Fritz Arndt and His Chemistry Books in the Turkish Language
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Boron-Nitrogen Compounds
springer.com Chemistry : Inorganic Chemistry Niedenzu, Kurt, Dawson, J.W. Boron-Nitrogen Compounds Although the chemistry of boron is still relatively young, it is developing at a pace where even specific areas of research are difficult to compile into a monograph. Besides the boron hydrides, boron-nitrogen compounds are among the most fascinating derivatives of boron. Nitrogen compounds exist in a wide variety of molecular structures and display many interesting properties. The combination of nitrogen and boron, however, has some unusual features that are hard to match in any other combination of elements. This situation was first recognized by ALFRED STOCK and it seems proper to pay tribute to his outstanding work in the area of boron chemistry. One should realize that about forty years ago, STOCK and his coworkers had to develop completely new experimental techniq'\les and that no guidance for the interpreta• tion of their rather unusual data had been advanced by theoretical chemists. In this monograph an attempt has been made to explore the general characteristics of structure and the principles involved in the preparation and reactions of boron-nitroge~ compounds. It was a somewhat difficult task to select that information which appears to be of the most Springer interest to "inorganic and general chemistry" since the electronic relationship between a boron- nitrogen and a carbon-carbon grouping is reflected in the "organic" character of many of the Softcover reprint of the 1st reactions and compounds. original 1st ed. 1965, VIII, -
Curriculum Vitae Professor Dr. Martin Jansen
Curriculum Vitae Professor Dr. Martin Jansen Name: Martin Jansen Born: 5 November 1944 Main areas of research: preparative solid-state chemistry, crystal chemistry, materials research, structure-property relationship of solids Since 1998, he has been a member of the scientific council of the Max Planck Society and a director at the Max Planck Institute for solid-state research in StuttgartHe has developed a concept for plan- ning solid state syntheses, combining computational and experimental tools, that is pointing the way to rational and efficient discovery of new materials. Academic and Professional Career since 1998 Director at the Max Planck Institute for Solid State Research, Stuttgart and Honorary Professor at the University of Stuttgart, Germany 1987 - 1998 Professor (C4) and Director of the Institute at the University of Bonn, Germany 1981 - 1987 Professor (C4), Chair B for Inorganic Chemistry of the University of Hannover, Germany 1978 Habilitation at the University of Gießen, Germany 1973 Promotion (Ph.D.) at the University of Gießen, Germany 1966 - 1970 Study of Chemistry at the University of Gießen, Germany Honours and Awarded Memberships (Selection) 2019 Otto-Hahn-Prize 2009 Centenary Prize, Royal Society of Chemistry, UK 2009 Georg Wittig - Victor Grignard Prize, Société Chimique de France 2008 Member of acatech (National Academy of Science and Engineering) Nationale Akademie der Wissenschaften Leopoldina www.leopoldina.org 1 2007 Karl Ziegler Award, Germany 2004 Honorary Doctorate of the Ludwig Maximilians-University of -
04. Si Monsters
IV The Chemistry of Bug-Eyed Silicon Monsters 1. The Rise and Fall of an Analogy Carbon and silicon were not always regarded as isova- lent analogs of one another. The great Swedish chem- ist, Jöns Jakob Berzelius (figure 1), who was the first to isolate silicon as a simple substance in 1823, thought that it most resembled boron (1, 2). This assignment was based on the fact that both elements formed acidic, nonvolatile oxides which could act as glass formers, and on a similarity in the appearance of the simple substances themselves, both of which had been pre- pared only as highly-impure, amorphous, nonmetallic powders. This analogy was further reinforced by errors in the determination of their atomic weights, which assigned the analogous formulas, BO3 and SiO3, to their respective oxides, in sharp contrast to the formu- las, CO and CO2, assigned to the oxides of carbon. With the gradual correction of atomic weights and the equally gradual substitution of “stoichiometric type” or valence, in place of acidity and electronegativity, as the preferred basis for chemical classification, silicon was reassigned as an analog of carbon. In 1857, the German chemist, Friedrich Wöhler (figure 2), discovered silicon tetrahydride (SiH4), the stoichiometric and structural analog of methane (CH4), and the logical starting point for speculations on an Figure 2. Friedrich Wöhler (1800-1882). alternative organic chemistry based on silicon rather than carbon (3). Ironically, however, Wöhler did not consider this possibility until 1863 and then only as a result of a faulty interpretation of his experimental data. Having obtained, via the hydrolysis of magne- sium silicide, a series of apparent compounds of sili- con, hydrogen and oxygen, he found it very difficult to assign them exact formulas. -
Download Author Version (PDF)
Dalton Transactions Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/dalton Page 1 of 11 PleaseDalton do not Transactions adjust margins Journal Name ARTICLE Boron Nitride Ceramics from Molecular Precursor: Synthesis, Properties and Applications Received 00th January 20xx, † Accepted 00th January 20xx Samuel Bernard, Chrystelle Salameh and Philippe Miele* DOI: 10.1039/x0xx00000x www.rsc.org/ Hexagonal boron nitride (h-BN) attracts considerable interest according to its structure similar to carbon graphite while it displays different properties which offer attractivity for environmental and green technologies. The polar nature of the B-N bond in sp 2-bonded BN makes it a wide band gap insulator with different chemistry on its surface and particular physical and chemical properties such as a high thermal conductivity, a high temperature stability, a high resistance to corrosion and oxidation and a strong UV emission. -
David Rivett
DAVID RIVETT: FIGHTER FOR AUSTRALIAN SCIENCE OTHER WORKS OF ROHAN RIVETT Behind Bamboo. 1946 Three Cricket Booklets. 1948-52 The Community and the Migrant. 1957 Australian Citizen: Herbert Brookes 1867-1963. 1966 Australia (The Oxford Modern World Series). 1968 Writing About Australia. 1970 This page intentionally left blank David Rivett as painted by Max Meldrum. This portrait hangs at the Commonwealth Scientific and Industrial Research Organisation's headquarters in Canberra. ROHAN RIVETT David Rivett: FIGHTER FOR AUSTRALIAN SCIENCE RIVETT First published 1972 All rights reserved No part of this book may be reproduced in any form without permission © Rohan Rivett, 1972 Printed in Australia at The Dominion Press, North Blackburn, Victoria Registered in Australia for transmission by post as a book Contents Foreword Vll Acknowledgments Xl The Attack 1 Carving the Path 15 Australian at Edwardian Oxford 28 1912 to 1925 54 Launching C.S.I.R. for Australia 81 Interludes Without Playtime 120 The Thirties 126 Through the War-And Afterwards 172 Index 219 v This page intentionally left blank Foreword By Baron Casey of Berwick and of the City of Westminster K.G., P.C., G.C.M.G., C.H., D.S.a., M.C., M.A., F.A.A. The framework and content of David Rivett's life, unusual though it was, can be briefly stated as it was dominated by some simple and most unusual principles. He and I met frequently in the early 1930's and discussed what we were both aiming to do in our respective fields. He was a man of the most rigid integrity and way of life. -
THEODORE WILLIAM RICHARDS January 31, 1868-April 2, 1928
NATIONAL ACADEMY OF SCIENCES T H E O D O R E W I L L I A M R ICHARDS 1868—1928 A Biographical Memoir by JAMES BRYANT CONANT Any opinions expressed in this memoir are those of the author(s) and do not necessarily reflect the views of the National Academy of Sciences. Biographical Memoir COPYRIGHT 1974 NATIONAL ACADEMY OF SCIENCES WASHINGTON D.C. THEODORE WILLIAM RICHARDS January 31, 1868-April 2, 1928 BY JAMES BRYANT CONANT HEODORE WILLIAM RICHARDS was a precocious son of distin- Tguished parents. He was born in Philadelphia on January 31, 1868, the third son and fifth child of William Trost Richards and Anna Matlack Richards, who had been married on June 30, 1856. As strict members of the Society of Friends, the Matlack family looked askance at a young man who earned his living painting pictures. Anna was "read out of meeting." The Quaker marriage ceremony took place in the house of a friend. The first months of the honeymoon were devoted to the com- position and illustration of a manuscript volume of poems for the lady who had first brought the young couple together. A mutual interest in Browning and Tennyson had started an acquaintanceship which rapidly became a romance. An old friend and fellow artist of Philadelphia reminiscing long after W. T. Richards had established his reputation as a landscape painter said, "He amazed me by getting married and resigning his position as designer [in a local firm manufacturing gas fixtures] in order to devote himself entirely to his art. -
From Physical Chemistry to Chemical Physics, 1913-1941
International Workshop on the History of Chemistry 2015 Tokyo From Physical Chemistry to Chemical Physics, 1913-1941 Jeremiah James Ludwig-Maximillian University, Munich, Germany There has never been one unique name for the intersection of chemistry and physics. Nor has it ever been defined by a single, stable set of methods. Nevertheless, it is possible and arguably rewarding to distinguish changes in the constellation of terms and techniques that have defined the intersection over the years. I will speak today about one such change, the advent and ascendancy of chemical physics in the interwar period. When the young Friedrich Wilhelm Ostwald first began to formulate his campaign for “physical chemistry” in 1877, he used the term almost interchangeably with two others, “general chemistry” and “theoretical chemistry.” According to his vision of what would soon become a new chemical discipline, physical chemistry would investigate and formulate the general principles that underlie all chemical reactions and phenomena. The primary strategy that he and his allies used to generate these principles was to formulate mathematical “laws” or “rules” generalizing the results of numerous experiments, often performed using measuring apparatus borrowed from physics. Their main fields of inquiry were thermochemistry and solution theory, and they avoided and often openly maligned speculations regarding structures or mechanisms that might underlie the macroscopic regularities embodied in their laws.1 In the first decades of the 20th-century, the modern atomic theory was firmly established, and with only a slight delay, the methods of 19th-century physical chemistry lost a considerable proportion of their audience. Theories relying upon atomistic thinking began to reshape the disciplinary intersections of chemistry and physics, and by the end of the 1930s, cutting-edge research into the general principles of chemistry looked quite different than it had at the turn of the century. -
Uma Breve História Da Geometria Molecular Sob a Perspectiva Didático-Epistemológica De Guy Brousseau
Uma Breve História da Geometria Molecular sob a Perspectiva Didático-Epistemológica de Guy Brousseau Kleyfton Soares da Silva Laerte Silva da Fonseca Johnnatan Duarte de Freitas RESUMO O objetivo desta pesquisa foi analisar a evolução histórica da Geometria Molecular (GM), de modo a apresentar discussões, limitações, dificuldades e avanços associados à concepção do saber em jogo e, através disso, contribuir com elementos para análise crítica da organização didática em livros e sequências de ensino. Foi realizado um levantamento histórico na perspectiva epistemológica defendida por Brousseau (1983), em que a compreensão da evolução conceitual do conteúdo visado pelo estudo é alcançada quando há o entrelaçamento de fatos que ajudam a identificar obstáculos que limitaram e/ou limitam a aprendizagem de um dado conteúdo. Trata-se de uma abordagem inédita tanto pelo direcionamento do conteúdo como pela metodologia adotada. A análise histórica permitiu traçar um conjunto de oito obstáculos que por um lado estagnou a evolução do conceito de GM e por outro impulsionou cientistas a buscarem alternativas teóricas e metodológicas para resolver os problemas que foram surgindo ao longo do tempo. O estudo mostrou que a questão da visualização em química e da necessidade de manipulação física de modelos moleculares é constitutiva da própria evolução história da GM. Esse ponto amplifica a necessidade de superação contínua dos obstáculos epistemológicos e cognitivos associados às representações moleculares. Palavras-chave: Análise Epistemológica. Geometria -
Book Review Tuxedo Park, by Jennet Conant (Simon & Schuster, 2002), 330 Pp., ISBN 0684872870, $26.00
Book Review Tuxedo Park, by Jennet Conant (Simon & Schuster, 2002), 330 pp., ISBN 0684872870, $26.00 Reviewed by Jane A. Roman Department of Chemistry, Regis College, Weston, MA In the early chapters of this book, Jennet Conant, granddaughter of James Conant former President of Harvard and esteemed scientist, describes brilliantly the life of Alfred Lee Loomis, philanthropist, scientist and Wall Street tycoon. Prompted by the mysterious circumstances surrounding the suicide of her granduncle, William Richards, son of Nobel laureate Theodore William Richards, Jennet using her granduncles’ notes and letters, wrote this biography, which is a small but significant chapter in the history of American science. Her accounts of Loomis depict his relationships with many Nobel Laureates in science and also detail an illicit love affair Loomis had with Manette Hobart, the wife of Garrett A. Hobart III, his protégé and secretary at Tuxedo Park. The setting for most of the book is the region of Tuxedo Park in Orange County, New York where Loomis established a research laboratory, funded solely by his personal fortune. Very important discoveries in radar detection, atomic fission, and other wartime inventions that led the allies to victory over the Germans were made there. Because the circumstances surrounding her granduncle’s death and the hush-up carried out by her family were indicative of the gentry at that time, Ms. Conant was prompted to reveal in her novel the relationship her granduncle had with Loomis in Tuxedo Park. From his papers and letters, she describes how Richards and his friend at Princeton, George Kistiakowsky, came to work at Tuxedo Park, often referring to it as a private scientific playground in the Ramapo Mountains. -
Arndt's Story: the Life of an Australian Economist
BOOK REVIEWS their targets? Will Australia meet ignored. It is unlikely that Scorcher Arndt’s Story: The life of an its Kyoto target? Will it come will convince people of the need Australian economist close to meeting its target? Clearly, to take action to reduce our by Peter Coleman, Selwyn the fairness of Australia’s Kyoto greenhouse gas emissions unless Cornish and Peter Drake target can be debated. they were already predisposed with Bettina Arndt Dr Hamilton is of the view that to this position. As a result, Dr Asia Pacific Press Australia’s emission cap under the Hamilton fails where Mr Gore Canberra, 2007 Kyoto protocol is too generous. and Professor Stern succeeded. $45, 338pp Nonetheless, when analysing the impact of Australia’s decision Reviewed by Damien ISBN 9780731538102 not to ratify the Kyoto protocol, S Eldridge. Damien einz Arndt was a fortunate it seems reasonable to compare has worked for two man. He escaped the fate of actual Australian emissions with organisations mentioned H most of those of Jewish extraction the target emissions for Australia in Scorcher, the Australian born in the Germany of 1915 by in the fi rst commitment period. Greenhouse Office and If Australia is closer to meeting being able to move to Oxford in Charles River Associates 1933 for his university education. its target than some countries International. that did ratify the protocol, why Australia was a fortunate country would the fact that Australia because in 1946 Arndt, just married didn’t ratify the protocol be and embarking on a career as an particularly significant? Maybe economist, accepted a lectureship it sent a particularly bad signal at Sydney University. -
Open-Circuit Voltage Comes from Non-Equilibrium Thermodynamics
J. Non-Equilib. Thermodyn. 2021; 46(1): 91–108 Research Article Diego del Olmo*, Michal Pavelka, and Juraj Kosek Open-Circuit Voltage Comes from Non-Equilibrium Thermodynamics https://doi.org/10.1515/jnet-2020-0070 Received June 25, 2020; revised August 14, 2020; accepted September 22, 2020 Abstract: Originally derived by Walther Nernst more than a century ago, the Nernst equation for the open- circuit voltage is a cornerstone in the analysis of electrochemical systems. Unfortunately, the assumptions behind its derivation are often overlooked in the literature, leading to incorrect forms of the equation when applied to complex systems (for example, those with ion-exchange membranes or involving mixed poten- tials). Such faws can be avoided by applying a correct thermodynamic derivation independently of the form in which the electrochemical reactions are written. The proper derivation of the Nernst equation becomes important, for instance, in modeling of vanadium redox fow batteries or zinc-air batteries. The rigorous path towards the Nernst equation derivation starts in non-equilibrium thermodynamics. Keywords: redox fow batteries, open-circuit voltage, non-equilibrium thermodynamics, Zn-air battery 1 Introduction “Thermodynamics is a funny subject. The frst time you go through it, you don’t understand it at all. The second time you go through it, you think you understand it, except for one or two points. The third time you go through it, you know you don’t understand it, but by that time you are so used to the subject, it doesn’t bother you anymore.” (Arnold Sommerfeld) The open-circuit voltage (OCV) is generally defned as the voltage between the terminals of an electrochem- ical cell when no current fows through the cell. -
Contemporary Issues Concerning Scientific Realism
The Future of the Scientific Realism Debate: Contemporary Issues Concerning Scientific Realism Author(s): Curtis Forbes Source: Spontaneous Generations: A Journal for the History and Philosophy of Science, Vol. 9, No. 1 (2018) 1-11. Published by: The University of Toronto DOI: 10.4245/sponge.v9i1. EDITORIALOFFICES Institute for the History and Philosophy of Science and Technology Room 316 Victoria College, 91 Charles Street West Toronto, Ontario, Canada M5S 1K7 [email protected] Published online at jps.library.utoronto.ca/index.php/SpontaneousGenerations ISSN 1913 0465 Founded in 2006, Spontaneous Generations is an online academic journal published by graduate students at the Institute for the History and Philosophy of Science and Technology, University of Toronto. There is no subscription or membership fee. Spontaneous Generations provides immediate open access to its content on the principle that making research freely available to the public supports a greater global exchange of knowledge. The Future of the Scientific Realism Debate: Contemporary Issues Concerning Scientific Realism Curtis Forbes* I. Introduction “Philosophy,” Plato’s Socrates said, “begins in wonder” (Theaetetus, 155d). Two and a half millennia later, Alfred North Whitehead saw fit to add: “And, at the end, when philosophical thought has done its best, the wonder remains” (1938, 168). Nevertheless, we tend to no longer wonder about many questions that would have stumped (if not vexed) the ancients: “Why does water expand when it freezes?” “How can one substance change into another?” “What allows the sun to continue to shine so brightly, day after day, while all other sources of light and warmth exhaust their fuel sources at a rate in proportion to their brilliance?” Whitehead’s addendum to Plato was not wrong, however, in the sense that we derive our answers to such questions from the theories, models, and methods of modern science, not the systems, speculations, and arguments of modern philosophy.