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WaTEn RESOURCESINVESTIGATIONS O'Brien and W J. Stone, 1984:Ground Water, Newpublications v.22, no. 6, pp.717-727. 83-4l18-B-Maps showing ground-water levels, Volcanogenic-exhalativetungsten mineralization springs, and depth to ground water, Basin and T{MBMMR of Proterozoic age near Santa Fe, New Mexico, Range Province, New Mexico, by B. T. Brady, *Circular L90--The skull of Sphenacodon and implicationsfor exploration,by M. S. Fulp ferocior, D. A. Mulvihill, D. L Hart, and W. H. Lan- and comoarisons with other sphenacodontines Jr., andJ.L. Renshaw,1985: Geology, v.73,pp.66- ger, 7984,6 pp., 2 sheets,scale 1:500,000 (ReptiliaiPelycosauria), by D.-A. Eberth, 1985, 69. 83-411.8-C-Maps showing distribution of dis- 39 pp., 2 tables, 39 figs $4.00 in Virtually complete, disarticulated cranial re- solved solids and dominant chemical type New 0pen-filereports ma\nsof Sohenacodonferociorfrom the Cutler and ground water, Basin and Range Province, and NMBMMR Abo Formations (Lower Permian) of north-cen- Mexico,by T. H. Thompson, R. Chappell, scale *215--Evaluation tral New Mexico are described in detail for the D. L. Hart, Jr., 7984, 5 pp., 2 sheets, of laboratory procedures for de- first time. These descriptions provide the basis 1:500,000. termining soil-water chloride, by B. E. McGurk for the most detailedcomparisons to datewithin 83-41.18-D-Map showing outcrops of granitic and W. f. Stone,1985, 36 pp., 12 tables,2 figs. and the subfamily Sphen- rocks and silicic shallow-intrusive rocks, Basin $7.20 the genus Sphenacodon *21.9-Geology acodontinae. -
Kosnarite Kzr2(PO4)3 C 2001-2005 Mineral Data Publishing, Version 1
Kosnarite KZr2(PO4)3 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal, pseudocubic. Point Group: 32/m. As rhombohedral pseudocubic crystals, to 0.9 mm, with {1012} and tiny {0001}. Physical Properties: Cleavage: Perfect on {1012}. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 4.5 D(meas.) = 3.194(2) D(calc.) = 3.206 Optical Properties: Transparent to translucent. Color: Pale blue to blue-green, bluish gray, nearly colorless. Streak: White. Luster: Vitreous. Optical Class: Uniaxial (+). ω = 1.656(2) = 1.682(2) Cell Data: Space Group: R3c. a = 8.687(2) c = 23.877(7) Z = 6 X-ray Powder Pattern: Mt. Mica, Maine, USA. 4.329 (100), 3.806 (90), 2.928 (90), 6.41 (50), 4.679 (50), 2.502 (50), 1.903 (45) Chemistry: (1) (2) (3) P2O5 43.3 42.2 42.04 ZrO2 44.5 47.9 48.66 HfO2 0.5 0.9 FeO 0.2 < 0.1 MnO 1.0 < 0.1 Na2O 1.4 < 0.1 K2O 8.7 9.25 9.30 Rb2O 0.25 0.2 F 0.20 0.2 −O=F2 0.08 0.08 Total 99.97 100.57 100.00 (1) Mt. Mica, Maine, USA; by electron microprobe, total Fe as FeO, total Mn as MnO; corresponds to (K0.93Na0.08Rb0.01)Σ=1.02(Zr1.81Na0.15Mn0.07Fe0.01Hf0.01)Σ=2.05 [P1.02(O3.98F0.02)Σ=4.00]3. (2) Black Mountain, Maine, USA; by electron microprobe, total Fe as FeO, total Mn as MnO; corresponds to (K0.99Rb0.01)Σ=1.00(Zr1.96Hf0.02)Σ=1.98 [P1.00(O3.98F0.02)Σ=4.00]3. -
Review 1 Sb5+ and Sb3+ Substitution in Segnitite
1 Review 1 2 3 Sb5+ and Sb3+ substitution in segnitite: a new sink for As and Sb in the environment and 4 implications for acid mine drainage 5 6 Stuart J. Mills1, Barbara Etschmann2, Anthony R. Kampf3, Glenn Poirier4 & Matthew 7 Newville5 8 1Geosciences, Museum Victoria, GPO Box 666, Melbourne 3001, Victoria, Australia 9 2Mineralogy, South Australian Museum, North Terrace, Adelaide 5000 Australia + School of 10 Chemical Engineering, The University of Adelaide, North Terrace 5005, Australia 11 3Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 12 Exposition Boulevard, Los Angeles, California 90007, U.S.A. 13 4Mineral Sciences Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, 14 Ontario, Canada, K1P 6P4 15 5Center for Advanced Radiation Studies, University of Chicago, Building 434A, Argonne 16 National Laboratory, Argonne. IL 60439, U.S.A. 17 *E-mail: [email protected] 18 19 20 21 22 23 24 25 26 27 Abstract 28 A sample of Sb-rich segnitite from the Black Pine mine, Montana, USA has been studied by 29 microprobe analyses, single crystal X-ray diffraction, μ-EXAFS and XANES spectroscopy. 30 Linear combination fitting of the spectroscopic data provided Sb5+:Sb3+ = 85(2):15(2), where 31 Sb5+ is in octahedral coordination substituting for Fe3+ and Sb3+ is in tetrahedral coordination 32 substituting for As5+. Based upon this Sb5+:Sb3+ ratio, the microprobe analyses yielded the 33 empirical formula 3+ 5+ 2+ 5+ 3+ 6+ 34 Pb1.02H1.02(Fe 2.36Sb 0.41Cu 0.27)Σ3.04(As 1.78Sb 0.07S 0.02)Σ1.88O8(OH)6.00. -
Ceramic Mineral Waste-Forms for Nuclear Waste Immobilization
materials Review Ceramic Mineral Waste-Forms for Nuclear Waste Immobilization Albina I. Orlova 1 and Michael I. Ojovan 2,3,* 1 Lobachevsky State University of Nizhny Novgorod, 23 Gagarina av., 603950 Nizhny Novgorod, Russian Federation 2 Department of Radiochemistry, Lomonosov Moscow State University, Moscow 119991, Russia 3 Imperial College London, South Kensington Campus, Exhibition Road, London SW7 2AZ, UK * Correspondence: [email protected] Received: 31 May 2019; Accepted: 12 August 2019; Published: 19 August 2019 Abstract: Crystalline ceramics are intensively investigated as effective materials in various nuclear energy applications, such as inert matrix and accident tolerant fuels and nuclear waste immobilization. This paper presents an analysis of the current status of work in this field of material sciences. We have considered inorganic materials characterized by different structures, including simple oxides with fluorite structure, complex oxides (pyrochlore, murataite, zirconolite, perovskite, hollandite, garnet, crichtonite, freudenbergite, and P-pollucite), simple silicates (zircon/thorite/coffinite, titanite (sphen), britholite), framework silicates (zeolite, pollucite, nepheline /leucite, sodalite, cancrinite, micas structures), phosphates (monazite, xenotime, apatite, kosnarite (NZP), langbeinite, thorium phosphate diphosphate, struvite, meta-ankoleite), and aluminates with a magnetoplumbite structure. These materials can contain in their composition various cations in different combinations and ratios: Li–Cs, Tl, Ag, Be–Ba, Pb, Mn, Co, Ni, Cu, Cd, B, Al, Fe, Ga, Sc, Cr, V, Sb, Nb, Ta, La, Ce, rare-earth elements (REEs), Si, Ti, Zr, Hf, Sn, Bi, Nb, Th, U, Np, Pu, Am and Cm. They can be prepared in the form of powders, including nano-powders, as well as in form of monolith (bulk) ceramics. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
MINERALIZATION in the GOLD HILL MINING DISTRICT, TOOELE COUNTY, UTAH by H
MINERALIZATION IN THE GOLD HILL MINING DISTRICT, TOOELE COUNTY, UTAH by H. M. EI-Shatoury and J. A. Whelan UTAH GEOLOGICAL AND MINERALOGIC~4L SURVEY affiliated with THE COLLEGE OF MINES AND MINERAL INDUSTRIES University of Utah~ Salt Lake City~ Utah Bulletin 83 Price $2.25 March 1970 CONTENTS Page ABSTRACT. • • . • . • . • . • • . • . • . • • • . • • . • . • .. 5 INTRODUCTION 5 GENERAL GEOLOGY. .. 7 ECONOMIC GEOLOGY. 7 Contact Metasomatic Deposits. 11 Veins. • . 11 Quartz-Carbonate-Adularia Veins 11 Quartz Veins . 15 Calcite Veins. 15 Replacement Deposits . 15 Replacement Deposits in the Ochre Mountain Limestone 15 Replacement Deposits in the Quartz Monzonite 17 HYDROTHERMAL ALTERATION. 17 Alteration of Quartz Monzonite. • 17 Alteration of Limestones. 22 Alteration of the Manning Canyon Formation 23 Alteration of the Quartzite. 23 Alteration of Volcanic Rocks. 23 Alteration of Dike Rocks. 23 Alteration of Quartz-Carbonate Veins . 23 OXIDATION OF ORES. 23 Oxidation of the Copper-Lead-Arsenic-Zinc Replacement Deposits 24 Oxidation of Tungsten and Molybdenum Deposits. 24 Oxidation of the Lead-Zinc Deposits 25 MINERALOGY. 25 CONTROLS OF MINERAL LOCALIZATION 25 ZONAL ARRANGEMENT OF ORE DEPOSITS. 25 GENESIS OF ORE DEPOSITS. 29 DESCRIPTION OF PROPERTIES. 29 The Alvarado Mine. 29 The Cane Spring Mine 30 The Bonnemort Mine 32 The Rube Gold Mine . 32 The Frankie Mine 32 The Yellow Hammer Mine 33 The Rube Lead Mine . 34 FUTURE OF THE DISTRICT AND RECOMMENDATIONS. .. 34 ACKNOWLEDGMENTS. .. 36 REFERENCES. • . .. 36 2 ILLUSTRATIONS Page Frontis piece Figure I. Index map showing location and accessibility to the Gold Hill mining district, Utah . 4 2. Geologic map of Rodenhouse Wash area, showing occurrence of berylliferous quartz-carbonate-adularia veins and sample locations. -
Alphab Etical Index
ALPHAB ETICAL INDEX Names of authors are printed in SMALLCAPITALS, subjects in lower-case roman, and localities in italics; book reviews are placed at the end. ABDUL-SAMAD, F. A., THOMAS, J. H., WILLIAMS, P. A., BLASI, A., tetrahedral A1 in alkali feldspar, 465 and SYMES, R. F., lanarkite, 499 BORTNIKOV, N. S., see BRESKOVSKA, V. V., 357 AEGEAN SEA, Santorini I., iron oxide mineralogy, 89 Boulangerite, 360 Aegirine, Scotland, in trachyte, 399 BRAITHWAITE, R. S. W., and COOPER, B. V., childrenite, /~kKERBLOM, G. V., see WILSON, M. R., 233 119 ALDERTON, D. H. M., see RANKIN, A. H., 179 Braunite, mineralogy and genesis, 506 Allanite, Scotland, 445 BRESKOVSKA, V. V., MOZGOVA, N. N., BORTNIKOV, N. S., Aluminosilicate-sodalites, X-ray study, 459 GORSHKOV, A. I., and TSEPIN, A. I., ardaite, 357 Amphibole, microstructures and phase transformations, BROOKS, R. R., see WATTERS, W. A., 510 395; Greenland, 283 BULGARIA, Madjarovo deposit, ardaite, 357 Andradite, in banded iron-formation assemblage, 127 ANGUS, N. S., AND KANARIS-SOTIRIOU, R., autometa- Calcite, atomic arrangement on twin boundaries, 265 somatic gneisses, 411 CANADA, SASKATCHEWAN, uranium occurrences in Cree Anthophyllite, asbestiform, morphology and alteration, Lake Zone, 163 77 CANTERFORD, J. H., see HILL, R. J., 453 Aragonite, atomic arrangements on twin boundaries, Carbonatite, evolution and nomenclature, 13 265 CARPENTER, M. A., amphibole microstructures, 395 Ardaite, Bulgaria, new mineral, 357 Cassiterite, SW England, U content, 211 Arfvedsonite, Scotland, in trachyte, 399 Cebollite, in kimberlite, correction, 274 ARVlN, M., pumpellyite in basic igneous rocks, 427 CHANNEL ISLANDS, Guernsey, meladiorite layers, 301; ASCENSION ISLAND, RE-rich eudialyte, 421 Jersey, wollastonite and epistilbite, 504; mineralization A TKINS, F. -
Evolution of Zincian Malachite Synthesis by Low Temperature Co
Evolution of zincian malachite synthesis by low temperature co- precipitation and its catalytic impact on the methanol synthesis Leon Zwienera, Frank Girgsdiesa, Daniel Brenneckea, Detre Teschnera,b, Albert G.F. Machokeb, Robert Schlögla,b, and Elias Frei*a [a] Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society, Faradayweg 4-6, 14195 Berlin, Germany. [b] Department of Heterogeneous Reactions, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34 – 36, 45470 Mülheim an der Ruhr, Germany. *E-mail: [email protected] Keywords: zincian malachite • co-precipitation • methanol synthesis Abstract: Low temperature co-precipitation enabled, for the first time, the preparation of phase pure zincian malachite precursors with Zn contents of up to 31 at.-%. The high Zn content was beneficial for maximizing the dispersion of Cu and oxygen defect sites on the ZnO surface. Further, an increase of the Zn loading from 10 to 31 at.-% doubled the specific surface areas obtained from N2O-RFC (Reactive Frontal Chromatography) and H2- TA (Transient Adsorption). As the Zn content was increased from 10 to 31 at.-%, the apparent activation energy for methanol formation was strongly decreased. Furthermore, water formation was reduced indicating a retardation of the rWGS in favor of methanol formation at high Zn loadings. Additionally, compared to high temperature co-precipitation, low temperature precipitated catalysts exhibited increased catalytic activities. 1. Introduction Rising global energy demand, relying on the ongoing consumption of fossil fuels, has led to a drastic increase in atmospheric CO2 concentration over the past century.[1] Since CO2 has been attributed to be the main anthropogenic source of the greenhouse effect, CO2 has become a valuable carbon source available for chemical conversion (e.g. -
Anorogenic Alkaline Granites from Northeastern Brazil: Major, Trace, and Rare Earth Elements in Magmatic and Metamorphic Biotite and Na-Ma®C Mineralsq
Journal of Asian Earth Sciences 19 (2001) 375±397 www.elsevier.nl/locate/jseaes Anorogenic alkaline granites from northeastern Brazil: major, trace, and rare earth elements in magmatic and metamorphic biotite and Na-ma®c mineralsq J. Pla Cida,*, L.V.S. Nardia, H. ConceicËaÄob, B. Boninc aCurso de PoÂs-GraduacËaÄo em in GeocieÃncias UFRGS. Campus da Agronomia-Inst. de Geoc., Av. Bento GoncËalves, 9500, 91509-900 CEP RS Brazil bCPGG-PPPG/UFBA. Rua Caetano Moura, 123, Instituto de GeocieÃncias-UFBA, CEP- 40210-350, Salvador-BA Brazil cDepartement des Sciences de la Terre, Laboratoire de PeÂtrographie et Volcanologie-Universite Paris-Sud. Centre d'Orsay, Bat. 504, F-91504, Paris, France Accepted 29 August 2000 Abstract The anorogenic, alkaline silica-oversaturated Serra do Meio suite is located within the Riacho do Pontal fold belt, northeast Brazil. This suite, assumed to be Paleoproterozoic in age, encompasses metaluminous and peralkaline granites which have been deformed during the Neoproterozoic collisional event. Preserved late-magmatic to subsolidus amphiboles belong to the riebeckite±arfvedsonite and riebeckite± winchite solid solutions. Riebeckite±winchite is frequently rimmed by Ti±aegirine. Ti-aegirine cores are strongly enriched in Nb, Y, Hf, and REE, which signi®cantly decrease in concentrations towards the rims. REE patterns of Ti-aegirine are strikingly similar to Ti-pyroxenes from the IlõÂmaussaq peralkaline intrusion. Recrystallisation of mineral assemblages was associated with deformation although some original grains are still preserved. Magmatic annite was converted into magnetite and biotite with lower Fe/(Fe 1 Mg) ratios. Recrystallised amphibole is pure riebeckite. Magmatic Ti±Na-bearing pyroxene was converted to low-Ti aegirine 1 titanite ^ astrophyllite/aenigmatite. -
Aurichalcite (Zn, Cu)5(CO3)2(OH)6 C 2001-2005 Mineral Data Publishing, Version 1
Aurichalcite (Zn, Cu)5(CO3)2(OH)6 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic, pseudo-orthorhombic by twinning. Point Group: 2/m. As acicular to lathlike crystals with prominent {010}, commonly striated k [001], with wedgelike terminations, to 3 cm. Typically in tufted divergent sprays or spherical aggregates, may be in thick crusts; rarely columnar, laminated or granular. Twinning: Observed in X-ray patterns. Physical Properties: Cleavage: On {010} and {100}, perfect. Tenacity: “Fragile”. Hardness = 1–2 D(meas.) = 3.96 D(calc.) = 3.93–3.94 Optical Properties: Transparent to translucent. Color: Pale green, greenish blue, sky-blue; colorless to pale blue, pale green in transmitted light. Luster: Silky to pearly. Optical Class: Biaxial (–). Pleochroism: Weak; X = colorless; Y = Z = blue-green. Orientation: X = b; Y ' a; Z ' c. Dispersion: r< v; strong. α = 1.654–1.661 β = 1.740–1.749 γ = 1.743–1.756 2V(meas.) = Very small. Cell Data: Space Group: P 21/m. a = 13.82(2) b = 6.419(3) c = 5.29(3) β = 101.04(2)◦ Z=2 X-ray Powder Pattern: Mapim´ı,Mexico. 6.78 (10), 2.61 (8), 3.68 (7), 2.89 (4), 2.72 (4), 1.827 (4), 1.656 (4) Chemistry: (1) CO2 16.22 CuO 19.87 ZnO 54.01 CaO 0.36 H2O 9.93 Total 100.39 (1) Utah; corresponds to (Zn3.63Cu1.37)Σ=5.00(CO3)2(OH)6. Occurrence: In the oxidized zones of copper and zinc deposits. Association: Rosasite, smithsonite, hemimorphite, hydrozincite, malachite, azurite. -
Adamsite-(Y), a New Sodium–Yttrium Carbonate Mineral
1457 The Canadian Mineralogist Vol. 38, pp. 1457-1466 (2000) ADAMSITE-(Y), A NEW SODIUM–YTTRIUM CARBONATE MINERAL SPECIES FROM MONT SAINT-HILAIRE, QUEBEC JOEL D. GRICE§ and ROBERT A. GAULT Research Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada ANDREW C. ROBERTS Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario K1A 0E8, Canada MARK A. COOPER Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada ABSTRACT Adamsite-(Y), ideally NaY(CO3)2•6H2O, is a newly identified mineral from the Poudrette quarry, Mont Saint-Hilaire, Quebec. It occurs as groups of colorless to white and pale pink, rarely pale purple, flat, acicular to fibrous crystals. These crystals are up to 2.5 cm in length and form spherical radiating aggregates. Associated minerals include aegirine, albite, analcime, ancylite-(Ce), calcite, catapleiite, dawsonite, donnayite-(Y), elpidite, epididymite, eudialyte, eudidymite, fluorite, franconite, gaidonnayite, galena, genthelvite, gmelinite, gonnardite, horváthite-(Y), kupletskite, leifite, microcline, molybdenite, narsarsukite, natrolite, nenadkevichite, petersenite-(Ce), polylithionite, pyrochlore, quartz, rhodochrosite, rutile, sabinaite, sérandite, siderite, sphalerite, thomasclarkite-(Y), zircon and an unidentified Na–REE carbonate (UK 91). The transparent to translucent mineral has a vitreous to pearly luster and a white streak. It is soft (Mohs hardness 3) and brittle with perfect {001} and good {100} and {010} cleav- ␣  ␥ ° ° ages. Adamsite-(Y) is biaxial positive, = V 1.480(4), = 1.498(2), = 1.571(4), 2Vmeas. = 53(3) , 2Vcalc. = 55 and is nonpleochroic. Optical orientation: X = [001], Y = b, Z a = 14° (in  obtuse). It is triclinic, space group P1,¯ with unit-cell parameters refined from powder data: a 6.262(2), b 13.047(6), c 13.220(5) Å, ␣ 91.17(4),  103.70(4), ␥ 89.99(4)°, V 1049.1(5) Å3 and Z = 4.