Taylor Creek Tin Distrisl
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Kennedyite, a New Mineral of the Pseudobrookite Series
676 Kennedyite, a new mineral of the pseudobrookite series. By O. VON KNORRING, Ph.D., and K. G. Cox, Ph.D. Research Institute of African Geology, University of Leeds. [Read 26 January 1961.] Summary. A new mineral with the approximate composition of F%MgTiaOxoand isostructural with pseudobrookite F%Ti2010has been observed in an olivine-augite- alkali-feldsparrock of the Karroo succession from the Mateke Hills area in south- eastern Southern Rhodesia. Chemical analysis and indexed X-ray powder data (a 9"77, b 9-95, c 3"73 ~.) of the mineral are given, and the name kennedyite is pro- posed. The name karrooite is proposed for the artificial product MgTi~O5. HE Mateke Hills area lies in the south-eastern part of Southern T Rhodesia and is characterized by several ring-complexes of late- Karroo age, which are emplaced in an extensive trough of Karroo vol- canics with generally thin basal sediments. The Karroo rocks rest un- conformably on the paragneisses of the Limpopo valley. The lower part of the Karroo volcanic succession consists mainly of olivine-rich rocks. These are in part extrusive and may be termed in general limburgites, and in part intrusive as sills, dykes, and plugs. The intrusive rocks are fine- to medium-grained and vary in composition from olivine-dolerites to pieritic and shonkinitic types. The specimens containing the new mineral were collected from what is believed to be an extensive sill at the base of the volcanic succession immediately overlying the Cave Sandstone. Petrographic description. Under the microscope the rock (table I, anal. 1) consists predominantly of broken and abraded olivine pheno- crysts from 1 to 5 mm. -
Fe2tio5) Based Thick films
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Serbian Academy of Science and Arts Digital Archive (DAIS) Accepted Manuscript Title: Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films Authors: Maria Vesna Nikolic, Zorka Z. Vasiljevic, Miloljub D. Lukovic, Vera P. Pavlovic, Jelena Vujancevic, Milan Radovanovic, Jugoslav B. Krstic, Branislav Vlahovic, Vladimir B. Pavlovic PII: S0925-4005(18)31683-6 DOI: https://doi.org/10.1016/j.snb.2018.09.063 Reference: SNB 25369 To appear in: Sensors and Actuators B Received date: 15-5-2018 Revised date: 23-8-2018 Accepted date: 15-9-2018 Please cite this article as: Nikolic MV, Vasiljevic ZZ, Lukovic MD, Pavlovic VP, Vujancevic J, Radovanovic M, Krstic JB, Vlahovic B, Pavlovic VB, Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films, Sensors and Actuators: B. Chemical (2018), https://doi.org/10.1016/j.snb.2018.09.063 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. Humidity sensing properties of nanocrystalline pseudobrookite (Fe2TiO5) based thick films Maria Vesna Nikolic1*, Zorka Z. Vasiljevic2, Miloljub D. Lukovic1, Vera P. Pavlovic3, Jelena Vujancevic2, Milan Radovanovic4, Jugoslav B. Krstic5, Branislav Vlahovic6, Vladimir B. -
Descriptive Mineralogy
Descriptive Mineralogy Oxides and Hydroxides Classification of the Minerals • Non-Silicates • Silicates – Native Elements – Orthosilicates – Halides – Sorosilicates – Sulfides – Cyclosilicates – Oxides – Chain Silicates – Hydroxides – Layer Silicates – Carbonates – Tektosilicates – Sulfates – Phosphates Simple Oxides • Hemioxides • Sesquioxides – Cuprite (Cu O) 2 – Corundum (Al2O3) – Ice (H O) 2 – Hematite (Fe2O3) • Monoxides – Bixbyite (Mn2O3) – Periclase (MgO) • Dioxides – Wüstite (FeO) – Rutile (TiO2) – Manganosite (MnO) – Anatase (TiO2) – Lime (CaO) – Brookite (TiO2) – Zincite (ZnO) – Cassiterite(SnO2) – Bromellite (BeO) – Pyrolusite(MnO2) – Tenorite (CuO) Simple Oxides Hemi-Oxides (M2O) • Ice (H2O) Hexagonal • Cuprite (Cu2O) • Why not Na2O? – (Na radius too large) Cuprite Cu2O • Occurrence: Low Temp Hydrothermal (Supergene) • Use: Minor ore of Cu Ice H2O Crystal System Hexagonal Point Group 6/mmm Space Group P63/mmc Optical Uniaxial Color Colorless Luster Vitreous Hardness 1.5 Density 0.95 Ice H2O Ice H2O Ice H2O High Pressure Phase Diagram Monoxides (MO) • Rocksalt oxides – Periclase MgO - Wüstite FeO – Manganosite MnO – Lime CaO – Bunsenite NiO • Zincite oxides: – Zincite ZnO, – Bromellite BeO • Other monoxides: – TenoriteCuO, Montroydite HgO Rocksalt Oxides MgO-FeO-MnO-CaO Crystal System Cubic Point Group 4/m-32/m Space Group Fm3m Optical Isotropic Periclase - Wüstite MgO - FeO Lower mantle phase Mg2SiO4 = MgSiO3 + MgO Ringwoodite = Perovskite + periclase Periclase MgO Sesquioxides (M2O3) • Corundum Group – Corundum Al2O3 – Hematite -
Geology and Beryl Deposits of the Peerless Pegmatite Pennington County South Dakota
Geology and Beryl Deposits of the Peerless Pegmatite Pennington County South Dakota GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-A This report concerns work done partly on behalj of the U. S. Atomic Energy Commission and is published with the permission of the , » Commission Geology and Beryl Deposits of the Peerless Pegmatite Pennington County South Dakota By DOUGLAS M. SHERllDAN, HAL G. STEPHENS, MORTIMER H. STAATZ and JAMES J. NORTON PEGMATITES AND OTHER PRECAMBRIAN ROCKS IN THE SOUTHERN BLACK HILLS GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-A This report concerns work done partly on behalf of the U. S. Atomic Energy Commission and is published with the permission of the Commission UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1957 UNITED STATES DEPARTMENT OF THE INTERIOR FRED A. SEATON, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director For sale by the Superintendent of Documents, U. S. Government Printing Office Washington 25, D. C. - Price $1.50 (paper cover) CONTENTS Page Page Abstract.__________________________________________ 1 Geology Continued Introduction _______________________________________ 1 Peerless pegmatite Continued Location_____________________________________ 1 Chemical composition......____________ 17 History and production________________________ 2 Origin________ ____________________ _. 18 Past and present investigations.__________________ 3 Mineral deposits_____________________________ 21 Acknowledgments__________________________ 4 Mica__ _________ _________________________ 21 Mine workings _____________________________________ -
Cassiterite Recovery from a Sulfide Ore Flotation Tailing by Combined Gravity and Flotation Separations
Physicochem. Probl. Miner. Process., 57(1), 2021, 206-215 Physicochemical Problems of Mineral Processing ISSN 1643-1049 http://www.journalssystem.com/ppmp © Wroclaw University of Science and Technology Received August 11, 2020; reviewed; accepted November 29, 2020 Cassiterite recovery from a sulfide ore flotation tailing by combined gravity and flotation separations Limin Zhang, Sultan an Khoso, Mengjie Tian, Wei Sun School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing Mineral Resources, Central South University, Changsha 410083, China Corresponding author: [email protected] (Mengjie Tian) Abstract: Cassiterite (SnO2), which is the most important Sn-containing mineral, is extensively found in large quantities in discarded tailings. The recovery of cassiterite from discarded sulfide ore flotation tailings can reduce resource wastage and environmental pollution. The gravity separation technique can recover multiple valuable minerals, such as cassiterite, whose densities considerably differ from those of their associated gangue minerals. However, its recovery efficiency rapidly decreases as the mineral particle grain size decreases. To recover the finer valuable mineral particles from gravity separation tailings, flotation separation can be used as a supplementary method. In this study, the gravity and flotation separation techniques are combined to recover cassiterite from a sulfide ore tailing. The Sn grade and recovery of the final concentrate is 31.40% and 88.05%, respectively, thus indicating a highly efficient recovery of cassiterite by using the combined gravity and flotation separation technique. This study can be an important reference for recovering cassiterite from low-Sn-grade tailings. -
Porphyry Deposits
PORPHYRY DEPOSITS W.D. SINCLAIR Geological Survey of Canada, 601 Booth St., Ottawa, Ontario, K1A 0E8 E-mail: [email protected] Definition Au (±Ag, Cu, Mo) Mo (±W, Sn) Porphyry deposits are large, low- to medium-grade W-Mo (±Bi, Sn) deposits in which primary (hypogene) ore minerals are dom- Sn (±W, Mo, Ag, Bi, Cu, Zn, In) inantly structurally controlled and which are spatially and Sn-Ag (±W, Cu, Zn, Mo, Bi) genetically related to felsic to intermediate porphyritic intru- Ag (±Au, Zn, Pb) sions (Kirkham, 1972). The large size and structural control (e.g., veins, vein sets, stockworks, fractures, 'crackled zones' For deposits with currently subeconomic grades and and breccia pipes) serve to distinguish porphyry deposits tonnages, subtypes are based on probable coproduct and from a variety of deposits that may be peripherally associat- byproduct metals, assuming that the deposits were econom- ed, including skarns, high-temperature mantos, breccia ic. pipes, peripheral mesothermal veins, and epithermal pre- Geographical Distribution cious-metal deposits. Secondary minerals may be developed in supergene-enriched zones in porphyry Cu deposits by weathering of primary sulphides. Such zones typically have Porphyry deposits occur throughout the world in a series significantly higher Cu grades, thereby enhancing the poten- of extensive, relatively narrow, linear metallogenic tial for economic exploitation. provinces (Fig. 1). They are predominantly associated with The following subtypes of porphyry deposits are Mesozoic to Cenozoic orogenic belts in western North and defined according to the metals that are essential to the eco- South America and around the western margin of the Pacific nomics of the deposit (metals that are byproducts or poten- Basin, particularly within the South East Asian Archipelago. -
Tungsten Minerals and Deposits
DEPARTMENT OF THE INTERIOR FRANKLIN K. LANE, Secretary UNITED STATES GEOLOGICAL SURVEY GEORGE OTIS SMITH, Director Bulletin 652 4"^ TUNGSTEN MINERALS AND DEPOSITS BY FRANK L. HESS WASHINGTON GOVERNMENT PRINTING OFFICE 1917 ADDITIONAL COPIES OF THIS PUBLICATION MAY BE PROCURED FROM THE SUPERINTENDENT OF DOCUMENTS GOVERNMENT PRINTING OFFICE WASHINGTON, D. C. AT 25 CENTS PER COPY CONTENTS. Page. Introduction.............................................................. , 7 Inquiries concerning tungsten......................................... 7 Survey publications on tungsten........................................ 7 Scope of this report.................................................... 9 Technical terms...................................................... 9 Tungsten................................................................. H Characteristics and properties........................................... n Uses................................................................. 15 Forms in which tungsten is found...................................... 18 Tungsten minerals........................................................ 19 Chemical and physical features......................................... 19 The wolframites...................................................... 21 Composition...................................................... 21 Ferberite......................................................... 22 Physical features.............................................. 22 Minerals of similar appearance................................. -
Heinrich&Candela TOG2 For
Research Collection Book Chapter Fluids and Ore Formation in the Earth's Crust Author(s): Heinrich, Christoph A.; Candela, Philip A. Publication Date: 2014 Permanent Link: https://doi.org/10.3929/ethz-b-000095425 Originally published in: 13, http://doi.org/10.1016/B978-0-08-095975-7.01101-3 Rights / License: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International This page was generated automatically upon download from the ETH Zurich Research Collection. For more information please consult the Terms of use. ETH Library This is the Green Open Access version of: Heinrich C.A., and Candela P.A. (2014) Fluids and Ore Formation in the Earth's Crust. In: Holland H.D. & Turekian K.K. (eds.) Treatise on Geochemistry, 2nd Edition, vol. 13 (Geochemistry of Mineral Deposits, S. D. Scott, ed.), p. 1-28. Original publication see http://dx.doi.org/10.1016/B978-0-08-095975-7.01101-3 Fluids and Ore Formation in the Earth’s Crust Christoph A. Heinrich1 and Philip A. Candela2 1 ETH Zurich, Department of Earth Sciences, and University of Zurich, Faculty of Mathematics and Natural Sciences, Clausiusstr. 25, 8092 Zurich, Switzerland 2 Laboratory for Mineral Deposits Research, Department of Geology, University of Maryland, College Park, MD,20742, USA Synopsis Ore deposits are rock volumes containing selected elements in sufficient concentration and quantity that they can Be extracted economically. Except for Fe and Al, all technically important metals and other elements are scarce, in total constituting less that 1% of the Earth’s crust. Depending on the element and its mineralogy, a 10- to 10,000-fold enrichment is required for economic extraction today. -
The Genetic Association Between Quartz Vein- and Greisen-Type
minerals Article The Genetic Association between Quartz Vein- and Greisen-Type Mineralization at the Maoping W–Sn Deposit, Southern Jiangxi, China: Insights from Zircon and Cassiterite U–Pb Ages and Cassiterite Trace Element Composition Li-Li Chen, Pei Ni *, Bao-Zhang Dai *, Wen-Sheng Li, Zhe Chi and Jun-Yi Pan State Key Laboratory for Mineral Deposits Research, Institute of Geo–Fluids, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, China * Correspondence: [email protected] (P.N.); [email protected] (B.-Z.D.); Tel.: +86-25-8968-0883 (P.N.); +86-25-8368-6649 (B.-Z.D.) Received: 28 May 2019; Accepted: 3 July 2019; Published: 4 July 2019 Abstract: The large-scale Maoping W–Sn deposit in the Gannan metallogenic belt of the eastern Nanling Range, South China, spatially associated with the Maoping granite pluton, hosts total ore reserves of 103,000 t WO3 and 50,000 t Sn. Two different types of mineralization developed in this deposit: Upper quartz vein-type mineralization, mostly within the Cambrian metamorphosed sandstone and slate, and underneath greisen-type mineralization within the Maoping granite. Cassiterites from both types of mineralization coexist with wolframite. Here we report for the first time in situ U–Pb data on cassiterite and zircon of the Maoping deposit obtained by LA-ICP-MS. Cassiterite from quartz vein and greisen yielded weighted average 206Pb/238U ages of 156.8 1.5 Ma ± and 156.9 1.4 Ma, respectively, which indicates that the two types of mineralization formed roughly ± at the same time. In addition, the two mineralization ages are consistent with the emplacement age of the Maoping granite (159.0 1.5 Ma) within error, suggesting a close temporal and genetic link ± between W–Sn mineralization and granitic magmatism. -
Cassiterite Solubility and Tin Speciation in Supercritical Chloride Solutions
Fluid-Mineral Interactions: A Tribute to H. P. Eugster © The Geochemical Society, Special Publication No.2, 1990 Editors: R. J. Spencer and I-Ming Chou Cassiterite solubility and tin speciation in supercritical chloride solutions GLENN A. WILSON* and HANS P. EUGSTERt Department of Earth and Planetary Sciences, The Johns Hopkins University, Baltimore, Maryland 21218, U.S.A. Abstract-In order to model the evolution of hydrothermal cassiterite deposits, a quantitative un- derstanding of the chemistry of cassiterite-fluid reactions under supercritical conditions is needed. To obtain this information, the solubility of cassiterite in HCl solutions was measured in closed- system experiments from 400 to 700°C, 1.5 kb, with the oxygen fugacity controlled by nickel-nickel oxide (NNO) and hematite-magnetite (HM). From the measured total chloride and tin concentrations, and the conditions of electrical neutrality at P and T, a set of equations was established for each run. By solving the equations simultaneously and finding the best-fit solution for all runs at the same set of P and T conditions, data were obtained on the identity of the dominant aqueous tin-chloride species and the equilibrium constants for the cassiterite dissolution reaction, X 4-X Sn02 + XH+ + nCl- <=± SnCl;,'-n + '2 H20 + -4- O2, where X is the oxidation state of aqueous tin and n is the ligation number of the tin-chloride species. With the 10, ofNNO at 400 to 600°C, it was found that SnCI+and SnClg are dominant in solution, and at 700°C only SnClg was detected. With the 10, ofHM at 500 and 600°C, SnClj was found to be dominant. -
Kiiash Journalofafrican Earth Sciences
kiiash JournalofAfrican Earth Sciences. Vol. 28. No. 3. DD. 581-598. 1999 Pergamon a 1999 Eisevier Science Ltd Pll:SO899-5382(99)00033-O All rights reserved. Printed in Great Britain 0699.5362199 $- see front matter Mineralogical and geochemical investigation of emerald and beryl mineralisation, Pan-African Belt of Egypt: genetic and exploration aspects H. M. ABDALLA’ and F. H. MOHAMED2 ‘Nuclear Materials Authority, Cairo, Egypt *Geology Department, Faculty of Science, Alexandria University, Egypt ABSTRACT-Mineralogical, geochemical and fluid inclusion studies reveal two favourable environments for the localisation of beryl mineralisations in the Precambrian rocks of Egypt: (1)emerald-schist; and (2) beryl-specialised granitoid associations. Emerald occurs within the mica schists and is typically confined to the Nugrus major shear zone. However, beryl associated with granitoids occurs in pegmatite veins, greisen bodies, and cassiterite quartz veins cutting the granites and the exocontacts of the volcanosedimentary country rocks. Compositionally, emerald is of octahedral type and its cell edge is lengthened along the a-axis, while beryl associated with granitoids is normal in composition and structural constants. Emerald is thought to be formed as the result of epitactic nucleation of Be, Al and alkali-rich solutions on the mica of the schist country rocks. Fluid inclusion studies show that the solutions are saline (8-22 wt% NaCl equiv.) and the reactions proceeded in the temperature range 260-382OC. On the other hand, aqueous inclusions in beryl associated with granitoids show the following sequence of formation with decreasing temperatures and salinities: beryl pegmatite (320-480°C and 7-16 wt% NaCl equiv.)+greisen bodies (190-400°C and 4-7 wt% NaCl equiv.)+cassiterite-quartz veins (1 90-380°C and 2-4 wt% NaCl equiv.). -
MINERALS from TOPAZ MT., UTAH Cuanr,Bs Par,-A.Cuo, H Araard, U
MINERALS FROM TOPAZ MT., UTAH Cuanr,Bs PAr,-a.cuo,H araard,U niaersity. In the spring of 1933 Mr. Edwin Over, Jr. of Colorado Springs made a mineral collecting trip in the interest of the Harvard Mineralogical Museum. The largest part of his time was spent at Topaz Mt. in the Thomas Range, Utah, and he succeededin ob- taining a very fine suite of the well-known topaz of that locality. He also added several minerals to the paragenetic series there as hitherto recorded. These additions are pseudobrookite, beryl, fluorite and calcite. Topaz: The topaz collected is nearly all of the pale wine-color long known from Topaz Mt. The crystals are in part in typical lithophysae in the rhyolite, in part in small gash veins or vein-like cavities more or less completely filled with late calcite. The finest specimenis a doubly terminated crystal of beautiful quality about 3 cm. in length. The walls are lined with minute quartz crystals and the quartz continued to form throughout the period of mineral formation, as crystals of it are included both in topaz and beryl. When calcite is present it is in snow-white masses,coarsely crystal- lized, massive,and completely filling the cavities. Again it projects from the walls in platy form, the crystals showing the outline of a hexagonal prism of first order and a rough basal plane, evidently modified to a rough surface by etching. The pale purple fluorite is intermingled with it and shows no definite crystals. Bnnyr,: This mineral, so unfamiliar in such surroundings, has beenreported recently from this locality under the name of apatite.