222 SURFACE CO2, CH4 AND RN CONCENTRATIONS AND EMISSIONS OVER RUSSIA FROM OBSERVATIONS IN TROICA EXPERIMENTS E.V. Berezina A.M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences, 3 Pyzhevsky lane, 119017 Moscow, Russia
[email protected] Estimation of greenhouse gases emissions is a very important problem but it is complex enough because of nonunifornm distribution of greenhouse gases sources and sinks in the surface atmospheric layer. A chemically inert radioactive gas 222Rn emitted from the soil more or less uniformly over the continents [Biraud at al., 2000] can help in solving this problem. The only significant sink of 222Rn is a radioactive decay and its half-life (~3.8 days) is long enough to use it as a reference tracer for investigations of different atmospheric processes including emissions of different compounds over land [1-5]. 222 In this paper the Rn tracer method for estimation of biogenic CO2 and CH4 emissions over continental Russia from continuous measurements in railroad expeditions TROICA (Transcontinental Observations Into the Chemistry of the Atmosphere) along the Trans-Siberian railroad crossing the immense territory of Russia with different meteorological and geological features is presented. 222 Surface CO2, CH4 and Rn concentrations as well as meteorological parameters were measured simultaneously at a height of about 4-5 meters during the mobile laboratory movement in 7 expeditions 222 from Moscow to Vladivostok and back. The obtained data allowed us to investigate CO2, CH4 and Rn variations over the continent in detail. It was noted that night concentrations of the observed gases are significantly higher than the day ones that is caused by the influence of temperature inversions.