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004157Pm Strawberry Flavour 004157PM STRAWBERRY FLAVOUR The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 2 Version No: 1.1 Issue Date: 21/01/2021 Safety Data Sheet according to WHS and ADG requirements Print Date: 21/01/2021 S.GHS.AUS.EN SECTION 1 Identification of the substance / mixture and of the company / undertaking Product Identifier Product name: 004157PM STRAWBERRY FLAVOUR Chemical Name: Not Applicable Other means of identification: Not Available Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: INTEGRITY CHECK: Product contains BOTH an alcohol and an acid as ingredients. Details of the supplier of the safety data sheet Emergency telephone number Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation The Product Makers (Australia) Pty Ltd Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300 Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available Fax 61 3 9771 0301 Website www.theproductmakers.com Email Not Available SECTION 2 Hazards identification Classification of the substance or mixture HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. ChemWatch Hazard Ratings Flammability 0 Toxicity 1 0 = Minimum Body Contact 2 1 = Low 2 = Moderate Reactivity 0 3 = High Chronic 0 4 = Extreme Poisons Schedule Not Applicable Classification [1] Eye Irritation Category 2A, Skin Corrosion/Irritation Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI Label elements Hazard pictogram(s) Signal word: Warning Hazard statement(s) H319: Causes serious eye irritation. H315: Causes skin irritation. Precautionary statement(s) Prevention P280: Wear protective gloves/protective clothing/eye protection/face protection. Precautionary statement(s) Response Page 1 continued... Version No: 1.1 Page 2 of 12 Issue Date: 21/01/2021 Print Date: 21/01/2021 004157PM STRAWBERRY FLAVOUR P321: Specific treatment (see advice on this label). P362: Take off contaminated clothing and wash before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P302+P352: IF ON SKIN: Wash with plenty of water. P332+P313: If skin irritation occurs: Get medical advice/attention. Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal Not Applicable SECTION 3 Composition / information on ingredients Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 57-55-6 90-99 propylene glycol 118-71-8 1-10 maltol 105-54-4 <1 ethyl butyrate 554-12-1 <1 methyl propionate 64-19-7 <1 acetic acid glacial 706-14-9 <1 gamma-decalactone 7452-79-1 <1 ethyl 2-methylbutyrate 79-09-4 <1 propionic acid 116-53-0 <1 2-methylbutyric acid 5471-51-2 <1 4-(p-hydroxyphenyl)-2-butanone 16491-36-4 <1 cis-3-hexenyl butyrate 109-21-7 <1 butyl butyrate 3681-71-8 <1 cis-3-hexenyl acetate 2497-18-9 <1 trans-2-hexenyl acetate SECTION 4 First aid measures Description of first aid measures Eye Contact If this product comes in contact with the eyes: – Wash out immediately with fresh running water. – Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. – Seek medical attention without delay; if pain persists or recurs seek medical attention. – Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Skin Contact If skin contact occurs: – Immediately remove all contaminated clothing, including footwear. – Flush skin and hair with running water (and soap if available). – Seek medical attention in event of irritation. Inhalation – If fumes, aerosols or combustion products are inhaled remove from contaminated area. – Other measures are usually unnecessary. Ingestion – If swallowed do NOT induce vomiting. – If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. – Observe the patient carefully. – Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. – Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. – Seek medical advice. – If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus. Indication of any immediate medical attention and special treatment needed Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours. – Polyethylene glycols are generally poorly absorbed orally and are mostly unchanged by the kidney. – Dermal absorption can occur across damaged skin (e.g. through burns) leading to increased osmolality, anion gap metabolic acidosis, elevated calcium, low ionised calcium, CNS depression and renal failure. – Treatment consists of supportive care. [Ellenhorn and Barceloux: Medical Toxicology] Continued... Version No: 1.1 Page 3 of 12 Issue Date: 21/01/2021 Print Date: 21/01/2021 004157PM STRAWBERRY FLAVOUR Propylene glycol is primarily a CNS depressant in large doses and may cause hypoglycaemia, lactic acidosis and seizures. – The usual measures are supportive care and decontamination (Ipecac/ lavage/ activated charcoal/ cathartics), within 2 hours of exposure should suffice. – Check the anion gap, arterial pH, renal function and glucose levels. Ellenhorn and Barceloux: Medical Toxicology SECTION 5 Firefighting measures Extinguishing media – Alcohol stable foam. Special hazards arising from the substrate or mixture Fire Incompatibility – Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Advice for firefighters Fire Fighting – Alert Fire Brigade and tell them location and nature of hazard. Fire/Explosion Hazard – Combustible. Combustion products include: carbon dioxide (CO2) other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes. HAZCHEM Not Applicable SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills – Remove all ignition sources. Major Spills Moderate hazard. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage Precautions for safe handling Safe handling – Avoid all personal contact, including inhalation. – DO NOT allow clothing wet with material to stay in contact with skin Other information Store tightly closed under cool dry conditions in an approved storage area. Avoid exposure to light. Shelf Life : 12 months Conditions for safe storage, including any incompatibilities Suitable container – Metal can or drum – Packaging as recommended by manufacturer. Storage incompatibility – Glycols and their ethers undergo violent decomposition in contact with 70% perchloric acid. Acetic acid: – vapours forms explosive mixtures with air (above 39 C.) – reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide – reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus isocyanate, phosphorus trichloride, sodium peroxide, xylene – attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas – attacks many forms of rubber, plastics and coatings Continued... Version No: 1.1 Page 4 of 12 Issue Date: 21/01/2021 Print Date: 21/01/2021 004157PM STRAWBERRY FLAVOUR Alcohols – are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents. – Esters react with acids to liberate heat along with alcohols and acids. SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Propane-1,2-diol total: (vapour & 150 ppm / 474 Not Not propylene glycol Not Available Standards particulates) mg/m3 Available Available Australia Exposure Not Not propylene glycol Propane-1,2-diol: particulates only 10 mg/m3 Not Available Standards Available Available Australia Exposure acetic acid 37 mg/m3 / 15 Not Not Acetic acid 10 ppm / 25 mg/m3 Standards glacial ppm Available Available Australia Exposure Not Not propionic acid Propionic acid 10 ppm / 30 mg/m3 Not Available Standards Available Available Occupational Exposure Banding Ingredient Occupational
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