Thermo-Gas Dynamics of Hydrogen Combustion and Explosion
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Shock Wave and High Pressure Phenomena Thermo-Gas Dynamics of Hydrogen Combustion and Explosion Bearbeitet von Boris E. Gelfand, Mikhail V. Silnikov, Sergey P. Medvedev, Sergey V. Khomik 1. Auflage 2012. Buch. xxii, 326 S. Hardcover ISBN 978 3 642 25351 5 Format (B x L): 15,5 x 23,5 cm Gewicht: 684 g Weitere Fachgebiete > Technik > Werkstoffkunde, Mechanische Technologie > Technische Thermodynamik schnell und portofrei erhältlich bei Die Online-Fachbuchhandlung beck-shop.de ist spezialisiert auf Fachbücher, insbesondere Recht, Steuern und Wirtschaft. Im Sortiment finden Sie alle Medien (Bücher, Zeitschriften, CDs, eBooks, etc.) aller Verlage. Ergänzt wird das Programm durch Services wie Neuerscheinungsdienst oder Zusammenstellungen von Büchern zu Sonderpreisen. Der Shop führt mehr als 8 Millionen Produkte. Contents 1 Fundamental Combustion Characteristics of Hydrogenous Mixtures ................................................................... 1 1.1 Laminar Flame Velocity ............................................... 1 1.2 Flame Stretch Rate (Stretch Effect) ................................... 1 1.3 Markstein Length ...................................................... 3 1.4 Lewis Number and Selective Diffusion ............................... 4 1.5 Diffusion-Thermal and Hydrodynamic Flame Instability ............. 5 1.6 Turbulent Flame Velocity ............................................. 6 1.7 Mixture Composition .................................................. 7 1.8 Macroscopic Combustion Parameters of Hydrogenous Mixtures ................................................................ 8 References .. ............................................................... 11 2 Laminar and Cellular Combustion of Hydrogenous Gaseous Mixtures ........................................................ 15 2.1 Measurement of Laminar Flame Velocity ... ........................ 15 2.2 Results of Laminar Flame Velocity Measurements .................. 18 2.3 Development of Laminar Flame Velocity Measuring Techniques .. 20 2.4 Simulation of Flame Propagation .................................... 23 2.5 Initial Temperature Effect on Laminar Flame Velocity ............. 24 2.6 Pressure Effect on Laminar Flame Velocity . ........................ 27 2.7 Mixture Composition Effect on Laminar Flame Velocity ........... 30 2.8 Effect of Noncombustible Gas Additives on Laminar Flame Velocity ............................................................... 33 2.9 Carbon Dioxide Effect on Laminar Flame Velocity ................. 33 2.10 Water Steam Effect on Laminar Flame Velocity ................... 34 2.11 Laminar Flame Velocity in H2 þ CO þ Air Mixture .............. 38 2.12 Laminar Flame Velocity in H2 þ CH4 þ Air Mixture ............. 43 References .. ............................................................... 47 xvii xviii Contents 3 Turbulent Combustion of Hydrogenous Gas Mixtures ............... 53 3.1 Measurement of Turbulent Flame Velocity .. ........................ 53 3.2 Effect of Turbulent Intensity and Mixture Composition on Flame Velocity .................................................... 56 3.3 Pressure Effect on Turbulent Flame Velocity ........................ 59 3.4 Carbon Dioxide Gas Effect on Turbulent Flame Velocity ........... 60 3.5 Water Steam Effect on Turbulent Flame Velocity ................... 61 3.6 CO Effect on Turbulent Flame Velocity ............................. 61 3.7 Turbulent Flame Quenching .......................................... 63 3.8 Means of Combustion Suppression ................................... 64 3.9 Measurement of Turbulent Combustion Suppression Efficiency in HydrogenþAirþWater Fog System .................. 65 3.10 Experimental Data on Suppression of Turbulent Combustion ..... 67 References .. ............................................................... 71 4 Concentration Limits of Flame Propagation .......................... 73 4.1 Measurement of Concentration Limits ............................... 73 4.2 Concentration Limits of Hydrogenous Mixtures H2þO2þN2 ...... 74 4.3 Concentration Limits of Hydrogenous Mixtures with CO2 .......... 76 4.4 Concentration Limits of Hydrogenous Mixtures with Helium ....... 77 4.5 Concentration Limits of Combustion of Hydrogenous Mixtures with Water Steam .......................................... 77 4.6 Vessel Wall Temperature Effect on Combustion Concentration Limits ................................................................. 79 4.7 Combustion Limits of H2þHydrocarbonþAir Mixtures ............ 82 4.8 Critical Energy Characteristics of Ignition Source ................... 86 4.9 Geometrical Limitations of Flame Propagation ...................... 89 4.10 Combustion Limits of HydrogenþAmmonia Mixtures ............ 91 References .. ............................................................... 92 5 Fast Deflagration and Quasi-Detonation ............................... 95 5.1 Fast Deflagration and Quasi-Detonation in a Confined Volume ..... 95 5.2 Fast Deflagration in Open Spaces .................................... 97 5.3 Flame Acceleration in Volume with Turbulence Promoters ......... 98 5.4 Quasi-Detonation in Tubes and Ducts ................................ 99 5.5 Quasi-Detonation in Porous Medium .............................. 102 5.6 Quasi-Detonation in Semi-Closed Encumbered Space ............ 107 5.7 Blast Processes in LiquidþCombustible Mixture Bubbles ........ 109 5.8 Scale Factors of Fast Explosion Processes ... ...................... 111 5.9 General Properties of Explosive Processes ... ...................... 113 5.10 Thermal and Pressure Loads at Deflagration-to-Detonation Transition .......................................................... 115 References .. .............................................................. 117 Contents xix 6 Self-Ignition of Hydrogenous Mixtures ............................... 121 6.1 Preliminary Comments ............................................. 121 6.2 Self-Ignition of Pre-mixed HydrogenþAir/Oxygen Mixtures Under Real Initial Conditions ...................................... 122 6.3 Pressure and Temperature Effect on Hydrogenous Mixture Self-Ignition ......................................................... 124 6.4 Self-Ignition Delay ................................................. 127 6.5 Spatial Characteristics of Generation of Self-Ignition Centers and Self-Ignition Regimes .......................................... 129 6.6 Special Cases of Self-Ignition ...................................... 134 6.7 Nitrogen Oxide Effect on Hydrogenous Mixture Self-Ignition .... 134 6.8 Self-Ignition of Hydrogenous Mixtures with Hydrocarbon Fuel Additives ............................................................ 138 6.9 Self-Ignition of Heterogeneous Hydrogenous Combustible Mixtures ............................................................. 139 6.10 Thermo-Gas Dynamic Phenomena Occurring at Homogenous Mixture Ignition and Combustion Near Non-Flat Surfaces ...... 140 6.11 Experimental Study of the Self-Ignition Process ................. 143 6.12 Simulation of Shock Wave Focusing in Combustible Mixture ... 149 6.13 Practical Application of Investigation Data for Self-Ignition Processes ........................................................... 150 6.14 Water Steam Effect on Self-Ignition .............................. 152 6.15 Carbon Dioxide Effect on Self-Ignition ........................... 155 References .. .............................................................. 158 7 Regimes of Supersonic Combustion: Detonation Waves ............ 165 7.1 Detonation Parameters of Hydrogenous Mixtures ................. 165 7.2 Reflected Detonation Wave Parameters ............................ 167 7.3 Effects of Initial Temperature and Non-combustible Gases on Detonation Parameters .......................................... 169 7.4 Size of Detonation Cell ............................................. 172 7.5 Temperature Effect on Detonation Cell Size . ...................... 175 7.6 Effect of Hydrogenous Mixture Composition on Detonation Cell Size ............................................................ 176 7.7 Concentration Limits of Detonation ................................ 179 7.8 Geometrical Limitation for Detonation Propagation ............... 181 7.9 Critical Energy for Direct Initiation of Spherical Detonation ..... 185 7.10 Detonation in Hydrogenous Mixtures with Two-Component Combustible Gas Substances ...................................... 189 7.11 Detonation Limits of Triple Mixtures ............................. 191 References .. .............................................................. 193 8 Shock-Free and Spontaneous Initiation of Explosive Regimes ...... 197 8.1 Deflagration-to-Detonation Transition ............................. 197 8.2 Processes of Flame Acceleration in Tubes with Obstacles ........ 199 xx Contents 8.3 Alternative Resources of Shock-Free (Mild) Initiation in Explosive Regimes ............................................................. 202 8.4 Effect of Temperature and Concentration Non-uniformity on Shock-Free Detonation Initiation ............................... 203 8.5 Critical Temperature and Concentration Gradients Causing Deflagration-to-Detonation Transition ............................. 204 8.6 Occurrence of Regions with Temperature and Concentration Gradients (TCG) .................................................... 206 8.7 Conditions of Spontaneous Blast Processes Initiation ............. 208 8.8 Estimation of Minimum Distances for Spontaneous Detonation Development