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Fundamental Flotation Behaviors of Chalcopyrite and Galena Using O-Isopropyl-N-Ethyl Thionocarbamate As a Collector
minerals Article Fundamental Flotation Behaviors of Chalcopyrite and Galena Using O-Isopropyl-N-Ethyl Thionocarbamate as a Collector Yongjie Bu ID , Yuehua Hu *, Wei Sun *, Zhiyong Gao ID and Runqing Liu School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China; [email protected] (Y.B.); [email protected] (Z.G.); [email protected] (R.L.) * Correspondence: [email protected] (Y.H.); [email protected] (W.S.); Tel.: +86-731-8830-482 (Y.H.); +86-0731-8883-6873 (W.S.) Received: 31 January 2018; Accepted: 12 March 2018; Published: 13 March 2018 Abstract: Copper and lead are two important and widely used metals in industry. Chalcopyrite (CuFeS2) is associated with galena (PbS) in ore, and it has been a research hotspot in separating galena from chalcopyrite by flotation. In this study, the flotation behaviors of chalcopyrite and galena were studied through flotation tests, adsorption measurements, solution chemistry calculation, Fourier transform infrared spectroscopy (FTIR) and molecular dynamics (MD) simulations. The results show that the floatability of chalcopyrite is better than that of galena in the presence of O-isopropyl-N-ethyl thionocarbamate (IPETC), and the recovery difference between chalcopyrite and galena is about 20% when IPETC is 7 × 10−4 mol/L at pH 9.5, while the floatability difference between the two minerals is significant. Competitive adsorption of OH− and IPETC on mineral surfaces leads to lower floatability of galena than that of chalcopyrite. IPETC is able to remove the hydration layer on mineral surfaces and then adsorb on active sites. The floatability of minerals is enhanced with the increase of their hydrophobicity. -
A Column Leaching Model of Low-Grade Chalcopyrite Ore: Mineral Preferences and Chemical Reactivity
minerals Article A Column Leaching Model of Low-Grade Chalcopyrite Ore: Mineral Preferences and Chemical Reactivity Heike Bostelmann and Gordon Southam * School of Earth and Environmental Sciences, The University of Queensland, St Lucia 4072, Australia; [email protected] * Correspondence: [email protected]; Tel.: +61-07-3365-8505 Received: 16 November 2020; Accepted: 8 December 2020; Published: 17 December 2020 Abstract: Bioleaching models to examine copper extraction from low-grade chalcopyrite ores were set up to identify the influence of pyrite on leaching efficacy. A combination of scanning electron microscopy and geochemical analysis showed that extraction was marginally enhanced by the addition of pyrite when using a combination of Leptospirillum ferrooxidans, an iron oxidiser, Acidithiobacillus thiooxidans, a sulphur oxidising species and Acidithiobacillus ferrooxidans, an iron and sulphur oxidiser. Extensive biofilms formed on the pyrite surfaces (>106 cells/mm2) but were severely limited on chalcopyrite, possessing approximately the same number of cells as quartz grains, an internal non-nutrient control “substrate” (with ca. 2 103 cells/mm2). The presence of dissolved copper did × not inhibit the growth of this consortium. Indirect “bioleaching” of chalcopyrite appears to be limited by proton activity at the chalcopyrite surface. Keywords: bioleaching; chalcopyrite; pyrite; low-grade ore 1. Introduction Economic processing of chalcopyrite ores through bioleaching, i.e., the mobilisation of metals from ore by microorganisms, has not been as successful as secondary copper sulphide leaching operations [1]. This chalcopyrite “problem” needs to be solved, as it is the dominant copper mineral in many low-grade copper deposits. This has resulted in large quantities of low-grade waste material being stockpiled or discarded in mining operations, as they are not economic to process, though they do contain massive quantities of metals (i.e., copper) simply due to their combined volume [1–3]. -
The Krásno Sn-W Ore District Near Horní Slavkov: Mining History, Geological and Mineralogical Characteristics
Journal of the Czech Geological Society 51/12(2006) 3 The Krásno Sn-W ore district near Horní Slavkov: mining history, geological and mineralogical characteristics Sn-W rudní revír Krásno u Horního Slavkova historie tìby, geologická a mineralogická charakteristika (47 figs, 1 tab) PAVEL BERAN1 JIØÍ SEJKORA2 1 Regional Museum Sokolov, Zámecká 1, Sokolov, CZ-356 00, Czech Republic 2 Department of Mineralogy and Petrology, National Museum, Václavské nám. 68, Prague 1, CZ-115 79, Czech Republic The tin-tungsten Krásno ore district near Horní Slavkov (Slavkovský les area, western Bohemia) belongs to the most important areas of ancient mining in the Czech Republic. The exceptionally rich and variable mineral associations, and the high number of mineral species, make this area one of the most remarkable mineralogical localities on a worldwide scale. The present paper reviews the data on geological setting of the ore district, individual ore deposits and mining history. Horní Slavkov and Krásno were known as a rich source of exquisite quality mineral specimens stored in numerous museum collections throughout Europe. The old museum specimens are often known under the German locality names of Schlaggenwald (= Horní Slavkov) and Schönfeld (=Krásno). The megascopic properties and paragenetic position of selected mineral classics are reviewed which include arsenopyrite, fluorapatite, fluorite, hübnerite, chalcopyrite, carpholite, cassiterite, quartz, molybdenite, rhodochrosite, sphalerite, topaz and scheelite. Key words: Sn-W ores; tin-tungsten mineralization; mining history; ore geology; mineralogy; Slavkovský les; Krásno, Horní Slavkov ore district; Czech Republic. Introduction valleys dissected parts of the area. In the ore district area, the detailed surface morphology is modified by large de- In the mining history of Central Europe, Bohemia and pressions caused by the collapse of old underground Moravia are known as important source of gold, silver, workings and by extensive dumps. -
40 Common Minerals and Their Uses
40 Common Minerals and Their Uses Aluminum Beryllium The most abundant metal element in Earth’s Used in the nuclear industry and to crust. Aluminum originates as an oxide called make light, very strong alloys used in the alumina. Bauxite ore is the main source aircraft industry. Beryllium salts are used of aluminum and must be imported from in fluorescent lamps, in X-ray tubes and as Jamaica, Guinea, Brazil, Guyana, etc. Used a deoxidizer in bronze metallurgy. Beryl is in transportation (automobiles), packaging, the gem stones emerald and aquamarine. It building/construction, electrical, machinery is used in computers, telecommunication and other uses. The U.S. was 100 percent products, aerospace and defense import reliant for its aluminum in 2012. applications, appliances and automotive and consumer electronics. Also used in medical Antimony equipment. The U.S. was 10 percent import A native element; antimony metal is reliant in 2012. extracted from stibnite ore and other minerals. Used as a hardening alloy for Chromite lead, especially storage batteries and cable The U.S. consumes about 6 percent of world sheaths; also used in bearing metal, type chromite ore production in various forms metal, solder, collapsible tubes and foil, sheet of imported materials, such as chromite ore, and pipes and semiconductor technology. chromite chemicals, chromium ferroalloys, Antimony is used as a flame retardant, in chromium metal and stainless steel. Used fireworks, and in antimony salts are used in as an alloy and in stainless and heat resisting the rubber, chemical and textile industries, steel products. Used in chemical and as well as medicine and glassmaking. -
Eparation of the Purest Aluminum Chemicals
III. MINERAL COMMODITIES A. INDIVIDUAL MINERAL COMMODITY REVIEWS ALUMINA & ALUMINUM A. Commodity Summary Aluminum, the third most abundant element in the earth's crust, is usually combined with silicon and oxygen in rock. Rock that contains high concentrations of aluminum hydroxide minerals is called bauxite. Although bauxite, with rare exceptions, is the starting material for the production of aluminum, the industry generally refers to metallurgical grade alumina extracted from bauxite by the Bayer Process, as the ore. Aluminum is obtained by electrolysis of this purified ore.1 The United States is entirely dependent on foreign sources for metallurgical grade bauxite. Bauxite imports are shipped to domestic alumina plants, which produce smelter grade alumina for the primary metal industry. These alumina refineries are in Louisiana, Texas, and the U.S. Virgin Islands.2 The United States must also import alumina to supplement this domestic production. Approximately 95 percent of the total bauxite consumed in the United States during 1994 was for the production of alumina. Primary aluminum smelters received 88 percent of the alumina supply. Fifteen companies operate 23 primary aluminum reduction plants. In 1994, Montana, Oregon, and Washington accounted for 35 percent of the production; Kentucky, North Carolina, South Carolina, and Tennessee combined to account for 20 percent; other states accounted for the remaining 45 percent. The United States is the world’s leading producer and the leading consumer of primary aluminum metal. Domestic consumption in 1994 was as follows: packaging, 30 percent; transportation, 26 percent; building, 17 percent; electrical, 9 percent; consumer durables, 8 percent; and other miscellaneous uses, 10 percent. -
The Electrical Resistivity of Galena, Pyrite, and Chalcopyrite
American Mineralogist, Volume61, pages248-259, 1976 The electricalresistivity of galena,pyrite, and chalcopyrite Doneln F. PnlorrronreNn RnlpH T. Suurv Departmentof Geologyand Geophysics,Uniuersity of Utah Salt Lake Cily, Utah 84112 Abstract. The sulfidesgalena, chalcopyrite, and pyrite are semiconductorswhose electrical resistivity and type are controlled by deviationsfrom stoichiometryand impurity content,and henceby their geochemicalenvironment. We measuredelectrical resistivity,type, and the impurity content (emissionspectrograph and microprobe) on small volumesof sample.Our results, together with those obtained from a comprehensiveliterature analysis, are usedto construct histogramsof the natural variability in carrier density and resistivity. Sulfur deficiency is the dominant defect in chalcopyrite and hence almost all natural samplesare n-type. lt appearsthat the copper/iron ratio is also important electrically,the copper-richsamples being the more resistive. lmportant donor deiectsin galena(z-type samples)are antimony and bismuth impurities, and sulfur vacancies;acceptor defects(p-type samples) include silver impurities and lead 'Mississippi vacancies.P-type samplesappear to be restrictedto Valley' and argentiferous deposits. In pyrite, electricallyactive impurities include cobalt, nickel, and copper as donors, and arsenicas an acceptor.Deviations from stoichiometry,in the same senseas galena,may be important. Pyritesfrom sedimentaryand epithermaldeposits are usuallyp-type if cupriferous sulfidesare not present.Samples from hypothermaldeposits -
Ofr034 85.Pdf
GALLIUM AND GERMANIUM POTENTIAL IN ALASKA by: Steven A. Fechner **k*t******k**************-k****f******* 1\ 34-85 I I UNITED STATES DEPARTMENT OF THE INTERIOR Donald P. Hodel, Secretary I BUREAU OF MINES I Robert C. Horton, Director I CONTENTS Page Abstract............. ................... .... .............. ... .... 1 Introduction........ ..................................... 1 Acknowledgments............................................. 2 Bureau of Mines investigation.................................. 2 Results............. .................. .......................... 3 Gallium............ ................... ...... .... ............. 3 Germanium....................... .......................... 6 Potential ......... ........................................ ...... 7 Conclusions and recommendations................................. 7 References............... ............... ................... 9 ILLUSTRATIONS 1. Gallium and germanium location map of Alaska............(in pocket) TABLES 1. Recoverable gallium and germanium concentrations in ore deposits............................................. ........ 4 2. Analytical results from selected mineral specimens and concentrates................................................ 5 i UNIT OF MEASURE ABBREVIATIONS USED IN THIS REPORT ppm Parts per million % Percent ii GALLIUM AND GERMANIUM POTENTIAL IN ALASKA By Steven A. Fechner 1/ ABSTRACT The U.S. Bureau of Mines is currently conducting a mineral study of the gallium and germanium potential in Alaska as part of the critical and strategic -
Taylor Creek Tin Distrisl
tions such as Paramount Canyon, the veins TaylorCreek tin distrisl- may reach three to four centimeters in width and a few meters in height and length. A dis- seminated cassiterite halo has been noted stratigraphy,structure, around the veins in Squaw Creek. A recently discoveredrhyolite porphyry has andtiming of mineralizationintensely altered the surrounding country rock near NM-59 where the road crossesthe Conti- byTed L. Egglestonand David L Norman,New Mexico lnstitute of Miningand Technology, Socorro, NM nental Divide. This porphyry is locally quartz- sericite altered and contains as much as I go pyrite. Similar intrusives have been mapped Introduction The Taylor Creek tin district is located in by Woodard (1982) southeast of the Taylor Primary tin depositscommonly are found in the north-central Black Range some 80 km Creek region. granitic plutonic environments where the tin west of Truth or Consequences,New Mexico occurs as cassiterite in greisen veins and as (fig. l). Cassiteritenuggets were first found in Regional geology disseminations in altered granite (Taylor, placers (Fries, 1940a). in the district in 1909 The tin-bearing Taylor Creek Rhyolite is 1979).In southwest New Mexico, however, tin Shortly wood tin thereafter, cassiterite and located in the Mogollon-Datil volcanic field, a occurs as cassiterite in hematite-cassiterite were porphyritic found in vein depositsin rhy- mid-Tertiary volcanic field consisting of inter- veins which cut Tertiary rhyolite domes and placer (Hill, olite lavas as well as in deposits mediate to -
The Mineralogical Fate of Arsenic During Weathering Of
THE MINERALOGICAL FATE OF ARSENIC DURING WEATHERING OF SULFIDES IN GOLD-QUARTZ VEINS: A MICROBEAM ANALYTICAL STUDY A Thesis Presented to the faculty of the Department of Geology California State University, Sacramento Submitted in partial satisfaction of the requirements for the degree of MASTER OF SCIENCE in Geology by Tamsen Leigh Burlak SPRING 2012 © 2012 Tamsen Leigh Burlak ALL RIGHTS RESERVED ii THE MINERALOGICAL FATE OF ARSENIC DURING WEATHERING OF SULFIDES IN GOLD-QUARTZ VEINS: A MICROBEAM ANALYTICAL STUDY A Thesis by Tamsen Leigh Burlak Approved by: __________________________________, Committee Chair Dr. Charles Alpers __________________________________, Second Reader Dr. Lisa Hammersley __________________________________, Third Reader Dr. Dave Evans ____________________________ Date iii Student: Tamsen Leigh Burlak I certify that this student has met the requirements for format contained in the University format manual, and that this thesis is suitable for shelving in the Library and credit is to be awarded for the project. _______________________, Graduate Coordinator ___________________ Dr. Dave Evans Date Department of Geology iv Abstract of THE MINERALOGICAL FATE OF ARSENIC DURING WEATHERING OF SULFIDES IN GOLD-QUARTZ VEINS: A MICROBEAM ANALYTICAL STUDY by Tamsen Leigh Burlak Mine waste piles within the historic gold mining site, Empire Mine State Historic Park (EMSHP) in Grass Valley, California, contain various amounts of arsenic and are the current subject of remedial investigations to characterize the arsenic present. In this study, electron microprobe, QEMSCAN (Quantitative Evaluation of Minerals by SCANning electron microscopy), and X-ray absorption spectroscopy (XAS) were used collectively to locate and identify the mineralogical composition of primary and secondary arsenic-bearing minerals at EMSHP. -
Selective Separation of Chalcopyrite from Galena Using a Green Reagent Scheme
minerals Article Selective Separation of Chalcopyrite from Galena Using a Green Reagent Scheme Kaile Zhao 1,2,3, Chao Ma 1,4, Guohua Gu 1,* and Zhiyong Gao 1,* 1 School of Minerals Processing and Bio-Engineering, Central South University, Changsha 410083, China; [email protected] (K.Z.); [email protected] (C.M.) 2 State Key Laboratory of Mineral Processing, Beijing 100162, China 3 Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu 610041, China 4 Hunan Research Academy of Environmental Sciences, Changsha 410004, China * Correspondence: [email protected] (G.G.); [email protected] (Z.G.) Abstract: The study of the depression effect of non-toxic depressants on the flotation separation of chalcopyrite from galena is of great importance for both industrial applications and theoretical research. The mixed depressant (DFinal) of four common inhibitors—sodium carboxymethyl cellulose, sodium silicate, sodium sulfite, and zinc sulfate—exhibited high selectivity during the separation of chalcopyrite from galena. Flotation tests on an industrial copper–lead bulk concentrate showed that using this depressant mixture can achieve highly efficient separation of chalcopyrite from galena at the natural pH of the pulp. Copper and lead concentrates were produced at grades of 21.88% (Cu) and 75.53% (Pb), with recoveries of 89.07% (Cu) and 98.26% (Pb). This showed a similar performance of DFinal with dichromate, which is a depressant that is widely used in industry, but without the environmental risks or the need for pH control. Zeta potential and Fourier transform infrared (FT-IR) results showed that interaction between the surface of the chalcopyrite and the mixed depressant Citation: Zhao, K.; Ma, C.; Gu, G.; was prevented by pre-treatment with a composite thiophosphate collector (CSU11), while the mixed Gao, Z. -
The Journal of the Geological Society of Jamaica Bauxite /Alumina Symposium 1971
I THE JOURNAL OF THE GEOLOGICAL SOCIETY OF JAMAICA BAUXITE /ALUMINA SYMPOSIUM 1971 LIBRARY 01' ISSUE '/// <°* PREFACE The recent Bauxite/Alumina Industry Symposium, which was sponsored by the Geo logical Society of Jamaica, was an attempt to bring together scientists and engineers to discuss the many problems relating to the industry. Ihe use of a multi-dicipli- nary approach has the advantage of permitting different lines of attack on the same problems, and thereby increasing the likelihood of finding solutions to them. Also, the interaction of people from the University, industry and Government greatly facilitates communication and allows problems to be evaluated and examined from different points of view. The bauxite/alumina industry was selected for discussion because of its significance in the economy of Jamaica. It contributed about 16% of the country's total Gross Domestic Product in 1970, and is the economic sector with the greatest potential for growth. Jamaica's present viable mineral industry only dates back to 19S2 when Reynolds Jamaica Mines, Limited started the export of kiln dried metallurgical grade bauxite ore. This was followed shortly by the production and export of alumina by the then Alumina Jamaica Limited (now Alcan Jamaica, Limited), a subsidiary of the Aluminium Company of Canada. The commencement of this new and major industry followed a successful exploration and development programme which resulted largely from the keen perception and perseverance of two men. First, Mr. R.F. Innis observed that some of the cattle lands on the St. Ann plateau were potential sources of aluminium ore, and then Sir Alfred DaCosta persisted in attempts to interest aluminium companies in undertaking exploration work here. -
CHALCOPYRITE Visiting
communication, 2000). The quarry is privately owned and permission must be obtained before CHALCOPYRITE visiting. 13. Groveland mine, near Felch. CuFeS2 Common as attractive microcrystals (DeMark, A widespread and common copper ore mineral 2000). occurring in veins, disseminations, or as replacement deposits. Northern Peninsula. Alpena County: 1. Lafarge Corporation, Great Lakes Region (formerly National Gypsum Company) quarry, Alpena: Rare, with calcite, dolomite, barite, sphalerite, marcasite, pyrite, and strontianite (Morris, 1983). 2. Paxton quarry, Paxton: With calcite, dolomite, quartz, sphalerite, pyrite, and marcasite (Morris, 1983). Baraga County: Ohio mines (Webster and Imperial mines), Imperial Heights near Michigamme: Associates are apatite, goethite, grunerite, graphite, palygorskite, carbonates, and Figure 56: A 1.3 mm chalcopyrite crystal on dolomite other sulfides (Morris, 1983; DeMark, 2000). from the Groveland mine, Dickinson County. Ramon Crystals on calcite rhombohedra. DeMark specimen, Dan Behnke photograph. Dickinson County: 1. Metronite quarry, 4 km east-northeast of Felch: In tremolite marble Gogebic County: 1. Eureka mine near Ramsay, (Randville Dolomite) along contact of aplite- sections 12 and 13, T47N, R46W: With pyrite and pegmatite dike and in marginal parts of the dike gold in quartz veins at contact between granite and itself (Heinrich, 1962b). 2. Rian’s quarry southeast the Palms slate (Dickey and Young, 1938). 2. of Felch: Similar occurrence (Pratt, 1954). 3. In Copp’s mine 10 km north of Marenisco: With iron formation of the Menominee iron range and galena, sphalerite, pyrite, and dolomite (Dana, also just north of Felch: Rare, usually associated 1892). 3. Roadside exposure on south side of with secondary pyrite (Pratt, 1954; Brower, 1968).