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Stockpile Stewardshipquarterly DOE/NA-0066 Office of Research, Development, Test, and Evaluation Stockpile Stewardship Quarterly VOLUME 7 | NUMBER 4 | DECEMBER 2017 essage from the Assistant Deputy Administrator for Research, M Development, Test, and Evaluation, Dr. Kathleen Alexander In stockpile stewardship, one of the most Laboratory (LANL) takes a different focus, widely studied phenomena is the equation looking at the EOS and shock-driven of state (EOS). An EOS is a mathematical decomposition of ‘soft’ materials. LANL relationship that describes the state of uses a two-stage gas gun to collect shock matter (i.e., gas, liquid, or solid) using data of polymers to incorporate in their the material properties of temperature, EOS. volume, pressure, and internal energy. The The Joint Actinide Shock Physics EOS characterizes the properties of a state Experimental Research facility two-stage of matter under a given set of physical gas gun at Nevada National Security Site conditions. It is of interest for the metals (NNSS) is used for both hazardous and and non-metals of stockpile stewardship non-hazardous material studies for input application and is critical to understanding to EOS tables. Many EOS experiments Hong Sio, NNSA-supported senior Physics material behavior. Each of our weapon Department PhD student at the Massachusetts at NNSS involve dynamic materials and laboratories has extensive EOS activities. Institute of Technology (second from left) associated diagnostic developments found time to strike a pose with (left to This issue of the Stockpile Stewardship pertaining to stockpile materials. right) Dr. Njema Frazier and Dr. Bryan Sims Quarterly (SSQ) highlights representative (Research, Development, Test, and Evaluation) EOS activities at our national laboratories, Some of our innovative EOS work origi- and Mark Visosky (TechSource, Inc.) at the the Nevada National Security Site, and nated from the LDRD program projects at 59th Annual Meeting of the American Physical in the Laboratory Directed Research and Sandia. Two Sandia projects are pushing Society Division of Plasma Physics in October 2017. Hong designed and implemented a Development (LDRD) program as well as the envelope to deliver EOSs that provide new and unique diagnostic that can measure, efforts to continue our pipeline through data used to determine phase transitions simultaneously, multiple-nuclear-burn histories the Research, Development, Test, and accurately under extreme conditions. We occurring during an ICF implosion. His innova- Evaluation academic alliances programs. tive diagnostic work at NIF and OMEGA led to his invited talk by APS. Congratulations, Hong! We begin with an article that discusses prepareclose out tomorrow’s this issue by stockpile showcasing stewardship the Office how Sandia National Laboratories leadersof Inertial through Confinement the academic Fusion alliances efforts to (Sandia) uses pulsed power to carry out Your efforts in 2017 were greatly programs. The High-Energy-Density appreciated. Happy new year. EOS experiments necessary to model and Sciences Summer School aimed to inspire understand nuclear weapon performance. the 114 young scientists in attendance to Sandia’s Z pulsed power facility is become the next generation of leaders in providing capabilities that are unique for stockpile stewardship. measuring the EOS properties of materials under dynamic compression. At Lawrence Inside Livermore National Laboratory, Gbar pressures on the National Ignition Facility 2 Equation of State Research at Sandia National Laboratories (NIF) are reaching unexplored regimes of 4 Assessing Extreme Equation of State Conditions on the National Ignition Facility density and pressure. NIF experiments 6 Equation of State and Shock-Driven Decomposition of 'Soft' Materials on EOS allow us to address long-standing 8 Dynamic Materials Research at the Nevada National Security Site programmatic questions and meet new 10 LDRD Innovations for Stockpile Stewardship: New Flexibility in Dynamic Materials Research challenges associated with our national Via Pulsed Power and Compressing Materials Under Extreme Conditions security mission. Los Alamos National 12 Preparing Tomorrow's Stockpile Stewardship Leaders Comments The Stockpile Stewardship Quarterly is produced by the National Nuclear Security Administration (NNSA) Office of Research, Development, Test, and Evaluation. Questions and comments regarding this publication should be directed to Terri Stone at [email protected]. Technical Editor: Dr. Joseph Kindel | Publication Editor: Millicent Mischo 2 Equation of State Research at Sandia National Laboratories by T.R. Mattsson, D.G. Flicker, S. Root, and L. Shulenburger (Sandia National Laboratories) An EOS is a mathematical relationship methods are developed to create and THOR described in an accompanying that describes the state of matter (i.e., diagnose extreme conditions of matter. An article “New Flexibility in Dynamic gas, liquid, or solid) using the material example of a new exciting development Materials Research Via Pulsed Power" properties of temperature, volume, for Z is the pre-compression capability pressure, and internal energy. The EOS described in the article “Compressing machine. In addition to the experimental characterizes the properties of a state Materials Under Extreme Conditions" capabilities,on page 10 and our finally dynamic the material powerful Z of matter under a given set of physical on page 11. By compressing the sample, properties program has a distinguished conditions. For example, the EOS record of collaborative efforts between determines how hot a material gets when studied as a homogenous liquid mixture experiments and corresponding ab subjected to a strong shock wave. High- andotherwise a range immiscible of additional fluids thermodynamic can be initio calculations, principally those with conditions can be accessed since the density functional theory (DFT). Theory is to model and understand a broad range loading path is shifted compared to used in direct simulation of experimental offidelity systems, EOSs including are, therefore, the structure necessary of experiments at normal pressure. conditions achieved on Z and other Earth and giant planets, high energy platforms, and these calculations have Sandia has a long history of research in EOS, a history that was recently fusion (ICF) experiments on the Z physics models for the design and documented in the book “Impactful machinedensity (HED) at Sandia and Nationalinertial confinement Laboratories simulationbeen critical of to Z developingexperiments. high-fidelity Use of DFT Times: Memories of 60 Years of Shock (Sandia) or the National Ignition Facility is now routine for calculating EOSs and Wave Research at Sandia National (NIF) at Lawrence Livermore National electrical and thermal conductivities. Laboratory (LLNL), and nuclear weapon Laboratories” by Jim Asay, Lalit Chhabildas, Jeff Lawrence, and Mary-Ann The Z machine is a multi-purpose high Sweeney.1 The book presents six decades energy density (HED) facility that modelsperformance. when Itperforming is difficult multi-physics to overstate the of development of experimental, material provides capabilities that are unique hydrodynamicimportance of usingsimulations high-fidelity for stockpile material modeling, and hydrodynamics code in the world for measuring the EOS stewardship applications, a critical technologies. At present, EOS properties properties of materials under dynamic activity at all NNSA national laboratories. are measured at multiple Sandia facilities: compression: the Shock Thermodynamic Applied Under extreme conditions in Research (STAR) facility holds several Flexible pulse shaping that enables temperature, density, and pressure, the powerful gas guns/launchers and a range adjustable loading rates for EOS for solids, liquids, gases, and dense of diagnostics; the Dynamic Integrated • ramp compression, shock-ramp plasmas are far more complex than Compression Experimental (DICE) facility compression, and very high pressure textbook EOS models like ideal gas or van with a small launcher and the 2.6-MA (10-20 Mbar or 1,000-2,000 GPa) der Waals. Many different experimental shock experiments techniques, therefore, exist and new next-generation pulsed power platform pulsed power machine VELOCE; the first handbook.3 The excellent agreement is strong support for the theoretical work.2 principlesFigure 1. Shock results, compression direct measured of MgO. temperatures, Left: Shock pressure4 and experimental as a function data of densityfrom Z in from pressure first principles with the temperature theory, experiments inferred on from Z, and calculations data from at the the shock same Right: pressure/temperature phase diagram of MgO showing first conditions.shock pressure. The behavior as the Hugoniot crosses the phase boundaries is particularly important. Notice the significant co-existance between solid B2 and liquid during melting. By combining first-principles theory with experimental data we learn more about the behavior of materials at extreme Volume 7 | Number 4 | December 2017 Stockpile Stewardship Quarterly 3 Adequate sample sizes for extreme pressure experiments to investigate • the effects of microstructure on material response and/or understand the response of bulk heterogeneous materials Pressures and/or time scales that cannot be attained on gas guns or in • laser-driven compression experiments Capability for hazardous materials like beryllium, uranium, and plutonium An• example of recent research combining theory
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