Environmental Impact Assessment Report For Expansion of M/s Shogun Organics Ltd. Located At Kurkumbh MIDC, Taluka Daund, District Pune, Maharashtra.

SEEPL/EIA/F/IND/SOL/001/2017-18/00 Chapter 7: Additional Studies

Risk Assessment 7.1.1 Introduction As indicated in the earlier chapter the expansion project facilitates to manufacture pesticide, pesticide intermediates and related formulations various types of hazards due to storage, handling & transportation of various chemicals, which are indicated in Chapter no. 2. In order to study the risks envisaged by the activities, the following methodology was adopted. 7.1.1.1 The factory would be manufacturing various products with production quantity Pesticide Technical – 44.5 MT/M, Intermediates – 12.25 MT/M, By-products – 13.8 MT/M and heater machines – 25,000 nos./month. The products would be manufactured on batch basis; a maximum of five products will be manufactured at any given point of time. However hazop studies have been carried out for some hazardous operations and process. 7.1.1.2 A detailed scrutiny of various chemicals which would be stored on the site was done. All the raw materials will be stored either in bags/drums/boxes or carbuoy. Details of the raw materials in storage area is tabulated in Table no – 7.1. 7.1.1.3 Plot layouts showing locations of tanks, fire hydrant tanks & other safety features are depicted in the plot layout discussed in the onsite emergency plan.

7.1.1.4 M.S.D.S.s: Brief M.S.D.S.s of all the above chemicals and other raw materials which would be used in the manufacturing processes of products are used as reference for preparation of Quantitative Risk Assessment & Hazop study.The copies of MSDS is attached as Annexure – 7.5. Table No. 7.1: Raw Material List Quantity Drum No. of Qty at Qty at Area occupied Sr. Raw Material per Cap. Drums any given any pint by drum No. Description Month ( Kg ) time of time (Sq. Ft.) ( MT ) (Tonnes) 1. Allethlone Alcohol 3.744 50 75 28 1.4 24 2. Chrysanthemic Acid 10.894 50 218 83 4.15 71 Chloride

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SEEPL/EIA/F/IND/SOL/001/2017-18/00 Chapter 7: Additional Studies 3. Sodium Hydroxide 2.912 50 58 22 1.1 19 4. Pyridine 6.474 225 29 11 2.475 44 5. Hydrochloric Acid 10.608 50 212 81 4.05 70 6. Toluene 21.931 220 100 38 8.36 152 7. Prallethlone Alcohol 3.614 50 72 28 1.4 24 8. Potassium 1.586 50 32 12 0.6 10 Carbonate 9. Activated Clay 1.56 50 31 12 0.6 10 10. 2,3,5,6-Tetra Fluoro 3.094 50 62 23 1.15 19 Benzyl Alcohol 11. R-Cypermethric 4.056 200 20 8 1.6 32 Acid Chloride 12. Activated Charcoal 0.312 50 6 2 0.100 2 13. m-Phenoxy 3.328 200 17 7 1.4 28 Benzaldehyde 14. Becisthemic Acid 1.742 200 9 3 0.6 12 Chloride 15. Sodium 1.092 50 22 8 0.4 7 Hypochloride 16. Sodium Cynaide 0.962 50 19 7 0.35 6 17. 2-chloro-5-chloro 3.796 200 19 7 1.4 28 methyl pyridine 18. NitroiminoImidazoli 3.354 200 17 7 1.4 28 dine 19. Dimethyl 21.32 200 106 41 8.2 164 Formamide 20. 2-Methyl-3- 1.456 200 7 2 0.4 8 Biphenyl Methanol 21. Cyhalothric Acid 0.936 200 5 2 0.4 8 Chloride 22. n-Hexane 2.575 210 12 4 0.84 16 23. Sodium Bicarbonate 0.312 50 6 2 0.100 2 24. Thiopyrazol 2.47 200 12 4 0.800 16 Alcohol 25. Trichloro Acetic 6.162 200 31 12 2.4 48 Acid 26. Monochloro 2.626 200 13 5 1.0 20 Benzene 27. Hydrogen Peroxide 0.468 50 9 3 0.15 2 28. Boric Acid 0.026 25 1 1 25 2 29. Cypermethric Acid 5.746 225 25 10 2.25 40

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SEEPL/EIA/F/IND/SOL/001/2017-18/00 Chapter 7: Additional Studies Chloride 30. 3-methyl Benzoic 1.222 200 6 2 0.4 8 Acid 31. D-ethyl Amine 0.754 50 15 6 0.3 5 32. Orthophosphric 0.104 25 4 1 0.025 2 Acid 33. W-52 Alcohol 4.134 50 83 32 1.6 27 34. Chrysanthemic Acid 2.028 200 10 4 0.8 16 35. n-Heptane 1.534 210 7 3 0.630 12 36. Thionyl Chloride 7.436 275 27 10 2.75 40 37. Cypermethric Acid 17.134 220 78 30 6.6 120 38. Ephedrine 8.944 200 45 17 3.4 68 39. Caustic Flakes 2.236 50 45 17 0.85 15 40. EDC 26.39 200 132 50 10 200 41. MDC 10.868 200 54 20 4 80 Total : 1751 665 1505

7.1.2 DOW Index

The Dow index has been performed for raw materials which are flammable. As it is a manufacturing industry the use of the solvents are limited. The solvents requirement are less in quantity, therefore the storage of the solvents are mostly in drums. The DOW summary sheet is displayed below in table no. 7.4 which states that the degrees of hazard for all the raw materials are light.

The DOW index worksheet is attached as Annexure 7.1.

Table No. 7.2: DOW Index Summary Sheet

Chemical EDC Toluene n-Hexane Monochloro Benzene Storage Considered Drums Drums Drums Drums

N h 2 2 1 3

N f 3 3 3 1

N r 0 0 0 1 Material Factor, MF 16 16 16 14

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F1 (General Process Hazard) 2.55 2.55 2.55 2.55 F2 (Special Process Hazard) 1.6 1.7 1.4 1.6

F3 (Hazard Factor) 4.08 4.335 3.57 4.08 Fire & Explosion Index 65.28 69.36 57.12 65.28 Degree of Hazard Moderate Moderate Light Moderate

Interpretation

DOW index was performed for four different materials. The degrees of hazard for all the materials were understand to be moderate, except for n-Hexane where it was found to be light. Fire & explosive Index for Toluene was higher than the other materials i.e. 69.3. Therefore the radius and area of exposure was calculated for methanol drum storage. The radius of exposure for toluene is determined to be 18.4 m & area of exposure is around 1072.34 sq. m. The impact would be confined within the factory boundaries. It will lead to an onsite emergency situation which could be handled through appropriate mitigation measures listed below-

Recommendation/Suggestions

1. The raw materials are stored according to their compatibility with other raw materials.

2. Company has adequate written operating instruction and fully documented operating discipline for emergency shutdown, normal operating conditions, routine shutdown etc. which are important for maintaining satisfactory control of a unit.

3. The raw materials are stored in a dedicated area with minimum interference.

4. Appropriate drainage with the slope of 2 % is provided to remove small and large spillage of the chemicals.

5. The provision of fire water supply is provided through the hydrant line passing from the raw material storage area.

6. Provision of hand Extinguishers are provided and found to be adequate with reference to the storage quantity of raw materials.

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The existing safety features provided are satisfactory to tackle the emergency situation raised in the site.

7.1.3 Mond's Index

The principle and general approach used in the DOW method of hazard evaluation have been further developed by ICI Mond Division, Their revised Mond fire, explosive and toxicity index is a series of papers by lewis (1979). The main development made to the DOW Index in the Mond Index are:

1. It covers a wider range of process and storage installation 2. It covers the processing of chemicals with explosive properties 3. A calculation procedure is included to allow for the off-setting effects of good design and control and safety instrumentation 4. The procedure has been extended to cover plant layout 5. Separate indices are calculated to access the hazards of fire, internal explosion and aerial explosion.

Most of the raw materials stored in the site are toxic, corrosive in nature. Hence appropriate standard operating procedure are established by the company for ensuring the safety of the workers handling the raw materials on daily basis. Some selected toxic raw materials are used for calculating the toxicity index using Mond's index.

The Mond's index worksheet is attached as Annexure 7.1

Table 7.3: Mond's Index Summary Sheet

Trichloro Thionyl Chemicals NaOH HCl Acetic acid Chloride Storage Bags Drums Drums Bags N (NFPA Index h 3 3 3 3 Number)

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SEEPL/EIA/F/IND/SOL/001/2017-18/00 Chapter 7: Additional Studies T (Toxicity h 250 250 250 250 factor) MAC (Max allowable 1.22 1.22 5 0.87 concentration)ppm Ts (Correction 125 125 125 125 factor) F1 General 1.2 1.2 1.2 1.2 Process Hazard F2 Special Process 1.6 1.6 1.6 1.8 Hazard Toxicity Index 7.25 7.25 7.25 8.25 Degree of Hazard Moderate Moderate Moderate Moderate

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Interpretation.

According to the Mond's Index the highest toxicity is calculated for the storage of Thionyl Chloride i.e. 8.5 indicating high degree of hazard. Thionyl Chloride is a corrosive liquid & classified as class 8 Corrosive materials under UN DOT classification of Hazardous chemicals. Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over- exposure can result in death. To reduce the intensity of the hazard following recommendation and suggestion should be followed.

Recommendations/ Suggestions

1. The raw materials are stored according to their compatibility.

2. Company has adequate written operating instruction and fully documented operating discipline for emergency shutdown, normal operating conditions, routine shutdown etc. which are important for maintaining satisfactory control of a unit. The SOP‟s are attached as Annexure – 7.3.

3. The raw materials are stored in a dedicated area with minimum interference and well ventilated.

4. Appropriate drainage with the slope of 2 % is provided to remove small and large spillage of the chemicals.

5. The provision of fire water supply is provided through the hydrant line passing from the raw material storage area.

6. Provision of hand Extinguishers are provided and found to be adequate with reference to the storage quantity of raw materials.

7. Provision of neutralizing agents or absorbents in the spill kit is provided to deal with the minor spillage scenario.

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8. The storage & handling of the raw materials SOP‟s have been prepared.

The existing safety features provided are satisfactory to tackle the emergency situation raised in the site.

7.2 Hazop Study

Hazop study has been carried out for hazardous operations and process. For the preparation of the hazop study P & IDs, Operating Procedures, Mass balances and MSDS were used. The hazop study is attached as Annexure 7.2. The brief recommendations of the Hazop studies are highlighted below,

1. It is suggested to translate work instruction in Marathi & display in plants.

2. It is suggested to train all the workmen and supervisors in work instruction.

3. Preventive maintenance schedule should be prepared and strictly followed.

4. It is advised to calibrate weighing balance periodically. Before charging any materials in reactor. It should be tested and confirmed by Q.C Laboratory.

5. It is suggested to prepare Spill control procedure. It is suggested to train all workmen and supervisors in work instructions.

6. Monitoring and calibration of Temperature controllers should be done periodically.

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7.3 DISASTER MANAGEMENT PLAN

The Disaster Management Plan (DMP) is aimed to ensure safety of life, protection of environment, protection of installation, restoration of production and salvage operations in the same order of priorities. For effective implementation of the DMP, it should be widely circulated and personnel training through rehearsals/drills should be organized. Further, the management should be able to demonstrate that its assessment of the consequences as good supporting evidence. To tackle the consequences of a major emergency inside the factory or immediate vicinity of the factory, a DMP has to be formulated and this planned emergency document is called "Disaster Management Plan".

Objectives of Disaster Management Plan [DMP] The objective of the Industrial Disaster Management Plan is to make use of the combined resources of the plant and the outside services to achieve the following:  Effect the rescue and medical treatment of causalities  Safeguard other people  Minimize damage to property and the environment  Initially contain and ultimately bring the incident under control  Identify any dead  Provide for the needs of relatives  Provide authoritative information to the news media  Secure the safe rehabilitation of affected area  Preserve relevant records and equipment for the subsequent inquiry into the cause and circumstances of the emergency. In effect, it is to optimize operational efficiency to rescue rehabilitation and render medical help and to restore normalcy.

7.3.1 Onsite Emergency Plan

The Onsite emergency plan is prepared based on the guidelines mentioned under schedule 6 of the rule 12 (1) of the Maharashtra factories (Control of industrial Major Accidents Hazards) Rules 2003. On-Site emergency preparedness plan has the following objectives:

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1. Safeguard lives and property at site and in its vicinity area. 2. Contain the incident and bring it under control; 3. Minimize damage to lives, property and environment; 4. Rescue and treat casualties; 5. To train the people to act efficiently and with confidence in an emergency. 6. Evacuate people to safe areas; 7. To minimize its occurrence.

7.3.1.1 Name & Address of the person furnishing the Information. Name : Mr. M.V Hande Designation: Director Address: Plot No.D-18, MIDC Kurkumbh, Taluka - Daund, District – Pune.

7.3.1.2 Key personnel of the organization and responsibility assigned to them in case of an emergency.

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Figure No. 7.1: Key personnel of the organization and responsibility assigned

Mr. Amit R. Kalyanaraman Managing Director

Mr. M. V. Hande DIRECTOR

Mr. V. Rajiv Mr. Yuvraj Gharge Accounts & Finance Factory Manager Operation Manager Manager

Mr. R. Lad Mr. Bankar Mr. Bajrang Mr. K. Lad Mr. K. Rao Mr. Nilesh H. Mr. Mahesh Ms. Rupali Technical Prodn. Suryanvanshi Pur & Imp Finance Admin. & Manager Manager Maintenance & Sales & Mktg. Accounts Ex. HR Safety Exe. Exe. Exe. Executive Manager & Safety Ex. Prodn. Mech. & Elect. Q.C. R & D Exec. Exec. Supervisors Supervisors Office Driver

Operators and Chemist ChemisManagert Boys Workers

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1) Site Main Controller During the onsite emergency situation the Site Main Controller shall,  Activate the Emergency Control Centre & personnel  Relieve the Site Incident Controller of overall responsibility during off shift hours  Take stock of situation with SIC & direct operations to control the emergency.  Ensure that all the key persons are called on site. Delegate any extra duty to any person depending upon the situation and his judgment.  Verify the head count & arrange for search / rescue  Instruct for shutting & evacuation if required.  Seek assistance from external agencies & Mutual aid  Withdraw the staff in case of the human life is in peril.  Liaison with statutory authorities  Arrange to call the experts/ the supplier.  Give All Clear siren when everything becomes normal.  Works as liaison officer between outside fire brigade & police advice on specialized technical aspects of the materials involved and internal details of the factory.  Report the event to the nearest district police station, fire brigade, civil defense force, district emergency officer, factory Inspectorate and other voluntary body to assist to the task. M/s Shogun Organics Ltd. has established an Emergency Control Centre at the cabin of the Site Main Controller (Factory Manager). It has external telephone, telefax and telex facility & contact number of the Incident Controller Officer, Senior Personnel etc. 2) Site Incident Controller  Assume the responsibility of the Site Main Controller till the arrival of the site main controller.  Brief the Site Main Controller on arrival - during off shift hours.  Be over all in charge of the emergency situation and head of fire fighting team.  Arrive immediately to the site of emergency and issue instructions for speedy combat.  On arrival immediately assess the scale of emergency and decide if a major emergency exists or is likely.  Report head count to Site Main Controller.

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 Activate the security head to report the emergency to Site Main Controller.  Activate the Onsite action plan depending on the type of emergency.  Direct all operations and call the external help from emergency control center.  Search for the injured and / or casualties.  Direct the shutdown and evacuation of the plant. Identify the areas likely to be affected by the emergency.  Provide information to emergency services about the chemicals / incident 3) EHS Team.

In addition to his general duties of maintaining order of administration he shall discharge following duties:

 Execute all directions and instruction of site main controller regarding.  Calling mutual aid members.  Specialist from the supplying company.  Lead the fire fighting & rescue operations

For efficient and successful operation of the plan statutory agencies listed below should be actively involved for guidance and help: -

 Fire Brigade  Police Authorities  Collectorate / revenue officials  Directorate of Industrial Safety and Health  Maharashtra Pollution Control Board.  District Health Authorities  Non Government organization  Local News Media.  Local Leaders  Supervise the duties of Security Personnel.  Supervise rescue & medical operations  If injuries and casualties does occur then he shall obtain names and addresses of the injured and dead.

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 Arrange for the medical aid. Talk to the hospital and doctors. Report about the type of injury / burn injuries and or toxic effects.  Report to the hospital and make arrangement for likely more cases of injuries.  In consultation with the site main controller he shall identify the antidote or any special medical procedure and report the same to hospitals. 4) Production Manager & Team

(In affected Plant Area)

 Inform EHS Manager / Factory Manager / Plant / Dept Manager or his nominee / Site Main Controller on the telephone immediately.  Assume the role of Site Incident Controller till his arrival.  Direct employees / contractor's workers / visitors at the assembly point.  Take head count of employees.  Deploy trained Emergency Response Team & direct.  Hold personnel at the Assembly point till „All Clear‟ signal is obtained.  Act as per instructions from Site Incident Controller / Site Main Controller.  Open plant drain valves to FWRB  Provide information to external agency about the chemical involved to control emergency/ treating injured employees. (Non –affected Plant Area)  Ensure that all employees including contractor‟s workers / visitors assemble at the Assembly Point and take roll call of employees.  Take Head Count & report to SMC at ECC  Switch off all critical operations.  Be Alert for evacuation & evacuate on instructions from SMC  Keep ready - Emergency Response Team members  Provide necessary information and support to affected dept/plant to control emergency.  Hold personnel at Assembly Point till „All Clear” siren is raised

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5) Security Personnel

In addition to the normal duties of maintaining security at the place of work they shall discharge following duties:

 On hearing the fire alarm, proceed to the incident immediately.  Be in charge of Fire Fighting and rescue operations with the assistance of essential workers and key personnel till the arrival of Fire Brigade and Police. (These operations shall be under the direct supervision of Site Incident Controller)  Ask the ambulance to proceed to the scene of the incident in case of serious injury.  Remove obstruction from the road to help Fire brigade to proceed to the scene of fire.  Restrict entry of unauthorized and untrained persons from the scene of incident. Also don't allow unauthorized persons / vehicles to enter the premises. Control traffic movement for smooth & normal flow.  Initiate rescue operation if required.  Call for fire brigade & ambulance during off hours  Depending on seriousness arrange to inform police personnel if instructed by Factory Manager.

7.3.2 General Instructions and Response during the Onsite Emergency Situation

1. Major Fire/ Explosion

 Operate the nearest fire alarm or alert the personnel by raising an audible alarm or by shouting Fire!, Fire!!”  Inform the Manager Production / Shift Supervisor available who is in charge of the factory at that time about the  Place of Fire / Explosion  Extent of Fire fighting Action taken by him  The material involved  No. of persons affected.  Try to extinguish the fire with the help of fire extinguishers, if without risk. If he is unable to extinguish the fire, he should see that the fire does not spread to nearby area.

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2. Collapse of structure/ Serious Injury

 Inform the Manager Production / Supervisor etc.  Remove the injured person to a safe place. Take help of trained first-aiders.

3. Release of toxic and hazardous material

Inform the Manager Production / Supervisor or person available who is in-charge of the factory at that time about the

 Place of Gas leak  Extent of leakage  Action taken by him  The material involved  No. of persons affected. Table No 7.4: Emergency Do’s & Don’t’s EMERGENCY DO ‘S DON 'TS ANY ONE NOTICING AN EMERGENCY : DO NOT panic and avoid running all Actuate nearest fire alarm button and /or inform over the place prevent others from doing the supervisor. Get back to your normal so. workstation (if safe) or else report to the DO NOT enter the site unless instructed assembly point. if you are out side and emergency alarm is heard. CONTRACTOR PERSONNEL : DO NOT enter the site until it is cleared Stop work on hearing alarm and assemble at the for the normal work by Incident ASSEMBLY POINT and be ready to evacuate. Controller. SECURITY : DO NOT allow unauthorized visitors to Keep the gate manned. enter. Keep the road clear for movement of fire tenders. Control traffic at gates. VISITORS : DO NOT enter the site if emergency Leave the place and assemble at assembly point. alarm is heard. ALL OTHER EMPLOYEES ON SITE : DO NOT panic/run On hearing Emergency alarm DO NOT go to the scene of emergency Get back to work place (if safe) for head count unless specifically instructed by Incident and get instructions from supervisor. Be alert. Controller.

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7.3.2.1 Establishment of the Safety Committee

M/s Shogun Organics Ltd. would be having around 68 Nos. of employees after the expansion activity. Since the company deals with the dangerous operations as mentioned in the section 87 of the Factories Act 1948, it is mandatory for the company to establish an safety committee. The safety committee shall include a senior official, safety officer and representatives of workers & each department. The tenure of the safety committee would be for 2 years. The Roles and responsibility of the safety committee is listed below,

(a) Assisting and co-operating with the management in achieving the aims and objectives outlined in the 'Health and Safety Policy' of the occupier;

(b) Dealing with all matters concerning health, safety and environment and to arrive at practicable solutions to problems encountered;

(c) Creating safety awareness amongst all workers;

(d) Undertaking educational, training and promotional activities;

(e) Deliberating on reports of safety, environmental and occupational health surveys, emergency plans safety audits, risk assessment and implementation of the recommendations made in the reports;

(f) Carrying out health and safety surveys and identify causes of accidents;

(g) Looking into any complaint made on the likelihood of an imminent danger to the safety and health of the workers and suggest corrective measures; and

(h) Reviewing the implementation of the recommendations made by it.

The safety committee established for M/s Shogun Organics Ltd is depicted in fig. no.7.3.

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7.3.2.2 Establishment of Mutual Aid Response Group

M/s Shogun Organics Ltd. are grouped under Kurkumbh Environment Protection Co - operative Society Maryadit which help the industries to club their resources during emergency with the neighboring factory. The copy of Share Certificate is attached as Annexure – 7.4.

Figure No. 7.2 Establishment of Safety Committee

7.3.2.3 Outside Organization Involvement in assisting during the On-site emergency.

The Outside organization that would be involved during the On-site emergency would be fire, hospital and Police authority. This authority would be contacted when the resources provided within the factory will not fulfill the requirement.

7.3.2.4 Information on the preliminary hazard analysis.

A detailed Hazop Study for process operations & Risk Assessment have been prepared considering all possible and rare events for raw materials in the above section. Based on the study the maximum credible scenario has been identified for the particular scenario and recommendation to reduce the effect and its occurrence has been suggested /recommended.

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7.3.2.5 Details about Safety related features in Plant a) Location of the Dangerous Substances

The dangerous substances are stored in a demarcated area in the plant premises. The raw materials are stored based on their compatibility with other raw materials. The raw materials whose quantities are large are stored in tanks with appropriate safety measures. The plot layout is marked with the locations of such raw materials. b) Seat of Key Personal

Table No. 7.5 List of Important Personnel

Name Designation Mr. Amit R. Kalyanaraman Managing Director Mr. M. V. Hande. Director Mr. Yuvraj Gharge. Factory Manager Mr. V. Rajiv. Accounts and Finance Manager. Mr. Bajrang Suryavanshi. Maintenance & Safety Exe.

c) Emergency Control Room

EMERGENCY CONTROL ROOM as marked on site plan will be focal point in case of an emergency, from where the operations to handle the emergency are directed and co-ordinate by Site Main Controller. The following information and equipment is provided at the Emergency Control Centre (ECC):  Intercom, telephone  P and T telephone  Safe contained breathing apparatus  Fire suit/gas tight goggles/gloves/helmets  Hand tools, wind direction/velocities indicators  Public address megaphone, hand bell, telephone directories  (Internal, P and T) factory layout, site plan  Emergency lamps/torch lights/batteries

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 Plan indicating locations of hazard inventories, plant control room, sources of safety equipment, work road plan, assembly points, rescue location, vulnerable zones, and escape routes  Hazard chart  Emergency shut-down procedures  Nominal roll of employees  List of key personnel, list of essential employees, list of Emergency Co-ordinators  Duties of key personnel  Addresses with telephone numbers of key personnel, emergency coordinator, and essential employees.  Important addresses and telephone numbers including Government agencies, neighboring industries and sources of help, outside experts, chemical fact sheets, population details around the factory.

Description of Hazardous chemicals stored at plant site is tabulated in the below table.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Table No: 7.6: Detailed list of Hazardous Chemicals

Sr. Common Name of Molecular Physical Odor Flash Boiling Melting Stability No Raw Material Weight in State Point (°C) Point Point g/mol (°C) (°C) 1 Allethlone Alcohol N.A N.A N.A N.A N.A N.A N.A 2 Chry. Acid Chloride N.A N.A N.A N.A N.A N.A N.A 3 Sodium Hydroxide 40 g/mole Solid. Odorless NA 1388°C 323°C Stable. 4 Pyridine 214.22 Solid. Not available. Not Not 70°C The product is stable. g/mole (Powdered available. available. (158°F) - solid.) 72 C 5 HCL Not Liquid. Pungent. NA 83° C @ -46.2 Stable applicable Irritating 760 mm (Strong.) Hg 6 Toluene 92.141 Liquid. Sweet, pungent, CLOSED 110.6 -95 Stable g/mol Benzene-like. CUP: 4.4444°C 7 Potassium Carbonate 138.21 Solid. Odorless. Not Decompo 891°C Stable g/mole (Powdered applicable. ses. (1635.8° solid. F) Deliquescen t solid.) 8 Activated Clay N.A. Granules or Odourless NA NA >1000 Stable under normal beads Deg C. temperatures and pressures 9 2,3,5,6,Tetrafluoro 180.10 Liquid NA NA 198 - 202 NA Stable under Benzyl Alcohol g/mo °C - lit. recommended storage

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies conditions. 10 R-Cypermetric Acid NA Liquid Weak aromatic NA 78 - 80°C NA Stable under normal Chloride at 1.5 storage conditions. mm Hg and 116 - 117°C at 7.5 mm Hg 11 Activated Charcoal 12.01 Solid. (Solid Odorless. NA NA 3500°C The product is stable. g/mole powder.) (6332°F) 12 M- 198.22 Liquid No information > 112 °C / Not 13 °C / Stable Phenoxybenzaldehyd available > 233.6 °F Available 55.4 °F e 13 Becisthemic Acid N.A N.A N.A N.A N.A N.A N.A Chloride 14 Sodium Hypochlorite 74.44 Liquid. Characteristic. Not Decompo Not The product is stable. Chlorine-like applicable. sition available. (Slight.) temperat ure: 40°C (104°F) 15 Sodium Cyanide 49.01 Solid. Faint almond- N.A 1496°C 563°C The product is stable. g/mole (Granular like odor. (2724.8° (1045.4° solid. Flakes Odorless when F) F) solid.) perfectly dry. Emits odor of hydrogen cyanide when damp. 16 2-Chloro 5- 162.02 Divided - 230 (CC) Not 99- 108 Conditions contributing

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Chloromethyl solid Applicabl to instability Pyridine (CCMP) e Contact with alkaline material liberates heat. Presence of incompatible materials. Product is considered stable. Storage incompatibility Reacts with mild steel, galvanized steel / zinc producing hydrogen gas which may form an explosive mixture with air. Segregate from alkalis, oxidizing agents and chemicals readily decomposed by acids, i.e. Cyanides, sulfides, carbonates. Avoid strong bases. 17 Nitroiminoimidazolid N.A N.A N.A N.A N.A N.A N.A ene 18 Dimethyl Formamide 73.09 Liquid. Amine like. closed cup: 153°C -61°C (- The product is stable. g/mole (Slight.) 57.778°C (307.4°F) 77.8°F 19 2-Methyl-3-Biphenyl N.A N.A N.A N.A N.A N.A N.A Methanol 20 Cyhalothric Acid N.A N.A N.A N.A N.A N.A N.A Chloride 21 N-Hexane 86.18 Liquid Petroleum (-22 Deg (69 deg (-95 deg Stable under normal distillates cel) cel) cel) conditions.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 22 Sodium Bicarbonate 84.01g/mol Solid Odorless Not Not Not Stability: The product is e available. available. available. stable. Instability Temperature: Not available. Conditions of Instability: Incompatible materials, Moisture. Stable in dry air, but slowly decomposes in moist air 23 Thiopyrazole Alcohol N.A N.A N.A N.A N.A N.A N.A 24 Trichloro Acetic Acid 163.39 Solid. Characteristic. Not 195.5°C 57.5°C The product is stable g/mole (Crystals Pungent. applicable. (383.9°F) (135.5°F) solid. Deliquescen t crystals solid.) 25 Mono Chloro 112.56 Liquid. Almond-like. Closed 132°C -45.6°C The product is stable Benzene g/mole cup: (269.6°F) (-50.1°F) 29.44°C (85°F). 26 Hydrogen peroxide 34.014 Liquid Odorless NA 108°C -33 Stable g/mol 27 Boric Acid 61.83 Solid. Odorless. Not 300°C 169°C The product is stable. g/mole (Powdered applicable. (572°F) (336.2°F) solid.) 28 3 Methyl Benzoic 136.15 Solid. Not available Closed 260°C 109°C The product is stable Acid g/mole (Flakes cup: 150°c (500°F) (228.2°F) solid.) (302°F). 29 Di-ethylamine 73.14 Liquid. Ammoniacal. Closed 55.5°C -50°C (- The product is stable.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies g/mole (Liquid.) cup: Lower (131.9°F) 58°F) than -18°C (0°F). 30 Ortho Phosphoric 97.99 Liquid. Odorless. Not 158°C 21°C The product is stable. Acid g/mole (Syrupy applicable. (316.4°F) (69.8°F) liquid Viscous liquid.) 31 W-52 Alcohol N.A N.A N.A N.A N.A N.A N.A 32 Chrysanthamic Acid N.A N.A N.A N.A N.A N.A N.A 33 Thionyl chloride 118.98 Liquid. Not available Not 76°C -104.5°C The product is stable g/mole (Fuming applicable. (168.8°F) (- liquid.) 156.1°F) Decompo sition temperat ure: >140 deg. C 34 Transfluthrin 371.15 Liquid to N.A N.A 242 deg 35 deg Stable under g/mole semi solid cel cel. recommended storage and mass handling conditions 35 Ketrul D-80 N.A Clear and Hydrocarbon. 72-80 ° C N.A N.A The product is stable at transparent (ISO 2719) normal storage, handling liquid and use temperatures 36 Hydroseal N.A Liquid Characteristic Not N.A N.A Stable under White / applicable recommended conditions coloured of storage. pour able liquid

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 37 Perfume N.A N.A N.A N.A N.A N.A N.A 38 BHT N.A N.A N.A N.A N.A N.A N.A 39 Imidacloprid N.A Off-white Weak Not N.A 143.6 deg Stable but may powder characteristics applicable cel decompose if heated 40 Levulose ( Fructose) 180.16 Solid. Odorless. Not Not Decompo The product is stable. g/mole (Crystalline available available. sition solid.) temperat ure: 103°C (217.4°F) 41 Glycerine 92.09 Liquid. Mild CLOSED 290°C 19°C The product is stable. g/mole (Viscous CUP: (554°F) (66.2°F) (Syrupy) 160°C liquid.) (320°F). 42 Thickner Gum N.A N.A N.A N.A N.A N.A N.A 43 Geling Agent N.A N.A N.A N.A N.A N.A N.A 44 Dye ( Colour ) N.A N.A N.A N.A N.A N.A N.A 45 Non Ionic Emulsifier N.A N.A N.A N.A N.A N.A N.A 46 Polyvinyl copolymer N.A N.A N.A N.A N.A N.A N.A 47 Dimethyl Sulfoxide 78.13 Liquid. Sulfurous. CLOSED 189°C 18.45°C The product is stable. g/mole (Slight.) CUP: 89°C (372.2°F) (65.2°F) (192.2°F). 48 N-Methyl Pyrolidone 99.14 Liquid. Amine like. CLOSED 202°C (-24°C (- The product is stable. g/mole CUP: (395.6°F) 11.2°F)) 92.778°C (199°F). 49 Ethoxylated Phenols N.A N.A N.A N.A N.A N.A N.A 50 Propylene Glycol 76.1g/mole Liquid. Practically CLOSED 188°C (-59°C (- The product is stable. (Oily Odorless. CUP: 99°C (370.4°F) 74.2°F))

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies liquid.) 51 Trihydroxy Propane 92.09 Clear Liquid N.A. 160°C 290°C 20°C The product is stable. g/mole 52 Phenyl Methoxy N.A N.A N.A N.A N.A N.A N.A Methanol 53 Blend of Methyl N.A N.A N.A N.A N.A N.A N.A Isothio 54 Polydimethylsiloxane Not Liquid. Mild CLOSED Not Not The product is stable. available CUP: available available >204°C (399.2°F). 55 Fipronil 437.2 White or Mouldy odour Not: 200℃- N.A. off-white Available 201℃ Powder 56 Potassium Nitrate 101.1 Solid. Odorless. Not Decompo 334°C The product is stable. g/mole (Crystalline applicable sition (633.2°F) solid. temperat Granular ure: solid.) 400°C (752°F) 57 Denotium Benzoate 446.59 Solid. Not available. Not Decompo 168°C The product is stable. g/mole available ses. (334.4°F) 58 Cetyl Alcohol 242.43 Solid. Odorless. Faint OPEN 344°C 49.3°C The product is stable. g/mole odor CUP: (651.2°F) (120.7°F) 160°C (320°F). 59 Isopropyl Myristate 270.45 Liquid. Not available. Not Decompo 3°C The product is stable. g/mole available. ses. (37.4°F) (208°C

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies or 406.4°F) 60 Renofluthrin N.A N.A N.A N.A N.A N.A N.A 61 Diethyl phthalate 222.24 Liquid. Odorless. CLOSED 298°C (-40.5°C The product is stable g/mole (Oily CUP: (568.4°F) (- liquid.) 117°C 40.9°F)) 62 Premix powder N.A N.A N.A N.A N.A N.A N.A 63 LPG Gas at 15 oc Mercaptan added (- 104.4 >-40 oc Not Stable and 1 atm. as an odouriser (CC)) pertinent 64 Cypermethrin 416.3 Characteristic 60- Conditions to avoid: avoid odor; 80℃(pur high temperature and e flame; isomers) Products to avoid: alkaline pesticides; Thermal decomposition: 150～300℃;

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies

Table No: 7.7 Threshold limits Hazardous Raw Material

Sr. Common Name of Raw LEL UEL TLV Nh Nf Nr No Material 1 Allethlone Alcohol NA NA NA NA NA NA 2 Chry. Acid Chloride NA NA NA NA NA NA 3 Sodium Hydroxide NA NA 2 (mg/m3) 3 0 1 4 Pyridine NA NA N.A 2 1 0 5 HCl NA NA 2(mg/m3) 3 0 1 6 Toluene 1.10% 7.1% 200 ppm 2 3 0 7 Potassium Carbonate NA NA NA 2 0 0 8 Activated Clay NA NA NA NA NA NA 9 2,3,5,6,Tetrafluoro Benzyl NA NA NA NA NA NA Alcohol 10 R-Cypermetric Acid NA NA NA NA NA NA Chloride 11 Activated Charcoal NA NA TWA: 3.5 1 3 0 (mg/m3) from ACGIH (TLV) [United States] 12 m-Phenoxybenzaldehyde NA NA NA 3 1 0 13 Becisthemic Acid NA NA NA NA NA NA Chloride 14 Sodium Hypochlorite NA NA TWA: 1 ppm. 1 0 0 15 Sodium Cyanide NA NA NA 3 0 0 16 2-Chloro 5-Chloromethyl NA NA NA 3 1 NA Pyridine (CCMP) 17 NitroiminoImidazolidene NA NA NA NA NA NA 18 Dimethyl Formamide NA NA TWA: 10 (ppm) 1 2 0 from ACGIH 19 2-Methyl-3-Biphenyl NA NA NA NA NA NA Methanol 20 Cyhalothric Acid Chloride NA NA NA NA NA NA 21 n-Hexane NA NA ACGIH - 50 ppm 2 3 NA TWA 22 Sodium Bicarbonate NA NA NA 1 0 0 23 Thiopyrazole Alcohol NA NA NA NA NA NA 24 Trichloro Acetic Acid NA NA TWA: 1 (ppm) 3 0 0 from ACGIH (TLV) 25 Mono Chloro Benzene 13000 96000 TWA – 10 ppm 2 3 0 26 Hydrogen peroxide NA NA 1 2 0 1 27 Boric Acid NA NA NA 1 0 0

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 28 3 Methyl Benzoic Acid NA NA NA 2 3 0 29 Di-ethylamine NA NA TWA: (30 mg/m3) 3 3 0 30 Ortho Phosphoric Acid NA NA NA 3 0 0 31 W-52 Alcohol NA NA 32 Chrysanthamic Acid NA NA 33 Thionyl chloride NA NA CEIL: 1 from 4 0 2 ACGIH (TLV) [United States] 34 Transfluthrin NA NA NA NA NA NA 35 Ketrul D-80 NA NA NA NA NA NA 36 Hydroseal NA NA NA NA NA NA 37 Perfume NA NA NA NA NA NA 38 BHT NA NA NA NA NA NA 39 Imidacloprid NA NA NA NA NA NA 40 Levulose ( Fructose) NA NA NA 1 1 0 41 Glycerine NA NA Exposure Limits: 1 1 0 TWA: 10 (mg/m3) from ACGIH (TLV) 42 Thickner Gum NA NA NA NA NA NA 43 Geling Agent NA NA NA NA NA NA 44 Dye ( Colour ) NA NA NA NA NA NA 45 Non Ionic Emulsifier NA NA NA NA NA NA 46 Polyvinyl copolymer NA NA NA NA NA NA 47 Dimethyl Sulfoxide NA NA NA 2 2 0 48 N-Methyl Pyrolidone NA NA Exposure Limits: 2 1 0 TWA: 25 ppm 49 Ethoxylated Phenols NA NA NA NA NA NA 50 Propylene Glycol NA NA Exposure Limits: 0 1 0 TWA: 10 (mg/m3) 51 Trihydroxy Propane NA NA Exposure Limits: 1 1 0 TWA: 10 (mg/m3) from ACGIH (TLV) 52 Phenyl Methoxy Methanol NA NA NA NA NA NA 53 Blend of Methyl Isothio NA NA NA NA NA NA 54 PolydimethylSiloxane NA NA Not available 2 1 0 55 Fipronil NA NA NA NA NA NA 56 Potassium Nitrate NA NA Not available 2 0 0 57 Denotium Benzoate NA NA Not available 2 1 0 58 Cetyl Alcohol NA NA Not available 1 1 0 59 Isopropyl Myristate NA NA Not available 2 1 0 60 Renofluthrin NA NA NA NA NA NA

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 61 Diethyl phthalate NA NA Exposure Limits: 1 1 0 TWA: 5 (mg/m3) from ACGIH (TLV) 62 Premix powder NA NA NA NA NA NA 63 LPG NA NA NA 1 4 0 64 Cypermethrin NA NA NA NA NA NA

Table No 7.8: Toxicological Data of the Raw Materials

Sr. Raw Material LD50 LC50 Chronic Effects on No Humans 1 Allethlone Alcohol NA NA NA 2 Chry. Acid Chloride NA NA NA 3 Sodium Hydroxide NA NA Causes damage to the following organs: lungs. 4 Pyridine NA NA NA 5 HCL Acute oral Acute Carcinogenic effects: toxicity (LD50): toxicity of Classified 3 (Not classifiable 900 mg/kg the vapor for human.) By IARC [Rabbit]. (LC50): [Hydrochloric acid]. May 1108 ppm, cause damage to the 1 hours following organs: kidneys, [Mouse]. liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth. 6 Toluene ORAL (LD50): VAPOR Carcinogenic effects: A4 Acute: 636 (LC50): (Not classifiable for human mg/kg [Rat] Acute: or animal.) By ACGIH, 3 49000 (Not classifiable for human.) mg/m 4 By IARC. May cause hours [Rat] damage to the following organs: blood, kidneys, the nervous system, liver, brain, central nervous system (CNS). 7 Potassium Carbonate Acute oral NA Causes damage to the toxicity (LD50): following organs: mucous 1870 mg/kg membranes. May cause [Rat]. damage to the following organs: skin, eyes. 8 Activated Clay Oral, rat: NA NA LD50>31600 mg/kg; Skin, rabbit: LD50

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans >2000mg/kg 9 2,3,5,6,Tetrafluoro NA NA No component of this Benzyl Alcohol product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. 10 R- Cypermetric Acid NA NA NA Chloride 11 Activated Charcoal NA NA Causes damage to the following organs: mucous membranes. May cause damage to the following organs: lungs. 12 M- LD50 Oral - rat - LC50 No component of this Phenoxybenzaldehyde 1,222 mg/kg Inhalation - product present at levels rat - 4 h - greater than or equal to 0.1% 270 mg/m3 is identified as probable, possible or confirmed human carcinogen by IARC. 13 Becisthemic Acid NA NA NA Chloride

14 Sodium Hypochloride Acute oral NA Carcinogenic effects: toxicity (LD50): Classified 3 (Not classifiable 5800 mg/kg for human.) By IARC [Mouse]. [Sodium hypochlorite] Mutagenic effects: Mutagenic for bacteria and / or yeast. [Sodium hypochlorite]. Mutagenic for mammalian somatic cells. [Sodium hydroxide]. Contains material which may cause damage to the following organs: lungs, mucous membranes, skin, eyes. 15 Sodium Cyanide Acute oral NA May cause damage to the toxicity (LD50): following organs: skin, eyes, 6.44 mg/kg central nervous system [Rat]. (CNS). 16 2-Chloro 5- NA NA NA Chloromethyl Pyridine (CCMP)

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans 17 Nitroiminoimidazolide NA NA NA ne 18 Dimethyl Formamide Acute oral Acute Carcinogenic effects: 3 (Not Toxicity (LD50): toxicity of classifiable for human) by 2800 mg/kg the vapor IARC. Mutagenic effects: [Rat]. Acute (LC50): Mutagenic for mammalian 9400 somatic cells. Mutagenic for dermal toxicity 1 hours bacteria and/or yeast. (LD50): 4720 [Mouse]. Teratogenic effects: mg/kg [Rabbit] Classified possible for human. Developmental toxicity: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [Possible]. Causes damage to the following organs: kidneys, liver, central nervous system (CNS). May cause damage to the following organs: blood, the nervous system. 19 2-Methyl-3-Biphenyl NA NA NA Methanol 20 Cyhalothric Acid NA NA NA Chloride 21 N-Hexane Oral LD50 Rat Inhalation NA 25 g/Kg LC 50 48 ppm 4 Hr 22 Sodium Bicarbonate Acute oral Not Not available toxicity (LD50): available 3360 mg/kg [Mouse]. 23 Thiopyrazole Alcohol NA NA NA 24 Trichloro Acetic Acid Not available Not Carcinogenic effects: available Classified A3 (Proven for animal.) By ACGIH. 3 (Not classifiable for human.) By IARC. Mutagenic effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: lungs. 25 Mono Chloro Benzene NA NA The substance is toxic to

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans kidneys, lungs, the nervous system, liver, mucous membranes. 26 Hydrogen peroxide Acute oral Vapor Carcinogenic effects: toxicity (LD50): (LC50): Classified A3 (Proven for 6667 mg/kg Acute: animal.) By ACGIH [Hydrogen Peroxide]. (Mouse) 2000 mg/m Classified 3 (Not classifiable 4 hours for human.) By IARC [Rat]. [Hydrogen Peroxide]. Mutagenic effects: Mutagenic for mammalian somatic cells. [Hydrogen Peroxide]. Mutagenic for bacteria and/or yeast. [Hydrogen Peroxide]. Contains material which may cause damage to the following organs: blood, upper respiratory tract, skin, eyes, central nervous system (CNS). 27 Boric Acid Acute oral NA Mutagenic effects: toxicity (LD50): Mutagenic for bacteria 2660 mg/kg and/or yeast. Developmental [Rat]. toxicity: Classified Reproductive System/toxin/female, Reproductive system/toxin/ male [possible]. May cause damage to the following organs: kidneys, Cardiovascular system, central nervous system (CNS). 28 3 Methyl Benzoic Acute oral NA NA Acid toxicity (LD50): 1630 mg/kg [Mouse]. 29 Di-ethylamine ORAL (LD50): VAPOR Carcinogenic Effects: Acute: 540 (LC50): Classified A5 (Not suspected mg/kg [Rat.]. Acute: for human.) By ACGIH. 4000 ppm 4 hour(s)

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans [Rat.].

30 Ortho Phosphoric Acid ORAL (LD50): DUST May cause damage to the Acute: 1530 (LC50): following organs: blood, mg/kg [Rat]. Acute: liver, skin, eyes, bone >850 marrow mg/m 1 hours [Rat].

31 W-52 Alcohol NA NA NA 32 Chrysanthamic Acid NA NA NA 33 Thionyl chloride NA Acute May cause damage to the toxicity following organs: upper Of the respiratory tract, skin, eyes. vapor (LC50): 500 1 hours [Rat]. 34 Transfluthrin Oral LD50 Inhalation NA >5000 mg/kg bw LC50 > rat 513 mg/m3 rat 35 Ketrul D-80 LD50 (Rabbit) > Acute Not applicable 2000 mg/kg toxicity. (CONCAWE) LC50 96 hours fish > 1000 mg/l 36 Hydroseal NA NA NA 37 Perfume NA NA NA 38 BHT NA NA NA 39 Imidacloprid Oral LD50 Rat Inhalation Not Applicable 425/427 mg/kg LC50 Rat >5.33 mg/l 40 Levulose ( Fructose) Acute oral Not Not available. toxicity (LD50): available. 4000 mg/kg [Rat]. 41 Glycerine Acute: 12600 MIST(LC5 May cause damage to the mg/kg [Rat]. 0): Acute: following organs: kidneys. 4090 mg/kg >570 [Mouse]. mg/m 1 hours

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans [Rat]. 42 Thickner Gum NA NA NA 43 Geling Agent NA NA NA 44 Dye ( Colour ) NA NA NA 45 Non Ionic Emulsifire NA NA NA 46 Polyvinyl copolymer NA NA NA 47 Dimethyl Sulfoxide Acute oral NA Mutagenic effects: toxicity (LD50): Mutagenic for mammalian 7920 mg/kg somatic cells. Mutagenic for [Mouse]. Acute bacteria and/or yeast. May dermal toxicity cause damage to (LD50): 40000 The following organs: blood, mg/kg [Rat]. kidneys, liver, mucous membranes, skin, eyes. 48 N-Methyl Pyrolidone Acute oral NA Mutagenic effects: toxicity (LD50): Mutagenic for bacteria 3914 mg/kg and/or yeast. May cause [Rat]. Acute damage to the following dermal toxicity organs: blood, kidneys, (LD50): 8000 Lymphatic system, Urinary mg/kg [Rabbit]. system, bone marrow. 49 Ethoxylated Phenols NA NA NA 50 Propylene Glycol Acute oral Ecotoxicity May cause damage to the toxicity (LD50): in water following organs: central 18500 mg/kg (LC50): nervous system (CNS). [Rabbit]. Acute >5000 mg/l dermal toxicity 24 hours (LD50): 20800 [Goldfish]. mg/kg [Rabbit]. >10000 mg/l 48 hours [guppy]. >10000 mg/l 48 hours [water flea]. 51 Trihydroxy Propane Acute: 12600 MIST(LC5 May cause damage to the mg/kg [Rat]. 0): Acute: following organs: kidneys. 4090 mg/kg >570 [Mouse]. mg/m 1 hours [Rat]. 52 Phenyl Methoxy NA NA NA

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans Methanol 53 Blend of Methyl NA NA NA Isothio 54 Polydimethylsiloxane Acute oral NA Not available. toxicity (LD50): >17000 mg/kg [Rat (RTECS #VX6390000)]. Acute dermal toxicity (LD50): >2000 mg/kg [Rabbit (RTECS #VX6390000)]. 55 Fipronil Acute oral LD50 Fish NA (rat) : 97mg/kg toxicity: LC50: 0.34 mg/L Acute dermal Japanese LD50(rat) : carp >2000mg/kg Daphnia toxicity: LC50: 19 μg/L daphnia

56 Potassium Nitrate Acute oral NA May cause damage to the toxicity (LD50): following organs: blood, 1901 mg/kg kidneys, central nervous system (CNS). [Rabbit].

57 Denotium Benzoate Acute oral NA The substance is toxic to toxicity (LD50): lungs, mucous membranes. 584 mg/kg [Rat].

58 Cetyl Alcohol Acute oral NA Not available. toxicity (LD50): 3200 mg/kg [Mouse]. Acute dermal toxicity (LD50): >2600 mg/kg [Rabbit].

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Sr. Raw Material LD50 LC50 Chronic Effects on No Humans 59 Isopropyl Myristate Not available Not Not available. available

60 Renofluthrin NA NA NA 61 Diethyl phthalate Acute oral NA Carcinogenic Effects: A4 toxicity (LD50): (Not classifiable for human 1000 mg/kg or animal.) By ACGIH. Mutagenic effects: [Rabbit]. Mutagenic for Bacteria and/or yeast. May cause damage to the following organs: liver, central nervous system (CNS). 62 Premix powder NA NA Ductal premic is not listed as a carcinogen by IARC or NTP; however, Ductal Premix contains trace amount of crystalline silica and hexavalent chromium which are classified by IARC and NTP as known human carcinogens 63 LPG Not listed NA NA 64 Cypermethrin Rat LD50 Oral : Cyprinus NA > 300-2000 caprio, 96 mg/kg bw Hrs : LC50 0.53 µg/l Rat LD50 (Cypermet Dermal : >2000 hrin mg/kg bw Technical)

Table No 7.9: Likely Dangers to the Plant

Sr. Accident Causes Consequence No. Scenario Zone 1. Spill Hose failure during road tanker unloading to Local storage tank at tank farm. Spill of – (Hydrochloric Acid, Thionyl Chloride, Trichloro Acetic acid, Sodium Cyanide, n- phenoxy benzaldehyde) etc.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 2. Spill Pipe line /pump gland leakage, Gasket failure Local Spill of - (Hydrochloric Acid, Thionyl Chloride, Trichloro Acetic acid, Sodium Cyanide, n- phenoxy benzaldehyde) 3. Pressure Pressure development , Local development Uncontrolled reaction exothermic 4. Fire Any spill of flammable chemical, Local e.g. solvent spill finding source catching fire on finding of ignition source. 5. Electric fire At transformer area Local 6. Release of failure of the Storage tank Lead to an off- Toxic / site flammable consequences Vapors 7. Fall of structure Earthquake , poor maintenance Local

7.3.3 Details of Safety Systems in the Plant Premises

The below section will explain about the safety features & measures adopted by M/s Shogun Organics Ltd. for dealing with the onsite emergency situation.

A) Alarm / Siren

There are 9 no of hooters located in the plant premises. Every Saturday at 1130 hours by giving an “All Clear” siren will be sounded for testing purpose. Emergency Alarm annountiator panel is located at gate office building as marked on the site plan.

On hearing alarm the incident controller will activate the action on Disaster control plan by giving proper instructions or predetermined signals. the alarm code used in the company is explained below,

Alarm Code

Table No:7.10 Alarm Code

Sr. No Situation Type of Siren/Alarm 1. Emergency at Site One Minute waxing and wailing siren 2. All Clear One Minute continuous siren 3. Evacuation Three minutes waxing and wailing siren

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B) Assembly Points

Numbers of assemblies depending upon the plant location are identified wherein employees who are not directly connected with the disaster management would be assembled for safety and rescue. Emergency breathing apparatus, minimum facilities like water etc. would be organized. In view of the size of plant, different locations are earmarked as assembly points. Two assembly points are identified by the company i.e. one near the main gate of the company and other one is located near the guest house of the company. Depending upon the location of hazard, the assembly points are to be used.

C) Mock Drills The company organizes periodical mock drill / rehearsal every 6 months as per suggested format by creating an emergency situation so as to verify preparedness and awareness as well as shortcomings on the part of the person to overcome the same. Sufficient time is provided prior to mock drill to the emergency services and public for proper response to exercise and provide training also. Record the deficiencies of the system during the trial and take appropriate actions to improve the efficiency of the plan in terms of preparedness and response.

D) Training

By imparting an effective training from time to time, the awareness is being kept alive all the time to ensure safety awareness, preparedness for emergency situations, good housekeeping, discipline, etc. Display of safety slogans, operative instructions and motivation for safety should is made the part of the company‟s normal activities. All the persons earmarked for the emergency services are trained to respond to the emergency. The company conducts internal & external training for Environment Health & safety. The training is conducted at a documented frequency. The external training is conducted six monthly and internal training is conducted every month.

Training is imparted to the employees by raising siren in specific pattern. Employees are given training of escape routes, taking shelter, protecting from toxic effects. Employees are provided with information related to fire hazards and first aid measures.

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Environmental Impact Assessment Report For Expansion of M/s Shogun Organics Ltd. Located At Kurkumbh MIDC, Taluka Daund, District Pune, Maharashtra.

SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies E) Emergency Power Supply Plant facilities would be connected to Generator and is placed in an auto mode. Thus, water pumps, plant‟s lighting and emergency control centre, administrative building and other auxiliary services are connected to emergency power supply. In all the blocks, flameproof type emergency lamps are provided.

F) Wind Sock Wind sock is provided in the company. The workers are trained in the mock drill regarding the usage of the wind sock for identifying the directions for taking shelter or identifying the area of high toxicity in case of emergency.

G) Communication facilities available during Onsite emergency

Table No: 7.11 Communication facilities available during Onsite emergency Name Designation Mr. Amit R. Kalyanaraman Managing Director Mr. M. V. Hande. Director Mr. Yuvraj Gharge. Factory Manager Mr. V. Rajiv. Accounts and Finance Manager. Mr. Bajrang Suryavanshi. Maintenance & Safety Exe.

H) Fire Fighting Facilities Firefighting equipment suitable for emergency are maintained well in each section in the plant. This would be developed according to the statutory requirements. However, fire hydrant line covering major areas has been laid. Fire alarms have been located in the bulk storage areas. The below details highlights the fire fighting facilities at site. Table No: 7.12 Fire Fighting Tank Details

Fire Fighting Tank Details Capacity of Fire Fighting tanks 2,00,000 Type of tank Overhead/ Below head Below Head. Material of Construction RCC Pump Capacity of fire fighting tank 171 m3/hr No of assembly points 2 No of exit points for emergency evacuation 6 Fire Hydrant system Available No of Existing fire hydrant points in the 9 premises

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 7.3.4 List of Existing fire extinguishers & fire buckets provided Total no. of fire extinguishers – 45 nos. Type of fire extinguishers - AB, BC, ABC, CO2 (Gas)

Table No: 7.13. List of Existing fire extinguishers & fire buckets provided Sr. Type of fire No extinguisher Location of Fire Extinguishers MV-8 F.Floor , R-7 G. Floor , R-5 G Floor , R-3 G. Floor , 3 AB (Mechanical 1 nos. in Solvent shade , Boiler utility , MV-23 , First floor R-16 , Foam) Ground floor R-16 ,2 Nos in L.V. shed, MV-19 , MV-22. BC ( Dry Power house = 1 , R- 8 Ground floor = 1 , R-8 First floor=1 , 2 Chemical Powder) FG shade=1, Panel Room=1 Plant No.1 entrance , R-2 First floor , R-5 first floor , R- 7 first floor , R- 9 first floor, R-9 Ground floor , Pump room , R-1 ABC ( Dry 3 Ground floor , East side of plant No. 1 , Utility , CQC Lab -2 Chemical Powder) Nos. R&D = 3 NOS , LV = 4 Nos. Transformer yard = 1 No. Plant No. 3 West side = 1 No. Plant No.3 Near Electric Panel.

4 CO2 gas 1 Power House. 2 R- 9 GF , 3 Utility 7.4.5 Location of Existing Fire Hydrants Table No :7.14 Location of Existing Fire Hydrants

Sr No Location 1. Near Admin & Q.C. Dept. 2. Near Fire Hydrant Pump House 3. Near Power House 4. Near Raw Material Shed (Plant -1) 5. North side LV Plant ( Plant-2)

6. East side LV Plant ( Plant-2) 7. Near Utility 8. West side of Plant -3 9. Near ETP

7.4.6 Type and no. of protective and rescue equipment on site maintenance frequency Table No.7.15. Type of protective & rescue equipment

Sr No Type No Location 1 Self Contained Breathing Apparatus Set 01 Plant Office 2 Chemical Cartridge Nose mask 10 Individually provided.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies Chemical Cartridge Nose mask, Dust Mask, Safety Helmet, Safety Goggle, Full Face- Face Shield, Safety Shoes, Rubber Hand Gloves, Names of PPE's Used Surgical Hand Gloves, Cotton Mix Uniform, Fire Fighting Apron, PVC Hand Gloves. Frequency of Maintenance of Once in every Quarter. PPE's and Fire- fighting systems Preventive Maintenance (To Period Avoid Emergency) Inspection of the Plants Reactors Monthly, Half Yearly Centrifuges Monthly, Half Yearly Boiler, Chiller Monthly, Half Yearly Compressor Air Compressors Monthly, Half Yearly D.G. Sets Bimonthly

7.3.7 Location of smoke detectors Table No.7.16. Location of smoke detectors

Sr. No Location of Smoke detectors 1 Office - 07 nos. 2 Conference Hall - 1 no. 3 Quality Control Lab - 2 nos. 4 R & D Lab - 3 nos 5 Liquidator Plant - 3 nos 6 Reception Hall - 1 no. 7 Plant-1 Office - 1 no. 8 Plant-1 Worker Changing Room - 1 no. 9 Plant-1 Pump Room - 1 no. Plant-1 Panel Room - 1 no.

7.3.8 Location of sprinklers Table No.7.17. Location of sprinklers

Sr. No Location of Sprinklers 1 Plant No.1 , QC , R&D , Administration Building , LV shade ,

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 7.3.9 Fire Water Tank Justification

The quantity of firefighting tank is 200 m3.

The pump capacity in the plant is 171m3/hr, therefore according to the discharge capacity of the pump installed. The back-up time by which the tank will be empty is calculated below,

Time (min) = [Total water in fire fighting tank (m3)]/discharge capacity (m3/hr)

= 200/171

= 1.16 hours

= 70.17 mins.

The existing along with the proposed fire safety measures are depicted in the plot layout.

7.3.10 Medical Facilities The total number of employees in M/s Shogun Organics Ltd. after expansion would be around 68 Nos. According to the Factories Act 1948 & Maharashtra Factories Rules, 1963 an Occupational Health Center of 15 sq.m should be provided in which a part time factory medical officer shall visit the factory at least twice in a week. Also one qualified person on First Aid measures will be on duty. First aid box will be provided in every department of the company. At present there are two first aid box located as per the above table with 5 people trained in using it. Out of which one person is always on site. Necessary specific medicines for emergency treatment of burns patients and for those affected by toxicity would be maintained. Breathing apparatus and other emergency medical equipment would be provided and maintained in the OHC. Private medical practitioners & government hospital would be approached in case of emergency & short supply in the plant. Names of medical personnel and medical facilities in the surrounding area would be prepared and updated which can be identified in the security office and emergency control center. The help of nearby industrial managements would be taken under mutual aid response group agreement if required.

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies 7.3.10.1 Location of Existing First Aid Kit in the Plant Premises

Table No.7.18 First Aid Kit Location No. of Locations Person first aid where the first responsible Sr kits aid kit is and No available available Components of first aid box designation 1 5 Plant No. 1 , Adhesive plaster , starlised dressing , Mr. Bajrang Plant No. 2 , Savlon, Soframycin , Eye drop , Rose Suryawanshi Plant No. 3 , water , Starlised Eye pads , Crosin Safety Main Gate , Tablets , Burn heal cream , Safety Officer QC Lab pins , scissor , sterilised cotton wool .

Interpretation Keeping in view the nature of the emergency, two levels of co-ordination are proposed. In the case of an On Site Emergency, resources within the organization would be mobilized as explained in the above section and in the event of an extreme emergency, local authorities‟ help would be sought. In the event of an emergency developing into an offsite emergency, local authority and District Emergency Authority (normally the Collector) would be apprised and under his supervision, the Off Site Disaster Management Plan would be exercised. The detailed risk analysis has indicated that the toxic effects would be felt outside the factory. Hence it is suggested that in case of such an emergency event people are advised to stay indoors, complete evacuation is not recommended. For this purpose, the offsite emergency plan has been highlighted in the below section, for the facilities that are available locally, i.e. medical, transport, personnel, rescue accommodation, voluntary organizations etc. would be mustered. Necessary rehearsals and training in the form of mock drills should be organized in consultation with the district emergency authority.

7.4 Off-Site Emergency Preparedness Plan The off-site plan will be prepared with the help of the local district authorities. The proposed plan will be based on the following guidelines.

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7.4.1 Introduction Off-site emergency plan follows the on-site emergency plan. When the consequences of an emergency situation go beyond the plant boundaries, it becomes an off-site emergency. Off- site emergency is essentially the responsibility of the public administration. However, the factory management will provide the public administration with the technical information relating to the nature, quantum and probable consequences on the neighboring population. The off-site plan in detail will be based on those events, which are most likely to occur, but other less likely events, which have severe consequence, will also be considered. Incidents, which have very severe consequences yet have a small probability of occurrence, should also be considered during the preparation of the plan. However, the key feature of a good off-site emergency plan is flexibility in its application to emergencies other than those specifically included in the formation of the plan. The roles of the various parties who will be involved in the implementation of an off-site plan are described below. Depending on local arrangements, the responsibility for the off-site plan should either rest with the works management or, with the local authority. Either way, the plan should identify an emergency coordinating officer, who would take the overall command of the off-site activities. As with the on-site plan, an emergency control centre should be set up with whom the emergency coordinating officer & emergency planning officer can operate. An early decision will be required in many cases on the advice to be given to people living "within range" of the accident; in particular, whether they should be evacuated or told to go indoor. In the latter case, the decision can regularly be reviewed in the event of an escalation of the incident. Consideration of evacuation may include the following factors:  In the case of a major fire but without explosion risk (e.g. an oil storage tank), only houses close to the fire are likely to need evacuation, although a severe smoke hazard may require this to be reviewed periodically  If a fire is escalating and in turn threatening a store of hazardous material, it might be necessary to evacuate people nearby, but only if there is time; if insufficient time exists, people should be advised to stay indoors and shield themselves from the fire For release or potential release of toxic materials, limited evacuation may be

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SEEPL/EIA/F/IND/SOL/001/2016-17/00 Chapter 7: Additional Studies appropriate downwind if there is time. The decision would depend partly on the type of housing "at risk". Conventional housing of solid construction with windows closed offers substantial protection from the effects of a toxic cloud, while shanty house, which can exist close to factories, offers little or no protection.

Site Controller

Emergency Co-ordinating Emergency Planning Chief Officer Officer Inspector Appointed by District Authority Appointed by Local Authority Appointed by State Gov.Authority

General Fire Heath Police State Pollution Public Authority Authority Authority Control Board

Figure No7.3: OffsiteEmergency Emergency Plan Plan

7.4.2 Role of the Chief Inspector Chief Inspectors are likely to want to satisfy themselves that the organization responsible for producing the off-site plan has made adequate arrangements for handling emergencies of all types including major emergencies. Chief Inspector may verify the documented procedures and evidence of exercise undertaken to test the onsite & offsite plan. The copy of the information furnished to the workers, local authority, general public & District Emergency Authority is submitted to the Chief Inspector for review. If the Chief Inspector is not satisfied with the content, he may direct the occupier to supply further information to the workers, authority, general public & District Emergency Authority as deemed necessary.

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7.4.3 Role of the Emergency Coordinating Officer The various emergency services will be coordinated by an emergency coordinating officer (ECO), who is designated by the District Collector. The ECO will liaise closely with the Site Controller. Again, depending on local arrangements, for very severe incidents with major or prolonged off-site consequences, the external control should be passed on to a Emergency Planning Officer of the local authority administrator.

7.4.4 Role of the Local Authority The company will enter into an agreement with the Emergency Planning Officer (EPO) of the area, within whose jurisdiction the factory is situated for the Emergency officer to take appropriate steps to inform the general public outside the factory who likely to be affected by an accident. The information in the prescribed format would be shared with the EPO by the site controller. The duty to prepare the off-site plan lies with the local authorities. The emergency planning officer (EPO) appointed should carry out his duty in preparing for a whole range of different emergencies within the local authority area. The EPO should liase with the site controller for ensuring that the plan is continually updated. It is the responsibility of the EPO to ensure that all those organizations, which will be involved off site in, handling the emergency, know of their role and are able to accept it by having for example, sufficient staff and appropriate equipment to cover their particular responsibilities. Rehearsals for off-site plans are organized by the EPO.

7.4.5 Role of Fire Authorities The control of a fire should normally be the responsibility of the senior fire brigade officer who would take over the handling of the fire from the site incident controller on arrival at the site. The senior fire brigade officer should also have a similar responsibility for other events, such as explosions and toxic release. Fire authorities in the region should be apprised about the location of all stores of flammable materials, water and foam supply points, and fire- fighting equipment. They should be involved in on-site emergency rehearsals both as participants and, on occasion, as observers of exercises involving on-site personnel.

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7.4.6 Role of Health Authorities Health authorities, including doctors, surgeons, hospitals, ambulances, and similar other persons/institutions should have a vital part to play following a major accident, and they should form an integral part of the emergency plan. For major fires, injuries should be the result of the effects of thermal radiation to a varying degree, and the knowledge and experience to handle this in all but extreme cases may be generally available in most hospitals. For major toxic releases, the effects vary according to the chemical in question, and the health authorities should be apprised about the likely toxic releases from the plant, which will enable them to deal with the aftermath of a toxic release with treatment appropriate to such casualties. Major off-site incidents are likely to require medical equipment and facilities in additional to those available locally, and a medical "mutual aid" scheme should exist to enable the assistance of neighboring authorities to be obtained in the event of an emergency.

7.4.7 Role of Police Authority Formal duties of the police during an emergency include protecting life and property and controlling traffic movements. Their functions should include controlling bystanders, evacuating the public, identifying the dead and dealing with casualties, and informing relatives of dead or injured.

7.4.8 Role of Pollution Control Board On receipt of information officer of the pollution control board shall proceed to the affected site. Conduct investigation including collection of data. Ensure that the spills have been contained with no further damage possible to humans and environment. Further to declare the area fit for re-entry after the decontamination is completed. In case of an environmental disaster, the pollution control board shall, based on the contaminant released in to the environment, carry out with the help of the industry and other agencies, such investigations as may be necessary to establish the degree of contamination. Arrange for suitable decontamination using resources available in the area as well as with the board.

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7.4.9 External agencies contact details involved during emergency Table No. 7.19 External agencies contact details involved during emergency Sr.No Name of Person /Authority Telephone Nos.

1 M/s Shogun Organics Ltd. 9920183331 Police Station 2 Police Station, Kurkumbh 02117 - 235308 Police Station, Daund. 02117 - 262333

Fire Station 3 Reliance Industries 02117 - 235112 Alkyl Amines Chemicals Ltd. 02117 - 235175 Fire Station M.I.D.C. 02117 - 235999

Hospital 10 Pyramid Hospital 02117 - 262355 11 Dr. Bhattad Hospital 02117 - 262027 12 Dr.Lonkar Hospital 02117 - 262029 MIDC 11 Baramati M.I.D.C 02112 - 222395 12 Jejuri M.I.D.C 02115 - 253162 Ranjangaon M.I.D.C 7385600445

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