2012 Bmc Auction Specimens
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Vanadium Pentoxide and Other Inorganic Vanadium Compounds
This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organization, or the World Health Organization. Concise International Chemical Assessment Document 29 VANADIUM PENTOXIDE AND OTHER INORGANIC VANADIUM COMPOUNDS Note that the layout and pagination of this pdf file are not identical to the printed CICAD First draft prepared by Dr M. Costigan and Mr R. Cary, Health and Safety Executive, Liverpool, United Kingdom, and Dr S. Dobson, Centre for Ecology and Hydrology, Huntingdon, United Kingdom Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization, and the World Health Organization, and produced within the framework of the Inter-Organization Programme for the Sound Management of Chemicals. World Health Organization Geneva, 2001 The International Programme on Chemical Safety (IPCS), established in 1980, is a joint venture of the United Nations Environment Programme (UNEP), the International Labour Organization (ILO), and the World Health Organization (WHO). The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management -
Download PDF About Minerals Sorted by Mineral Name
MINERALS SORTED BY NAME Here is an alphabetical list of minerals discussed on this site. More information on and photographs of these minerals in Kentucky is available in the book “Rocks and Minerals of Kentucky” (Anderson, 1994). APATITE Crystal system: hexagonal. Fracture: conchoidal. Color: red, brown, white. Hardness: 5.0. Luster: opaque or semitransparent. Specific gravity: 3.1. Apatite, also called cellophane, occurs in peridotites in eastern and western Kentucky. A microcrystalline variety of collophane found in northern Woodford County is dark reddish brown, porous, and occurs in phosphatic beds, lenses, and nodules in the Tanglewood Member of the Lexington Limestone. Some fossils in the Tanglewood Member are coated with phosphate. Beds are generally very thin, but occasionally several feet thick. The Woodford County phosphate beds were mined during the early 1900s near Wallace, Ky. BARITE Crystal system: orthorhombic. Cleavage: often in groups of platy or tabular crystals. Color: usually white, but may be light shades of blue, brown, yellow, or red. Hardness: 3.0 to 3.5. Streak: white. Luster: vitreous to pearly. Specific gravity: 4.5. Tenacity: brittle. Uses: in heavy muds in oil-well drilling, to increase brilliance in the glass-making industry, as filler for paper, cosmetics, textiles, linoleum, rubber goods, paints. Barite generally occurs in a white massive variety (often appearing earthy when weathered), although some clear to bluish, bladed barite crystals have been observed in several vein deposits in central Kentucky, and commonly occurs as a solid solution series with celestite where barium and strontium can substitute for each other. Various nodular zones have been observed in Silurian–Devonian rocks in east-central Kentucky. -
JAN Iia 20U T6T1/V
IN REPLY REFER TO: UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY WASHINGTON 25. D.C. November 19, 1956 AEC-193/7 Mr. Robert D. Nininger Assistant Director for Exploration Division of Bav Materials U* S. Atomic Energy Commission Washington 25, D. C, Dear Bobs Transmitted herewith are three copies of TEI-622, "The crystal chemistry and mineralogy of vanadium," by Ho-ward T. Evans, Jr. Me are asking Mr. Hosted to approve our plan to publish this report as a chapter of a Geological Survey professional paper on miner alogy and geochemistry of the ores of the Colorado Plateau. Aelrnovledg- ment of AEC sponsorship will be made in the introductory chapter* Sincerely yours, r ^ O U—— TV , Z^*i—w«__ ™~ W. H. Bradley Chief Geoldigist .JAN iia 20U T6T1/V Geology and 8$i:aeralQgy This document consists of k-2 pages* Series A» Howard T. Erans, Jr, Trace Elements Investigations Report 622 This preliminary report is distributed without editorial and technical review for conformity with official standards and nomenclature. It is not for public inspection or quotation* *This report concerns work done on behalf of the Division of Raw Materials of the U. S« Atomic Energy Commission* - TEI-622 AHD MIHERALQ6T Distribution (Series A) Ro. of copies Atomic Energy Commission, Washington .»**«»..*»..«*»..««..*... 2 Division of Rs¥ Materials, Albuquerque ,...****.*.«.»*.....*.. 1 Division of Raw Materials, Austin »«,..«.»...»*.»...*«..*...«» 1 Diylsion of Raw Materials, Butte *«*,.»».*..,*...».»......*.*. 1 Division of Raw Materials, Casper ............a............... 1 Division of Raw Ifeterials, Denver ,........»...».....«.,.*..... 1 Division of Raw Materials, Ishpeming .................a....... 1 Division of Raw Materials, Pnoenix ...a.....,....*........*... 1 Division of Eaw Materials, Rapid City ....................... -
Barite (Barium)
Barite (Barium) Chapter D of Critical Mineral Resources of the United States—Economic and Environmental Geology and Prospects for Future Supply Professional Paper 1802–D U.S. Department of the Interior U.S. Geological Survey Periodic Table of Elements 1A 8A 1 2 hydrogen helium 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 lithium beryllium boron carbon nitrogen oxygen fluorine neon 6.94 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 sodium magnesium aluminum silicon phosphorus sulfur chlorine argon 22.99 24.31 3B 4B 5B 6B 7B 8B 11B 12B 26.98 28.09 30.97 32.06 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.64 74.92 78.96 79.90 83.79 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon 85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 cesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon 132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.5 204.4 207.2 209.0 (209) (210)(222) 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 -
Twinning in Pyromorphite: the First Documented Occurrence of Twinning by Merohedry in the Apatite Supergroup
American Mineralogist, Volume 97, pages 415–418, 2012 Twinning in pyromorphite: The first documented occurrence of twinning by merohedry in the apatite supergroup STUART J. MILLS,1,2,* GIOVANNI FERRARIS,3 ANTHONY R. KAMPF,2 AND GEORGES FAVREAU4 1Geosciences, Museum Victoria, GPO Box 666, Melbourne 3001, Australia 2Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, California 90007, U.S.A. 3Dipartimento di Scienze Mineralogiche e Petrologiche, Università degli Studi di Torino, Via Valperga Caluso 35, I-10125 Torino, Italy 4421 Avenue Jean Monnet, 13090 Aix-en-Provence, France ABSTRACT We describe the first documented case of {1010} twinning by reflection (or by twofold rotation about [100]) or merohedry (class II) in a member of the apatite supergroup. Twinning about [100] had previously been noted for the apatite supergroup but not confirmed. Pyromorphite crystals from Puech de Compolibat, Combret, Aveyron, France, were studied by single-crystal X-ray diffraction 3 [a = 10.0017(19), c = 7.3413(16) Å, and V = 636.0(2) Å , in P63/m], where twinning was confirmed with the approximate twin fraction 62:38. Subsequent inspection of the morphology confirmed the nature of the twinning. The pyromorphite crystals are typically elongate and show the faces: (21 10), (2110), (0001), (0001), (1010), (1010), (101 2), and (1012). Keywords: Twinning by merohedry class II, pyromorphite, Puech de Compolibat, apatite supergroup, crystal structure INTRODUCTION and the center of symmetry 1 may always be considered as twin Twinning is the oriented association of two or more law. In class II twins, instead, the superimposed lattice nodes individuals that are related by a twin operation belonging to (and the corresponding superimposed diffracted intensities) are the point group either of the lattice (twinning by merohedry) not equivalent in the Laue group [e.g., crystal point group 6/m, or of a sublattice (twinning by reticular merohedry), but not Laue group 6/m, twin operation (1010) plane]. -
Adsorption of RNA on Mineral Surfaces and Mineral Precipitates
Adsorption of RNA on mineral surfaces and mineral precipitates Elisa Biondi1,2, Yoshihiro Furukawa3, Jun Kawai4 and Steven A. Benner*1,2,5 Full Research Paper Open Access Address: Beilstein J. Org. Chem. 2017, 13, 393–404. 1Foundation for Applied Molecular Evolution, 13709 Progress doi:10.3762/bjoc.13.42 Boulevard, Alachua, FL, 32615, USA, 2Firebird Biomolecular Sciences LLC, 13709 Progress Boulevard, Alachua, FL, 32615, USA, Received: 23 November 2016 3Department of Earth Science, Tohoku University, 2 Chome-1-1 Accepted: 15 February 2017 Katahira, Aoba Ward, Sendai, Miyagi Prefecture 980-8577, Japan, Published: 01 March 2017 4Department of Material Science and Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama This article is part of the Thematic Series "From prebiotic chemistry to 240-8501, Japan and 5The Westheimer Institute for Science and molecular evolution". Technology, 13709 Progress Boulevard, Alachua, FL, 32615, USA Guest Editor: L. Cronin Email: Steven A. Benner* - [email protected] © 2017 Biondi et al.; licensee Beilstein-Institut. License and terms: see end of document. * Corresponding author Keywords: carbonates; natural minerals; origins of life; RNA adsorption; synthetic minerals Abstract The prebiotic significance of laboratory experiments that study the interactions between oligomeric RNA and mineral species is difficult to know. Natural exemplars of specific minerals can differ widely depending on their provenance. While laboratory-gener- ated samples of synthetic minerals can have controlled compositions, they are often viewed as "unnatural". Here, we show how trends in the interaction of RNA with natural mineral specimens, synthetic mineral specimens, and co-precipitated pairs of synthe- tic minerals, can make a persuasive case that the observed interactions reflect the composition of the minerals themselves, rather than their being simply examples of large molecules associating nonspecifically with large surfaces. -
Mottramite Pbcu(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Orthorhombic
Mottramite PbCu(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or dipyramidal {111}, prismatic [001] or [100], with {101}, {201}, many others, to 3 mm, in drusy crusts, botryoidal, usually granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼5.9 D(calc.) = 6.187 Optical Properties: Transparent to nearly opaque. Color: Grass-green, olive-green, yellow- green, siskin-green, blackish brown, nearly black. Streak: Yellowish green. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.17(2) β = 2.26(2) γ = 2.32(2) 2V(meas.) = ∼73◦ Cell Data: Space Group: P nma. a = 7.667–7.730 b = 6.034–6.067 c = 9.278–9.332 Z=4 X-ray Powder Pattern: Mottram St. Andrew, England; close to descloizite. 3.24 (vvs), 5.07 (vs), 2.87 (vs), 2.68 (vs), 2.66 (vs), 2.59 (vs), 1.648 (vs) Chemistry: (1) (2) (1) (2) CrO3 0.50 ZnO 0.31 10.08 P2O5 0.24 PbO 55.64 55.30 As2O5 1.33 H2O 3.57 2.23 V2O5 21.21 22.53 insol. 0.17 CuO 17.05 9.86 Total 100.02 100.00 (1) Bisbee, Arizona, USA; average of three analyses. (2) Pb(Cu, Zn)(VO4)(OH) with Zn:Cu = 1:1. -
Descloizite Pbzn(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1
Descloizite PbZn(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or pyramidal {111}, prismatic [001] or [100], or tabular {100}, with {101}, {201}, many others, rarely skeletal, to 5 cm, commonly in drusy crusts, stalactitic or botryoidal, coarsely fibrous, granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼6.2 D(calc.) = 6.202 Optical Properties: Transparent to nearly opaque. Color: Brownish red, red-orange, reddish brown to blackish brown, nearly black. Streak: Orange to brownish red. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.185(10) β = 2.265(10) γ = 2.35(10) 2V(meas.) = ∼90◦ Cell Data: Space Group: P nma. a = 7.593 b = 6.057 c = 9.416 Z = 4 X-ray Powder Pattern: Venus mine, [El Guaico district, C´ordobaProvince,] Argentina; close to mottramite. 3.23 (vvs), 5.12 (vs), 2.90 (vs), 2.69 (vsb), 2.62 (vsb), 1.652 (vs), 4.25 (s) Chemistry: (1) (2) (1) (2) SiO2 0.02 ZnO 19.21 10.08 As2O5 0.00 PbO 55.47 55.30 +350◦ V2O5 22.76 22.53 H2O 2.17 −350◦ FeO trace H2O 0.02 MnO trace H2O 2.23 CuO 0.56 9.86 Total 100.21 100.00 (1) Abenab, Namibia. -
Toxicological Profile for Vanadium
VANADIUM 107 4. CHEMICAL AND PHYSICAL INFORMATION 4.1 CHEMICAL IDENTITY Vanadium is a naturally occurring element that appears in group 5(B5) of the periodic table (Lide 2008). Vanadium is widely distributed in the earth’s crust at an average concentration of 100 ppm nd (approximately 100 mg/kg), similar to that of zinc and nickel (Byerrum 1991). Vanadium is the 22 most abundant element in the earth’s crust (Baroch 2006). Vanadium is found in about 65 different minerals; carnotite, roscoelite, vanadinite, and patronite are important sources of this metal along with bravoite and davidite (Baroch 2006, Lide 2008). It is also found in phosphate rock and certain ores and is present in some crude oils as organic complexes (Lide 2008). Table 4-1 lists common synonyms and other pertinent identification information for vanadium and representative vanadium compounds. 4.2 PHYSICAL AND CHEMICAL PROPERTIES Vanadium is a gray metal with a body-centered cubic crystal system. It is a member of the first transition series. Because of its high melting point, it is referred to as a refractory metal (Baroch 2006). When highly pure, it is a bright white metal that is soft and ductile. It has good structural strength and a low- fission neutron cross section. Vanadium has good corrosion resistance to alkalis, sulfuric and hydrochloric acid, and salt water; however, the metal oxidizes readily above 660 °C (Lide 2008). The chemistry of vanadium compounds is related to the oxidation state of the vanadium (Woolery 2005). Vanadium has oxidation states of +2, +3, +4, and +5. When heated in air at different temperatures, it oxidizes to a brownish black trioxide, a blue black tetraoxide, or a reddish orange pentoxide. -
Ferricerite-(La) (La, Ce, Ca)9Fe (Sio4)3(Sio3oh)4(OH)3
3+ Ferricerite-(La) (La, Ce, Ca)9Fe (SiO4)3(SiO3OH)4(OH)3 Crystal Data: Hexagonal. Point Group: 3m. Forms boxwork-like aggregates of equant to tabular crystals flattened on [00*1] to 2 mm with dominant rhombohedral and pinacoidal faces, as pseudomorphs after an unidentified hexagonal prismatic mineral. Physical Properties: Cleavage: None. Tenacity: Brittle. Fracture: Conchoidal. Hardness = 5 D(meas.) = 4.7(1) D(calc.) = 4.74 Optical Properties: Translucent. Color: Light yellow to pinkish brown. Streak: White. Luster: Vitreous. Optical Class: Uniaxial (+). ω = 1.810(5) ε = 1.820(5) Cell Data: Space Group: R3c. a = 10.7493(6) c = 38.318(3) Z = 6 X-ray Powder Pattern: Mt. Yuksporr, Khibina massif, Kola Peninsula, Russia. 2.958 (100), 3.47 (40), 3.31(38), 2.833 (37), 2.689 (34), 1.949 (34), 3.53 (26) Chemistry: (1) (2) La2O3 37.57 CaO 5.09 Ce2O3 23.67 Fe2O3 1.40 Pr2O3 0.61 MgO 0.51 Nd2O3 1.48 SiO2 22.38 Sm2O3 0.10 P2O5 0.63 Gd2O3 0.24 H2O 3.20 SrO 1.97 Total 98.85 (1) Mt. Yuksporr, Khibina massif, Kola Peninsula, Russia; average electron microprobe analysis supplemented by IR spectroscopy, H2O by Penfield method; corresponds to (La4.23Ce2.65Ca1.37Sr0.35 Nd0.16Pr0.07Gd0.02Sm0.01)Σ=8.86(Fe0.32Ca0.30Mg0.23)Σ=0.85[SiO4]3[(Si0.84P0.16)Σ=1.00O3(OH)]4(OH)2.78. Mineral Group: Cerite supergroup, cerite group. Occurrence: A late-stage, low-temperature secondary phase in a symmetrically zoned, aegirine- natrolite-microcline vein in gneissose foyaite. -
Tungsten Minerals and Deposits
DEPARTMENT OF THE INTERIOR FRANKLIN K. LANE, Secretary UNITED STATES GEOLOGICAL SURVEY GEORGE OTIS SMITH, Director Bulletin 652 4"^ TUNGSTEN MINERALS AND DEPOSITS BY FRANK L. HESS WASHINGTON GOVERNMENT PRINTING OFFICE 1917 ADDITIONAL COPIES OF THIS PUBLICATION MAY BE PROCURED FROM THE SUPERINTENDENT OF DOCUMENTS GOVERNMENT PRINTING OFFICE WASHINGTON, D. C. AT 25 CENTS PER COPY CONTENTS. Page. Introduction.............................................................. , 7 Inquiries concerning tungsten......................................... 7 Survey publications on tungsten........................................ 7 Scope of this report.................................................... 9 Technical terms...................................................... 9 Tungsten................................................................. H Characteristics and properties........................................... n Uses................................................................. 15 Forms in which tungsten is found...................................... 18 Tungsten minerals........................................................ 19 Chemical and physical features......................................... 19 The wolframites...................................................... 21 Composition...................................................... 21 Ferberite......................................................... 22 Physical features.............................................. 22 Minerals of similar appearance................................. -
Mottramite, Descloizite, and Vanadinite) in the Caldbeck Area of Cumberland
289 New occurrences of vanadium minerals (mottramite, descloizite, and vanadinite) in the Caldbeck area of Cumberland. By ART~VR W. G. KINGSBURu F.G.S., Dept. of Geology and Mineralogy, University Museum, Oxford, and J. HARTLnY, B.Sc., F.G.S., Dept. of Geology, University of Leeds. [Taken as read 10 June 1954.] Summary.--Four new occurrences of vanadium minerals are described. New X-ray powder data are given for descloizite and mottramite, and show appreciable differences. Evidence is brought that the original occurrence of mottramite was not at Mottram St. Andrew, Cheshire, but Pim Hill, Shropshire, and that most if not all specimens labelled Mottram St. Andrew or Cheshire really came from Pim Hill. ANADIUM minerals are rare in the British Isles, and only two V species, mottramite (Cu, Zn)PbV0tOH and vanadinite Pbs(VO4)aC1, have so far been recorded from a limited number of localities. We do not include the vanadiferous nodules from Budleigh Salterton in Devon, as the vanadiferous mineral has not been identified. Mottramite, supposedly from Mottram St. Andrew in Cheshire, was first described in 1876,1 but we have evidence (below, p. 293) that the locality was in fact Pim Hill in Shropshire. ~ Vanadinite has so far only been found at Leadhills and Wanlockhead in Scotland. Vauquelinite has been de- scribed from Leadhills and Wanlockhead,a but the specimens have since been shown to be mottramite. 4 As a result of our investigations in the Lake District, we have found several new localities in the Caldbeck area for raottramite, deseloizite, and vanadinite. Higher part of Brandy Gill, Carroek Fell.