polymers Review Extending Cellulose-Based Polymers Application in Additive Manufacturing Technology: A Review of Recent Approaches Denesh Mohan 1,2 , Zee Khai Teong 1,2, Afifah Nabilah Bakir 1,2, Mohd Shaiful Sajab 1,2,* and Hatika Kaco 3 1 Research Center for Sustainable Process Technology (CESPRO), Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor, Malaysia;
[email protected] (D.M.);
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[email protected] (A.N.B.) 2 Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor, Malaysia 3 Kolej GENIUS Insan, Universiti Sains Islam Malaysia, Bandar Baru Nilai, Nilai 71800, Negeri Sembilan, Malaysia;
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[email protected]; Tel.: +60-3-8921-6425 Received: 17 July 2020; Accepted: 18 August 2020; Published: 20 August 2020 Abstract: The materials for additive manufacturing (AM) technology have grown substantially over the last few years to fulfill industrial needs. Despite that, the use of bio-based composites for improved mechanical properties and biodegradation is still not fully explored. This limits the universal expansion of AM-fabricated products due to the incompatibility of the products made from petroleum-derived resources. The development of naturally-derived polymers for AM materials is promising with the increasing number of studies in recent years owing to their biodegradation and biocompatibility. Cellulose is the most abundant biopolymer that possesses many favorable properties to be incorporated into AM materials, which have been continuously focused on in recent years. This critical review discusses the development of AM technologies and materials, cellulose-based polymers, cellulose-based three-dimensional (3D) printing filaments, liquid deposition modeling of cellulose, and four-dimensional (4D) printing of cellulose-based materials.