 (1R)-(+)-Pinane, trans-; 279 (R)-(+)-Limonene; (R)- (1R,2R)-(+)-2,6,6- (+)-p-Mentha-1,8-diene Trimethylbicyclo[3.1.1]he 280 (S)-(-)-Limonene; (S)-(-)- ptane p-Mentha-1,8-diene 250 Quadricyclane; 281 (+)-3R-Isolimonene, Tetracyclo[3.2.0.0(2,7).0( trans-; (1R,4R)-(+)-p- 4,6)]heptane Mentha-2,8-diene 251 1,7,7- 282 1-Methyl-1-cycloheptene Trimethyltricyclo[2.2.1.0( 283 Methylenecyclobutane 2,6)]heptane; Tricyclene 284 Methylenecyclopentane 252 Tricyclo[5.2.1.0(2,6)]deca 285 Ethylidenecyclopentane ne 286 Methylenecyclohexane 253 Adamantane; 287 Ethylidenecyclohexane Tricyclo[3.3.1.1(3,7)]deca 288 2-Carene; 3,7,7- ne Trimethylbicyclo[4.1.0]he 254 1,3- pt-2-ene Dimethyladamantane; 289 (+)-Camphene; 2,2- 1,3- Dimethyl-3- Dimethyltricyclo[3.3.1.1(3 methylenebicyclo[2.2.1]h ,7)]decane eptane 255 Cyclopentene 290 2,2-Dimethyl-3- 256 Cyclohexene methylenebicyclo[2.2.1]h 257 Cycloheptene eptane; Camphene 258 (Z)-Cyclooctene 291 1,1- 259 (Z)-Cyclodecene Dicyclopropylethylene 260 Cyclododecene 292 Vinylcyclopentane 261 1-Methyl-1-cyclopentene 293 Vinylcyclohexane 262 1-Ethyl-1-cyclopentene 294 Vinylcyclooctane 263 1,2,3,4,5- 295 Allylcyclopentane Pentamethylcyclopentadi 296 Allylcyclohexane ene 297 1,2-Divinylcyclohexane, 264 Ethyltetramethylcyclopen cis- tadiene Expanded Vapor Phase Library, page 4 of 159 Index Number Compound Name Index Number Compound Name 298 1,2,4- 324 5-Methyl-2-norbornene; Trivinylcyclohexane, 5- mixture of isomers Methylbicyclo[2.2.1]hept- 299 1,3-Cyclohexadiene 2-ene 300 1,4-Cyclohexadiene 325 (1S)-(-)-a-Pinene; 2,6,6- 301 1-Methyl-1,4- Trimethylbicyclo[3.1.1]he cyclohexadiene pt-2-ene 302 1-Ethyl-1,4- 326 (1R)-(+)-a-Pinene; 2,6,6- cyclohexadiene Trimethylbicyclo[3.1.1]he 303 4-Isopropyl-1-methyl-1,3- pt-2-ene cyclohexadiene; a- 327 2,6,6- Terpinene; p-Mentha- Trimethylbicyclo[3.1.1]he 1,3-diene pt-2-ene; a-Pinene 304 4-Isopropyl-1-methyl-1,4- 328 (+)-Sabinene; 1- cyclohexadiene; g- Isopropyl-4- Terpinene; p-Mentha- methylenebicyclo[3.1.0]h 1,4-diene exane; 4(10)-Thujene 305 a-Phellandrene; p- 329 (1S)-)-)-6,6-Dimethyl-2- Mentha-1,5-diene methylenebicyclo[3.1.1]h 306 1,2,4,5-Tetramethyl-1,4- eptane; (1S)-(-)-b-Pinene cyclohexadiene 330 b-Pinene; 6,6-Dimethyl- 307 4-Vinyl-1-cyclohexene 2- 308 1,2-Bis(3-cyclohexen-1- methylenebicyclo[3.1.1]h yl)ethylene eptane 309 4-Isopropylidene-1- 331 a-Humulene; (E,E,E)- methyl-1-cyclohexene; 2,6,6,9-Tetramethyl- Terpinolene; p-Mentha- 1,4,8-cycloundecatriene 1,4(8)-diene 332 5-Methylene-2- 310 1,3-Cycloheptadiene norbornene; 5- 311 (Z,Z)-1,3-Cyclooctadiene Methylenebicyclo[2.2.1]h 312 1,5-Cyclooctadiene
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    Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine
  • "Fluorine Compounds, Organic," In: Ullmann's Encyclopedia Of

    "Fluorine Compounds, Organic," In: Ullmann's Encyclopedia Of

    Article No : a11_349 Fluorine Compounds, Organic GU¨ NTER SIEGEMUND, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany WERNER SCHWERTFEGER, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany ANDREW FEIRING, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States BRUCE SMART, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States FRED BEHR, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States HERWARD VOGEL, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States BLAINE MCKUSICK, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States 1. Introduction....................... 444 8. Fluorinated Carboxylic Acids and 2. Production Processes ................ 445 Fluorinated Alkanesulfonic Acids ...... 470 2.1. Substitution of Hydrogen............. 445 8.1. Fluorinated Carboxylic Acids ......... 470 2.2. Halogen – Fluorine Exchange ......... 446 8.1.1. Fluorinated Acetic Acids .............. 470 2.3. Synthesis from Fluorinated Synthons ... 447 8.1.2. Long-Chain Perfluorocarboxylic Acids .... 470 2.4. Addition of Hydrogen Fluoride to 8.1.3. Fluorinated Dicarboxylic Acids ......... 472 Unsaturated Bonds ................. 447 8.1.4. Tetrafluoroethylene – Perfluorovinyl Ether 2.5. Miscellaneous Methods .............. 447 Copolymers with Carboxylic Acid Groups . 472 2.6. Purification and Analysis ............. 447 8.2. Fluorinated Alkanesulfonic Acids ...... 472 3. Fluorinated Alkanes................. 448 8.2.1. Perfluoroalkanesulfonic Acids
  • Aec-Nasa Tech Brief '11-41

    Aec-Nasa Tech Brief '11-41

    April 1970 Brief 70-10233 ))110)^ AEC-NASA TECH BRIEF '11-41 AEC-NASA Tech Briefs announce new technology derived from the research and development program of the U.S. AEC or from AEC-NASA interagency efforts. They are issued to encourage commercial application. Tech Briefs are available on a subscription basis from the Clearinghouse for Federal Scientific and Technical Information, Springfield, Virginia 22151. Requests for individual copies or questions relating to the Tech Brief program may be directed to the Technology Utilization Division, NASA, Code UT, Washington, D.C. 20546. Reactions of Technetium Hexafluoride with Nitric Acid, Nitrosyl Fluoride, and Nitryl Fluoride The problem: by weighing both starting materials and reaction To determine the reactions of technetium hexa- products in tared reaction vessels. fluoride with nitric oxide, nitrosyl fluoride, and nitryl Considerable difficulties were encountered in chemi- fluoride. The reactions of various hexafluorides with cal. analyses of the samples. In general, fluoride nitrogen oxides and nitrogen oxide fluorides have analyses were low owing to the exceptional stability recently been studied increasingly. In particular, the of the TcF 6 2 ion which is formed upon hydrolysis of reactions of third-transition-series hexafluorides with the solids. Technetium analyses were performed by nitric oxide and nitrosyl fluoride have been used for evaporation of aliquots of the solutions on platinum assessment of the relative oxidizing powers of these plates, and counting of the Tc 99 betas in a calibrated hexafluorides. Of the thermodynamically stable metal PCC-10 proportional counter having an overall geometry factor of 0.785. These results are somewhat . hexafluorides, least is known about technetium hexa- fluoride, possibly because the radioactivity of tech- uncertain because of self-absorption of the soft betas netium has inhibited experimental work.
  • Megalomania's Controversial Chem Lab

    Megalomania's Controversial Chem Lab

    Megalomania's Controversial Chem Lab Navigation Welcome to the Controversial Chem Lab. Here at the Chem Lab you » Home can find information on a large number of chemicals that have a » Explosives certain stigma attached to them. Chemicals such as explosives, drugs, and pesticides are vitally important for the survival of our civilization. » Chemical Unfortunately, the scientific elite jealously hoards the knowledge on Weapons using and preparing these chemicals. Adding to the confusion is the » Pharmaceuticals scientific ignorant who fear chemistry and think these chemicals are » Pesticides dangerous. As my chemistry professor used to say about what they think, “chemistry equals bad.” » Precursors The Controversial Chem Lab was created to be a free reference on » Lab Skills how to synthesize chemicals. It is also a virtual laboratory skills » Lab Equipment manual, complete with descriptions on how to conduct laboratories, » Safety and a visual database on many different kinds of laboratory apparatus. While the Chem Lab is written for the non-chemist audience, it does » Rogue Science require a basic understanding of laboratory skills. Of course, all of the » Links information needed to acquire a basic understanding of lab skills is » What’s New included within the site. The Chem Lab even goes the extra mile in providing information on » Contact Me how to synthesize many of the chemicals used in making explosives, » Disclaimer etc. It also provides information on where to acquire certain chemicals » Search this site and apparatus. While all of this information is perfectly legal, it may be against the law in certain areas to prepare some of these chemicals without the proper license.