Curriculum Vitae Professor Dr. Martin Jansen

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Curriculum Vitae Professor Dr. Martin Jansen Name: Martin Jansen Born: 5 November 1944 Main areas of research: preparative solid-state chemistry, crystal chemistry, materials research, structure-property relationship of solids Since 1998, he has been a member of the scientific council of the Max Planck Society and a director at the Max Planck Institute for solid-state research in StuttgartHe has developed a concept for plan- ning solid state syntheses, combining computational and experimental tools, that is pointing the way to rational and efficient discovery of new materials. Academic and Professional Career since 1998 Director at the Max Planck Institute for Solid State Research, Stuttgart and Honorary Professor at the University of Stuttgart, Germany 1987 - 1998 Professor (C4) and Director of the Institute at the University of Bonn, Germany 1981 - 1987 Professor (C4), Chair B for Inorganic Chemistry of the University of Hannover, Germany 1978 Habilitation at the University of Gießen, Germany 1973 Promotion (Ph.D.) at the University of Gießen, Germany 1966 - 1970 Study of Chemistry at the University of Gießen, Germany Honours and Awarded Memberships (Selection) 2019 Otto-Hahn-Prize 2009 Centenary Prize, Royal Society of Chemistry, UK 2009 Georg Wittig - Victor Grignard Prize, Société Chimique de France 2008 Member of acatech (National Academy of Science and Engineering) Nationale Akademie der Wissenschaften Leopoldina www.leopoldina.org 1 2007 Karl Ziegler Award, Germany 2004 Honorary Doctorate of the Ludwig Maximilians-University of Munich, Germany 2004 Science Award of the Stifterverband for the German science system, Germany 2000 Member of the German Academy of Sciences Leopoldina 2000 Member of Berlin-Brandenburg Academy of Sciences and Humanities 2000 Member of Academia Europaea 1996 Alfred Stock Memorial Award 1996 Member of North Rhine-Westphalia Academy of Scienc, Humanities and Art, Düssedorf (since 1998 corresponding member), Germany 1989 Gottfried Wilhelm Leibniz Award, Germany Major Scientific Interests Jansen's group puts its main emphasis on basic research in the field of preparative solid state chemistry with the goal of developing modern materials. Classes of materials currently under investigation include oxides and nitrides of metals and nonmetals as well as fullerenes, e.g., new binary and ternary oxides, ionic conductors, structural oxide ceramics and pigments, amorphous inorganic nitridic covalent networks, or endohedral fullerenes and fullerides. Be- sides employing traditional solid state synthesis methods, a large number of alternative techniques is used, e.g., the sol-gel process, synthesis under high pressure, via an rf-furnace, at low temperatures in liquid ammonia, by electrochemical methods, or by low-temperature atomic beam deposition. Optimizing the syntheses of new materials is only a first, though crucial step, however. In addition, their chemical and physical properties, in particular optical, electrical and magnetic behavior, are analyzed both at high and low temperatures. This pro- vides the basis for placing the results in the proper context regarding structure-property rela- tionships and modern concepts of bond theory. A long-term goal of the department is to in- crease the predictability of solid state chemistry, i.e., to predict the existence of not-yet syn- thesized compounds, calculate their properties, and finally provide prescriptions for their synthesis. This work involves both theoretical and synthetic aspects. On the theoretical side, structure candidates are determined by studying the energy landscapes of chemical systems using global exploration techniques, while on the preparative side kinetically controlled types of reactions that allow low-temperature synthesis of (possibly metastable) compounds are being developed. Nationale Akademie der Wissenschaften Leopoldina www.leopoldina.org 2 .

Recommended publications

Boron-Nitrogen Compounds

springer.com Chemistry : Inorganic Chemistry Niedenzu, Kurt, Dawson, J.W. Boron-Nitrogen Compounds Although the chemistry of boron is still relatively young, it is developing at a pace where even specific areas of research are difficult to compile into a monograph. Besides the boron hydrides, boron-nitrogen compounds are among the most fascinating derivatives of boron. Nitrogen compounds exist in a wide variety of molecular structures and display many interesting properties. The combination of nitrogen and boron, however, has some unusual features that are hard to match in any other combination of elements. This situation was first recognized by ALFRED STOCK and it seems proper to pay tribute to his outstanding work in the area of boron chemistry. One should realize that about forty years ago, STOCK and his coworkers had to develop completely new experimental techniq'\les and that no guidance for the interpreta• tion of their rather unusual data had been advanced by theoretical chemists. In this monograph an attempt has been made to explore the general characteristics of structure and the principles involved in the preparation and reactions of boron-nitroge~ compounds. It was a somewhat difficult task to select that information which appears to be of the most Springer interest to "inorganic and general chemistry" since the electronic relationship between a boron- nitrogen and a carbon-carbon grouping is reflected in the "organic" character of many of the Softcover reprint of the 1st reactions and compounds. original 1st ed. 1965, VIII,
04. Si Monsters

IV The Chemistry of Bug-Eyed Silicon Monsters 1. The Rise and Fall of an Analogy Carbon and silicon were not always regarded as isova- lent analogs of one another. The great Swedish chem- ist, Jöns Jakob Berzelius (figure 1), who was the first to isolate silicon as a simple substance in 1823, thought that it most resembled boron (1, 2). This assignment was based on the fact that both elements formed acidic, nonvolatile oxides which could act as glass formers, and on a similarity in the appearance of the simple substances themselves, both of which had been pre- pared only as highly-impure, amorphous, nonmetallic powders. This analogy was further reinforced by errors in the determination of their atomic weights, which assigned the analogous formulas, BO3 and SiO3, to their respective oxides, in sharp contrast to the formu- las, CO and CO2, assigned to the oxides of carbon. With the gradual correction of atomic weights and the equally gradual substitution of “stoichiometric type” or valence, in place of acidity and electronegativity, as the preferred basis for chemical classification, silicon was reassigned as an analog of carbon. In 1857, the German chemist, Friedrich Wöhler (figure 2), discovered silicon tetrahydride (SiH4), the stoichiometric and structural analog of methane (CH4), and the logical starting point for speculations on an Figure 2. Friedrich Wöhler (1800-1882). alternative organic chemistry based on silicon rather than carbon (3). Ironically, however, Wöhler did not consider this possibility until 1863 and then only as a result of a faulty interpretation of his experimental data. Having obtained, via the hydrolysis of magne- sium silicide, a series of apparent compounds of sili- con, hydrogen and oxygen, he found it very difficult to assign them exact formulas.
Download Author Version (PDF)

Dalton Transactions Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/dalton Page 1 of 11 PleaseDalton do not Transactions adjust margins Journal Name ARTICLE Boron Nitride Ceramics from Molecular Precursor: Synthesis, Properties and Applications Received 00th January 20xx, † Accepted 00th January 20xx Samuel Bernard, Chrystelle Salameh and Philippe Miele* DOI: 10.1039/x0xx00000x www.rsc.org/ Hexagonal boron nitride (h-BN) attracts considerable interest according to its structure similar to carbon graphite while it displays different properties which offer attractivity for environmental and green technologies. The polar nature of the B-N bond in sp 2-bonded BN makes it a wide band gap insulator with different chemistry on its surface and particular physical and chemical properties such as a high thermal conductivity, a high temperature stability, a high resistance to corrosion and oxidation and a strong UV emission.
Fritz Arndt and His Chemistry Books in the Turkish Language

42 Bull. Hist. Chem., VOLUME 28, Number 1 (2003) FRITZ ARNDT AND HIS CHEMISTRY BOOKS IN THE TURKISH LANGUAGE Lâle Aka Burk, Smith College Fritz Georg Arndt (1885-1969) possibly is best recog- his “other great love, and Brahms unquestionably his nized for his contributions to synthetic methodology. favorite composer (5).” The Arndt-Eistert synthesis, a well-known reaction in After graduating from the Matthias-Claudius Gym- organic chemistry included in many textbooks has been nasium in Wansbek in greater Hamburg, Arndt began used over the years by numerous chemists to prepare his university education in 1903 at the University of carboxylic acids from their lower homologues (1). Per- Geneva, where he studied chemistry and French. Fol- haps less well recognized is Arndt’s pioneering work in lowing the practice at the time of attending several in- the development of resonance theory (2). Arndt also stitutions, he went from Geneva to Freiburg, where he contributed greatly to chemistry in Turkey, where he studied with Ludwig Gattermann and completed his played a leadership role in the modernization of the sci- doctoral examinations. He spent a semester in Berlin ence (3). A detailed commemorative article by W. Walter attending lectures by Emil Fischer and Walther Nernst, and B. Eistert on Arndt’s life and works was published then returned to Freiburg and worked with Johann in German in 1975 (4). Other sources in English on Howitz and received his doctorate, summa cum laude, Fritz Arndt and his contributions to chemistry, specifi- in 1908. Arndt remained for a time in Freiburg as a cally discussions of his work in Turkey, are limited.
AWARDS, HONORS, DISTINGUISHED LECTURESHIPS Prof. Dr. Dieter Seebach

AWARDS, HONORS, DISTINGUISHED LECTURESHIPS Prof. Dr. Dieter Seebach 1964 <> Wolf-Preis for the Ph.D. thesis, Universität Karlsruhe, Germany 1969 <> Dozentenpreis Fonds der Chemischen Industrie, Germany 1969/1970 – Visiting Professorship, University of Wisconsin, Madison, USA 1972 – "DuPont Travel Grantee", USA (lectures at 15 universities and companies) 1974 – Visiting Professorship, California Institute of Technology, Pasadena, USA 1977 – Visiting Professorship, Rand Afrikaans University, Johannesburg, South Africa – "Pacific Coast Lectureship“, USA/Canada (9 lectures at universities and companies along theUSA west coast) 1978 – Visiting Professorship, Polish Academy of Sciences (lectures in Warsaw and Lodz) 1980 – Visiting Professorship, Australian National University, Canberra, Australia – Visiting Professorship, Imperial College, London, U.K. 1981 – Visiting Professorship at the Weizmann Institute of Science, Rehovot, Israel –"Kolthoff Lectureship", University of Minnesota, Minneapolis, USA 1981 – „Carl Ziegler Visiting Professorship“, Max-Planck-Institut für Kohlenforschung, Mülheim a.d.Ruhr, Germany 1982 – "Vorhees Memorial Lectureship", University of Illinois, Urbana-Champaign, USA – "First Atlantic Coast Lectureship", (6 lectures at universities of the South-East of USA) – "Organic Syntheses Lectureship", Princeton University, Princeton, USA 1984 <> FRSC (Fellow of the Royal Society of Chemistry, U.K.) <> Elected member of the Deutsche Akademie der Naturforscher Leopoldina, D-Halle – "Greater Manchester Lectureship", University
Philip D. Lane Ziegler-Natta Catalysis: the Nature of the Active Site Literature Seminar April 3, 1992 Karl Ziegler, While Study

47 Ziegler-Natta Catalysis: The Nature of the Active Site Philip D. Lane Literature Seminar April 3, 1992 Karl Ziegler, while studying ethylene insertion into aluminum-alkyl bonds, serendipi tously discovered the effect transition metals had on ethylene polymerization. He and Guilio Natta made significant contributions to the catalytic polymerization of olefins using a transition metal from groups 4-8 and an organometallic from groups 1, 2, or 13, the most famous com bination being TiC4 + Al(C2H5)3 for the polymerization of polyethylene. The Nobel Prize in Chemistry was awarded to them in 1963 for their contributions in this area [l,2]. The impor tance of this catalytic process can be seen by the amount of polyethylene produced in the U.S. In 1990, 8.3 billion lbs. of high-density polyethylene were produced [3]. The heterogeneous nature of Ziegler-Natta catalysts make them difficult to study [l,4,5]. Despite improved techniques for studying surfaces, information on an atomic level about the active sites remains elusive. For example, the surface reaction of [Zr(allyl)4] with SiQi leads to different surface species [5]. It is not clear which of the resulting surface species is responsible for the polymerization process. Various mechanisms [6,7] have been proposed for Ziegler-Natta catalysis, with the most widely accepted proposal from Cossee and Adman (Figure 1). The aluminum-alkyl is suggested to be responsible for alkylating the transition metal which is in an octahedral environment with one site vacant. Ethylene is thought to coordinate, followed by direct insertion into the metal-alkyl bond of the transition metal.
The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals

University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange Masters Theses Graduate School 8-2013 The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals Zachary Reynolds Sprigler [email protected] Follow this and additional works at: https://trace.tennessee.edu/utk_gradthes Recommended Citation Sprigler, Zachary Reynolds, "The Design of Redox-Active, Olefin Polymerization Catalysts Using Late- Transition Metals. " Master's Thesis, University of Tennessee, 2013. https://trace.tennessee.edu/utk_gradthes/2458 This Thesis is brought to you for free and open access by the Graduate School at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Masters Theses by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. To the Graduate Council: I am submitting herewith a thesis written by Zachary Reynolds Sprigler entitled "The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals." I have examined the final electronic copy of this thesis for form and content and recommend that it be accepted in partial fulfillment of the equirr ements for the degree of Master of Science, with a major in Chemistry. Brian K. Long, Major Professor We have read this thesis and recommend its acceptance: Jimmy Mays, David Jenkens Accepted for the Council: Carolyn R. Hodges Vice Provost and Dean of the Graduate School (Original signatures are on file with official studentecor r ds.) The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals A Thesis Presented for the Masters of Science Degree The University of Tennessee, Knoxville Zachary Reynolds Sprigler August 2013 Copyright © 2013 by Zachary R.
COMMITTEE RSC Historical Group Newsletter No. 60 August 2011

COMMITTEE RSC Historical Group Newsletter No. 60 August 2011 Chairman: Prof A T Dronsfield School of Education, Health and Sciences, Contents University of Derby, Derby, DE22 1GB From the Editor 3 [e-mail [email protected]] Royal Society of Chemistry Historical Group News 4 Secretary: Prof W P Griffith Electronic Version of the Newsletter 4 Depositing the RSC Historical Group Newsletter at the British Library 5 Department of Chemistry, Imperial College, Royal Society of Chemistry Historical Group AGM 5 South Kensington, London, SW7 2AZ Minutes of AGM - 19 March 2010 6 [e-mail [email protected]] January 2011 Newsletter – Feedback Marelene Rayner-Canham and Geoff Treasurer; Dr J A Hudson Rayner-Canham 8 Membership Graythwaite, Loweswater, Cockermouth, Members’ Publications 10 Secretary: Cumbria, CA13 0SU Recent publications by Historical Group Committee Members 11 NEWS AND UPDATES 13 [e-mail [email protected]] Partington Prize 13 Newsletter Dr A Simmons Royal Society Exhibition - Visualising Matter: The Graphic Teaching Tools of Editor Epsom Lodge, La Grande Route de St Jean, Chemistry in the Age of Revolution 14 St John, Jersey, JE3 4FL Syracuse University Plastics Collection Goes Online 14 [e-mail [email protected]] USEFUL WEBSITES AND ADDRESSES 15 Newsletter Dr G P Moss Centenary of Marie Curie’s Nobel Prize for Chemistry - Bill Griffith 17 Production & School of Biological and Chemical Sciences, Some Thoughts on Marie Curie, Double Nobel Laureate - Marelene Rayner-Canham Distribution: Queen Mary University of London, and Geoff Rayner-Canham 23 BOOK REVIEW 27 Mile End Road, London E1 4NS Joséf Hurwic, Maria Sklodowska-Curie and Radioactivity- Bill Griffith 27 [e-mail [email protected]] SHORT ESSAYS 28 Committee: Prof J Betteridge (Twickenham, Middlesex) George Kakabadse (1917-2002): Analytical Chemist with a Remarkable History - Dr N G Coley (Open University) Derry W.
The First Hydrides of Boron

UNIVERSIDADE DE LISBOA FACULDADE DE CIÊNCIAS SECÇÃO AUTÓNOMA DE HISTÓRIA E FILOSOFIA DAS CIÊNCIAS UNDER THE CARBON SPELL: DIBORANE’S PUZZLING STRUCTURE AND THE EMERGENGE OF BORON CHEMISTRY Nuno Manuel Castanheira de Figueiredo Dissertação orientada pela Professora Doutora Ana Simões, da Secção Autónoma de Filosofia e História das Ciências da Faculdade de Ciências da Universidade de Lisboa. MESTRADO EM HISTÓRIA E FILOSOFIA DAS CIÊNCIAS 2011 Resumo Este trabalho apresenta o primeiro estudo sistemático da história da química dos boranos, compostos de boro e hidrogénio cujas estruturas e natureza das ligações químicas desafiaram de forma irredutível a teoria da ligação química até aos anos cinquenta do século XX. Actualmente, a química do boro é um dos mais promissores ramos da química, com um vasto leque de aplicações às indústrias química e farmacéutica, à nano-tecnologia e à medicina. Neste último ramo, destacam-se as aplicações na luta contra o cancro e no desenvolvimento de medicamentos com um elevado grau de especificidade e inovação. Num futuro próximo, espera-se que a química do boro seja capaz de operar uma verdadeira revolução social, posicionando-se como uma poderosa alternativa à química do carbono que será capaz de oferecer todo um novo mundo de aplicações inéditas. Estas são o resultado da fascinante capacidade do átomo de boro para se ligar de formas surpreendentes e formar complexas estruturas que se baseiam em compostos de boro e hidrogénio (boranos). A grande apetência do boro para se ligar ao oxigénio impede que os boranos existam na natureza. A grande susceptibilidade destes à acção da humidade e do ar torna-os especialmente instáveis e difíceis de manusear e preservar.
Karl Ziegler

K ARL Z I E G L E R Consequences and development of an invention* Nobel Lecture, December 12, 1963 The awarding of the Nobel Prize for Chemistry for the year 1963 is related to the precipitous expansion of macromolecular chemistry and its industrial ap- plications, which began precisely ten years ago at my Max-Planck-Institute for Coal Research, in Mülheim/Ruhr. The suddenness with which this began, and the rapidity with which it was propagated are comparable to an explosion. The energy carriers in this case were the ingenuity, activity, creative imagina- tion and bold concepts of the many unnamed chemists, designers and entre- preneurs in the world who have fashioned great industries from our humble beginnings. If today I stand with my colleague Natta, who has been particularly effective in promoting this explosive wave, in the limelight of distinction, and do wish to manifest, with this address, my appreciation for the honor bestowed upon me, I must begin by thanking these many anonymous persons. They, too, deserve this distinction. The extent of this "explosion" may be illustrated by two charts 1, in which the location of newly-established plants is indicated. The places marked by black circles refer to the production of high molecular weight materials, the crosses to new production facilities which, though concerned with low mo- lecular weight materials, nevertheless also have some connection with the ad- dress I am delivering today (Figs. 1 and 2). The new development had its inception near the end of 1953, when I, to- gether with Holzkamp, Breil and Martina, observed-during only a few days of an almost dramatic course of events-that ethylene gas will polymerize very rapidly with certain catalysts that are extremely easy to prepare, at 100, 20 and 5 atmospheres and, finally, even at normal pressure, to a high molecular weight plastic.
Karl Ziegler Mülheim an Der Ruhr, 8

Historische Stätten der Chemie Karl Ziegler Mülheim an der Ruhr, 8. Mai 2008 Karl Ziegler, Bronzebüste, gestaltet 1964 von Professor Herbert Kaiser-Wilhelm-/Max-Planck-Institut für Kohlenforschung, Mülheim Kühn, Mülheim an der Ruhr (Foto T. Hobirk 2008; Standort Max- an der Ruhr. Oben: Altbau von 1914 am Kaiser-Wilhelm-Platz. Unten: Plancn k-Institut für Kohlenforschung, Mülheim an der Ruhr). Laborhochhaus von 1967 an der Ecke Lembkestraße/Margaretenplatz (Fotos G. Fink, M. W. Haenel, um 1988). Gesellschaft Deutscher Chemiker 1 137051_GDCh_Broschuere_Historische_StaettenK2.indd 1 02.09.2009 16:13:26 Uhr Mit dem Programm „Historische Stätten der Chemie“ würdigt die Gesellschaft Deutscher Chemiker (GDCh) Leistungen von geschichtlichem Rang in der Chemie. Zu den Zielen des Programms gehört, die Erinnerung an das kulturelle Erbe der Chemie wach zu halten und diese Wis- senschaft sowie ihre historischen Wurzeln stärker in das Blickfeld der Öffentlichkeit zu rücken. So werden die Wirkungsstätten von Wissenschaftlerinnen oder Wissen- schaftlern als Orte der Erinnerung in einem feierlichen Akt ausgezeichnet. Außerdem wird eine Broschüre er- stellt, die das wissenschaftliche Werk der Laureaten einer breiten Öffentlichkeit näherbringt und die Tragweite ihrer Arbeiten im aktuellen Kontext beschreibt. Am 8. Mai 2008 gedachten die GDCh und das Max- Planck-Institut für Kohlenforschung in Mülheim an der Ruhr des Wirkens von KARL ZIEGLER, der mit seinen bahnbrechenden Arbeiten auf dem Gebiet der organischen Chemie zu den Begründern der metallorganischen
James, Steinhauser, Hoffmann, Friedrich One Hundred Years at The

James, Steinhauser, Hoffmann, Friedrich One Hundred Years at the Intersection of Chemistry and Physics Published under the auspices of the Board of Directors of the Fritz Haber Institute of the Max Planck Society: Hans-Joachim Freund Gerard Meijer Matthias Schefﬂer Robert Schlögl Martin Wolf Jeremiah James · Thomas Steinhauser · Dieter Hoffmann · Bretislav Friedrich One Hundred Years at the Intersection of Chemistry and Physics The Fritz Haber Institute of the Max Planck Society 1911–2011 De Gruyter An electronic version of this book is freely available, thanks to the support of libra- ries working with Knowledge Unlatched. KU is a collaborative initiative designed to make high quality books Open Access. More information about the initiative can be found at www.knowledgeunlatched.org Aut ho rs: Dr. Jeremiah James Prof. Dr. Dieter Hoffmann Fritz Haber Institute of the Max Planck Institute for the Max Planck Society History of Science Faradayweg 4–6 Boltzmannstr. 22 14195 Berlin 14195 Berlin [email protected] [email protected] Dr. Thomas Steinhauser Prof. Dr. Bretislav Friedrich Fritz Haber Institute of the Fritz Haber Institute of the Max Planck Society Max Planck Society Faradayweg 4–6 Faradayweg 4–6 14195 Berlin 14195 Berlin [email protected] [email protected] Cover images: Front cover: Kaiser Wilhelm Institute for Physical Chemistry and Electrochemistry, 1913. From left to right, “factory” building, main building, director’s villa, known today as Haber Villa. Back cover: Campus of the Fritz Haber Institute of the Max Planck Society, 2011. The Institute’s his- toric buildings, contiguous with the “Röntgenbau” on their right, house the Departments of Physical Chemistry and Molecular Physics.