180th Technical Meeting of the ACS Rubber Division & Advanced Materials in Health Care 2011
Cleveland, Ohio, USA
11-13 October 2011
Volume 1 of 2
ISBN: 978-1-61839-311-1 ISSN: 1547-1977 Printed from e-media with permission by:
Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571
Some format issues inherent in the e-media version may also appear in this print version.
Copyright© (2011) by the Rubber Division, ACS All rights reserved.
Printed by Curran Associates, Inc. (2011)
For permission requests, please contact the Rubber Division, ACS at the address below.
Rubber Division, ACS PO Box 499 Akron, OH 44309-0499
Phone: (330) 972-7814 Fax: (330) 972-5574 [email protected]
Additional copies of this publication are available from:
Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2634 Email: [email protected] Web: www.proceedings.com TABLE OF CONTENTS
VOLUME 1
TUESDAY MORNING
SESSION A – ADVANCES IN MATERIALS AND TIRE TECHNOLOGY
Using Sulfron to Improve Rolling Resistance and Durability of Tires...... 1 Nico Huntink, Tony Mathew, Mukund Tiwari, Sarah Parker, Teijin Aramid
Investigation Of The Influence Of Stearic Acid On Rubber–Brass Adhesion...... 21 Elisabeth Ziegler, Johannes Macher, Dieter Gruber, Peter Polt, Wolfgang Kem, Thomas Lummerstorfer, Claudia Feldgitscher, Armin Holzner, Gregor Trimmel
Novel And Advanced Bio-Based Engineering Elastomers Ang Biodegradable Elastomers ...... 47 Liqun Zhang, Hailan Kang, Runguo Wang, Zhao Wang, Yan Wu, Tao Wei, Kuo-Chi Hua
Usage of Low-Viscosity HNBR Polymers to Increase Productivity in High-Shear Molding Methods ...... 77 Andy Anderson, Mark Jones
SESSION B – CONTRIBUTED SESSION
New Product Specification Development Process For Silicone Rubber ...... 107 C. W. Olsen Jr., H. D. Mun, J. H. Choi, S. S. Eun, Y. S. Heo
Testing of AEM and FKM Compounds in Acid Condensates for Turbocharger Systems...... 117 Edward McBride, K. Kammerer, L. Lefebvre
Review Of Intellectual Property Law Applicable To The Rubber And Plastics Industry...... 140 Jacob M. Ward, J. Douglas Miller
The Origin Of Strength Of Natural Rubber Studied By Synchrotron X-Ray: Network In Raw Rubber And Vulcanized Rubber...... 149 Shigeyuki Toki, Justin Che, Lixia Rong, Benjamin S. Hsiao, Adul Nimpaiboon, Jitladda Sakdapipanich
Strain-Induced Crystallization of Pre- and Post-Vulcanized Natural Rubber Latex During Uniaxial Deformation by In-Situ Synchrotron X-Ray Diffraction...... 161 Justin Che, Shigeyuki Toki, Lixia Rong, Benjamin S. Hsiao, Juan Valentin, Justo Brasero
SESSION C – NEW COMMERCIAL DEVELOPMENTS
Durability Testing Of Silicone Materials For Proton Exchange Membrane Fuel Cell Use...... 186 S. Bhargava, K. A. O'Leary, T. C. Jackson, B. Lakshmanan
A Versatile Sponge Grade Combining Easy Processing With Excellent Physical Properties...... 200 Graham Choonoo, Michiel Dees, Philip Hough
Kneader Technology For The Direct Devolatilization Of Temperature Sensitive Elastomers ...... 222 Boyd T. Safrit, Andreas E. Diener
A New Natural Product that Lowers Compound Costs and Produces a Greener Rubber Compound…The Next Generation of Kaolin...... 233 Doug Carter, Mark Beavers
Novel Silica Coated Iron Oxide, “MAGSILICA®” for Speed Up Crosslinking in Rubber ...... 244 Orawan Taikum, Andrea Korch, Rainer Friehmelt, Frank Minister, Mario Scholz, Harald Herzog, Stipan Katusic
An Enhanced Corrosion Protection Mechanism for Rubber-to-Metal Bonding...... 263 Paul Mills, Tony Hall, Jake Adams
TUESDAY AFTERNOON
SESSION A – ADVANCES IN MATERIALS AND TIRE TECHNOLOGY
Evaluation of Antidegradants Systems for Enhancing Performance of Bromobutyl Based Tire Innerliners...... 279 Bernard D'Cruz, Bharat B. Sharma, Brendan Rodgers
Effects Of Filler Morphology On Tire Innerliner Permeability: A Computational Study...... 306 T. C. Gruber, S. D. Crossley, A. P. Smith
A New Constitutive Equation To Include The Mullins Effect...... 323 Goang-Ding Shyu
Influence Of ZnO And Stearic Acid On The Hydrophobation Reaction Of Silica ...... 345 Anke Blume
SESSION B – NANOSTRUCTURE AND FUNCTIONAL ELASTOMERS
Mapping Storage Modulus And Loss Modulus Of Polyolefin/Polystyrene Blends With Atomic Force Microscopy ...... 362 Dalia G. Yablon, Roger Proksch, Anil Gannepalli, Andy H. Tsou
Loss Tangent Imaging with Atomic Force Microscopy...... 375 Roger Proksch, Dalia Yablon
Preparation, Structure And Properties Of The Nano-Reinforced Thermal Conductive Rubber Composites ...... 390 Yong-Lai Lu, Li-Qun Zhang, Yao-Ling Feng, Zhen-Hua Wang, Jin-Bo Ding
Functional Imidazolium Ionomer Derivatives of Isobutylene-Rich Elastomers...... 416 J. Scott Parent, Adam Ozvald, Ralph A. Whitney
Curing Studies Of Magnetorheological Elastomers...... 427 C. Hintze, G. Heinrich
SESSION C – AEROSPACE AND ENGINEERING APPLICATIONS OF RUBBER
An Investigation in the Use and Performance of Diatomaceous Earth in an EPDM Rubber Gasket for Domestic Laundry Application...... 437 Rajendra K. Singh, Andy Riley, Kelvin Thomas
Improved Media Resistance - A Comprehensive Study ...... 467 Konstantin Zoumis
WEDNESDAY MORNING
SESSION A – ADVANCES IN MATERIALS AND TIRE TECHNOLOGY
Novel Functionalized SSBR For Silica- & Carbon Black-Containing Tires...... 483 Sven K. H. Thiele, Susanne Knoll
Comparative Study of Silica, Carbon Black and Novel Fillers in Tread Compounds ...... 504 Cynthia M. Flanigan, Laura Beyer, David Klekamp, David Rohweder
Nano And Nanostructured Fillers And Their Synergistic Behavior In Rubber Composites Such As Tires...... 536 Maurizio Galimberti, Michele Coombs, Valeria Cipolletti, Luca Giannini, Lucia Conzatti, Theonis Ricco, Marco Mauro, Gaetano Guerra
High Performance Silicas Reinforced Elastomers : From Standard Technology To Advanced Solutions ...... 600 Soline Daudey, Laurent Guy
The Use of a Surface-Modified Carbon Black with an In-Chain Functionalized Solution SSBR as an Alternative to Higher Cost Green Tire Technology...... 634 Judy Douglas, Steve Crossley, Joseph Hallett, John Curtis, Dave Hardy, Thomas Gross, Norbert Steinhauser, Alex Lucassen, Heike Kloppenburg
SESSION B – NANOSTRUCTURE AND FUNCTIONAL ELASTOMERS
Strength Enhancement from Heterogeneous Networks ...... 676 C. M. Roland, G. S. Buckley, D. Fragiadakis
Dynamic Heterogeneity in Polymers – How Many Chain Segments Must Move So That One Can Move? ...... 688 C. M. Roland, D. Fragiadakis, R. Casalini
Rubber Microfibers With Morphological Stability Prepared Through Combination Of Electrospinning And In-Situ Chemical Crosslinking...... 704 Ming Tian, Xiuying Zhao, Qinghua Hu, Haiyan Wu, Hao Fong, Liqun Zhang
Mussel-Mimetic Elastomers Of Varied Functionality Design For Nanocomposites ...... 717 Xiao-Dong Pan, Yuan-Yong Yan, Zengquan Qin, Dennis R. Brumbaugh, Pat Sadhukhan
Characterization of Phase Separated Structure and Interface in SBR/NBR Blend by AFM and DSC ...... 749 Junhyeok Jang, Masayuki Kawazoe, Hirohisa Yoshida
Surface Modification Of Carbonnanotubes By Poly(Dopamine) Coatings And Its Application In The Nature Rubber/MWCNTS Nanocomposites ...... 761 Wencai Wang, Yonglai Lu, Yi Jiang, Tuyuan Xu, Liqun Zhang
SESSION C – AEROSPACE AND ENGINEERING APPLICATIONS OF RUBBER
Effectiveness of a Thermal Protective Coating for Automotive Components...... 777 Russell L. Warley, Tejbans S. Kohli
Fuel and Permeation Resistance of Fluoroelastomers To Methanol Blends...... 798 Theresa Dobel, Christopher Grant
Temperature Dependency of Gum and Filled (Unaccelerated) Rubber Compounds in the 40 – 180 °C Range ...... 815 Jean L. Leblanc
A New EPDM Grade With Improved Processing Characteristics For Automotive Hose Applications...... 836 Mark F. Welker, Sunny Jacob, Eric Jourdain, Guy Wouters, Yann Devorest, Milind Joshi
The Impact of Antiozonants on Rubber-to-Metal Adhesion: Part 2 ...... 861 James R. Halladay, Patrick A. Warren
Elastomers in Compression: Testing and Performance ...... 893 Paul Tuckner
WEDNESDAY AFTERNOON
SESSION A – ADVANCES IN MATERIAL AND TIRE TECHNOLOGY
Role Of Starch In Improving The Fatigue Life Of Carbon Black Filled SBR Composites ...... 912 You-Ping Wu, Lei Yang, Li-Qun Zhang, Xiao-Mei He
Reinforcement Effect Of Plasma Modified Halloysite Nanotubes In A Carbon Black Filled Natural Rubber-Butadiene Rubber Matrix...... 930 Minna Poikelispaa, Amit Das, Wilma Dierkes, Jyrki Vuorinen
Worldwide Tire Survey: Inflation Pressure Loss Rates ...... 946 R. Christopher Napier, Walter H. Waddell, Dirk F. Rouckhout
VOLUME 2
The Role Of Material Composition In The Construction Of Viscoelastic Master Curves: Silica-Filler Network Effects...... 964 S. Maghami, W. K. Dierkes, T. V. Tolpekina, S. M. Schultz, J. W. M. Noordermeer
An Approach For Verifying Filler Components In Rubber Compounds ...... 987 D. M. Tucker, R. A. Webb, A. G. Olsen
Evaluation of Non- Nitrosamine Generating Accelerator Systems for the Vulcanization of Chlorobutyl Elastomer...... 1007 Bernard D'Cruz, Bharat B. Sharma, Brendan Rodgers
SESSION B – CURING OF ELASTOMERS
Choosing the Right Peroxide for Today’s High Performance Applications ...... 1032 Steven Monthey
Phosphate Accelerators in the Vulcanization of Ethylene Propylene Based EPDM Elastomers ...... 1051 Brendan Rodgers, Mark Welker, Sunny Jacob, Eric Jourdain, Bharat B. Sharma, Bernard D'Cruz
Studies Of Zinc-Oxide Free – Non Peroxide – Cross-Linking Of Compounds Based On Acrylonitrile – Butadiene – Polymers...... 1081 Hans Magg, Sven Brandau
Fundamentals of Bis-Maleimide Cure Chemistry...... 1096 Karthic Vikram Siva Shanmugam, J. Scott Parent, Ralph A. Whitney
Functional, Peroxide-Curable Isobutylene-Rich Elastomers...... 1105 Ralph A. Whitney, Karthik V. S. Shanmugam, J. Scott Parent
Effects Of Carbon Black On The Reversion Behavior Of A Cured Natural Rubber Compound ...... 1122 K. Boonkerd, W. Phasook, C. Deeprasertkul
A Comprehensive Numerical Model For The Interpretation Of Crosslinking With Peroxides And Sulphur: Chemical Mechanisms And Optimal Vulcanization Of Real Items...... 1147 Gabriele Milani, Federico Milani
Cure Simulation of Large Rubber Components; A Comparison of Compression and Extrusion Moulding ...... 1181 Marina Fernando, Wong Hon Fei, Colin Hull
SESSION C – SILICA TECHNOLOGY
“Greener” Tire Manufacturing using Agilon™ Performance Silicas ...... 1204 Timothy A. Okel
AgilonTM Performance Silicas In Natural Rubber Truck Tire Tread Compounds...... 1225 Justin J. Martin, Timothy A. Okel, Raphael Kollah
Effect of F-S-SBR in Silica Tire Tread Formulation ...... 1240 Jonathan E. Martens, Edward R. Terrill, James T. Lewis
Optimization Of Mixing Conditions For Silica-Reinforced Natural Rubber Tire Tread Compounds ...... 1256 W. Kaewsakul, K. Sahakaro, W. K. Dierkes, J. W. M. Noordermeer
Aging characteristics of Carbon Black Filled vs Silica Filled Compound...... 1292 Frederick Ignatz-Hoover, Diane Killmeyer, Byron H. To
Ultra Small-Angle X-Ray Scattering Study Of Flocculation In Silica-Filled Rubber...... 1315 Satoshi Mihara, Rabin N. Datta, Wilma K. Dierkes, Jacques W. M. Noordermeer, Naoya Amino, Yasuhiro Ishikawa, Shoutaro Nishitsuji, Mikihiko Takenaka
SESSION E – 8TH ANNUAL STUDENT COLLOQUIUM
Investigation Of Polymer-Filler Interaction In Liquid Silicone Rubber...... 1341 Anthony E. Sullivan, Mary A. Krenceski
Investigation Of Thermoplastic Elastomer Properties For Microfeature Replication ...... 1351 Younghyo Kim, Sung-Hwan Yoon, Jin-Goo Park, Joey L. Mead, Carol M. F. Barry
Highly Impermeable Nanocomposites of Brominated Butyl Rubber with Modified Montmorillonite Clay...... 1369 Arun Kumar, Satyam Modi, Daniel Schmidt, Carol M. F. Barry, Joey L. Mead
Can a Quasilinear Viscoelastic Model Describe the Nonlinear Mechanical Behavior of Unfilled Elastomers?...... 1393 Rasika Prabhu, Aparajita Bhattacharya, Grigori A. Medvedev, James M. Caruthers
Effect of Polymer Hardness and Clay Loadings on Electrospun Thermoplastic Polyurethane/Modified Montmorillonite Clay Fibers ...... 1401 Satyam Modi, Arun Kumar, Daniel Q. Murphy, Carol M. F. Barry, Joey L. Mead
Photovulcanization of Otherwise Uncured Rubber Components and Effects on Adhesion ...... 1419 Jennifer Hegarty, Henry Obermeyer
THURSDAY MORNING
SESSION A – MIXING AND PROCESSING
Crosslinked Blends of Polyolefin Elastomers with EPDM Rubber ...... 1456 Tim Clayfield, Arnis Paeglis, Dave Schiff, Olaf Henschke
Natural Rubber/Carbon Nanotube Nanocomposites Prepared By Ultrasonically Aided Extrusion ...... 1471 Jaesun Choi, Avraam I. Isayev
SESSION B – RUBBER RECYCLING
Characterization Of Micronized Rubber Powders With Cost Effective Performance Benefits In Rubber Compounds ...... 1516 Tom Rosenmayer, Ravi Ayyer, Frank Papp
Pathway For High-Quality Reclaim By Thermal Treatment Of Sulfur-Vulcanized SBR...... 1522 S. Saiwari, W. K. Dierkes, J. W. M. Noordermeer
Optimizing The Use Of Micronized Rubber Powder...... 1552 F. P. Papp
A Novel Strategy Of Reuse Of Waste Rubber...... 1599 Yiqing Wang, Liqun Zhang, Yuxing Feng, Xiaoming Tao
SESSION C – NEW COMMERCIAL DEVELOPMENTS
Liquid EPDM For Liquid Injection Molding Application ...... 1615 Yonghui Zhang, John Summers, Wasif Khan, Arthur Fontenot III, Bob Ohm
The Yerzley Oscillograph Revisited ...... 1626 Ismail Saltuk, Tavdi Corp, Nuri Akgerman
EPDM for Wire & Cable Applications - New Commercial Developments Session...... 1633 Russ Vogelsong, Bob Ohm
An Effective DOTG Replacement Accelerator for Both High Performance and General Elastomers...... 1644 Jennifer Forgue
Further Advances in Use of Polymer Process Aids to reduce Material Cost...... 1658 Chandrasekaran R. Pillai, Hari Chandra, Krish Chandran
THURSDAY AFTERNOON
SESSION A – MIXING AND PROCESSING
Effect Of Talc On The Dispersion Of Carbon Black ...... 1667 Nicole Hershberger, Bonnie L. Stuck, Oscar Noel, Gilles Meli
Tire Halobutyl Innerliners and Compounding Components ...... 1682 Brendan Rodgers, Bharat B. Sharma, Bernard D'Cruz
Upgrading Mixing Operations for Improved Productivity Adding Mixing Capacity to an Existing Mill Room...... 1709 Lawrence R. Gooch
Compounding And Processing Studies Of Rubber Compounds Reinforced By Short Aramid Fibers With Different Surface Treatments...... 1726 C. Hintze, S. Wiessner, G. Heinrich
SESSION B – RUBBER RECYCLING
European R.E.A.C.H. Overview...... 1742 Bonnie L. Stuck
Value Added Tire Recycling - Rubber Meets Plastic...... 1758 Jim Anderson
Hyberdized Modified Asphalt (HMA) With Enhanced PG Plus Characteristics...... 1769 G. Mohammed Memon, Mohammed Rehan Karim, Rasdan Momin
Pyrolysis Carbon Black, An Opportunity For The Rubber Industry ...... 1779 Nicolaus Probst, Martin Loeffler
SESSION C - CONTRIBUTED
Linear-Nonlinear Dichotomy Of The Rheological Response Of Particle-Filled Polymers ...... 1811 Amy M. Randall, Christopher G. Robertson
The Effect Of Acrylonitrile Content On The Thermo-Oxidative Aging Of Nitrile Rubber ...... 1830 Richard J. Pazur, J. G. Cormier, K. Korhan-Taymaz
Development of an Elastomeric Material That Swells in Water-Based Fluids...... 1854 Aaron D. Clark, Kelly A. Williams
Rubber, Rubber Recycling, Sealing & Bonding with Polybutadienes...... 1878 Andreas Berlineanu
SESSION D – ADVANCED MATERIALS IN HEALTH CARE – PLENARY & BIOMATERIALS GENERAL
Novel Polyisobutylene-Based Polyurethanes for Health Care ...... 1880 Gabor Erdodi, Jungmee Kang, Joseph P. Kennedy
SESSION D – ADVANCED MATERIALS IN HEALTH CARE – BENCHMARKS/STANDARD/ISO/ASTM
Silicone And Other Synthetic Rubber Standards For Medical Use...... 1897 Rick Ziebell
Author Index