003537 SOURSOP FLAVOUR NATURAL The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 2 Version No: 1.1 Issue Date: 07/12/2017 Safety Data Sheet according to WHS and ADG requirements Print Date: 07/12/2017 S.GHS.AUS.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name: XP11538/01 SOURSOP FLAVOUR NATURAL Other means of identification: Not Available Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: INTEGRITY CHECK: Product contains BOTH an alcohol and an acid as ingredients. Details of the supplier of the safety data sheet Emergency telephone number Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation Not Available Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300 Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available Fax 61 3 9771 0301 Website www.theproductmakers.com Email Not Available SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. ChemWatch Hazard Ratings Flammability 0 Toxicity 2 0 = Minimum 1 = Low Body Contact 2 2 = Moderate Reactivity 0 3 = High Chronic 2 4 = Extreme Poisons Schedule Not Applicable Classification [1] Eye Irritation Category 2A, Acute Aquatic Hazard Category 3, Chronic Aquatic Hazard Category 3 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI Label elements Hazard pictogram(s) SIGNAL WORD: WARNING Hazard statement(s) H319: Causes serious eye irritation. H412: Harmful to aquatic life with long lasting effects. Precautionary statement(s) Prevention P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. Precautionary statement(s) Response Continued... Chemwatch: 9-494159 Page 2 of 11 Issue Date: 07/12/2017 Version No: 1.1 Print Date: 07/12/2017 003537 SOURSOP FLAVOUR NATURAL P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501: Dispose of contents/container in accordance with local regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 102-76-1 1-10 glyceryl triacetate 141-78-6 <1 ethyl acetate 105-54-4 <1 ethyl butyrate 108-64-5 <1 ethyl isovalerate 123-92-2 <1 iso-amyl acetate 5989-27-5 <1 d-limonene 123-66-0 <1 ethyl butyl acetate 106-27-4 <1 iso-amyl butyrate 106-30-9 <1 ethyl heptanoate 2639-63-6 <1 hexyl butyrate 64-19-7 <1 acetic acid glacial 78-70-6 <1 linalool 556-24-1 <1 methyl iso-valerate 140-11-4 1-10 benzyl acetate 104-67-6 1-10 gamma-undecalactone 2305-05-7 <1 gamma-dodecalactone SECTION 4 FIRST AID MEASURES Description of first aid measures Eye Contact - Generally not applicable. Skin Contact If skin contact occurs: - Immediately remove all contaminated clothing, including footwear. - Flush skin and hair with running water (and soap if available). - Seek medical attention in event of irritation. - Generally not applicable. Inhalation - Generally not applicable. Ingestion - IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. - For advice, contact a Poisons Information Centre or a doctor. - Urgent hospital treatment is likely to be needed. - In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. - If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the SDS should be provided. Further action will be the responsibility of the medical specialist. - If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the SDS. Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: - INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. NOTE: Wear a protective glove when inducing vomiting by mechanical means. - Generally not applicable. Indication of any immediate medical attention and special treatment needed - Polyethylene glycols are generally poorly absorbed orally and are mostly unchanged by the kidney. - Dermal absorption can occur across damaged skin (e.g. through burns) leading to increased osmolality, anion gap metabolic acidosis, elevated calcium, low ionised calcium, CNS depression and renal failure. - Treatment consists of supportive care. [Ellenhorn and Barceloux: Medical Toxicology] Continued... Chemwatch: 9-494159 Page 3 of 11 Issue Date: 07/12/2017 Version No: 1.1 Print Date: 07/12/2017 003537 SOURSOP FLAVOUR NATURAL Propylene glycol is primarily a CNS depressant in large doses and may cause hypoglycaemia, lactic acidosis and seizures. - The usual measures are supportive care and decontamination (Ipecac/ lavage/ activated charcoal/ cathartics), within 2 hours of exposure should suffice. - Check the anion gap, arterial pH, renal function and glucose levels. Ellenhorn and Barceloux: Medical Toxicology SECTION 5 FIREFIGHTING MEASURES Extinguishing media - Alcohol stable foam. Special hazards arising from the substrate or mixture Fire Incompatibility - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Advice for firefighters Fire Fighting - Alert Fire Brigade and tell them location and nature of hazard. Slight hazard when exposed to heat, flame and oxidisers. Fire/Explosion Hazard Combustible. Combustion products include: carbon monoxide (CO) carbon dioxide (CO2) other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. Articles and manufactured articles may constitute a fire hazard where polymers form their outer layers or where combustible packaging remains in place. HAZCHEM Not Applicable SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills - Clean up all spills immediately. Major Spills - Clear area of personnel and move upwind. Minor hazard. - Clean up all spills immediately. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 HANDLING AND STORAGE Precautions for safe handling Safe handling - Avoid all personal contact, including inhalation. Other information Store in a cool dry place out of direct sunlight. Shelf Life: 12 Months According to the specified storage conditions. Conditions for safe storage, including any incompatibilities Suitable container Generally packaging as originally supplied with the article or manufactured item is sufficient to protect against physical hazards. Storage incompatibility - Glycols and their ethers undergo violent decomposition in contact with 70% perchloric acid. Acetic acid: - vapours forms explosive mixtures with air (above 39 C.) - reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide - reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus isocyanate, phosphorus trichloride, sodium peroxide, xylene - attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas - attacks many forms of rubber, plastics and coatings Alcohols - are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents. Continued... Chemwatch: 9-494159 Page 4 of 11 Issue Date: 07/12/2017 Version No: 1.1 Print Date: 07/12/2017 003537 SOURSOP FLAVOUR NATURAL SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards ethyl acetate Ethyl acetate 720 mg/m3 / 200 ppm 1440 mg/m3 / 400 ppm Not Available Not Available Australia Exposure Standards iso-amyl acetate Isoamyl acetate 270 mg/m3 / 50 ppm 541 mg/m3 / 100 ppm Not Available Not Available Australia Exposure Standards acetic acid glacial Acetic acid 25 mg/m3 / 10 ppm 37 mg/m3 / 15 ppm Not Available Not Available Exposure controls Appropriate engineering controls Articles or manufactured items, in their original condition, generally don't require engineering controls during handling or in normal use. Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Personal protection Eye and face protection - Safety glasses with side shields. No special equipment required due to the