U.S. Disposal of Chemical Weapons in the Ocean: Background and Issues for Congress
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The History of the Chemical Weapons Movement
Chemical Weapons Movement History Compilation William R. Brankowitz 27 April 1987 . Office of the Program Manager for Chemical Munitions (Demilitarization and Binary) (Provisional) Aberdeen Proving Ground, Maryland 21010-5401 I Chemical Weapons Movement History CcX@latiOn Table of Contents Page Executive Surnnaq 1 How To Use The Cmpilation 2 Introduction 6 Location Key 15 Incident Summarization Sheets 18 Compilation of Moves Pages w Year 1946 11 pages 1947 1 page 1948 2 pages 1949 4 pages 1950 3 pages 1951 2 pages 1952 2 pages 1953 3 pages 1954 3 pages 1955 1 w-e 1956 2 pages 1957 2 pages 1958 3 pages 1959 1 page 1960 1 Page 1961 1 page 1962 2 pages 1963 3 pages 1964 4 pages . 1965 5 pages 1966 4 pages 1967 6 pages 1968 a pages 1969 1 Page 1970-77 2 pages SE'EONI 3 pages SmON II 2 pages 1981-86 3 pages Reccrmendations and Conclusioris 25 f-4 i 4' References Executive Summary The production of a compilation of movement operations provides a base of data which can be used or interpreted in many ways. Some are favorable to the Army, and some are not. However, the Army wishes to show that (1) it has moved large quantities of chemical weapons over many years with relatively few problems and that (2) the Army has learned lessons from the problems which is has encountered. The Army also shows in this study that although there have been some problems associated with the movement of chemical weapons, there has never been a chemical agent fatality associated with such a move. -
Critical Evaluation of Proven Chemical Weapon Destruction Technologies
Pure Appl. Chem., Vol. 74, No. 2, pp. 187–316, 2002. © 2002 IUPAC INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY ORGANIC AND BIOMOLECULAR CHEMISTRY DIVISION IUPAC COMMITTEE ON CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES* WORKING PARTY ON EVALUATION OF CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES** CRITICAL EVALUATION OF PROVEN CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES (IUPAC Technical Report) Prepared for publication by GRAHAM S. PEARSON1,‡ AND RICHARD S. MAGEE2 1Department of Peace Studies, University of Bradford, Bradford, West Yorkshire BD7 1DP, UK 2Carmagen Engineering, Inc., 4 West Main Street, Rockaway, NJ 07866, USA *Membership of the IUPAC Committee is: Chairman: Joseph F. Burnett; Members: Wataru Ando (Japan), Irina P. Beletskaya (Russia), Hongmei Deng (China), H. Dupont Durst (USA), Daniel Froment (France), Ralph Leslie (Australia), Ronald G. Manley (UK), Blaine C. McKusick (USA), Marian M. Mikolajczyk (Poland), Giorgio Modena (Italy), Walter Mulbry (USA), Graham S. Pearson (UK), Kurt Schaffner (Germany). **Membership of the Working Group was as follows: Chairman: Graham S. Pearson (UK); Members: Richard S. Magee (USA), Herbert de Bisschop (Belgium). The Working Group wishes to acknowledge the contributions made by the following, although the conclusions and contents of the Technical Report remain the responsibility of the Working Group: Joseph F. Bunnett (USA), Charles Baronian (USA), Ron G. Manley (OPCW), Georgio Modena (Italy), G. P. Moss (UK), George W. Parshall (USA), Julian Perry Robinson (UK), and Volker Starrock (Germany). ‡Corresponding author Republication or reproduction of this report or its storage and/or dissemination by electronic means is permitted without the need for formal IUPAC permission on condition that an acknowledgment, with full reference to the source, along with use of the copyright symbol ©, the name IUPAC, and the year of publication, are prominently visible. -
Nerve Agent - Lntellipedia Page 1 Of9 Doc ID : 6637155 (U) Nerve Agent
This document is made available through the declassification efforts and research of John Greenewald, Jr., creator of: The Black Vault The Black Vault is the largest online Freedom of Information Act (FOIA) document clearinghouse in the world. The research efforts here are responsible for the declassification of MILLIONS of pages released by the U.S. Government & Military. Discover the Truth at: http://www.theblackvault.com Nerve Agent - lntellipedia Page 1 of9 Doc ID : 6637155 (U) Nerve Agent UNCLASSIFIED From lntellipedia Nerve Agents (also known as nerve gases, though these chemicals are liquid at room temperature) are a class of phosphorus-containing organic chemicals (organophosphates) that disrupt the mechanism by which nerves transfer messages to organs. The disruption is caused by blocking acetylcholinesterase, an enzyme that normally relaxes the activity of acetylcholine, a neurotransmitter. ...--------- --- -·---- - --- -·-- --- --- Contents • 1 Overview • 2 Biological Effects • 2.1 Mechanism of Action • 2.2 Antidotes • 3 Classes • 3.1 G-Series • 3.2 V-Series • 3.3 Novichok Agents • 3.4 Insecticides • 4 History • 4.1 The Discovery ofNerve Agents • 4.2 The Nazi Mass Production ofTabun • 4.3 Nerve Agents in Nazi Germany • 4.4 The Secret Gets Out • 4.5 Since World War II • 4.6 Ocean Disposal of Chemical Weapons • 5 Popular Culture • 6 References and External Links --------------- ----·-- - Overview As chemical weapons, they are classified as weapons of mass destruction by the United Nations according to UN Resolution 687, and their production and stockpiling was outlawed by the Chemical Weapons Convention of 1993; the Chemical Weapons Convention officially took effect on April 291997. Poisoning by a nerve agent leads to contraction of pupils, profuse salivation, convulsions, involuntary urination and defecation, and eventual death by asphyxiation as control is lost over respiratory muscles. -
Chemical Munitions Igloos for the Container Storage of Wastes Generated from the Maintenance of the Chemical Munitions Stockpile Attachment D.2
Tooele Army Depot - South Hazardous Wae Storage Permit Permit Attachment 12 - Container Management Modification Date: March 3. 1994 Chemical Munitions Igloos for the Container Storage of Wastes Generated from the Maintenance of the Chemical Munitions Stockpile Attachment D.2. Containers with Free Liquids The stockpile of chemical munitions stored at TEAD(S) (which included the M-55 rockets before they were declarbed obsolete, and became a hazardous waste) requires continual maintenance. These maintenance activities generate wastes, examples of which are: The valves and plugs used on ton containers used to store bulk chemical agent are changed out on a periodic basis, the valves and plugs that are removed are decontaminated, containerized, and managed as a hazardous waste. Wastes of this type would typically carry waste numbers F999 and/or P999, in addition to other waste numbers where applicable. Discarded protective clothing (including suites, boots, gloves, canister to personnel breathing apparatus, etc.) is containerized and managed as a hazardous waste. Certain types of impregnated carbon have been found to contain chromium and silver in leachable quantities exceeding the TCLP criteria for hazardous waste. In such cases, EPA Waste Numbers D007 and DOll would be assigned to these wastes in addition to any other applicable hazardous waste numbers. Any indoor area where chemical agents, or agent filled munitions are stored has the potential to be ventilated. The air removed from the area passes through a bed of activated carbon before being released to the atmosphere. When the activated charcoal is changed out, the spent' carbon is containerized, and managed as a hazardous waste. -
Modern Chemical Weapons
Modern Chemical Weapons Modern Chemical Weapons causes serious diseases like cancer and serious birth defects in newly born Large scale chemical weapons were children. first used in World War One and have been used ever since. About 100 years ago Modern warfare has developed significantly since the early 20th century Early chemical weapons being used but the use of toxic chemicals to kill around a hundred years ago included: and badly injure is still very much in use tear gas, chlorine gas, mustard gas today. There have been reports of and phosgene gas. Since then, some chemical weapon attacks in Syria of the same chemicals have been during 2016. Chemical weapons have used in more modern warfare, but also been the choice of terrorists other new chemical weapons have because they are not very expensive also been developed. and need very little specialist knowledge to use them. These Chlorine gas (Cl2) weapons can cause a lot of causalities as well as fatalities, but also There have been reports of many spread panic and fear. chlorine gas attacks in Syria since 2013. It is a yellow-green gas which has a very distinctive smell like bleach. However, it does not last very long and therefore it is sometimes very difficult to prove it has been used during an attack. Victims would feel irritation of the eyes, nose, throat and lungs when they inhale it in large enough quantities. In even larger quantities it can cause the death of a person by suffocation. Mustard gas (C4H8Cl2S) There are reports by the United Nations (UN) of terrorist groups using Mustard Agent Orange (mixture of gas during chemical attacks in Syria. -
Epidemiological Findings of Major Chemical Attacks in the Syrian War Are Consistent with Civilian Targeting: a Short Report Jose M
Rodriguez-Llanes et al. Conflict and Health (2018) 12:16 https://doi.org/10.1186/s13031-018-0150-4 SHORTREPORT Open Access Epidemiological findings of major chemical attacks in the Syrian war are consistent with civilian targeting: a short report Jose M. Rodriguez-Llanes1, Debarati Guha-Sapir2 , Benjamin-Samuel Schlüter2 and Madelyn Hsiao-Rei Hicks3* Abstract Evidence of use of toxic gas chemical weapons in the Syrian war has been reported by governmental and non-governmental international organizations since the war started in March 2011. To date, the profiles of victims of the largest chemical attacks in Syria remain unknown. In this study, we used descriptive epidemiological analysis to describe demographic characteristics of victims of the largest chemical weapons attacks in the Syrian war. We analysed conflict-related, direct deaths from chemical weapons recorded in non-government-controlled areas by the Violation Documentation Center, occurring from March 18, 2011 to April 10, 2017, with complete information on the victim’s date and place of death, cause and demographic group. ‘Major’ chemical weapons events were defined as events causing ten or more direct deaths. As of April 10, 2017, a total of 1206 direct deaths meeting inclusion criteria were recorded in the dataset from all chemical weapons attacks regardless of size. Five major chemical weapons attacks caused 1084 of these documented deaths. Civilians comprised the majority (n = 1058, 97.6%) of direct deaths from major chemical weapons attacks in Syria and combatants comprised a minority of 2.4% (n = 26). In the first three major chemical weapons attacks, which occurred in 2013, children comprised 13%–14% of direct deaths, ranging in numbers from 2 deaths among 14 to 117 deaths among 923. -
Health Aspects of Biological and Chemical Weapons
[cover] WHO guidance SECOND EDITION WORLD HEALTH ORGANIZATION GENEVA DRAFT MAY 2003 [inside cover] PUBLIC HEALTH RESPONSE TO BIOLOGICAL AND CHEMICAL WEAPONS DRAFT MAY 2003 [Title page] WHO guidance SECOND EDITION Second edition of Health aspects of chemical and biological weapons: report of a WHO Group of Consultants, Geneva, World Health Organization, 1970 WORLD HEALTH ORGANIZATION GENEVA 2003 DRAFT MAY 2003 [Copyright, CIP data and ISBN/verso] WHO Library Cataloguing-in-Publication Data ISBN xxxxx First edition, 1970 Second edition, 2003 © World Health Organization 1970, 2003 All rights reserved. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. Dotted lines on maps represent approximate border lines for which there may not yet be full agreement. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damages incurred as a result of its use. Publications of the World Health Organization can be obtained from Marketing and Dissemination, World Health Organization, 20 Avenue Appia, 1211 Geneva 27, Switzerland (tel: +41 22 791 2476; fax: +41 22 791 4857; email: [email protected]). -
Countering the Use of Chemical Weapons in Syria: Options for Supporting International Norms and Institutions
EU Non-Proliferation and Disarmament Consortium NON-PROLIFERATION AND DISARMAMENT PAPERS Promoting the European network of independent non-proliferation and disarmament think tanks No. 63 June 2019 COUNTERING THE USE OF CHEMICAL WEAPONS IN SYRIA: OPTIONS FOR SUPPORTING INTERNATIONAL NORMS AND INSTITUTIONS una becker-jakob* INTRODUCTION SUMMARY For more than six years the people of Syria and the Chemical weapons are banned by international law. international community have had to face the fact Nonetheless, there have been numerous alleged and proven that chemical weapons have become part of the chemical attacks during the Syrian civil war. The international community has found ways to address this weapons arsenal in the Syrian civil war. By using these problem, but it has not managed to exclude the possibility weapons, those responsible—the Syrian Government of further chemical attacks once and for all. Nor has it included—have violated one of the most robust taboos created accountability for the perpetrators. The in international humanitarian law. In recent years, establishment in 2018 of the Investigation and the international community, the United Nations Identification Team within the Organisation for the and the Organisation for the Prohibition of Chemical Prohibition of Chemical Weapons (OPCW) is a step in the Weapons (OPCW) have found creative ways to address right direction, but it came at the price of increased this situation, but no strategy has so far succeeded in polarization among member states. To maintain the truly redressing -
Desind Finding
NATIONAL AIR AND SPACE ARCHIVES Herbert Stephen Desind Collection Accession No. 1997-0014 NASM 9A00657 National Air and Space Museum Smithsonian Institution Washington, DC Brian D. Nicklas © Smithsonian Institution, 2003 NASM Archives Desind Collection 1997-0014 Herbert Stephen Desind Collection 109 Cubic Feet, 305 Boxes Biographical Note Herbert Stephen Desind was a Washington, DC area native born on January 15, 1945, raised in Silver Spring, Maryland and educated at the University of Maryland. He obtained his BA degree in Communications at Maryland in 1967, and began working in the local public schools as a science teacher. At the time of his death, in October 1992, he was a high school teacher and a freelance writer/lecturer on spaceflight. Desind also was an avid model rocketeer, specializing in using the Estes Cineroc, a model rocket with an 8mm movie camera mounted in the nose. To many members of the National Association of Rocketry (NAR), he was known as “Mr. Cineroc.” His extensive requests worldwide for information and photographs of rocketry programs even led to a visit from FBI agents who asked him about the nature of his activities. Mr. Desind used the collection to support his writings in NAR publications, and his building scale model rockets for NAR competitions. Desind also used the material in the classroom, and in promoting model rocket clubs to foster an interest in spaceflight among his students. Desind entered the NASA Teacher in Space program in 1985, but it is not clear how far along his submission rose in the selection process. He was not a semi-finalist, although he had a strong application. -
Chemical Bonds, Chemical Compounds, and Chemical Weapons
Chemical Bonds, Chemical Compounds, and Chemical Weapons http://preparatorychemistry.com/Bishop_Book_atoms_5.pdf Elements, Compounds, and Mixtures • Element: A substance that cannot be chemically converted into simpler substances; a substance in which all of the atoms have the same number of protons and therefore the same chemical characteristics. • Compound: A substance that contains two or more elements, the atoms of these elements always combining in the same whole-number ratio. • Mixture: A sample of matter that contains two or more pure substances (elements and compounds) and has variable composition. Classification of Matter Elements and Compounds Exhaust – a Mixture Covalent Bond Formation Covalent Bond • A link between atoms due to the sharing of two electrons. This bond forms between atoms of two nonmetallic elements. – If the electrons are shared equally, there is a even distribution of the negative charge for the electrons in the bond, so there is no partial charges on the atoms. The bond is called a nonpolar covalent bond. – If one atom in the bond attracts electrons more than the other atom, the electron negative charge shifts to that atom giving it a partial negative charge. The other atom loses negative charge giving it a partial positive charge. The bond is called a polar covalent bond. Polar Covalent Bond Ionic Bond • The attraction between cation and anion. • Atoms of nonmetallic elements often attract electrons so much more strongly than atoms of metallic elements that one or more electrons are transferred from the metallic atom (forming a positively charged particle or cation), to the nonmetallic atom (forming a negatively charged particle or anion). -
The History of Chemical and Biological Warfare: an American
History of Chemical and Biological Warfare: An American Perspective Chapter 2 HISTORY OF CHEMICAL AND BIOLOGICAL WARFARE: AN AMERICAN PERSPECTIVE JEFFERY K. SMART, M.A.* INTRODUCTION PRE–WORLD WAR I DEVELOPMENTS WORLD WAR I THE 1920S: THE LEAN YEARS THE 1930S: THE GROWING THREAT OF CHEMICAL AND BIOLOGICAL WARFARE THE 1940S: WORLD WAR II AND THE NUCLEAR AGE THE 1950S: HEYDAY OF THE CHEMICAL CORPS THE 1960S: DECADE OF TURMOIL THE 1970S: THE NEAR END OF THE CHEMICAL CORPS THE 1980S: THE RETURN OF THE CHEMICAL CORPS THE 1990S: THE THREAT MATERIALIZES SUMMARY *Command Historian, U.S. Army Chemical and Biological Defense Command, Aberdeen Proving Ground, Maryland 21010-5423 9 Medical Aspects of Chemical and Biological Warfare INTRODUCTION Webster’s Ninth New Collegiate Dictionary defines or biological warfare went virtually unnoticed by the term “chemical warfare,” first used in 1917, the U.S. Army. By the end of World War I, the situ- as “tactical warfare using incendiary mixtures, ation had drastically changed. Chemical warfare smokes, or irritant, burning, poisonous, or asphyx- had been used against and by American soldiers iating gases.” A working definition of a chem- on the battlefield. Biological warfare had been used ical agent is “a chemical which is intended for covertly on several fronts. In an effort to determine use in military operations to kill, seriously injure, what had gone wrong with their planning and train- or incapacitate man because of its physiological ing, U.S. Army officers prepared a history of chemi- effects. Excluded from consideration are riot con- cal and biological warfare. To their surprise, they trol agents, chemical herbicides and smoke found numerous documented cases of chemical and and flame materials.”1(p1-1) Chemical agents were biological agents having been used or proposed to usually divided into five categories: nerve agents, influence the outcome of a battle or campaign. -
VX Binary (VX2) – Developed by the US • Novichok Agent
THE FOUR LIKELY BINARY AGENTS Working paper Charles P. Blair Last Updated, January 2013 Binary sarin (GB2) – developed by the U.S. Binary soman (GD2) VX binary (VX2) – developed by the U.S Novichok agent (“New Comer) –developed by the Soviets Additionally, Eric Croddy has written that VNSAs may use “binarytype designs” in an attack…with simple designs most likely using common chemical ingredients (e . g. , c ya n id e . ) ” 1 Aum is an example o f t h is . 1. Binary sarin . With binary sarin (also referred to as “GB binary” and “GB2”) a forward container has methylphosphonic difluoride (DF), while a second, rear container has an isopropyl alcohol and isopropylamine solution (OPA). The DF resides in the munition prior to use. The OPA is added just prior to launch. After deployment of the weapon, the two canisters rupture, “the isopropyl amine binds to the hydrogen fluoride generated during the chemical reaction, and the chemical mixture produces GB.”2 Experts note that, “The final product of the weapon is of the same chemical structure as the original nerve agent. The term binary refers only to the storage and deployment method used, not to the chemical structure of the substance.”3 With regard to how long it takes the DF and OPA to mix before binary sarin is extant, Eric Croddy notes that, “as in any chemical reaction, a certain amount of time is required for the [binary] reaction to run its course. In the case of GB binary, this required about seven seconds.”4 2. Binary soman (also referred to as “GD binary” and “GD2”).