The interference of tetrachloromethane in the measurement of benzene in air by Gas Chromatography - Photoionisation Detector (GC-PID) Cristina Romero-Trigueros1, Esther González 2, Marta Doval Miñarro3, Enrique González Ferradás2 5 1Dipartimento di Scienze Agro-Ambientali e Territoriali, University of Bari Aldo Moro, Via Amendola, 165/A, 70126, Bari, Italy 2Chemical Engineering Department, School of Chemistry, University of Murcia, 30071, Murcia, Spain 3Chemical and Environmental Engineering Department, Technical University of Cartagena, Paseo Alfonso XIII, 52, 30203 Cartagena, Murcia, Spain 10 Correspondence to: Esther González (
[email protected]) Abstract. The European Union requires that benzene in air is continuously measured due to its toxicity and widespread presence in the population nuclei, mainly motivated by vehicle emissions. The reference measuring technique is gas chromatography (GC). Automatic chromatographs used in monitoring stations must verify the operating conditions 15 established in Standard EN 14662 part 3, which includes a type approval section with a number of tests that analysers must pass. Among these tests, the potential interference of a number of compounds is evaluated. The 2005 version of the mentioned standard requires the evaluation of the potential interference of tetrachloromethane (TCM). The 2015 version eliminates TCM as a potential interferent. Although most consumer uses of TCM have been banned, recent studies have measured significant concentrations of TCM in air. In this paper, the potential interference