Chemical Weapons
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Page 1 EXAMPLES of ACUTE TOXINS (By CAS#) APPENDIX V(H)-B
EXAMPLES OF ACUTE TOXINS (by CAS#) APPENDIX V(h)-B Key: SA -- Readily Absorbed Through the Skin Revised: 12/2012 ___________________________________________________ _____________ _________________________ | | | CHEMICAL NAME CAS # | SA | TARGET ORGAN | ___________________________________________________ ____________ | _ | _______________________ | AFLATOXINS 000000-00-0 | | systemic | ANILINE AND COMPOUNDS 000000-00-0 | x | blood | ARSENIC ACID AND SALTS 000000-00-0 | x | systemic | ARSENIUOS ACID AND SALTS 000000-00-0 | | systemic | ARSONIC ACID AND SALTS 000000-00-0 | | systemic | BOTULINUM TOXINS 000000-00-0 | | systemic | CYANIDE AND COMPOUNDS 000000-00-0 | x | blood | CYANOGEN AND COMPOUNDS 000000-00-0 | | blood | METHYL MERCURY AND COMPOUNDS 000000-00-0 | x | CNS | VENOM, SNAKE, CROTALUS ADAMANTEUS 000000-00-0 | | systemic | VENOM, SNAKE, CROTALUS ATROX 000000-00-0 | | systemic | MITOMYCIN C 000050-07-7 | | systemic | DINITROPHENOL, 2,4- 000051-28-5 | x | systemic | ATROPINE 000051-55-8 | x | CNS | HN2 (NITROGEN MUSTARD-2) 000051-75-2 | x | systemic | THIOTEPA 000052-24-4 | | systemic | NICOTINE 000054-11-5 | x | CNS | NITROGEN MUSTARD HYDROCHLORIDE 000055-86-7 | x | systemic | PARATHION 000056-38-2 | x | CNS | CYANIDE 000057-12-5 | x | blood | STRYCHNINE 000057-24-9 | | systemic,CNS | TUBOCURARINE CHLORIDE HYDRATE,(+)- 000057-94-3 | x | systemic | METHYL HYDRAZINE 000060-34-4 | x | pulmonary,CNS,blood | ANILINE 000062-53-3 | x | blood | DICHLORVOS 000062-73-7 | x | systemic | SODIUM FLUOROACETATE 000062-74-8 | x | systemic | COLCHICINE -
Critical Evaluation of Proven Chemical Weapon Destruction Technologies
Pure Appl. Chem., Vol. 74, No. 2, pp. 187–316, 2002. © 2002 IUPAC INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY ORGANIC AND BIOMOLECULAR CHEMISTRY DIVISION IUPAC COMMITTEE ON CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES* WORKING PARTY ON EVALUATION OF CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES** CRITICAL EVALUATION OF PROVEN CHEMICAL WEAPON DESTRUCTION TECHNOLOGIES (IUPAC Technical Report) Prepared for publication by GRAHAM S. PEARSON1,‡ AND RICHARD S. MAGEE2 1Department of Peace Studies, University of Bradford, Bradford, West Yorkshire BD7 1DP, UK 2Carmagen Engineering, Inc., 4 West Main Street, Rockaway, NJ 07866, USA *Membership of the IUPAC Committee is: Chairman: Joseph F. Burnett; Members: Wataru Ando (Japan), Irina P. Beletskaya (Russia), Hongmei Deng (China), H. Dupont Durst (USA), Daniel Froment (France), Ralph Leslie (Australia), Ronald G. Manley (UK), Blaine C. McKusick (USA), Marian M. Mikolajczyk (Poland), Giorgio Modena (Italy), Walter Mulbry (USA), Graham S. Pearson (UK), Kurt Schaffner (Germany). **Membership of the Working Group was as follows: Chairman: Graham S. Pearson (UK); Members: Richard S. Magee (USA), Herbert de Bisschop (Belgium). The Working Group wishes to acknowledge the contributions made by the following, although the conclusions and contents of the Technical Report remain the responsibility of the Working Group: Joseph F. Bunnett (USA), Charles Baronian (USA), Ron G. Manley (OPCW), Georgio Modena (Italy), G. P. Moss (UK), George W. Parshall (USA), Julian Perry Robinson (UK), and Volker Starrock (Germany). ‡Corresponding author Republication or reproduction of this report or its storage and/or dissemination by electronic means is permitted without the need for formal IUPAC permission on condition that an acknowledgment, with full reference to the source, along with use of the copyright symbol ©, the name IUPAC, and the year of publication, are prominently visible. -
Nerve Agent - Lntellipedia Page 1 Of9 Doc ID : 6637155 (U) Nerve Agent
This document is made available through the declassification efforts and research of John Greenewald, Jr., creator of: The Black Vault The Black Vault is the largest online Freedom of Information Act (FOIA) document clearinghouse in the world. The research efforts here are responsible for the declassification of MILLIONS of pages released by the U.S. Government & Military. Discover the Truth at: http://www.theblackvault.com Nerve Agent - lntellipedia Page 1 of9 Doc ID : 6637155 (U) Nerve Agent UNCLASSIFIED From lntellipedia Nerve Agents (also known as nerve gases, though these chemicals are liquid at room temperature) are a class of phosphorus-containing organic chemicals (organophosphates) that disrupt the mechanism by which nerves transfer messages to organs. The disruption is caused by blocking acetylcholinesterase, an enzyme that normally relaxes the activity of acetylcholine, a neurotransmitter. ...--------- --- -·---- - --- -·-- --- --- Contents • 1 Overview • 2 Biological Effects • 2.1 Mechanism of Action • 2.2 Antidotes • 3 Classes • 3.1 G-Series • 3.2 V-Series • 3.3 Novichok Agents • 3.4 Insecticides • 4 History • 4.1 The Discovery ofNerve Agents • 4.2 The Nazi Mass Production ofTabun • 4.3 Nerve Agents in Nazi Germany • 4.4 The Secret Gets Out • 4.5 Since World War II • 4.6 Ocean Disposal of Chemical Weapons • 5 Popular Culture • 6 References and External Links --------------- ----·-- - Overview As chemical weapons, they are classified as weapons of mass destruction by the United Nations according to UN Resolution 687, and their production and stockpiling was outlawed by the Chemical Weapons Convention of 1993; the Chemical Weapons Convention officially took effect on April 291997. Poisoning by a nerve agent leads to contraction of pupils, profuse salivation, convulsions, involuntary urination and defecation, and eventual death by asphyxiation as control is lost over respiratory muscles. -
Modern Chemical Weapons
Modern Chemical Weapons Modern Chemical Weapons causes serious diseases like cancer and serious birth defects in newly born Large scale chemical weapons were children. first used in World War One and have been used ever since. About 100 years ago Modern warfare has developed significantly since the early 20th century Early chemical weapons being used but the use of toxic chemicals to kill around a hundred years ago included: and badly injure is still very much in use tear gas, chlorine gas, mustard gas today. There have been reports of and phosgene gas. Since then, some chemical weapon attacks in Syria of the same chemicals have been during 2016. Chemical weapons have used in more modern warfare, but also been the choice of terrorists other new chemical weapons have because they are not very expensive also been developed. and need very little specialist knowledge to use them. These Chlorine gas (Cl2) weapons can cause a lot of causalities as well as fatalities, but also There have been reports of many spread panic and fear. chlorine gas attacks in Syria since 2013. It is a yellow-green gas which has a very distinctive smell like bleach. However, it does not last very long and therefore it is sometimes very difficult to prove it has been used during an attack. Victims would feel irritation of the eyes, nose, throat and lungs when they inhale it in large enough quantities. In even larger quantities it can cause the death of a person by suffocation. Mustard gas (C4H8Cl2S) There are reports by the United Nations (UN) of terrorist groups using Mustard Agent Orange (mixture of gas during chemical attacks in Syria. -
Epidemiological Findings of Major Chemical Attacks in the Syrian War Are Consistent with Civilian Targeting: a Short Report Jose M
Rodriguez-Llanes et al. Conflict and Health (2018) 12:16 https://doi.org/10.1186/s13031-018-0150-4 SHORTREPORT Open Access Epidemiological findings of major chemical attacks in the Syrian war are consistent with civilian targeting: a short report Jose M. Rodriguez-Llanes1, Debarati Guha-Sapir2 , Benjamin-Samuel Schlüter2 and Madelyn Hsiao-Rei Hicks3* Abstract Evidence of use of toxic gas chemical weapons in the Syrian war has been reported by governmental and non-governmental international organizations since the war started in March 2011. To date, the profiles of victims of the largest chemical attacks in Syria remain unknown. In this study, we used descriptive epidemiological analysis to describe demographic characteristics of victims of the largest chemical weapons attacks in the Syrian war. We analysed conflict-related, direct deaths from chemical weapons recorded in non-government-controlled areas by the Violation Documentation Center, occurring from March 18, 2011 to April 10, 2017, with complete information on the victim’s date and place of death, cause and demographic group. ‘Major’ chemical weapons events were defined as events causing ten or more direct deaths. As of April 10, 2017, a total of 1206 direct deaths meeting inclusion criteria were recorded in the dataset from all chemical weapons attacks regardless of size. Five major chemical weapons attacks caused 1084 of these documented deaths. Civilians comprised the majority (n = 1058, 97.6%) of direct deaths from major chemical weapons attacks in Syria and combatants comprised a minority of 2.4% (n = 26). In the first three major chemical weapons attacks, which occurred in 2013, children comprised 13%–14% of direct deaths, ranging in numbers from 2 deaths among 14 to 117 deaths among 923. -
Health Aspects of Biological and Chemical Weapons
[cover] WHO guidance SECOND EDITION WORLD HEALTH ORGANIZATION GENEVA DRAFT MAY 2003 [inside cover] PUBLIC HEALTH RESPONSE TO BIOLOGICAL AND CHEMICAL WEAPONS DRAFT MAY 2003 [Title page] WHO guidance SECOND EDITION Second edition of Health aspects of chemical and biological weapons: report of a WHO Group of Consultants, Geneva, World Health Organization, 1970 WORLD HEALTH ORGANIZATION GENEVA 2003 DRAFT MAY 2003 [Copyright, CIP data and ISBN/verso] WHO Library Cataloguing-in-Publication Data ISBN xxxxx First edition, 1970 Second edition, 2003 © World Health Organization 1970, 2003 All rights reserved. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. Dotted lines on maps represent approximate border lines for which there may not yet be full agreement. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damages incurred as a result of its use. Publications of the World Health Organization can be obtained from Marketing and Dissemination, World Health Organization, 20 Avenue Appia, 1211 Geneva 27, Switzerland (tel: +41 22 791 2476; fax: +41 22 791 4857; email: [email protected]). -
Countering the Use of Chemical Weapons in Syria: Options for Supporting International Norms and Institutions
EU Non-Proliferation and Disarmament Consortium NON-PROLIFERATION AND DISARMAMENT PAPERS Promoting the European network of independent non-proliferation and disarmament think tanks No. 63 June 2019 COUNTERING THE USE OF CHEMICAL WEAPONS IN SYRIA: OPTIONS FOR SUPPORTING INTERNATIONAL NORMS AND INSTITUTIONS una becker-jakob* INTRODUCTION SUMMARY For more than six years the people of Syria and the Chemical weapons are banned by international law. international community have had to face the fact Nonetheless, there have been numerous alleged and proven that chemical weapons have become part of the chemical attacks during the Syrian civil war. The international community has found ways to address this weapons arsenal in the Syrian civil war. By using these problem, but it has not managed to exclude the possibility weapons, those responsible—the Syrian Government of further chemical attacks once and for all. Nor has it included—have violated one of the most robust taboos created accountability for the perpetrators. The in international humanitarian law. In recent years, establishment in 2018 of the Investigation and the international community, the United Nations Identification Team within the Organisation for the and the Organisation for the Prohibition of Chemical Prohibition of Chemical Weapons (OPCW) is a step in the Weapons (OPCW) have found creative ways to address right direction, but it came at the price of increased this situation, but no strategy has so far succeeded in polarization among member states. To maintain the truly redressing -
HA Lee, R Gabriel, AJ Bale, D Welch. Clinical Findings in 111 Ex-Porton
J R Army Med Corps 2004; 150: 14-19 J R Army Med Corps: first published as 10.1136/jramc-150-01-03 on 1 March 2004. Downloaded from Clinical Findings In 111 Ex-Porton Down Volunteers HA Lee, R Gabriel, AJ Bale, D Welch ABSTRACT clothing. Also there has been considerable Objective research into protective pre-treatments and To determine whether the health of treatments for chemical and biological agent Porton Down volunteers (PDV) has poisoning and the effects of exposure to low suffered as a result of their participation doses of chemical warfare and potential in medical trials, during which they threat agents. These have included mustard were exposed to single low dose con- blister agents, organophosphate derivatives centrations of chemical warfare agents. such as nerve agents, lachrymators, vomiting inductors, incapacitants and antidotes. It is Methods this latter category of studies that has Data were obtained from a self-selected attracted most concern from the popular series of ex-Porton Down volunteers media and public alike. who attended the MOD’s Porton Down Approximately 3,000 volunteers have Volunteers’ Medical Assessment Prog- participated in studies involving nerve agents ramme (PDVMAP). One hundred and and about 6,000 with mustard gas. Some eleven men attended with a mean age of individuals have been potentially exposed to 62 (range 37-81) years. Information ob- both agents. Participation in such studies did tained was analysed to determine whe- not necessarily involve exposure to the agent ther clinical diagnoses and symptoms concerned; for instance, some volunteers reported had any relationship to acted as ‘control’ and where protective chemical exposures. -
Chemical Bonds, Chemical Compounds, and Chemical Weapons
Chemical Bonds, Chemical Compounds, and Chemical Weapons http://preparatorychemistry.com/Bishop_Book_atoms_5.pdf Elements, Compounds, and Mixtures • Element: A substance that cannot be chemically converted into simpler substances; a substance in which all of the atoms have the same number of protons and therefore the same chemical characteristics. • Compound: A substance that contains two or more elements, the atoms of these elements always combining in the same whole-number ratio. • Mixture: A sample of matter that contains two or more pure substances (elements and compounds) and has variable composition. Classification of Matter Elements and Compounds Exhaust – a Mixture Covalent Bond Formation Covalent Bond • A link between atoms due to the sharing of two electrons. This bond forms between atoms of two nonmetallic elements. – If the electrons are shared equally, there is a even distribution of the negative charge for the electrons in the bond, so there is no partial charges on the atoms. The bond is called a nonpolar covalent bond. – If one atom in the bond attracts electrons more than the other atom, the electron negative charge shifts to that atom giving it a partial negative charge. The other atom loses negative charge giving it a partial positive charge. The bond is called a polar covalent bond. Polar Covalent Bond Ionic Bond • The attraction between cation and anion. • Atoms of nonmetallic elements often attract electrons so much more strongly than atoms of metallic elements that one or more electrons are transferred from the metallic atom (forming a positively charged particle or cation), to the nonmetallic atom (forming a negatively charged particle or anion). -
The History of Chemical and Biological Warfare: an American
History of Chemical and Biological Warfare: An American Perspective Chapter 2 HISTORY OF CHEMICAL AND BIOLOGICAL WARFARE: AN AMERICAN PERSPECTIVE JEFFERY K. SMART, M.A.* INTRODUCTION PRE–WORLD WAR I DEVELOPMENTS WORLD WAR I THE 1920S: THE LEAN YEARS THE 1930S: THE GROWING THREAT OF CHEMICAL AND BIOLOGICAL WARFARE THE 1940S: WORLD WAR II AND THE NUCLEAR AGE THE 1950S: HEYDAY OF THE CHEMICAL CORPS THE 1960S: DECADE OF TURMOIL THE 1970S: THE NEAR END OF THE CHEMICAL CORPS THE 1980S: THE RETURN OF THE CHEMICAL CORPS THE 1990S: THE THREAT MATERIALIZES SUMMARY *Command Historian, U.S. Army Chemical and Biological Defense Command, Aberdeen Proving Ground, Maryland 21010-5423 9 Medical Aspects of Chemical and Biological Warfare INTRODUCTION Webster’s Ninth New Collegiate Dictionary defines or biological warfare went virtually unnoticed by the term “chemical warfare,” first used in 1917, the U.S. Army. By the end of World War I, the situ- as “tactical warfare using incendiary mixtures, ation had drastically changed. Chemical warfare smokes, or irritant, burning, poisonous, or asphyx- had been used against and by American soldiers iating gases.” A working definition of a chem- on the battlefield. Biological warfare had been used ical agent is “a chemical which is intended for covertly on several fronts. In an effort to determine use in military operations to kill, seriously injure, what had gone wrong with their planning and train- or incapacitate man because of its physiological ing, U.S. Army officers prepared a history of chemi- effects. Excluded from consideration are riot con- cal and biological warfare. To their surprise, they trol agents, chemical herbicides and smoke found numerous documented cases of chemical and and flame materials.”1(p1-1) Chemical agents were biological agents having been used or proposed to usually divided into five categories: nerve agents, influence the outcome of a battle or campaign. -
Application of Gaussian Bayes Classifier to Differentiate Chlorine-Based Chemical Agents
INL/EXT-20-57785 Application of Gaussian Bayes classifier to differentiate chlorine-based chemical agents Dongwon Lee Brian Bucher Ken Krebs Ed Seabury Jason Wharton April 7, 2020 The INL is a U.S. Department of Energy National Laboratory operated by Battelle Energy Alliance DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. INL/EXT-20-57785 Application of Gaussian Bayes classifier to differentiate chlorine-based chemical agents D. Lee B. Bucher K. Krebs E. Seabury J. Wharton April 7, 2020 Idaho National Laboratory Nuclear Nonproliferation Division Idaho Falls, Idaho 83415 http://www.inl.gov Prepared for the U.S. Department of Energy Office of National Nuclear Security Administration Under DOE Idaho Operations Office Contract DE-AC07-05ID14517 ABSTRACT The Portable Isotopic Neutron Spectroscopy (PINS) is a commercialized system developed by Idaho National Laboratory (INL) to examine chemical warfare agents (CWA) non-destructively, utilizing Prompt Gamma Neutron Activation Analysis (PGNAA) techniques. -
The Yellow Rain Affair Lessons from a Discredited Allegation
chapter four The Yellow Rain Affair Lessons from a Discredited Allegation matthew s. meselson and julian perry robinson U.S. Secretary of State Alexander Haig, in a speech in West Berlin1 in September 1981 and in a detailed report to the Congress the following March,2 charged So- viet-backed Laotian and Vietnamese forces with waging toxin warfare against Hmong resistance fighters and their villages in Laos and against Khmer Rouge soldiers and villages in Cambodia. The charges were repeated with additional details in a further report to the Congress and to the member states of the United Nations in November 1982 by Haig’s successor, Secretary of State George Shultz.3 The investigation on which the allegation was based, however, failed to em- ploy reliable methods of witness interrogation or of forensic laboratory inves- tigation; it was further marred by the dismissal and withholding of contrary evidence and a lack of independent review. When the evidence for toxin attacks or any other form of chemical/biological warfare (CBW) was subjected to more careful examination, it could not be confirmed or was discredited. In what be- came known as the “Yellow Rain” affair, these charges—that toxic substances called trichothecenes were used in CBW—were initially pressed vigorously by the U.S. government and, even when the allegations proved unsustainable, they were not withdrawn. This chapter reviews all of the evidence adduced at the time that is now The Yellow Rain Affair 73 public, including a large body of material declassified and provided to us and others starting in 1986 under the Freedom of Information Act.