Witherite Composition, Physical Properties, and Genesis
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Download PDF About Minerals Sorted by Mineral Name
MINERALS SORTED BY NAME Here is an alphabetical list of minerals discussed on this site. More information on and photographs of these minerals in Kentucky is available in the book “Rocks and Minerals of Kentucky” (Anderson, 1994). APATITE Crystal system: hexagonal. Fracture: conchoidal. Color: red, brown, white. Hardness: 5.0. Luster: opaque or semitransparent. Specific gravity: 3.1. Apatite, also called cellophane, occurs in peridotites in eastern and western Kentucky. A microcrystalline variety of collophane found in northern Woodford County is dark reddish brown, porous, and occurs in phosphatic beds, lenses, and nodules in the Tanglewood Member of the Lexington Limestone. Some fossils in the Tanglewood Member are coated with phosphate. Beds are generally very thin, but occasionally several feet thick. The Woodford County phosphate beds were mined during the early 1900s near Wallace, Ky. BARITE Crystal system: orthorhombic. Cleavage: often in groups of platy or tabular crystals. Color: usually white, but may be light shades of blue, brown, yellow, or red. Hardness: 3.0 to 3.5. Streak: white. Luster: vitreous to pearly. Specific gravity: 4.5. Tenacity: brittle. Uses: in heavy muds in oil-well drilling, to increase brilliance in the glass-making industry, as filler for paper, cosmetics, textiles, linoleum, rubber goods, paints. Barite generally occurs in a white massive variety (often appearing earthy when weathered), although some clear to bluish, bladed barite crystals have been observed in several vein deposits in central Kentucky, and commonly occurs as a solid solution series with celestite where barium and strontium can substitute for each other. Various nodular zones have been observed in Silurian–Devonian rocks in east-central Kentucky. -
Barite (Barium)
Barite (Barium) Chapter D of Critical Mineral Resources of the United States—Economic and Environmental Geology and Prospects for Future Supply Professional Paper 1802–D U.S. Department of the Interior U.S. Geological Survey Periodic Table of Elements 1A 8A 1 2 hydrogen helium 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 lithium beryllium boron carbon nitrogen oxygen fluorine neon 6.94 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 sodium magnesium aluminum silicon phosphorus sulfur chlorine argon 22.99 24.31 3B 4B 5B 6B 7B 8B 11B 12B 26.98 28.09 30.97 32.06 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.64 74.92 78.96 79.90 83.79 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon 85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 cesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon 132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.5 204.4 207.2 209.0 (209) (210)(222) 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 -
2012 Bmc Auction Specimens
A SAMPLER OF SELECTED 2017 BMC AUCTION SPECIMENS (2017 Auction Date is Saturday, 21 January) Volume 3 3+ Hematite [Fe 2O3] & Quartz [SiO2] Locality Cleator Moor Iron Mines Cleator Moor West Cumberland Iron Field Cumbria, England, UK Size 13.5 x 9.5 x 7.0 cm 1498 g Donated by Stonetrust Hematite Crystal System: Trigonal Photograph by Mike Haritos Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 6.5 Density: approx 5.3 gm/cm3 Streak: Red Luster: Metalic Vanadinite [Pb5(VO4)3Cl] var. Endlichite Locality Erupción Mine (Ahumada Mine) Los Lamentos Mountains (Sierra de Los Lamentos) Mun. de Ahumada Chihuahua, Mexico Size 12.0 x 9.5 x 7.0 cm 1134 g Donated by Stonetrust Crystal System: Hexagonal Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 3.5-4 Photograph by Mike Haritos Density: 6.8 to 7.1 gm/cm3 Streak: Brownish yellow Endlichite, Pb5([V, As]O4)3Cl, is the arsenic rich Luster: Adamantine variety of vanadinite with arsenic atoms (As) substituting for some of the vanadium (V) 2+ Dolomite [CaMg(CO3)2] & Chalcopyrite [CuFe S2] Locality Picher Field Tri-State District Ottawa Co. Oklahoma, USA Size 19.0 x 14.5 x 6.0 cm 1892 g Consigned with Reserve by Stonetrust Dolomite Crystal System: Trigonal Physical Properties Photograph by Mike Haritos Transparency: Transparent, Translucent, Opaque Mohs hardness: 3.5 to 4 Density: 2.8 to 2.9 gm/cm3 Streak: White Luster: Vitreous Calcite [CaCO3] Locality Mexico Size 15.5 x 12.8 x 6.2 cm 1074 g Donated by Stonetrust Calcite Crystal System: Trigonal Physical Properties Transparency: Transparent, Translucent Mohs hardness: 3 Density: 2.71 gm/cm3 Streak: White Luster: Vitreous, Sub-Vitreous, Photograph by Mike Haritos Resinous, Waxy, Pearly Quartz [SiO2], var. -
Selective Flotation of Witherite from Calcite Using Potassium Chromate As a Depressant
Physicochem. Probl. Miner. Process., 55(2), 2019, 565-574 Physicochemical Problems of Mineral Processing ISSN 1643-1049 http://www.journalssystem.com/ppmp © Wroclaw University of Science and Technology Received May 31, 2018; reviewed; accepted September 2, 2018 Selective flotation of witherite from calcite using potassium chromate as a depressant Yangshuai Qiu 1, Lingyan Zhang 1,2, Xuan Jiao 1, Junfang Guan 1,2, Ye Li 1,2, Yupeng Qian 1,2 1 School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China 2 Hubei Key Laboratory of Mineral Resources Processing & Environment, Wuhan 430070, China Corresponding author: [email protected] (Lingyan Zhang) Abstract: Witherite has been widely used as an industrial and environmental source of barium, with calcite being the primary associated carbonate mineral. However, few studies have been conducted to effectively concentrate witherite from barium ores. In this work, with the treatment of potassium chromate (K2CrO4) and sodium oleate (NaOL), witherite was selectively separated from calcite through selective flotation at different pH conditions. In addition, contact angle, Zeta potential, adsorption and X-ray photoelectron spectroscopy measurements were performed to characterize the separation mechanisms. The results demonstrated that NaOL had a strong collecting ability for both witherite and calcite; nevertheless, witherite could be effectively selected from calcite with the highest recovery at pH 9 in the presence of K2CrO4. From the XPS measurements, NaOL and K2CrO4 were found to be primarily attached to the surfaces of witherite and calcite through chemisorption. The presence of K2CrO4 on the surface of calcite adversely influenced the NaOL adsorption, which could make the flotation separation efficient and successful. -
Infrare D Transmission Spectra of Carbonate Minerals
Infrare d Transmission Spectra of Carbonate Mineral s THE NATURAL HISTORY MUSEUM Infrare d Transmission Spectra of Carbonate Mineral s G. C. Jones Department of Mineralogy The Natural History Museum London, UK and B. Jackson Department of Geology Royal Museum of Scotland Edinburgh, UK A collaborative project of The Natural History Museum and National Museums of Scotland E3 SPRINGER-SCIENCE+BUSINESS MEDIA, B.V. Firs t editio n 1 993 © 1993 Springer Science+Business Media Dordrecht Originally published by Chapman & Hall in 1993 Softcover reprint of the hardcover 1st edition 1993 Typese t at the Natura l Histor y Museu m ISBN 978-94-010-4940-5 ISBN 978-94-011-2120-0 (eBook) DOI 10.1007/978-94-011-2120-0 Apar t fro m any fair dealin g for the purpose s of researc h or privat e study , or criticis m or review , as permitte d unde r the UK Copyrigh t Design s and Patent s Act , 1988, thi s publicatio n may not be reproduced , stored , or transmitted , in any for m or by any means , withou t the prio r permissio n in writin g of the publishers , or in the case of reprographi c reproductio n onl y in accordanc e wit h the term s of the licence s issue d by the Copyrigh t Licensin g Agenc y in the UK, or in accordanc e wit h the term s of licence s issue d by the appropriat e Reproductio n Right s Organizatio n outsid e the UK. Enquirie s concernin g reproductio n outsid e the term s state d here shoul d be sent to the publisher s at the Londo n addres s printe d on thi s page. -
Adsorption of RNA on Mineral Surfaces and Mineral Precipitates
Adsorption of RNA on mineral surfaces and mineral precipitates Elisa Biondi1,2, Yoshihiro Furukawa3, Jun Kawai4 and Steven A. Benner*1,2,5 Full Research Paper Open Access Address: Beilstein J. Org. Chem. 2017, 13, 393–404. 1Foundation for Applied Molecular Evolution, 13709 Progress doi:10.3762/bjoc.13.42 Boulevard, Alachua, FL, 32615, USA, 2Firebird Biomolecular Sciences LLC, 13709 Progress Boulevard, Alachua, FL, 32615, USA, Received: 23 November 2016 3Department of Earth Science, Tohoku University, 2 Chome-1-1 Accepted: 15 February 2017 Katahira, Aoba Ward, Sendai, Miyagi Prefecture 980-8577, Japan, Published: 01 March 2017 4Department of Material Science and Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama This article is part of the Thematic Series "From prebiotic chemistry to 240-8501, Japan and 5The Westheimer Institute for Science and molecular evolution". Technology, 13709 Progress Boulevard, Alachua, FL, 32615, USA Guest Editor: L. Cronin Email: Steven A. Benner* - [email protected] © 2017 Biondi et al.; licensee Beilstein-Institut. License and terms: see end of document. * Corresponding author Keywords: carbonates; natural minerals; origins of life; RNA adsorption; synthetic minerals Abstract The prebiotic significance of laboratory experiments that study the interactions between oligomeric RNA and mineral species is difficult to know. Natural exemplars of specific minerals can differ widely depending on their provenance. While laboratory-gener- ated samples of synthetic minerals can have controlled compositions, they are often viewed as "unnatural". Here, we show how trends in the interaction of RNA with natural mineral specimens, synthetic mineral specimens, and co-precipitated pairs of synthe- tic minerals, can make a persuasive case that the observed interactions reflect the composition of the minerals themselves, rather than their being simply examples of large molecules associating nonspecifically with large surfaces. -
Conservation of Coated and Specialty Papers
RELACT HISTORY, TECHNOLOGY, AND TREATMENT OF SPECIALTY PAPERS FOUND IN ARCHIVES, LIBRARIES AND MUSEUMS: TRACING AND PIGMENT-COATED PAPERS By Dianne van der Reyden (Revised from the following publications: Pigment-coated papers I & II: history and technology / van der Reyden, Dianne; Mosier, Erika; Baker, Mary , In: Triennial meeting (10th), Washington, DC, 22-27 August 1993: preprints / Paris: ICOM , 1993, and Effects of aging and solvent treatments on some properties of contemporary tracing papers / van der Reyden, Dianne; Hofmann, Christa; Baker, Mary, In: Journal of the American Institute for Conservation, 1993) ABSTRACT Museums, libraries, and archives contain large collections of pigment-coated and tracing papers. These papers are produced by specially formulated compositions and manufacturing procedures that make them particularly vulnerable to damage as well as reactive to solvents used in conservation treatments. In order to evaluate the effects of solvents on such papers, several research projects were designed to consider the variables of paper composition, properties, and aging, as well as type of solvent and technique of solvent application. This paper summarizes findings for materials characterization, degradative effects of aging, and some effects of solvents used for stain reduction, and humidification and flattening, of pigment-coated and modern tracing papers. Pigment-coated papers have been used, virtually since the beginning of papermaking history, for their special properties of gloss and brightness. These properties, however, may render coated papers more susceptible to certain types of damage (surface marring, embedded grime, and stains) and more reactive to certain conservation treatments. Several research projects have been undertaken to characterize paper coating compositions (by SEM/EDS and FTIR) and appearance properties (by SEM imaging of surface structure and quantitative measurements of color and gloss) in order to evaluate changes that might occur following application of solvents used in conservation treatments. -
4. CHEMICAL, PHYSICAL, and RADIOLOGICAL INFORMATION
STRONTIUM 189 4. CHEMICAL, PHYSICAL, and RADIOLOGICAL INFORMATION 4.1 CHEMICAL IDENTITY Strontium is an alkaline earth element in Group IIA of the periodic table. Because of its high reactivity, elemental (or metallic) strontium is not found in nature; it exists only as molecular compounds with other elements. The chemical information for elemental strontium and some of its compounds is listed in Table 4-1. Radioactive isotopes of strontium (e.g., 89Sr and 90Sr, see Section 4.2) are the primary cause of concern with regard to human health (see Chapter 3). 4.2 PHYSICAL, CHEMICAL, AND RADIOLOGICAL PROPERTIES The physical properties of strontium metal and selected strontium compounds are listed in Table 4-2. The percent occurrence of strontium isotopes and the radiologic properties of strontium isotopes are listed in Table 4-3. Strontium can exist in two oxidation states: 0 and +2. Under normal environmental conditions, only the +2 oxidation state is stable enough to be of practical importance since it readily reacts with both water and oxygen (Cotton and Wilkenson 1980; Hibbins 1997). There are 26 isotopes of strontium, 4 of which occur naturally. The four stable isotopes, 84Sr, 86Sr, 87Sr, and 88Sr, are sometimes referred to as stable strontium. The most important radioactive isotopes, 89Sr and 90Sr, are formed during nuclear reactor operations and during nuclear explosions by the nuclear fission of 235U, 238U, or 239Pu. For example, 235U is split into smaller atomic mass fragments such as 90Sr by a nuclear chain reaction initiated by high energy neutrons of approximately 1 million electron volts (or 1 MeV). -
Strontium Minerals from Wise County, Virginia - an Update 1 2 D
Vol. 29 May 1983 No. 2 STRONTIUM MINERALS FROM WISE COUNTY, VIRGINIA - AN UPDATE 1 2 D. Allen Penick and Lynn D. Haynes The two principal minerals containing Strontianite crystallizes in the ortho- strontium, celestite and strontianite, have rhcanbic crystal system, and in Wise Funty been found in relative abundance in the area usually forms dull globular msses terrmnat- around East Stone Gap in Wise County, Vir- ed by acicular crystals. Crystals are gen- @ ginia. Celestite is strontium sulfate erally white and often can be seen as small (SrS04) and contains 56.4 percent strontium sprays attached to the celestite crystals. oxide. The name celestite is derived fm The mineral has a specific gravity of 3.7, the Latin mrd caelistis "of the sky" in hardness of 3.5 to 4, and good primtic reference to the typical blue color. Crys- cleavage. tals are predminantly blue and zoned in According to R. V. Dietrich (1970) and J. color but can also be red, green, or brown. A. Speer (1977) , strontium minerals have The mineral crystallizes in the ortho- been reported frcm seven different areas in rhcmbic crystal system and can fom thin to Virginia. These localities, all in the Val- thick heavy tabular crystals elongated along ley and Ridge Province, extend frcm Wise the b-axis; prismatic crystals elongated County in Southwest Virginia to Frederick along the a-axis; or equant crystals elon- County in the northwestern corner of the gated on the c-axis. Crystals can also have State (Figure 1). All exposures except two pyramidal faces with good terminations. -
List of Abbreviations
List of Abbreviations Ab albite Cbz chabazite Fa fayalite Acm acmite Cc chalcocite Fac ferroactinolite Act actinolite Ccl chrysocolla Fcp ferrocarpholite Adr andradite Ccn cancrinite Fed ferroedenite Agt aegirine-augite Ccp chalcopyrite Flt fluorite Ak akermanite Cel celadonite Fo forsterite Alm almandine Cen clinoenstatite Fpa ferropargasite Aln allanite Cfs clinoferrosilite Fs ferrosilite ( ortho) Als aluminosilicate Chl chlorite Fst fassite Am amphibole Chn chondrodite Fts ferrotscher- An anorthite Chr chromite makite And andalusite Chu clinohumite Gbs gibbsite Anh anhydrite Cld chloritoid Ged gedrite Ank ankerite Cls celestite Gh gehlenite Anl analcite Cp carpholite Gln glaucophane Ann annite Cpx Ca clinopyroxene Glt glauconite Ant anatase Crd cordierite Gn galena Ap apatite ern carnegieite Gp gypsum Apo apophyllite Crn corundum Gr graphite Apy arsenopyrite Crs cristroballite Grs grossular Arf arfvedsonite Cs coesite Grt garnet Arg aragonite Cst cassiterite Gru grunerite Atg antigorite Ctl chrysotile Gt goethite Ath anthophyllite Cum cummingtonite Hbl hornblende Aug augite Cv covellite He hercynite Ax axinite Czo clinozoisite Hd hedenbergite Bhm boehmite Dg diginite Hem hematite Bn bornite Di diopside Hl halite Brc brucite Dia diamond Hs hastingsite Brk brookite Dol dolomite Hu humite Brl beryl Drv dravite Hul heulandite Brt barite Dsp diaspore Hyn haiiyne Bst bustamite Eck eckermannite Ill illite Bt biotite Ed edenite Ilm ilmenite Cal calcite Elb elbaite Jd jadeite Cam Ca clinoamphi- En enstatite ( ortho) Jh johannsenite bole Ep epidote -
Ferricerite-(La) (La, Ce, Ca)9Fe (Sio4)3(Sio3oh)4(OH)3
3+ Ferricerite-(La) (La, Ce, Ca)9Fe (SiO4)3(SiO3OH)4(OH)3 Crystal Data: Hexagonal. Point Group: 3m. Forms boxwork-like aggregates of equant to tabular crystals flattened on [00*1] to 2 mm with dominant rhombohedral and pinacoidal faces, as pseudomorphs after an unidentified hexagonal prismatic mineral. Physical Properties: Cleavage: None. Tenacity: Brittle. Fracture: Conchoidal. Hardness = 5 D(meas.) = 4.7(1) D(calc.) = 4.74 Optical Properties: Translucent. Color: Light yellow to pinkish brown. Streak: White. Luster: Vitreous. Optical Class: Uniaxial (+). ω = 1.810(5) ε = 1.820(5) Cell Data: Space Group: R3c. a = 10.7493(6) c = 38.318(3) Z = 6 X-ray Powder Pattern: Mt. Yuksporr, Khibina massif, Kola Peninsula, Russia. 2.958 (100), 3.47 (40), 3.31(38), 2.833 (37), 2.689 (34), 1.949 (34), 3.53 (26) Chemistry: (1) (2) La2O3 37.57 CaO 5.09 Ce2O3 23.67 Fe2O3 1.40 Pr2O3 0.61 MgO 0.51 Nd2O3 1.48 SiO2 22.38 Sm2O3 0.10 P2O5 0.63 Gd2O3 0.24 H2O 3.20 SrO 1.97 Total 98.85 (1) Mt. Yuksporr, Khibina massif, Kola Peninsula, Russia; average electron microprobe analysis supplemented by IR spectroscopy, H2O by Penfield method; corresponds to (La4.23Ce2.65Ca1.37Sr0.35 Nd0.16Pr0.07Gd0.02Sm0.01)Σ=8.86(Fe0.32Ca0.30Mg0.23)Σ=0.85[SiO4]3[(Si0.84P0.16)Σ=1.00O3(OH)]4(OH)2.78. Mineral Group: Cerite supergroup, cerite group. Occurrence: A late-stage, low-temperature secondary phase in a symmetrically zoned, aegirine- natrolite-microcline vein in gneissose foyaite. -
Barite–Celestine Geochemistry and Environments of Formation Jeffrey S
Barite–Celestine Geochemistry and Environments of Formation Jeffrey S. Hanor Department of Geology and Geophysics Louisiana State University Baton Rouge, Louisiana 70803 INTRODUCTION Minerals in the barite (BaSO4)–celestine (SrSO4) solid solution series, (Ba,Sr)SO4, occur in a remarkably diverse range of sedimentary, metamorphic, and igneous geological environments which span geological time from the Early Archean (~3.5 Ga) to the present. The purpose of this chapter is to review: (1) the controls on the chemical and isotopic composition of barite and celestine and (2) the geological environments in which these minerals form. Some health risks are associated with barite, and these are discussed near the end of this chapter. Although complete solid solution exists between BaSO4 and SrSO4 most representa- tives of the series are either distinctly Ba-rich or Sr-rich. Hence, it is convenient to use the term barite to refer to not only the stochiometric BaSO4 endmember but also to those (Ba,Sr)SO4 solid solutions dominated by Ba. Similarly, the term celestine will refer here not only to the stoichiometric SrSO4 endmember but to solid solutions dominated by Sr. Such usage is in accord with standard mineral nomenclature. The Committee on Mineral Names and Nomenclature of the International Mineralogical Association recognizes “celestine” as the official name for SrSO4. However, the name “celestite” is still commonly used in the literature. Geological significance of barite and celestine Most of the barite which exists in the Earth’s crust has formed through the mixing of fluids, one containing Ba leached from silicate minerals, and the other an oxidized shallow fluid, such as seawater, which contains sulfate.