Glaciers and Their Significance for the Earth Nature - Vladimir M
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Proton Ordering and Reactivity of Ice
1 Proton ordering and reactivity of ice Zamaan Raza Department of Chemistry University College London Thesis submitted for the degree of Doctor of Philosophy September 2012 2 I, Zamaan Raza, confirm that the work presented in this thesis is my own. Where information has been derived from other sources, I confirm that this has been indicated in the thesis. 3 For Chryselle, without whom I would never have made it this far. 4 I would like to thank my supervisors, Dr Ben Slater and Prof Angelos Michaelides for their patient guidance and help, particularly in light of the fact that I was woefully unprepared when I started. I would also like to express my gratitude to Dr Florian Schiffmann for his indispens- able advice on CP2K and quantum chemistry, Dr Alexei Sokol for various discussions on quantum mechanics, Dr Dario Alfé for his incredibly expensive DMC calculations, Drs Jiri Klimeš and Erlend Davidson for advice on VASP, Matt Watkins for help with CP2K, Christoph Salzmann for discussions on ice, Dr Stefan Bromley for allowing me to work with him in Barcelona and Drs Aron Walsh, Stephen Shevlin, Matthew Farrow and David Scanlon for general help, advice and tolerance. Thanks and also apologies to Stephen Cox, with whom I have collaborated, but have been unable to contribute as much as I should have. Doing a PhD is an isolating experience (more so in the Kathleen Lonsdale building), so I would like to thank my fellow students and friends for making it tolerable: Richard, Tiffany, and Chryselle. Finally, I would like to acknowledge UCL for my funding via a DTA and computing time on Legion, the Materials Chemistry Consortium (MCC) for computing time on HECToR and HPC-Europa2 for the opportunity to work in Barcelona. -
Ice Ic” Werner F
Extent and relevance of stacking disorder in “ice Ic” Werner F. Kuhsa,1, Christian Sippela,b, Andrzej Falentya, and Thomas C. Hansenb aGeoZentrumGöttingen Abteilung Kristallographie (GZG Abt. Kristallographie), Universität Göttingen, 37077 Göttingen, Germany; and bInstitut Laue-Langevin, 38000 Grenoble, France Edited by Russell J. Hemley, Carnegie Institution of Washington, Washington, DC, and approved November 15, 2012 (received for review June 16, 2012) “ ” “ ” A solid water phase commonly known as cubic ice or ice Ic is perfectly cubic ice Ic, as manifested in the diffraction pattern, in frequently encountered in various transitions between the solid, terms of stacking faults. Other authors took up the idea and liquid, and gaseous phases of the water substance. It may form, attempted to quantify the stacking disorder (7, 8). The most e.g., by water freezing or vapor deposition in the Earth’s atmo- general approach to stacking disorder so far has been proposed by sphere or in extraterrestrial environments, and plays a central role Hansen et al. (9, 10), who defined hexagonal (H) and cubic in various cryopreservation techniques; its formation is observed stacking (K) and considered interactions beyond next-nearest over a wide temperature range from about 120 K up to the melt- H-orK sequences. We shall discuss which interaction range ing point of ice. There was multiple and compelling evidence in the needs to be considered for a proper description of the various past that this phase is not truly cubic but composed of disordered forms of “ice Ic” encountered. cubic and hexagonal stacking sequences. The complexity of the König identified what he called cubic ice 70 y ago (11) by stacking disorder, however, appears to have been largely over- condensing water vapor to a cold support in the electron mi- looked in most of the literature. -
Calving Processes and the Dynamics of Calving Glaciers ⁎ Douglas I
Earth-Science Reviews 82 (2007) 143–179 www.elsevier.com/locate/earscirev Calving processes and the dynamics of calving glaciers ⁎ Douglas I. Benn a,b, , Charles R. Warren a, Ruth H. Mottram a a School of Geography and Geosciences, University of St Andrews, KY16 9AL, UK b The University Centre in Svalbard, PO Box 156, N-9171 Longyearbyen, Norway Received 26 October 2006; accepted 13 February 2007 Available online 27 February 2007 Abstract Calving of icebergs is an important component of mass loss from the polar ice sheets and glaciers in many parts of the world. Calving rates can increase dramatically in response to increases in velocity and/or retreat of the glacier margin, with important implications for sea level change. Despite their importance, calving and related dynamic processes are poorly represented in the current generation of ice sheet models. This is largely because understanding the ‘calving problem’ involves several other long-standing problems in glaciology, combined with the difficulties and dangers of field data collection. In this paper, we systematically review different aspects of the calving problem, and outline a new framework for representing calving processes in ice sheet models. We define a hierarchy of calving processes, to distinguish those that exert a fundamental control on the position of the ice margin from more localised processes responsible for individual calving events. The first-order control on calving is the strain rate arising from spatial variations in velocity (particularly sliding speed), which determines the location and depth of surface crevasses. Superimposed on this first-order process are second-order processes that can further erode the ice margin. -
A Globally Complete Inventory of Glaciers
Journal of Glaciology, Vol. 60, No. 221, 2014 doi: 10.3189/2014JoG13J176 537 The Randolph Glacier Inventory: a globally complete inventory of glaciers W. Tad PFEFFER,1 Anthony A. ARENDT,2 Andrew BLISS,2 Tobias BOLCH,3,4 J. Graham COGLEY,5 Alex S. GARDNER,6 Jon-Ove HAGEN,7 Regine HOCK,2,8 Georg KASER,9 Christian KIENHOLZ,2 Evan S. MILES,10 Geir MOHOLDT,11 Nico MOÈ LG,3 Frank PAUL,3 Valentina RADICÂ ,12 Philipp RASTNER,3 Bruce H. RAUP,13 Justin RICH,2 Martin J. SHARP,14 THE RANDOLPH CONSORTIUM15 1Institute of Arctic and Alpine Research, University of Colorado, Boulder, CO, USA 2Geophysical Institute, University of Alaska Fairbanks, Fairbanks, AK, USA 3Department of Geography, University of ZuÈrich, ZuÈrich, Switzerland 4Institute for Cartography, Technische UniversitaÈt Dresden, Dresden, Germany 5Department of Geography, Trent University, Peterborough, Ontario, Canada E-mail: [email protected] 6Graduate School of Geography, Clark University, Worcester, MA, USA 7Department of Geosciences, University of Oslo, Oslo, Norway 8Department of Earth Sciences, Uppsala University, Uppsala, Sweden 9Institute of Meteorology and Geophysics, University of Innsbruck, Innsbruck, Austria 10Scott Polar Research Institute, University of Cambridge, Cambridge, UK 11Institute of Geophysics and Planetary Physics, Scripps Institution of Oceanography, University of California, San Diego, La Jolla, CA, USA 12Department of Earth, Ocean and Atmospheric Sciences, University of British Columbia, Vancouver, British Columbia, Canada 13National Snow and Ice Data Center, University of Colorado, Boulder, CO, USA 14Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada 15A complete list of Consortium authors is in the Appendix ABSTRACT. The Randolph Glacier Inventory (RGI) is a globally complete collection of digital outlines of glaciers, excluding the ice sheets, developed to meet the needs of the Fifth Assessment of the Intergovernmental Panel on Climate Change for estimates of past and future mass balance. -
Edges of Ice-Sheet Glaciology
Important Things Ice Sheets Do, but Ice Sheet Models Don’t Dr. Robert Bindschadler Chief Scientist Hydrospheric and Biospheric Sciences Laboratory NASA Goddard Space Flight Center [email protected] I’ll talk about • Why we need models – from a non-modeler • Why we need good models – recent observations have destroyed confidence in present models • Recent ice-sheet surprises • Responsible physical processes “…understanding of (possible future rapid dynamical changes in ice flow) is too limited to assess their likelihood or provide a best estimate or an upper bound for sea level rise.” IPCC Fourth Assessment Report, Summary for Policy Makers (2007) Future Sea Level is likely underestimated A1B IPCC AR4 (2007) Ice Sheets matter Globally Source: CReSIS and NASA Land area lost by 1-meter rise in sea level Impact of 1-meter sea level rise: Source: Anthoff et al., 2006 Maldives 20th Century Greenland Ice Sheet Sea level Change (mm/a) -1 0 +1 accumulation 450 Gt/a melting 225 Gt/a ice flow 225 Gt/a Approximately in “mass balance” 21st Century Greenland Ice Sheet Sea level Change (mm/a) -1 0 +1 accumulation melting ice flow Things could get a little better or a lot worse Increased ice flow will dominate the future rate of change A History Lesson • Less ice in HIGH SEA LEVEL Less warmer ice climates • Ice sheets More shrink faster LOW ice than they TEMPERATURE WARM grow • Sea level change is not COLD THEN NOW smooth Time Decreasing Mass Balance (Source: Luthcke et al., unpub.) Greenland Ice Sheet Mass Balance GREENLAND (Source: IPCC FAR) Antarctic Ice Sheet Mass Balance ANTARCTICA (Source: IPCC FAR) Pace of ice sheet changes have astonished experts is the common agent behind these changes Ice sheets HATE water! Fastest Flow at the Edges Interior: 1000’s meters thick and slow Perimeter: 100’s meters thick and fast Source: Rignot and Thomas Response time and speed of perturbation propagation are tied directly to ice flow speed 1. -
Thermodynamic Stability of Hydrogen Hydrates of Ice Ic and II Structures
PHYSICAL REVIEW B 82, 144105 ͑2010͒ Thermodynamic stability of hydrogen hydrates of ice Ic and II structures Lukman Hakim, Kenichiro Koga, and Hideki Tanaka Department of Chemistry, Faculty of Science, Okayama University, 3-1-1 Tsushima, Kitaku, Okayama 700-8530, Japan ͑Received 6 August 2010; published 13 October 2010͒ The occupancy of hydrogen inside the voids of ice Ic and ice II, which gives two stable hydrogen hydrate compounds at high pressure and temperature, has been examined using a hybrid grand-canonical Monte Carlo simulation in wide ranges of pressure and temperature. The simulation reproduces the maximum hydrogen-to- water molar ratio and gives a detailed description on the hydrogen influence toward the stability of ice structures. A simple theoretical model, which reproduces the simulation results, provides a global phase dia- gram of two-component system in which the phase transitions between various phases can be predicted as a function of pressure, temperature, and chemical composition. A relevant thermodynamic potential and statistical-mechanical ensemble to describe the filled-ice compounds are discussed, from which one can derive two important properties of hydrogen hydrate compounds: the isothermal compressibility and the quantification of thermodynamic stability in term of the chemical potential. DOI: 10.1103/PhysRevB.82.144105 PACS number͑s͒: 64.70.Ja I. INTRODUCTION relative to other water-hydrogen composite phases in a wide range of thermodynamic conditions has been scarcely ex- Storage of hydrogen has been actively investigated to plored. On the other hand, constructing a global phase dia- meet the demand on environmentally clean and efficient gram is a tedious task from experimental view point, consid- hydrogen-based fuel.1 A search for practical hydrogen- ering the number of thermodynamic states to be explored. -
Ilulissat Icefjord
World Heritage Scanned Nomination File Name: 1149.pdf UNESCO Region: EUROPE AND NORTH AMERICA __________________________________________________________________________________________________ SITE NAME: Ilulissat Icefjord DATE OF INSCRIPTION: 7th July 2004 STATE PARTY: DENMARK CRITERIA: N (i) (iii) DECISION OF THE WORLD HERITAGE COMMITTEE: Excerpt from the Report of the 28th Session of the World Heritage Committee Criterion (i): The Ilulissat Icefjord is an outstanding example of a stage in the Earth’s history: the last ice age of the Quaternary Period. The ice-stream is one of the fastest (19m per day) and most active in the world. Its annual calving of over 35 cu. km of ice accounts for 10% of the production of all Greenland calf ice, more than any other glacier outside Antarctica. The glacier has been the object of scientific attention for 250 years and, along with its relative ease of accessibility, has significantly added to the understanding of ice-cap glaciology, climate change and related geomorphic processes. Criterion (iii): The combination of a huge ice sheet and a fast moving glacial ice-stream calving into a fjord covered by icebergs is a phenomenon only seen in Greenland and Antarctica. Ilulissat offers both scientists and visitors easy access for close view of the calving glacier front as it cascades down from the ice sheet and into the ice-choked fjord. The wild and highly scenic combination of rock, ice and sea, along with the dramatic sounds produced by the moving ice, combine to present a memorable natural spectacle. BRIEF DESCRIPTIONS Located on the west coast of Greenland, 250-km north of the Arctic Circle, Greenland’s Ilulissat Icefjord (40,240-ha) is the sea mouth of Sermeq Kujalleq, one of the few glaciers through which the Greenland ice cap reaches the sea. -
Searching for Crystal-Ice Domains in Amorphous Ices
PHYSICAL REVIEW MATERIALS 2, 075601 (2018) Searching for crystal-ice domains in amorphous ices Fausto Martelli,1,2,* Nicolas Giovambattista,3,4 Salvatore Torquato,2 and Roberto Car2 1IBM Research, Hartree Centre, Daresbury WA4 4AD, United Kingdom 2Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA 3Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210, USA 4The Graduate Center of the City University of New York, New York, New York 10016, USA (Received 7 May 2018; published 2 July 2018) Weemploy classical molecular dynamics simulations to investigate the molecular-level structure of water during the isothermal compression of hexagonal ice (Ih) and low-density amorphous (LDA) ice at low temperatures. In both cases, the system transforms to high-density amorphous ice (HDA) via a first-order-like phase transition. We employ a sensitive local order metric (LOM) [F. Martelli et al., Phys. Rev. B 97, 064105 (2018)] that can discriminate among different crystalline and noncrystalline ice structures and is based on the positions of the oxygen atoms in the first- and/or second-hydration shell. Our results confirm that LDA and HDA are indeed amorphous, i.e., they lack polydispersed ice domains. Interestingly, HDA contains a small number of domains that are reminiscent of the unit cell of ice IV,although the hydrogen-bond network (HBN) of these domains differs from the HBN of ice IV. The presence of ice-IV-like domains provides some support to the hypothesis that HDA could be the result of a detour on the HBN rearrangement along the Ih-to-ice-IV pressure-induced transformation. -
Modeling the Ice VI to VII Phase Transition
Modeling the Ice VI to VII Phase Transition Dawn M. King 2009 NSF/REU PROJECT Physics Department University of Notre Dame Advisor: Dr. Kathie E. Newman July 31, 2009 Abstract Ice (solid water) is found in a number of different structures as a function of temperature and pressure. This project focuses on two forms: Ice VI (space group P 42=nmc) and Ice VII (space group Pn3m). An interesting feature of the structural phase transition from VI to VII is that both structures are \self clathrate," which means that each structure has two sublattices which interpenetrate each other but do not directly bond with each other. The goal is to understand the mechanism behind the phase transition; that is, is there a way these structures distort to become the other, or does the transition occur through the breaking of bonds followed by a migration of the water molecules to the new positions? In this project we model the transition first utilizing three dimensional visualization of each structure, then we mathematically develop a common coordinate system for the two structures. The last step will be to create a phenomenological Ising-like spin model of the system to capture the energetics of the transition. It is hoped the spin model can eventually be studied using either molecular dynamics or Monte Carlo simulations. 1 Overview of Ice The known existence of many solid states of water provides insight into the complexity of condensed matter in the universe. The familiarity of ice and the existence of many structures deem ice to be interesting in the development of techniques to understand phase transitions. -
Glacier Movement
ISSN 2047-0371 Glacier Movement C. Scott Watson1 and Duncan Quincey1 1 School of Geography and water@leeds, University of Leeds ([email protected]) ABSTRACT: Quantification of glacier movement can supplement measurements of surface elevation change to allow an integrated assessment of glacier mass balance. Glacier velocity is also closely linked to the surface morphology of both clean-ice and debris-covered glaciers. Velocity applications include distinguishing active from inactive ice on debris-covered glaciers, identifying glacier surge events, or inferring basal conditions using seasonal observations. Surface displacements can be surveyed manually in the field using trigonometric principles and a total station or theodolite for example, or dGPS measurements, which allow horizontal and vertical movement to be quantified for accessible areas. Semi-automated remote sensing techniques such as feature tracking (using optical or radar imagery) and interferometric synthetic aperture radar (InSAR) (using radar imagery), can provide spatially distributed and multi-temporal velocity fields of horizontal glacier surface displacement. Remote-sensing techniques are more practical and can provide a greater distribution of measurements over larger spatial scales. Time-lapse imagery can also be exploited to track surface displacements, providing fine temporal and spatial resolution, although the latter is dependent upon the range between camera and glacier surface. This chapter outlines the costs, benefits, and methodological considerations -
Glacial Geomorphology☆ John Menzies, Brock University, St
Glacial Geomorphology☆ John Menzies, Brock University, St. Catharines, ON, Canada © 2018 Elsevier Inc. All rights reserved. This is an update of H. French and J. Harbor, 8.1 The Development and History of Glacial and Periglacial Geomorphology, In Treatise on Geomorphology, edited by John F. Shroder, Academic Press, San Diego, 2013. Introduction 1 Glacial Landscapes 3 Advances and Paradigm Shifts 3 Glacial Erosion—Processes 7 Glacial Transport—Processes 10 Glacial Deposition—Processes 10 “Linkages” Within Glacial Geomorphology 10 Future Prospects 11 References 11 Further Reading 16 Introduction The scientific study of glacial processes and landforms formed in front of, beneath and along the margins of valley glaciers, ice sheets and other ice masses on the Earth’s surface, both on land and in ocean basins, constitutes glacial geomorphology. The processes include understanding how ice masses move, erode, transport and deposit sediment. The landforms, developed and shaped by glaciation, supply topographic, morphologic and sedimentologic knowledge regarding these glacial processes. Likewise, glacial geomorphology studies all aspects of the mapped and interpreted effects of glaciation both modern and past on the Earth’s landscapes. The influence of glaciations is only too visible in those landscapes of the world only recently glaciated in the recent past and during the Quaternary. The impact on people living and working in those once glaciated environments is enormous in terms, for example, of groundwater resources, building materials and agriculture. The cities of Glasgow and Boston, their distinctive street patterns and numerable small hills (drumlins) attest to the effect of Quaternary glaciations on urban development and planning. It is problematic to precisely determine when the concept of glaciation first developed. -
Estimation of the Dependence of Ice Phenomena Trends on Air and Water Temperature in River
water Article Estimation of the Dependence of Ice Phenomena Trends on Air and Water Temperature in River Renata Graf Department of Hydrology and Water Management, Institute of Physical Geography and Environmental Planning, Adam Mickiewicz University in Poznan, Bogumiła Krygowskiego 10 str., 61-680 Poznan, Poland; [email protected] Received: 6 November 2020; Accepted: 9 December 2020; Published: 11 December 2020 Abstract: The identification of changes in the ice phenomena (IP) in rivers is a significant element of analyses of hydrological regime features, of the risk of occurrence of ice jam floods, and of the ecological effects of river icing (RI). The research here conducted aimed to estimate the temporal and spatial changes in the IP in a lowland river in the temperate climate (the Note´cRiver, Poland, Central Europe), depending on air temperature (TA) and water temperature (TW) during the multi-annual period of 1987–2013. Analyses were performed of IP change trends in three RI phases: freezing, when there appears stranded ice (SI), frazil ice (FI), or stranded ice with frazil ice (SI–FI); the phase of stable ice cover (IC) and floating ice (FoI); and the phase of stranded ice with floating ice (SI–FoI), frazil ice with floating ice (FI–FoI), and ice jams (IJs). Estimation of changes in IP in connection with TA and TW made use of the regression model for count data with a negative binomial distribution and of the zero-inflated negative binomial model. The analysis of the multi-annual change tendency of TA and TW utilized a non-parametric Mann–Kendall test for detecting monotonic trends with Yue–Pilon correction (MK–YP).