003537 Soursop Flavour Natural

Home , Ethyl heptanoate

003537 SOURSOP FLAVOUR NATURAL The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 2 Version No: 1.1 Issue Date: 07/12/2017 Safety Data Sheet according to WHS and ADG requirements Print Date: 07/12/2017 S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier Product name: XP11538/01 SOURSOP FLAVOUR NATURAL Other means of identification: Not Available

Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: INTEGRITY CHECK: Product contains BOTH an alcohol and an acid as ingredients.

Details of the supplier of the safety data sheet Emergency telephone number Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation Not Available Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300 Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available Fax 61 3 9771 0301 Website www.theproductmakers.com Email Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. ChemWatch Hazard Ratings Flammability 0 Toxicity 2 0 = Minimum 1 = Low Body Contact 2 2 = Moderate Reactivity 0 3 = High Chronic 2 4 = Extreme

Poisons Schedule Not Applicable

Classification [1] Eye Irritation Category 2A, Acute Aquatic Hazard Category 3, Chronic Aquatic Hazard Category 3 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

Hazard pictogram(s)

SIGNAL WORD: WARNING

Hazard statement(s) H319: Causes serious eye irritation. H412: Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

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P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention.

Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501: Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures

Mixtures CAS No %[weight] Name 102-76-1 1-10 glyceryl triacetate 141-78-6 <1 ethyl acetate 105-54-4 <1 ethyl butyrate 108-64-5 <1 ethyl isovalerate 123-92-2 <1 iso-amyl acetate 5989-27-5 <1 d-limonene 123-66-0 <1 ethyl butyl acetate 106-27-4 <1 iso-amyl butyrate 106-30-9 <1 ethyl heptanoate 2639-63-6 <1 hexyl butyrate 64-19-7 <1 acetic acid glacial 78-70-6 <1 linalool 556-24-1 <1 methyl iso-valerate 140-11-4 1-10 benzyl acetate 104-67-6 1-10 gamma-undecalactone 2305-05-7 <1 gamma-dodecalactone

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact - Generally not applicable.

Skin Contact If skin contact occurs: - Immediately remove all contaminated clothing, including footwear. - Flush skin and hair with running water (and soap if available). - Seek medical attention in event of irritation. - Generally not applicable.

Inhalation - Generally not applicable.

Ingestion - IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. - For advice, contact a Poisons Information Centre or a doctor. - Urgent hospital treatment is likely to be needed. - In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. - If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the SDS should be provided. Further action will be the responsibility of the medical specialist. - If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the SDS.

Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: - INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. NOTE: Wear a protective glove when inducing vomiting by mechanical means.

- Generally not applicable.

Indication of any immediate medical attention and special treatment needed - Polyethylene glycols are generally poorly absorbed orally and are mostly unchanged by the kidney. - Dermal absorption can occur across damaged skin (e.g. through burns) leading to increased osmolality, anion gap metabolic acidosis, elevated calcium, low ionised calcium, CNS depression and renal failure. - Treatment consists of supportive care. [Ellenhorn and Barceloux: Medical Toxicology]

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Propylene glycol is primarily a CNS depressant in large doses and may cause hypoglycaemia, lactic acidosis and seizures. - The usual measures are supportive care and decontamination (Ipecac/ lavage/ activated charcoal/ cathartics), within 2 hours of exposure should suffice. - Check the anion gap, arterial pH, renal function and glucose levels.

Ellenhorn and Barceloux: Medical Toxicology

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media - Alcohol stable foam.

Special hazards arising from the substrate or mixture

Fire Incompatibility - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting - Alert Fire Brigade and tell them location and nature of hazard. Slight hazard when exposed to heat, flame and oxidisers.

Fire/Explosion Hazard Combustible. Combustion products include: carbon monoxide (CO) carbon dioxide (CO2) other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. Articles and manufactured articles may constitute a fire hazard where polymers form their outer layers or where combustible packaging remains in place.

HAZCHEM Not Applicable

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures See section 8

Environmental precautions See section 12

Methods and material for containment and cleaning up

Minor Spills - Clean up all spills immediately.

Major Spills - Clear area of personnel and move upwind. Minor hazard. - Clean up all spills immediately.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling - Avoid all personal contact, including inhalation.

Other information Store in a cool dry place out of direct sunlight. Shelf Life: 12 Months According to the specified storage conditions.

Conditions for safe storage, including any incompatibilities

Suitable container Generally packaging as originally supplied with the article or manufactured item is sufficient to protect against physical hazards.

Storage incompatibility - Glycols and their ethers undergo violent decomposition in contact with 70% perchloric acid. Acetic acid: - vapours forms explosive mixtures with air (above 39 C.) - reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide - reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus isocyanate, phosphorus trichloride, sodium peroxide, xylene - attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas - attacks many forms of rubber, plastics and coatings Alcohols - are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents.

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SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Occupational Exposure Limits (OEL) INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards ethyl acetate Ethyl acetate 720 mg/m3 / 200 ppm 1440 mg/m3 / 400 ppm Not Available Not Available Australia Exposure Standards iso-amyl acetate Isoamyl acetate 270 mg/m3 / 50 ppm 541 mg/m3 / 100 ppm Not Available Not Available Australia Exposure Standards acetic acid glacial Acetic acid 25 mg/m3 / 10 ppm 37 mg/m3 / 15 ppm Not Available Not Available

Exposure controls

Appropriate engineering controls Articles or manufactured items, in their original condition, generally don't require engineering controls during handling or in normal use. Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.

Personal protection

Eye and face protection - Safety glasses with side shields. No special equipment required due to the physical form of the product.

Skin protection See Hand protection below

Hands/feet protection - Wear chemical protective gloves, e.g. PVC. NOTE: - The material may produce skin sensitisation in predisposed individuals. No special equipment required due to the physical form of the product.

Body protection See Other protection below

Other protection - Overalls.

Thermal hazards Not Available

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties Appearance: Clear colourless to pale yellow liquid

Physical state article Relative density (Water = 1) 1.03 Odour Characteristic Partition coefficient n-octanol / water Not Available Odour threshold Characteristic of \Soursop Auto-ignition temperature (°C) Not Available pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available Flash point (°C) >60 Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Combustible. Oxidising properties Not Available Refractive Index 1.432 Surface Tension (dyn/cm or mN/m) Not Available Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water (g/L) Not Available pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity: See section 7 Chemical stability: Product is considered stable and hazardous polymerisation will not occur. Possibility of hazardous reactions: See section 7 Conditions to avoid: See section 7

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Incompatible materials: See section 7 Hazardous decomposition products: See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as classified by EC Directives using animal models). Aliphatic alcohols with more than 3-carbons cause headache, dizziness, drowsiness, muscle weakness and delirium, central depression, coma, seizures and behavioural changes. Inhalation hazard is increased at higher temperatures.

Ingestion Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual. Ingestion of propylene glycol produced reversible central nervous system depression in humans following ingestion of 60 ml. If swallowed, the toxic effects of glycols (dihydric alcohols) are similar to those of alcohol, with depression of the central nervous system, nausea, vomiting, and degenerative changes in the liver and kidney. Overexposure to non-ring alcohols causes nervous system symptoms.

Skin Contact A single prolonged exposure is not likely to result in the material causing harm. Most liquid alcohols appear to act as primary skin irritants in humans. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.

Eye Irritation of the eyes may produce a heavy secretion of tears (lachrymation). Limited evidence or practical experience suggests, that the material may cause eye irritation in a substantial number of individuals.

Chronic Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment. Propylene glycol is thought to be sensitizing following the regular use of topical creams by eczema patients.

TOXICITY IRRITATION XP11538/01 SOURSOP FLAVOUR NATURAL Not Available Not Available

TOXICITY IRRITATION glyceryl triacetate Oral (rat) LD50: >2000 mg/kg[1] Not Available

TOXICITY IRRITATION

ethyl acetate Inhalation (rat) LC50: 50 mg/l1 h[1] Eye (human): 400 ppm

Oral (rat) LD50: 5620 mg/kg[2]

TOXICITY IRRITATION ethyl butyrate Oral (rat) LD50: 13000 mg/kg[2] Not Available

TOXICITY IRRITATION ethyl isovalerate Oral (rabbit) LD50: 7031 mg/kg[2] Skin (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION iso-amyl acetate Oral (rat) LD50: 16600 mg/kg[2] Not Available

TOXICITY IRRITATION

d-limonene Dermal (rabbit) LD50: >5000 mg/kg[2] Skin (rabbit): 500mg/24h moderate

Oral (rat) LD50: >2000 mg/kg[1]

TOXICITY IRRITATION

Dermal (rabbit) LD50: >2000 mg/kg[1] Skin (rabbit): 500 mg/24h - mod

ethyl butyl acetate Dermal (rabbit) LD50: >2000 mg/kg[1]

Oral (rat) LD50: >2000 mg/kg[1]

Oral (rat) LD50: >5000 mg/kg[1]

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TOXICITY IRRITATION iso-amyl butyrate Not Available Skin (rabbit):500 mg/24h moderate

TOXICITY IRRITATION

ethyl heptanoate Dermal (rabbit) LD50: >5000 mg/kg[2] Not Available

Oral (rat) LD50: >34640 mg/kg[2]

TOXICITY IRRITATION

hexyl butyrate Dermal (rabbit) LD50: >5000 mg/kg[2] Skin : Mild

Oral (rat) LD50: >5000 mg/kg[2]

TOXICITY IRRITATION

Dermal (rabbit) LD50: 1060 mg/kg[2] Eye (rabbit): 0.05mg (open)-SEVERE acetic acid glacial Inhalation (mammal) LC50: 11.4 mg/l/4H[2] Skin (human):50mg/24hr - mild

Oral (rat) LD50: 3310 mg/kg[2] Skin (rabbit):525mg (open)-SEVERE

TOXICITY IRRITATION

dermal (rat) LD50: 5610 mg/kg[2] Skin (guinea pig):100mg/24h-mild

linalool Oral (rat) LD50: 2790 mg/kg[2] Skin (man): 16 mg/48h-mild Skin (rabbit): 100 mg/24h-SEVERE Skin (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION

methyl iso-valerate Inhalation (rabbit) LC50: 10.125 mg/l/2h[2] Not Available

Oral (rabbit) LD50: 5693 mg/kg[2]

TOXICITY IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg[2] Skin (rabbit): 100mg/24h-moderate benzyl acetate Inhalation (mammal) LC50: 489.44091 mg/l/8H[2]

Oral (rat) LD50: >2000 mg/kg[1]

TOXICITY IRRITATION

gamma-undecalactone Oral (rat) LD50: 18500 mg/kg[2] Skin (guinea pig): 100 mg/24h-mod Skin (rabbit): 100 mg/24h-SEVERE

TOXICITY IRRITATION gamma-dodecalactone Not Available Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

D-LIMONENE d-Limonene is readily absorbed by inhalation and swallowing. A member or analogue of a group of of aliphatic and aromatic terpene hydrocarbons generally considered as safe (GRAS) based, in part, on their self-limiting properties as flavouring substances in food; their rapid absorption, metabolic detoxication, and excretion in humans and other animals; their low level of flavour use; the wide margins of safety between the conservative estimates of intake and the no-observed-adverse effect levels determined from subchronic and chronic studies and the lack of significant genotoxic potential. Tumorigenic by RTECS criteria

HEXYL BUTYRATE Skin (rabbit) 500: mg/24h -

ACETIC ACID GLACIAL For acid mists, aerosols, vapours Test results suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5. The material may produce severe irritation to the eye causing pronounced inflammation. Prolonged or repeated exposure to acetic acid may produce irritation and/ or corrosion at the site of contact as well as systemic toxicity.

LINALOOL The terpenoid hydrocarbons are found in needle trees and deciduous plants. Inhalational exposure of mice and man to linalool caused slight sedative effects but a dose dependent response characteristic could not be determined.

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Opinion holds that there are no safety concerns for linalool and the linalyl esters, as fragrance ingredients, under the present declared levels of use and exposure for the following reasons: · Linalool and the linalyl esters have a low order of acute toxicity. A member or analogue of a group of aliphatic and alicyclic terpenoid tertiary alcohols and structurally related substances generally regarded as safe. With few exceptions* (see below), there are no safety concerns regarding certain cyclic and non-cyclic terpene alcohols **, as fragrance ingredients, under present declared levels of use and exposure, because - They have low acute toxicity - No significant toxicity was observed in repeat dose toxicity tests - They were not found to cause mutations or genetic toxicity - Substances in this group are processed similarly in the body - There is no indication of persistent breakdown products causing severe toxicity - They practically do not irritate the skin - They have a generally low potential for sensitization - The margin of safety is more than 100 times the maximum daily exposure. For terpenoid tertiary alcohols and their related esters: These substances are metabolised in the liver and excreted primarily in the urine and faeces. Current opinion holds that there are no safety concerns regarding the branched chain unsaturated non-cyclic alcohols, as fragrance ingredients, at current declared levels of use and exposure; however, use of these materials at higher maximum levels of skin or whole-body exposure requires re-evaluation. Alkyl alcohols of chain length C6-13 are absorbed from skin, when inhaled or swallowed but show evidence of little harm.

BENZYL ACETATE For certain benzyl derivatives: The members of this group are rapidly absorbed through the gastrointestinal tract, metabolised primarily in the liver, and excreted primarily in the urine either unchanged or as conjugates of benzoic acid derivatives. This is a member or analogue of a group of benzyl derivatives generally regarded as safe (GRAS), based partly on their self-limiting properties as flavouring substances in food. Aryl alkyl alcohol simple acid ester derivates (AAASAE) have a low level of acute toxicity. The aryl alkyl alcohol (AAA) fragrance ingredients have diverse chemical structures, with similar metabolic and toxicity profiles. Neoplastic by RTECS criteria

GAMMA-UNDECALACTONE Fragrance allergens act as haptens, low molecular weight chemicals that cause an immune response only when attached to a carrier protein.

GAMMA-DODECALACTONE No significant acute toxicological data identified in literature search.

ETHYL BUTYRATE & ETHYL ISOVALERATE & ETHYL BUTYL ACETATE & ETHYL HEPTANOATE & ACETIC ACID GLACIAL & BENZYL ACETATE & GAMMA-UNDECALACTONE & GAMMA-DODECALACTONE Asthma-like symptoms may continue for months or even years after exposure to the material ends.

ETHYL BUTYRATE & ETHYL ISOVALERATE & ETHYL BUTYL ACETATE & HEXYL BUTYRATE & BENZYL ACETATE The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

D-LIMONENE & LINALOOL The following information refers to contact allergens as a group and may not be specific to this product.

D-LIMONENE & LINALOOL & GAMMA-UNDECALACTONE Adverse reactions to fragrances in perfumes and fragranced cosmetic products include allergic contact dermatitis, irritant contact dermatitis, sensitivity to light, immediate contact reactions, and pigmented contact dermatitis.

D-LIMONENE & LINALOOL Fragrance allergens act as haptens, which are small molecules that cause an immune reaction only when attached to a carrier protein.

D-LIMONENE & BENZYL ACETATE The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans.

ACETIC ACID GLACIAL & LINALOOL & GAMMA-UNDECALACTONE The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

GAMMA-UNDECALACTONE & GAMMA-DODECALACTONE Gamma-butyrolactone may cause thymus atrophy, brain damage, severe weakness and low body weight in rats.

GAMMA-UNDECALACTONE & GAMMA-DODECALACTONE This is a member or analogue of a group of lactones generally considered as safe (GRAS).

Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin sensitisation STOT - Repeated Exposure Mutagenicity Aspiration Hazard

Legend: – Data available but does not fill the criteria for classification – Data available to make classification – Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE XP11538/01 SOURSOP FLAVOUR NATURAL Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE glyceryl triacetate EC50 48 Crustacea 380mg/L 1

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EC50 72 Algae or other aquatic plants >940mg/L 2 NOEC 504 Crustacea >=94mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 212.5mg/L 4 EC50 48 Crustacea =164mg/L 1 ethyl acetate EC50 96 Algae or other aquatic plants 2500mg/L 4 BCF 24 Algae or other aquatic plants 0.05mg/L 4 NOEC 504 Crustacea 2.4mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE ethyl butyrate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE ethyl isovalerate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE iso-amyl acetate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 0.702mg/L 2 d-limonene EC50 48 Crustacea 0.421mg/L 2 EC50 72 Algae or other aquatic plants ca.8mg/L 2 NOEC 72 Algae or other aquatic plants 2.62mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE ethyl butyl acetate LC50 96 Fish 8.94mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE iso-amyl butyrate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE ethyl heptanoate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE hexyl butyrate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 31.3-67.6mg/L 2 acetic acid glacial EC50 48 Crustacea 18.9mg/L 2 EC50 72 Algae or other aquatic plants 29.23mg/L 2 NOEC 48 Crustacea 21.5mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish <19.9mg/L 1 linalool EC50 48 Crustacea =20mg/L 1 EC50 96 Algae or other aquatic plants =88.3mg/L 1 NOEC 96 Fish <3.5mg/L 1

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE methyl iso-valerate Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE benzyl acetate LC50 96 Fish 4mg/L 4

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EC50 72 Algae or other aquatic plants 92mg/L 2 NOEC 672 Fish 0.92mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE LC50 96 Fish 569mg/L 4 gamma-undecalactone EC50 48 Crustacea 17.0mg/L 4 EC50 72 Algae or other aquatic plants 63.5mg/L 2 NOEC 48 Algae or other aquatic plants 0.779mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE gamma-dodecalactone Not Available Not Available Not Available Not Available Not Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Propylene glycol is known to exert high levels of biochemical oxygen demand (BOD) during degradation in surface waters. For Acetic Acid: Acetic acid and its salts (the acetates) can be grouped together because of their close structural relationships, their natural occurrence in plants and animals, and their fundamental role in cell metabolism. DO NOT discharge into sewer or waterways.

Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air glyceryl triacetate LOW LOW ethyl acetate LOW (Half-life = 14 days) LOW (Half-life = 14.71 days) ethyl butyrate LOW LOW ethyl isovalerate LOW LOW iso-amyl acetate LOW LOW d-limonene HIGH HIGH ethyl butyl acetate LOW LOW iso-amyl butyrate LOW LOW ethyl heptanoate LOW LOW hexyl butyrate LOW LOW acetic acid glacial LOW LOW linalool HIGH HIGH methyl iso-valerate LOW LOW benzyl acetate LOW LOW gamma-undecalactone LOW LOW gamma-dodecalactone LOW LOW

Bioaccumulative potential Ingredient Bioaccumulation glyceryl triacetate LOW (BCF = 1.3) ethyl acetate HIGH (BCF = 3300) ethyl butyrate LOW (LogKOW = 1.8464) ethyl isovalerate LOW (LogKOW = 2.264) iso-amyl acetate LOW (LogKOW = 2.264) d-limonene HIGH (LogKOW = 4.8275) ethyl butyl acetate LOW (LogKOW = 2.8286) iso-amyl butyrate LOW (LogKOW = 3.2462) ethyl heptanoate LOW (LogKOW = 3.3197) hexyl butyrate MEDIUM (LogKOW = 3.8108) acetic acid glacial LOW (LogKOW = -0.17) linalool LOW (LogKOW = 2.97) methyl iso-valerate LOW (LogKOW = 1.82) benzyl acetate LOW (LogKOW = 1.96) gamma-undecalactone LOW (LogKOW = 3.0583) gamma-dodecalactone LOW (LogKOW = 3.5494)

Mobility in soil

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Ingredient Mobility glyceryl triacetate LOW (KOC = 48.06) ethyl acetate LOW (KOC = 6.131) ethyl butyrate LOW (KOC = 21.85) ethyl isovalerate LOW (KOC = 33.78) iso-amyl acetate LOW (KOC = 32.24) d-limonene LOW (KOC = 1324) ethyl butyl acetate LOW (KOC = 74.33) iso-amyl butyrate LOW (KOC = 114.9) ethyl heptanoate LOW (KOC = 137.1) hexyl butyrate LOW (KOC = 252.8) acetic acid glacial HIGH (KOC = 1) linalool LOW (KOC = 56.32) methyl iso-valerate LOW (KOC = 18.31) benzyl acetate LOW (KOC = 133.7) gamma-undecalactone LOW (KOC = 476.5) gamma-dodecalactone LOW (KOC = 878.9)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal · Recycle wherever possible or consult manufacturer for recycling options. - DO NOT allow wash water from cleaning or process equipment to enter drains. - Recycle wherever possible or consult manufacturer for recycling options.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

HAZCHEM Not Applicable

Land transport (ADG): NOT Air transport (ICAO-IATA / DGR): NOT Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF DANGEROUS GOODS DANGEROUS GOODS DANGEROUS GOODS UN number: Not Applicable UN proper shipping name: Not Applicable Transport hazard class(es): Not Applicable Subrisk: Not Applicable Packing group: Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

glyceryl triacetate(102-76-1) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

ethyl acetate(141-78-6) is found on the following regulatory lists - Australia Exposure Standards - Australia Inventory of Chemical Substances (AICS) - Australia Hazardous Substances Information System - Consolidated Lists

ethyl butyrate(105-54-4) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

ethyl isovalerate(108-64-5) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

iso-amyl acetate(123-92-2) is found on the following regulatory lists - Australia Exposure Standards - Australia Inventory of Chemical Substances (AICS) - Australia Hazardous Substances Information System - Consolidated Lists

Continued... Chemwatch: 9-494159 Page 11 of 11 Issue Date: 07/12/2017 Version No: 1.1 Print Date: 07/12/2017 003537 SOURSOP FLAVOUR NATURAL

d-limonene(5989-27-5) is found on the following regulatory lists - Australia Hazardous Substances Information System - Consolidated Lists - International Agency for Research on Cancer (IARC) - Agents Classified by the IARC - Australia Inventory of Chemical Substances (AICS) Monographs

ethyl butyl acetate(123-66-0) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

iso-amyl butyrate(106-27-4) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

ethyl heptanoate(106-30-9) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

hexyl butyrate(2639-63-6) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

acetic acid glacial(64-19-7) is found on the following regulatory lists - Australia Exposure Standards - Australia Inventory of Chemical Substances (AICS) - Australia Hazardous Substances Information System - Consolidated Lists

linalool(78-70-6) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

methyl iso-valerate(556-24-1) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

benzyl acetate(140-11-4) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS) - International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

gamma-undecalactone(104-67-6) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

gamma-dodecalactone(2305-05-7) is found on the following regulatory lists - Australia Inventory of Chemical Substances (AICS)

National Inventory Status Australia - AICS Y Canada - DSL Y N (gamma-undecalactone; iso-amyl butyrate; ethyl acetate; gamma-dodecalactone; iso-amyl acetate; d-limonene; ethyl butyl acetate; ethyl heptanoate; acetic acid Canada - NDSL glacial; ethyl butyrate; ethyl isovalerate; methyl iso-valerate; benzyl acetate; hexyl butyrate; linalool; glyceryl triacetate) China - IECSC Y Europe - EINEC / Y ELINCS / NLP Japan - ENCS N (ethyl butyl acetate; ethyl heptanoate) Korea - KECI Y New Zealand - NZIoC Y Philippines - PICCS Y USA - TSCA Y Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers Name CAS No d-limonene 5989-27-5, 138-86-3 linalool 78-70-6, 126-91-0, 126-90-9 gamma-dodecalactone 2305-05-7, 69830-91-7, 69830-92-8, 57084-18-1

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.

end of SDS