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United States Patent Office Patiented Aug 3,00,732 United States Patent Office Patiented Aug. 3, 1963 2 at the end of the conventional peroxide bleaching stage, the residual peroxide will be utilized and an even greater 3,100,732 increase in brightness gain can be realized. The use of PROCESS Oil BAEACHENG WOOD PULP BY COM borohydride at the end of the peroxide bleaching stage BNEO TREATMENT WITH PEROXDE AND AN confers the added advantage of effectively eliminating GeorgeALKAEA E. Smedberg, METAL BOROHYDREEWilmington, Dei, assignor to E. residual peroxide; it is then no longer necessary to use duPont de Nemours and Company, Wilmington, Dei; hydrosulfite in a subsequent stage. Additionally it is a corporation of Delaware possible to neutralize the slurry with sulfuric acid rather No Drawing. Filed Oct. 5, 1959, Ser. No. 844,182 than neutralizing with the more expensive sulfur dioxide. 6 Cairns. (C. 162-78) Although both borohydride and peroxide have been used 10 to bleach wood pulp through reduction and oxidation The present invention relates to the bleaching of wood actions respectively, so far as known these agents have pulp using a novel combination of reducing and oxidiz not been used in combination. ing agents. More particularly, the present invention re It is an object of the present invention to provide an lates to the bleaching of wood pulp wherein the pulp is improved process of bleaching both mechanically dis subjected to the combined and simultaneous action of 15 integrated and chemical pulp by the combined and simul peroxide and borohydride. taneous actions of an oxidizing agent and a reducing The present invention relates to the bleaching of wood agent. pulps in general, but has particular application to me It is another object of the present invention to provide chanically disintegrated wood pulps. The term "mechan 20 a process for effectively utilizing the residual peroxide ically disintegrated wood pulp' embraces both ground remaining in pulp slurries before neutralization. wood pulp and chip-mechanical pulp; the former is ob It is still another object of the present invention to tained by well-known methods of reducing logs to fibers provide a process wherein alkaline pulp slurries can be by grinding and the latter is obtained by refining hard neutralized by sulfuric acid. wood or softwood chips with chemicals, such as sodium These and other objects will be apparent from the bisulfite or caustic soda with or without pressure, elevated 25 following description. temperatures or merely treating the chips with steam, hot The instant invention relates to (1) the use of peroxide or cold water, and thereafter grinding the chips to fibers. and borohydride in admixture to bleach mechanically The bleaching of mechanically disintegrated wood pulps disintegrated or chemical pulp and (2) to the use of began over a decade ago using a single peroxide treating borohydride as a post treatment to effectively utilize the step. Thus bleached, the pulp can be used in varying 30 residual peroxide remaining at the end of the peroxide amounts in paper finish to improve the printability and bleaching cycle. In both applications, superior results other characteristics of the paper. Increasing demands are obtained by the combined and simultaneous action for higher brightness of mechanically disintegrated wood of an oxidizing agent and a reducing agent. pulp has resulted in increased efficiency in bleaching In the first of the above procedures, an alkali metal processes. More recently instead of bleaching this pulp 35 borohydride, preferably sodium borohydride, is dissolved in a single stage, commercial practice has adopted the in the peroxide solution containing suitable buffering and procedure of initially bleaching the pulp with peroxide, Stabilizing agents, such as Epsom salt, sodium silicate, neutralizing the slurry and thereafter subjecting the slurry sodium tripolyphosphate (or ethylene diamine tetracetic to the action of a reducing agent, usually hydrosulfite. 40 acid as a chelating agent), sodium carbonate and caustic Such a two-stage procedure is well known having been soda, immediately before the solution is mixed with the used for several years. The same trend to up-grade pulp has taken place in pulp. The pulp slurry, which can have a consistency of the chemical pulp field. Instead of a single hypochlorite about 4-30%, is retained for completion of the reaction bleaching stage, common practice today is to bleach such at a temperature of about 90-180° F. for a period of pulp in five or six stages. A conventional bleaching pro 45 15 minutes up to six hours or longer if necessary. The cedure is to employ a five-stage process where the pulp length of the treating period largely depends on consis is subjected to chlorination, caustic treatment, the action tency and temperature. At the end of the bleaching cycle, of hypochlorite, chlorine dioxide treatment, and there the pulp is neutralized with sulfuric acid to about pH after a final peroxide bleach. U.S. Patent 2,494,542 6.5-7 or lower. The presence of borohydride insures relates to such a process. This and other multi-stage 50 that little or no residual peroxide remains. - bleaching procedures result in producing chemical pulp. In the second of these applications the peroxide of high brightness and superior brightness stability. bleaching stage is carried out in the conventional man In the instance of mechanically disintegrated wood pulp, ner at the above-indicated consistency and temperature. the recently developed two-stage procedure initially pro At the end of the peroxide bleaching stage, the pulp is vides for the pulp to be subjected to an alkaline bleach 55 preferably reduced in consistency to about 4 or 5% by ing solution containing peroxide. Thereafter the slurry adding water. Borohydride is then added to the pulp is neutralized with sulfur dioxide while the residual per and the slurry is retained at about 90-130 F. for one oxide content is sufficiently high (at least about 5%, half to two hours or longer and thereafter neutralized preferably about 15-25%) to prevent caustic color rever with sulfuric acid. Alternatively, the acid can be added sion. The usual practice of treating the pulp in the per 60 at about the same time as the borohydride is introduced oxide bleaching cycle is to introduce peroxide under into the slurry. Pulp so treated can then be bleached alkaline conditions and bleach the pulp for the required at neutral or slightly acid pH (about 6) and need not time. After neutralization the pulp slurry is treated with be further neutralized; after bleaching the pulp is ready a reducing agent, usually a metal hydrosulfite and a for paper furnish use. It is actually unnecessary to chelating agent. reduce the consistency of the pulp before adding boro It has been found that when borohydride is added to hydride, adequate mixing permits the use of pulps having the pulp during the initial peroxide bleaching stage in consistencies of 30% or more. The amount of boro the conventional two-stage process, a marked increase in hydride can be as high as economical and brightness brightness gain is realized. Thus treated, it is unneces requirements demand. Broadly, 0.1-3%, calculated as sary to treat the pulp with hydrosulfite. Subsequent treat 70 sodium borohydride, is satisfactory and preferably 0.5- ment with hydrosulfite is optional, however. It has also 1% is used. been found that if the borohydride compound is added Throughout the specification and examples percent 3,100,732 3. ages are by weight based on the dry weight of the 4. pulp. Although sodium borohydride is preferred, potas dioxide and sulfuric acid in the conventional manner gave sium and other alkali metal borohydrides are suitable in a 9.4 G.E. unit brightness increase. A portion of the the form of water stable solutions, powder or pellets, pulp in the peroxide stage containing 27% residual preferably in powder form. The preferred peroxide is peroxide was diluted to 5% consistency and 1.0% sodium an alkali metal peroxide, specifically sodium peroxide, but borohydride was added. The pulp was retained at 110 0.1-2.0% of any conventional peroxide based on sodium F. for 120 minutes and then neutralized to a pH of peroxide can be used. Thus hydrogen peroxide is suitable 4.5 with sulfuric acid. The brightness gain was 14.4 in amounts up to 5%. Preferably 0.5-2% peroxide, G.E. units, or 5 units more than the pulp bleached by based on sodium peroxide, is used. peroxide alone. The pH of the pulp prior to neutraliza A batch of ground wood pulp was dewatered to 14% O tion with sulfuric acid was 9.8 and there was no residual consistency and bleached with a conventional 2% sodium peroxide in the pulp. peroxide formula with a resultant brightness increase The relative brightness stability of the pulp bleached of 8.5 G.E. units after neutralization. Two additional with peroxide alone, peroxide and borohydride in ad samples were bleached in the same manner except that mixture, or with borohydride as a post treatment Was in one case 0.1% sodium borohydride was dissolved 5 the same in all experiments. in the peroxide solution and, in the second case, 1.0% The combination of peroxide and borohydride in either sodium borohydride was added. The brightness in the initial alkaliperoxide bleaching cycle or as a post treat crease using 0.1% sodium borohydride with the peroxide ment to utilize residual peroxide can be applied in pre solution was 9.7 G.E. units, or 1.2 G.E. units greater sently used peroxide bleacheries using conventional equip ?than peroxide alone. When the 1.0% sodium boro 20 ment. The superior results obtained were unexpected hydride was used, the brightness increase was 12.4 G.E.
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