Report-Of Committee on Chemicals and Explosives
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Thermochemical Properties of Methyl and Chloro-Methyl Hyplochlorites and Ethers and Reaction of Methyl Radical with CLO
New Jersey Institute of Technology Digital Commons @ NJIT Theses Electronic Theses and Dissertations Spring 5-31-2000 Thermochemical properties of methyl and chloro-methyl hyplochlorites and ethers and reaction of methyl radical with CLO Dawoon Jung New Jersey Institute of Technology Follow this and additional works at: https://digitalcommons.njit.edu/theses Part of the Chemistry Commons Recommended Citation Jung, Dawoon, "Thermochemical properties of methyl and chloro-methyl hyplochlorites and ethers and reaction of methyl radical with CLO" (2000). Theses. 778. https://digitalcommons.njit.edu/theses/778 This Thesis is brought to you for free and open access by the Electronic Theses and Dissertations at Digital Commons @ NJIT. It has been accepted for inclusion in Theses by an authorized administrator of Digital Commons @ NJIT. For more information, please contact [email protected]. Copyright Warning & Restrictions The copyright law of the United States (Title 17, United States Code) governs the making of photocopies or other reproductions of copyrighted material. Under certain conditions specified in the law, libraries and archives are authorized to furnish a photocopy or other reproduction. One of these specified conditions is that the photocopy or reproduction is not to be “used for any purpose other than private study, scholarship, or research.” If a, user makes a request for, or later uses, a photocopy or reproduction for purposes in excess of “fair use” that user may be liable for copyright infringement, This institution reserves -
Ni33nh3+3Nhi
Pure & Appi. Chem., Vol. 49, pp.67—73. Pergamon Press, 1977. Printed in Great Britain. NON-AQJEOUS SOLVENTS FOR PREPARATION AND REACTIONS OF NITROGEN HALOGEN COMPOUNDS Jochen Jander Department of Chemistry, University of Heidelberg, D 69 Heidelberg, Germany Abstract -Theimportance of non—aqueous solvents for the chemistry of haloamines is shown in more recent reaction examples. The solvents must be low-melting because of the general temperature sensitivity of the haloamines. They may take part in the reaction (formation of CH NI •CH NH (CH )2NI, NI-,.5 NH-, and NH0I.NH-)ormay e ner (ormation of I .quinuiilidin, 2 NI •1 trithylenediamine, [I(qunuclidine),] salts pure NBr, and compounds of the type R1R2NC103 with R1 and R2 =orgnicgroup or hydrogen). INTRODUCTION Non-aqueous solvents play an important role in preparation and reactions of nitrogen halogen compounds. Due to the fact, that all haloamines are derivatives of ammonia or amines, liquid ammonia or liquid organic amines are used as solvents very often. Liquid ammonia and the lower organic amines reveal, in addition, the advantage of low melting points (liquid ammonia -78, liquid monomethylamine -93.5, liquid dimethylamine -92, liquid tn-. methylamine -12k°C); these meet the general temperature sensitivity of the nitrogen halogen compounds, especially of the pure .lorganic ones. Ammonia and amines are very seldom inert solvents; they mostly take part in the reaction planned for synthesis or conversion of the haloamine. In case a reaction of the solvent is to be avoided, one has to look for a low melting inert solvent, for example methylene chloride (m.p. -
NSF Renewal Proposal Appendix B
Appendix B – Part II Results from Prior Support (one-pagers) As examples of the breadth and vitality of the scientific achievements of the COMPRES community, Appendix B of this proposal provides 143 research “one-pagers” that have been submitted by research groups in preparation of this proposal that summarize selected published results enabled by COMPPRES investment in community facilities and infrastructure from 2012- 2016. B-1 Table of Contents – One-Pagers High pressure-temperature phase diagrams of energetic materials: FOX-7 & TATB B-6 Nanocrystals in compression: Unexpected structural phase transition and amorphization due to surface impurities B-7 Pressure induced conductivity and yellow-to-black piezochromism in a layered Cu-Cl hybrid perovskite B-8 High-pressure single-crystal structures of 3D lead-halide hybrid perovskites and pressure effects on their electronic and optical properties B-9 Pressure-driven high-to-low spin transition in the bimetallic quantum magnet [Ru2(O2CMe)4]3[Cr(CN)6] B-10 Pressure-induced magnetic crossover driven by hydrogen bonding in CuF2(H2O)2(3- chloropyridine) B-11 Pressure-induced structural transition in copper pyrazine dinitrate and implications for quantum magnetism B-12 High pressure vibrational properties of WS2 nanotubes B-13 Infrared study of the pressure-induced insulator-to-metal transition in PrRu4P12 B-14 Material and elastic properties of Al-tobermorite in ancient Roman seawater concrete B-15 High-pressure behavior of osmium: An analog for iron in Earth’s core B-16 Pressure-induced phase -
Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
While There Are Many Thousands of Different Chemical Compounds There
NAMING CHEMICAL COMPOUNDS & WRITING CHEMICAL FORMULAS While there are many thousands of different chemical compounds there is a very definite system of nomenclature whereby we can name or write chemical formulas for most compounds. We divide the compounds into two main types – binary compounds and ternary compounds. I. Binary Compounds All true binary compounds contain only two elements. The name of every binary compound ends with “ide.” Binary compounds come in three types. They are: Type I ………. the metal forms only one type of cation Type II ……… the metal forms two or more types of cations Type III …….. contains only nonmetals We will look at each type, one at a time. Type I Binary Compounds For Type I binary compounds the metal present can be found in either Group 1 or Group 2 on the periodic table. The naming system for this type of compound is quite simple and is found below. Rules for naming Type I binary compounds 1. The cation is always name first and the anion second. 2. A simple cation (obtained from a single atom) takes its name from the name of the element. 3. A simple anion (obtained from a single atom) is named by taking the first part of the element name (the root) and adding the letters “IDE.” 4. Write the name for the compound by combining the names of the ions. When naming Type I binary compounds: name of first element root + ide The root is merely an abbreviation for the name of the second element. The roots of the most commonly used elements are listed in the following table. -
Operation Permit Application
Un; iy^\ tea 0 9 o Operation Permit Application Located at: 2002 North Orient Road Tampa, Florida 33619 (813) 623-5302 o Training Program TRAINING PROGRAM for Universal Waste & Transit Orient Road Tampa, Florida m ^^^^ HAZARDOUS WAb 1 P.ER^AlTTlNG TRAINING PROGRAM MASTER INDEX CHAPTER 1: Introduction Tab A CHAPTER 2: General Safety Manual Tab B CHAPTER 3: Protective Clothing Guide Tab C CHAPTER 4: Respiratory Training Program Tab D APPENDIX 1: Respiratory Training Program II Tab E CHAPTER 5: Basic Emergency Training Guide Tab F CHAPTER 6: Facility Operations Manual Tab G CHAPTER 7: Land Ban Certificates Tab H CHAPTER 8: Employee Certification Statement Tab. I CHAPTER ONE INTRODUCTION prepared by Universal Waste & Transit Orient Road Tampa Florida Introducti on STORAGE/TREATMENT PERSONNEL TRAINING PROGRAM All personnel involved in any handling, transportation, storage or treatment of hazardous wastes are required to start the enclosed training program within one-week after the initiation of employment at Universal Waste & Transit. This training program includes the following: Safety Equipment Personnel Protective Equipment First Aid & CPR Waste Handling Procedures Release Prevention & Response Decontamination Procedures Facility Operations Facility Maintenance Transportation Requirements Recordkeeping We highly recommend that all personnel involved in the handling, transportation, storage or treatment of hazardous wastes actively pursue additional technical courses at either the University of South Florida, or Tampa Junior College. Recommended courses would include general chemistry; analytical chemistry; environmental chemistry; toxicology; and additional safety and health related topics. Universal Waste & Transit will pay all registration, tuition and book fees for any courses which are job related. The only requirement is the successful completion of that course. -
Catalysis of the Oxygen Evolution Reaction by 4–10 Nm Cobalt Nanoparticles
Topics in Catalysis https://doi.org/10.1007/s11244-018-0923-4 ORIGINAL PAPER Catalysis of the Oxygen Evolution Reaction by 4–10 nm Cobalt Nanoparticles Edward Locke1 · Shan Jiang1 · Simon K. Beaumont1 © The Author(s) 2018 Abstract Electrolysis of water is key technology, not only for clean energy production, but to ensure a continued supply of hydrogen beyond fossil resources, essential to the manufacture of many chemical goods other than fuels. Cobalt nanomaterials have been widely identified as a promising candidate for the anode (oxygen evolution) reaction in this process, but much work has focused on applied materials or electrode design. Given the importance of oxidation state changes Co(III) → Co(IV) in the accepted reaction mechanism, in this work we look at size effects in small (4–10 nm) cobalt nanoparticles, where the ease of oxidation for lower cobalt oxidation states is known to change with particle size. To discriminate between geometric and chemical effects we have compared the catalysts in this study to others in the literature by turnover frequency (widely used in other areas of catalysis), in addition to the more commonly employed performance metric of the overpotential required to produce a current density of 10 mA cm−2. Comparisons are drawn to key examples of using well defined nanomaterials (where the surface are of cobalt sites can be estimated). This has enabled an estimated intrinsic turnover rate of ~ 1 O2 mol- ecule per surface Co atom per second at an overpotential of 500 mV in the oxygen evolution reaction under typical alkaline reaction conditions (pH 14.0) to be identified. -
Underactive Thyroid
Underactive Thyroid PDF generated using the open source mwlib toolkit. See http://code.pediapress.com/ for more information. PDF generated at: Thu, 21 Jun 2012 14:27:58 UTC Contents Articles Thyroid 1 Hypothyroidism 14 Nutrition 22 B vitamins 47 Vitamin E 53 Iodine 60 Selenium 75 Omega-6 fatty acid 90 Borage 94 Tyrosine 97 Phytotherapy 103 Fucus vesiculosus 107 Commiphora wightii 110 Nori 112 Desiccated thyroid extract 116 References Article Sources and Contributors 121 Image Sources, Licenses and Contributors 124 Article Licenses License 126 Thyroid 1 Thyroid thyroid Thyroid and parathyroid. Latin glandula thyroidea [1] Gray's subject #272 1269 System Endocrine system Precursor Thyroid diverticulum (an extension of endoderm into 2nd Branchial arch) [2] MeSH Thyroid+Gland [3] Dorlands/Elsevier Thyroid gland The thyroid gland or simply, the thyroid /ˈθaɪrɔɪd/, in vertebrate anatomy, is one of the largest endocrine glands. The thyroid gland is found in the neck, below the thyroid cartilage (which forms the laryngeal prominence, or "Adam's apple"). The isthmus (the bridge between the two lobes of the thyroid) is located inferior to the cricoid cartilage. The thyroid gland controls how quickly the body uses energy, makes proteins, and controls how sensitive the body is to other hormones. It participates in these processes by producing thyroid hormones, the principal ones being triiodothyronine (T ) and thyroxine which can sometimes be referred to as tetraiodothyronine (T ). These hormones 3 4 regulate the rate of metabolism and affect the growth and rate of function of many other systems in the body. T and 3 T are synthesized from both iodine and tyrosine. -
Safety Data Sheets
Safety Data Sheets Production Power Dry KC 03/23/2018 Safety Data Sheet Index Binder: Power Dry KC - Production Product Name CAS Number Manufacturer Version Date Page #2 Diesel Fuel - #2 Diesel Fuel 68334-30-5 ACCUSTANDARD, INC. 04/20/2016 4 #2 Diesel Fuel - Purex UltraPacks The Dial Corporation 09/13/2011 11 1-K KEROSENE, LS - 1-K KEROSENE, LS BP PRODUCTS NORTH AMERICA 12/12/2014 17 INC. 1.0 M CITRIC ACID - 1.0 M CITRIC ACID 77-92-9 HAMPTON RESEARCH 01/10/2017 30 2CTJ1 - Car Wash Soap Concentrate - 2CTJ1 - 3M - Automotive Aftermarket 05/08/2007 39 Car Wash Soap Concentrate 2U135 - Soap Hand 1 G - 2U135- Soap Hand GOJO Industries, Inc. 10/15/2007 41 1G 3M Hi-Strength 90 Bulk Adhesive, Clear - 3M 3M - Industrial Adhesives and 12/06/2017 43 Hi-Strength 90 Bulk Adhesive, Clear Tapes A07265 ZEP SS CLEANER ZUSCP16 STK ZEP Inc. 05/05/2015 56 20N16 - A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 A1121 Tire Shine - A1121 Tire Shine Omega Industrial Supply Inc 06/10/2015 66 AIRIEL SPICE AIR REFILLS - AIRIEL SPICE ECOLAB CO. 04/22/2009 70 AIR REFILLS AMSOIL Metal Protector - AMSOIL Metal Amsoil Inc 03/30/2016 74 Protector AVENGE PRO - AVENGE PRO Bridgepoint Systems 06/15/2013 85 Big Bubble Leak Detector - Big Bubble Leak J.C. WHITLAM MANUFACTURING 07/10/2015 91 Detector COMPANY BLM TIRE WET 5GL - BLM TIRE WET 5GL ZEP Inc. 02/08/2017 97 C L R - CALCIUM LIME & RUST REMOVER Jelmar, LLC 03/01/2009 106 ENHANCED FORMULA - CLR- Calcium Lime & Rust Remover (Enhanced Formula) Clorox Bleach - Clorox Bleach The Clorox Company 01/05/2015 111 Conoco Gasoline, Unleaded, with MTBE (All ConocoPhillips 02/13/2003 132 Grades) - Conoco Gasoline, Unleaded, with MTBE (All Grades) Dri-Eaz MILGO SR - Dri-Eaz MILGO SR Legend Brands Products 03/24/2015 143 FAB SET - CR12 - FAB SET - CR12 Bridgepoint Systems 02/01/2011 152 Freeze-proof RV & Marine -50 °F Burst South Win Ltd. -
19770005666.Pdf
General Disclaimer One or more of the Following Statements may affect this Document This document has been reproduced from the best copy furnished by the organizational source. It is being released in the interest of making available as much information as possible. This document may contain data, which exceeds the sheet parameters. It was furnished in this condition by the organizational source and is the best copy available. This document may contain tone-on-tone or color graphs, charts and/or pictures, which have been reproduced in black and white. This document is paginated as submitted by the original source. Portions of this document are not fully legible due to the historical nature of some of the material. However, it is the best reproduction available from the original submission. Produced by the NASA Center for Aerospace Information (CASI) V NASA TECHNICAL NASA TM X-73983 MEMORANDUM 00 X I-- A SURVEY OF KINETIC DATA OF COMPOUNDS CONTAINING FLUORINE Dana A. Brewer Langley Research Center (NASA-TM-X-73983) A SURVEY OF KINETIC DATA N77-12609 OF COMPOUNDS CONTAINING FLOURINE (NASA) 119 p, HC A06/MF A01 CSCL 04A Unclas G3/46 55838 November 1976 This informal documentation medium is used to provide accelerated or special release of technical information to selected users. The contents may not meet NASA formal editing and publication standards, may be re- vised, or may I be incorporated in another publication. 4WAil NATIONAL AERONAUTICS AND SPACE ADMINISTRATION DEC 1976 LANGLEY RESEARCH CENTER, HAMPTON, VIRGINIA 23665 WEIVED 0M tosp, Sn PACILITY INpUT BRANCH < C' ' r ^| ' 1. Report No. -
Chemical Innovation Technologies to Make Processes and Products More Sustainable
United States Government Accountability Office Center for Science, Technology, and Engineering Natural Resources and Environment Report to Congressional Requesters February 2018 TECHNOLOGY ASSESSMENT Chemical Innovation Technologies to Make Processes and Products More Sustainable GAO-18-307 The cover image displays a word cloud generated from the transcript of the meeting we convened with 24 experts in the field of sustainable chemistry. The size of the words in the cloud corresponds to the frequency with which each word appeared in the transcript. In most cases, similar words—such as singular and plural versions of the same word— were combined into a single term. Words that were unrelated to the topic of sustainable chemistry were removed. The images around the periphery are stylized representations of chemical molecules that seek to illustrate a new conceptual framework, whereby molecules can be transformed to provide better performance; however, they are not intended to represent specific chemical compounds. TECHNOLOGY ASSESSMENT Highlights of GAO-18-307, a report to congressional requesters Chemical Innovation February 2018 Technologies to Make Processes and Products More Sustainable Why GAO did this study What GAO found Chemistry contributes to virtually every Stakeholders lack agreement on how to define sustainable chemistry and how to aspect of modern life and the chemical measure or assess the sustainability of chemical processes and products; these industry supports more than 25 percent differences hinder the development and adoption of more sustainable chemistry of the gross domestic product of the technologies. However, based on a review of the literature and stakeholder United States. While these are positive interviews, GAO identified several common themes underlying what sustainable contributions, chemical production can chemistry strives to achieve, including: have negative health and environmental · improve the efficiency with which natural resources—including energy, consequences. -
Potentially Explosive Chemicals*
Potentially Explosive Chemicals* Chemical Name CAS # Not 1,1’-Diazoaminonaphthalene Assigned 1,1-Dinitroethane 000600-40-8 1,2,4-Butanetriol trinitrate 006659-60-5 1,2-Diazidoethane 000629-13-0 1,3,5-trimethyl-2,4,6-trinitrobenzene 000602-96-0 1,3-Diazopropane 005239-06-5 Not 1,3-Dinitro-4,5-dinitrosobenzene Assigned Not 1,3-dinitro-5,5-dimethyl hydantoin Assigned Not 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate Assigned Not 1,7-Octadiene-3,5-Diyne-1,8-Dimethoxy-9-Octadecynoic acid Assigned 1,8 –dihydroxy 2,4,5,7-tetranitroanthraquinone 000517-92-0 Not 1,9-Dinitroxy pentamethylene-2,4,6,8-tetramine Assigned 1-Bromo-3-nitrobenzene 000585-79-5 Not 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene Assigned 2,2-di-(4,4,-di-tert-butylperoxycyclohexyl)propane 001705-60-8 2,2-Dinitrostilbene 006275-02-1 2,3,4,6- tetranitrophenol 000641-16-7 Not 2,3,4,6-tetranitrophenyl methyl nitramine Assigned Not 2,3,4,6-tetranitrophenyl nitramine Assigned Not 2,3,5,6- tetranitroso nitrobenzene Assigned Not 2,3,5,6- tetranitroso-1,4-dinitrobenzene Assigned 2,4,6-Trinitro-1,3,5-triazo benzene 029306-57-8 Not 2,4,6-trinitro-1,3-diazabenzene Assigned Not 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate Assigned Not 2,4,6-Trinitroso-3-methyl nitraminoanisole Assigned 2,4-Dinitro-1,3,5-trimethyl-benzene 000608-50-4 2,4-Dinitrophenylhydrazine 000119-26-6 2,4-Dinitroresorcinol 000519-44-8 2,5-dimethyl-2,5-diydroperoxy hexane 2-Nitro-2-methylpropanol nitrate 024884-69-3 3,5-Dinitrosalicylic acid 000609-99-4 Not 3-Azido-1,2-propylene glycol dinitrate