DOCSLIB.ORG

Vanadium Pentoxide and Other Inorganic Vanadium Compounds

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Vanadium Pentoxide and Other Inorganic Vanadium Compounds This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organization, or the World Health Organization. Concise International Chemical Assessment Document 29 VANADIUM PENTOXIDE AND OTHER INORGANIC VANADIUM COMPOUNDS Note that the layout and pagination of this pdf file are not identical to the printed CICAD First draft prepared by Dr M. Costigan and Mr R. Cary, Health and Safety Executive, Liverpool, United Kingdom, and Dr S. Dobson, Centre for Ecology and Hydrology, Huntingdon, United Kingdom Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization, and the World Health Organization, and produced within the framework of the Inter-Organization Programme for the Sound Management of Chemicals. World Health Organization Geneva, 2001 The International Programme on Chemical Safety (IPCS), established in 1980, is a joint venture of the United Nations Environment Programme (UNEP), the International Labour Organization (ILO), and the World Health Organization (WHO). The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management of chemicals. The Inter-Organization Programme for the Sound Management of Chemicals (IOMC) was established in 1995 by UNEP, ILO, the Food and Agriculture Organization of the United Nations, WHO, the United Nations Industrial Development Organization, the United Nations Institute for Training and Research, and the Organisation for Economic Co-operation and Development (Participating Organizations), following recommendations made by the 1992 UN Conference on Environment and Development to strengthen cooperation and increase coordination in the field of chemical safety. The purpose of the IOMC is to promote coordination of the policies and activities pursued by the Participating Organizations, jointly or separately, to achieve the sound management of chemicals in relation to human health and the environment. WHO Library Cataloguing-in-Publication Data Vanadium pentoxide and other inorganic vanadium compounds. (Concise international chemical assessment document ; 29) 1.Vanadium compounds - adverse effects 2.Risk assessment 3.Environmental exposure I.International Programme on Chemical Safety II.Series ISBN 92 4 153029 4 (NLM Classification: QV 290) ISSN 1020-6167 The World Health Organization welcomes requests for permission to reproduce or translate its publications, in part or in full. Applications and enquiries should be addressed to the Office of Publications, World Health Organization, Geneva, Switzerland, which will be glad to provide the latest information on any changes made to the text, plans for new editions, and reprints and translations already available. ©World Health Organization 2001 Publications of the World Health Organization enjoy copyright protection in accordance with the provisions of Protocol 2 of the Universal Copyright Convention. All rights reserved. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the World Health Organization concerning the legal status of any country, territory, city, or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The Federal Ministry for the Environment, Nature Conservation and Nuclear Safety, Germany, provided financial support for the printing of this publication. Printed by Wissenschaftliche Verlagsgesellschaft mbH, D-70009 Stuttgart 10 TABLE OF CONTENTS FOREWORD .................................................................................. 1 1. EXECUTIVE SUMMARY ....................................................................... 4 2. IDENTITY AND PHYSICAL/CHEMICAL PROPERTIES ............................................. 6 3. ANALYTICAL METHODS ...................................................................... 6 3.1 Workplace air monitoring ................................................................... 6 3.2 Biological monitoring ...................................................................... 6 3.3 Environmental monitoring .................................................................. 7 4. SOURCES OF HUMAN AND ENVIRONMENTAL EXPOSURE ....................................... 8 5. ENVIRONMENTAL TRANSPORT, DISTRIBUTION, AND TRANSFORMATION ...................... 9 5.1 Chemical speciation of vanadium ............................................................. 9 5.2 Essentiality of vanadium ................................................................... 9 5.3 Bioaccumulation .......................................................................... 9 5.4 Leaching and bioavailability in soils .......................................................... 10 6. ENVIRONMENTAL LEVELS AND HUMAN EXPOSURE ........................................... 10 6.1 Environmental levels ..................................................................... 10 6.1.1 Air ............................................................................. 10 6.1.2 Surface waters and sediments ......................................................... 11 6.1.3 Biota ............................................................................ 11 6.1.4 Soil ............................................................................. 12 6.2 Human exposure ......................................................................... 12 7. COMPARATIVE KINETICS AND METABOLISM IN LABORATORY ANIMALS AND HUMANS ................................................................................... 14 8. EFFECTS ON LABORATORY MAMMALS AND IN VITRO TEST SYSTEMS .......................... 14 8.1 Single exposure .......................................................................... 15 8.1.1 Vanadium pentoxide ................................................................ 15 8.1.2 Other pentavalent vanadium compounds ................................................ 15 8.1.3 Tetravalent vanadium compounds ..................................................... 15 8.1.4 Trivalent vanadium compounds ....................................................... 15 8.2 Irritation and sensitization ................................................................. 15 8.3 Effects of inhaled vanadium compounds on the respiratory tract ................................... 16 8.4 Other short-term exposure studies ........................................................... 17 8.4.1 Vanadium pentoxide ................................................................ 17 8.4.2 Other pentavalent vanadium compounds ................................................ 17 8.4.3 Tetravalent vanadium compounds ..................................................... 18 8.5 Medium-term exposure ................................................................... 18 8.5.1 Vanadium pentoxide and other pentavalent vanadium compounds ............................ 18 8.5.2 Tetravalent vanadium compounds ..................................................... 19 8.6 Long-term exposure and carcinogenicity ...................................................... 19 8.6.1 Vanadium pentoxide and other pentavalent vanadium compounds ............................ 19 iii Concise International Chemical Assessment Document 29 8.6.2 Tetravalent vanadium compounds ..................................................... 19 8.7 Genotoxicity and related end-points ......................................................... 19 8.7.1 Studies in prokaryotes .............................................................. 19 8.7.1.1 Vanadium pentoxide ........................................................ 19 8.7.1.2 Other pentavalent vanadium compounds ........................................ 19 8.7.1.3 Tetravalent vanadium compounds ............................................. 19 8.7.1.4 Trivalent vanadium compounds ............................................... 19 8.7.2 In vitro studies in eukaryotes ......................................................... 19 8.7.2.1 Vanadium pentoxide ........................................................ 19 8.7.2.2 Other pentavalent vanadium compounds ........................................ 20 8.7.2.3 Tetravalent vanadium compounds ............................................. 21 8.7.2.4 Trivalent vanadium compounds ............................................... 21 8.7.3 Sister chromatid exchange ............................................................ 21 8.7.4 Other in vitro studies ............................................................... 21 8.7.4.1 Vanadium pentoxide ........................................................ 21 8.7.4.2 Other pentavalent vanadium compounds ........................................ 21 8.7.4.3 Tetravalent vanadium compounds ............................................
Load more

Recommended publications
  • JAN Iia 20U T6T1/V
    IN REPLY REFER TO: UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY WASHINGTON 25. D.C. November 19, 1956 AEC-193/7 Mr. Robert D. Nininger Assistant Director for Exploration Division of Bav Materials U* S. Atomic Energy Commission Washington 25, D. C, Dear Bobs Transmitted herewith are three copies of TEI-622, "The crystal chemistry and mineralogy of vanadium," by Ho-ward T. Evans, Jr. Me are asking Mr. Hosted to approve our plan to publish this report as a chapter of a Geological Survey professional paper on miner­ alogy and geochemistry of the ores of the Colorado Plateau. Aelrnovledg- ment of AEC sponsorship will be made in the introductory chapter* Sincerely yours, r ^ O U—— TV , Z^*i—w«__ ™~ W. H. Bradley Chief Geoldigist .JAN iia 20U T6T1/V Geology and 8$i:aeralQgy This document consists of k-2 pages* Series A» Howard T. Erans, Jr, Trace Elements Investigations Report 622 This preliminary report is distributed without editorial and technical review for conformity with official standards and nomenclature. It is not for public inspection or quotation* *This report concerns work done on behalf of the Division of Raw Materials of the U. S« Atomic Energy Commission* - TEI-622 AHD MIHERALQ6T Distribution (Series A) Ro. of copies Atomic Energy Commission, Washington .»**«»..*»..«*»..««..*... 2 Division of Rs¥ Materials, Albuquerque ,...****.*.«.»*.....*.. 1 Division of Raw Materials, Austin »«,..«.»...»*.»...*«..*...«» 1 Diylsion of Raw Materials, Butte *«*,.»».*..,*...».»......*.*. 1 Division of Raw Materials, Casper ............a............... 1 Division of Raw Ifeterials, Denver ,........»...».....«.,.*..... 1 Division of Raw Materials, Ishpeming .................a....... 1 Division of Raw Materials, Pnoenix ...a.....,....*........*... 1 Division of Eaw Materials, Rapid City .......................
    [Show full text]
  • Kinetic Studies of Sodium and Metforminium Decavanadates Decomposition and in Vitro Cytotoxicity and Insulin- Like Activity
    inorganics Article Kinetic Studies of Sodium and Metforminium Decavanadates Decomposition and In Vitro Cytotoxicity and Insulin- Like Activity Aniela M. Silva-Nolasco 1,2, Luz Camacho 2 , Rafael Omar Saavedra-Díaz 1, Oswaldo Hernández-Abreu 1 , Ignacio E. León 3 and Irma Sánchez-Lombardo 1,* 1 Centro de Investigación de Ciencia y Tecnología Aplicada de Tabasco, División Académica de Ciencias Básicas (CICTAT), Universidad Juárez Autónoma de Tabasco, Carretera Cunduacán-Jalpa km. 1 Col. La Esmeralda, Cunduacán 86690, Tabasco, Mexico; [email protected] (A.M.S.-N.); [email protected] (R.O.S.-D.); [email protected] (O.H.-A.) 2 Laboratorio de Nutrición Experimental, Instituto Nacional de Pediatría, Ciudad de Mexico 04530, Mexico; [email protected] 3 Centro de Química Inorgánica CEQUINOR (CONICET, UNLP), Bv 120 1465, La Plata 1900, Argentina; [email protected] * Correspondence: [email protected] Received: 22 October 2020; Accepted: 2 December 2020; Published: 8 December 2020 Abstract: The kinetics of the decomposition of 0.5 and 1.0 mM sodium decavanadate (NaDeca) and metforminium decavanadate (MetfDeca) solutions were studied by 51V NMR in Dulbecco’s modified Eagle’s medium (DMEM) medium (pH 7.4) at 25 ◦C. The results showed that decomposition products 2 4 are orthovanadate [H2VO4]− (V1) and metavanadate species like [H2V2O7] − (V2), [V4O12] − (V4) 5 and [V5O15] − (V5) for both compounds. The calculated half-life times of the decomposition reaction were 9 and 11 h for NaDeca and MetfDeca, respectively, at 1 mM concentration. The hydrolysis products that presented the highest rate constants were V1 and V4 for both compounds.
    [Show full text]
  • US Schedule for Internet V2
    Draft as of March 23, 2007 Subject to legal review for accuracy, clarity and consistency. Annex 3.3 - - Industrial/Textile Schedule for the United States Tariff Elimination US 8 digit Description MFN RATE Schedule 03011000 Live ornamental fish Free I 03019100 Live trout Free I 03019200 Live eels Free I 03019300 Live carp Free I 03019900 Live fish, other than trout, eel, carp or ornamental fish Free I 03021100 Trout, fresh or chilled, excluding fillets, other meat portions, livers and roes Free I Pacific, Atlantic and Danube salmon, fresh or chilled, excluding fillets, other 03021200 meat portions, livers and roes Free I Salmonidae other than trout or Pacific, Atlantic & Danube salmon, fresh or 03021900 chilled, excluding fillets, other meat portions, livers & roes Free I Halibut and Greenland turbot, fresh or chilled, excluding fillets, other meat 03022100 portions, livers and roes Free I 03022200 Plaice, fresh or chilled, excluding fillets, other meat portions, livers and roes Free I 03022300 Sole, fresh or chilled, excluding fillets, other meat portions, livers and roes 1.1 cents/kg A Flat fish, nesi, fresh or chilled, excluding fillets, other meat portions, livers 03022900 and roes Free I Albacore or longfinned tunas, fresh or chilled, excluding fillets, other meat 03023100 portions, livers and roes Free I Yellowfin tunas, fresh or chilled, excluding fillets, other meat portions, livers 03023200 and roes Free I Skipjack or stripe-bellied bonito, fresh or chilled, excluding fillets, other meat 03023300 portions, livers and roes Free
    [Show full text]
  • PROVISIONAL PEER-REVIEWED TOXICITY VALUES for VANADIUM and ITS SOLUBLE INORGANIC COMPOUNDS OTHER THAN VANADIUM PENTOXIDE (CASRN 7440-62-2 and Others)
    EPA/690/R-09/070F l Final 9-30-2009 Provisional Peer-Reviewed Toxicity Values for Vanadium and Its Soluble Inorganic Compounds Other Than Vanadium Pentoxide (CASRN 7440-62-2 and Others) Derivation of Subchronic and Chronic Oral RfDs Superfund Health Risk Technical Support Center National Center for Environmental Assessment Office of Research and Development U.S. Environmental Protection Agency Cincinnati, OH 45268 Commonly Used Abbreviations BMD Benchmark Dose IRIS Integrated Risk Information System IUR inhalation unit risk LOAEL lowest-observed-adverse-effect level LOAELADJ LOAEL adjusted to continuous exposure duration LOAELHEC LOAEL adjusted for dosimetric differences across species to a human NOAEL no-observed-adverse-effect level NOAELADJ NOAEL adjusted to continuous exposure duration NOAELHEC NOAEL adjusted for dosimetric differences across species to a human NOEL no-observed-effect level OSF oral slope factor p-IUR provisional inhalation unit risk p-OSF provisional oral slope factor p-RfC provisional inhalation reference concentration p-RfD provisional oral reference dose RfC inhalation reference concentration RfD oral reference dose UF uncertainty factor UFA animal to human uncertainty factor UFC composite uncertainty factor UFD incomplete to complete database uncertainty factor UFH interhuman uncertainty factor UFL LOAEL to NOAEL uncertainty factor UFS subchronic to chronic uncertainty factor i FINAL 9-30-2009 PROVISIONAL PEER-REVIEWED TOXICITY VALUES FOR VANADIUM AND ITS SOLUBLE INORGANIC COMPOUNDS OTHER THAN VANADIUM PENTOXIDE (CASRN 7440-62-2 and others) Background On December 5, 2003, the U.S. Environmental Protection Agency's (U.S. EPA) Office of Superfund Remediation and Technology Innovation (OSRTI) revised its hierarchy of human health toxicity values for Superfund risk assessments, establishing the following three tiers as the new hierarchy: 1) U.S.
    [Show full text]
  • 2012 Bmc Auction Specimens
    A SAMPLER OF SELECTED 2017 BMC AUCTION SPECIMENS (2017 Auction Date is Saturday, 21 January) Volume 3 3+ Hematite [Fe 2O3] & Quartz [SiO2] Locality Cleator Moor Iron Mines Cleator Moor West Cumberland Iron Field Cumbria, England, UK Size 13.5 x 9.5 x 7.0 cm 1498 g Donated by Stonetrust Hematite Crystal System: Trigonal Photograph by Mike Haritos Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 6.5 Density: approx 5.3 gm/cm3 Streak: Red Luster: Metalic Vanadinite [Pb5(VO4)3Cl] var. Endlichite Locality Erupción Mine (Ahumada Mine) Los Lamentos Mountains (Sierra de Los Lamentos) Mun. de Ahumada Chihuahua, Mexico Size 12.0 x 9.5 x 7.0 cm 1134 g Donated by Stonetrust Crystal System: Hexagonal Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 3.5-4 Photograph by Mike Haritos Density: 6.8 to 7.1 gm/cm3 Streak: Brownish yellow Endlichite, Pb5([V, As]O4)3Cl, is the arsenic rich Luster: Adamantine variety of vanadinite with arsenic atoms (As) substituting for some of the vanadium (V) 2+ Dolomite [CaMg(CO3)2] & Chalcopyrite [CuFe S2] Locality Picher Field Tri-State District Ottawa Co. Oklahoma, USA Size 19.0 x 14.5 x 6.0 cm 1892 g Consigned with Reserve by Stonetrust Dolomite Crystal System: Trigonal Physical Properties Photograph by Mike Haritos Transparency: Transparent, Translucent, Opaque Mohs hardness: 3.5 to 4 Density: 2.8 to 2.9 gm/cm3 Streak: White Luster: Vitreous Calcite [CaCO3] Locality Mexico Size 15.5 x 12.8 x 6.2 cm 1074 g Donated by Stonetrust Calcite Crystal System: Trigonal Physical Properties Transparency: Transparent, Translucent Mohs hardness: 3 Density: 2.71 gm/cm3 Streak: White Luster: Vitreous, Sub-Vitreous, Photograph by Mike Haritos Resinous, Waxy, Pearly Quartz [SiO2], var.
    [Show full text]
  • Adsorption of RNA on Mineral Surfaces and Mineral Precipitates
    Adsorption of RNA on mineral surfaces and mineral precipitates Elisa Biondi1,2, Yoshihiro Furukawa3, Jun Kawai4 and Steven A. Benner*1,2,5 Full Research Paper Open Access Address: Beilstein J. Org. Chem. 2017, 13, 393–404. 1Foundation for Applied Molecular Evolution, 13709 Progress doi:10.3762/bjoc.13.42 Boulevard, Alachua, FL, 32615, USA, 2Firebird Biomolecular Sciences LLC, 13709 Progress Boulevard, Alachua, FL, 32615, USA, Received: 23 November 2016 3Department of Earth Science, Tohoku University, 2 Chome-1-1 Accepted: 15 February 2017 Katahira, Aoba Ward, Sendai, Miyagi Prefecture 980-8577, Japan, Published: 01 March 2017 4Department of Material Science and Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama This article is part of the Thematic Series "From prebiotic chemistry to 240-8501, Japan and 5The Westheimer Institute for Science and molecular evolution". Technology, 13709 Progress Boulevard, Alachua, FL, 32615, USA Guest Editor: L. Cronin Email: Steven A. Benner* - [email protected] © 2017 Biondi et al.; licensee Beilstein-Institut. License and terms: see end of document. * Corresponding author Keywords: carbonates; natural minerals; origins of life; RNA adsorption; synthetic minerals Abstract The prebiotic significance of laboratory experiments that study the interactions between oligomeric RNA and mineral species is difficult to know. Natural exemplars of specific minerals can differ widely depending on their provenance. While laboratory-gener- ated samples of synthetic minerals can have controlled compositions, they are often viewed as "unnatural". Here, we show how trends in the interaction of RNA with natural mineral specimens, synthetic mineral specimens, and co-precipitated pairs of synthe- tic minerals, can make a persuasive case that the observed interactions reflect the composition of the minerals themselves, rather than their being simply examples of large molecules associating nonspecifically with large surfaces.
    [Show full text]
  • Gravimetric Determination of Vanadium As V(IV)-Oxinate
    Chem. Anal. (Warsaw), 38, 639 (1993) Gravimetric Determination of Vanadium as V(IV)-Oxinate by S. Kaur, A. K. Chhakkarand L. R. Kakkar* Department ofChemistry, Kurukshetra University, Kurukshetra -132119, Haryana; India Key words: vanadium(V), oxine, 8-hydroxyquinoline, gravimetry A very simple gravimetric method for the determination of vanadium has been worked out. In acid medium vanadium is reduced to tetravalent state which forms greenish-black precipitate with 8-hydroxyquinoline (2 % in 2 mol 1-1 CH3COOH) in the presence of ammonium acetate. The precipitate is dried and weighedas VO(C9H60 N)2. The con­ version factor for vanadium is 0.1437. The method is free from the interference of molybdenum(VI), chromium(III,VI), uranium(VI), selenium(IV), arsenic(I1I), bis­ muth(III), lead(U), calcium(II), manganese(I1) and maguesium(II). Opracowanoprosta wagow'\ metode oznaczania wanadu. Wauad(V) redukuje silt w kwasnym roztworze do wanadu(IV), ktory w obecnosci octanuamonu tworzy z 8-hydro­ ksychinolina (2 % roztwor w 2 mol 1-1CH3COOH) zielonoczaruy osad. Po wysuszeniu osad jestwazonyjako VO(C9H60 Nh Mnoznik analityczny wynosi dla wanadu 0,1437. W oznaczeniu nie przeszkadzaja: molibden(VI), chrom(III,VI), uran(VI), selen(IV), arsen(III), bizmut(III), o16w(II), wapriffl), mangan(II} i magnez(II), Many inorganic [1-4a] and organic [5-8, 11] precipitants employed for the estimation of vanadium in milligram amounts are. unsuitable for routine analysis, either because they are not quantitative or because other elements are coprecipitated withvanadium, and also in some cases, the precipitate formed does not have a definite composition. Cup ferron [4b] is generally recommended for the precipitation of vanadium, but several precautions are necessary because ofthe instability of cupfer­ ron and many other elements are precipitated by the reagent under conditions ofthe * Senior author for correspondence.
    [Show full text]
  • Step-By-Step Guide to Better Laboratory Management Practices
    Step-by-Step Guide to Better Laboratory Management Practices Prepared by The Washington State Department of Ecology Hazardous Waste and Toxics Reduction Program Publication No. 97- 431 Revised January 2003 Printed on recycled paper For additional copies of this document, contact: Department of Ecology Publications Distribution Center PO Box 47600 Olympia, WA 98504-7600 (360) 407-7472 or 1 (800) 633-7585 or contact your regional office: Department of Ecology’s Regional Offices (425) 649-7000 (509) 575-2490 (509) 329-3400 (360) 407-6300 The Department of Ecology is an equal opportunity agency and does not discriminate on the basis of race, creed, color, disability, age, religion, national origin, sex, marital status, disabled veteran’s status, Vietnam Era veteran’s status or sexual orientation. If you have special accommodation needs, or require this document in an alternate format, contact the Hazardous Waste and Toxics Reduction Program at (360)407-6700 (voice) or 711 or (800) 833-6388 (TTY). Table of Contents Introduction ....................................................................................................................................iii Section 1 Laboratory Hazardous Waste Management ...........................................................1 Designating Dangerous Waste................................................................................................1 Counting Wastes .......................................................................................................................8 Treatment by Generator...........................................................................................................12
    [Show full text]
  • Chemical Analyses for Selected Minor Elements in Pierre Shale
    Chemical Analyses for Selected Minor Elements in Pierre Shale GEOLOGICAL SURVEY PROFESSIONAL PAPER 391-A Chemical Analyses for Selected Minor Elements in Pierre Shale By L. F. RADER and F. S. GRIMALDI ANALYTICAL METHODS IN GEOCHEMICAL INVESTIGATIONS OF THE PIERRE SHALE GEOLOGICAL SURVEY PROFESSIONAL PAPER 391-A UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1961 UNITED STATES DEPARTMENT OF THE INTERIOR STEW ART L. UDALL, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director For sale by the Superintendent of Documents, U.S. Government Printing Office Washington 25, D.C. CONTENTS Page Page Abstract--_________________________________________ A-l Methods for the determination of individual Introduction ___-----_-_--_________________-__--__-_ 1 constituents Continued General remarks._________________________ ______ 1 Copper lead, and zinc Continued Laboratories. -._---____-_-______________________ 2 Zinc, dithizone method._____^_______________ A-20 Acknowledgments. ___-_-_-_--______--_-_________ 2 Lead, dithizone method______------_-____-__- 22 Division of work________________________________ 2 Arsenic.___________,__________-_-_--___-__---_- 23 Methods selected and treatment of data ___________ 3 Acid digestion, heteropoly blue method________ 23 Sample preparation _________________________________ 4 Alternative fusion-heteropoly blue method_____ 24 Methods for the determination of individual constituents. 4 Titanium. _____________________________________ 4 Selenium, distillation, visual-estimation method.____ 25 Peroxide method._--_--_-____._____________ 4 Molybdenum and tungsten______-____------_---_- 27 Alternative tiron method, ___________________ 5 Isolation by method 1, alpha-benzoinoxime pre­ Vanadium. _--.---_____-_-___.__________________ 7 cipitation. ___----_-_-_-__--_----_-----_-- 27 Fusion-leach separation method. _____________ 7 Isolation by alternative method 2, alpha-ben­ Alternative cupferron separation method......
    [Show full text]
  • New Methods for the Determination of Trace Quantities of Vanadium. Sham Lal Sachdev Louisiana State University and Agricultural & Mechanical College
    Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1966 New Methods for the Determination of Trace Quantities of Vanadium. Sham Lal Sachdev Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Sachdev, Sham Lal, "New Methods for the Determination of Trace Quantities of Vanadium." (1966). LSU Historical Dissertations and Theses. 1135. https://digitalcommons.lsu.edu/gradschool_disstheses/1135 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. This dissertation has been microfilmed exactly as received SACHDEV, Sham Lai, 1937- NEW METHODS FOR THE DETERMINATION OF TRACE QUANTITIES OF VANADIUM. Louisiana State University, Ph.D., 1966 Chemistry, analytical University Microfilms, Inc., Ann Arbor, Michigan NEW METHODS FOR THE DETERMINATION OF TRACE QUANTITIES OF VANADIUM A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Chemistry by Sham Lai Sachdev B.S., Panjab University, 1959 M.S.., Pan jab University, i960 January, 1966 ACKNOWLEDGMENTS The author wishes to express his gratitude to Professor Philip W. West for directing this research. He also wishes to express his appreciation for the help and encouragement extended to him by Dr. J. W. Robinson, his colleagues and many members of the graduate faculty of the Chemistry Department at Louisiana State University.
    [Show full text]
  • Toxicological Profile for Vanadium
    VANADIUM 107 4. CHEMICAL AND PHYSICAL INFORMATION 4.1 CHEMICAL IDENTITY Vanadium is a naturally occurring element that appears in group 5(B5) of the periodic table (Lide 2008). Vanadium is widely distributed in the earth’s crust at an average concentration of 100 ppm nd (approximately 100 mg/kg), similar to that of zinc and nickel (Byerrum 1991). Vanadium is the 22 most abundant element in the earth’s crust (Baroch 2006). Vanadium is found in about 65 different minerals; carnotite, roscoelite, vanadinite, and patronite are important sources of this metal along with bravoite and davidite (Baroch 2006, Lide 2008). It is also found in phosphate rock and certain ores and is present in some crude oils as organic complexes (Lide 2008). Table 4-1 lists common synonyms and other pertinent identification information for vanadium and representative vanadium compounds. 4.2 PHYSICAL AND CHEMICAL PROPERTIES Vanadium is a gray metal with a body-centered cubic crystal system. It is a member of the first transition series. Because of its high melting point, it is referred to as a refractory metal (Baroch 2006). When highly pure, it is a bright white metal that is soft and ductile. It has good structural strength and a low- fission neutron cross section. Vanadium has good corrosion resistance to alkalis, sulfuric and hydrochloric acid, and salt water; however, the metal oxidizes readily above 660 °C (Lide 2008). The chemistry of vanadium compounds is related to the oxidation state of the vanadium (Woolery 2005). Vanadium has oxidation states of +2, +3, +4, and +5. When heated in air at different temperatures, it oxidizes to a brownish black trioxide, a blue black tetraoxide, or a reddish orange pentoxide.
    [Show full text]
  • Ferro Vanadium Production Business. Ferrovanadium Market Is Expected to Expand at a CAGR of 5.0% Between 2018 and 2028
    www.entrepreneurindia.co Introduction Ferro Vanadium is an alloy which is formed by combining iron and vanadium with a vanadium content range of 35%-85%. Ferro Vanadium is a universal hardener, strengthener and anti-corrosive additive for steels like high-strength low-alloy (HSLA) steel, tool steels, as well as other ferrous-based products. Ferro vanadium belongs to the category of ferroalloy. Ferro vanadium is an alloy which is formed by combining iron and vanadium. Ferrovanadium contains 35% to 85% of vanadium depending on applications of the product in end-use industry. Ferro vanadium is an alloy material that is used in manufacturing of steel. It imparts desirable properties such as abrasion resistance, high temperature and hardenability. www.entrepreneurindia.co Ferro vanadium used for manufacturing of steel offers the end product with high stability against alkalis as well as acids such as sulphuric and hydrochloric acids. In addition, products containing ferro vanadium are at reduced risk to be susceptible to corrosion. Ferro vanadium also helps in reducing the overall weight of the material as well as increasing the overall tensile strength of the end product. In addition, it helps in promoting fine grain size and increasing hardenability through precipitation of nitrides and carbides. Ferro vanadium is manufactured using an electric arc furnace in which scrap iron is melted initially and then it is combined with the mixture of aluminum as well as flux such as calcium fluoride and calcium oxide. It is usually supplied in pallet boxes or in shrink wrapped in super bags. www.entrepreneurindia.co Ferro Vanadium is produced from Vanadium Sludge & usually available in the range with V: 50-85%.
    [Show full text]