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Synchronous Fluorescence Spectroscopic Study Of
Spectrochimica Acta Part A 79 (2011) 1034–1041 Contents lists available at ScienceDirect Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy jou rnal homepage: www.elsevier.com/locate/saa Synchronous fluorescence spectroscopic study of solvatochromic curcumin dye ∗ Digambara Patra , Christelle Barakat Department of Chemistry, Faculty of Arts and Sciences, American University of Beirut, P.O. Box 11-0236, Riad El Solh, Beirut 1107-2020, Lebanon a r t i c l e i n f o a b s t r a c t Article history: Curcumin, the main yellow bioactive component of turmeric, has recently acquired attention by chemists Received 1 July 2010 due its wide range of potential biological applications as an antioxidant, an anti-inflammatory, and an Accepted 13 April 2011 anti-carcinogenic agent. This molecule fluoresces weakly and poorly soluble in water. In this detailed study of curcumin in thirteen different solvents, both the absorption and fluorescence spectra of curcumin Keywords: was found to be broad, however, a narrower and simple synchronous fluorescence spectrum of curcumin Curcumin was obtained at = 10–20 nm. Lippert–Mataga plot of curcumin in different solvents illustrated two Solvent polarity E sets of linearity which is consistent with the plot of Stokes’ shift vs. the 30. When Stokes’s shift in SFS T wavenumber scale was replaced by synchronous fluorescence maximum in nanometer scale, the solvent max E polarity dependency measured by SFS vs. Lippert–Mataga plot or T30 values offered similar trends as max measured via Stokes’ shift for protic and aprotic solvents for curcumin. Better linear correlation of SFS vs. -
Fundamentals of Modern UV-Visible Spectroscopy
Fundamentals of modern UV-visible spectroscopy Primer Tony Owen Copyright Agilent Technologies 2000 All rights reserved. Reproduction, adaption, or translation without prior written permission is prohibited, except as allowed under the copyright laws. The information contained in this publication is subject to change without notice. Printed in Germany 06/00 Publication number 5980-1397E Preface Preface In 1988 we published a primer entitled “The Diode-Array Advantage in UV/Visible Spectroscopy”. At the time, although diode-array spectrophotometers had been on the market since 1979, their characteristics and their advantages compared with conventional scanning spectrophotometers were not well-understood. We sought to rectify the situation. The primer was very well-received, and many thousands of copies have been distributed. Much has changed in the years since the first primer, and we felt this was an appropriate time to produce a new primer. Computers are used increasingly to evaluate data; Good Laboratory Practice has grown in importance; and a new generation of diode-array spectrophotometers is characterized by much improved performance. With this primer, our objective is to review all aspects of UV-visible spectroscopy that play a role in obtaining the best results. Microprocessor and/or computer control has taken much of the drudgery out of data processing and has improved productivity. As instrument manufacturers, we would like to believe that analytical instruments are now easier to operate. Despite these advances, a good knowledge of the basics of UV-visible spectroscopy, of the instrumental limitations, and of the pitfalls of sample handling and sample chemistry remains essential for good results. -
Chloroform Safety Data Sheet According to Federal Register / Vol
Chloroform Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 06/03/2013 Revision date: 03/21/2017 Supersedes: 03/21/2017 Version: 1.3 SECTION 1: Identification 1.1. Identification Product form : Substance Substance name : Chloroform CAS-No. : 67-66-3 Product code : LC13040 Formula : CHCl3 Synonyms : 1,1,1-trichloromethane / Chloroform / formyl trichloride / freon 20 / methane trichloride / methane, trichloro- / methenyl chloride / methenyl trichloride / methyl trichloride / R 20 / R 20 refrigerant / TCM (=trichloromethane) / trichloroform / trichloromethane 1.2. Recommended use and restrictions on use Use of the substance/mixture : Bactericide Fumigant Insecticide Solvent Chemical substance for research Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem, Inc. Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Acute toxicity (oral) H302 Harmful if swallowed Category 4 Acute toxicity (inhalation) H331 Toxic if inhaled Category 3 Skin corrosion/irritation H315 Causes skin irritation Category 2 Serious eye damage/eye H319 Causes serious eye irritation irritation Category 2A Carcinogenicity Category 2 H351 Suspected of causing cancer Reproductive toxicity H361 Suspected of damaging the unborn child. Category 2 Specific target organ H372 Causes damage to organs (liver, kidneys) through prolonged or repeated exposure toxicity (repeated exposure) (Inhalation, oral) Category 1 Full text of H statements : see section 16 2.2. -
Locating and Estimating Air Emissions from Sources of Chloroform
United States Office of Air Quality EPA-450/4-84-007c Environmental Protection Planning And Standards Agency Research Triangle Park, NC 27711 March 1984 AIR EPA LOCATING AND ESTIMATING AIR EMISSIONS FROM SOURCES OF CHLOROFORM L &E EPA- 450/4-84-007c March 1984 LOCATING & ESTIMATING AIR EMISSIONS FROM SOURCES OF CHLOROFORM U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Air and Radiation Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 This report has been reviewed by the Office Of Air Quality Planning And Standards, U.S. Environmental Protection Agency, and has been approved for publication as received from GCA Technology. Approval does not signify that the contents necessarily reflect the views and policies of the Agency, neither does mention of trade names or commercial products constitute endorsement or recommendation for use. ii CONTENTS Figures ...................... iv Tables ...................... v 1. Purpose of Document ............... 1 2. Overview of Document Contents .......... 3 3. Background .................... 5 Nature of Pollutant ............ 5 Overview of Production and Uses ...... 8 4. Chloroform Emission Sources ........... 11 Chloroform Production ........... 11 Fluorocarbon Production .......... 20 Pharmaceutical Manufacturing ........ 26 Ethylene Dichloride Production ....... 29 Perchloroethylene and Trichloroethylene Production . ............. 38 Chlorination of Organic Precursors in Water. 44 Miscellaneous Chloroform Emission Sources . 61 5. Source Test Procedures ............... 63 References 66 Appendix - Derivation of Emission Factors from Chloroform Production .................... A-1 References for Appendix ............... A-23 iii FIGURES Number Page 1 Chemical use tree for chloroform ............ 10 2 Basic operations that may be used in the methanol hydrochlorination/methyl chloride chlorination process 12 3 Basic operations that may be used in the methane chlorination process ................ -
Equilibrium Critical Phenomena in Fluids and Mixtures
: wil Phenomena I Fluids and Mixtures: 'w'^m^ Bibliography \ I i "Word Descriptors National of ac \oo cop 1^ UNITED STATES DEPARTMENT OF COMMERCE • Maurice H. Stans, Secretary NATIONAL BUREAU OF STANDARDS • Lewis M. Branscomb, Director Equilibrium Critical Phenomena In Fluids and Mixtures: A Comprehensive Bibliography With Key-Word Descriptors Stella Michaels, Melville S. Green, and Sigurd Y. Larsen Institute for Basic Standards National Bureau of Standards Washington, D. C. 20234 4. S . National Bureau of Standards, Special Publication 327 Nat. Bur. Stand. (U.S.), Spec. Publ. 327, 235 pages (June 1970) CODEN: XNBSA Issued June 1970 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 (Order by SD Catalog No. C 13.10:327), Price $4.00. NATtONAL BUREAU OF STAHOAROS AUG 3 1970 1^8106 Contents 1. Introduction i±i^^ ^ 2. Bibliography 1 3. Bibliographic References 182 4. Abbreviations 183 5. Author Index 191 6. Subject Index 207 Library of Congress Catalog Card Number 7O-6O632O ii Equilibrium Critical Phenomena in Fluids and Mixtures: A Comprehensive Bibliography with Key-Word Descriptors Stella Michaels*, Melville S. Green*, and Sigurd Y. Larsen* This bibliography of 1088 citations comprehensively covers relevant research conducted throughout the world between January 1, 1950 through December 31, 1967. Each entry is charac- terized by specific key word descriptors, of which there are approximately 1500, and is indexed both by subject and by author. In the case of foreign language publications, effort was made to find translations which are also cited. Key words: Binary liquid mixtures; critical opalescence; critical phenomena; critical point; critical region; equilibrium critical phenomena; gases; liquid-vapor systems; liquids; phase transitions; ternairy liquid mixtures; thermodynamics 1. -
THE STUDY of EXCESS REFRACTIVE INDICES of BENZENE+ETHANOL and HEXANE+ETHANOL BINARY SYSTEMS Dilbar Bozorova1, Shukur Gofurov2, Kokhkharov A
Senhri Journal of Multidisciplinary Studies, Vol. 5, No. 1 (January - June 2020), p. 19-23 Senhri Journal of Multidisciplinary Studies 2456-3757 (P) 2582-6840 (e) A Journal of Pachhunga University College Vol. 05, No. 01 (A Peer Reviewed Journal) Jan.-June, 2020 https://senhrijournal.ac.in 10.36110/sjms.2020.05.01.002 THE STUDY OF EXCESS REFRACTIVE INDICES OF BENZENE+ETHANOL AND HEXANE+ETHANOL BINARY SYSTEMS Dilbar Bozorova1, Shukur Gofurov2, Kokhkharov A. M.1 & Oksana B. Ismailova 3,4* 1Ion-plasma and Laser Technologies Institute, Tashkent, Uzbekistan 2University of Tsukuba, Japan 3Turin Polytechnic University in Tashkent, Uzbekistan 4Uzbek-Japan Innovation Center of Youth, Tashkent, Uzbekistan * [email protected] Oksana B. Ismailova: https://orcid.org/0000-0001-8972-546X ABSTRACT In many technological processes, ethanol solvents and their mixtures are actively used to prepare nanostructured matrices, substrates and devices. A change in the concentration of one of the components leads to a change in the structure as a whole, affecting a number of quantities, such as the electrical conductivity of solutions, the diffusion coefficient, and the thermodynamics of processes, which is important to take into account when selecting optimal systems that use new nanomaterials with predetermined properties and characteristics for targeted preparation. The most informative method in the study of structural processes associated with the cluster formation of molecules is the method of refractometry. In this work, the refractive indices measured for binary system benzene+ethanol and hexane+ethanol at the 298.15K and the atmospheric pressure are reported. The refractive indices were measured over a wide range of benzene, hexane and ethanol concentrations (0÷1.0 mole fractions). -
A Hansen Solubility Parameter Approach
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Sussex Research Online Understanding solvent spreading for Langmuir deposition of nanomaterial films: A Hansen solubility parameter approach Matthew J. Large,∗ Sean P. Ogilvie, Alice A. K. King, and Alan B. Dalton∗ University of Sussex, Falmer, Brighton, BN1 9RH, United Kingdom E-mail: [email protected]; [email protected] Abstract In order to prepare high-quality Langmuir films of two-dimensional materials it is important to select a solvent optimized for both exfoliation and spreading at the air-water interface. Whilst it is generally accepted that exfoliation and stabilisation of two-dimensional materials is well-described using the Hansen solubility parameter theory, a complementary description of solvent spreading behaviour is lacking. To this end we develop an understanding of solvent spreading using a Hansen sol- ubility parameter framework. Our model accurately predicts the behaviour of both water-immiscible and water-miscible solvents in Langmuir film formation experiments. We demonstrate that spreading behaviour can be modified by controlling the surface pressure of the subphase using an amphiphilic species and accordingly utilise this ap- proach to determine the maximum spreading pressure for a selection of solvents. Ultimately, by building on this understanding we open up additional routes to optimize the preparation of Langmuir films of two-dimensional materials and other nanoparticles. Keywords: Langmuir film, spreading solvent, interfacial interaction 1 Introduction Langmuir film formation (combined with Blodgett or Schaefer deposition methods) has emerged as an attractive method for preparation of large-area, particulate monolayer films of liquid-exfoliated graphene1{4 and other two-dimensional (2D) nanomaterials. -
LIQUID VISCOSITY and CHEMICAL CONSTITUTION of ORGANIC COMPOUNDS : a NEW CORRELATION Mmw and a COMPILATION of LITERATURE DATA
vìi ιΤ»Αϋ.ΓΪ*>*ν >tíÀí.k *ΊιπίιΠ IFIULJ-V.!·» 'ft' Λ'. -låiiSiip ¡Ili^iilfeÉ COMMISSION OF THE EUROPEAN COMMUNITIES ■Mié LIQUID VISCOSITY AND CHEMICAL CONSTITUTION OF ORGANIC COMPOUNDS : A NEW CORRELATION mMW AND A COMPILATION OF LITERATURE DATA by D. VAN VELZEN (Euratom) R. LOPES CARDOZO (A.K.Z.O., Albatros Koninklijke Zout Organon, Hengelo, the Netherlands) H. LANGENKAMP (Euratom) 1972 Joint Nuclear Research Centre Ispra Establishment Italy i Chemistry wmSËSS^gSSXÊÊ. m -li LEGAL NOTICE iiíliip mm•m' This document was prepared under the sponsorship of the CommissioM'Ai n of the European Communities. mr 'MÈwffi!mw-'< Neither the Commission of the European Communities, its contractors nor any person acting on their behalf: make any warranty or representation, express or implied, with respect to the accuracy, completeness, or usefulness of the information contained in this document, or that the use of any information, apparatus, method or process disclosed in this document may not infringe privately owned rights; or assume any liability.mtmmEEm with respect to the use of, or fo r damages resultin11.11g $ from the use of any information, apparatus, method or process disclosed in this document. «If ;-«Thi s report is on sale at the addresses listed on cover page iliPili4 i ¡Éill¡p^ ommission of the Europeanui upean Communitievjommunmes D.G. XIII C.I.D. {VTI-f Ïm4w 29, rue Aldringen xembourg Jw i $m M ,**■ ii '.»■>« 'f f F* ■*[..-■: UI: J Uni f||i »sira This document was reproduced on the basis of the best available copy. mm ιΛ« EUR 4735 e LIQUID VISCOSITY AND CHEMICAL CONSTITUTION OF ORGANIC COMPOUNDS : A NEW CORRELATION AND A COMPILATION OF LITERATURE DATA by D. -
Pentane, Hexane, and Heptane - in a Supersonic Nozzle
Investigating the Phase Transitions of lower n-alkanes – pentane, hexane, and heptane - in a supersonic nozzle DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University By Kehinde Emeka Ogunronbi, M.S. Graduate Program in Chemical Engineering The Ohio State University 2019 Dissertation Committee: Barbara E. Wyslouzil, Advisor Isamu Kusaka Nicholas Brunelli Copyright by Kehinde Emeka Ogunronbi 2019 Abstract n-Alkanes play important roles in our everyday lives, and they are basic constituents of many complex lipid molecules. A knowledge of the phase behavior of these aliphatic hydrocarbons provides insight into the behavior of any given lipid class, as there are interesting similarities between chain packing in normal alkanes and other aliphatic lipids. The importance of saturated aliphatic hydrocarbons is not limited to terrestrial applications, as interplanetary studies have shown that they are both major and minor components of the giant planet atmospheres and Saturn’s moon -Titan. Thus, in these situations, short chain alkanes can play a role similar to that of water on earth. Nucleation is a phenomenon that initiates many phase transitions, and supersonic nozzles are characterized by a large temperature gradient that results in high supersaturations and nucleation rates. Therefore, the goal of this work is to study the phase transitions of lower n-alkanes in a supersonic nozzle. First, we investigate and expand the vapor to liquid nucleation and condensation database for lower n-alkanes – pentane, hexane, and heptane - over a broad range of temperatures and partial pressures. Secondly, we apply the first and second nucleation theorems to determine the properties of the critical clusters of these chain molecules and advance our understanding of the nucleation physics. -
Chemical Response Guide
CHLOROFORM Dans la même collection Acide phosphorique, 2008 - 76 p. Acide sulfurique, 2006 - 64 p. Acrylate d’éthyle, 2006 - 57 p. Ammoniac, 2006 - 68 p. Benzène, 2004 - 56 p. Chlorure de vinyle, 2004 - 50 p. 1,2-Dichloroéthane, 2005 - 60 p. Diméthyldisulfure, 2007 - 54 p. Essence sans plomb, 2008 - 56 p. Hydroxyde de sodium en solution à 50 %, 2005 - 56 p. E.U. Classification: Méthacrylate de méthyle stabilisé, 2008 - 72 p. Méthyléthylcétone, 2009 - 70 p. Styrène, 2004 - 62 p. Xylènes, 2007 - 69 p. UN n°: 1888 Centre de documentation, de recherche et d’expérimentations sur les pollutions accidentelles des eaux 715 rue Alain Colas, CS 41836, F 29218 BREST CEDEX 2 MARPOL Classification: Y Tél. +33 (0)2 98 33 10 10 - Fax +33 (0)2 98 44 91 38 Cedre Courriel : [email protected] - Internet : http://www.cedre.fr SEBC Classification: SD Guide d’intervention chimique : Chloroforme ISBN 978-2-87893-099-3 ISSN 1950-0556 © Cedre - 2011 CHEMICAL RESPONSE GUIDE couverture.indd 1 11/08/2011 14:07:10 Cedre Chloroform Chemical Response Guide CHLOROFORM PRACTICAL GUIDE INFORMAT I ON DEC I S I ON -MAK I NG RESPONSE This document was drafted by Cedre (the Centre of Documentation, Research and Experimentation on Accidental Water Pollution) with financial support and technical guidance from ARKEMA and financial Warning support from the French Navy. Certain data, regulations, values and Cedre norms may be liable to change sub- sequent to publication. We recom- mend that you check them. The information contained in this guide is the result of research and experimentation conducted by Cedre. -
Chemical Thermodynamics
CHEMICAL THERMODYNAMICS Handbook of Exercises Valentim Maria Brunheta Nunes 2013 Chemical Thermodynamics _____________________________________________________________________________________ "A theory is the more impressive the greater the simplicity of its premises, the more varied the kinds of things that it relates and the more extended the area of its applicability. Therefore classical thermodynamics has made a deep impression on me. It is the only physical theory of universal content which I am convinced, within the areas of the applicability of its basic concepts, will never be overthrown." -- Einstein (1949) INTRODUCTION Thermodynamics it’s a discipline that is very important for many engineering degree programs like Chemical and Biochemical Engineering, Environment Engineering or Mechanical Engineering. With the Chemical Thermodynamics course we intend to introduce the principles of thermodynamics, and apply them to systems, that are solids, liquids or gases, with an interest in chemical engineering, don’t forgetting environmental issues. This course is also fundamental in the development of important calculation techniques in engineering. This exercise book will serve to accomplish the lectures, and the problems presented seek to encompass the entire program taught to prepare students for the final evaluations. The resolution of examinations of previous academic years may be also quite helpful for the students. Handbook of Exercises 2 _________________________________________________________________________________ Chemical Thermodynamics _____________________________________________________________________________________ 1st Series of Exercises - Gaseous State 1. Calculate the volume occupied by 3 moles of a perfect gas at 2 bar and 350 K. 2. Calculate the final pressure when 1 mole of nitrogen at 300 K and 100 atm is heated, at constant volume, until attaining 500 K. 3. The mass percentage of dry air at sea level is approximately: N2, 75%; O2, 23.2% and Ar, 1.3%. -
Predicting the Viscosity of Liquid Mixtures Consisting of N-Alkane
Predicting the viscosity of liquid mixtures consisting of n-alkane, alkylbenzene and cycloalkane species based on molecular description Thanh-Binh Nguyen,1,2,3 and Velisa Vesovic2,* 1. Faculty of Chemical Engineering, The University of Danang - University of Science and Technology, 54 Nguyen Luong Bang St., Danang city, Vietnam. 2. Department of Earth Science and Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, United Kingdom. 3 Qatar Carbonates and Carbon Storage Research Centre (QCCSRC), Imperial College London, London SW7 2AZ, UK * To whom correspondence should be addressed. E-mail: [email protected] 1 Abstract 1-component Extended Hard-Sphere (1-cEHS) model has been developed recently to predict the viscosity of liquid, n-alkane mixtures. It represents a mixture by a single pseudo- component characterized by an appropriate molecular weight and calculates the viscosity by means of the modified, extended hard-sphere model (EHS) that makes use of a universal function relating reduced viscosity to reduced volume. In this work we have extended the model to also predict the viscosity of mixtures containing alkylbenzene and cycloalkane species. Furthermore, we have developed a new 3-component Extended Hard-Sphere (3- cEHS) model which requires only a knowledge of the overall composition of n-alkane, alkylbenzene and cycloalkane species. Extensive comparison with the available experimental data indicates that both models (1-cEHS and 3-cEHS) predict the viscosity of binary and multicomponent mixtures containing n-alkane, alkylbenzene and cycloalkane species with uncertainty of 5-10%. The proposed models are a precursor of a new family of models that do not require a knowledge of the detailed composition of the mixture, but still take advantage of the underlying molecular description.