Vulcanization & Accelerators
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The Difference of Butyl Rubber and Butadiene Styrene Rubber? by Butyl Rubber Sheets - [email protected], Date: Sep.18.06
The difference of butyl rubber and butadiene styrene rubber? By Butyl Rubber Sheets - www.dongrubber.com, [email protected], Date: Sep.18.06 Butyl rubber sheets is a kind of synthetic rubber which is a copolymer of Isobutylene and a small amount of isoprene copolymer, short for IIR. Butyl rubber sheeting has good chemical stability and thermal stability, the most prominent character is the air tightness and water tightness. Its air transmittance is only about 1/7 of the natural rubber, 1/5 of the styrene-butadiene rubber. Meanwhile its transmittance of steam is 1/200 of the natural rubber, and 1/140 of the styrene-butadiene rubber. Thus IIR is mainly used in the manufacture of tires, inner tubes, steam pipe, water dam and bottom gasket and other rubber products. Styrene-butadiene rubber (SBR) is one of the biggest general synthetic rubber varieties, and is also among the first rubber to realize industrialization production. Styrene butadiene rubber sheet is a random copolymer of butadiene and styrene. Its physical performance, processing performance and product performance is close to those of natural rubber sheets, and some properties such as wear resistance, heat resistance, ageing resistance and curing rate are more excellent than natural rubber sheeting, SBR can be used with a variety of natural rubber sheets and synthetic rubbers, widely applied to tires, tape, rubber hose, wire and cable, medical instruments and various kinds of rubber products production and other fields. Author: Butyl Rubber Sheets copyright reserved. Original URL should be kept in reproduction. . -
A Little Book About BIG Chemistry the Story of Man-Made Polymers
SPRINGER BRIEFS IN MATERIALS Jim Massy A Little Book about BIG Chemistry The Story of Man-Made Polymers www.ebook3000.com SpringerBriefs in Materials The SpringerBriefs Series in Materials presents highly relevant, concise mono- graphs on a wide range of topics covering fundamental advances and new applications in the field. Areas of interest include topical information on innovative, structural and functional materials and composites as well as fundamental principles, physical properties, materials theory and design. SpringerBriefs present succinct summaries of cutting-edge research and practical applications across a wide spectrum of fields. Featuring compact volumes of 50 to 125 pages, the series covers a range of content from professional to academic. Typical topics might include: • A timely report of state-of-the-art analytical techniques • A bridge between new research results, as published in journal articles, and a contextual literature review • A snapshot of a hot or emerging topic • An in-depth case study or clinical example • A presentation of core concepts that students must understand in order to make independent contributions Briefs are characterized by fast, global electronic dissemination, standard publishing contracts, standardized manuscript preparation and formatting guide- lines, and expedited production schedules. More information about this series at http://www.springer.com/series/10111 www.ebook3000.com Jim Massy A Little Book about BIG Chemistry The Story of Man-Made Polymers 123 Jim Massy Norwich, Norfolk UK ISSN 2192-1091 ISSN 2192-1105 (electronic) SpringerBriefs in Materials ISBN 978-3-319-54830-2 ISBN 978-3-319-54831-9 (eBook) DOI 10.1007/978-3-319-54831-9 Library of Congress Control Number: 2017934463 © The Author(s) 2017 This work is subject to copyright. -
5. Progress in Radiation Vulcanization of Natural Rubber Latex
JP0050691 JAERI-Conf 2000^003 5. Progress in Radiation Vulcanization of Natural Rubber Latex K. MAKUUCHI Takasaki Radiation Chemistry Research Establishment, JAERI 1233 Watanuki, Takasaki Gunma, 370-12 Japan 1. INTRODUCTION Radiation-induced crosslinking of natural rubber in latex can be accomplished by irradiating NR latex. The dose at which the maximum tensile strength (Tb) is found is called vulcanization dose (Dv). The Dv of NR latex is more than 250 kGy that is too high to be used in industry. The first RV accelerators proposed was carbon tetrachloride. Addition of 5 phr of carbon tetrachloride can reduce. The RVNRL was selected as one of the regional projects of the International Atomic Energy Agency (IAEA) known as the Regional Cooperative Agreement in the Asia and Pacific Region (RCA) in 1981. A pilot plant for the RVNRL was built in. Jakarta in 1983. The products from the pilot plant were tested and evaluated by several institutes in the region during 1983-1985, The results were as follows: Low tensile strength (less than 20MPa) Poor aging properties Inconsistent properties Not economic due to high dose requirement No advantages The results caused argument among the RCA member states and the IAEA whether the project should be continued or stopped. The preliminary R&D in the TRCRE on RVNRL indicated that the properties of RVNRL could be improved by proper selection of an accelerator. Finally, the IAEA decided to support the R&D on RVNRL at Takasaki. The following R&D were carried out in 1985 - 1989. Selection of NR latex to improve tensile strength Selection of accelerator to reduce required dose Selection of process factors to avoid inconsistency Selection of antioxidants to improve aging properties Biological safety test to find advantages of RVNRL As an accelerator n-butyl acrylate (n-BA) was selected by reason of its high accelerating efficiency, no residue in the final dipped products and tolerable price. -
Information to Users
INFORMATION TO USERS This reproduction was made from a copy of a manuscript sent to us for publication and microfilming. While the most advanced technology has been used to pho tograph and reproduce this manuscript, the quality of the reproduction is heavily dependent upon the quédlty of the material submitted. Pages in any manuscript may have indistinct print. In all cases the best available copy has been filmed. The following explanation of techniques is provided to help clarify notations which may appear on this reproduction. 1. Manuscripts may not always be complete. When it is not possible to obtain missing pages, a note appears to indicate this. 2. When copyrighted materials are removed from the manuscript, a note ap pears to indicate this. 3. Oversize materials (maps, drawings, and charts) are photographed by sec tioning the original, beginning at the upper left hemd comer and continu ing from left to right in equal sections with small overlaps. Each oversize page is also filmed as one exposure and is available, for an additional charge, as a standard 35mm slide or in black and white paper format. * 4. Most photographs reproduce acceptably on positive microfilm or micro fiche but lack clarity on xerographic copies made from the microfilm. For an additional charge, all photographs are available in black and white stcmdard 35mm slide format.* *For more information about black and white slides or enlarged paper reproductions, please contact the Dissertations Customer Services Department. IVBcrofilnis lateniai^oiial 8612390 Lee, Jong-Kwon STRESS CORROSION CRACKING AND PITTING OF SENSITIZED TYPE 304 STAINLESS STEEL IN CHLORIDE SOLUTIONS CONTAINING SULFUR SPECIES AT TEMPERATURES FROM 50 TO 200 DEGREES C The Ohio State University Ph.D. -
1,2,4-Triazine Sulfonamides: Synthesis by Sulfenamide Intermediates, in Vitro Anticancer Screening, Structural Characterization, and Molecular Docking Study
molecules Article 1,2,4-Triazine Sulfonamides: Synthesis by Sulfenamide Intermediates, In Vitro Anticancer Screening, Structural Characterization, and Molecular Docking Study Danuta Branowska 1, Zbigniew Karczmarzyk 1,*, Ewa Woli ´nska 1, Waldemar Wysocki 1, Maja Morawiak 2 , Zofia Urba ´nczyk-Lipkowska 2 , Anna Bielawska 3 and Krzysztof Bielawski 3 1 Faculty of Exact and Natural Sciences, Siedlce University of Natural Sciences and Humanities, 3 Maja 54, 08-110 Siedlce, Poland; [email protected] (D.B.); [email protected] (E.W.); [email protected] (W.W.) 2 Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland; [email protected] (M.M.); zofi[email protected] (Z.U.-L.) 3 Medical University of Bialystok, Department of Medicinal Chemistry and Drug Technology, J. Kilinskiego 1, 15-089 Bialystok, Poland; [email protected] (A.B.); [email protected] (K.B.) * Correspondence: [email protected]; Tel.: +48-25-643-1017 Received: 24 March 2020; Accepted: 14 May 2020; Published: 16 May 2020 Abstract: In this study, we synthesized novel sulfonamides with a 1,2,4-triazine moiety according to pharmacophore requirements for biological activity. All the synthesized compounds were tested in vitro to verify whether they exhibited anticancer activity against the human breast cancer cell lines MCF-7 and MDA-MB-231. Among them, two most active ones, having IC50 values of 50 and 42 µM, respectively, were found to show higher anticancer activity than chlorambucil used as the reference in the in vitro tests. In addition, two other compounds, which had IC50 values of 78 and 91 µM, respectively, exhibited a similar level of activity as chlorambucil. -
Reinforcement of Styrene Butadiene Rubber Employing Poly(Isobornyl Methacrylate) (PIBOMA) As High Tg Thermoplastic Polymer
polymers Article Reinforcement of Styrene Butadiene Rubber Employing Poly(isobornyl methacrylate) (PIBOMA) as High Tg Thermoplastic Polymer Abdullah Gunaydin 1,2, Clément Mugemana 1 , Patrick Grysan 1, Carlos Eloy Federico 1 , Reiner Dieden 1 , Daniel F. Schmidt 1, Stephan Westermann 1, Marc Weydert 3 and Alexander S. Shaplov 1,* 1 Luxembourg Institute of Science and Technology (LIST), 5 Avenue des Hauts-Fourneaux, L-4362 Esch-sur-Alzette, Luxembourg; [email protected] (A.G.); [email protected] (C.M.); [email protected] (P.G.); [email protected] (C.E.F.); [email protected] (R.D.); [email protected] (D.F.S.); [email protected] (S.W.) 2 Department of Physics and Materials Science, University of Luxembourg, 2 Avenue de l’Université, L-4365 Esch-sur-Alzette, Luxembourg 3 Goodyear Innovation Center Luxembourg, L-7750 Colmar-Berg, Luxembourg; [email protected] * Correspondence: [email protected]; Tel.: +352-2758884579 Abstract: A set of poly(isobornyl methacrylate)s (PIBOMA) having molar mass in the range of 26,000–283,000 g mol−1 was prepared either via RAFT process or using free radical polymerization. ◦ These linear polymers demonstrated high glass transition temperatures (Tg up to 201 C) and thermal Citation: Gunaydin, A.; stability (T up to 230 ◦C). They were further applied as reinforcing agents in the preparation of the Mugemana, C.; Grysan, P.; onset Eloy Federico, C.; Dieden, R.; vulcanized rubber compositions based on poly(styrene butadiene rubber) (SBR). The influence of the Schmidt, D.F.; Westermann, S.; PIBOMA content and molar mass on the cure characteristics, rheological and mechanical properties of Weydert, M.; Shaplov, A.S. -
Exxon™ Butyl Rubber Innertube Technology Manual
Exxon™ butyl rubber Exxon™ butyl rubber innertube technology manual Country name(s) 2 - Exxon™ butyl rubber innertube technology manual Exxon™ butyl rubber innertube technology manual - 3 Abstract Many bias and radial tires have innertubes. Radial truck tube-type tires are particularly common, and in many instances, such as in severe service, off-road applications, are preferred over tubeless radial tire constructions. The technology requirements for tubes for such tires is, in many respects, equally demanding when compared to that for the tire and wheel in the assembly. This manual has been prepared to describe how butyl rubber is important in meeting the demanding performance requirements of tire innertubes. Representative innertube compound formulations and compound properties are discussed along with typical processing guidelines of the compound in the manufacture of innertubes. Chlorobutyl rubber based compound formulations are also used in innertubes. Such innertubes show good heat resistance, durability, allow greater flexibility in compounding, and process equally well as regular butyl rubber tube compounds. An extensive discussion of bicycle tire innertubes has been included. Service conditions can range from simple commuting and recreation to high speed competitive sporting applications. Like automobile and truck tire innertubes, tubes for bicycle tires can thus have demanding performance requirements. Guidelines on troubleshooting provide a checklist for the factory process engineer to enhance manufacturing efficiency, high -
Tensile Properties of Pre-Vulcanised Natural Rubber Latex Films Via Hybrid Radiation and Peroxide Vulcanisations
ASM Sci. J., 11(2), 67-75 Tensile Properties of Pre-vulcanised Natural Rubber Latex Films via Hybrid Radiation and Peroxide Vulcanisations Sofian Ibrahim1;2∗, Chai Chee Keong1, Chantara Thevy Ratnam1 and Khairiah Badri2 1Malaysian Nuclear Agency, 43000 Kajang, Selangor, Malaysia 2School of Chemical Science and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia Radiation pre-vulcanised natural rubber latex (RVNRL) prepared by using gamma irradia- tion technique has many advantages over the conventionally prepared sulphur pre-vulcanised natural rubber latex (SPVL). Despite the fact that many potential latex dipped products can be made from RVNRL, little effort was made to fully commercialise the products because of the inferior strength of RVNRL products compared to SPVL products. An attempt was made to improve the tensile strength of RVNRL by combining both radiation and peroxide vulcanisation in order to ensure that the products will not tear or fail, and has sufficient stretch. Hexanediol diacrylate (HDDA) plays the main role as sensitizer during radiation vulcanisation and tert-butyl hydroperoxide (t-BHPO) as the co-sensitizer in peroxide vul- canisation. Pre-vulcanised natural rubber latex dipped films via hybrid radiation and perox- idation vulcanisations obtained showed tensile strength of 26.7 MPa, an increment of more than 15% compared to controlled film (22.5 MPa). Besides, the crosslink percentage of the rubber films also showed around 5% increment from 90.7% to 95.6%. Keywords: RVNRL, vulcanisation, irradiation, latex I. INTRODUCTION the expansion of this positive sales performance. One of the major contributors to Malaysia's national income is rubber and latex-based prod- ucts. -
California Skid Tests with Butyl Rubber Tires and Report of Visit to Road Research Laboratories in Europe Engaged in Skid Prevention Research
California Skid Tests with Butyl Rubber Tires and Report of Visit to Road Research Laboratories in Europe Engaged in Skid Prevention Research RALPH A. MOYER, Professor of Transportation Engineering and Research Engineer, TnctH11to nf 'T'l"<>ncnnrtsitinn sinrl 'T'rsiffir F.naino,:,rina TTniv,:,rcitv nf r.silifnrnisi - -------- -- -- - ---- .1,·· ..... ., Berkeley •AN EXTENSIVE California program of skid resistance tests conducted in 1961 was reported in HRB Bull. 348 (1962). The 1961 tests yielded significant results primarily because of the use of a new torque meter device to measure the friction forces. The tests were run with four different types of tires including one tire with the recently developed butyl rubber tread which provided high hysteresis or energy losses and high coefficients of friction on wet pavements. In view of the improved accuracy obtained with the new torque meter, and the high friction values obtained in the exploratory tests with the butyl rubber tire, a program of tests was carried out in 1962. Skid resistance measurements were made on a wide variety of pavement surfaces with two different brands of butyl rubber tires, and also with the 1958 and 1961 pavement test standard tires. Before 1961, it was generally assumed that the only way to obtain significant improvement in the skid resistance of wet pavements was by the selection of aggregate types and pavement construction methods and controls, and/or by de-slicking treatments which had been established by laboratory and field tests. Studies were conducted by California in 1961, by the British Road Research Laboratory, and by Dr. Tabor of Cambridge University, England. -
Model Vulcanization Systems for Butyl Rubber and Halobutyl Rubber Manual
Exxon™ butyl and halobutyl rubber Model vulcanization systems for butyl rubber and halobutyl rubber manual Country name(s) 2 - Model vulcanization systems for butyl rubber and halobutyl rubber manual Model vulcanization systems for butyl rubber and halobutyl rubber manual - 3 Abstract The vulcanization of isobutylene-co-isoprene rubber (IIR), brominated isobutylene-co-isoprene rubber (BIIR), chlorinated isobutylene-co-isoprene rubber (CIIR), and brominated isobutylene-co-para-methylstyrene elastomer (BIMSM) differs from that of general-purpose rubbers (GPR). Butyl rubber has approximately 2% unsaturation in the backbone. Halobutyl rubber (BIIR and CIIR) incorporates the butyl backbone with either bromine or chlorine, which significantly increases the chemical reactivity of the isoprenyl units located in the butyl backbone. Similarly, in BIMSM the bromine atom is bonded to the para-methylstyrene (PMS) group, thus affording the completely saturated polymer backbone a site of chemical reactivity. Utilization of the unique attributes of butyl rubber and halobutyl rubbers with their minimal backbone unsaturation and of BIMSM elastomers with no backbone unsaturation is found in many areas of industry. These properties are excellent vapor impermeation, resistance to heat degradation, and improved chemical resistance as compared to general-purpose rubbers. However, this low amount of reactivity requires special consideration to vulcanize these isobutylene-based polymers. The type of vulcanization system selected is a function of the composite structure in which it is used, and the cured product performance requirements. Therefore, vulcanization systems vary and may include an accelerator package along with resins, zinc oxide, zinc oxide and sulfur, and quinoid systems. This review will discuss the types and selection of appropriate vulcanization systems for isobutylene-based elastomers. -
SAFETY DATA SHEET for Mission Rubber Neoprene Gaskets
SAFETY DATA SHEET for Mission Rubber Neoprene Gaskets SECTION TOPIC PG 1 Identification 1 2 Hazard Identification 1-2 3 Composition/Information On Ingredients 2 4 First Aid Measures 2 5 Firefighting Measures 2 6 Accidental Release Measures 3 7 Handling and Storage 3 8 Exposure Controls/Personal Protection 3 9 Physical and Chemical Properties 4 10 Stability and Reactivity 4 11 Toxicological Information 4 12 Ecological Information 5 13 Disposal Considerations 5 14 Exposure Controls/Personal Protection 5 15 Regulatory Information 5-6 16 Other Information 6 missionrubber.com (800) 854-9991 SAFETY DATA SHEET NEOPRENE GASKETS Section 1: IDENTIFICATION 1.1 Product identifier Product name: Neoprene Product part number: DPESISGRP251 CAS number: Ingredients: 184963-09-1. Synonyms: Neoprene. Product description: Neoprene Synthetic Rubber Gasket is a black color rubber with a mild characteristic odor. Product type: Solid 1.2 Relevant identified uses of the substance or mixture and uses advised against Product use: For use only as specified in product literature 1.3 Details of the supplier of the safety data sheet Mission Rubber Company, LLC 1660 Lesson Lane Corona, CA 92879 1.4 Telephone number: 800-854-9991 Section 2: HAZARD IDENTIFICATION 2.1 Classification of Substance or Mixture Potential Health Effects Before using Neoprene Synthetic Rubbers, read Bulletin "Guide for Safety in Handling and FDA Status of Neoprene Solid Polymers". ADDITIONAL HEALTH EFFECTS POLYCHLOROPRENE BLEND ACUTE OR IMMEDIATE EFFECTS: ROUTES OF ENTRY AND SYMPTOMS Ingestion One type of Neoprene was tested for oral toxicity in rats. The LD-50 is in excess of 20,000 milligrams per kilogram body weight which is low toxicity. -
THE CHEMISTRY of SULFENIMIDES by Barbara Ann Orwig a Thesis
THE CHEMISTRY OF SULFENIMIDES by Barbara Ann Orwig A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfilment of the requirements for the degree of Master of Science Department of Chemistry McGill University Montreal, P.Q. Canada May 1971 @) Barbara Ann Orwig 1972 Dedicated to My Parents Il Thanx Il i ACKNOWLEDGEMENTS 3l MY thanks to Dr. D.F.R. Gilson for the p nmr spectra, to Victor Yu for the A-60 nmr spectra, and to Peter Currie for the mass spectra. For helpful discussions and worthwhile suggestions l thank David Ash 1 Errol Chang 1 and John Gleason. For his guidance and help as my research director l thank Dr. David N. Harpp. And to Elva and Hermann Heyge go special thanks for their help and for "putting up wi th œil. TABLE OF CONTENTS Page ACKNOWLEDGEMENTS i INTRODUcrION 1 EXPERIMENTAL SECTION 22 RESULTS AND DISCUSSION 42 TABLES 1 Preparation of Sulfenyl Chlorides 72 2 Preparation of N-(alkyl/aryl thio)phthalimides 73 3 Desulfurization Reactions of N-(alkyl/aryl thio)phthalimides 76 4 Mass Spectra of N-(alkyl/aryl thio)phthalimides 77 FIGURES (Spectra) 78 - 87 BIBLIOGRAPHY 88 INTRODUcrION AND BACKGROUND Sulfenic acids Cl), in which sulfur exists in its R-S-OH l lcwest oxidation state, are highly lmstable compolmds and only a few l have been isolated. The derivatives of sulfenic acid {~.> however, are generally isolable and usually stable. 2 R-S-Y 2 When Y is -NH ' -~HR, or -NR ' the resulting class of compolmds is 2 2 ter.med sulfenamides.