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Safety Data Sheet SAFETY DATA SHEET Creation Date 20-Jun-2005 Revision Date 07-Jan-2021 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Cadmium acetate dihydrate Cat No. : 11865 Synonyms Acetic acid cadmium salt dihydrate; Cadmium diacetate dihydrate. CAS-No 5743-04-4 Molecular Formula C4 H6 Cd O4 . 2 H2 O Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Thermo Fisher (Kandel) GmbH . Erlenbachweg 2 76870 Kandel Germany Tel: +49 (0) 721 84007 280 Fax: +49 (0) 721 84007 300 E-mail address [email protected] www.alfa.com Product safety Tel + +049 (0) 7275 988687-0 1.4. Emergency telephone number Carechem 24: +44 (0) 1235 239 670 (Multi-language emergency number) Poison Information Center Mainz www.giftinfo.uni-mainz.de Telephone: +49(0)6131/19240 Exclusively for customers in Austria: Poison Information Center (VIZ) Emergency call 0-24 clock: +43 1 406 43 43 Office hours: Monday to Friday, 8am to 4pm, tel: +43 1 406 68 98 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met ______________________________________________________________________________________________ ALFAA11865 Page 1 / 12 SAFETY DATA SHEET Cadmium acetate dihydrate Revision Date 07-Jan-2021 ______________________________________________________________________________________________ Health hazards Acute oral toxicity Category 4 (H302) Acute dermal toxicity Category 4 (H312) Acute Inhalation Toxicity - Dusts and Mists Category 4 (H332) Carcinogenicity Category 1A (H350) Environmental hazards Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H350 - May cause cancer H410 - Very toxic to aquatic life with long lasting effects H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell Additional EU labelling Restricted to professional users 2.3. Other hazards Toxic to terrestrial vertebrates SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Cadmium acetate dihydrate 5743-04-4 >95 Carc. 1A (H350) Acute Tox. 4 (H302) Acute Tox. 4 (H312) ______________________________________________________________________________________________ ALFAA11865 Page 2 / 12 SAFETY DATA SHEET Cadmium acetate dihydrate Revision Date 07-Jan-2021 ______________________________________________________________________________________________ Acute Tox. 4 (H332) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Cadmium acetate 543-90-8 EEC No. 208-853-2 - Carc. 1A (H350) Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Component Concentration limits M-Factor Component notes Cadmium acetate dihydrate - - Note 1 Cadmium acetate - - Note 1 Note Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation (Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of the metallic element calculated with reference to the total weight of the mixture Reach Registration Number - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media ______________________________________________________________________________________________ ALFAA11865 Page 3 / 12 SAFETY DATA SHEET Cadmium acetate dihydrate Revision Date 07-Jan-2021 ______________________________________________________________________________________________ Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire-fighting to enter drains or water courses. Hazardous Combustion Products Toxic fumes. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and material for containment and cleaning up Sweep up and shovel into suitable containers for disposal. Avoid dust formation. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid dust formation. Use only under a chemical fume hood. Do not breathe (dust, vapor, mist, gas). Do not ingest. If swallowed then seek immediate medical assistance. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Storage Class/LGK 6.1D (Germany) 7.3. Specific end use(s) ______________________________________________________________________________________________ ALFAA11865 Page 4 / 12 SAFETY DATA SHEET Cadmium acetate dihydrate Revision Date 07-Jan-2021 ______________________________________________________________________________________________ Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. Component European Union The United Kingdom France Belgium Spain Cadmium acetate STEL: 0.075 mg/m3 15 TWA / VME: 0.004 TWA / VLA-ED: 0.01 dihydrate min mg/m3 (8 heures). mg/m3 (8 horas) TWA: 0.025 mg/m3 8 hr indicative limit TWA / VLA-ED: 0.002 mg/m3 (8 horas) Cadmium acetate STEL: 0.075 mg/m3 15 TWA / VME: 0.004 TWA / VLA-ED: 0.01 min mg/m3 (8 heures). mg/m3 (8 horas) TWA: 0.025 mg/m3 8 hr indicative limit TWA / VLA-ED: 0.002 mg/m3 (8 horas) Component Italy Germany Portugal The Netherlands Finland Cadmium acetate TWA: 0.002 mg/m3 8 dihydrate horas Cadmium acetate TWA: 0.002 mg/m3 8 horas Component Austria Denmark Switzerland Poland Norway Cadmium acetate Haut/Peau dihydrate TWA: 0.015 mg/m3 8 Stunden TWA: 0.004 mg/m3 8 Stunden Cadmium acetate Haut/Peau TWA: 0.015 mg/m3 8 Stunden TWA: 0.004 mg/m3 8 Stunden Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No
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