Safety Data Sheets
Production
Power Dry KC
03/23/2018 Safety Data Sheet Index Binder: Power Dry KC - Production
Product Name CAS Number Manufacturer Version Date Page
#2 Diesel Fuel - #2 Diesel Fuel 68334-30-5 ACCUSTANDARD, INC. 04/20/2016 4
#2 Diesel Fuel - Purex UltraPacks The Dial Corporation 09/13/2011 11
1-K KEROSENE, LS - 1-K KEROSENE, LS BP PRODUCTS NORTH AMERICA 12/12/2014 17 INC.
1.0 M CITRIC ACID - 1.0 M CITRIC ACID 77-92-9 HAMPTON RESEARCH 01/10/2017 30
2CTJ1 - Car Wash Soap Concentrate - 2CTJ1 - 3M - Automotive Aftermarket 05/08/2007 39 Car Wash Soap Concentrate
2U135 - Soap Hand 1 G - 2U135- Soap Hand GOJO Industries, Inc. 10/15/2007 41 1G
3M Hi-Strength 90 Bulk Adhesive, Clear - 3M 3M - Industrial Adhesives and 12/06/2017 43 Hi-Strength 90 Bulk Adhesive, Clear Tapes
A07265 ZEP SS CLEANER ZUSCP16 STK ZEP Inc. 05/05/2015 56 20N16 - A07265 ZEP SS CLEANER ZUSCP16 STK 20N16
A1121 Tire Shine - A1121 Tire Shine Omega Industrial Supply Inc 06/10/2015 66
AIRIEL SPICE AIR REFILLS - AIRIEL SPICE ECOLAB CO. 04/22/2009 70 AIR REFILLS
AMSOIL Metal Protector - AMSOIL Metal Amsoil Inc 03/30/2016 74 Protector
AVENGE PRO - AVENGE PRO Bridgepoint Systems 06/15/2013 85
Big Bubble Leak Detector - Big Bubble Leak J.C. WHITLAM MANUFACTURING 07/10/2015 91 Detector COMPANY
BLM TIRE WET 5GL - BLM TIRE WET 5GL ZEP Inc. 02/08/2017 97
C L R - CALCIUM LIME & RUST REMOVER Jelmar, LLC 03/01/2009 106 ENHANCED FORMULA - CLR- Calcium Lime & Rust Remover (Enhanced Formula)
Clorox Bleach - Clorox Bleach The Clorox Company 01/05/2015 111
Conoco Gasoline, Unleaded, with MTBE (All ConocoPhillips 02/13/2003 132 Grades) - Conoco Gasoline, Unleaded, with MTBE (All Grades)
Dri-Eaz MILGO SR - Dri-Eaz MILGO SR Legend Brands Products 03/24/2015 143
FAB SET - CR12 - FAB SET - CR12 Bridgepoint Systems 02/01/2011 152
Freeze-proof RV & Marine -50 °F Burst South Win Ltd. 03/27/2015 156 Antifreeze - Freeze-proof RV & Marine -50 °F Burst Antifreeze
Page 2 of 276 Product Name CAS Number Manufacturer Version Date Page
Burst Antifreeze
Graffiti Gone - Graffiti Gone QuestSpecialty Corporation 11/10/2014 166
Gumout Regane Auto Parts Cleaner & ITW Global Brands 05/13/2015 171 Degreaser - Gumout Regane Auto Parts Cleaner & Degreaser
KILL ODOR PLUS - KILL ODOR PLUS Chemspec 09/08/2014 181
Liquid HE 150 XPT - Liquid HE 150 XPT Drilling Specialties Company 04/10/2013 188
Mass Air Flow Sensor Cleaner - Mass Air Flow CRC Industries, Inc. 08/07/2017 199 Sensor Cleaner
Microban Milgo Plus - Microban Milgo Plus Legend Brands 04/03/2017 211
Northex Anti-Freeze - Northex Anti-Freeze CADILLAC OIL COMPANY 10/09/2014 221
On and Gone – Mould and Mildew Stain 7681-52-9 ClearTech Industries, Inc. 02/03/2015 224 Remover - On and Gone – Mould and Mildew Stain Remover
POWDERED DEFOAMER - POWDERED GENICARE INC. 11/01/2002 235 DEFOAMER
PURELL Advanced Hand Sanitizer - PURELL GOJO Industries, Inc. 03/18/2015 237 Advanced Hand Sanitizer
Purple Power - Purple Power Leysons Products, a division of 12/19/2017 252 1787528 Ontario Inc.
Scotch-gard Shoe Guard Liquid Shoe Polish 3M - Materials Resource Division 02/12/2014 258 with Water Repellent - Scotch-gard Shoe Guard Liquid Shoe Polish with Water Repellent
ShockWave - ShockWave Fiberlock Technologies, Inc. 04/08/2009 267
Truckmount Descaler - Truckmount Descaler 5329-14-6 PROCHEM - Kärcher North 02/24/2009 269 America
Ultrapac Trafficlean - Ultrapac Trafficlean PROCHEM - Kärcher North 11/12/2013 273 America
Page 3 of 276 SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 1.1 - Product Identifiers Catalog Name: SDF-BL-100ML Description: #2 Diesel Fuel CAS No.: 68334-30-5 1.2 - Relevant Identified Uses of the Substance or Mixture Laboratory Chemical Reference Material 1.3 - Supplier Details Company: AccuStandard, Inc. 125 Market St. New Haven, CT 06513 USA Telephone Number: 203-786-5290 Fax: 203-786-5287 Email: [email protected] 1.4 - Emergency Telephone Number Emergency Phone #: AccuStandard, Inc. 1-203-502-7070 (USA) 1-203-502-7070 (International)
24 hours / 7 days a week
SECTION 2 - HAZARDS IDENTIFICATION 2.1 - GHS Label Elements
2 2 HEALTH 2 0 2 FLAMMABILITY 0 PHYSICAL HAZARD Signal Word: Warning Hazard Codes: H226 - Flammable liquid. (Flammable liquids, category 3) H302 - Harmful if swallowed. (Acute toxicity, oral, category 4) H305 - Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard, catagory 2) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H320 - Irritating to eyes. (Eye damage/irritation, category 2B) H413 - May cause long-term adverse effects in the aquatic environment. Precautionary Codes: P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. P210 - Store in a cool dry place away from ignition sources.
SDS Date: 4/20/2016 Page 1 of 7
Page 4 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
SECTION 2 - HAZARDS IDENTIFICATION - continued 2.1 - GHS Label Elements - continued P260 - Do not breathe vapor. P262 - Do not get in eyes, on skin or clothing. P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure. P331 - Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. P404 - Store in a tightly closed container. 2.2 - Other Hazards 2.2.1 - Symptom of Exposure Health/Environment Flammable liquid. (Flammable liquids, category 3) Ingestion may cause drowsiness, blood pressure depression, diarrhea, nausea, and decrease in red blood cells. Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard, catagory 2) Causes depression of central nervous system. Inhalation of excessive vapor or mist concentrations may be irritating to the respiratory passages. May cause headache, dizziness, nausea, vomiting and loss of coordination can result, depending on the concentration and exposure time. May cause long-term adverse effects in the aquatic environment. (H413) 2.2.2 - Potential Health Effects Irritating to eyes. (Eye damage/irritation, category 2B) Irritating to skin. (Skin corrosion/irritation, category 2) May be harmful if absorbed through the skin. (Acute toxicity, dermal, category 5) Irritating to mucous membrane and upper respiratory system. May be harmful if inhaled. (Acute toxicity, inhalation, category 5) Harmful if swallowed. (Acute toxicity, oral, category 4) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity California Proposition 65 cancer hazard. This product is or contains a component that is not listed (ACGIH, IARC, NTP, OSHA) as a cancer causing agent.
SECTION 3 - COMPOSITION / ANALYTES DATA Description: #2 Diesel Fuel Synonyms: N/A
SDS Date: 4/20/2016 Page 2 of 7
Page 5 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
SECTION 3 - COMPOSITION / ANALYTES DATA - continued Molecular Weight: N/A Molecular Formula: N/A EC#: 269-822-7 Index#: 649-224-00-6
ACGIH -TLV (mg/m³) OSHA -PEL (mg/m³) Analyte CAS Number % Concentration TWA STEL Skin TWA STEL Skin # 2 Diesel Fuel 68334-30-5 100.000
SECTION 4 - FIRST AID MEASURES 4.1 - First Aid Procedures - General Get medical assistance for all cases of overexposure. 4.2 - Eye Contact Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. (P338) 4.3 - Skin Contact Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. (P360) 4.4 - Inhalation Inhalation: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. 4.5 - Ingestion Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. (P331)
SECTION 5 - FIRE FIGHTING MEASURES 5.1 - Flammable Properties Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. 5.2 - Extinguishing Media Use alcohol foam, carbon dioxide, or dry chemical when fighting fires involving this material. Water or foam may cause frothing. Do not spray water directly on oil fire. Water spray to cool fire-exposed containers and disperse vapors. 5.3 - Protection of Firefighters As in any fire, wear self-contained breathing apparatus pressure demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
SDS Date: 4/20/2016 Page 3 of 7
Page 6 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
SECTION 6 - ACCIDENTAL RELEASE MEASURES 6.1 - Spill Response Wear suitable protective equipment listed under Exposure Controls / Personal Protection. Eliminate any ignition sources until the area is determined to be free from explosion or fire hazards. Contain the release and eliminate its source, if this can be done without risk. Dispose as hazardous waste. Comply with Federal, State and local regulations.
SECTION 7 - HANDLING AND STORAGE Store in a tightly closed container. (P404) Store in a cool dry place away from ignition sources. Do not breathe vapor. (P260) Use with adequate ventilation. Do not get in eyes, on skin or clothing. (P262) Avoid prolonged or repeated exposure. This product should only by used by persons trained in the safe handling of hazardous chemicals. (P202)
SECTION 8 - EXPOSURE CONTROLS 8.1 - Engineering Controls/PPE Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. (P264) 8.2 - General Hygene Considerations Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure. Material should be handled or transferred in an approved fume hood or with adequate ventilation. Protective gloves should be worn to prevent skin contact. (Nitrile or equivalent) Use eye protection tested and approved under the appropriate government standards such as NIOSH (US) or EN 166 (EU). All recommendations are advisory only and must be evaluated by an industrial hygienist and/or safety officer familiar with the specific situation of anticipated use, such as concentration and amount of the substance in the workplace. Any recommendation should not be construed as offering an approval for any specific use of the product.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Light color to brown oily liquid Odor: Kerosene-like Odor Threshold: N/A pH: N/A Melting Point: < -38 °C Boiling Point: 171.5 - 315.5 °C (340 - 600 °F) Flash Point: 130 °F (54 °C) (tcc) Evaporation Rate (Butyl Acetate=1): 10-11 (approx.)
SDS Date: 4/20/2016 Page 4 of 7
Page 7 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES - continued Flammability Class: N/A Lower Flammability Level: 0.4 Upper Flammability Level: 6 Vapor Pressure: >1 mmHg Vapor Density (Air = 1): 5 (approx.) Specific Gravity: 0.85 - 0.93 g/cm3 Solubility in Water: Insoluble Partition Coefficient: N/A Autoignition Temperature: 230°C Decomposition Temperature: N/A Viscosity: 11 cSt (40 °C) VOC Content: N/A Percent Volatile: 99+
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Oxidizers Hazardous Decomposition: Carbon oxides; Hydrocarbons Hazardous Polymerization: Will not occur Condition to Avoid: Heat; Contact with ignition sources
SECTION 11 - TOXICOLOGICAL INFORMATION Human Health Toxicity See section 2 for specific toxicological information for the ingredients of this product. LD50 (Oral): Rat - 490 mg/kg LD50 (Dermal) : Rabbit - >2000 mg/kg LC50 (Inhalation): Rat - >20 mg/L Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard, catagory 2) No other information related to the toxicological properties of this product is available at this time.
SECTION 12 - ECOLOGICAL INFORMATION Environmental Toxicity By complying with sections 6 and 7 there should be no release to the environment. LC50 (Fish): 35mg/L 96H EC50 (Aquatic Invertebrate): N/A BCF: N/A Readily biodegradable. Contains constituents with the potential to bioaccumulate. No other information related to the ecological properties of this product is available at this time.
SDS Date: 4/20/2016 Page 5 of 7
Page 8 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
SECTION 13 - DISPOSAL CONSIDERATIONS Recycle or incinerate at any EPA approved facility or dispose in compliance with Federal, State and local regulations. Empty containers must be triple-rinsed prior to disposal.
SECTION 14 - TRANSPORT INFORMATION Transportation Information (DOT/IATA) UN Number: UN1202 Class: 3 Packing Group: III Proper Shipping Name: Diesel fuel Poison by Inhalation: No Marine Pollutant: No
SECTION 15 - REGULATORY INFORMATION This product is or contains a variable complex mixture of components, principally hydrocarbons, blended to performance, rather than chemical specifications, and typically contains the following components: Naphtha (petroleum) light-heavy catalytic cracked, full-range reformed/alkylyte, sweetened; Butane; Proprietary additives. May also include varying amounts of the following components: Benzene; Cumene; Cyclohexane; Ethylbenzene; Naphthalene; Hexane; Toluene; Xylene. All components are listed on the TSCA Inventory. For laboratory, research and development use only. Not for manufacturing or commercial purposes. In addition to federal and state regulations, local regulations may apply. Check with your local regulatory authorities.
SECTION 16 - OTHER INFORMATION This document has been designed to meet the requirements of OSHA, ANSI, GHS and CHIPs regulations. Chemicals are classified using the Globally Harmonized System for Classification and Labeling of Chemicals.
The statements contained herein are offered for informational purposes only and are based on technical data that we believe to be accurate. The manufacturer will not assume any liability for the accuracy and completeness of this information. Final determination of the suitability of the material is the responsibility of the user. Although certain hazards are described herein, the user should not presume that these are the only hazards that exist. Since conditions and manner of use are outside of the manufacturers control, we make NO WARRANTY OF MERCHANTABILITY, EXPRESSED OR IMPLIED, AND ASSUME NO LIABILITY RESULTING FROM ITS USE. Legend : N/A = Not Available ND = Not Determined NR = Not Regulated
Alteration of any information contained herein without written permission from the manufacturer is strictly prohibited.
HMIS/NFPA HAZARD INDEX 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
* - Additional Hazard
SDS Date: 4/20/2016 Page 6 of 7
Page 9 of 276 AccuStandard, Inc. SAFETY DATA SHEET Catalog Number: SDF-BL-100ML
GHS HAZARD INDEX Category 1 - Most Severe Category 5 - Least Severe **** End of Document ****
SDS Date: 4/20/2016 Page 7 of 7
Page 10 of 276 MATERIAL SAFETY DATA SHEET MSDS G-113 REVISION 0
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
The Dial Corporation Medical Emergencies: 1-888-689-9082 19001 N. Scottsdale Road Chemtrec: 1-800-424-9300 (24 Hours Daily) Scottsdale, Arizona 85255-9672 Other Information: 1-888-468-6673 PRODUCT: Purex® UltraPacks DATE OF ISSUE: September 13, 2011 TRADE NAMES/SYNONYMS: Purex® UltraPacks Liquid Laundry Detergent – Free & Clear, Mountain Breeze CHEMICAL FAMILY: Mixture I.D. NUMBERS: IDH# 1599132 (F&C); IDH# 1599135 (Mountain Breeze)
SECTION 2: HAZARD IDENTIFICATION
EMERGENCY OVERVIEW CAUTION: This product is clear to pale yellow or clear blue liquid with a pleasant odor. Direct contact with eyes causes irritation. Harmful if swallowed. Repeated or prolonged excessive exposure with skin can result in defatting and drying which may result in irritation and dermatitis. Keep out of reach of children. No significant environmental effects. Not a fire hazard. Product is stable. This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission. The use pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the Occupational Safety and Health Administration applicable to this Material Safety Data Sheet differ from the requirements of the CPSC and as a result, this MSDS may contain additional health hazard information not pertinent to consumer use and not found on the product label. REGULATORY STATUS This material is considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR 1900.1200). This MSDS should be retained and available for employees and other users of this product. POTENTIAL HEALTH EFFECTS NOTE: The acute health effects described below are those which could potentially occur for the finished product. They are based on the toxicology information available for the finished product and/or each hazardous ingredient, and are consistent with the product type and the likelihood of a specific route of exposure. Known chronic health effects related to exposure to a specific ingredient are indicated. EYE CONTACT: This product may cause moderate-to-severe irritation with pain, tearing, and blurred vision. SKIN CONTACT: Repeated or prolonged excessive exposure can result in defatting and drying of the skin which may result in irritation and dermatitis. INGESTION: Ingestion may cause severe irritation or burns to esophagus, mouth, and stomach with nausea, vomiting and diarrhea. INHALATION: Unlikely to occur due to the physical properties of the product. Mists may cause respiratory tract irritation. CHRONIC HEALTH EFFECTS: None known. MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: Persons with history of chronic skin conditions. POTENTIAL ENVIRONMENTAL EFFECTS See Section 12: Ecological Information.
______The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 1 of 6
Page 11 of 276 PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
Based on our hazard evaluation, the following chemical substance(s) in this product have been identified as hazardous. INGREDIENT CAS NUMBER PERCENT (w/w) Alcohol Ethoxylates 68213-23-0 / 68551-12-2 30 – 60 % Alcohol Ether Sulfate 68081-91-4 10 – 30 % Glycerin 56-81-5 10 – 30 % Propylene Glycol 57-55-6 5 – 10 %
SECTION 4: FIRST AID MEASURES
EYES: Immediately rinse eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention if pain or irritation persist. SKIN: Rinse affected area with large amounts of water until no evidence of product remains. Get medical attention if irritation persists. INGESTION: Treat symptomatically and supportively. Maintain airway and respiration. If vomiting occurs, keep head below hips to prevent aspiration. Dilution by rinsing the mouth and giving a glass of water to drink is generally recommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poison control center. INHALATION: Remove from exposure area to fresh air. Keep affected person warm and at rest. Treat symptomatically and supportively. NOTE TO PHYSICIAN: The physician's judgment should be used to control symptoms and clinical condition based on the individual reactions of the patient.
SECTION 5: FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES OSHA FLAMMABILITY CLASSIFICATION: Not applicable FLASH POINT: None UPPER FLAMMABILITY LIMIT: Not applicable LOWER FLAMMABILITY LIMIT: Not applicable AUTO-IGNITION TEMPERATURE: Not applicable FIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat or flame. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and oxides of nitrogen. EXTINGUISHING MEDIA Dry chemical, carbon dioxide, water spray or regular foam. PROTECTION OF FIREFIGHTERS In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Use flooding amounts of water as a fog, solid streams may be ineffective. Avoid breathing vapors; keep upwind.
SECTION 6: ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so. Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Make sure area is slip-free before re-opening to traffic.
The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 2 of 6
Page 12 of 276 PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011 ENVIRONMENTAL PRECAUTIONS Small or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check with your local water treatment plant. METHODS FOR CONTAINMENT AND CLEAN UP SMALL SPILLS: Contain and absorb with sand or other absorbent material and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover by pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable waste container.
SECTION 7: HANDLING AND STORAGE
HANDLING: Avoid contact with eyes, skin and clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Wash thoroughly after handling STORAGE: Store in original containers in a cool dry area. Store away from excessive heat and incompatible substances. Storage areas for large quantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.
SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use. The information provided below refers to the occupational settings. WORKER EXPOSURE LIMITS The following exposure limits exist for the ingredients listed below. The TLV-TWA is the ACGIH Threshold Limit Value – Time Weighted Average. TLV-Ceiling Limit is the ACGIH Threshold Limit Value – Ceiling Limit. PEL-TWA is the OSHA Permissible Exposure Limit. INGREDIENT CAS NUMBER EXPOSURE LIMIT Glycerin 56-81-5 TLV-TWA: 10 mg/m3 (mist), PEL-TWA: 5mg/m3 (respirable fraction), PEL-TWA: 10mg/m3 (total mist) ENGINEERING CONTROLS: Provide local exhaust or general dilution ventilation to keep potential exposure to airborne contaminants as low as possible. RESPIRATOR: None required under normal use conditions. If respiratory protection is required, it must be based on the contamination levels found in the workplace, must not exceed the working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). FOR FIRE FIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: Any self- contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive- pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure demand or other positive-pressure mode. CLOTHING: Protective clothing (impervious to liquids) is required where splashing of product may occur. GLOVES: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur. EYE/FACE PROTECTION: Splash-proof safety glasses are required to prevent eye contact where splashing of product may occur.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear to pale yellow or clear blue liquid. ODOR/ODOR THRESHOLD: Pleasant fragrance PHYSICAL STATE: Liquid pH (@ 25°C): 11.0 VAPOR DENSITY: Not available BOILING POINT: Not available VAPOR PRESSURE: Not available The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 3 of 6
Page 13 of 276 PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011 MELTING/FREEZING POINT: Not available FLASH POINT: See Section 5. FLAMMABLE PROPERTIES: See Section 5. SOLUBILITY IN WATER: Complete DENSITY/SPECIFIC GRAVITY: 1.030 g/ml @ 25°C EVAPORATION RATE: Not available
OCTANOL/WATER PARTITION COEFFICIENT (Kow): Not available VISCOSITY: 350 cps @ 25qC CLOUD POINT: Not determined
SECTION 10: STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm). CONDITIONS TO AVOID: Avoid storing in direct sunlight and avoid extremes of temperature. INCOMPATIBLE MATERIALS: Strong oxidizers and reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition products may include oxides of carbon. POSSIBILITY OF HAZARDOUS REACTIONS: Polymerization does not occur under normal temperatures and pressures.
SECTION 11: TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION SUMMARY: This product is a laundry care product. The use of this product by consumers is safe under normal and reasonable foreseen use. Direct contact with eyes may cause irritation. It may be harmful If swallowed. Repeated or prolonged excessive exposure with skin can result in defatting and drying which may result in irritation and dermatitis. COMPONENT ANALYSIS: The following toxicity information is for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings. PRODUCT / INGREDIENT LD50 / DRAIZE SCORE TOXICITY / IRRITATION RATING ACUTE ORAL TOXICITY Alcohol Ethoxylate > 2,000 mg/kg (rat) Practically Non-hazardous Glycerin 12,600 mg/kg (rat) Non-hazardous ACUTE DERMAL TOXICITY Glycerin > 10,000 mg/kg (rabbit) Non-hazardous SENSITIZATION: This product is not considered a skin or respiratory sensitizer. CARCINOGENICITY: None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA). MUTAGENICITY: None of the ingredients in this product are known to cause mutagenicity. REPRODUCTIVE/FETAL/DEVELOPMENTAL TOXICITY: None of the ingredients in this product are known as reproductive, fetal, or developmental hazards. TARGET ORGAN TOXICITY: None of the ingredients in this product are known to have target organ toxicity. EPIDEMIOLOGICAL INFORMATION: None of the ingredients in this product are known to have health-related information in working populations.
SECTION 12: ECOLOGICAL INFORMATION
This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions. The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings. PRODUCT / INGREDIENT LC50 / ED50 (mg/L) TOXICITY RATING VERTEBRATES The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 4 of 6
Page 14 of 276 PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011 Alcohol Ethoxylate 96h LC50: 1 - 10 mg/l (fish) Toxic Glycerin 96-hr LC50: 50 mg/L (Oncorhynchus mykiss) Harmful Propylene Glycol 96h LC50: 700 mg/l (Pimephales promelas) Practically Non-hazardous (static) INVERTEBRATES Alcohol Ethoxylate 48h EC50: 1 - 10 mg/l (Daphnia magna) Toxic Glycerin 24-hr EC50: > 500 mg/L (Daphnia magna) Practically Non-Hazardous Propylene Glycol 48h EC50: >1,000 mg/l (Daphnia magna) Practically Non-hazardous ENVIRONMENTAL FATE: No environmental fate data exists for the product. The product is anticipated to be rapidly biodegradable. PERSISTENCE AND DEGRADABILITY: The persistence and degradability of this product has not been determined. BIOACCUMULATION POTENTIAL: The bioaccumulation potential of this product has not been determined. MOBILITY: The mobility of this product (in soil and water) has not been determined.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE NUMBER AND DESCRIPTION: Not applicable, not regulated. DISPOSAL CONSIDERATIONS: This product is not a RCRA hazardous waste and can be disposed of in accordance with federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
GROUND TRANSPORT DOT Hazard Class: Not regulated Packing Group: Not applicable DOT Proper Shipping Name: Not applicable Shipping Label Information: Not applicable UN/NA Number: Not applicable AIR TRANSPORT (ICAO/IATA) MARINE TRANSPORT (IMDG/IMO) ICAO/IATA Hazard Class: Not regulated IMDG/IMO Hazard Class: Not regulated ICAO/IATA Proper Shipping Name: Not applicable IMDG/IMO Proper Shipping Name: Not applicable
SECTION 15: REGULATORY INFORMATION
UNITED STATES: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: The Occupational Safety and Health Administration requires Material Safety Data Sheets to provide any hazards that may be associated with the product, and make this information available in the workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this MSDS may contain additional health hazard information not pertinent to consumer use. EPA - SARA TITLE III SECTION 313: Not applicable - Consumer product. EPA CERCLA/SARA TITLE III SUPERFUND AMENDMENT AND REAUTHORIZATION ACT: This product contains no CERCLA/SARA Title III materials. This product contains no hazardous chemicals reportable under Sections 311/312. This product contains no hazardous chemicals reportable under Section 304. TSCA: All components of this product are listed on U.S. Toxic Substances Control Act (TSCA) chemical substance inventory. STATE REGULATIONS CALIFORNIA PROPOSITION 65: This product does not contain substances listed under California Proposition 65. CANADA: CANADIAN ENVIRONMENTAL PROTECTION ACT: INVENTORY STATUS: Some components of this product are not listed on the Canadian Domestic Substances List (DSL) nor the NDSL. The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 5 of 6
Page 15 of 276 PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011 WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM: WHMIS CLASSIFICATION: D2B.
SECTION 16: OTHER INFORMATION
DISCLAIMER: The information contained herein is provided in good faith and is believed to be correct as of the date hereof. However, The Dial Corporation makes no representation as to the comprehensiveness or accuracy of the information. It is expected that individuals receiving the information will exercise their independent judgment in determining its appropriateness for a particular purpose. Accordingly, The Dial Corporation will not be responsible for damages of any kind resulting from the use of or reliance upon such information. No representations, or warranties, either expressed or implied of merchantability, fitness for a particular purpose or of any other nature is made hereunder with respect to the information set forth herein or to the product to which the information refers. NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=1 REACTIVITY=0 HMIS RATINGS (Scale 0-4, where 4=severe hazard): HEALTH=2 FLAMMABILITY=1 REACTIVITY=0 MSDS CREATION DATE: 09/13/11 SUPERCEDES: REVISION DATE: REVISION:
The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672 Page 6 of 6
Page 16 of 276 SAFETY DATA SHEET
Section 1. Identification Product name 1-K Kerosene, LS SDS # 10925 Code 10925
Relevant identified uses of the substance or mixture and uses advised against Product use Fuel.
Supplier BP Products North America Inc. 150 West Warrenville Road Naperville, Illinois 60563-8460 USA EMERGENCY HEALTH 1 (800) 447-8735 INFORMATION: Outside the US: +1 703-527-3887 (CHEMTREC)
EMERGENCY SPILL 1 (800) 424-9300 CHEMTREC (USA) INFORMATION: OTHER PRODUCT 1 (866) 4 BP - MSDS INFORMATION (866-427-6737 Toll Free - North America) email: [email protected] Section 2. Hazards identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the FLAMMABLE LIQUIDS - Category 3 substance or mixture SKIN IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1
GHS label elements Hazard pictograms
Signal word Danger Hazard statements Flammable liquid and vapor. Causes skin irritation. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. Precautionary statements Prevention Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Do not breathe vapor. Wear protective gloves and eye protection. Avoid release to the environment. Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs, seek medical advice/attention.
Product name 1-K Kerosene, LS Product code 10925 Page: 1/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 17 of 276 Section 2. Hazards identification Storage Store in a well-ventilated place. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise None known. classified
Section 3. Composition/information on ingredients Substance/mixture Substance Ingredient name CAS number % Kerosene 8008-20-6 100 Contains: xylene 1330-20-7 < 1 Naphthalene 91-20-3 0.5 - 1 There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures Description of necessary first aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention. Inhalation If inhaled, remove to fresh air. Get medical attention.
If exposure to vapor, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice. Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Most important symptoms/effects, acute and delayed See Section 11 for more detailed information on health effects and symptoms.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treatment should in general be symptomatic and directed to relieving any effects. Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias. Specific treatments No specific treatment.
Product name 1-K Kerosene, LS Product code 10925 Page: 2/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 18 of 276 Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray. media Unsuitable extinguishing Do not use water jet. media
Specific hazards arising Flammable liquid and vapor. Fire water contaminated with this material must be from the chemical contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Hazardous combustion Combustion products may include the following: products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) other hazardous substances.
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) equipment for fire-fighters and full turnout gear. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency Immediately contact emergency personnel. No action shall be taken involving any personnel personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources. For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapor, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non- emergency personnel".
Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and materials for containment and cleaning up Small spill Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Large spill Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilled product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Product name 1-K Kerosene, LS Product code 10925 Page: 3/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 19 of 276 Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Avoid contact of spilled material and runoff with soil and surface waterways. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion- proof electrical (ventilating, lighting and material handling) equipment. Use only non- sparking tools. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage. Never siphon by mouth. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area. including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/ containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Light hydrocarbon vapors can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapor in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. Entry to any tanks or other confined space requires a full risk assessment and appropriate control measures to be put in place in conformance with appropriate regulations and industry practice on confined space entry. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapor mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurized fuel pipes, the vapor or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Kerosene ACGIH TLV (United States). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Issued/Revised: 1/2003
naphthalene ACGIH TLV (United States). Absorbed through skin. TWA: 52 mg/m³ 8 hours. Issued/Revised: 5/1996 TWA: 10 ppm 8 hours. Issued/Revised: 5/1996
Product name 1-K Kerosene, LS Product code 10925 Page: 4/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 20 of 276 Section 8. Exposure controls/personal protection OSHA PEL (United States). TWA: 50 mg/m³ 8 hours. Issued/Revised: 6/1993 TWA: 10 ppm 8 hours. Issued/Revised: 6/1993
xylene ACGIH TLV (United States). STEL: 651 mg/m³ 15 minutes. Issued/ Revised: 5/1996 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1996 TWA: 434 mg/m³ 8 hours. Issued/Revised: 5/1996 TWA: 100 ppm 8 hours. Issued/Revised: 5/1996 OSHA PEL (United States). TWA: 435 mg/m³ 8 hours. Issued/Revised: 6/1993 TWA: 100 ppm 8 hours. Issued/Revised: 6/1993 While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.
Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to ensure controls exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they controls comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Recommended: Safety glasses with side shield or chemical goggles. Skin protection Hand protection Wear chemical resistant gloves. Nitrile gloves.
Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use. Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions.
Product name 1-K Kerosene, LS Product code 10925 Page: 5/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 21 of 276 Section 8. Exposure controls/personal protection Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Wear suitable protective clothing. Footwear highly resistant to chemicals. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static. When there is a risk of ignition wear inherently fire resistant protective clothes and gloves. Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes. When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear clothing and footwear that cannot be penetrated by chemicals or oil. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use only with adequate ventilation. If ventilation is inadequate, use a NIOSH certified respirator with an organic vapor cartridge and P95 particulate filter.
If operating conditions cause high vapor concentrations or the TLV is exceeded, use NIOSH-certified, supplied-air respirator.
Use with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn. The filter class must be suitable for the maximum contaminant concentration (gas/vapor/ aerosol/particulates) that may arise when handling the product. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Recommended: If ventilation is inadequate, use respirator that will protect against organic vapor and dust/mist. Section 9. Physical and chemical properties Appearance Physical state Liquid. Color Clear (May be dyed) Odor Hydrocarbon. Odor threshold Not available. pH Not available. Melting point Not available. Boiling point 171.11 to 287.78°C (340 to 550°F) Flash point Closed cup: >37.778°C (>100°F) [Tagliabue.] Evaporation rate Not available. Flammability (solid, gas) Not applicable. Based on - Physical state Lower and upper explosive Lower: >0.7% (flammable) limits Upper: <5% Vapor pressure Not available.
Product name 1-K Kerosene, LS Product code 10925 Page: 6/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 22 of 276 Section 9. Physical and chemical properties Vapor density Not available. Density Not available. Relative density 0.83 Solubility insoluble in water. Solubility Insoluble in the following materials: cold water. Partition coefficient: n- Not available. octanol/water Auto-ignition temperature 210°C (410°F) Decomposition temperature Not available. Viscosity Kinematic: 1 to 1.9 mm2/s (1 to 1.9 cSt) at 40°C Section 10. Stability and reactivity Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Incompatible materials Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. halogenated compounds.
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should products not be produced.
Section 11. Toxicological information Information on toxicological effects Classification Product/ingredient name OSHA IARC NTP Kerosene (petroleum) - 3 - naphthalene - 2B Reasonably anticipated to be a human carcinogen. xylene - 3 - IARC : 2B - Possible carcinogen to human. 3 - Not classifiable as a human carcinogen.
NTP : Possible - Reasonably anticipated to be human carcinogens. Specific target organ toxicity (single exposure) Name Category Route of Target organs exposure Kerosene (petroleum) Category 3 Not applicable. Narcotic effects xylene Category 3 Not applicable. Respiratory tract irritation Aspiration hazard Name Result Kerosene (petroleum) ASPIRATION HAZARD - Category 1 xylene ASPIRATION HAZARD - Category 1
Product name 1-K Kerosene, LS Product code 10925 Page: 7/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 23 of 276 Section 11. Toxicological information
Information on the likely Routes of entry anticipated: Oral, Dermal, Inhalation. routes of exposure Potential acute health effects Eye contact No known significant effects or critical hazards. Skin contact Causes skin irritation. Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Ingestion Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following: pain or irritation watering redness Skin contact Adverse symptoms may include the following: irritation redness Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Ingestion Adverse symptoms may include the following: nausea or vomiting
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal effects decomposition products occurs. Vapor, mist or fume may irritate the nose, mouth and respiratory tract. Potential delayed effects Not available. Long term exposure Potential immediate Not available. effects Potential delayed effects Not available. Potential chronic health effects General May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal decomposition products occurs. Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Not available.
Product name 1-K Kerosene, LS Product code 10925 Page: 8/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 24 of 276 Section 11. Toxicological information Other information Aspiration of this product into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Do not siphon by mouth. Additional information Middle distillate: From skin-painting studies of petroleum distillates of similar composition and distillate range, it has been shown that these types of materials often possess weak carcinogenic activity in laboratory animals. In these tests, the material is painted on the shaved backs of mice twice a week for their lifetime. The material is not washed off between applications. Therefore, there may be a potential risk of skin cancer from prolonged or repeated skin contact with this product in the absence of good personal hygiene. This particular product has not been tested for carcinogenic activity, but we have chosen to be cautious in light of the findings with other distillate streams.
Occasional skin contact with this product is not expected to have serious effects, but good personal hygiene should be practiced and repeated skin contact avoided. This product can also be expected to produce skin irritation upon prolonged or repeated skin contact. Personal hygiene measures taken to prevent skin irritation are expected to be adequate to prevent risk of skin cancer.
Diesel exhaust particulates have been classified by the National Toxicological Program (NTP) to be a reasonably anticipated human carcinogen. Exposure should be minimized to reduce potential risk.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits. Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation. Naphthalene exposure has been associated with cataracts in animals and humans.
Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapor becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.
Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.
Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations, but no malformations. Because of the high exposure levels used in these studies, we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.
Xylene and its isomers are not genotoxic.
Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.
Product name 1-K Kerosene, LS Product code 10925 Page: 9/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 25 of 276 Section 12. Ecological information Toxicity No testing has been performed by the manufacturer.
Persistence and degradability Inherently biodegradable
Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.
Mobility in soil Soil/water partition Not available. coefficient (KOC) Mobility Spillages may penetrate the soil causing ground water contamination.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. United States - RCRA Toxic hazardous waste "U" List Ingredient CAS # Status Reference number Naphthalene 91-20-3 Listed U165 Xylene 1330-20-7 Listed U239
Section 14. Transport information
DOT TDG IMDG IATA Classification Classification UN number UN1223 UN1223 UN1223 UN1223
UN proper Kerosene KEROSENE KEROSENE KEROSENE shipping name Transport 3 3 3 3 hazard class(es)
Product name 1-K Kerosene, LS Product code 10925 Page: 10/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 26 of 276 Section 14. Transport information Packing group III III III III Environmental No. No. Yes. No. hazards Additional This product - The marine The information may be re- pollutant mark environmentally classified as is not required hazardous "Combustible when substance Liquid," unless transported in mark may transported by sizes of ≤5 L or appear if vessel or ≤5 kg. required by aircraft. Non- other bulk packages Emergency transportation (less than or schedules regulations. equal to 119 (EmS) gal) of F-E, S-E combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity.
Reportable quantity 100 lbs / 45.4 kg [14.45 gal / 54.699 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
Remarks Passenger aircraft: 60L Cargo Aircraft Only: 220L
Special precautions for user Not available.
Transport in bulk according Proper shipping name MARPOL Annex 1 rules apply for bulk shipments by to Annex II of MARPOL sea. 73/78 and the IBC Code Category: gas oils, including ship's bunkers
Product name 1-K Kerosene, LS Product code 10925 Page: 11/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 27 of 276 Section 15. Regulatory information U.S. Federal regulations United States inventory All components are listed or exempted. (TSCA 8b) SARA 302/304 Composition/information on ingredients No products were found.
SARA 311/312 Classification Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard SARA 313
Product name CAS number Concentration Form R - Reporting naphthalene 91-20-3 0.5 - 1 requirements xylene 1330-20-7 0 - 1 Supplier notification naphthalene 91-20-3 0.5 - 1 xylene 1330-20-7 0 - 1 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State regulations Massachusetts The following components are listed: KEROSINE; NAPHTHALENE; XYLENE New Jersey The following components are listed: KEROSENE; FUEL OIL #1; NAPHTHALENE; MOTH FLAKES; XYLENES; BENZENE, DIMETHYL- Pennsylvania The following components are listed: KEROSINE (PETROLEUM); NAPHTHALENE; BENZENE, DIMETHYL- California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer. naphthalene Other regulations Australia inventory (AICS) All components are listed or exempted. Canada inventory All components are listed or exempted. China inventory (IECSC) All components are listed or exempted. Japan inventory (ENCS) All components are listed or exempted. Korea inventory (KECI) All components are listed or exempted. Philippines inventory All components are listed or exempted. (PICCS) REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1. Section 16. Other information Hazardous Material Information System (U.S.A.) Health * 2 Flammability 2 Physical hazards 0 Personal protection X Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. National Fire Protection Association (U.S.A.)
Product name 1-K Kerosene, LS Product code 10925 Page: 12/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 28 of 276 Section 16. Other information
2 Flammability Health 2 0 Instability/Reactivity Special
History Date of issue/Date of 12/12/2014. revision Date of previous issue No previous validation. Key to abbreviations ACGIH = American Conference of Industrial Hygienists ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS Number = Chemical Abstracts Service Registry Number GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OEL = Occupational Exposure Limit SDS = Safety Data Sheet STEL = Short term exposure limit TWA = Time weighted average UN = United Nations UN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods. Indicates information that has changed from previously issued version. Notice to reader All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.
Product name 1-K Kerosene, LS Product code 10925 Page: 13/13 Version 1 Date of issue 12/12/2014. Format US Language ENGLISH (US) (ENGLISH) Page 29 of 276 Safety Data Sheet According to Regulation (EC) No 1907/2006 Revision Date: 01/10/2017 Version: 1.1 Date Printed: GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers Product Name : 1.0 M Citric acid Product Number : HR2-831 REACH No. : A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS Number : 77-92-9
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances.
1.3 Details of the supplier of the Safety Data Sheet Company : Hampton Research 34 Journey Aliso Viejo, CA 92656-3317 United States Telephone : 949 425 1321 Telephone technical support is available 8:00 a.m. to 4:30 p.m. USA Pacific Standard Time. Fax : 949 425 1611 Fax Technical Support is available 24 hours a day. e-mail : [email protected] e-mail Technical Support is available 24 hours a day.
1.4 Emergency telephone number Emergency phone : 949 425 1321 For CHEMTREC Assistance : 800 424 9300 For CHEMTREC Assistance : 703 527 3887 (International)
SECTION 2: Hazards Identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Eye irritation (Category 2)
Classification according to EU Directives 67/548/EEC or 1999/45/EC Irritating to eyes.
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 [CLP]
HR2-831 www.hamptonresearch.com Page 1 of 9 Page 30 of 276 (CONTINUED) - SECTION 2: Hazards Identification
Pictogram :
Signal word : Warning
Hazard statement(s) H319 : Causes serious eye irritation.
Precautionary statement(s) P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard : none Statements
According to European Directive 67/548/EEC as amended. Hazard symbol(s) :
R-phrase(s) R36 : Irritating to eyes. S-phrase(s) S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
2.3 Other hazards - none
SECTION 3: Composition/Information on Ingredients
3.1 Substances Synonym : Citric acid anhydrous
Formula : C6H8O7 or HOC(COOH)(CH2COOH)2 Molecular Weight : 192.13 CAS Number : 77-92-9 EC Number : 201-069-1
RTECS Merck Beilstein SARA MDL # PubChem Substance ID GE7350000 14,2326 782061 No MFCD00011669 24856611
Component Concentration Citric acid CAS-No. 77-92-9 - EC-No. 201-069-1
HR2-831 www.hamptonresearch.com Page 2 of 9 Page 31 of 276 SECTION 4: First Aid Measures
4.1 Description of first aid measures General Advice Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact Wash off with soap and plenty of water. Consult a physician.
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes as a precaution and consult a physician.
If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed Vomiting, Diarrhoea, Damage to tooth enamel., Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The most important known symptoms and effects are described in the labeling (see Section 2.2) and/or in Section 11.
4.3 Indication of any immediate medical attention and special treatment needed no data available
SECTION 5: Fire Fighting Measures
5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture Carbon oxides
5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further Information no data available
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Ensure adequate ventilation. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. HR2-831 www.hamptonresearch.com Page 3 of 9 Page 32 of 276 (CONTINUED) - SECTION 6: Accidental Release Measures
6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections For disposal see section 13.
SECTION 7: Handling and Storage
7.1 Personal Precautions Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. For precautions see section 2.2. Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
SECTION 8: Exposure Controls/Personal Protection
8.1 Control parameters Components with workplace control parameters
8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contami- nated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 480 min Material tested:Dermatril® (Aldrich Z677272, Size M)
HR2-831 www.hamptonresearch.com Page 4 of 9 Page 33 of 276 (CONTINUED) - SECTION 8: Exposure Controls/Personal Protection
Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril® (Aldrich Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected], test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
SECTION 9: Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: Fine Crystals Color: White b) Odor no data available c) Odor Threshold no data available d) pH 1.2 - 1.5 at 25°C e) Melting point/freezing point 153 - 159°C (lit.) f) Initial boiling point and no data available boiling range g) Flash point no data available h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability no data available or explosive limits k) Vapor pressure no data available l) Vapor density no data available m) Relative density no data available n) Water solubility no data available
HR2-831 www.hamptonresearch.com Page 5 of 9 Page 34 of 276 (CONTINUED) - SECTION 9: Physical and Chemical Properties
o) Partition coefficient: no data available noctanol/water p) Autoignition temperature no data available q) Decomposition no data available temperature r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available
9.2 Other safety information Surface tension no data available Relative vapour density no data available
SECTION 10: Stability and Reactivity
10.1 Reactivity no data available
10.2 Chemical stability no data available
10.3 Possibility of hazardous reactions no data available
10.4 Conditions to avoid no data available
10.5 Incompatible materials Oxidizing agents, Bases, Reducing agents, Nitrates
10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5
SECTION 11: Toxicological Information
11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 5.400 mg/kg LD50 Dermal - rat - > 2.000 mg/kg
Skin irritation / corrosion Skin - rabbit - Mild skin irritation - OECD Test Guideline 404
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Serious eye damage/eye irritation Eyes - rabbit - Irritating to eyes. - OECD Test Guideline 405
Respiratory or skin sensitization Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.
Germ cell mutagenicity no data available
Chronic exposure
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity no data available
Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure no data available
Aspiration hazard no data available
Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes Causes serious eye irritation.
Signs and Symptoms of Exposure Vomiting, Diarrhoea, Damage to tooth enamel., Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Additional information RTECS: GE7350000
SECTION 12: Ecological Information
12.1 Toxicity Toxicity to fish mortality LC50 - Leuciscus idus melanotus - 440 mg/l - 48 h Method: OECD Test Guideline 203 Toxicity to daphnia and static test - Daphnia magna (Water flea) - 1.535 mg/l - 24 h other aquatic invertebrates
HR2-831 www.hamptonresearch.com Page 7 of 9 Page 36 of 276 (CONTINUED) - SECTION 12: Ecological Information
12.2 Persistence and degradability no data available
12.3 Bioaccumulative potential no data available
12.4 Mobility in soil no data available
12.5 Results of PBT and vPvB assessment no data available
12.6 Other adverse effects no data available
SECTION 13: Disposal Considerations
13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging Dispose of as unused product.
SECTION 14: Transportation Information
14.1 UN number ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods
14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: -
14.4 Packaging group ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user no data available
HR2-831 www.hamptonresearch.com Page 8 of 9 Page 37 of 276 SECTION 15: Regulatory Information
This safety datasheet complies with the requirements of Regulation (EC) No 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available
15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out.
SECTION 16: Other Information
DISCLAIMER For research use only. Not for drug, household, or other use.
WARRANTY The above information is believed to be correct but does no purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of this product. Hampton Research Corp., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and condi- tions of sale. License granted to make unlimited paper copies for internal use only.
© 1991-2017 Hampton Research Corp.
HR2-831 www.hamptonresearch.com Page 9 of 9 Page 38 of 276 Page 39 of 276 Page 40 of 276 Page 41 of 276 Page 42 of 276 3M™ Hi-Strength 90 Bulk Adhesive, Clear 12/06/17
Safety Data Sheet
Copyright,2017,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 09-2094-2 Version Number: 12.00 Issue Date: 12/06/17 Supercedes Date: 03/18/16
SECTION 1: Identification
1.1. Product identifier 3M™ Hi-Strength 90 Bulk Adhesive, Clear
Product Identification Numbers 62-4479-7536-8, 62-4479-8532-6, 62-4479-9532-5
1.2. Recommended use and restrictions on use
Recommended use Adhesive, Industrial use
1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Specific Target Organ Toxicity (single exposure): Category 3.
2.2. Label elements Signal word Danger
Symbols Flame | Exclamation mark |
Pictograms
______
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Hazard Statements Highly flammable liquid and vapor.
Causes serious eye irritation. May cause drowsiness or dizziness.
Precautionary Statements
Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt Acetone 67-64-1 25 - 35 Trade Secret * Non-Volatile Components Trade Secret* 20 - 30 Trade Secret * Cyclohexane 110-82-7 15 - 25 Trade Secret * Pentane 109-66-0 15 - 25 Trade Secret * Cyclopentane 287-92-3 < 2 Trade Secret * Isopentane 78-78-4 < 2 Trade Secret *
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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If Swallowed: Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion
5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and ______
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could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling For industrial or professional use only. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer.
7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Pentane 109-66-0 ACGIH TWA:1000 ppm Pentane 109-66-0 OSHA TWA:2950 mg/m3(1000 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Cyclopentane 287-92-3 ACGIH TWA:600 ppm Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) Isopentane 78-78-4 ACGIH TWA:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average ______
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STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles
Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Fluoroelastomer Nitrile Rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: clear-light yellow, mild solvent odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point 36 ºC Flash Point -40 ºF [Test Method:Closed Cup] Evaporation rate 28 [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.6 % volume Flammable Limits(UEL) 9.4 % volume Vapor Pressure <=500 mmHg [@ 18.5 ºC] Vapor Density >=1 [Ref Std:AIR=1] Density 0.77 g/ml Specific Gravity 0.77 [Ref Std:WATER=1] ______
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Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 100 - 500 centipoise [@ 73.4 ºF ] Hazardous Air Pollutants 0 % weight [Test Method:Calculated] Molecular weight No Data Available VOC Less H2O & Exempt Solvents <=531 g/l [Test Method:calculated SCAQMD rule 443.1] Solids Content 20 - 30 % SECTION 10: Stability and reactivity
10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability Stable.
10.3. Possibility of hazardous reactions Hazardous polymerization will not occur.
10.4. Conditions to avoid Heat Sparks and/or flames
10.5. Incompatible materials Strong oxidizing agents
10.6. Hazardous decomposition products Substance Condition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. ______
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May cause additional health effects (see below).
Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.
Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- No data available; calculated ATE >50 mg/l Vapor(4 hr) Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Rat LC50 76 mg/l Vapor (4 hours) Acetone Ingestion Rat LD50 5,800 mg/kg Pentane Dermal Rabbit LD50 3,000 mg/kg Pentane Inhalation- Rat LC50 > 18 mg/l Vapor (4 hours) Pentane Ingestion Rat LD50 > 2,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Rat LC50 > 32.9 mg/l Vapor (4 hours) Cyclohexane Ingestion Rat LD50 6,200 mg/kg Non-Volatile Components Dermal Rabbit LD50 > 2,000 mg/kg Non-Volatile Components Ingestion Rat LD50 > 5,000 mg/kg Isopentane Dermal Rabbit LD50 3,000 mg/kg Isopentane Inhalation- Rat LC50 > 18 mg/l Vapor (4 hours) Isopentane Ingestion Rat LD50 > 2,000 mg/kg Cyclopentane Dermal LD50 estimated to be > 5,000 mg/kg Cyclopentane Inhalation- Rat LC50 > 25.3 mg/l Vapor (4 hours) Cyclopentane Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate
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Skin Corrosion/Irritation Name Species Value
Acetone Mouse Minimal irritation Pentane Rabbit Minimal irritation Cyclohexane Rabbit Mild irritant Non-Volatile Components Professio No significant irritation nal judgeme nt Isopentane Rabbit Minimal irritation Cyclopentane Rabbit Minimal irritation
Serious Eye Damage/Irritation Name Species Value
Acetone Rabbit Severe irritant Pentane Rabbit Mild irritant Cyclohexane Rabbit Mild irritant Isopentane Rabbit Mild irritant Cyclopentane Rabbit Mild irritant
Skin Sensitization Name Species Value Pentane Guinea Not classified pig Isopentane Guinea Not classified pig
Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity Name Route Value
Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification Pentane In vivo Not mutagenic Pentane In Vitro Some positive data exist, but the data are not sufficient for classification Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Isopentane In vivo Not mutagenic Isopentane In Vitro Some positive data exist, but the data are not sufficient for classification
Carcinogenicity Name Route Species Value Acetone Not Multiple Not carcinogenic Specified animal species
Reproductive Toxicity
Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700 13 weeks mg/kg/day Acetone Inhalation Not classified for development Rat NOAEL 5.2 during ______
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mg/l organogenesi s Pentane Ingestion Not classified for development Rat NOAEL 1,000 during mg/kg/day organogenesi s Pentane Inhalation Not classified for development Rat NOAEL 30 during mg/l organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 2 generation mg/l Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 2 generation mg/l Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 2 generation mg/l Isopentane Ingestion Not classified for development Rat NOAEL 1,000 during mg/kg/day organogenesi s Isopentane Inhalation Not classified for development Rat NOAEL 30 during mg/l organogenesi s
Target Organ(s)
Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Inhalation central nervous May cause drowsiness or Human NOAEL Not system depression dizziness available Acetone Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not data are not sufficient for available classification Acetone Inhalation immune system Not classified Human NOAEL 1.19 6 hours mg/l Acetone Inhalation liver Not classified Guinea NOAEL Not pig available Acetone Ingestion central nervous May cause drowsiness or Human NOAEL Not poisoning system depression dizziness available and/or abuse Pentane Inhalation central nervous May cause drowsiness or Multiple NOAEL Not not available system depression dizziness animal available species Pentane Inhalation respiratory irritation Some positive data exist, but the Not NOAEL Not not available data are not sufficient for available available classification Pentane Inhalation cardiac sensitization Not classified Dog NOAEL Not not available available Pentane Ingestion central nervous May cause drowsiness or Professio NOAEL Not not available system depression dizziness nal available judgeme nt Cyclohexane Inhalation central nervous May cause drowsiness or Human NOAEL Not system depression dizziness and available animal Cyclohexane Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not data are not sufficient for and available classification animal Cyclohexane Ingestion central nervous May cause drowsiness or Professio NOAEL Not system depression dizziness nal available judgeme nt Isopentane Inhalation central nervous May cause drowsiness or Multiple NOAEL Not not available system depression dizziness animal available species Isopentane Inhalation respiratory irritation Some positive data exist, but the Not NOAEL Not not available data are not sufficient for available available classification Isopentane Inhalation cardiac sensitization Not classified Dog NOAEL Not not available ______
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available Isopentane Ingestion central nervous May cause drowsiness or Professio NOAEL Not not available system depression dizziness nal available judgeme nt Cyclopentane Inhalation central nervous May cause drowsiness or similar NOAEL Not system depression dizziness compoun available ds Cyclopentane Ingestion central nervous May cause drowsiness or Professio NOAEL Not system depression dizziness nal available judgeme nt
Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Dermal eyes Not classified Guinea NOAEL Not 3 weeks pig available Acetone Inhalation hematopoietic Not classified Human NOAEL 3 6 weeks system mg/l Acetone Inhalation immune system Not classified Human NOAEL 1.19 6 days mg/l Acetone Inhalation kidney and/or Not classified Guinea NOAEL 119 not available bladder pig mg/l Acetone Inhalation heart | liver Not classified Rat NOAEL 45 8 weeks mg/l Acetone Ingestion kidney and/or Not classified Rat NOAEL 900 13 weeks bladder mg/kg/day Acetone Ingestion heart Not classified Rat NOAEL 13 weeks 2,500 mg/kg/day Acetone Ingestion hematopoietic Not classified Rat NOAEL 200 13 weeks system mg/kg/day Acetone Ingestion liver Not classified Mouse NOAEL 14 days 3,896 mg/kg/day Acetone Ingestion eyes Not classified Rat NOAEL 13 weeks 3,400 mg/kg/day Acetone Ingestion respiratory system Not classified Rat NOAEL 13 weeks 2,500 mg/kg/day Acetone Ingestion muscles Not classified Rat NOAEL 13 weeks 2,500 mg/kg Acetone Ingestion skin | bone, teeth, Not classified Mouse NOAEL 13 weeks nails, and/or hair 11,298 mg/kg/day Pentane Inhalation peripheral nervous Not classified Human NOAEL Not occupational system available exposure Pentane Inhalation heart | skin | Not classified Rat NOAEL 20 13 weeks endocrine system | mg/l bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system Pentane Ingestion kidney and/or Not classified Rat NOAEL 28 days bladder 2,000 mg/kg/day Cyclohexane Inhalation liver Not classified Rat NOAEL 24 90 days mg/l Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 90 days ______
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mg/l Cyclohexane Inhalation kidney and/or Not classified Rabbit NOAEL 2.7 10 weeks bladder mg/l Cyclohexane Inhalation hematopoietic Not classified Mouse NOAEL 24 14 weeks system mg/l Cyclohexane Inhalation peripheral nervous Not classified Rat NOAEL 8.6 30 weeks system mg/l Isopentane Inhalation peripheral nervous Not classified Human NOAEL Not occupational system available exposure Isopentane Inhalation heart | skin | Not classified Rat NOAEL 20 13 weeks endocrine system | mg/l bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system Isopentane Ingestion kidney and/or Not classified Rat NOAEL 28 days bladder 2,000 mg/kg/day
Aspiration Hazard Name Value Pentane Aspiration hazard Cyclohexane Aspiration hazard Isopentane Aspiration hazard Cyclopentane Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations
13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
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SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations Contact 3M for more information.
EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids)
Health Hazards Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 Trade Secret 15 - 25
15.2. State Regulations Contact 3M for more information.
15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group: 09-2094-2 Version Number: 12.00 Issue Date: 12/06/17 Supercedes Date: 03/18/16
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES ______
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NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M
3M USA SDSs are available at www.3M.com
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Page 55 of 276 SAFETY DATA SHEET
A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name : A07265 ZEP SS CLEANER ZUSCP16 STK 20N16
Material number : 000000000001041003 Manufacturer or supplier's details Company : Zep Inc.
Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318
Telephone : 404-352-1680
Emergency telephone numbers
For SDS Information : Compliance Services 1-877-428-9937 For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded For a Transportation : CHEMTREC: 800-424-9300 - All Calls Recorded. Emergency In the District of Columbia 202-483-7616
Note: This product is labeled as a consumer product in accordance with the United States Consumer Product Safety Commission regulations. The warnings presented below in this Safety Data Sheet (SDS) comply with the 2012 OSHA Hazard Communication Standard (GHS - Globally Harmonized System of Classification and Labeling). The requirements for the labeling and warnings of consumer products may differ from those required for GHS based hazard communication.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview Appearance Aerosol containing a liquefied gas Colour opaque Odour pleasant
GHS Classification Flammable aerosols : Category 1 Gases under pressure : Liquefied gas GHS Label element Hazard pictograms :
Signal word : Danger
Hazard statements : H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated.
Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
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P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Potential Health Effects
Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical Name CAS-No. Concentration [%] alkanes, C12-14-iso- 68551-19-9 >= 10 - < 20 butane 106-97-8 >= 10 - < 20 propane 74-98-6 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact : If on clothes, remove clothes. If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes.
In case of eye contact : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.
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A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
If in eyes, rinse with water for 15 minutes.
If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet
Unsuitable extinguishing : High volume water jet media
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water firefighting courses.
Hazardous combustion : Carbon dioxide (CO2) products Carbon monoxide Smoke Silicon oxides Specific extinguishing : methods Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Further information : For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. protective equipment and Remove all sources of ignition. emergency procedures Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel, containment and cleaning up acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal.
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A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use. Do not breathe vapours or spray mist.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.
Materials to avoid : Do not store near acids. Oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Components CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration butane 106-97-8 TWA 800 ppm NIOSH REL 1,900 mg/m3 TWA 800 ppm OSHA P0 1,900 mg/m3 propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm OSHA Z-1 1,800 mg/m3 TWA 1,000 ppm OSHA P0 1,800 mg/m3
Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
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Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. Tightly fitting safety goggles
Skin and body protection : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures : Wash hands before breaks and at the end of workday. When using do not smoke. When using do not eat or drink.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Colour : opaque Odour : pleasant Odour Threshold : no data available pH : not applicable Melting point/freezing point : no data available Boiling point : 100 °C Flash point : no data available Evaporation rate : < 1 n-Butyl Acetate = 1.0 Flammability (solid, gas) : Extremely flammable aerosol.
Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : not determined Density : 0.941 g/cm3 Solubility(ies) Water solubility : insoluble Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : not determined Thermal decomposition : no data available
Viscosity Viscosity, kinematic : no data available
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Page 60 of 276 SAFETY DATA SHEET
A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
Possibility of hazardous : No decomposition if stored and applied as directed. reactions Vapours may form explosive mixture with air.
Conditions to avoid : Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials : Acids Oxidizing agents
Hazardous decomposition : Carbon oxides products
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity Components: butane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h
LC50 rat: 1,355 mg/l
propane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h
LC50 rat: 658 mg/l Exposure time: 4 h
LC50 rat: 1,355 mg/l
Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity
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Page 61 of 276 SAFETY DATA SHEET
A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015 no data available Carcinogenicity no data available
Reproductive toxicity no data available alkanes, C12-14-iso-: butane: propane: STOT - single exposure no data available
STOT - repeated exposure no data available Aspiration toxicity no data available
Further information Product: Remarks: no data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Product: Partition coefficient: n- : Remarks: no data available octanol/water Components: butane : Partition coefficient: n- : Pow: 2.89 octanol/water Mobility in soil no data available Other adverse effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I
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Page 62 of 276 SAFETY DATA SHEET
A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological : no data available information
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations.
Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quantity
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ.
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Page 63 of 276 SAFETY DATA SHEET
A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard Sudden Release of Pressure Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory DSL This product contains the following components that are not on the Canadian DSL nor NDSL. AICS Not in compliance with the inventory NZIoC Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III: Flammability
HEALTH 3
4 Instability
3 0 FLAMMABILITY 4
Health
PHYSICAL HAZARD 2
0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015
OSHA GHS Label Information:
Hazard pictograms :
Signal w ord : Danger: Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statements : Prevention: Keep aw ay from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep® , Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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Page 65 of 276 This brief provides a general overview of the Safety Data Sheet requirements in the Hazard Communication Standard OSHA’s 29 CFR 1910.1200(g) and Appendix D of 29 CFR 1910.1200). Section 1 ~ Identification Identity (As Used On Label and List) Date Prepared: A1121 Tire Shine 06-10-2015 Company Information: Emergency Telephone Number: OMEGA INDUSTRIAL SUPPLY, INC 1-800-424-9300 Address (Number, Street, Suite/Apt#) Telephone Number for Information: 101 Grobric Ct #1 1-800-571-7347 (City, State, and Zip Code) Signature of Prepare (Optional) Fairfield, CA 94534 REGULATORY DEPT. Section 2 ~ Hazard(s) Identification Physical Hazards Flammable aerosols Category 1 Health Hazards Not classified Environmental Hazards Not classified OSHA Defined Hazards Not classified
Label elements Signal Word: Danger
Hazard Statement Extremely flammable aerosol. Precautionary Statement Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Do not spray on a open flame or other ignition source. Pressurized container: Do not Prevention pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazards(s) not otherwise Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. classified (HNOC) May cause flash fire or explosion. Section 3 ~ Composition/Information on Ingredients
Components (Specific Chemical Identity, Common Name(s)) CAS No. %(Wt.) Butane 106-97-8 2.5 – 10% Propane 74-98-6 1 – 2.5% Other components below reportable levels - 90 – 100%
*Designates that a specific chemival identity and/or percentage of composition has been withheld as a trade secret. Section 4 ~ First Aid Measures
Eyes — Get medical attention if irritation develops and persists. Skin— Get medical attention if irritation develops and persists. Inhalation — If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Ingestion — In the unlikely event of swallowing contact a physician or poison control center. Most Important Symptoms/Effects, Acute And Delayed — Direct contact with eyes may cause temporary irritation. Indication Of Immediate Medical Attention And Special Treatment Needed — Provide general supportive measures and treat symptomatically. General information— Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Section 5 ~ Fire Fighting Measures
Suitable Extinguishing Media – Water fog, foam, carbon dioxide (CO2) dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media – Do not use water jet as an extinguisher as this will spread the fire. Specific hazards arising from the chemical – Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Special protective equipment and precautions for firefighters – Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots and in enclosed spaces, SCBA. Fire-fighting equipment/instructions –– Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods – Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards – Extremely flammable aerosol. Section 6 ~ Accidental Release Measures
Personal Precautions, Protective Equipment And Emergency Procedures –Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods And Materials For Containment And Cleaning Up – Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental Precautions - Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.
Page 66 of 276 A1121 Tire Shine Page 2 of 4 Section 7 ~ Handling and Storage
Precautions For Safe Handling – Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Conditions for safe storage, including any incompatibilities – Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B) Section 8 ~ Exposure Controls/Personal Protection
Occupational Exposure Limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Components Type Value Propane (CAS 74-98-6) PEL 1800 mg/m3 Butane (CAS 106-97-8) TWA 1900 mg/m3 1000 ppm 800 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 US. ACGIH Threshold Limit Values 1000 ppm Components Type Value Butane (CAS 106-97-8) STEL 1000 ppm
Biological limit values No biological exposure limits noted for the ingredient(s)
Appropriate Engineering Controls – Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Respiratory Protection– If permissible levels are exceeded use NIOSH mechanical filter/organic vapor cartridge or an air-supplied respirator. Skin Protection Other– Wear suitable protective clothing. Hand Protection – Wear appropriate chemical resistant gloves. Eye/face protection – Wear safety glasses with side shields (or goggles). Thermal hazards – Wear appropriate thermal protective clothing, when necessary. General hygiene considerations – When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routine wash work clothing and protective equipment to remove contaminants. Section 9 ~ Physical Chemical Properties
Initial Boiling Point 212 °F (100 °C) estimated Specific Gravity 0.888 estimated Vapor Pressure 45 – 55 psig @ 20°C estimated Melting/Freezing Point N/A Vapor Density N/A Evaporation Rate (Butyl Acetate = 1) N/A Solubility in Water N/A pH N/A
Appearance and Odor— Liquid, aerosol. VOC% - Flash Point (Method Used): Auto - Ignition Temperature: Lower Flammability Level: Upper Flammability Level: -156.0 °F (-104.4 °C) PROPELLANT estimated N/A N/A N/A Section 10 ~ Stability and Reactivity
Stability: Unstable Stable Conditions to Avoid – Avoid temperatures exceeding the flash Hazardous May Occur Will Not Occur point. Contact with incompatible materials. Polymerization: Incompatibility (Materials to Avoid) – Strong oxidizing agents, nitrates, fluorine, chlorine. Hazardous Decomposition or Byproducts – No hazardous decomposition products are known. Reactivity – The product is stable and non-reactive under normal conditions of use, storage and transport. Section 11 ~ Toxicological Information
Information on likely routes of exposure Ingestion – Expected to be a low ingestion hazard. Inhalation – Prolonged inhalation may be harmful. Skin contact – No adverse effects due to skin contact are expected. Eye contact – Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics: Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute Toxicity:
Product Species Test Results Butane (CAS 106-97-8) Inhalation – LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l
Page 67 of 276 A1121 Tire Shine Page 3 of 4 Acute toxicity Continued: Propane (CAS 74-98-6) Acute Inhalation – LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h
Skin corrosion/irritation: Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation: Direct contact with eyes may cause temporary irritation. Respiratory sensitization: Not available Skin sensitization: This product is not expected to cause skin sensitization. Germ cell mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. Reproductive toxicity; This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure: Not classified Specific target organ toxicity - repeated exposure: Not classified. Aspiration hazard – Not available. Chronic effects – Prolonged inhalation may be harmful. Section 12 ~ Ecological Information
Ecotoxicity Product Species Test Results 11 oz Tire Shine (CAS Mixture) Aquatic Crustacea EC50 Daphnia 1595.2933 mg/l, 48 hours estimated Fish LC50 Fish 145.3649 mg/l, 96 hours estimated * Estimates for product may be based on additional component data not shown.
Persistence and degradability: No data is available on the degradability of this product. Bioaccumulative potential: No data available. Partition coefficient n-octanol / water (log Kow) Butane 2.89 Propane 2.36
Mobility in soil: No data available. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Section 13 ~ Disposal Considerations
Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
US RCRA (Resource Conservation and Recovery Act ) Hazardous Waste U List: Reference: Waste from residues / Unused products: Dispose of accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. Section 14 ~ Transport Information
US Depart. of Transportation (DOT) Water Transportation (IMDG) Air Transportation (IATA) Proper Shipping Name: Aerosols, flammable Proper Shipping Name: Aerosols Proper Shipping Name: Aerosols, flammable
Hazard Class: 2.1 Hazard Class: 2.1 Hazard Class: 2.1 UN Number: UN1950 UN Number: UN1950 UN Number: UN1950 Packing Group: Not applicable Packing Group: Not applicable Packing Group: Not applicable Labels(s): 2.1 Label(s): None Label(s): 2.1 Environmental Hazard Special Provisions: N82 Marine Pollutant: No Environmental Hazards: No
Packaging Exceptions: 306 Packaging Exceptions: Ltd. Qty. Packaging Exceptions: Ltd. Qty. Special precautions for user: Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. DOT IATA;IMDG
General Information: IMDG Regulated Marine Pollutant
Page 68 of 276 A1121 Tire Shine Page 4 of 4 Section 15 ~ Regulatory Information
US Federal Regulations: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous CERCLA Hazardous Not listed. Listed. Listed. SARA 304 Emergency Release Notification: Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA): Hazard categories: Immediate Hazard – No; Delayed Hazard – No; Fire Hazard – Yes; Pressure Hazard – Yes; Reactivity Hazard – No. SARA 302 Extremely Hazardous Substance: No listed. SARA 311/312 Hazardous Chemical: No. SARA 313 (TRI reporting); Not regulated. Other Federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention Butane (CAS 106-97-8) Propane (CAS 74-98-6) (40 CFR 68.130): Safe Drinking Water Act (SDWA): Not regulated.
US State Regulations
US. New Jersey Worker and Community US. Pennsylvania Worker and Community US. Massachusetts RTK - Substance List Right-to-Know Act Right-to-Know Law US. Rhode Island RTK Butane (CAS 106-97-8) Butane (CAS 106-97-8) Butane (CAS 106-97-8) Butane (CAS 106-97-8)
Propane (CAS 74-98-60 Propane (CAS 74-98-60 Propane (CAS 74-98-60 Propane (CAS 74-98-60
US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).
Section 16 ~ Other Information NFPA HMIS Key HEALTH 1 1 4= Severe FLAMMABILITY 2 2 3= Serious REACTIVITY 1 1 2= Moderate OTHER/PROTECTION - X 1= Slight 0= Minimal Disclaimer: Omega Industrial Supply, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Page 69 of 276 Material Safety Data Sheet AIRIEL SPICE AIR REFILLS Section 1. Chemical product and company identification Trade name : AIRIEL SPICE AIR REFILLS Product use : Air Freshener Supplier : Ecolab Co. 5105 Tomken Road Mississauga ON L4W 2X5 1-800-352-5326 Code : 915074-01 Date of issue 22-April-2009 EMERGENCY HEALTH INFORMATION: 1-800-328-0026 Outside United States and Canada CALL 1-651-222-5352 (in USA) Section 2. Hazards identification Physical state : Liquid. [absorbed liquid (wipes, pads, ...)] Emergency : CAUTION! overview MAY CAUSE EYE IRRITATION. Avoid contact with eyes. Wash thoroughly after handling. Routes of entry : Skin contact, Eye contact, Inhalation, Ingestion Potential acute health effects Eyes : Slightly irritating to the eyes. Skin : Slightly irritating to the skin. Inhalation : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. See toxicological information (section 11) Section 3. Composition/information on ingredients Name CAS number % by weight Perfume ingredient. Mixture 60 - 100 Section 4. First-aid measures Eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses and flush again. Get medical attention if irritation persists. Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation : If irritation persists, get medical attention. Ingestion : Do not induce vomiting. Never give anything by mouth to an unconscious person. If irritation persists, get medical attention. Section 5. Fire-fighting measures Auto-ignition temperature : Not available. Flash point : If the product is in its liquid form: 62.7778 °C (Closed cup) Flammable limits : Not available. Hazardous thermal : No specific data. decomposition products
Fire-fighting media and : Use dry chemical, CO2, water spray (fog) or foam. instructions
Page 70 of 276 AIRIEL SPICE AIR REFILLS Page: 2/4 Use water spray to keep fire-exposed containers cool. Dyke area of fire to prevent runoff. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-contained fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Risk of explosion of the product in the presence of mechanical impact: Not available. Risk of explosion of the product in the presence of static discharge: Not available. Section 6. Accidental release measures Personal : Use suitable protective equipment (section 8). Do not allow to enter drains or watercourses. precautions Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. precautions Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for : If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent cleaning up (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof means to transfer material to a sealable, appropriate container for disposal. For large spills, dyke spilt material or otherwise contain it to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposal. Section 7. Handling and storage Handling : Wash thoroughly after handling. Storage : Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, well- ventilated area. Do not store above the following temperature: 10°C Section 8. Exposure controls/personal protection Engineering measures : No special ventilation requirements. Personal protection : Eyes : No protective equipment is needed under normal use conditions. Hands : No protective equipment is needed under normal use conditions. Skin : No protective equipment is needed under normal use conditions. Respiratory : No protective equipment is needed under normal use conditions.
Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Physical state : Liquid. [absorbed liquid (wipes, pads, ...)] Colour : Clear. Odour : Fragrance-like. pH : 7 [Conc. (% w/w): 100%] Boiling/condensation point : Not available. Melting/freezing point : Not available. Relative density : 0.9 Vapour pressure : Not available. Vapour density : Not available. Odour threshold : Not available.
Evaporation rate : Not available.
LogKow : Not available.
Page 71 of 276 AIRIEL SPICE AIR REFILLS Page: 3/4
Section 10. Stability and reactivity Stability : The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not occur. Conditions of instability : Not available. Reactivity : Not available. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Hazardous polymerisation : Under normal conditions of storage and use, hazardous polymerisation will not occur. Section 11. Toxicological information Potential acute health effects Eyes : Slightly irritating to the eyes. Skin : Slightly irritating to the skin. Inhalation : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Potential chronic health effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significant effects or critical hazards. Teratogenic effects : No known significant effects or critical hazards. Reproductive effects : No known significant effects or critical hazards. Sensitization to Product : No known significant effects or critical hazards. Synergistic products : Not available. (toxicologically) Toxicity data Not applicable.
Target organs : Not available. Section 12. Ecological information Ecotoxicity Ingredient name Species Period Not available. Section 13. Disposal considerations Waste disposal : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Consult your local or regional authorities. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes.
UN Classification Not regulated. See shipping documents for specific transportation information.
Page 72 of 276 AIRIEL SPICE AIR REFILLS Page: 4/4
Section 15. Regulatory information WHMIS : Not controlled under WHMIS (Canada). Manufactured Article. Canada inventory : All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Section 16. Other information
Hazardous Material : Health 1 Information System (U.S.A.) Flammability 0 Physical hazards 0
Date of issue : 22-April-2009. Responsible name : Regulatory Affairs 1-800-352-5326 Date of previous issue : 10-May-2006. Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.
Page 73 of 276 Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada SAFETY DATA SHEET
R AMSOIL Metal Protector
Date : 03/30/2016 Section 1. Identification Version : 7
GHS product identifier : AMSOIL Metal Protector Code : AMPSC/CMPSC Product type : Aerosol.
Identified uses : Lubricant and Protectant.
Manufacturer : AMSOIL INC. One AMSOIL Center Superior, WI 54880 Tel: +1 715-392-7101 Initial Supplier : AMSOIL INC. (Canada) Bordner, Ladner, Gervais Scotia Plaza, 40 King St W Toronto, ON, Canada M5H 3Y4 Tel: +1 416-367-6547
Emergency telephone : CHEMTREC: Within USA and Canada: 1-800-424-9300; number (with hours of Outside USA and Canada: +1 703-741-5970 (collect calls accepted) operation) (24/7)
Section 2. Hazards identification
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE AEROSOLS - Category 1 substance or mixture GASES UNDER PRESSURE - Compressed gas AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 2
GHS label elements Hazard pictograms :
Signal word : Danger Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Toxic to aquatic life with long lasting effects. Precautionary statements
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Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Avoid release to the environment. Pressurized container: Do not pierce or burn, even after use. Response : Collect spillage. Storage : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) Physical hazards not : None known. otherwise classified (PHNOC) Health hazards not : None known. otherwise classified (HHNOC)
Section 3. Composition/information on ingredients
Substance/mixture : Mixture Other means of : Not available. identification
CAS number/other identifiers CAS number : Not applicable. Product code : AMPSC/CMPSC Ingredient name % CAS number Distillates, hydrotreated light ≥50 - ≤75 64742-47-8 Distillates, hydrotreated heavy naphthenic ≥1 - ≤3 64742-52-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
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Page 75 of 276 AMSOIL Metal Protector AMPSC/CMPSC
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: irritation redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
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Page 76 of 276 AMSOIL Metal Protector AMPSC/CMPSC
Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and materials for containment and cleaning up Spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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Section 7. Handling and storage
Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool including any and well-ventilated area, away from incompatible materials (see Section 10) and food incompatibilities and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection
Control parameters Occupational exposure limits United States Ingredient name Exposure limits Distillates, hydrotreated light ACGIH TLV (United States, 3/2015). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Distillates, hydrotreated heavy naphthenic ACGIH TLV (United States, 3/2015). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Canada Occupational exposure limits None.
Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor controls or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
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Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Section 9. Physical and chemical properties
Appearance Physical state : Liquid. [Aerosol.] Color : Clear. Odor : Solvent. Odor threshold : Not available. pH : Not available. Melting point : Not available. Boiling point : Not available. Flash point : Not available. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : Not available. Relative density : Not available.
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Solubility : Insoluble. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. Volatility : Not available. Aerosol product Type of aerosol : Spray
Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame).
Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced.
Section 11. Toxicological information
Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Distillates, hydrotreated heavy LD50 Oral Rat >5000 mg/kg - naphthenic Irritation/Corrosion There is no data available. Sensitization There is no data available. Carcinogenicity Classification Product/ingredient name OSHA IARC NTP ACGIH EPA NIOSH Distillates, hydrotreated light - - - A3 - -
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Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard Name Result Distillates, hydrotreated light ASPIRATION HAZARD - Category 1 Distillates, hydrotreated heavy naphthenic ASPIRATION HAZARD - Category 1
Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion. routes of exposure Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: irritation redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
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Numerical measures of toxicity Acute toxicity estimates There is no data available.
Section 12. Ecological information
Toxicity Product/ingredient name Result Species Exposure Distillates, hydrotreated light Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days
Persistence and degradability There is no data available.
Bioaccumulative potential There is no data available. Mobility in soil Soil/water partition : There is no data available. coefficient (KOC)
Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
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Section 14. Transport information
DOT TDG IMDG IATA UN number UN1950 UN1950 UN1950 UN1950
UN proper Aerosols, flammable (each not Aerosols, flammable (each Aerosols, flammable (each not Aerosols, flammable (each not shipping name exceeding 1 L capacity) not exceeding 1 L capacity) exceeding 1 L capacity). exceeding 1 L capacity) Marine pollutant Transport 2.1 2.1 2.1 2.1 hazard class(es)
Packing group - - - - Environmental No. Yes. Yes. No. hazards Additional Remarks Product classified as per the The marine pollutant mark is The environmentally information Limited quantity following sections of the not required when transported hazardous substance mark Transportation of Dangerous in sizes of ≤5 L or ≤5 kg. may appear if required by Goods Regulations: 2.13-2. other transportation 17 (Class 2), 2.7 (Marine Emergency schedules (EmS) regulations. pollutant mark). F-D, S-U Remarks The marine pollutant mark is Remarks Limited quantity not required when Limited quantity transported by road or rail. Remarks Limited quantity AERG : 126
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according : Not available. to Annex II of MARPOL and the IBC Code
Section 15. Regulatory information
U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals)
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DEA List I Chemicals : Not listed (Precursor Chemicals) SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Sudden release of pressure Composition/information on ingredients Name % Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard Distillates, hydrotreated light ≥50 - ≤75 Yes. No. No. No. No.
SARA 313
No products were found. State regulations Massachusetts : The following components are listed: Carbon dioxide, gas New York : None of the components are listed. New Jersey : The following components are listed: Carbon dioxide, gas Pennsylvania : The following components are listed: Distillates, hydrotreated light; Carbon dioxide, gas; Distillates, hydrotreated heavy naphthenic California Prop. 65 No products were found.
Canada Canadian lists Canadian NPRI : The following components are listed: Distillates, hydrotreated light CEPA Toxic substances : The following components are listed: Carbon dioxide, gas
Section 16. Other information
History Date of issue mm/dd/yyyy : 03/30/2016 Date of previous issue : 02/15/2016 Version : 7 Prepared by : AMSOIL INC. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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SAFETY DATA SHEET
This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements and the International Chemical Safety Cards of the Global Harmonizing System. THIS SDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD) IMPORTANT: Read this SDS before handling & disposing of this product. Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
PRODUCT IDENTITY: AVENGE PRO PRODUCT PURPOSE: SPOTTER COMPANY IDENTITY: Bridgepoint Systems COMPANY ADDRESS: 4282 S 590 W COMPANY CITY: Salt Lake City, UT 84123 COMPANY PHONE: 1-800-658-5314 EMERGENCY PHONES: INFOTRAC: 1-800-535-5053 (USA)
SECTION 2. HAZARDS IDENTIFICATION
WARNING!
EXPOSURE PREVENTION: STRICT HYGIENE!
HAZARD STATEMENTS: H100s = General, H200s = Physical, H300s = Health, H400s = Environmental H315 Causes skin irritation. H320 Causes eye irritation. H335 May cause respiratory irritation.
PRECAUTIONARY STATEMENTS: P100s = General, P200s = Prevention, P300s = Response, P400s = Storage, P500s = Disposal P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present & easy to do - Continue rinsing.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
MATERIAL CAS# EINECS# WT %
Sodium Carbonate 497-19-8 - Trade Secret 1-Methoxy-2-propanol 107-98-2 203-539-1 Trade Secret
TRACE COMPONENTS: Trace ingredients (if any) are present in < 1% concentration, (< 0.1% for potential carcinogens, reproductive toxins, respiratory tract mutagens, and sensitizers). None of the trace ingredients contribute significant additional hazards at the concentrations that may be present in this product. All pertinent hazard information has been provided in this document, per the requirements of the Federal Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalents, and Canadian Hazardous Materials Identification System Standard (CPR 4).
SEE SECTIONS 8, 11 & 12 FOR TOXICOLOGICAL INFORMATION. SECTION 4. FIRST AID MEASURES
EYE CONTACT: For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT: In case of contact with skin immediately remove contaminated clothing. Wash thoroughly with soap & water. Wash contaminated clothing before reuse.
INHALATION: After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, trained personnel should immediately begin artificial respiration. If the heart has stopped, trained personnel should immediately begin cardiopulmonary resuscitation (CPR).
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COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013
SECTION 4. FIRST AID MEASURES (CONTINUED)
SWALLOWING: Rinse mouth. Do NOT induce vomiting. GET MEDICAL ATTENTION IMMEDIATELY. Do NOT give liquids to an unconscious or convulsing person.
SECTION 5. FIRE FIGHTING MEASURES
FIRE & EXPLOSION PREVENTIVE MEASURES Above flash point, use a closed system, ventilation, explosion-proof electrical equipment, lighting.
EXTINGUISHING MEDIA Use dry powder, alcohol-resistant foam, water spray, carbon dioxide. . use appropriate extinguishing media.
SPECIAL FIRE FIGHTING PROCEDURES Water spray may be ineffective on fire but can protect fire-fighters & cool closed containers. Use fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (Helmet with face shield, bunker coats, gloves & rubber boots). Use NIOSH approved positive-pressure self-contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES Isolate from oxidizers, heat, & open flame. Closed containers may burst if exposed to extreme heat. Applying to hot surfaces requires special precautions.
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE MEASURES: Keep unprotected personnel away. Remove all ignition sources. Wear appropriate personal protective equipment given in Section 8.
ENVIRONMENTAL PRECAUTIONS: Keep from entering storm sewers and ditches which lead to waterways.
CONTAINMENT AND CLEAN-UP MEASURES: Stop spill at source. Dike and contain. Wash away remainder with plenty of water.
SECTION 7. HANDLING AND STORAGE
HANDLING Use only with adequate ventilation. Avoid breathing of vapor or spray mist. Avoid prolonged or repeated contact with skin. Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear goggles, face shield, gloves, apron & footwear impervious to material. Wash clothing before reuse. Check for peroxides prior to distillation, eliminate if found.
STORAGE Keep in fireproof surroundings. Keep separated from strong oxidants. Keep cool. Keep dry. Keep in the dark. Use ventilation along the floor. Do not store above 49 C/120 F. Keep container tightly closed & upright when not in use to prevent leakage.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
MATERIAL CAS# EINECS# TWA (OSHA) TLV (ACGIH) Sodium Carbonate 497-19-8 - None Known None Known 1-Methoxy-2-propanol 107-98-2 203-539-1 None Known 100 ppm MATERIAL CAS# EINECS# CEILING STEL(OSHA/ACGIH) HAP 1-Methoxy-2-propanol 107-98-2 203-539-1 None Known 150 ppm No
This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%.
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COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED)
RESPIRATORY EXPOSURE CONTROLS A respiratory protection program that meets OSHA 29 CFR 1910.134 and ANSI Z86.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
VENTILATION LOCAL EXHAUST: Necessary MECHANICAL (GENERAL): Acceptable SPECIAL: None OTHER: None Please refer to ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.
PERSONAL PROTECTIONS: Wear OSHA Standard goggles & gloves as a standard practice.
SECTION 9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE: Clear Liquid ODOR: Lemon ODOR THRESHOLD: Not Available pH (Neutrality): 9.5 MELTING POINT/FREEZING POINT: Not Available BOILING RANGE (IBP,50%,Dry Point): > 100 C / >212 F FLASH POINT (TEST METHOD): > 93 C / > 200 F (PMCC) EVAPORATION RATE (n-BUTYL ACETATE=1): Not Applicable FLAMMABILITY CLASSIFICATION: Class III-B LOWER FLAMMABLE LIMIT IN AIR (% by vol): Not Available UPPER FLAMMABLE LIMIT IN AIR (% by vol): Not Available VAPOR PRESSURE (mm of Hg)@20 C 17.1 VAPOR DENSITY (air=1): 0.732 GRAVITY @ 68/68 F / 20/20 C: DENSITY: 1.054 SPECIFIC GRAVITY (Water=1): 1.055 POUNDS/GALLON: 8.788 WATER SOLUBILITY: Complete PARTITION COEFFICIENT (n-Octane/Water): Not Available AUTO IGNITION TEMPERATURE: Not Available DECOMPOSITION TEMPERATURE: Not Available VOCs (>0.044 Lbs/Sq In) : Not Available TOTAL VOC'S (TVOC)*: 0.2 Lbs/Gal NONEXEMPT VOC'S (CVOC)*: 0.2 Lbs/Gal HAZARDOUS AIR POLLUTANTS (HAPS): 0.0 Wt% NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C) Not Available VISCOSITY @ 20 C (ASTM D445): Not Available * Using CARB (California Air Resources Board Rules).
SECTION 10. STABILITY & REACTIVITY
STABILITY Stable under normal conditions.
CONDITIONS TO AVOID Isolate from oxidizers, heat, & open flame.
MATERIALS TO AVOID The substance can presumably form explosive peroxides, under the influence of light & air. Check for peroxide prior to distillation, eliminate if found. Reacts with strong oxidants, acid chlorides, acid anhydrides, causing fire & explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS Carbon Monoxide, Carbon Dioxide from heating.
HAZARDOUS POLYMERIZATION Will not occur.
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COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE HAZARDS
EYE & SKIN CONTACT: Primary irritation to skin, defatting, dermatitis. Absorption thru skin increases exposure. Primary irritation to eyes, redness, tearing, blurred vision. Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION: Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system depression. Vapor harmful. Breathing vapor can cause irritation. Acute overexposure can cause harm to kidneys, blood, nerves, liver, lungs.
SWALLOWING: Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
SUBCHRONIC HAZARDS/CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED Chronic overexposure can cause harm to kidneys, blood, nerves, liver, lungs. Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS: This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA or ACGIH, as of this date, greater or equal to 0.1%. Product may contain impurities which may alter toxic properties.
IRRITANCY OF PRODUCT: This product is irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a sensitizer.
MUTAGENICITY: This product is not reported to produce mutagenic effects in humans.
EMBRYOTOXICITY: This product is not reported to produce embryotoxic effects in humans.
TERATOGENICITY: This product is not reported to produce teratogenic effects in humans.
REPRODUCTIVE TOXICITY: This product is not reported to cause reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (such as: within the eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process.
MAMMALIAN TOXICITY INFORMATION
No mammalian information is available on this product.
SECTION 12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
EFFECT OF MATERIAL ON PLANTS AND ANIMALS: This product may be harmful or fatal to plant and animal life if released into the environment. Refer to Section 11 (Toxicological Information) for further data on the effects of this product's components on test animals.
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COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013
SECTION 12. ECOLOGICAL INFORMATION (CONTINUED)
EFFECT OF MATERIAL ON AQUATIC LIFE: No aquatic environmental information is available on this product.
MOBILITY IN SOIL Mobility of this material has not been determined.
DEGRADABILITY This product is completely biodegradable.
ACCUMULATION Bioaccumulation of this product has not been determined.
GREEN INGREDIENTS >99.5% of ingredients are approved or on an approved list of at least one third party green certification organization. This >99.5% threshold earns our manufacturer Green Balance designation.
SECTION 13. DISPOSAL CONSIDERATIONS
Processing, use or contamination may change the waste disposal requirements. Do not dispose of on land, in surface waters, or in storm drains. Waste should be recycled or disposed of in accordance with regulations. Large amounts should be collected for reuse or consigned to licensed hazardous waste haulers for disposal. ALL DISPOSAL MUST BE IN ACCORDANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL REGULATIONS. IF IN DOUBT, CONTACT PROPER AGENCIES.
SECTION 14. TRANSPORT INFORMATION
DOT/TDG SHIP NAME: Not Regulated DRUM LABEL: None IATA / ICAO: Not Regulated IMO / IMDG: Not Regulated EMERGENCY RESPONSE GUIDEBOOK NUMBER: None
SECTION 15. REGULATORY INFORMATION
EPA REGULATION: SARA SECTION 311/312 HAZARDS: Acute Health All components of this product are on the TSCA list. This material contains no known products restricted under SARA Title III, Section 313 in amounts greater or equal to 1%.
STATE REGULATIONS: THIS PRODUCT MEETS REQUIREMENTS OF SOUTHERN CALIFORNIA AQMD RULE 443.1 & SIMILAR REGULATIONS
CALIFORNIA SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product contains no chemicals known to the State of California to cause cancer or reproductive toxicity.
INTERNATIONAL REGULATIONS The components of this product are listed on the chemical inventories of the following countries: Australia (AICS), Canada (DSL or NDSL), China (IECSC), Europe (EINECS, ELINCS)G Japan (METI/CSCL, MHLW/ISHL), South Korea (KECI), New Zealand (NZIoC), Philippines (PICCS), Switzerland (SWISS), Taiwan (NECSI), USA (TSCA).
CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) B2: Flammable Liquid. D2B: Irritating to skin / eyes.
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR.
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COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013
SECTION 16. OTHER INFORMATION
HAZARD RATINGS: HEALTH (NFPA): 1, HEALTH (HMIS): 1, FLAMMABILITY: 1, PHYSICAL HAZARD: 0 (Personal Protection Rating to be supplied by user based on use conditions.) This information is intended solely for the use of individuals trained in the NFPA & HMIS hazard rating systems.
EMPLOYEE TRAINING See Section 2 for Risk & Safety Statements. Employees should be made aware of all hazards of this material (as stated in this SDS) before handling it.
SDS DATE: 06/15/2013
NOTICE Bridgepoint Systems disclaims all expressed or implied warranties of merchantability or fitness for a specific use, with respect to the product or the information provided herein, except for conformation to contracted specifications. All information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their handling, and disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance upon information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or process.
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Safety Data Sheet
SDS ID: Stock Code LD Revision date: July 10, 2015 Section 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Big Bubble Leak Detector Synonyms: None Chemical family: Surfactant mixture Producer: J.C. Whitlam Manufacturing Company 200 West Walnut Street P.O. Box 380 Wadsworth, Ohio 44282-0380 www.jcwhitlam.com
Telephone: 330-334-2524 Available during normal business hours
Emergency: 330-334-2524 Available during normal business hours
Section 2. HAZARDS IDENTIFICATION
GHS Classification in accordance with 29 CFR 1910.1200
Skin Corrosion/Irritation, Category 3
Eye Damage/Irritation, Category 2B
GHS Label elements, including precautionary statements: Warning
Hazard statements H316 Causes mild skin irritation H320 Causes eye irritation
Precautionary Statements P264 Wash skin thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Get medical attention/advice. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+313 If eye irritation persists: Get medical advice/ attention.
Hazards not otherwise classified or not covered by GHS
Ingestion: May cause abdominal discomfort, nausea, and diarrhea.
Carcinogenic: No ingredients listed by the IARC, NTP, OSHA, or the ACHIH.
Section 3. COMPOSITION / INFORMATION ON INGREDIENTS
Material information: Name CAS No.Weight % Alpha-(Nonylphenyl)-(Omega- 9016-45-9 1 hydroxypoly (oxy-1,2-ethanediyl) Non-hazardous ingredients Not Applicable 99 *Note: The above weight percentages are represented in ranges as estimates. Due to variation among production batches, component percentages may vary.
J.C. Whitlam Big Bubble Gas Leak Detector Page 1 of 6
Page 91 of 276 Section 4. FIRST AID MEASURES
General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Inhalation: Move exposed persons to fresh air. If the person is not breathing or breathing is irregular, provide artificial respiration or oxygen by trained personnel. Consult a physician.
Skin contact: Wash affected skin with soap and water. Get medical attention if symptoms occur. Wash contaminated clothing before reuse.
Ingestion: Do not induce vomiting, unless instructed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If conscious and alert, rinse the mouth with water. Consult a physician.
Eye contact: Check for and remove any contact lenses, if easy to do so. If eye irritation persists, consult physician after flushing eyes with tepid water for 15 minutes.
Section 5. FIREFIGHTING MEASURES
Suitable Use extinguishing measures that are suitable to local circumstances extinguishing and the surrounding fire and environment. media: Specific hazards: Combustion products may include carbon oxides.
Advice for Full protective equipment including self-contained breathing Firefighters: apparatus should be used. Do not allow run-off from fire-fighting to enter drains or water courses.
FIRE
R NFPA rating: HMIS rating: E SlightlHazardousy Hazardous Health: 1 1 H 30 A E C FPW -ill Below not burn 73 F Flammability: 0 0 A T L I Instability/reactivity: 0 0 T 21 0 V Stable H I Other: N/A A (PPE) T N/A Y SPECIAL
Section 6. ACCIDENTAL RELEASE MEASURES
Personal Immediately contact emergency personnel. Evacuate any potentially affected Precautions: area and isolate personnel from entry. Personnel must have appropriate training, per Occupational Safety and Large Spill: Health Administration (OSHA) 29 CFR 1910.120. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment (Section 8). Methods for Shut off source if possible and if safe. Prevent entry into waterways and Containment sewers. Advise applicable authorities if material has entered sewers or water and Clean up courses.
J.C. Whitlam Big Bubble Gas Leak Detector Page 2 of 6
Page 92 of 276 Section 7. HANDLING AND STORAGE
Handling: Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash thoroughly with soap and water after handling. Storage: Keep all containers tightly closed when not in use. Do not store with incompatible materials. See Section 10, Stability and Reactivity.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational Exposure Limits: Name CAS No. ACGIH® TLV® Federal OSHA PELs 1989 C Exposure Limits: OSHA PELs Alpha-(Nonylphenyl)- (Omega-hydroxypoly (oxy- 9016-45-9 None None None 1,2-ethanediyl)
All exposure limits listed are 8-hour time weighted average (TWA) — except where noted otherwise.
A Time Weighted Average (TWA) is an average exposure over the course of an 8-hour work shift. B A Short Term Exposure Limit TWA over the course of 15 minutes. PEL — Permissible Exposure Limit is the maximum 8-hour TWA concentration of a chemical that a worker may be exposed to under Occupational Safety and Health Administration (OSHA) regulations. C Federal OSHA 1989 PELs were vacated but are in use and enforced by many state OSHA plans.
Engineering measures: Handle is accordance with good industrial hygiene and safety practices. Wash hands before breaks and at the end of the workday.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory protection: For nuisance exposures, use type N95 (US) or type 1 (Europe Union EN 143) particle/mist respirator. For higher level protection, use type OV/AG/P99 (US) respirator cartridges. Use respirators and components approved by NIOSH.
Skin and body protection: Wear impervious clothing and gloves to prevent contact. Use the manufacturer’s degradation and permeation data for protective material selection.
Eye protection: Wear safety spectacles with unperforated sideshields.
Hygiene measures: Avoid repeated or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove contaminated clothing and launder before reuse.
Other precautions: Do not let the product enter drains.
J.C. Whitlam Big Bubble Gas Leak Detector Page 3 of 6
Page 93 of 276 Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Fluorescent yellow liquid Physical state (solid/liquid/gas): Liquid Substance type (pure/mixture): Mixture Color: Yellow Odor: None Molecular weight: Not available pH: Not Applicable Boiling point/range (5-95%): 212°F, 100°C Melting point/range: 32°F, 0°C Decomposition temperature: Not Available Specific gravity: 1.01 Vapor density: (AIR = 1) Not available Vapor pressure: Not available Evaporation rate (Butyl acetate= 1): Not available Flash point, method used: Not flammable Water solubility: 100% VOC Content: Not available Auto-ignition temperature: Not applicable Flammable limits in air — lower (%): Not applicable Flammable limits in air — upper (%): Not applicable
Section 10. STABILITY AND REACTIVITY
Reactivity: No data available Stability: Stable under recommended storage conditions Possibly hazardous reactions: No data available Conditions to avoid: No data available Incompatible Materials: Strong oxidizing agents. Hazardous decomposition products: By fire, see Section 5. Other decomposition products: No data available Polymerization: Will not occur.
Section 11. TOXICOLOGICAL INFORMATION
Acute toxicity: Skin and eye irritation.
Product information: Name CAS No.Inhalation: Dermal: Oral: Alpha-(Nonylphenyl)- (Omega-hydroxypoly 9016-45-9 No data available No data available No data available (oxy-1,2-ethanediyl)
LC50 — The concentration of the chemical in air that kills 50% of the test animals in a given time (usually four hours).
Chronic toxicity: No component of this product, present at levels greater than or equal to 1% is identified as a probable, possible, or confirmed human carcinogen by the IARC, NTP, OSHA, and ACGIH.
Sensitization: Not known to cause sensitization in humans.
J.C. Whitlam Big Bubble Gas Leak Detector Page 4 of 6
Page 94 of 276 Section 12. ECOLOGICAL INFORMATION
Ecotoxicity effects: No data available.
Persistence No data available.
Degradability: No data available.
Section 13. DISPOSAL CONSIDERATIONS
Cleanup This product is not a hazardous waste as defined under RCRA 40 CFR Considerations: 261. The material destined for disposal must be characterized properly and may differ from the product described in this SDS if mixed with other wastes.
Section 14. TRANSPORT INFORMATION
Please refer to DOT regulation 49 CFR 172.101: Transport information: This material is not regulated under DOT when transported via U.S. commerce routes: and IATA, and IMO via international routes Hazardous Materials Description: (DOT and IATA):
UN/identification no.: Not Applicable Proper shipping name: Not Applicable Hazard class: Not Applicable Packing group: Not Applicable DOT reportable quantity (lbs.): Not Applicable
Section 15. REGULATORY INFORMATION
U.S. federal regulatory information:
U.S. RCRA (40 CFR 261) This product is not a hazardous waste as defined under RCRA 40 CFR 261.
State and community right-to-know regulations: The following component(s) of this material are identified on the regulatory lists below:
U.S. TSCA Chemical inventory Section 8(b) OSHA — This product is determined to be hazardous as defined in the OSHA Hazard Communications Standard (29 CFR 1910.1200)
CERCLA Sections 102a/103 (40 FR 302.4): No ingredients are listed. Some Components of this product are listed in the following sections of SARA: SARA Title III Section 302 — N/A SARA Title III Section 304 — N/A SARA Title III Section 313 — This product does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels.
SARA Title III Sections 311/312 Hazardous Categories (40 CFR 370.21) Acute health hazard: Yes Chronic health hazard: No Fire hazard: No Reactive Hazard: No Pressure Hazard: No
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Page 95 of 276
California Proposition 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm.
NOTE: User must consult with applicable state and local agencies for special specifics, determinations or compliance obligations regarding this product.
Section 16. OTHER INFORMATION
The information and recommendations contained herein are based upon tests, data, and information resources believed to be reliable. However, the J.C. Whitlam Manufacturing Company, Inc., and its related operations or divisions (Whitlam) do not guarantee the accuracy or completeness, nor shall any of this information constitute a warranty, whether expressed or implied, as to the safety of goods, the merchantability of the goods or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage may be required. Whitlam assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of this data. No warranty against infringement of any patent, copyright or trademark is made or implied.
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Page 96 of 276 SAFETY DATA SHEET
BLM TIRE WET 5GL Version 1.2 Revision Date 02/08/2017 Print Date 05/11/2017
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name : BLM TIRE WET 5GL
Material number : 000000000030003745 Manufacturer or supplier's details Company : Zep Inc.
Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318
Telephone : 404-352-1680
Emergency telephone numbers
For SDS Information : Compliance Services 1-877-428-9937 For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded For a Transportation : CHEMTREC: 800-424-9300 - All Calls Recorded. Emergency In the District of Columbia 202-483-7616 Recommended use of the chemical and restrictions on use Recommended use : Transportation Wash
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview Appearance liquid Colour blue Odour odourless
GHS Classification Eye irritation : Category 2B GHS label elements Signal word : Warning
Hazard statements : H320 Causes eye irritation.
Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
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Substance / Mixture : Mixture
Hazardous components
Chemical name CAS-No. Concentration [%] Propane-1,2-diol, propoxylated 25322-69-4 >= 20 - < 30 The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
General advice : Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact : In case of contact, immediately flush skin with plenty of water. Take off contaminated clothing and shoes immediately. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
Most important symptoms : Effects are immediate and delayed. and effects, both acute and Symptoms may include irritation, redness, pain, and rash. delayed Effects are dependent on exposure (dose, concentration, contact time). Causes eye irritation. Review section 2 of SDS to see all potential hazards.
Notes to physician : Treat symptomatically. Symptoms may be delayed.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Hazardous combustion : Carbon dioxide (CO2) products Carbon monoxide Smoke Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment.
Further information : Standard procedure for chemical fires.
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Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Use personal protective equipment. protective equipment and Ensure adequate ventilation. emergency procedures Evacuate personnel to safe areas. Material can create slippery conditions.
Environmental precautions : No special environmental precautions required.
Methods and materials for : Wipe up with absorbent material (e.g. cloth, fleece). containment and cleaning up Keep in suitable, closed containers for disposal. Neutralise with acid.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area.
Conditions for safe storage : Electrical installations / working materials must comply with the technological safety standards.
Materials to avoid : Do not freeze.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Components CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Propane-1,2-diol, propoxylated 25322-69-4 TWA 10 mg/m3 US WEEL (aerosol)
Engineering measures : effective ventilation in all processing areas
Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required.
Hand protection Material : Gloves Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection : Safety glasses
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Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Protective measures : Wear suitable protective equipment. When using do not eat, drink or smoke.
Hygiene measures : General industrial hygiene practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : blue Odour : odourless Odour Threshold : No data available pH : 10.3 - 11 Melting point/freezing point : No data available Boiling point : No data available Flash point : Not applicable Evaporation rate : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : 0.99 - 1.02 Density : No data available Solubility(ies) Water solubility : No data available Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : not determined Thermal decomposition : No data available
Viscosity Viscosity, kinematic : No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
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Possibility of hazardous : Stable under recommended storage conditions. reactions No hazards to be specially mentioned.
Conditions to avoid : No data available
Incompatible materials : No data available
Hazardous decomposition : Carbon oxides products
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Aggravated Medical : None known. Condition Symptoms of Overexposure : Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Effects are dependent on exposure (dose, concentration, contact time).
Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Acute toxicity No data available Skin corrosion/irritation No data available Serious eye damage/eye irritation Product: Remarks: Irritating to eyes.
Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available
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Carcinogenicity No data available
Reproductive toxicity No data available Propane-1,2-diol, propoxylated: STOT - single exposure No data available
STOT - repeated exposure No data available Aspiration toxicity No data available
Further information Product: Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available Persistence and degradability No data available Bioaccumulative potential Product: Partition coefficient: n- : Remarks: No data available octanol/water Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological : No data available
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information
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
TSCA list : No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements.
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
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Page 103 of 276 SAFETY DATA SHEET
BLM TIRE WET 5GL Version 1.2 Revision Date 02/08/2017 Print Date 05/11/2017
Components CAS-No. Component RQ Calculated product RQ (lbs) (lbs) 2,2'-iminodiethanol 111-42-2 100 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. 2,2'-iminodiethanol 111-42-2 ethylbenzene 100-41-4 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. methanol 67-56-1
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL
For information on the country notification status for other regions please contact the manufacturer’s regulatory group. Inventory Acronym and Validity Area Legend: TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
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Further information
NFPA: HMIS III: Flammability
HEALTH 1
0 Instability
1 0 FLAMMABILITY 0
Health
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
OSHA - GHS Label Information:
Signal w ord : Warning: Hazard statements : Causes eye irritation. Precautionary statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
Version: 1.2 Revision Date: 02/08/2017 Print Date: 05/11/2017
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®, Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Mis ty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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Page 105 of 276 MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Jelmar LLC Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency Contact: Chemtrec 1(800) 424-9300
Product Name: CLR- Calcium Lime & Rust Remover (Enhanced Formula) MSDS ID: 03C0309 Chemical Family: Aqueous Acidic Cleaner Formula: Proprietary Mixture
SECTION 2 – HAZARDS IDENTIFICATION PHYSICAL STATE: Liquid COLOR: Crystal clear, lime green ODOR: Slightly sour
WARNING OVERVIEW: Irritating to eyes, respiratory tract and mucous membranes. Use with adequate ventilation. Avoid breathing mist or dust. Keep container closed when not in use.
POTENTIAL HEALTH EFFECTS ROUTES OF EXPOSURE: Eyes. Skin. Inhalation. Ingestion. TARGET ORGANS: No data. EYE CONTACT: Irritation and blurred vision. Effects may vary depending on length of exposure, solution concentration, and first aid measures. Prolonged contact may cause permanent damage. SKIN CONTACT: Prolonged contact may cause dermatitis, and itching. INHALATION: Irritation, breathing difficulties, headaches, dizziness. INGESTION: Oral burns, vomiting, and gastrointestinal disturbance. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO PRODUCT: Eye, skin, and respiratory disorders. CANCER INFORMATION: This product does not contain >0.10% of the known potential carcinogens listed in NTP, IRAC, or OSHA.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCT AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.
SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Water 7732-18-5 NO 70-81 2. Lactic Acid 79-33-4 YES 15-20 3. Gluconic Acid 526-95-4 N0 2-4 4. Lauryldimethyl Hydroxysultaine 13197-76-7 N0 1-4 5. Propylene Glycol Normal Butyl Ether 5131-66-8 YES 1-2
SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. Get immediate medical attention if irritation persists.
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INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest.
SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None (100º C): Method: TOC EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Water spray, dry chemical, alcohol foam or carbon dioxide. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self- contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE AND EXPLOSION HAZARDS: None known.
SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters.
SECTION 7- HANDLING AND STORAGE STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or fatal if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (14, 28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. Empty 5gallon containers and 55gallon drums, may contain product residue in form of vapor, dried product, or liquid, and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE THESE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.
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SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. If product is used in an industrial setting, respiratory protection must be worn if ventilation does not eliminate symptoms or keep levels below recommended exposure limits. If mist or dust is present, wear NIOSH-Approved respirator for dusts and mists, NIOSH-Approved self-contained breathing apparatus, NIOSH-Approved full-face piece positive-pressure, air-supplied respirator. DO NOT exceed limits established by respirator manufacturer. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product. EYE PROTECTION: Not required during normal household usage. Industrial users wear safety goggles. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling.
EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Water N.E. N.E. N.E. N.E. 2. Lactic Acid N.E N.E. N.E. N.E. 3. Gluconic Acid N.E. N.E. N.E. N.E. 4. Lauryldimethyl Hydroxysultaine N.E. N.E. N.E. N.E. 5. Propylene Glycol Normal Butyl Ether N.E. N.E. N.E. N.E.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Boiling point: 100º C / 212º F Specific Gravity: 1.05 – 1.06 Vapor Pressure: N.D. Percent Volatiles: ~78.6% (Calculated) Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1) Melting Point: N.D. VOC (Wt%): <1.5 (Calculated) Vapor Density (mm Hg): N.D. VOC (LBS/GAL): <0.13 (Calculated) pH: @20ºC ~2 Solubility in Water: 100%
SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals, acids, and bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases and vapors and carbon oxides. POSSIBILITY OF HAZARDOUS REACTIONS: No data.
SECTION 11 – TOXICOLOGICAL INFORMATION ACUTE ORAL EFFECTS: A dose of 5 ml/kg was given to 5 male and 5 female rats and no mortality occurred in 14 days. The acute oral LD50 was found to be > 5 ml/kg. The product is not toxic by oral ingestion in accordance with FHSA / CPSC Guidelines. SKIN: Not a primary dermal irritant in accordance with FHSA / CPSC Guidelines. EYE: Irritant in accordance with FHSA / CPSC Guidelines.
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SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: No data available. CHEMICAL FATE INFORMATION: 28-day biodegradation <60%. The matter is biodegradable.
SECTION 13 – DISPOSAL CONSIDERATIONS HAZARDOUS WASTE NUMBER: D002 DISPOSAL METHOD: Dispose of in a permitted hazardous waste management facility following all local, state, and federal regulations.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.
SECTION 14 - TRANSPORTATION INFORMATION DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Identification Number: N.A. Packaging Group: N.A. UN Number: N.A. TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.
SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements.
SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO
SARA SECTIONS 302/304/313/HAP: COMPENT RQ (LBS) RQ (LBS) TPQ (LBS) SEC 313 HAP (1*) (2*) (3*) (4*) (5*) Water N.A. N.A. N.A. NO NO Lactic Acid N.A. N.A. N.A. NO NO Gluconic Acid N.A. N.A. N.A. NO NO Lauryldimethyl Hydroxysultaine N.A. N.A. N.A. NO NO Propylene Glycol Normal Butyl Ether N.A. N.A. N.A. NO NO
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Page 109 of 276 MSDS ID: 03C0309 03/09 JELMAR MATERIAL SAFETY DATA SHEET CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA
______REGULATORY AGENCIES______*1: CERCLA Reportable Quantity *4: SARA 313 Toxic Chemical / Category *2: SARA Reportable Quantity *5: U. S. EPA Hazardous Air Pollutant *3: SARA EHS Threshold Planning Quantity
INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) NO* KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL ) NO PHILIPPINES YES
STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. None.
The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.
SECTION 16 – OTHER INFORMATION NFPA Rating System: Health-1 / Flammability-0 / Reactivity-0 / Special Hazard - None Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. A.: Not Applicable N. D.: Not Determined N.E.: Not Established C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound
Revision: Section 11 March 2009 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR LLC offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR LLC be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.
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SAFETY DATA SHEET
Issuing Date January 5, 2015 Revision Date New Revision Number 0
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox® Bleach
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended use Laundry and household bleach
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Address The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3
Emergency telephone number
Emergency Phone Numbers For Medical Emergencies, call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300
2. HAZARDS IDENTIFICATION
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Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Serious eye damage/eye irritation Category 2A
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning
Hazard Statements Causes serious eye irritation
Appearance Clear, pale yellow Physical State Liquid Odor Bleach
Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses.
Precautionary Statements - Response Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage None
Precautionary Statements - Disposal None
Hazards not otherwise classified (HNOC) Not applicable.
Unknown Toxicity 0.06% of the mixture consists of ingredient(s) of unknown toxicity
Other information Very toxic to aquatic life with long lasting effects.
Interactions with Other Chemicals Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 1 - 5 * Sodium hydroxide 1310-73-2 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists.
Skin Contact Take off contaminated clothing. Rinse skin with plenty of water. If irritation develops, call a doctor.
Inhalation Move to fresh air. If breathing is affected, call a doctor.
Ingestion Drink a glassful of water. Call a poison control center or doctor immediately. DO NOT induce vomiting unless told to do so by a poison control center or doctor.
Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Stinging and irritation of eyes. Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical No information available.
Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions See Section 12 for ecological Information.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Products Toilet bowl cleaners, rust removers, acids, and ammonia-containing products.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH 3 Sodium hydroxide 3 3 IDLH: 10 mg/m Ceiling: 2 mg/m TWA: 2 mg/m 1310-73-2 Ceiling: 2 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use.
Skin and Body Protection Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Liquid Appearance Clear Odor Bleach Color Pale yellow Odor Threshold No information available
Property Values Remarks/ Method pH ~12.5 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.05 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available
Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available
10. STABILITY AND REACTIVITY
Reactivity Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds.
Chemical stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Conditions to avoid None known based on information supplied.
Incompatible materials Toilet bowl cleaners, rust removers, acids, and ammonia-containing products.
Hazardous Decomposition Products None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Exposure to vapor or mist may irritate respiratory tract.
Eye Contact May cause eye irritation.
Skin Contact Prolonged contact may cause irritation.
Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea.
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - 7681-52-9 Sodium hydroxide - 1350 mg/kg (Rabbit) - 1310-73-2
Information on toxicological effects
Symptoms May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite - Group 3 - - 7681-52-9 IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI).
Aspiration Hazard No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document 117.20 mg/l ATEmix (4 hr)
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12. ECOLOGICAL INFORMATION
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Persistence and Degradability No information available.
Bioaccumulation No information available.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT NOT REGULATED
TDG UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT
ICAO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III
IATA UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III
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IMDG/IMO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III EmS No. F-A, S-F Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT
15. REGULATORY INFORMATION
Chemical Inventories
TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No
Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CWA - Reportable CWA - Hazardous Chemical Name CWA - Toxic Pollutants CWA - Priority Pollutants Quantities Substances Sodium hypochlorite 100 lb X 7681-52-9 Sodium hydroxide 1000 lb X 1310-73-2
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Extremely Hazardous Substances Chemical Name Hazardous Substances RQs RQ RQs Sodium hypochlorite RQ 100 lb final RQ 100 lb - 7681-52-9 RQ 45.4 kg final RQ Sodium hydroxide RQ 1000 lb final RQ 1000 lb - 1310-73-2 RQ 454 kg final RQ
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US State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Sodium hypochlorite X X X X 7681-52-9 Sodium hydroxide X X X X 1310-73-2
International Regulations
Canada WHMIS Hazard Class D2B - Toxic materials
16. OTHER INFORMATION
NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards -
HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B
Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Revision Date New
Revision Note New
Reference 1076851/173214.001
General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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FICHE DE DONNÉES DE
SÉCURITÉ
Date d'émission 5 janvier 2015 Date de révision Nouvelle Numéro de révision 0
\1. IDENTIFICATION DE LA SUBSTANCE/DE LA PRÉPARATION ET DE LA SOCIÉTÉ/L’ENTREPRISE
Identificateur de produit
Nom du produit Eau de Javel Clorox®
Autres moyens d’identification
Synonymes Aucun
Utilisation recommandée pour le produit chimique et restrictions en matière d’utilisation
Utilisation recommandée Lessive et eau de Javel domestique
Utilisations déconseillées Aucune information disponible
Renseignements concernant le fournisseur de la fiche de données de sécurité
Adresse du fournisseur The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3
Numéro de téléphone d’urgence
Numéros de téléphone d’urgence Pour des urgences médicales, appelez : 1 800 446-1014 Pour des urgences en matière de transport, appelez Chemtrec : 1 800 424-9300
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2. IDENTIFICATION DES DANGERS
Classification
Ce produit chimique est considéré comme dangereux selon la norme sur la communication des renseignements à l’égard des matières dangereuses 2012 d’OSHA (29 CFR 1910.1200)
Lésions oculaires graves/irritation oculaire Catégorie 2A
Éléments d’étiquetage SGH, y compris les conseils de prudence
Vue d’ensemble des procédures d’urgence
Mot indicateur Avertissement
Mentions de danger Provoque une sévère irritation des yeux
Apparence Transparent, jaune pâle État physique Liquide Odeur Javellisant
Conseils de prudence - Prévention Se laver les mains et toute peau exposée à fond après manutention. Porter une protection oculaire/faciale telle que des lunettes de sécurité.
Conseils de prudence - Réaction Yeux : EN CAS DE CONTACT AVEC LES YEUX : Rincer prudemment avec de l’eau pendant plusieurs minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Si l’irritation oculaire persiste : Obtenir une consultation médicale ou des soins médicaux.
Conseils de prudence - Stockage Aucun
Conseils de prudence - Élimination Aucun
Dangers non classés ailleurs (DNCA) Sans objet.
Toxicité inconnue 0,06 % du mélange est constitué d’ingrédients de toxicité inconnue
Autres informations Très toxique pour les organismes aquatiques, entraîne des effets à long terme
Interactions avec d’autres produits chimiques Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés.
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3. COMPOSITION / INFORMATION SUR LES COMPOSANTS
Nom chimique No CAS % en poids Secret commercial Hypochlorite de sodium 7681-52-9 1 - 5 * Hydroxyde de sodium 1310-73-2 0,1 - 1 * * Le pourcentage (concentration) exact de composition est retenu comme un secret commercial.
4. PREMIERS SOINS
Premiers soins
Conseils généraux Présenter cette fiche signalétique au médecin traitant.
Contact avec les yeux Rincer immédiatement avec une grande quantité d’eau, également sous les paupières, pendant au moins quinze minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Garder les yeux grands ouverts lors du rinçage. Ne pas frotter la partie touchée. Obtenir des soins médicaux si une irritation se produit et persiste.
Contact avec la peau Retirer les vêtements contaminés. Rincer la peau avec beaucoup d’eau. En cas d’irritaiton, appeler un médecin.
Inhalation Déplacer à l’air frais. Si la respiration est touchée, appeler un médecin.
Ingestion Boire un verre d’eau. Appeler immédiatement un centre antipoison ou un médecin. NE PAS provoquer de vomissements à moins d’en avoir reçu la directive d’un centre antipoison ou d’un médecin.
Protection des secouristes Éviter le contact avec la peau, les yeux ou les vêtements. Utiliser l’équipement de protection individuel requis. Porter des vêtements de protection individuelle (voir la section 8).
Symptômes/effets les plus importants, aigus et retardés
Symptômes/effets les plus Picotement et irritation des yeux. importants
Indications quant à la nécessité éventuelle d’une prise en charge médicale immédiate ou d’un traitement spécial
Notes au médecin Traiter en fonction des symptômes.
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5. MESURES À PRENDRE EN CAS D’INCENDIE
Agents extincteurs appropriés Utiliser des mesures d’extinction appropriées aux circonstances locales et à l’environnement immédiat.
Agents extincteurs inappropriés ATTENTION : L’utilisation d’une pulvérisation d’eau pour combattre un incendie peut se révéler inefficace.
Dangers spécifiques du produit Aucune information disponible.
Données sur les risques d’explosion
Sensibilité à un choc mécanique Aucune.
Sensibilité à une décharge statique Aucune.
Équipement de protection et précautions pour les pompiers Comme avec tout incendie, porter un appareil respiratoire autonome à demande de pression, MSHA/NIOSH (homologué ou équivalent) et une tenue de protection complète.
6. MESURES À PRENDRE EN CAS DE DÉVERSEMENTS ACCIDENTELS
Précautions individuelles, équipement de protection et mesures d’urgence
Précautions individuelles Éviter tout contact avec les yeux, la peau et les vêtements. Utiliser l’équipement de protection individuelle requis.
Autres informations Consulter les mesures de protection données aux sections 7 et 8.
Précautions relatives à l’environnement
Précautions relatives à Voir la Section 12 pour des données écologiques. l’environnement
Méthodes et matériaux pour l’isolation et le nettoyage
Méthodes d’isolation Empêcher d’autres fuites ou déversements lorsqu’il est possible de le faire en toute sécurité.
Méthodes de nettoyage Absorber et conteneuriser. Laver les résider et les envoyer à un égout sanitaire. Contacter une installation de traitement sanitaire à l’avance pour s’assurer de sa capacité à traiter le matériel emporté.
7. MANUTENTION ET STOCKAGE
Précautions relatives à la sécurité de manutention
Manutention Manipuler conformément aux bonnes pratiques de sécurité et d’hygiène industrielle. Éviter le contact avec la peau, les yeux et les vêtements Ne pas manger, boire ou fumer en manipulant le produit.
Conditions de sécurité de stockage, y compris les incompatibilités
Stockage Conserver les récipients bien fermés dans un endroit sec, frais et bien ventilé.
Produits incompatibles Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac.
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8. CONTRÔLE DE L’EXPOSITION/PROTECTION INDIVIDUELLE
Paramètres de contrôle
Directives relatives à l’exposition
Nom chimique ACGIH TLV OSHA PEL NIOSH IDLH 3 Hydroxyde de sodium 3 3 IDLH : 10 mg/m Valeur plafond : 2 mg/m TWA : 2 mg/m 1310-73-2 Valeur plafond : 2 mg/m3 ACGIH TLV : Conférence américaine des hygiénistes industriels gouvernementaux - valeur limite d’exposition OSHA PEL : Administration de la sécurité et de la santé professionnelle - limites d’exposition admissibles NIOSH IDLH : Dangereux immédiatement pour la santé ou la vie.
Contrôles d’ingénierie appropriés
Mesures techniques Douches Douches oculaires Systèmes de ventilation
Mesures de protection individuelle telles que les équipements de protection individuelle
Protection des yeux/du visage En cas d’éclaboussures probables : Porter des lunettes de sécurité à écrans latéraux (ou des lunettes à coques). Aucune nécessaire pour une utilisation par le consommateur.
Protection de la peau et du corps Porter des gants en caoutchouc ou en néoprène s’il existe une possibilité d’un contact répété ou prolongé avec la peau.
Protection respiratoire En cas d’irritation ou de dépassement des limites d’exposition, vous devez porter une protection respiratoire approuvée NIOSH/MSHA. Des respirateurs à adduction d’air à pression positive peuvent être requis pour des concentrations élevées de contaminants atmosphériques. Une protection respiratoire doit être fournie conformément à la réglementation locale en cours.
Mesures d’hygiène Retirer et laver les vêtements contaminés avant de les réutiliser. Éviter le contact avec la peau, les yeux ou les vêtements. Ne pas manger, boire ou fumer en manipulant le produit.
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9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
Propriétés physiques et chimiques
État physique Liquide Apparence Transparent Odeur Javellisant Couleur Jaune pâle Seuil olfactif Aucune information disponible
Propriété Valeurs Remarques/ Méthode pH ~ 12,5 Aucune connue Point de fusion/point de congélation Aucune donnée disponible Aucune connue Point d’ébullition / Domaine Aucune donnée disponible Aucune connue d’ébullition Point d’éclair Ininflammable Aucune connue Taux d’évaporation Aucune donnée disponible Aucune connue Inflammabilité (solide, gaz) Aucune donnée disponible Aucune connue Limites d’inflammabilité dans l’air Limite supérieure d’inflammabilité Aucune donnée disponible Aucune connue Limite inférieure d’inflammabilité Aucune donnée disponible Aucune connue Tension de vapeur Aucune donnée disponible Aucune connue Densité de la vapeur Aucune donnée disponible Aucune connue Densité ~ 1,05 Aucune connue Solubilité dans l’eau Soluble dans l’eau Aucune connue Solubilité dans d’autres solvants Aucune donnée disponible Aucune connue Coefficient de partage : Aucune donnée disponible Aucune connue n-octanol/eau Température d’auto-inflammation Aucune donnée disponible Aucune connue Température de décomposition Aucune donnée disponible Aucune connue Viscosité cinématique Aucune donnée disponible Aucune connue Viscosité dynamique Aucune donnée disponible Aucune connue Propriétés explosives Non explosif Propriétés comburantes Aucune donnée disponible
Autres informations Point de ramollissement Aucune donnée disponible Teneur en COV (%) Aucune donnée disponible Dimension de particules Aucune donnée disponible Distribution granulométrique Aucune donnée disponible
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10. STABILITÉ ET RÉACTIVITÉ
Réactivité Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés.
Stabilité chimique Stable dans les conditions de stockage recommandées.
Risque de réactions dangereuses Aucun dans des conditions normales de traitement.
Conditions à éviter Aucune connue selon les renseignements fournis.
Matériaux incompatibles Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac.
Produits de décomposition dangereux Aucune connue selon les renseignements fournis.
11. DONNÉES TOXICOLOGIQUES
Les voies d’exposition probables
Renseignements sur le produit .
Inhalation Une exposition aux vapeurs ou à la bruine peut irriter les voies respiratoires.
Contact avec les yeux Peut causer une irritation des yeux.
Contact avec la peau Un contact prolongé peut causer une irritation.
Ingestion Une ingestion peut provoquer une irritation des muqueuses et du tractus gastro-intestinal, des nausées, des vomissements et une diarrhée.
Informations sur les composants
Nom chimique DL50 orale DL50 cutanée CL50 par inhalation Hypochlorite de sodium 8 200 mg/kg (rat) > 10 000 mg/kg (lapin) - 7681-52-9 Hydroxyde de sodium - 1350 mg/kg (lapin) - 1310-73-2
Informations sur les effets toxicologiques
Symptômes Peut causer une rougeur et un larmoiement des yeux.
Les effets retardés et immédiats ainsi que les effets chroniques dus à une exposition à court et long terme
Sensibilisation Aucune information disponible.
Effets mutagènes Aucune information disponible.
Cancérogénicité Le tableau ci-dessous indique si chaque agence a inscrit un ingrédient comme étant cancérigène.
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Nom chimique ACGIH CIRC NTP OSHA Hypochlorite de sodium - Groupe 3 - - 7681-52-9 CIRC (Centre international de recherche sur le cancer) Groupe 3 - Ne peut être classifié pour la cancérogénicité chez les humains
Toxicité pour la reproduction Aucune information disponible.
Toxicité pour certains organes Aucune information disponible. cibles - exposition unique
Toxicité pour certains organes Aucune information disponible. cibles - exposition répétée Toxicité chronique Le potentiel cancérogène est inconnu. Effets sur les organes cibles Appareil respiratoire, yeux, peau, tractus gastro-intestinal (GI).
Danger par aspiration Aucune information disponible.
Valeurs numériques de la toxicité - Information sur le produit
Les valeurs suivantes sont calculées selon le chapitre 3.1 du document SGH : 117,20 mg/l ETAmél (4 h)
12. DONNÉES ÉCOLOGIQUES
Écotoxicité Très toxique pour les organismes aquatiques, entraîne des effets à long terme.
Persistance et dégradation Aucune information disponible.
Bioaccumulation Aucune information disponible.
Autres effets nocifs Aucune information disponible.
13. DONNÉES SUR L’ÉLIMINATION DU PRODUIT
Méthodes d’élimination Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux.
Récipients contaminés Ne pas réutiliser les récipients vides. Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux.
14. INFORMATIONS RELATIVES AU TRANSPORT
DOT NON RÉGLEMENTÉ
TMD Numéro ONU UN3082 Désignation officielle de MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. transport Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN
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OACI : Numéro ONU UN3082 Désignation officielle de MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. transport Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III
IATA Numéro ONU UN3082 Désignation officielle de MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. transport Classe de danger 9 Groupe d’emballage III Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III
IMDG/OMI Numéro ONU UN3082 Désignation officielle de MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. transport Classe de danger 9 Groupe d’emballage III EmS No F-A, S-F Polluant marin Le produit est un polluant marin selon les critères fixés par l’IMDG/OMI Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN
15. INFORMATIONS SUR LA RÉGLEMENTATION
Inventaire de produits chimiques
TSCA Tous les composants de ce produit sont soit inscrits sur l’inventaire TSCA 8(b) ou sont exempts d’inscription. LIS/LES Tous les composants sont inclus dans la LIS ou la LES.
TSCA - États-Unis - Section 8 (b) de l’inventaire TSCA (loi réglementant les substances toxiques) LIS/LES – liste intérieure des substances/liste extérieure des substances pour le Canada
ÉTATS-UNIS Règlements fédéraux
SARA 313 Section 313 du titre III de la loi du Superfund Amendments and Reauthorization Act de 1986 (SARA). Ce produit ne contient aucun produit chimique soumis aux exigences en matière de rapport de la Loi et du titre 40 du Code of Federal Regulations, partie 372
SARA 311/312 Catégories de dangers Risque aigu pour la santé Oui Danger chronique pour la santé Non Risque d’incendie Non Danger de libération soudaine de pression Non Danger de réaction Non
Loi sur la qualité de l’eau (Clean Water Act) Ce produit contient les substances suivantes qui sont des polluants réglementés conformément à la loi sur la qualité de l’eau (Clean Water Act) (40 CFR 122.21 et 40 CFR 122.42)
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CWA - polluants CWA - substances Nom chimique CWA - quantités à déclarer CWA - polluants toxiques prioritaires dangereuses Hypochlorite de sodium 100 lb X 7681-52-9 Hydroxyde de sodium 1000 lb X 1310-73-2
CERCLA Sous sa forme commerciale, ce produit contient une ou plusieurs substances réglementées comme une substance dangereuse en vertu de CERCLA (Comprehensive Environmental Response Compensation and Liability Act) (40 CFR 302)
Quantités à déclarer de Quantités à déclarer de Nom chimique Quantité à déclarer (QD) substances dangereuses substances très dangereuses Hypochlorite de sodium QD 100 lb QD finale 100 lb - 7681-52-9 QD 45,4 kg QD finale Hydroxyde de sodium QD 1000 lb QD finale 1000 lb - 1310-73-2 QD 454 kg QD finale
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États-Unis - Réglementation des états
Proposition 65 de la Californie Ce produit ne contient aucun produit chimique de la proposition 65.
Règlement d’état sur le droit à l’information aux États-Unis
Nom chimique New Jersey Massachusetts Pennsylvanie Rhode Island Illinois Hypochlorite de sodium X X X X 7681-52-9 Hydroxyde de sodium X X X X 1310-73-2
Règlements internationaux
Canada Classe de dangers du SIMDUT D2B - Matières toxiques
16. AUTRES INFORMATIONS
NFPA Danger pour la santé 2 Inflammabilité 0 Instabilité 0 Propriétés physiques et chimiques -
HMIS Danger pour la santé 2 Inflammabilité 0 Danger physique 0 Protection individuelle B
Préparée par Product Stewardship 23 British American Blvd. Latham, NY 12110 1 800 572-6501
Date de révision Nouvelle
Note de révision Nouvelle
Référence 1076851/173214.001
Avis de non-responsabilité général À notre connaissance et selon nos renseignements et notre opinion à la date de publication de cette fiche signalétique, les renseignements fournis dans cette dernière sont exacts. Les renseignements donnés sont conçus uniquement comme un guide pour la manipulation, l’utilisation, le traitement, l’entreposage, le transport, l’élimination et le rejet sécuritaires du produit et ne doivent pas être considérés comme une garantie ou une norme de qualité. Les renseignements sont liés uniquement au produit particulier indiqué et peuvent ne pas être valides pour un tel produit utilisé en association avec toute autre substance ou dans tout autre procédé, sauf si indiqué dans le texte.
Fin de la fiche signalétique
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SAFETY DATA SHEET
Issue Date 22-Mar-2015 Revision Date 24-Mar-2015 Version 2
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier Product Name Dri-Eaz MILGO SR Product Code LBCMGOBLLB-MSR Customer Code F448 Formula code W.20404 /LG-F1050 Other means of identification
Recommended use of the chemical and restrictions on use
Recommended Use Professional Deodorizer Uses advised against Use only as stated on label.
Details of the supplier of the safety data sheet
Manufactured For / Distributed By Legend Brands Products 15180 Josh Wilson Road Burlington, WA 98233 800-932-3030
Emergency telephone number
24 Hour Emergency Phone Number 1-800-535-5053
2. HAZARDS IDENTIFICATION
Classification
Acute toxicity - Oral Not classified Acute aquatic toxicity Category 3 Chronic aquatic toxicity Category 3 Flammable liquids Category 3
Label elements
Emergency Overview
Warning
Hazard statements Harmful to aquatic life with long lasting effects
Flammable liquid and vapor
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Precautionary Statements - Prevention - Avoid release to the environment - Keep away from heat/sparks/open flames/hot surfaces. — No smoking - Keep container tightly closed - Ground/bond container and receiving equipment - Use explosion-proof electrical/ventilating/lighting/equipment. - Use only non-sparking tools - Take precautionary measures against static discharge - Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response - Specific Treatment (See Section 4 on the SDS)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink plenty of water.
In case of fire: Use CO2, dry chemical, or foam for extinction.
Precautionary Statements - Storage - Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal - Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Other Information
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret Ethanol 64-17-5 3-7 * Ethoxylated Secondary Alcohol 84133-50-6 1-5 * Trade Secret Proprietary .1-1 * Glutaraldehyde 111-30-8 .1-1 *
.
4. FIRST AID MEASURES
First aid measures
General advice If symptoms persist, call a physician.
Skin Contact Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.
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Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing If symptoms persist, call a physician Inhalation Immediate medical attention is not required. If symptoms persist, call a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products. Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Do NOT induce vomiting.
Self-protection of the first aider Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms Any additional important symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam.
Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. Risk of ignition.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment as required. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges.
Environmental precautions
Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Soak up with inert absorbent material. Dam up. Pick up and transfer to properly labeled containers. Take precautionary measures against static discharges.
7. HANDLING AND STORAGE
Precautions for safe handling
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Advice on safe handling Use with local exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors).
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. Incompatible materials None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethanol STEL: 1000 ppm TWA: 1000 ppm IDLH: 3300 ppm 64-17-5 TWA: 1900 mg/m3 TWA: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1900 mg/m3 2-Propanol STEL: 400 ppm TWA: 400 ppm IDLH: 2000 ppm 67-63-0 TWA: 200 ppm TWA: 980 mg/m3 TWA: 400 ppm (vacated) TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 980 mg/m3 STEL: 500 ppm (vacated) STEL: 500 ppm STEL: 1225 mg/m3 (vacated) STEL: 1225 mg/m3 Glutaraldehyde Ceiling: 0.05 ppm activated and (vacated) Ceiling: 0.2 ppm Ceiling: 0.2 ppm 111-30-8 inactivated (vacated) Ceiling: 0.8 mg/m3 Ceiling: 0.8 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health
Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Appropriate engineering controls
Engineering Controls Showers, Eyewash stations & Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection No special technical protective measures are necessary. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Liquid Appearance Clear
Color Blue Green
Odor Lemon
Odor threshold No Information available
Property Values Remarks • Method
pH 6.0 - 8.0
Specific Gravity 1
Viscosity Water Thin
Melting point/freezing point No Information available
Flash point 51 °C 124 °F
Boiling point / boiling range No Information available /
Evaporation rate Same as water
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit: No Information available
Lower flammability limit: No Information available
Vapor pressure No Information available
Vapor density No Information available
Water solubility Soluble in water
Partition coefficient No Information available
Autoignition temperature No Information available
Decomposition temperature No Information available
Other Information
Density Lbs/Gal 8.23 VOC Content (%) 6.7
10. STABILITY AND REACTIVITY
Reactivity No data available
Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation No data available. Eye contact May cause irritation. Skin Contact Prolonged contact may cause redness and irritation. Ingestion May be harmful if swallowed.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 64-17-5 ______
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2-Propanol = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h 67-63-0 Glutaraldehyde = 252 mg/kg ( Rat ) = 560 µL/kg ( Rabbit ) = 0.1 mg/L ( Rat ) 4 h 111-30-8
Information on toxicological effects
Symptoms No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No Information available. Germ cell mutagenicity No Information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.
Chemical Name ACGIH IARC NTP OSHA Ethanol A3 Group 1 Known X 64-17-5 ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Reproductive toxicity No Information available. STOT - single exposure No Information available. STOT - repeated exposure No Information available. Chronic toxicity Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target organ effects Blood, Central nervous system, EYES, Liver, Reproductive System, Respiratory system, Skin. Aspiration hazard No Information available.
Numerical measures of toxicity - Product Information
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name Algae/aquatic plants Fish Crustacea Ethanol - 12.0 - 16.0: 96 h Oncorhynchus 9268 - 14221: 48 h Daphnia magna 64-17-5 mykiss mL/L LC50 static 100: 96 h mg/L LC50 2: 48 h Daphnia magna Pimephales promelas mg/L LC50 mg/L EC50 Static 10800: 24 h static 13400 - 15100: 96 h Daphnia magna mg/L EC50 Pimephales promelas mg/L LC50 flow-through
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Ethoxylated Secondary Alcohol - 3.2: 96 h Pimephales promelas 3.2: 48 h water flea mg/L EC50 84133-50-6 mg/L LC50 Glutaraldehyde 0.61: 72 h Desmodesmus 7.8 - 22: 96 h Lepomis macrochirus 14: 48 h Daphnia magna mg/L 111-30-8 subspicatus mg/L EC50 0.84: 96 h mg/L LC50 static 2.6 - 4.8: 96 h EC50 0.56 - 1.0: 48 h Daphnia Desmodesmus subspicatus mg/L Oncorhynchus mykiss mg/L LC50 magna mg/L EC50 Static EC50 flow-through 7.8 - 13: 96 h Oncorhynchus mykiss mg/L LC50 static 5.4: 96 h Pimephales promelas mg/L LC50 static
Persistence and degradability No Information available.
Bioaccumulation No Information available.
Chemical Name Partition coefficient Ethanol -0.32 64-17-5 Glutaraldehyde 0.22 111-30-8 Other adverse effects No Information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D001
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status Ethanol Toxic 64-17-5 Ignitable Glutaraldehyde Toxic 111-30-8
14. TRANSPORT INFORMATION
Note: The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS.
U.S. Department of Transportation (USDOT)
4x1 Gallon Case Not regulated
Pails & Drums (<119 Gallons) Not regulated
15. REGULATORY INFORMATION International Inventories
TSCA Does not comply DSL/NDSL Does not comply
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
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US Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Reactive Hazard No Sudden release of pressure hazard No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations
California Proposition 65 This product contains the following Proposition 65 chemicals
Chemical Name California Prop. 65
1,4-DIOXANE - 123-91-1 Carcinogen Ethylene oxide - 75-21-8 Carcinogen Developmental Female Reproductive Male Reproductive
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Ethanol X X X 64-17-5 2-Propanol X X X 67-63-0 Glutaraldehyde X X X 111-30-8 Sodium Sulfate - X X 7757-82-6
U.S. EPA Label Information
EPA Pesticide Registration Number Not Applicable
Additional information No Information available.
16. OTHER INFORMATION
HMIS ______
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Health hazards Flammability Physical hazards Personal protection 2 2 0 B
Prepared By Regulatory Department Issue Date 22-Mar-2015 Revision Date 24-Mar-2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 151 of 276 MATERIAL SAFETY DATA SHEET
PRODUCT NAME: FAB SET CR12
SECTION 1: COMPANY AND PRODUCT IDENTIFICATION
Distributed By: Bridgepoint Systems, 4282 W 590 W, Salt Lake City, Utah 84123 Company Phone Number: 801-261-1282 Emergency Phone Number: 1-800-535-5053 (Infotrac) Date Prepared: 02/01/2011
Hazard Rating (Zero=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme) Fire: 0 Health: 1 Reactivity: 1
SECTION 2: COMPOSITION/INFORMATION ON COMPONENTS
HAZARDOUS INGREDIENTS: OSHA PEL TLV Glycolic Acid (CAS # 79-14-1) N/E N/E Citric Acid (CAS # 77-92-9) N/E N/E
SECTION 3: HAZARDS IDENTIFICATION
Immediate Health Effects
Eye Contact: May cause temporary eye irritation; injury to eye tissue unlikely. Skin Contact: Frequent or prolonged contact may cause temporary irritation. Skin contact may aggravate an existing dermatitis condition. Inhalation: May cause slight temporary irritation. Ingestion: Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause temporary injury.
Primary Routes of Entry: Eyes, skin contact/absorption, inhalation or ingestion.
Signs/Symptoms of Overexposure: Gastrointestinal irritation (nausea, vomiting, diarrhea), and/or irritation to the skin, eyes, nose, throat, and respiratory tract.
Target Organ Effects: Irritation of the skin and eyes. Irritation of lungs possible if mists/aerosols are inhaled.
Reproductive/Developmental Information: No data available.
Carcinogenicity: NTP: Known – No; Anticipated – No OSHA: No IARC: No
Long Term Effects: No data available.
Page 152 of 276 MATERIAL SAFETY DATA SHEET PRODUCT NAME: FAB -SET CR12 Page 2 of 4 SECTION 4: FIRST AID MEASURES
E ye Contact: Immediately irrigate with flowing water continuously for 15 minutes. If irritation persists consult medical personnel. Skin Contact: Wash with soap and water. If irritation persists consult medical personnel. Inhalation: Move to fresh air. If irritation persists consult medical personnel. Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If injured party is conscious, give two glasses of water. Seek medical attention.
SECTION 5: FIRE-FIGHTING MEASURES
Flashpoint: >212° F Explosive limits: No data Autoignition temperature: No data General Hazard: Irritant Fire Fighting Procedures: Wear self-contained breathing apparatus and full protective clothing. Use water spray to cool nearby containers and structures exposed to fire. Hazardous Decomposition Products: During a fire, smoke may contain the original material in addition to unidentified toxic and/or irritating compounds. Hazardous combustion products may include and are not limited to carbon dioxide and carbon monoxide.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Keep all unnecessary personnel away. Prevent additional discharge of material. Prevent material from entering sewers, watercourses, or low areas. Contain and absorb spilled material with sand or earth. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
SECTION 7: HANDLING AND STORAGE
Store out of reach of children; keep container closed; store in a cool well-ventilated place away from strong oxidizing or alkaline products. Avoid contact with skin and eyes. Use in a well-ventilated area; do not breathe vapors. Wash hands thoroughly after handling.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Normal room ventilation is satisfactory for limited use. Eye Protection: Safety glasses Skin Protection: Use gloves impervious to this material when prolonged or frequently repeated contact could occur. Respiratory: No respiratory protection should be needed. Exposure guidelines: N/E
Page 153 of 276 MATERIAL SAFETY DATA SHEET PRODUCT NAME: FAB -SET CR12 Page 3 of 4 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor: Light Apple Scent Physical State: Liquid. Appearance: Clear, Light Green pH: 2.0 Specific Gravity: 1.008 Boiling Point: N/D Freezing/Melting Point: N/D Vapor Pressure: N/D Vapor Density: N/D Solubility in Water: Complete
SECTION 10: STABILITY AND REACTIVITY
Chemical stability: Stable Incompatibility with other substances: Strong oxidizing or alkaline agents Reactivity: None known. Hazardous Decomposition Products: Exposure to fire may liberate carbon dioxide, carbon monoxide, organic acids, and other unidentified thermal decomposition products from this product or its packaging.
SECTION 11: TOXICOLOGICAL INFORMATION
Route of Entry: Eye contact, and skin absorption/contact.
Effects of Acute Overexposure to Product: Eye Contact: May cause temporary eye irritation, redness, tearing and blurred vision. Skin Contact: May cause temporary skin irritation, defatting and dermatitis. Inhalation: Inhalation of mist or vapor may cause temporary respiratory irritation, temporary central nervous system effects including dizziness, weakness, fatigue, nausea, and headache. Ingestion: May cause gastrointestinal temporary irritation with nausea, vomiting and diarrhea, aspiration into the lungs can cause chemical pneumonitis.
Effects of Chronic Overexposure to Product: Exposure limits: N/D for mixture Teratogenicity: None Reproductive toxicity: None Sensitization to Product: None known Mutagenicity: None Carcinogenicity: None
SECTION 12: ECOLOGICAL INFORMATION
Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information.
Page 154 of 276 MATERIAL SAFETY DATA SHEET PRODUCT NAME: FAB -SET CR12 Page 4 of 4 SECTION 13: DISPOSAL CONSIDERATIONS
Contain with chemical absorbent material. Do not dispose of on the land, in surface waters, or in storm drains. Small spills and waste may be flushed into a waste treatment sewer where local regulations permit. Larger quantities should be collected for reuse or consigned to a licensed hazardous waste hauler for disposal in accordance with federal, state and local regulations. All disposal must be in accordance with all federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
No restrictions for Ground, Air, or Maritime Transportation in accordance with 49 CFR parts 100-185.
SECTION 15: REGULATORY INFORMATION
Glycolic Acid (CAS # 79-14-1) CERCLA All components are listed on TSCA.
CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act
16. OTHER INFORMATION
This product has no established regulatory information. All regulatory information given is based on individual components of the mixture by component number. While this information and recommendations set forth herein are believed to be accurate and reliable, it is provided without warranty regarding its accuracy. BRIDGEPOINT SYSTEMS MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. Users must determine safe conditions for use and assume liability for any loss, injury, damage or expense resulting from use of this product.
N/A = Not applicable N/D = Not determined N/E = Not established
Page 155 of 276
Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
1. Identification of the Substance / Preparation and of the Company / Undertaking
Product identifier Product Name Freeze-proof RV & Marine -50 °F Burst Antifreeze
Stock Numbers 130425 / 130414 / 130421
Other means of identification
Synonyms Not available. Recommended use of the chemical and restrictions on use
Recommended Use RV & Marine Antifreeze.
Uses advised against Not available. Details of the supplier of the safety data sheet
Supplier Name South/Win, Ltd. Supplier Address 112 Maxfield Rd. Greensboro, NC 27405 US Supplier Phone Number Phone: (800) 648-4393 Fax: (336) 398-5680
Emergency Phone: CHEMTREC: (800) 424-9300
2. Hazards Identification
GHS INFORMATION Classification: Not hazardous according to OSHA criteria (29 CFR 1910.1200). Not hazardous according to WHMIS 2015 criteria. LABEL ELEMENTS
Hazard Pictograms(s): None Signal Word: None Hazard Statements: Not applicable.
PRECAUTIONARYSTATEMENTS
Prevention: Not applicable. Response: Not applicable. Storage: Not applicable. Disposal: Not applicable.
Hazards Not Otherwise Classified: Not applicable.
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Ingredients with Unknown Toxicity: None
This material is not considered hazardous by the OSHA Hazard Communication Standard, 2012 (29 CFR 1910.1200).
This material is not considered hazardous by the Hazardous Products Regulations, 2015.
3. Composition / Information on Ingredients
Ingredient(s) Common name / Synonyms CAS No. % wt./wt. 1,2-Propanediol Propylene glycol 57-55-6 55 - 65 Water Not available. 7732-18-5 35 - 40 Phosphoric acid, potassium salt (1:2) Potassium phosphate, dibasic 7758-11-4 1 - 4
4. First-Aid Measures
If inhaled: Call a poison center or doctor if you feel unwell. Inhalation:
Acute and delayed symptoms and effects: May cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Eye Contact: If in eyes: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center or doctor if you feel unwell.
Acute and delayed symptoms and effects: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact: If on skin: Wash with plenty of soap and water. Call a poison center or doctor if you feel unwell.
Acute and delayed symptoms and effects: May cause skin irritation. Signs/symptoms may include localized redness, swelling, and itching.
Store in a well-ventilated place. Keep cool.
Ingestion: If swallowed: Call a poison center or doctor if you feel unwell. If vomiting occurs naturally, have victim lean forward to reduce the risk of aspiration. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
Acute and delayed symptoms and effects: May cause gastrointestinal irritation. Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
General Advice: In case of accident or if you feel unwell, seek medical advice immediately. (Show the label or SDS where possible.)
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Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
Note to Physicians: Symptoms may not appear immediately.
5. Fire-Fighting Measures
FLAMMABILITY AND EXPLOSION INFORMATION
Not flammable or combustible by OSHA / WHMIS criteria. Material will not burn unless preheated.
Sensitivity to Mechanical Impact: This material is not sensitive to mechanical impact. Sensitivity to Static Discharge: This material is sensitive to static discharge at temperatures at or above the flash point.
MEANS OF EXTINCTION
Suitable Extinguishing Media: Dry chemical, CO2 or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Unsuitable Extinguishing Media: Not. available.
Products of Combustion: Oxides of carbon. Oxides of phosphorus.
Protection of Firefighters: Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. Wear positive pressure self- contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.
66.. Accidental Accidental ReleaseRelease MeasuresMeasures
Emergency Procedures: Keep unauthorized personnel away. Stay upwind. Keep out of low
areas. Ventilate closed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Personal Precautions: Do not touch or walk through spilled material. Use personal protection
recommended in Section 8.
Environmental Precautions: Keep out of drains, sewers, ditches, and waterways.
Methods for Containment: Stop leak if without risk. Do not flush to sewer or allow to enter waterways.
Absorb or cover with dry earth, sand or other non-combustible material Methods for Clean-Up: and transfer to containers.
Other Information: See Section 13 for disposal considerations.
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Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
7. Handling and Storage
Handling: Do not swallow. Avoid breathing mist, vapours, or spray. Avoid contact with eyes, skin, or clothing. See Section 8 for information on Personal Protection Equipment.
Storage: Store in a well-ventilated place; keep container tightly closed. Store at temperatures below 40°C (104 °F). Do not reuse container. Avoid container damage while storing. Store away from incompatible materials. See Section 10 for information on Incompatible Materials. Keep out of the reach of children.
8. Exposure Controls / Personal Protection
Exposure Guidelines Component
Water [CAS No. 7732-18-5] ACGIH: No TLV established. OSHA: No PEL established. Propylene glycol [CAS No. 57-55-6] ACGIH: No TLV established. OSHA: No PEL established. Potassium phosphate, dibasic [CAS No. 7758-11-4] ACGIH: No TLV established. OSHA: No PEL established.
PEL: Permissible Exposure Limit TLV: Threshold Limit Value
Engineering Controls: Not normally required.
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Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Eye/Face Protection: Wear safety glasses with side shields or chemical goggles. Use
equipment for eye protection that meets the standards referenced
by CSA Standard CAN/CSA – Z94. 3-92 and OSHA regulations in 29 CFR 1910.133 for Personal Protective Equipment.
Hand Protection: Wear protective gloves. Neoprene rubber gloves are recommended. Consult manufacturer specifications for further information.
Skin and Body Protection: Wear protective clothing.
Respiratory Protection: Not required under normal use conditions.
General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Consult a competent industrial hygienist to determine hazard potential and/or the PPE manufacturers to ensure adequate protection.
9. Physical and Chemical Properties
Appearance: Clear or dyed liquid. Colour: Colourless or dyed.
Odour: Characteristic.
Odour Threshold: Not available.
Physical State: Liquid.
pH: 8.5 to 11
Melting Point / Freezing 15.6 °C (60 °F) Point:
Initial Boiling Point: Not available.
Boiling Point: 108.3 °C (227 °F) at 760 mHg
Flash Point: 109 °C (228 °F) (PMCC) (estimated) Evaporation Rate: Not available.
Flammability (solid, gas): Not applicable.
Lower Flammability Limit: 2.6 % (Propylene glycol)
Upper Flammability Limit: 12.6 % (Propylene glycol)
Vapor Pressure: Not available.
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Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
Vapor Density: Not available.
Relative Density: 1.030 to 1.040 (Water = 1) at 15 °C (59 °F)
Solubilities: Soluble in water.
Partition Coefficient: n- Not available. Octanol/Water:
Auto-ignition Temperature: 371 °C (699.8 °F) (Propylene glycol)
Decomposition Not available. Temperature:
Viscosity: Not available.
Percent Volatile, wt. %: 55 to 65
VOC content, wt. %: Not available.
Density: 8.62 lb/gal
Coefficient of Water/Oil Not available. Distribution:
10. Stability and Reactivity
Reactivity: Contact with incompatible materials. Sources of ignition. Exposure to heat.
Chemical Stability: Stable under normal storage conditions. Possibility of Hazardous None known. Reactions: ConditionsReactions: to Avoid: Contact with incompatible materials. Sources of ignition. Exposure to heat. .
Incompatible Materials: Strong acids. Strong bases. Oxidizers.
Hazardous Decomposition Products: Not available.
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11. Toxicological Information
EFFECTS OF ACUTE EXPOSURE Product Toxicity
Oral: Not available.
Dermal: Not available.
Inhalation: Not available. Component Toxicity
Component CAS No. LD50 oral LD50 dermal LC50 Water 7732-18-5 > 90 mL/kg (rat) Not available. Not available. Potassium phosphate, 7758-11-4 Not available. Not available. Not available. dibasic Propylene glycol 57-55-6 20000 mg/kg (rat) 20800 mg/kg (rabbit) Not available.
Likely Routes of Exposure: Eye contact. Skin contact. Inhalation. Ingestion.
Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Central nervous system.
Symptoms (including delayed and immediate effects) Inhalation: May cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Eye: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin: May cause skin irritation. Signs/symptoms may include localized redness, swelling, and itching. Ingestion: May cause gastrointestinal irritation. Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Skin Sensitization: Not available. Respiratory Sensitization: Not available. Medical Conditions Aggravated By Exposure: Not available.
EFFECTS OF CHRONIC EXPOSURE (from short and long-term exposure)
Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Central nervous system.
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Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation.
Carcinogenicity: This product does not contain any carcinogens or potential carcinogens as listed by the ACGIH, IARC, OSHA, or NTP.
Mutagenicity: Not available. Reproductive Effects: Not available. Developmental Effects Teratogenicity: Not available. Embryotoxicity: Not available. Toxicologically Synergistic Materials: Not available.
12. Ecological Information
Ecotoxicity: Not available.
Persistence / Degradability: When released into the soil, this material is expected to readily degrade. When released into the water, this material is expected to have a half-life between 1 and 10 days.
Bioaccumulation/Accumulation: Not available.
Mobility in Environment: Not available.
Other Adverse Effects: Not available.
13. Disposal Considerations
Disposal Instructions: Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements.
14. Transport information
U.S. Department of Transportation (DOT) Proper Shipping Name: Not regulated
Class: Not applicable. UN Number: Not applicable. Packing Group: Not applicable. Label Code: Not applicable.
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Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
Canada Transportation of Dangerous Goods (TDG) Proper Shipping Name: Not regulated.
Class: Not applicable. UN Number: Not applicable.
Packing Group: Not applicable. Label Code: Not applicable.
Section15 1.5 Regulatory: REGULATO informationRY INFORMA TION
Chemical Inventories US(TSCA) The components of this product are in compliance with the chemical notification requirements of TSCA. Canada(DSL) The components of this product are in compliance with the chemical notification requirements of the NSN Regulations under CEPA, 1999.
Federal Regulations United States This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SARA Title III No components are listed.
State Regulations Massachusetts US Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section 670.000)
No components are listed.
New Jersey US New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) Component CAS No. RTK List
Propylene glycol 57-55-6 Listed.
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Safety Data Sheet
Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174
Pennsylvania US Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323) Component CAS No. RTK List
Propylene glycol 57-55-6 Listed.
California California Prop 65: This product does not contain chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
16. Other information
Prepared By: Randy Boitz
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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SECTION I - IDENTIFICATION
PRODUCT NAME: Graffiti Gone PRODUCT CODE: 2210 PRODUCT USE: Paint and Varnish Remover COMPANY NAME: QuestSpecialty Corporation COMPANY ADDRESS: PO Box 624 Brenham, TX 77834 COMPANY PHONE: 1-800-231-0454 EMERGENCY PHONE: 800-255-3924 SECTION II – HAZARDS IDENTIFICATION
CLASSIFICATION: Flammable Aerosol: Category 1 Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2A Acute Toxicity Inhalation: Category 4 Specific Target Organ Toxicity (Single Exposure): Category 3 Aspiration Hazard: Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure: May explode if heated. Causes skin irritation , serious eye irritation, and may cause respiratory irritation. Harmful if inhaled. May be fatal if swallowed and enters airways. This product contains the following percentage of chemicals of unknown toxicity: 6% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. Wear protective gloves and protective glasses. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. Avoid breathing fumes, mist, vapors, and spray. Use only outdoors or in a well-ventilated area. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell.
SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENT CAS NUMBER PERCENT Acetone 67-64-1 30-60% Xylene 1330-20-7 15-40% Propane/n-Butane 68476-86-8 10-30% Ethyl Benzene 100-41-4 5-10%
SECTION IV - FIRST AID MEASURES
EYES: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention. INHALATION: If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. SKIN: If on skin: Wash with plenty of water. If skin irritation occurs: get medical attention. ACUTE HEALTH HAZARDS: Inhalation: dizziness, drowsiness, weakness, fatigue, and serious nervous system depression Eye: stinging, tearing, redness, blurred vision Oral: Aspiration risk PAGE 1 of 5 Page 166 of 276 Safety Data Sheet Graffiti Gone Skin: Defatting and dermatitis CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient.
SECTION V – FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, foam, water spray for cooling. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Use water spray only to cool exposed containers. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon
SECTION VI – ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Wpe up with rag or use some absorbent clay material. remove any source of ignition. use non-sparking tools and equipment. WASTE DISPOSAL: Dispose of in accordance with local, State and Federal regulations. Do not puncture or incinerate container. Do not reuse empty container. Wrap container and place in trash collection. RCRA STATUS: Waste solvent likely considered U239 (Xylene), hazardous, under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE
HANDLING AND STORAGE: Protect from sunlight. Store in a well ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. Store locked up. OTHER PRECAUTIONS: Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warning and precautions listed for the product. Keep out of the reach of children INCOMPATIBILITY: Concentrated nitric & sulfuric acid mixtures, oxidizing materials, chloroform, alkalis, chlorine cmpnds, acids, plastics, rubber, coatings.
SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION
HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Acetone 1000 ppm 500 ppm Xylene 100 ppm 100 ppm Propane/n-Butane 1000 ppm 1000 ppm Ethyl Benzene 100 ppm 100 ppm
ENGINEERING CONTROLS / VENTILATION: Use only in well ventilated areas or outside. Forced ventilation required. Local exhaust preferred to general. RESPIRATORY PROTECTION: Not required with normal use. Wear NIOSH/MSHA approved respiratory protection if exposure limits are exceeded. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Wash hands thoroughly after handling. Avoid breathing vapors.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear Aerosol Spray ODOR: Solvent odor ODOR THRESHOLD: N/D BOILING POINT: >150 FREEZING POINT: N/D PAGE 2 of 5 Page 167 of 276 Safety Data Sheet Graffiti Gone FLAMMABILITY: Flammable Aerosol FLASH POINT: 65°F AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): 77.3 @ 77°F (25°C) VAPOR DENSITY (AIR=1): > 2 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.87 @ 77° F pH: N/A SOLIDS (%): 7.5% SOLUBILITY IN WATER: 3% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER (%): > 80% VOLATILE ORGANIC COMPOUNDS (VOC): 50% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA
REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 122°F and sources of ignition.
INCOMPATIBILITY: Concentrated nitric & sulfuric acid mixtures, oxidizing materials, chloroform, alkalis, chlorine cmpnds, acids, plastics, rubber, coatings. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon POSSIBLE HAZARDOUS REACTIONS: None Known
SECTION XI – TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION: Acetone (67-64-1) LD50 (Oral, Rat) 5800 mg/kg; LD50 (Oral, Mouse) 3000 mg/kg; LD50 (Oral, 3 3 Rabbit) 5340 mg/kg; LC50 (Inhalation, Rat, 8hr) 50100 mg/m ; LC50 (Inhalation, Mouse, 4hr) 44,000 mg/m Xylenes (1330-20- 7) LD50 (Oral, Rat) 4300 mg/kg; LD50 (Oral, Mouse) 2119 mg/kg; LD50 (Dermal, Rat) 1700 mg/kg ROUTES OF ENTRY: Ingestion, Inhalation, Skin EYES: Redness, irritation, causes temporary corneal opacity INGESTION: May cause nausea, diarrhea, vomiting, depending on the amount ingested. INHALATION: Causes dizziness, nausea, vomiting, excessive or prolonged exposure may cause unconsciousness, death. SKIN: Causes severe irritation, localized defatting. MEDICAL CONDITION AGGRAVATED: None known ACUTE HEALTH HAZARDS: Inhalation: dizziness, drowsiness, weakness, fatigue, and serious nervous system depression Eye: stinging, tearing, redness, blurred vision Oral: Aspiration risk Skin: Defatting and dermatitis CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone marrow, central nervous system (CNS). CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A
SECTION XII – ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: Acetone (67-64-1) LC50 (Trout, 96hr) 5540 mg/L; LC50 (Bluegill, 96hr) 8300 mg/L; LC50 (Fathead Minnow, 96hr) 7500 mg/L BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: This material is toxic to aquatic life.
PAGE 3 of 5 Page 168 of 276 Safety Data Sheet Graffiti Gone
SECTION XIII – DISPOSAL CONSIDERATIONS
WASTE DISPOSAL: Dispose of in accordance with local, State and Federal regulations. Do not puncture or incinerate container. Do not reuse empty container. Wrap container and place in trash collection. RCRA STATUS: Waste solvent likely considered U239 (Xylene), hazardous, under RCRA, however product should be fully characterized prior to disposal (40 CFR 261).
SECTION XIV - TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A
AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: None
SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: None ENVIRONMENTAL HAZARDS WATER: 2102
SECTION XV - REGULATORY INFORMATION
TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Xylenes (1330-20-7) Reportable Quantity = 100 lbs Ethylbenzene (100-41-4): RQ 1000lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Xylenes - 1330-20-7 CLEAN WATER ACT: None STATE REGULATIONS: Xylenes - 1330-20-7 - Connecticut hazardous material survey, Illinois chemical safety act, New York acutely hazardous substances, Rhode Island RTK hazardous substances, Pennsylvania RTK, Minnesota, Michigan critical material, Massachusetts RTK, Massachusetts spill list, New Jersey spill list, Louisiana spill reporting, California Director's List of Hazardous Substances. INTERNATIONAL REGULATIONS: Xylenes - EINECS, WHMIS (Canada): CLASS B-2. CLASS D-2A. DSCL (EEC): R10- Flammable. R21- Harmful in contact with skin. R36/38- Irritating to eyes and skin. S2- Keep out of the reach of children. S36/37- Wear suitable protective clothing and gloves. S46- If swallowed, seek medical advice immediately and show this container or label.
NFPA HEALTH: 2 HMIS HEALTH: 2 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B
SECTION XVI - ADDTIONAL INFORMATION
PREPARATION BY: Jonathon Jarvis DATE PREPARED: 12/16/2013 REVISION DATE: 11/10/2014
N/A = Not Applicable; N/D = Not Determined PAGE 4 of 5 Page 169 of 276 Safety Data Sheet Graffiti Gone
DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance.
PAGE 5 of 5 Page 170 of 276 SAFETY DATA SHEET
Revision Date 13-May-2015 Version 1
1. IDENTIFICATION
Product identifier Product Name Gumout Regane Auto Parts Cleaner & Degreaser
Other means of identification Product Code 11893 Document SKU 540001 Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use Automotive parts cleaner & degreaser Uses advised against All other applications
Details of the supplier of the safety data sheet Supplier Address Manufacturer Address Distributor ITW Global Brands 6925 Portwest Dr., Suite 100 Houston, TX 77024
Company Phone Number 1-855-888-1988 24 Hour Emergency Phone Number (CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.) (RMPDC) 1-877-504-9352 (U.S.)
E-mail address [email protected]
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2
Label elements
Emergency Overview Warning
Causes serious eye irritation Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure
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Page 171 of 276 11893 - Gumout Regane Auto Parts Cleaner & Revision Date 13-May-2015 Degreaser ______
Appearance Colorless to light yellow Physical state Aerosol Liquid Odor Acetone liquid
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area
Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Do not expose to temperatures exceeding 122 °F (50 °C) Keep out of reach of children
Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Not applicable
Other Information Causes mild skin irritation. Harmful to aquatic life with long lasting effects.
3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s)
Chemical Name CAS No Weight-% Trade Secret ACETONE 67-64-1 60 - 100 * TOLUENE 108-88-3 5 - 10 * CARBON DIOXIDE 124-38-9 5 - 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice Get medical advice/attention if you feel unwell.
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Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse.
Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician.
Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician.
Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
Most important symptoms and effects, both acute and delayed
Symptoms See section 2 for more information.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Dry chemical, CO2, sand, earth, water spray or regular foam
Unsuitable extinguishing media None.
Specific hazards arising from the chemical Extremely flammable. Contents under pressure and can explode when exposed to heat or flames.
Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Do not get in eyes, on skin, or on clothing. Do not puncture or incinerate cans. Contents under pressure. Use personal protective equipment as required.
Environmental precautions
Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. ______
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Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Contents under pressure. Do not puncture or incinerate cans. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Do not expose to temperatures exceeding 50 °C/122 °F. Keep away from sunlight, ignition sources and other sources of heat. Keep out of the reach of children.
Incompatible materials Strong oxidizing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE STEL: 750 ppm TWA: 1000 ppm IDLH: 2500 ppm 67-64-1 TWA: 500 ppm TWA: 2400 mg/m3 TWA: 250 ppm (vacated) TWA: 750 ppm TWA: 590 mg/m3 (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm TOLUENE TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppm 108-88-3 (vacated) TWA: 100 ppm TWA: 100 ppm (vacated) TWA: 375 mg/m3 TWA: 375 mg/m3 (vacated) STEL: 150 ppm STEL: 150 ppm (vacated) STEL: 560 mg/m3 STEL: 560 mg/m3 Ceiling: 300 ppm CARBON DIOXIDE STEL: 30000 ppm TWA: 5000 ppm IDLH: 40000 ppm 124-38-9 TWA: 5000 ppm TWA: 9000 mg/m3 TWA: 5000 ppm (vacated) TWA: 10000 ppm TWA: 9000 mg/m3 (vacated) TWA: 18000 mg/m3 STEL: 30000 ppm (vacated) STEL: 30000 ppm STEL: 54000 mg/m3 (vacated) STEL: 54000 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health
Appropriate engineering controls
Engineering Controls Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. ______
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General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Aerosol; Liquid Appearance Colorless to light yellow liquid Odor Acetone Odor threshold No information available
Property Values Remarks • Method pH Not Applicable Melting point / freezing point No information available Boiling point / boiling range 56 °C / 133 °F Flash point -20 °C / -4 °F Setaflash Closed Cup Evaporation rate 14.4 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density 0.798 Water solubility Miscible in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature 465 °C / 869 °F Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available
Other Information
Softening point No information available Molecular weight No information available VOC Content (%) 9.6 Density 0.798 g/cm3 Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity Stable under normal use
Chemical stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Temperatures >50 °C / 122 °F.
Incompatible materials Strong oxidizing agents ______
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Hazardous Decomposition Products Carbon oxides
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation May cause irritation of respiratory tract.
Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
Skin contact May cause skin irritation and/or dermatitis.
Ingestion Ingestion may cause irritation to mucous membranes.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h 67-64-1 TOLUENE = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h 108-88-3
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TOLUENE - Group 3 - - 108-88-3 IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Chronic toxicity May cause adverse liver effects. Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5580 mg/kg ATEmix (dermal) 129032 mg/kg ATEmix (inhalation-dust/mist) 63.5 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name Algae/aquatic plants Fish Crustacea ACETONE - 4.74 - 6.33: 96 h Oncorhynchus 10294 - 17704: 48 h Daphnia 67-64-1 mykiss mL/L LC50 6210 - 8120: 96 magna mg/L EC50 Static 12600 - h Pimephales promelas mg/L LC50 12700: 48 h Daphnia magna mg/L static 8300: 96 h Lepomis EC50 macrochirus mg/L LC50
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TOLUENE 433: 96 h Pseudokirchneriella 15.22 - 19.05: 96 h Pimephales 5.46 - 9.83: 48 h Daphnia magna 108-88-3 subcapitata mg/L EC50 12.5: 72 h promelas mg/L LC50 flow-through mg/L EC50 Static 11.5: 48 h Pseudokirchneriella subcapitata 12.6: 96 h Pimephales promelas Daphnia magna mg/L EC50 mg/L EC50 static mg/L LC50 static 5.89 - 7.81: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 14.1 - 17.16: 96 h Oncorhynchus mykiss mg/L LC50 static 5.8: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 11.0 - 15.0: 96 h Lepomis macrochirus mg/L LC50 static 54: 96 h Oryzias latipes mg/L LC50 static 28.2: 96 h Poecilia reticulata mg/L LC50 semi-static 50.87 - 70.34: 96 h Poecilia reticulata mg/L LC50 static
Persistence and degradability No information available.
Bioaccumulation No information available.
Mobility Disperses in water.
Chemical Name Partition coefficient ACETONE -0.24 67-64-1 TOLUENE 2.65 108-88-3
Other adverse effects No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Recover or recycle if possible. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated packaging Do not reuse container.
US EPA Waste Number U002 U220
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACETONE - Included in waste stream: - U002 67-64-1 F039 TOLUENE U220 Included in waste streams: - U220 108-88-3 F005, F024, F025, F039, K015, K036, K037, K149, K151
Chemical Name RCRA - Halogenated RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes Organic Compounds
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TOLUENE - - Toxic waste - 108-88-3 waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status ACETONE Ignitable 67-64-1 TOLUENE Toxic 108-88-3 Ignitable
14. TRANSPORT INFORMATION
DOT UN/ID no UN 1950 Proper shipping name: Aerosols, Flammable, Consumer Commodity, Limited Quantity (LQ) Hazard Class 2.1
IATA UN/ID no UN 1950 Proper shipping name: Aerosols, flammable, Consumer commodity, Limited Quantity (LQ) Hazard Class 2.1
IMDG UN/ID no UN 1950 Proper shipping name: Aerosols, flammable, Consumer Commodity, Limited Quantity (LQ) Hazard Class 2.1
15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not determined IECSC Not determined KECL Not determined PICCS Not determined AICS Not determined
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances ______
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PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values % TOLUENE - 108-88-3 1.0 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No
CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances TOLUENE 1000 lb X X X 108-88-3 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 5000 lb - RQ 5000 lb final RQ 67-64-1 RQ 2270 kg final RQ TOLUENE 1 lb - RQ 1 lb final RQ 108-88-3 RQ 0.454 kg final RQ US State Regulations
California Proposition 65 WARNING: This product contains chemicals known to the state of California to cause birth defects or other reproductive harm This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania ACETONE X X X 67-64-1 TOLUENE X X X 108-88-3 CARBON DIOXIDE X X X 124-38-9 U.S. EPA Label Information EPA Pesticide Registration Number Not applicable
NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B
NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) ______
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Revision Date 13-May-2015 Revision Note 2
Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 180 of 276 Safety Data Sheet
Revision Date 08-Sep-2014 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product name KILL ODOR PLUS Product code W.20234
Manufacturer Chemspec 901 North Newkirk Street Baltimore, MD 21205
Emergency telephone number Chemtrec: 1-800-424-9300 for US +1 703-527-3887 outside US
2. Hazards identification Emergency Overview May cause central nervous system depression May cause adverse kidney effects
Potential Health Effects Acute toxicity Eyes May cause slight irritation.
Skin No known effect based on information supplied.
Inhalation May be harmful if inhaled.
Ingestion No known effect based on information supplied.
Chronic Effects May cause adverse liver effects.
Aggravated Medical Conditions Central nervous system. Preexisting eye disorders. Blood disorders. Kidney disorders. Liver disorders. Skin disorders. Respiratory disorders. Hematopoietic system.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Environmental hazard See Section 12 for additional Ecological Information.
3. Composition/information on ingredients
Component CAS-No Weight % ETHANOL, 2-BUTOXY- 111-76-2 10-30 111-76-2 ( 10-30 ) Butylated hydroxytoluene (BHT) 128-37-0 <0.1 128-37-0 ( <0.1 )
4. First aid measures
General advice Show this material safety data sheet to the doctor in attendance.
Eye contact Remove contact lenses. Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Page 181 of 276 KILL ODOR PLUS ______
Skin contact Wash off immediately with soap and plenty of water. Remove all contaminated clothes and shoes.
Inhalation Move to fresh air.
Ingestion Gently wipe or rinse the inside of the mouth with water.
Notes to physician Treat symptomatically.
5. Fire-fighting measures
Flammable Properties Not flammable.
Flash point Not determined. Not Determined
Suitable extinguishing media Water spray. Foam. Dry powder.
Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None.
Protective Equipment and As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH Precautions for Firefighters (approved or equivalent) and full protective gear.
6. Accidental release measures
Personal precautions Use personal protective equipment.
Environmental precautions No special environmental precautions required.
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
7. Handling and storage
Advice on safe handling Wear personal protective equipment.
Technical measures/Storage Use only in area provided with appropriate exhaust ventilation. Keep tightly closed in a dry conditions and cool place.
8. Exposure controls/personal protection
Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Mexico ETHANOL, 2-BUTOXY- TWA: 20 ppm TWA: 50 ppm IDLH: 700 ppm TWA: 26 ppm 111-76-2 TWA: 240 mg/m3 TWA: 5 ppm TWA: 120 mg/m3 (vacated) TWA: 25 ppm TWA: 24 mg/m3 STEL: 75 ppm (vacated) TWA: 120 mg/m3 STEL: 360 mg/m3 (vacated) S* S* Butylated hydroxytoluene TWA: 2 mg/m3 inhalable (vacated) TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 (BHT) fraction and vapor STEL: 20 mg/m3 128-37-0 Component British Columbia Alberta Quebec Ontario TWAEV ETHANOL, 2-BUTOXY- TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm 111-76-2 ( 10-30 ) TWA: 97 mg/m3 TWA: 97 mg/m3 Butylated hydroxytoluene (BHT) TWA: 2 mg/m3 TWA: 10 mg/m3 STEL: 10 mg/m3 TWA: 2 mg/m3 128-37-0 ( <0.1 )
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Page 182 of 276 KILL ODOR PLUS ______Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Engineering Measures Showers Eyewash stations Ventilation systems.
Personal Protective Equipment Hand Protection Rubber gloves Rubber/latex/neoprene or other suitable chemical resistant gloves Eye/Face Protection Safety glasses with side-shields. Goggles. Skin and body protection Skin and body protection. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Hygiene measures When using, do not eat, drink or smoke.
9. Physical and chemical properties
Physical state Liquid Appearance Clear liquid Odor Clean Color Yellow
Property Values Remarks • Methods pH 7.3 Boiling point/boiling range Not Determined Flash Point Not Determined Evaporation rate no data available Explosion Limits upper lower Vapor pressure no data available Vapor density no data available Specific Gravity 1.011 g/cc Viscosity, kinematic no data available Water solubility no data available Partition coefficient: n-octanol/waterno data available Explosive properties no data available
Other information Volatile organic compounds (VOC) 15% content Melting/freezing point Freezing Point Not Determined
10. Stability and reactivity
Stability/Reactivity Stable under recommended storage conditions.
Incompatible products None known based on information supplied.
Conditions to Avoid Direct sources of heat.
Hazardous Decomposition Products Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.
Hazardous Polymerization Hazardous polymerization does not occur.
11. Toxicological information ______
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Page 183 of 276 KILL ODOR PLUS ______
Acute toxicity
Product Information The product itself has not been tested.
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation ETHANOL, 2-BUTOXY- 470 mg/kg ( Rat ) 220 mg/kg ( Rabbit ) 450 ppm ( Rat ) 4 h Butylated hydroxytoluene (BHT) 890 mg/kg ( Rat ) Chronic toxicity
Chronic toxicity May cause adverse liver effects
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA Mexico ETHANOL, 2-BUTOXY- A3 Group 3 Butylated hydroxytoluene Group 3 (BHT) ACGIH: (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC: (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans
Target Organ Effects Blood Central nervous system Eyes Hematopoietic System Kidney Liver Respiratory system Skin
12. Ecological information
Ecotoxicity No information available. .
Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia Toxicity to Toxicity to other and other aquatic microorganisms organisms invertebrates ETHANOL, 2-BUTOXY- LC50: 96 h Lepomis EC50: 48 h Daphnia macrochirus 1490 magna 1000 mg/L mg/L static LC50: 96 h Lepomis macrochirus 2950 mg/L Butylated hydroxytoluene EC50: 72 h (BHT) Pseudokirchneriella subcapitata 6 mg/L EC50: 72 h Desmodesmus subspicatus 0.42 mg/L Persistence and degradability No information available.
Bioaccumulation .
Mobility No information available.
Chemical Name log Pow ETHANOL, 2-BUTOXY- 0.81 Butylated hydroxytoluene (BHT) 4.17
13. Disposal considerations
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Page 184 of 276 KILL ODOR PLUS ______Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT Not regulated
MEX Not regulated
15. Regulatory information International Inventories TSCA Complies DSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies NZIoC Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals "-" - Unknown. Not listed.
U.S. Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name Weight % SARA 313 - Threshold Values % ETHANOL, 2-BUTOXY- 10-30 1.0 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No
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Page 185 of 276 KILL ODOR PLUS ______Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Sodium hydroxide 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ RQs Sodium hydroxide 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ U.S. State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island ETHANOL, 2-BUTOXY- X X X X Sodium hydroxide X X X Butylated hydroxytoluene X X X (BHT) International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class Non-controlled
16. Other information
NFPA Health Hazard 2 Flammability 0 Stability/Reactivity 0 Physical and chemical hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal protection -
Prepared By Chemspec Regulatory Affairs/Product Safety
Revision Date 08-Sep-2014 Revision Note No information available.
Legend: NIOSH IDLH: Immediately Dangerous to Life or Health
Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
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Page 186 of 276 KILL ODOR PLUS ______End of Material Safety Data Sheet
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Page 187 of 276 MATERIAL SAFETY DATA SHEET
Liquid HE® 150 XPT Version 1.3 Revision Date 2013-04-10
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information Trade name : Liquid HE® 150 XPT Material : 1111304, 1103273, 1099686
Use : Drilling Fluid Additive
Company : Drilling Specialties Company 10001 Six Pines Drive The Woodlands, TX 77380
Emergency telephone:
Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: North America: CHEMTREC 800.424.9300 or 703.527.3887 Asia: +800 CHEMCALL (+800 2436 2255) EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
Emergency Overview
Physical state: Liquid Color: Opaque Odor: Slight hydrocarbon OSHA Hazards : Combustible Liquid GHS Classification : Flammable liquids, Category 4
GHS-Labeling Signal Word : Warning
Hazard Statements : H227: Combustible liquid
Precautionary Statements : Prevention:
MSDS Number:100000014523 1/11
Page 188 of 276 MATERIAL SAFETY DATA SHEET Liquid HE® 150 XPT Version 1.3 Revision Date 2013-04-10
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P264: Wash skin thoroughly after handling. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.
Carcinogenicity: IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
ACGIH No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
SECTION 3: Composition/information on ingredients
Synonyms : HE® 150 Liquid Liquid Acid Gelling Agent
Molecular formula : Mixture
Component CAS-No. Weight % Distillates (petroleum), Hydrotreated 64742-47-8 30 - 60 light
SECTION 4: First aid measures
General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes.
In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact MSDS Number:100000014523 2/11
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lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : > 77 °C (> 171 °F) Method: ASTM D 93
Autoignition temperature : 225 °C (437 °F)
Suitable extinguishing : Carbon dioxide (CO2). media
Unsuitable extinguishing : High volume water jet. media
Special protective : Wear self contained breathing apparatus for fire fighting if equipment for fire-fighters necessary.
Further information : For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers.
Fire and explosion : Do not spray on an open flame or any other incandescent protection material. Keep away from open flames, hot surfaces and sources of ignition.
Hazardous decomposition : No data available. products
SECTION 6: Accidental release measures
Personal precautions : Use personal protective equipment.
Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal.
SECTION 7: Handling and storage
Handling
Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or
MSDS Number:100000014523 3/11
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exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations.
Advice on protection : Do not spray on an open flame or any other incandescent against fire and explosion material. Keep away from open flames, hot surfaces and sources of ignition.
Storage
Requirements for storage : No smoking. Keep container tightly closed in a dry and well- areas and containers ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
SECTION 8: Exposure controls/personal protection
Engineering measures Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a supplied-air NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.
Hand protection : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Eye wash bottle with pure water. Tightly fitting safety goggles.
Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : When using do not eat or drink. When using do not smoke.
MSDS Number:100000014523 4/11
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Wash hands before breaks and at the end of workday.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties Appearance Physical state : Liquid Color : Opaque Odor : Slight hydrocarbon
Safety data Flash point : > 77 °C (> 171 °F) Method: ASTM D 93 Lower explosion limit : 0.6 %(V)
Upper explosion limit : 5.1 %(V)
Oxidizing properties : No
Autoignition temperature : 225 °C (437 °F)
Molecular formula : Mixture
Molecular Weight : Not applicable
pH : 7
Boiling point/boiling range : 208 °C (406 °F)
Vapor pressure : < 1.00 MMHG at 20 °C (68 °F)
Relative density : 0.96
Density : 958.6 g/l
Water solubility : dispersible
Partition coefficient: n- : No data available octanol/water Viscosity, dynamic : 20,000 cP
Viscosity, kinematic : 71.821 mm2/s at 40 °C (104 °F)
Relative vapor density : 6.2 (Air = 1.0)
Evaporation rate : 0.1
SECTION 10: Stability and reactivity
MSDS Number:100000014523 5/11
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Chemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions Conditions to avoid : Heat, flames and sparks.
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Liquid HE® 150 XPT Skin irritation : May cause skin irritation.
Liquid HE® 150 XPT Eye irritation : May cause eye irritation.
Vapors may cause irritation to the eyes, respiratory system and the skin.
Liquid HE® 150 XPT Aspiration toxicity : May be fatal if swallowed and enters airways.
Liquid HE® 150 XPT Further information : Solvents may degrease the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Concentrations substantially above the TLV value may cause narcotic effects. Solvents may degrease the skin.
SECTION 12: Ecological information
Toxicity to fish
Distillates (petroleum), : LL0: 1,000 mg/l Hydrotreated light Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)
LL0: 1,000 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)
Toxicity to daphnia and other aquatic invertebrates
Distillates (petroleum), : EL0: 1,000 mg/l Hydrotreated light Exposure time: 48 h Species: Daphnia magna (Water flea)
EL0: 1,000 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)
MSDS Number:100000014523 6/11
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Toxicity to algae
Distillates (petroleum), : EL50: 1,000 mg/l Hydrotreated light Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)
EL50: 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)
Elimination information (persistence and degradability)
Biodegradability : No data available
Additional ecological : No data available information
SECTION 13: Disposal considerations
The information in this MSDS pertains only to the product as shipped. Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.
Product : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
SECTION 14: Transport information The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the MSDS and the bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Testing (ASTM D4206) has shown product does not sustain combustion.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. MSDS Number:100000014523 7/11
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IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
SARA 311/312 Hazards : Fire Hazard Acute Health Hazard
CERCLA Reportable : This material does not contain any components with a CERCLA Quantity RQ.
SARA 302 Reportable : This material does not contain any components with a SARA Quantity 302 RQ.
SARA 302 Threshold : SARA 302: No chemicals in this material are subject to the Planning Quantity reporting requirements of SARA Title III, Section 302.
SARA 304 Reportable : This material does not contain any components with a section Quantity 304 EHS RQ.
MSDS Number:100000014523 8/11
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SARA 313 Ingredients : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
Ozone-Depletion : This product neither contains, nor was manufactured with a Class I or Potential Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).
US State Regulations
Pennsylvania Right To Know : Distillates (petroleum), Hydrotreated light - 64742-47-8
New Jersey Right To Know : Distillates (petroleum), Hydrotreated light - 64742-47-8
California Prop. 65 : This product does not contain any chemicals known to the State Ingredients of California to cause cancer, birth, or any other reproductive defects.
Notification status Europe REACH : On the inventory, or in compliance with the inventory United States of America US.TSCA : Not On TSCA Inventory Canada DSL : This product contains one or several components that are not on the Canadian DSL nor NDSL. Australia AICS : Not in compliance with the inventory New Zealand NZIoC : Not in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : Not in compliance with the inventory
MSDS Number:100000014523 9/11
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SECTION 16: Other information
NFPA Classification : Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 1
1 0
Further information Legacy MSDS Number : CPC00467
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions.
The information in this MSDS pertains only to the product as shipped. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of LD50 Lethal Dose 50% Government Industrial Hygienists AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect Substances Level DSL Canada, Domestic Substances NFPA National Fire Protection Agency List NDSL Canada, Non-Domestic NIOSH National Institute for Occupational Substances List Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health Scenario Tool Administration EOSCA European Oilfield Specialty PEL Permissible Exposure Limit Chemicals Association EINECS European Inventory of Existing PICCS Philippines Inventory of Chemical Substances Commercial Chemical Substances MAK Germany Maximum Concentration PRNT Presumed Not Toxic Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act. IARC International Agency for Research TLV Threshold Limit Value on Cancer IECSC Inventory of Existing Chemical TWA Time Weighted Average MSDS Number:100000014523 10/11
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Substances in China ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act New Chemical Substances KECI Korea, Existing Chemical UVCB Unknown or Variable Composition, Inventory Complex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50%
MSDS Number:100000014523 11/11
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1. Identification Product identifier Mass Air Flow Sensor Cleaner Other means of identification Product code No. 05110 (Item# 1003729) Recommended use Mass air flow sensor cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Gases under pressure Compressed gas Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Reproductive toxicity (fertility) Category 2 Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard Category 1 Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 2 long-term hazard OSHA defined hazards Not classified. Label elements
Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. Causes eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility. Toxic to aquatic life with long lasting effects.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 1 / 12 Page 199 of 276 Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not apply while equipment is energized. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise Static accumulating flammable liquid can become electrostatically charged even in bonded and classified (HNOC) grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2-methylpentane 107-83-5 40 - 50 naphtha (petroleum), hydrotreated 64742-49-0 20 - 30 light 2,2,4-trimethylpentane 540-84-1 5 - 10 carbon dioxide 124-38-9 5 - 10 n-hexane 110-54-3 5 - 10 n-pentane 109-66-0 1 - 3 2,2-dimethylbutane 75-83-2 < 1 2,3-dimethylbutane 79-29-8 < 1 3-methylpentane 96-14-0 < 1 methanol 67-56-1 < 1 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. symptoms/effects, acute and Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing, delayed redness, and discomfort. Skin irritation. May cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 2 / 12 Page 200 of 276 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This the chemical product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without equipment/instructions risk. Containers should be cooled with water to prevent vapor pressure build up. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Remove all possible sources of ignition in the surrounding protective equipment and area. Many gases are heavier than air and will spread along ground and collect in low or confined emergency procedures areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch or walk through spilled material. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, see the product label. Conditions for safe storage, Level 3 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 3 / 12 Page 201 of 276 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2,2,4-trimethylpentane PEL 2350 mg/m3 (CAS 540-84-1) 500 ppm carbon dioxide (CAS PEL 9000 mg/m3 124-38-9) 5000 ppm methanol (CAS 67-56-1) PEL 260 mg/m3 200 ppm naphtha (petroleum), PEL 400 mg/m3 hydrotreated light (CAS 64742-49-0) 100 ppm n-hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm n-pentane (CAS 109-66-0) PEL 2950 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value 2,2-dimethylbutane (CAS STEL 1000 ppm 75-83-2) TWA 500 ppm 2,3-dimethylbutane (CAS STEL 1000 ppm 79-29-8) TWA 500 ppm 2-methylpentane (CAS STEL 1000 ppm 107-83-5) TWA 500 ppm 3-methylpentane (CAS STEL 1000 ppm 96-14-0) TWA 500 ppm carbon dioxide (CAS STEL 30000 ppm 124-38-9) TWA 5000 ppm methanol (CAS 67-56-1) STEL 250 ppm TWA 200 ppm n-hexane (CAS 110-54-3) TWA 50 ppm n-pentane (CAS 109-66-0) TWA 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2,2,4-trimethylpentane Ceiling 1800 mg/m3 (CAS 540-84-1) 385 ppm TWA 350 mg/m3 75 ppm 2,2-dimethylbutane (CAS Ceiling 1800 mg/m3 75-83-2) 510 ppm TWA 350 mg/m3 100 ppm 2,3-dimethylbutane (CAS Ceiling 1800 mg/m3 79-29-8) 510 ppm TWA 350 mg/m3 100 ppm 2-methylpentane (CAS Ceiling 1800 mg/m3 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 4 / 12 Page 202 of 276 US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 3-methylpentane (CAS Ceiling 1800 mg/m3 96-14-0) 510 ppm TWA 350 mg/m3 100 ppm carbon dioxide (CAS STEL 54000 mg/m3 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm methanol (CAS 67-56-1) STEL 325 mg/m3 250 ppm TWA 260 mg/m3 200 ppm naphtha (petroleum), TWA 400 mg/m3 hydrotreated light (CAS 64742-49-0) 100 ppm n-hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm n-pentane (CAS 109-66-0) Ceiling 1800 mg/m3 610 ppm TWA 350 mg/m3 120 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time
methanol (CAS 67-56-1) 15 mg/l Methanol Urine * n-hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedio Urine * n, without hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. n-hexane (CAS 110-54-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies methanol (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. n-hexane (CAS 110-54-3) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton/butyl. Other Wear appropriate chemical resistant clothing.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 5 / 12 Page 203 of 276 Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Observe any medical surveillance requirements. When using do not smoke. Always observe good considerations personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Colorless. Odor Alcoholic. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling 123 °F (50.6 °C) estimated range Flash point < 0 °F (< -17.8 °C) Tag Closed Cup Evaporation rate Very fast. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 0.9 % estimated (%) Flammability limit - upper 36 % estimated (%) Vapor pressure 3201.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.7 estimated Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature 489.2 °F (254 °C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 93.8 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Carbon oxides. Formaldehyde. products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 6 / 12 Page 204 of 276 Eye contact Causes eye irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness. physical, chemical and Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing, toxicological characteristics redness, and discomfort. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Components Species Test Results 2,2,4-trimethylpentane (CAS 540-84-1) Acute Inhalation LC50 Rat 118 mg/l, 4 Hours naphtha (petroleum), hydrotreated light (CAS 64742-49-0) Acute Dermal LD50 Rabbit > 2000 mg/kg n-hexane (CAS 110-54-3) Acute Dermal LD50 Rabbit > 1300 mg/kg Oral LD50 Rat 15840 mg/kg n-pentane (CAS 109-66-0) Acute Inhalation Vapor LC50 Rat 364 mg/m3, 4 Hours Oral LD50 Rat > 2000 mg/kg
* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes eye irritation. irritation Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity Suspected of damaging fertility. Specific target organ toxicity - May cause drowsiness and dizziness. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 7 / 12 Page 205 of 276 Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Components Species Test Results 2-methylpentane (CAS 107-83-5) Aquatic Acute Crustacea EC50 Daphnia 1 - 10 mg/l, 48 hours Fish LC50 Fish 1 - 10 mg/l, 96 hours methanol (CAS 67-56-1) Aquatic Fish LC50 Rainbow trout,donaldson trout 18000 - 20000 mg/l, 96 hours (Oncorhynchus mykiss) Acute Crustacea EC50 Water flea (Daphnia magna) > 10000 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 18000 - 20000 mg/l, 96 hours (Oncorhynchus mykiss) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) Aquatic Acute Crustacea EC50 Daphnia 1 - 10 mg/l, 48 hours Fish LC50 Fish 1 - 10 mg/l, 96 hours n-hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2,2,4-trimethylpentane 5.18 2,2-dimethylbutane 3.82 2,3-dimethylbutane 3.42 2-methylpentane 3.74 3-methylpentane 3.6 methanol -0.77 n-hexane 3.9 n-pentane 3.39 Bioconcentration factor (BCF) naphtha (petroleum), hydrotreated light 10 - 25000 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or residues / unused products dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Contents under pressure. Do not puncture, incinerate or crush. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 8 / 12 Page 206 of 276 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols, flammable, Limited Quantity Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s) 2.1 Packing group Not applicable. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions N82 Packaging exceptions 306 Packaging non bulk None Packaging bulk None IATA UN number UN1950 UN proper shipping name Aerosols, flammable, Limited Quantity Transport hazard class(es) Class 2.1 Subsidiary risk - Packing group Not applicable. ERG Code 10L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Allowed with restrictions. aircraft Cargo aircraft only Allowed with restrictions. IMDG UN number UN1950 UN proper shipping name AEROSOLS, Limited Quantity Transport hazard class(es) Class 2.1 Subsidiary risk - Packing group Not applicable. Environmental hazards Marine pollutant No. EmS Not available. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. 15. Regulatory information US federal regulations All components are on the U.S. EPA TSCA Inventory List. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-hexane (CAS 110-54-3) CERCLA Hazardous Substance List (40 CFR 302.4) 2,2,4-trimethylpentane (CAS 540-84-1) Listed. methanol (CAS 67-56-1) Listed. n-hexane (CAS 110-54-3) Listed. n-pentane (CAS 109-66-0) Listed. CERCLA Hazardous Substances: Reportable quantity 2,2,4-trimethylpentane (CAS 540-84-1) 1000 LBS methanol (CAS 67-56-1) 5000 LBS
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 9 / 12 Page 207 of 276 n-hexane (CAS 110-54-3) 5000 LBS n-pentane (CAS 109-66-0) 100 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 2,2,4-trimethylpentane (CAS 540-84-1) n-hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) n-pentane (CAS 109-66-0) Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Not regulated. Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Immediate Hazard - Yes Hazard categories Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely No hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 2,2,4-trimethylpentane (CAS 540-84-1) methanol (CAS 67-56-1) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-hexane (CAS 110-54-3) n-pentane (CAS 109-66-0) US. New Jersey Worker and Community Right-to-Know Act 2,2,4-trimethylpentane (CAS 540-84-1) 2,2-dimethylbutane (CAS 75-83-2) 2,3-dimethylbutane (CAS 79-29-8) 2-methylpentane (CAS 107-83-5) carbon dioxide (CAS 124-38-9) methanol (CAS 67-56-1) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-hexane (CAS 110-54-3) n-pentane (CAS 109-66-0) US. Massachusetts RTK - Substance List 2,2,4-trimethylpentane (CAS 540-84-1) 2,2-dimethylbutane (CAS 75-83-2) 2,3-dimethylbutane (CAS 79-29-8) 2-methylpentane (CAS 107-83-5) 3-methylpentane (CAS 96-14-0) carbon dioxide (CAS 124-38-9) methanol (CAS 67-56-1) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-hexane (CAS 110-54-3) n-pentane (CAS 109-66-0) US. Pennsylvania Worker and Community Right-to-Know Law 2,2,4-trimethylpentane (CAS 540-84-1) 2,2-dimethylbutane (CAS 75-83-2) 2,3-dimethylbutane (CAS 79-29-8) 2-methylpentane (CAS 107-83-5) 3-methylpentane (CAS 96-14-0) carbon dioxide (CAS 124-38-9) methanol (CAS 67-56-1) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-hexane (CAS 110-54-3) n-pentane (CAS 109-66-0)
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 10 / 12 Page 208 of 276 US. Rhode Island RTK 2,2,4-trimethylpentane (CAS 540-84-1) carbon dioxide (CAS 124-38-9) methanol (CAS 67-56-1) naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-hexane (CAS 110-54-3) n-pentane (CAS 109-66-0) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin methanol (CAS 67-56-1) Listed: March 16, 2012 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 95 % 51.100(s)) Consumer products Not regulated (40 CFR 59, Subpt. C) State Consumer products Not regulated VOC content (CA) 95 % VOC content (OTC) 95 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 06-30-2014 Revision date 08-07-2017 Prepared by Allison Yoon Version # 02 Further information CRC # 599C/1002635 HMIS® ratings Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 4 Instability: 0
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 11 / 12 Page 209 of 276 NFPA ratings 4 2 0
Disclaimer The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc.. Revision Information This document has undergone significant changes and should be reviewed in its entirety.
Material name: Mass Air Flow Sensor Cleaner SDS US No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014 12 / 12 Page 210 of 276 SAFETY DATA SHEET
Revision Date 03-Apr-2017 Version 2.01
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Microban Milgo Plus Product code W.20403
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Disinfectant Cleaner Restrictions on use Professional Use Only EPA Registration Number 70385-6
Other information This SDS is reviewed as an US EPA registered product.
1.3 Details of the supplier of the safety data sheet
Supplier Legend Brands ProRestore Products 15180 Josh Wilson Road Burlington, WA 98233 800-932-3030
1.4 Emergency telephone number
Emergency telephone number INFOTRAC 1-800-535-5053 (North America) 1-352-323-3500 (International)
2. Hazards identification
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910.1200
OSHA Regulatory Status This product is regulated by EPA- not subject to 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1
2.2 Label elements
Signal Word Danger
Hazard Statements Causes severe skin burns and eye damage
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Precautionary Statements - Prevention Do not breathe dusts or mists Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response Immediately call a POISON CENTER or doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Wash contaminated clothing before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
Precautionary Statements - Storage Store locked up
Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
2.3. Other Hazards Hazards not otherwise classified (HNOC) Not Applicable
2.4 Other information
Not Applicable
Unknown Acute Toxicity 3.30002499% of the mixture consists of ingredient(s) of unknown toxicity
3. Composition/Information on Ingredients
Substance Mixture
Chemical Name CAS No. Weight-% Ammonium chloride compound 68424-85-1 1 - 5 TETRASODIUM EDTA 64-02-8 1 - 5 Ethanol 64-17-5 1 - 5 The exact percentage (concentration) of composition has been withheld as a trade secret.
4. First aid measures
4.1 Description of first-aid measures
General advice No information available.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash skin with soap and water.
Inhalation Remove to fresh air.
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Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms See Section 2.2, Label Elements and/or Section 11, Toxicological effects.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media None.
5.2 Special hazards arising from the substance or mixture
Special Hazard Immediately place absorbent material in a sealed water-filled metal container to avoid spontaneous combustion of absorbent material contaminated with this product.
Hazardous Combustion Products No information available.
Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None.
5.3 Advice for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation, especially in confined areas.
6.2 Environmental precautions
See Section 12 for additional Ecological information.
6.3 Methods and materials for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
7. Handling and storage
7.1 Precautions for safe handling
Hygiene measures Handle in accordance with good industrial hygiene and safety practice.
7.2 Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
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Page 213 of 276 W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017 ______Materials to Avoid No materials to be especially mentioned.
8. Exposure controls/personal protection
8.1 Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL British Columbia Alberta Quebec Ontario TWAEV Ethanol STEL: 1000 ppm TWA: 1000 ppm STEL: 1000 ppm TWA: 1000 ppm TWA: 1000 ppm STEL: 1000 ppm 64-17-5 TWA: 1900 mg/m3 TWA: 1880 mg/m3 TWA: 1880 mg/m3
8.2 Appropriate engineering controls
Engineering Measures Showers Eyewash stations Ventilation systems.
8.3 Individual protection measures, such as personal protective equipment
Eye/Face Protection Safety glasses with side-shields.
Skin and body protection Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as appropriate.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.
Hygiene measures See section 7 for more information
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Page 214 of 276 W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017 ______9. Physical and chemical properties
9.1 Information on basic physical and chemical properties Physical state Liquid Appearance Clear liquid Color Colorless
Odor Slight Odor Threshold No information available
Property Values Remarks • Methods pH 11.5 - 12.5 Melting/freezing point No information available Boiling point/boiling range No information available Flash Point Not Applicable Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limits in Air upper flammability limit No information available lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 1.01 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available
Explosive properties No information available Oxidizing Properties No information available
9.2 Other information Volatile organic compounds (VOC) 0.06 lb/gal content
10. Stability and Reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions
10.3 Possibility of hazardous reactions
None under normal processing.
10.4 Conditions to Avoid
Extremes of temperature and direct sunlight.
10.5 Incompatible Materials
None known based on information supplied.
10.6 Hazardous Decomposition Products
None known based on information supplied.
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11. Toxicological information
11.1 Acute toxicity
Numerical measures of toxicity: Product Information
The following values are calculated based on chapter 3.1 of the GHS document
Unknown Acute Toxicity 3.30002499% of the mixture consists of ingredient(s) of unknown toxicity
Oral LD50 11,311.00 mg/kg Dermal LD50 13,009.00 mg/kg LC50 (Dust/Mist) 78.10 mg/l LC50 (Vapor) 545.00 mg/l
Numerical measures of toxicity: Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Ammonium chloride compound 344 mg/kg ( Rat ) 340 mg/kg ( Rabbit ) - 68424-85-1 TETRASODIUM EDTA 1658 mg/kg ( Rat ) - - 64-02-8 Ethanol - - = 124.7 mg/L ( Rat ) 4 h 64-17-5
11.2 Information on toxicological effects
Skin corrosion/irritation Product Information • No information available Component Information • No information available
Serious eye damage/eye irritation Product Information • Causes serious eye damage Component Information • No information available
Respiratory or skin sensitization Product Information • No information available Component Information • No information available
Germ cell mutagenicity Product Information • No information available Component Information • No information available
Carcinogenicity Product Information • No information available Component Information • No information available
Reproductive toxicity
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Page 216 of 276 W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017 ______Product Information • No information available Component Information • No information available
STOT - single exposure No information available
STOT - repeated exposure No information available
Other adverse effects Product Information • No information available Component Information • No information available
Aspiration hazard Product Information • No information available Component Information • No information available
12. Ecological information
12.1 Toxicity
Ecotoxicity No information available
8.075 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Ecotoxicity effects Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates TETRASODIUM EDTA EC50: 72 h Desmodesmus LC50: 96 h Lepomis macrochirus 41 - 64-02-8 subspicatus 1.01 mg/L mg/L static LC50: 96 h Pimephales promelas 59.8 mg/L static Ethanol - LC50: 96 h Oncorhynchus mykiss LC50: 48 h Daphnia magna 9268 - 64-17-5 12.0 - 16.0 mL/L static LC50: 96 h 14221 mg/L EC50: 48 h Daphnia Pimephales promelas 100 mg/L magna 2 mg/L Static static LC50: 96 h Pimephales promelas 13400 - 15100 mg/L flow-through
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
Discharge into the environment must be avoided Chemical Name log Pow Ethanol -0.32 64-17-5
12.4 Mobility in soil
No information available.
12.5 Other adverse effects
Do not discharge effuent containing this product into lakes, streams, ponds, estuaries, oceans or other water unless in accordance with the requirments of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been
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Page 217 of 276 W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017 ______notified in writing prior to the discharge. Do not discharge effuent containing this product to sewer systems withour previously notifying the local sewage treatment plant authority. For guidance, conatct your State water board or Regional office of the EPA.
13. Disposal Considerations
13.1 Waste treatment methods
Disposal of wastes: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes can not be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. 70385-6 (containers equal to or less than 5 gallons) Container Disposal: Non-refillable container. Do Not reuse or refill this container. Triple rinse container (or equivalent) promptly after emptying. Triple rinse as follows: empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture and dispose of in sanitary landfill, or by incineration, or, if allowed by state and local authorites, by burning. If burned, stay out of smoke. 70385-6 for container over 5 gallons Container Disposal: Non-refillable container. Do Not reuse or refill this container. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. Then offer for recycling if avaiable or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local, by burning. If burned, stay out of smoke. Contaminated packaging: Do not reuse container.
14. Transport Information
DOT Not regulated
MEX Not regulated
IMDG Not regulated
IATA Not regulated
15. Regulatory information 15.1 International Inventories
TSCA Complies DSL Complies EINECS/ELINCS Complies ENCS - IECSC Complies KECL Complies PICCS Complies AICS Complies NZIoC -
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL - Canadian Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
15.2 U.S. Federal Regulations
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SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
15.3 Pesticide Information
U.S. EPA Pesticide Information EPA Pesticide Registration Number 70385-6 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label DANGER Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through the skin. Do not get in eyes, on skin, or on clothing. Wear goggles or face shield, protective clothing and rubber gloves when handling. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse.
15.4 U.S. State Regulations
California Proposition 65 This product contains the following Proposition 65 chemicals:
Chemical Name California Prop. 65 Ethanol - 64-17-5 Carcinogen Developmental METHANOL - 67-56-1 Developmental
16. Other information
NFPA Health Hazard 3 Flammability 0 Instability 0 Physical and chemical hazards - HMIS Health Hazard 3 Flammability 0 Physical Hazard 0 Personal protection X
Legend: ACGIH (American Conference of Governmental Industrial Hygienists) Ceiling (C) DOT (Department of Transportation) EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) International Air Transport Association (IATA) International Maritime Dangerous Goods (IMDG) NIOSH (National Institute for Occupational Safety and Health) NTP (National Toxicology Program) OSHA (Occupational Safety and Health Administration of the US Department of Labor) PEL (Permissible Exposure Limit) Reportable Quantity (RQ) Skin designation (S*) STEL (Short Term Exposure Limit) TLV® (Threshold Limit Value) TWA (time-weighted average)
Revision Date 03-Apr-2017 Revision Note No information available Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
______03-Apr-2017 - W.20403 - 2.01 - AGHS - English - Page 9 / 10
Page 219 of 276 W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017 ______relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 220 of 276 Safety Data Sheet Northex Anti Freeze
SECTION 1: PRODUCT AND COMPANY INFORMATION
Manufacturer Cadillac Oil Company, 13650 Helen, Detroit, Michigan 48212 · (313) 365-6200
Product Family Anti-Freeze Trade Name(s) Northex Anti-Freeze Recommended Uses Freeze prevention
24-Hour Emergency Phone Number, Chem-Tel: (800) 255-3924
SECTION 2: HAZARD IDENTIFICATION
EMERGENCY OVERVIEW HMIS HEALTH *2 Physical Hazards Not Classified FLAMMABILTY 1 PHYSICAL HAZARD 0 Health Hazards See Below PERSONAL PROTECTION See Section 8 Signal Word WARNING
Acute Toxicity Oral Category 4 – Harmful if swallowed
Precautionary Statements Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/ physician. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number Percentage Ethylene glycol 107-21-1 >90
SECTION 4: FIRST AID MEASURES
Skin Contact Remove contaminated clothing. Wash area of contact with soap and water. Wash clothing before reuse. Get medical attention if irritation occurs and persists. Eye Contact Remove contact lenses. Flush with water until all traces of material are gone. Eyelids should be held away from the eyeball to ensure thorough rinsing. Get medical attention if irritation persists. Inhalation Remove affected person from source of exposure. Get medical attention if discomfort persists. Give artificial respiration if not breathing. Ingestion Do not induce vomiting because of danger of aspiration into lungs. If spontaneous vomiting occurs, monitor for breathing difficulty. Get medical attention.
SECTION 5: FIREFIGHTING MEASURES
Basic Firefighting Procedures Use water spray, dry chemical, foam or CO2 to extinguish fire. Use a water spray to cool fire-exposed containers, structures and to protect personnel. Exposed firefighters should wear MSHA/NIOSH approved self-contained breathing apparatus with full-face mask and full protective equipment. Flush spills away from sources of ignition. Unusual Fire and Explosion Hazards Combustible at high temperatures. Irritating or toxic substances may be emitted.
Cadillac Oil Co - Detroit, MI Date Prepared or Revised: October 9, 2014 Page 1 of 3
Page 221 of 276 Safety Data Sheet Northex Anti Freeze
SECTION 6: ACCIDENTAL RELEASE MEASURES Refer to Section 8: Exposure Control and Personal Protection
Emergency Action Isolate release area and keep unnecessary people away. Exercise caution regarding personnel safety and exposure. Spill/Leak Procedure Floor and surfaces may be slippery. Dike with sand or other noncombustible material. Flush area with water provided runoff does not enter drain or sewer; use absorbent material and dispose of properly.
SECTION 7: HANDLING AND STORAGE Refer to Section 8: Exposure Control and Personal Protection
Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Do not ingest. For industrial use only. Use good hygiene practices when handling product, including changing and laundering work clothes after use. Ground equipment as required. The shipping and storage container is not designed to be pressurized. Do not use pressure to empty the container as it may rupture with explosive force. Containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. Empty containers may contain residue or vapors. Do not cut, grind, drill, weld or reuse containers. Storage Store product in closed containers in a well-ventilated area away from heat, sources of ignition and incompatibles. Do not store in unlabeled containers.
SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION
Component ACGIH TLV OSHA Ethylene glycol 100 ppm 50 ppm / 125 mg/m3
Engineering Controls Use appropriate ventilation to maintain airborne concentration limits below recommended exposure limits. Eye and Face Protection Wear safety glasses; use face shield if splashing is possible. Skin Protection Oil or chemical resistant gloves (e.g. nitrile rubber) should be used to avoid prolonged contact. Respiratory Protection Not normally needed. A NIOSH or MSHA approved respirator should be used in areas with high vapor concentrations or misting.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State Fluorescent liquid Flash Point (°F/°C) 254 °F Specific Gravity (Water=1) See data sheet Upper/Lower Flammability Limits (Vol. %) Not Determined pH 7.5 – 11.0 Auto-ignition Temperature (°F/°C) Not Determined Solubility in Water Complete Decomposition Temperature (°F/°C) Not Determined Odor Characteristic Vapor Pressure (kPa at 20°C / 68°F) Not Determined Odor Threshold Not Determined Vapor Density (Air-=1) >1 Melting/Freezing Point (°F/°C) Not Determined Partition Coefficient (n-octanol/water) Not Determined Boiling Range (°F/°C) Not Determined Viscosity (40°C mm2/s) or (cSt at 40°C) Not Determined Initial Boiling Point (°F/°C) Not Determined Critical Temperature Not Determined Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Those should be requested separately.
Cadillac Oil Co - Detroit, MI Date Prepared or Revised: October 9, 2014 Page 2 of 3
Page 222 of 276 Safety Data Sheet Northex Anti Freeze
SECTION 10: STABILITY AND REACTIVITY
Reactivity Does not react under normal conditions of use. Chemical Stability Stable under normal conditions of use. Stability/Incompatibility Avoid contact with strong oxidizers. Conditions to Avoid Open flame or sources of ignition. Hazardous Reactions/Decomposition Products Does not decompose under normal conditions; combustion may produce CO, CO2, volatile hydrocarbons and other possibly toxic gases.
SECTION 11: TOXICOLOGICAL INFORMATION
Likely Routes of Exposure Skin, eyes Acute Effects LD50 oral (rat) 4,700 mg/kg; LD50 dermal (rabbit) 10,626 mg/kg. Excessive contact, inhalation or ingestion may cause irritation or discomfort. Refer to Sections 2 and 4 for recommended actions. Medical conditions aggravated by long term exposure Eye, skin and respiratory disorders. Chronic Effects Any acute symptoms may be aggravated. Refer to Sections 2 and 4 for recommended actions. Symptoms Not Available. Carcinogenicity Ethylene glycol has not been found to be a carcinogen by NTP, IARC or OSHA.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity Toxicity levels for various aquatic organisms have been found to be high. Persistence and Biodegradability Not Determined Bioaccumulative Potential Does not bioaccumulate Mobility in Soil Not Determined
SECTION 13: DISPOSAL CONSIDERATION
Dispose of this product in compliance with all applicable federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
DOT Environmentally hazardous substance, liquid, N.O.S. (Ethylene glycol); UN3082, Cl 9, PG III
SECTION 15: REGULATORY INFORMATION
Chemical Inventory Lists All ingredients are listed on TSCA and DSL SARA (311/312) Reportable Hazard Categories Acute health hazard, chronic health hazard SARA Section 313 Ethylene glycol (CAS 107-21-1) – 95%
SECTION 16: OTHER INFORMATION
Notice The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by the vendor for any damage or injury resulting from abnormal use, from failure to adhere to recommended practices, or from any hazards inherent in the nature of the product.
This SDS complies with the requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200
Prepared By Cadillac Oil Co. Laboratory
Cadillac Oil Co - Detroit, MI Date Prepared or Revised: October 9, 2014 Page 3 of 3
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Section 01 - Identification Product Identifier On and Gone – Mould and Mildew Stain Remover.
Product Use and Restrictions on Use Removal of mold stains.
24-Hour Emergency Phone Phone: 1 (306) 664 – 2522 Alternative Phone: 1 (800) 387-7503
Section 02 - Hazard Identification
GHS-Classification Skin Corrosion/Irritation Category 1A Serious Eye Damage/Eye Irritation Category 1 Acute Aquatic Toxicity Category 1 Chronic Aquatic Toxicity Category 1 STOT-Single Exposure Category 3
Signal Word Danger Hazard Statements Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. Very toxic to aquatic life with long lasting effects.
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Physical Hazards Corrosive To Metals Category 1
Signal Word Warning
Hazard Statement May be corrosive to metals. Pictograms
Precautionary Statements Store locked up. Keep only in original container. Store container tightly closed in well-ventilated place. Store in corrosive resistant/container with a resistant inliner. Use only outdoors or in well-ventilated area. Absorb spillage to prevent material damage. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Do not breathe dust or mist. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. W ash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Avoid release to the environment. Collect spillage.
Section 03 - Composition / Information on Ingredients
Chemical Name CAS Number Weight % Unique Identifiers Sodium Hypochlorite 6% 7681-52-9 95% None Surfactant Solution Mixture 5% None
Common Name and None Synonyms
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Section 04 - First Aid Measures Inhalation Can release corrosive chlorine gas Rem Remove victim to fresh air. Give artificial respiration only if breathing has stopped. brea If breathing is difficult, give oxygen. DO NOT allow victim to move about pers unnecessarily. Symptoms of pulmonary edema can be delayed up to 48 hours after exposure. Seek immediate medical attention.
As quickly as possible, flush with lukewarm, gently flowing water for at least 20 Skin Contact / Absorption Rem minutes, or until the chemical is removed. If irritation persists, repeat flushing. med Under running water, remove contaminated clothing, shoes and leather goods. Completely decontaminate clothing, shoes and leather goods before reuse, or discard. Obtain medical advice immediately.
Eye Contact Contact lenses should never be worn when working with this product. Flush Cont immediately with lukewarm, gently flowing water for at least 20-30 minutes. Forcibly imm hold eyelids apart to ensure complete irrigation of eye tissue. DO NOT com INTERRUPT FLUSHING. Take care not to rinse contaminated water into the unaffected eye or onto the face. Seek immediate medical attention.
Ingestion NEVER give anything by mouth if victim is rapidly losing consciousness, is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 240 to 300 mL (8 to 10 oz.) of water to dilute material in stomach. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Rinse mouth and repeat administration of water. Quickly transport victim to an emergency care facility.
Additional Information Provide general supportive measures (comfort, warmth, rest). Consult a doctor and/or the nearest Poison Control Centre for all exposures except minor instances of inhalation or skin contact.
SectionSuitable E 05xtin -g uishingFire Fighting Media MeasuresSodi um hypochlorite solutions do not burn. Extinguish fire using extinguishing agents suitable for the surrounding fire and not contraindicated for use with sodium hypochlorite. Cool exposed containers with water.
Unsuitable Extinguishing Media DO NOT use dry chemical fire extinguishing agents containing ammonium compounds (such as some A:B:C agents), since an explosive compound can be formed.
Specific Hazards Arising From the Chlorine, hydrogen chloride gas, oxygen gas and disodium oxide. Chemical NOTE: releases chlorine when heated above 35°C. Special Protective Equipment and Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Precautions for Fire-Fighters The decomposition products of sodium hypochlorite, such as chlorine and hydrogen chloride are extremely hazardous to health. Do not enter without wearing specialized protective equipment suitable for the situation. Firefighter's normal protective equipment (Bunker Gear) will not provide adequate protection.
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Further Information Sodium hypochlorite solutions will not accumulate static charge. Since these solutions do not burn, they will not be ignited by a static discharge. Sodium hypochlorite is not combustible (will not burn). It decomposes when heated, giving off corrosive chlorine gas and hydrogen chloride. Solutions decompose when exposed to sunlight, giving off oxygen gas. However, the amount of oxygen produced is not sufficient to cause combustion. Explosive decomposition may occur under fire conditions and closed containers may rupture violently due to rapid decomposition, if exposed to fire or excessive heat for a sufficient period of time.
Section 06 - Accidental Release Measures Personal Precautions / Protective Wear appropriate personal protective equipment. Ventilate area. Only enter area Equipment / Emergency Procedures with PPE. Stop or reduce leak if safe to do so. Prevent material from entering sewers. Flush with water to remove any residue.
Environmental Precautions Harmful to aquatic life in very low concentrations. May be dangerous if it enters water intakes. Prevent material from entering sewers or confined spaces. Notify local health and wildlife officials. Notify operators of nearby water intakes. Methods and Materials for Containment Do not touch spilled material. Prevent material from entering into soil, ditches, and Cleaning Up sewers, waterways and/or groundwater.
Contain spill with earth, sand or absorbent material which does not react with spilled material.
SMALL SPILLS: Soak up spill with absorbent material which does not react with spilled chemical [sawdust, Cob grit, Zorb-all®. Hazorb®. Put material in suitable, covered, labelled containers. Flush area with water [AFTER material has been cleaned up with an absorbent material]. Contaminated absorbent material may pose the same hazards as the spilled product. Collect in suitable and properly labeled containers.
LARGE SPILLS: Contact fire and emergency services and supplier for advice.
Section 07 - Handling and Storage Precautions for Safe Handling This material is a CORROSIVE liquid. This material is a slipping hazard. Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Avoid generating mists. Prevent the release of mists into the workplace air. Inspect containers for damage or leaks before handling. Label containers. Never add water to a corrosive. Always add corrosives to water. When mixing with water, stir small amounts in slowly. Use cold water to prevent excessive heat generation. Never return contaminated material to its original container. Have suitable emergency equipment for fires, spills and leaks readily available.
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Conditions for Safe Storage Store in a cool, dry, well-ventilated area, out of direct sunlight and away from heat sources. Strong solutions (greater than 10% available chlorine) may slowly give off chlorine during storage, especially when warm (above 18°C). Vent caps may be required to prevent a build-up of pressure that could cause containers to burst. Always store in original labelled container. Keep containers tightly closed when not in use and when empty. Empty containers may contain hazardous residues. Protect label and keep it visible. Keep away from incompatible materials, such as acids, metals, primary or aromatic amines, ammonia and ammonia salts. – see section 10 for more information.
Section 08 - Exposure Controls / Personal Protection
Exposure Limit(s) Component Regulation Type of Listing Value Sodium hypochlorite AIHA WEEL-STEL 2mg/m3 (15 min) Chlorine ACGIH TLV-TWA 0.5 ppm
Engineering Control(s)
Ventilation Requirements Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions must be provided in accordance with all fire codes and regulatory requirements. Supply sufficient replacement air to make up for air removed by exhaust systems.
Other Emergency shower and eyewash must be available and tested in accordance with regulations and be in close proximity.
Protective Equipment
Eyes/Face Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury.
Hand Protection Impervious gloves of chemically resistant material (rubber or PVC) should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.
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Skin and Body Protection Body suite, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.
Guidelines for sodium hypochlorite, less than 30%: RECOMMENDED (resistance to breakthrough longer than 8 hours): Butyl rubber, Natural rubber, Neoprene rubber, Nitrile rubber, Polyethylene, Polyvinyl chloride, Viton(TM), Silver Shield/4H(TM) (polyethylene/ethylene vinyl alcohol), Tychem(TM) SL (Saranex(TM)).
There is evidence that this material can cause serious skin injury (e.g. corrosion or absorption hazard). Recommendations are NOT valid for very thin natural rubber, neoprene, nitrile and PVC gloves (0.3 mm or less). Resistance of specific materials can vary from product to product. Breakthrough times are obtained under conditions of continuous contact, generally at room temperature. Evaluate resistance under conditions of use and maintain clothing carefully.
Impervious boots of chemically resistant material should be worn at all times. No special footwear is required other than what is mandated at place of work.
Respiratory Protection No specific guidelines are available. Contact chemical manufacturer/supplier for advice. Respiratory protection guidelines for chlorine gas are available.
NIOSH RECOMMENDATIONS FOR CHLORINE CONCENTRATIONS IN AIR: Up to 5 ppm: (APF = 10) Chemical cartridge respirator*; SAR*.
Up to 10 ppm: (APF = 25) SAR operated in a continuous-flow mode;* Powered, air-purifying respirator with cartridge(s)*. (APF = 50) Chemical cartridge respirator with a full facepiece and cartridge(s); Air- purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back- mounted canister; SCBA with a full facepiece; Full facepiece SAR.
The respirator use limitations specified by the approving agency and the manufacturer must be observed. Recommendations apply only to NIOSH approved respirators. Air-purifying respirators do not protect against oxygen-deficient atmospheres.
A NIOSH-approved respirator suitable for chlorine is recommended. Where a higher level of protection is required, use a self-contained breathing apparatus.
Thermal Hazards Not Available
Section 09 - Physical and Chemical Properties
Appearance Physical State Liquid
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Colour Clear, greenish-yellow solution. Odour Strong chlorine odour. Odour Threshold Not Available
Property pH 12.6 Melting Point/Freezing Point Not Available Initial Boiling Point and Boiling Range Slowly decomposes above 40°C Flash Point Not Applicable Evaporation Rate Not Available Flammability Non-Flammable Upper Flammable Limit Not Applicable Lower Flammable Limit Not Applicable Vapour Pressure (mm Hg, 20oC) Not Available Vapour Density (Air=1) Not Available Relative Density Not Available Solubility(ies) Not Available Partition Coefficient: n-octanol/water Not Available Auto-ignition Temperature Not Available Decomposition Temperature Slowly decomposes above 40°C Viscosity Not Available Explosive Properties Pressure buildup in containers could result in an explosion when heated or in contact with acidic fumes. Vigorous reaction with oxidizable organic materials may result in a fire.
Specific Gravity (Water=1) 1.09 % Volatiles by Volume Not Available Formula Not Available Molecular Weight Not Available
Section 10 - Stability and Reactivity Reactivity Sodium hypochlorite solutions decompose slowly at normal temperatures releasing low concentrations of corrosive chlorine gas. Decomposition is influenced by temperature, concentration, pH, ionic strength, exposure to light and the presence of metals, such as copper, nickel or cobalt, metal oxides, e.g. rust and other impurities, such as acids and amines. Hypochlorites react with urea to form nitrogen trichloride which explodes spontaneously in air.
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Chemical Stability Unstable at temperatures above 40°C, in sunlight, and in contact with acid.
Possibility of Hazardous Reactions Hazardous polymerization will not occur. Reacts exothermically with acids. Reacts with ammonia, amines and ammonia salts to produce chloramines. Decomposes on heating to produce chlorine gas.
Conditions to Avoid Heat, sunlight, strong acids, the presence of metals and other impurities.
Incompatible Materials PRIMARY AMINES: (e.g. ethylamine) and AROMATIC AMINES (e.g. aniline) - react to form explosively unstable N-mono- or di- chloramines. AMMONIUM SALTS: (e.g. ammonium sulfate and ammonium nitrate), AMMONIA, UREA or PHENYLACETONITRILE: - form explosive nitrogen trichloride, if acid is present. ACIDS: (especially hydrochloric acid) - contact releases corrosive chlorine gas. METALS: (especially copper, aluminum, nickel, and cobalt) - accelerate decomposition. REDUCING AGENTS: (e.g. hydrides, such as lithium aluminum hydride) - cause a violent reaction. ETHYLENEIMINE (AZIRIDINE): - form the explosive N- chloroethyleneimine. METHANOL: - can form explosive methyl hypochlorite, especially in the presence of acids or other etherification catalysts. FORMIC ACID: - becomes explosive at 55°C. FURFURALDEHYDE: - drop wise addition of the aldehyde to a 10% excess of sodium hypochlorite solution at 20-25°C can lead to a violent explosion. ETHANEDIOL (ETHYLENE GLYCOL): erupts violently after an induction period of about 4 to 8 minutes. SODIUM ETHYLENEDIAMINETETRACETATE (EDTA) SOLUTION and SODIUM HYDROXIDE SOLUTION: mixing the three solutions leads to vigorous foaming decomposition. Hazardous Decomposition Products Chlorine (by reaction with acids), oxygen (by reaction with nickel, copper, tin, manganese, iron), sodium chloride, sodium chlorate, with increased temperature.
Section 11 - Toxicological Information
Acute Toxicity
Component Oral LD50 Dermal LD50 Inhalation LC50 Sodium Hypochlorite 8910mg/kg (rat, undiluted) > 10,000mg/kg (rabbit, > 5250mg/m3 (rat, 4hr undiluted) exposure, concentration not specified) ~7540mg/kg (female mouse, 50% solution ) Chronic Toxicity – Carcinogenicity Component IARC Sodium Hypochlorite Group 3: Not classifiable as to its carcinogenicity to humans. [hypochlorite salts]
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Skin Corrosion/Irritation Very dilute solutions have caused negligible irritation, while more concentrated solutions have caused corrosive injury to skin and eyes. Ingestion Burning of the mouth and throat, abdominal cramps, nausea, vomiting, diarrhea, shock. May lead to convulsions, coma, and even death. Inhalation Irritant of the nose and throat, causing coughing, difficulty breathing, and pulmonary edema. Serious Eye Damage/Irritation May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur. Respiratory or Skin Sensitization Negative results (0/20 guinea pigs sensitized) have been obtained for 8% sodium hypochlorite solution in a skin sensitization test. Insufficient details are available to evaluate a report of a positive result (positive reactions in 2/10 animals) obtained using 6% sodium hypochlorite (pH 11.2) with the guinea pig ear swelling test for non-immunological contact urticaria. Germ Cell Mutagenicity The available information does not suggest that sodium hypochlorite is mutagenic. Reproductive Toxicity There is insufficient information available to draw conclusions. STOT-Single Exposure May cause respiratory irritation. STOT-Repeated Exposure Not Available Aspiration Hazard Prolonged or repeated overexposure causes lung damage. Synergistic Materials Not Available
Section 12 – Ecological Information
Ecotoxicity Component Toxicity to Algae Toxicity to Fish Toxicity to Daphnia and Other Aquatic Invertebrates
Sodium Hypochlorite Not Available LC50(Salmo gairdneri, 96hr): LC50(Daphnia magna, 96hr): 0.172mg/L 2.1mg/L
Not Available LC50(Ictalurus punctatus, LC50(Gammarus fasciatus, 96hr): 0.156mg/L 96hr): 4mg/L Biodegradability Not Available
Bioaccumulation No evidence to support any rating.
Mobility Not Available
Other Adverse Effects Not Available
Section 13 - Disposal Considera tions Waste From Residues/Unused Products Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act.
Contaminated Packaging Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act.
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SectionUN Numb er14 - Transport InformationUN 3266
UN Proper Shipping Name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Transport Hazard Class(es) 8
Packaging Group III Environmental Hazards Listed as a marine pollutant under Canadian TDG Regulations Schedule 1, Column 10.
Transport in Bulk Not Available
Special Precautions Not Available
TDG Other Secure containers (full and/or empty) with suitable hold down devises during shipment and ensure all caps, valves, or closures are secured in the closed position.
Section 15 - Regulatory Information
NOTE: THE PRODUCT LISTED ON THIS SDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS SDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.
Section 16 - Other Information
Preparation Date February 3, 2015
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations.
Attention: Receiver of the chemical goods / SDS coordinator
As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution® initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request.
If you have any questions or concerns please call our customer service center or technical service department.
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References
1) CHEMINFO: Sodium Hypochlorite Solutions. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/cheminfo/records/351E.html#TOC11
2) CHRIS: Sodium Hypochlorite. (2014) Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/chris/records/1119.html
3) RTECS: Hypochlorous acid, sodium salt. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/rtecs/records/NH3486300.html
4) HSDB: Sodium Hypochlorite. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/hsdb/records/748.html
5) CESARS: Chlorine/hypochlorite. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/cesars/records/777.html
6) IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. List of classifications by alphabetical order. Agents Classified by the IARC Monographs, Volumes 1-111. http://monographs.iarc.fr/ENG/Classification/index.php
24 Hour Emergency Number - All Locations – 1(306) 664-2522 Alternative - 1(800) 387-7503
End of Safety Data Sheet
Page 234 of 276 fire POWDERED DEFOAMER HAZARD RATING MATERIAL SAFETY DATA 0 4=Extreme 3=High health 0 0 reactivity SHEET 2=Moderate
1=Slight 0=Insignificant special *=See Section IV LC160 Page 1 of 2
SECTION 1
GENICARE INC. EMERGENCY Spill, Leak, Fire, Exposure or Accident Date Prepared: 1407 Mahalo Place, Call Day or Night CHEM-TEL INC.: 800-255-3924 Rancho Dominguez, CA 90220 11/01/02 INFORMATION Telephone Number: 800-933-9133
SECTION 2 Hazardous Ingredients/Identity Information Hazardous Components CAS # % (Optional) Threshold Limit None
SECTION 3 Physical/Chemical Characteristics Boiling Point: N/A Specific Gravity (Water=1): N/A Vapor Pressure (mm Hg.): N/A Melting Point: ND Vapor Density (Air=1): N/A Evaporation Rate: N/A pH= N/A (Butyl Acetate=1)
Solubility in Water: Complete Appearance and Odor: White Free Flowing Powder
SECTION 4 Fire and Explosion Hazard Data Flash Point (Method Used): <200 Degrees F TCC
Extinguishing Media: Dry Chemical, Foam, CO2 or Water Spray Special Fire Fighting Procedures: Wear self-contained breathing apparatus whenever fighting chemical fires Unusual Fire and Explosion Hazards: None known
SECTION 5 Reactivity Data
Stability: Unstable Conditions to Avoid: None known Stable X Incompatibility (Material to Avoid): None known
Hazardous Decomposition or By-products: Hazardous May Occur Conditions to Avoid: None known Polymerization: Will Not Occur X
SECTION 6 Health Hazard Data Routes of Entry: Inhalation, Eyes, Skin, Ingestion Signs and Symptoms of Exposure: Inhalation: Minimally irritating. Eyes: Slight temporary irritation. Skin: No effect. Ingestion: Unlikely, no effect in small in small quantities. Carcinogen: No
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MATERIAL SAFETY DATA SHEET Genicare Inc., 1407 Mahalo Place, Rancho Dominguez, CA 90220 POWDERED DEFOAMER Page 2 of 2
Medical Conditions Generally Aggravated By Exposure: None known Emergency and First Aid Procedures Inhalation: Remove to fresh air. Give resuscitation if not breathing. Get immediate medical attention. Eyes: Flush eyes with lots of water for at least 15 minutes. Get immediate medical attention. Skin: Wash skin with soap and water. Remove contaminated clothing. Call for medical attention if ill effect or irritation develops. Ingestion: Give large amounts of water. Do not induce vomiting. Never give water to an unconscious person. Get immediate medical attention.
SECTION 7 Control Measures Respiratory Protection: None normally needed. If required use NIOSH approved canister type respirator. Ventilation: General or mechanical. Protective Gloves: Where hand contact is possible, wear impermeable gloves. Eye Protection: Where eye contact is possible, wear chemical goggles. No contact lenses. Other Protective Clothing or Equipment: As required by employer rules. Work/Hygienic Practices: Wash hands thoroughly after using. Practice good personal hygiene.
SECTION 8 Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled: Sweep or shovel up spilled material into DOT approved wash container. Flush spill area with water.
Waste Disposal Method: Treatment, storage, transportation and disposal of this material must be in accordance with applicable federal, state and local regulations.
Precautions to be Taken in Handling or Storage: Keep in closed container.
Other Precautions: None known
SECTION 9 Transportation and Reporting Data DOT Regulated As Hazardous: No X Yes
*Subject to the reporting requirements of SARA Title III, Section 313 and 40 CFR Part 372. No X Yes
NA = Not Applicable ND = Not Determined NE = Not Established
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. GENICARE INC. assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of the material.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
SECTION 1. IDENTIFICATION
Product name : PURELL® Advanced Hand Sanitizer
Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc.
Address : One GOJO Plaza, Suite 500 Akron OH 44311
Telephone : 1 (330) 255-6000
Emergency telephone : 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer
Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Flammable liquids : Category 3
Eye irritation : Category 2A
GHS Label element Hazard pictograms :
Signal Word : Warning
Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol 64-17-5 >= 50 - < 70 Propan-2-ol 67-63-0 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms : Causes serious eye irritation. and effects, both acute and delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet media
Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides ucts
Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Remove all sources of ignition. protective equipment and Use personal protective equipment. emergency procedures Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.
Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid : Do not store with the following product types: Strong oxidizing agents
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm NIOSH REL 980 mg/m3 ST 500 ppm NIOSH REL 1,225 mg/m3 TWA 400 ppm OSHA Z-1 980 mg/m3 Biological occupational exposure limits Ingredients CAS-No. Control Biological Sam- Permissible Basis parameters specimen pling concentratio time n Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH shift at BEI end of work- week Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.
Hand protection Material : Impervious gloves
Material : Flame retardant gloves
Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment: Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear, light green
Odor : alcohol-like
Odor Threshold : No data available
pH : 6.5 - 8.5
Melting point/freezing point : No data available
Initial boiling point and boiling : 76 °C range
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Flash point : 24 °C
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Density : 0.881 g/cm3
Solubility(ies) Water solubility : soluble
Partition coefficient: n- : Not applicable octanol/water
Autoignition temperature : No data available
Decomposition temperature : The substance or mixture is not classified self-reactive.
Viscosity Viscosity, kinematic : 3,500 - 23,000 mm2/s (20 °C)
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Flammable liquid and vapor. tions Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known. products
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method
Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor
Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation
Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation
Propan-2-ol: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation Causes serious eye irritation. Ingredients:
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405
Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization.
Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative
Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative
Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative
Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative
Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative
IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative
Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative
STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
STOT-repeated exposure Not classified based on available information. Repeated dose toxicity
Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y
Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.6 mg/l aquatic invertebrates Exposure time: 9 d (Chronic toxicity)
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h
Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l aquatic invertebrates Exposure time: 24 h
Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Exposure time: 8 d
Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h
Persistence and degradability
Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d
Propan-2-ol: Biodegradability : Result: rapidly degradable
Bioaccumulative potential
Ingredients: Ethanol: Partition coefficient: n- : log Pow: -0.35 octanol/water
Propan-2-ol: Partition coefficient: n- : log Pow: 0.05 octanol/water
Mobility in soil No data available Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
(Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.
Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/18/2015 36799-00003 Date of first issue: 12/12/2014
Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313:
Propan-2-ol 67-63-0 3.4086 %
US State Regulations
Pennsylvania Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III: Flammability
HEALTH 2 3 Instability
2 0 FLAMMABILITY 3 Health
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD compile the Material Safety eChem Portal search results and European Chemicals Agen- Data Sheet cy, http://echa.europa.eu/
Revision Date : 03/18/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid- ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
US / Z8
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Purple Power
SECTION 1. IDENTIFICATION Product Identifier Purple Power Other Means of Code No. 330 Identification Recommended Use All purpose cleaner and degreaser. Restrictions on Use Use only as directed according to label instructions. Manufacturer Leysons Products, a division of 1787528 Ontario Inc., 1366 Sandhill Drive, Ancaster, Ontario, L9G 4V5, (905) 648-7832 Emergency Phone No. CANUTECH, 613-996-6666, 24-hr for Emergencies involving Dangerous Goods SDS No. 0235
SECTION 2. HAZARD IDENTIFICATION Classification Skin irritation - Category 2; Serious eye damage - Category 1 Label Elements
Danger Corrosive Causes severe eye damage and skin irritation or burns. May be harmful if swallowed.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. % Other Identifiers Other Names
2-Butoxyethanol 111-76-2 5-10 Ethanolamine 141-43-5 1-5 Alcohols, C9-11, ethoxylated, liquids 68439-46-3 1-5
SECTION 4. FIRST-AID MEASURES First-aid Measures Inhalation If irritation is experienced, remove person to fresh air. Get medical advice or attention if you feel unwell or are concerned. Skin Contact In case of contact, immediately flush skin with plenty of water. Call a physician if irritation develops or persists.
Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 Date of Preparation: December 19, 2017 Date of Last Revision: Page 01 of 06
Page 252 of 276 Call a physician if irritation develops or persists. Eye Contact Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open. Remove contact lenses, if present and easy to do. If eye irritation persists, get medical advice or attention. Ingestion Never give anything by mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. If vomiting occurs naturally, lie on your side in the recovery position. Rinse mouth with water again. Immediately call a Poison Centre or doctor. Immediate Medical Attention and Special Treatment Target Organs Eyes, skin, respiratory system, digestive system. Medical Conditions Aggravated by Exposure Asthma, skin allergies.
SECTION 5. FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Not combustible. Use extinguishing agent suitable for surrounding fire. Unsuitable Extinguishing Media None known. Specific Hazards Arising from the Product This product presents no unusual hazards in a fire situation. Special Protective Equipment and Precautions for Fire-fighters Wear full fire fighting equipment and respirator.
SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures Use the personal protective equipment recommended in Section 8 of this safety data sheet. Increase ventilation to area or move leaking container to a well-ventilated and secure area. Environmental Precautions Do not allow into any sewer, on the ground or into any waterway. If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas. Minimize the use of water to prevent environmental contamination. Methods and Materials for Containment and Cleaning Up Contain and/or absorb spill with commercial absorbents and then place into a suitable container for disposal.
SECTION 7. HANDLING AND STORAGE Precautions for Safe Handling Do not get in eyes, on skin or on clothing. Do not breath gas/fumes/vapour/spray. Do NOT ingest. Keep containers tightly sealed when not in use. Conditions for Safe Storage Store in a cool dry area away from incompatible materials. Keep out of reach of children in a tightly closed container away from food, drink and animal feed.
Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 Date of Preparation: December 19, 2017 Date of Last Revision: Page 02 of 06
Page 253 of 276 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters ACGIH TLV® OSHA PEL AIHA WEEL Chemical Name TWA STEL TWA Ceiling 8-hr TWA TWA Ethanolamine 3 ppm 6 ppm 2-Butoxyethanol 20 ppm 25 ppm Alcohols, C9-11, ethoxylated, liquids Not Not established established Appropriate Engineering Controls Use ventilation adequate to keep exposures (airborne levels of vapour) below the recommended exposure limits. Provide eyewash and safety shower if contact or splash hazard exists. Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air. Individual Protection Measures Eye/Face Protection Wear chemical safety goggles and face shield when contact is possible. Skin Protection Wear protective gloves and clothing to prevent skin contact. Respiratory Protection Use in well ventilated areas. In case of insufficient ventilation, wear suitable respiratory equipment.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Basic Physical and Chemical Properties Appearance Clear purple liquid. pH 12.5 - 13.2 Melting Point/Freezing Point ~ 0 ºC (32 ºF) (freezing) Flash Point Not applicable Upper/Lower Flammability or Not available (upper); Not available (lower) Explosive Limit Vapour Pressure Not available Solubility Soluble in water Other Information Physical State Liquid Bulk Density ~ 1.03 kg/L
SECTION 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions of use. Chemical Stability Normally stable. Conditions to Avoid High temperatures. Freezing. Incompatible materials. Incompatible Materials Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid), strong reducing agents (e.g. hydrides).
Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 Date of Preparation: December 19, 2017 Date of Last Revision: Page 03 of 06
Page 254 of 276 Incompatible Materials Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid), strong reducing agents (e.g. hydrides). Hazardous Decomposition Products May include but are not limited to oxides of carbon, nitrogen and ammonia.
SECTION 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure Inhalation. Skin contact. Skin absorption. Eye contact. Ingestion. Acute Toxicity
Chemical Name LC50 LD50 (oral) LD50 (dermal) Ethanolamine > 1.21 mg/L (rat) (4-hour 1720 mg/kg (rat) 1000 mg/kg (rabbit) exposure) 2-Butoxyethanol 450 ppm (rat) (4-hour 530 mg/kg (rat) 400-500 mg/kg (rabbit) exposure) Alcohols, C9-11, ethoxylated, 1378 mg/kg (rat) > 2000 mg/kg (rabbit) liquids Skin Corrosion/Irritation May cause irritation or symptoms such as redness, edema, drying, defatting or cracking of the skin. Serious Eye Damage/Irritation May cause severe irritation or burns. STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation May cause irritation of the respiratory system. Skin Absorption May cause irritation on prolonged contact. Ingestion Harmful if swallowed. Aspiration Hazard May be drawn into the lungs (aspirated) if swallowed or vomited. STOT (Specific Target Organ Toxicity) - Repeated Exposure No chronic effects are expected provided adequate person protection is taken during usage. Respiratory and/or Skin Sensitization Not expected to produce any respiratory system problems when used in a well ventilated area. Carcinogenicity Not known to cause cancer. Reproductive Toxicity Development of Offspring Not known to harm the unborn child. Sexual Function and Fertility Not known to cause effects on sexual function or fertility. Effects on or via Lactation Not known to cause effects on or via lactation. Germ Cell Mutagenicity Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 Date of Preparation: December 19, 2017 Date of Last Revision: Page 04 of 06
Page 255 of 276 Germ Cell Mutagenicity Not known to be a mutagen. Interactive Effects No information was located.
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity May cause long-term adverse effects in the aquatic environment. Persistence and Degradability Readily biodegradable (test method #301D, OECD). Bioaccumulative Potential No information was located. Mobility in Soil No information was located.
SECTION 13. DISPOSAL CONSIDERATIONS Disposal Methods Dispose of contents and container in accordance with local, regional, national and international regulations.
SECTION 14. TRANSPORT INFORMATION
Transport Hazard Packing Regulation UN No. Proper Shipping Name Class(es) Group
Canadian TDG 2491 Ethanolamine Solution 8 III Special Precautions Not applicable Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code Not applicable
SECTION 15. REGULATORY INFORMATION Safety, Health and Environmental Regulations Canada WHMIS 1988 Classification
Class D2B Class E D2B - Toxic (Skin irritant; Eye irritant); E - Corrosive This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations.
SECTION 16. OTHER INFORMATION SDS Prepared By Mark Bryans Phone No. (905) 648-7832 ext 351 Date of Preparation December 19, 2017 Disclaimer The user of this product assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein is accurate. Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 However, the supplier assumes no liability whatsoever for the accuracy or completeness of the Date of Preparation: informationDecember contained19, 2017 herein. Date of Last Revision: No representation of warranties, either expressed or implied, of merchantability,Page fitness05 forof a 06 particular purpose or of any other nature are made hereunder with respect to the information or the product to which the information refers. The data contained on this sheet apply to the products supplied to the user. Page 256 of 276 Disclaimer To the best of our knowledge, the information contained herein is accurate. However, the supplier assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representation of warranties, either expressed or implied, of merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to the information or the product to which the information refers. The data contained on this sheet apply to the products supplied to the user.
Product Identifier: Purple Power - Ver. 1 SDS No.: 0235 Date of Preparation: December 19, 2017 Date of Last Revision: Page 06 of 06
Page 257 of 276 Scotchgard™ Shoe Guard Liquid Shoe Polish with Water Repellent 02/12/14
Safety Data Sheet
Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 27-5256-6 Version Number: 5.00 Issue Date: 02/12/14 Supercedes Date: 08/05/13
SECTION 1: Identification
1.1. Product identifier Scotchgard™ Shoe Guard Liquid Shoe Polish with Water Repellent
Product Identification Numbers JF-1000-8282-1
1.2. Recommended use and restrictions on use
Recommended use Shoe Polish with Water Repellent
1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Materials Resource Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B.
2.2. Label elements Signal word Warning
Symbols Not applicable
Pictograms Not applicable
Hazard Statements Causes eye irritation.
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Precautionary Statements General: Keep out of reach of children.
Prevention: Wash thoroughly after handling.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
2.3. Hazards not otherwise classified None.
3% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt WATER 7732-18-5 90 - 95 CARNAUBA WAX 8015-86-9 1 - 3 TRI(BUTOXYETHYL) PHOSPHATE 78-51-3 1 - 3 ACRYLATE POLYMER Trade Secret* 1 - 3 ACRYLATE POLYMER SALT Trade Secret* 1 - 3 FLUOROCHEMICAL ACRYLATE POLYMER Trade Secret* < 1 3-IODO-2-PROPYNYL BUTYLCARBAMATE 55406-53-6 < 0.05 1,2-BENZISOTHIAZOLIN-3-ONE 2634-33-5 < 0.025
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required Not applicable.
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SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture None inherent in this product.
Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion Toxic Vapor, Gas, Particulate During Combustion
5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling Avoid eye contact. Do not breathe thermal decomposition products. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment.
7.2. Conditions for safe storage including any incompatibilities No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
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No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.
8.2. Exposure controls
8.2.1. Engineering controls Provide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles
Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: White color liquid with mild odor. Odor threshold No Data Available pH 7.9 - 8.3 Melting point Not Applicable Boiling Point 212 ºF Flash Point No flash point Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure <=18 mmHg [@ 68 ºF] Vapor Density No Data Available Density 0.98 - 1.02 g/ml Specific Gravity 0.98 - 1.02 [Ref Std: WATER=1] Solubility in Water Complete
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Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Volatile Organic Compounds 2.77 g/l Percent volatile 92 - 93 SECTION 10: Stability and reactivity
10.1. Reactivity This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability Stable.
10.3. Possibility of hazardous reactions Hazardous polymerization will not occur.
10.4. Conditions to avoid None known.
10.5. Incompatible materials None known.
10.6. Hazardous decomposition products Substance Condition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
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Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion: No health effects are expected.
Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg CARNAUBA WAX Ingestion LD50 estimated to be > 5,000 mg/kg TRI(BUTOXYETHYL) PHOSPHATE Dermal Rabbit LD50 > 5,000 mg/kg TRI(BUTOXYETHYL) PHOSPHATE Inhalation- Rat LC50 > 6.4 mg/l Dust/Mist (4 hours) TRI(BUTOXYETHYL) PHOSPHATE Ingestion Rat LD50 4,700 mg/kg FLUOROCHEMICAL ACRYLATE POLYMER Dermal LD50 estimated to be > 5,000 mg/kg FLUOROCHEMICAL ACRYLATE POLYMER Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 3-IODO-2-PROPYNYL BUTYLCARBAMATE Dermal Rabbit LD50 > 2,000 mg/kg 3-IODO-2-PROPYNYL BUTYLCARBAMATE Inhalation- Rat LC50 0.67 mg/l Dust/Mist (4 hours) 3-IODO-2-PROPYNYL BUTYLCARBAMATE Ingestion Rat LD50 1,056 mg/kg ATE = acute toxicity estimate
Skin Corrosion/Irritation Name Species Value 3-IODO-2-PROPYNYL BUTYLCARBAMATE Rabbit Minimal irritation
Serious Eye Damage/Irritation Name Species Value 3-IODO-2-PROPYNYL BUTYLCARBAMATE Rabbit Corrosive
Skin Sensitization Name Species Value 3-IODO-2-PROPYNYL BUTYLCARBAMATE Multiple Sensitizing animal species
Respiratory Sensitization Name Species Value
Germ Cell Mutagenicity Name Route Value FLUOROCHEMICAL ACRYLATE POLYMER In Vitro Not mutagenic
Carcinogenicity Name Route Species Value
Reproductive Toxicity
Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration
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Target Organ(s)
Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration
Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 3-IODO-2-PROPYNYL Inhalation respiratory system Causes damage to organs Rat NOAEL 90 days BUTYLCARBAMATE through prolonged or repeated .00116 mg/l exposure
Aspiration Hazard Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations
13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations This material contains one or more substances that are subject to a TSCA Consent Order. Contact 3M for more information.
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311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt TRI(BUTOXYETHYL) PHOSPHATE 78-51-3 1 - 3 (GLYCOL ETHERS)
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status FLUOROCHEMICAL ACRYLATE POLYMER Trade Secret Toxic Substances Control Act (TSCA) 5 Applicable SNUR or Consent Order Chemicals
15.2. State Regulations Contact 3M for more information.
15.3. Chemical Inventories The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information.
The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification Health: *2 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA).
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Document Group: 27-5256-6 Version Number: 5.00 Issue Date: 02/12/14 Supercedes Date: 08/05/13
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M
3M USA SDSs are available at www.3M.com
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Page 266 of 276 MATERIAL SAFETY DATA SHEET MSDS DATE: 4/8/09 shockwave™ 10 oz SECTION 5: FIRE-FIGHTING MEASURES Per OSHA-recommended ANSI Z400.1-2004 standard format & in accordance with European standard format Product is non-combustible Flash point: Autoignition Temperature: SECTION 1: PRODUCT AND COMPANY IDENTIFICATION F: Not flammable F: Not Established Product Name: ShockWave™ C: Not flammable C: Not Established Product Description: EPA Registered Disinfectant/Sanitizer/Cleaner/Fungicide (10oz) Flammable Limits in Air: Product Code: 8311 (% BY VOLUME) Manufacturer: Fiberlock Technologies, Inc. Address: UPPER: Not applicable Fiberlock Technologies LOWER: Not applicable 150 Dascomb Road Andover MA, 01810 Extinguishing Media: Contact Info: Tel: (800) 342-3755 Use extinguishing media appropriate for surrounding fire Fax: (978) 475-6205 Water Spray OK Emergency Phone: 24 Hour Contact: CHEM-TEL: (800) 255-3924 Carbon Dioxide NO INTERNATIONAL 24 HOUR EMERGENCY Phone: 813-248-0585 Foam NO SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Dry Chemical OK Non-hazardous: Halon NO Hazardous: Other N/A Chemical Name CAS# Percent OSHA PEL ACGIH TLV SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus 1 - Dimethyl Benzyl 68391-01-5 < 2.25 Not Established Not Established and protective clothing should be worn when fighting chemical fires. Use water Ammonium Chloride spray to keep fire-exposed containers cool. 2 - Dimethyl 68956-79-6 < 2.25 Not Established Not Established Ethylbenzyl SECTION 6: ACCIDENTAL RELEASE MEASURES Ammonium Chloride Accidental Release Measures: This product does not contains any toxic chemical(s) subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Personal Precautions: Do not get in eyes. Do not take internally. Avoid skin Act of 1986 and of 40 CFR 372. contact. Prevent prolonged or repeated breathing of vapor or spray mists. Keep unnecessary people away. Floor may be slippery, use care to avoid falling. Remove all sources if ignition. Ventilate the area. Remove with inert absorbent. SECTION 3: HAZARDS IDENTIFICATION Environmental Precautions: Keep spills and cleaning run-offs out of municipal sewers and open bodies of water. Comply with local, national and state Potential Health Hazards: regulations. Skin Contact: Skin irritant. Prolonged or repeated contact may cause dermatitis. Eyes Contact: Severe eye irritant. Liquid and mists may injure the eyes causing corneal damage. SECTION 7: HANDLING AND STORAGE Inhalation: Inhalation of vapors or mists may cause irritation of the throat and respiratory Handling and Storage: tract. High vapor concentrations may cause central nervous system effects. Maximum Storage Temperature: 100°F (38°C), minimum 35°F (2°C). Ingestion: Irritating to the mouth, throat, and gastrointestinal system. Burning, pain, and Keep closure tight and containers upright to prevent leakage. diarrhea expected with large doses. Product is non-combustible.
SECTION 4: FIRST AID MEASURES SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Immediately flush eyes with large amounts of water for 15 minutes holding eyelids open. Get medical attention immediately. Precautions: Use only with adequate ventilation. Skin: Remove contaminated clothing. Flush affected areas with large quantities of water. Seek medical attention if irritation persists. Work Hygienic Practices: Avoid contact with skin. Do not get in eyes. Do not take internally. Avoid breathing vapors or spray mists. Ingestion: Drink 3-4 glasses of milk or water. Do not induce vomiting. Get medical attention immediately. Ventilation: Use in well-ventilated areas. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. Inhalation: Remove victim to fresh air and monitor. Seek medical attention if symptoms persist. Respiratory Protection: No special requirements. Avoid breathing mists. Eye Protection: Chemical goggles recommended when spraying diluted product. Skin Protection: Wear neoprene, rubber, vinyl, or nitrile gloves to prevent skin contact if prolonged skin contact is likely. Wash hands before eating, smoking or using the wash room. Other Protective Equipment: Eyewash station should be provided nearby.
Page 1: MSDS for Fiberlock Technologies ShockWave™ EPA Registered Disinfectant/Sanitizer/Cleaner/Fungicide (10oz) No. 8311
Page 267 of 276 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES SECTION 15: REGULATORY INFORMATION Appearance: Thin liquid Solubility in Water: Total U.S. Federal Regulations: Odor: Pleasant Color: Light Blue TSCA (TOXIC SUBSTANCE CONTROL ACT): All components of this product are in odor compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Boiling Point: 210°F Viscosity @ 77°F: 60-75 Kreb Units CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Releases of this material to air, land, or water are not reportable to the National Response Evaporation Rate: Slower Vapor Density Heavier Center under the Comprehensive Environmental Response, Compensation, and Liability (Butyl Acetate=1) (AIR = 1) @ 68°F: Act (CERCLA) or to state and local emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. Vapor Pressure: 20mm Hg @ Specific Gravity (H2O = 1.040 68 F 1) @ 68°F: SARA TITLE III (SARA 313): No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. pH 11.5-12.0 Percent Volatile 90+ SARA TITLE III (SARA 311/312): Ingredients in this product are subject to SARA 311/312 Immediate (acute) Health Hazard Supplier Notification. SECTION 10: STABILITY AND REACTIVITY CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT No Components of this product are on the California Proposition 65 Stability: Stable (PROPOSITION 65): lists. Incompatibility: None New Jersey Right to Know Hazardous Substance List: This product contains no Hazardous Decomposition or By-Products: Will not occur. components subject to reporting requirements. Hazardous Polymerization: Will not occur. Canada: Workplace Hazardous materials Information System (WHMIS)-listed material: This product contains the following components subject to reporting requirements: Sodium carbonate. SECTION 11: TOXICOLOGICAL INFORMATION Toxicological Information: SECTION 16: OTHER INFORMATION No Data Available To comply with New Jersey DOH Right-To-Know labeling law (NJAC 8:59 – 5.1 & 5.2)
SECTION 12: ECOLOGICAL INFORMATION CAS. No.: CHEMICAL INGREDIENTS Ecological Information: No Data Available 7732-18-5 Water 68391-01-5 Dimethyl Benzyl Ammonium Chloride SECTION 13: DISPOSAL CONSIDERATIONS 68956-79-6 Dimethyl Ethylbenzyl Ammonium Waste Disposal Method: Chloride Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Do not dump into sewers, any body of water or onto the 9016-45-9 Nonionic Surfactant ground. 497-19-8 Sodium Carbonate (+) Contents Partially Unknown SECTION 14: TRANSPORT INFORMATION U.S. Department of Transportation HMIS HAZARD RATING Proper Shipping Name: Hazard Class: “Not Regulated” Health 2 Flammability 0 Physical Hazard 0 Personal ID Number: Protection B Packing Group: HAZARD INDEX: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe Label Statement: “Keep From Freezing” Class: Cleaning Compound This company cannot anticipate all conditions of handling and use of this product. Therefore, this company accepts no responsibility for results obtained by the application of this information, or the safety and suitability of our products either alone or in combination with other products. It is the responsibility of the user to provide a safe workplace, using the health and safety information contained herein as a guide. This company will accept no liability for damages or loss incurred from the improper handling and use of this product.
Page 2: MSDS for Fiberlock Technologies ShockWave™ EPA Registered Disinfectant/Sanitizer/Cleaner/Fungicide (10oz) No. 8311
Page 268 of 276 Material Safety Data Sheet MSDS Prochem Truck Mount Descaler MSDS Number: E551 Revision Date: February 24, 2009 Page 1 of 4
1 PRODUCT AND COMPANY IDENTIFICATION
Manufacturer PROCHEM Kärcher North America 325 S. Price Road Chandler, AZ 85224
Contact: Prochem Telephone Number:480-899-7000 FAX Number: 480-786-9538 E-Mail: [email protected] Web www.prochem.com
Product Name: Truck Mount Descaler Revision Date: February 24, 2009 MSDS Number: E551 Emergency Telephone: (800) 535-5053 [Infotrac]
2 HAZARDS IDENTIFICATION
Route of Entry: Eyes; Skin; Inhalation; Ingestion; Target Organs: Eyes; Skin; Inhalation: Minimal respiratory tract irritation may occur with exposure to a large amount of material Skin Contact: May Cause Irritation. Eye Contact: May Cause Irritation. Ingestion: Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause temporary injury. HMIS III-ratings (scale 0-4): Health = 3, Fire = 0, Physical Hazard = 0
3 COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients: Cas # Chemical Name ------5329146 | Sulfamic acid OSHA Regulatory Status: This MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product.
Page 269 of 276 Material Safety Data Sheet MSDS Prochem Truck Mount Descaler MSDS Number: E551 Revision Date: February 24, 2009 Page 2 of 4 4 FIRST AID MEASURES
Inhalation: If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. If irritation persists consult medical personnel. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting eyelids occasionally to facilitate irrigation. Get immediate medical attention. Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If injured party is conscious, give two glasses of water. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flash Point: N/A Wear self contained breathing apparatus and other protective clothing. Use any standard agent - choose the one most appropriate for type of surrounding fire.
6 ACCIDENTAL RELEASE MEASURES
Keep away from drains and ground water. Keep all unnecessary personnel away. Spill area may be slippery.Sweep Up, Place In Bag and Hold For Waste Disposal. Ventilate Area and Wash Spill Site After Material Pickup is Complete. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
7 HANDLING AND STORAGE
Handling Precautions: Avoid contact with eyes, skin, or clothing; Consider normal working hygiene. Handle with care and avoid spillage on the floor (slippage). Keep away from sources of ignition; wash thoroughly after handling. Storage Requirements: Store out of reach of children; keep container closed; store in a cool well-ventilated place away from strong oxidizing or alkaline product.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Normal room ventilation is satisfactory for limited use. Protective Equipment: HMIS PP, X | Consult your supervisor for special instructions
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White Physical State: Powder Boiling Point: N/D Odor: None Freezing/Melting Pt.: N/D pH: 1.1 - 1.6 @ 1% Solution Solubility: Soluble Vapor Pressure: N/D Spec Grav./Density: N/A Vapor Density: N/D
Page 270 of 276 Material Safety Data Sheet MSDS Prochem Truck Mount Descaler MSDS Number: E551 Revision Date: February 24, 2009 Page 3 of 4 10 STABILITY AND REACTIVITY
Stability: Product is stable under normal conditions. Conditions to avoid: None Known Materials to avoid (incompatability): None Known Hazardous Decomposition products: Exposure to fire may liberate carbon dioxide, carbon monoxide, organic acids, and other unidentified thermal decomposition products from this product or its packaging. Hazardous Polymerization: Will not occur.
11 TOXICOLOGICAL INFORMATION
Route of Entry: Eye contact, and Skin absorption/contact
Effects of Acute Overexposure to Product: Eye Contact: Causes eye irritation, redness, tearing and blurred vision Skin Contact: Causes skin irritation, defatting and dermatitis Inhalation: Inhalation of mist or vapor may cause temporary respiratory irritation; temporary central nervous system effects including dizziness, weakness, fatigue, nausea, and headache. Ingestion: May cause temporary gastrointestinal irritation with nausea, vomiting and diarrhea.
None of the components in this product are listed by NTP, IARC or OSHA as a carcinogen.
12 ECOLOGICAL INFORMATION
Refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information.
13 DISPOSAL CONSIDERATIONS
Dispose of in accordance with local regulations.
14 TRANSPORT INFORMATION
Refer to bill of lading or container label for DOT or other transportation hazard classification. Ship in accordance with 49 CFR parts 100-185.
15 REGULATORY INFORMATION
COMPONENT / (CAS/PERC) / CODES ------*Sulfamic acid (5329146), WHMIS 1%
REGULATORY KEY DESCRIPTIONS ------WHMIS= Workforce Hazardous Material Information System
Page 271 of 276 Material Safety Data Sheet MSDS Prochem Truck Mount Descaler MSDS Number: E551 Revision Date: February 24, 2009 Page 4 of 4 16 OTHER INFORMATION
This document is prepared in accordance with 29 CFR 1910.1200. The purpose of this section is to ensure that the hazards of all chemicals produced or imported are evaluated, and that information concerning their hazards is transmitted to employers and employees.
All information appearing herein is based upon data obtained from the raw material manufacturer and/or recognized technical sources. While the information above is believed to be true and accurate, the author makes no representations as to its accuracy or sufficiency. Conditions of use are beyond the manufacturer's control; therefore the users are responsible to verify this data under their own particular conditions, applications and regulations to determine if the product is suitable for their particular purposes. The users assume all risks of product use, handling, disposal, reliance upon, publication or use of the information contained herein. This information applies only to the product designated above and does not necessarily apply to its use in combination with other materials, products, chemical compounds, structures or processes.
Prepared by: EHS Manager Phone Number: [480] 899-7000
END OF MSDS DOCUMENT
Page 272 of 276 Safety Data Sheet SDS Prochem Ultrapac Trafficlean MSDS Number: S711 Revision Date: November 12, 2013 Page 1 of 4
1 PRODUCT AND COMPANY IDENTIFICATION
Manufacturer PROCHEM Kärcher North America 325 S. Price Road Chandler, AZ 85224
Phone: 480-899-7000 Fax: 480-786-9538 Email: [email protected] Web: www.prochem.com
Product Name: Ultrapac Trafficlean Revision Date: November 12, 2013 Version: 44-43H MSDS Number: S711 Emergency Information: INFOTRAC 1-800-535-5053 International 1-352-323-3500
2 HAZARDS IDENTIFICATION
Route of Entry: Eyes; Skin; Inhalation; Ingestion; Target Organs: Eyes; Skin; Inhalation: Minimal respiratory tract irritation may occur with exposure to a large amount of material Skin Contact: May cause irritation. Eye Contact: May cause irritation. Ingestion: Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause temporary injury.
NFPA: Health = 1, Fire = 1, Reactivity = 0 HMIS III: H1/F1/PH0
1 1 1 1 0 0
B | Safety Glasses, Gloves
GHS Classifications: Health, Acute toxicity, 5 Dermal GHS Phrases:
Page 273 of 276 Safety Data Sheet SDS Prochem Ultrapac Trafficlean MSDS Number: S711 Revision Date: November 12, 2013 Page 2 of 4 Warning, H313 - May be harmful in contact with skin GHS Precautionary Statements: IF ON SKIN: Wash with soap and water. Call a POISON CENTER or doctor/physician if you feel unwell.
GHS PICTOGRAMS:
No GHS Pictograms 3 HAZARDS IDENTIFICATION
Ingredients:
CAS # Percent Chemical Name ------111762 | <24% | Ethylene glycol monobutyl ether
OSHA Regulatory Status: This MSDS Contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product.
4 FIRST AID MEASURES
Inhalation: If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. If irritation persists consult medical personnel. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting eyelids occasionally to facilitate irrigation. Get immediate medical attention. Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If injured party is conscious, give two glasses of water. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flash Point: 200°F Flash Point Method: Closed Cup Wear self-contained breathing apparatus and other protective clothing. Use any standard agent - choose the one most appropriate for type of surrounding fire.
6 ACCIDENTAL RELEASE MEASURES
Keep away from drains and ground water. Keep all unnecessary personnel away. Spill area may be slippery. Pick up excess with inert absorbent material and place into separate waste container. Ventilate area and wash spill site after material pickup is complete. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
Page 274 of 276 Safety Data Sheet SDS Prochem Ultrapac Trafficlean MSDS Number: S711 Revision Date: November 12, 2013 Page 3 of 4 7 HANDLING AND STORAGE
Handling Precautions: Avoid contact with eyes, skin, or clothing; Consider normal working hygiene. Handle with care and avoid spillage on the floor (slippage). Keep away from sources of ignition; wash thoroughly after handling. Storage Requirements: Store out of reach of children; keep container closed; store in a cool well-ventilated place.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Normal room ventilation is satisfactory for limited use. Personal Protective Equip: HMIS PP, B | Safety glasses, Gloves Ethylene glycol monobutyl ether 111-76-2 OSHA PEL 50 ppm - 240 mg/m3
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Opaque Caramel Physical State: Liquid Odor: Mint Spec Grav./Density: 9.44 lb/gallon Solubility: Soluble pH: 9.5 - 10.2 as is
10 STABILITY AND REACTIVITY
Stability: Product is stable under normal conditions. Conditions to Avoid: None known Materials to Avoid: None known Hazardous Decomposition: Exposure to fire may liberate carbon dioxide, carbon monoxide, organic acids, and other unidentified thermal decomposition products from this product or its packaging. Hazardous Polymerization: Will not occur
11 TOXICOLOGICAL INFORMATION
Toxicity Data: Ethylene glycol butyl ether 111-76-2
Oral ( LD 50): 917 mg/kg - Rat
Inhalation ( LC 50): 2900 mg/m3/7H - Rat
Skin irritation: Mild
Eye irritation: Mild
Sensitation: Not considered an occupational sensitizer
Page 275 of 276 Safety Data Sheet SDS Prochem Ultrapac Trafficlean MSDS Number: S711 Revision Date: November 12, 2013 Page 4 of 4 12 ECOLOGICAL INFORMATION
On the basis of available information, this material is not expected to produce any significant environmental effects when recommended use instructions are followed.
13 DISPOSAL CONSIDERATIONS
Dispose of in accordance with local regulations.
14 TRANSPORT INFORMATION
DOT Class: Not regulated # Ship in accordance with 49 CFR parts 100-185. Non-hazardous for air, sea and road freight.
15 REGULATORY INFORMATION COMPONENT / (CAS/PERCENT) / CODES ------*Ethylene glycol monobutyl ether (111762 <24%) HAP, MASS, OSHAWAC, PA, TXAIR, WHMIS
REGULATORY KEY DESCRIPTIONS ------All components are listed on TSCA HAP = Hazardous Air Pollutants MASS = MA Massachusetts Hazardous Substances List OSHAWAC = OSHA Workplace Air Contaminants PA = PA Right-To-Know List of Hazardous Substances TXAIR = TX Air Contaminants with Health Effects Screening Level WHMIS = Workforce Hazardous Material Information System
16 OTHER INFORMATION
This document is prepared in accordance with 29 CFR 1910.1200. The purpose of this section is to ensure that the hazards of all chemicals produced or imported are evaluated, and that information concerning their hazards is transmitted to employers and employees.
All information appearing herein is based upon data obtained from the raw material manufacturer and/or recognized technical sources. While the information above is believed to be true and accurate, the author makes no representations as to its accuracy or sufficiency. Conditions of use are beyond the manufacturer's control; therefore the users are responsible to verify this data under their own particular conditions, applications and regulations to determine if the product is suitable for their particular purposes. The users assume all risks of product use, handling, disposal, reliance upon, publication or use of the information contained herein. This information applies only to the product designated above and does not necessarily apply to its use in combination with other materials, products, chemical compounds, structures or processes.
Prepared by: EHS Manager Phone Number: [480] 899-7000
Page 276 of 276