Ingredient Disclosure List Liste De Divulgation Des Ingrédients
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Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
United States Patent Office Patented Jan
3,119,666 United States Patent Office Patented Jan. 28, 1964 1. 2 solvent is immaterial, since in practical operation, I re 3,119,666 use the solvent for the reaction after the suspended phos METHOS FOR THE PREPARATION OF phorus pentabromide is removed therefrom by filtration PHOSPHORUS PENTABROMIDE or by centrifuging after the reaction is completed. There Richard C. Nametz, St. Louis, Mich., assignor to fore, upon the first use of the solvent it becomes satu Michigan Chemical Corporation, St. Louis, Mich., a rated with the small amount of phosphorus pentabromide corporation of Michigan which it will dissolve, and will dissolve no more of the No Drawing. Fied Nov. 12, 1957, Ser. No. 695,548 product upon reuse. 12 Claims. (C. 23-205) In this method, I utilize substantially equimolar quan This invention relates to an improved method for the O tities of bromide and of phosphorus tribromide, together production of phosphorus pentabromide. with an amount of the co-solvent for bromine and phos Phosphorus pentabromide (phosphoric bromide) is a phorus tribromide relative to the quantities of the re known compound having a melting point above 100 C., actants used which is within the range which will suspend at which temperature it decomposes to form phosphorus the phosphorus pentabromide as a slurry which can be tribromide with the evolution of bromine. Due to its 5 readily stirred and which at the end of the reaction can heat sensitivity, phosphorus pentabromide cannot be puri be readily filtered, but which does not provide an un wieldly bulk of material to handle. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
The Replaceonetit of Hydi*Oxyl by Bromine
View Article Online / Journal Homepage / Table of Contents for this issue THE REPLACEMENT OF HYDROXYL BY BROMINE. 855 LXXXVIII:.- The ReplaceoneTit of Hydi*oxyl by Bromine. By WILLIAM HENRYPERKIN, jun., and JOHNLIONEL SIREONSEN. Published on 01 January 1905. Downloaded by University of Windsor 26/10/2014 01:06:14. THEmethods available for the preparation of aliphatic compounds in which several atoms of bromine are combined with different carbon atoms are few in number. It is usually assumed that a substance containing one or more hydroxyl groups may be converted into the corresponding bromo-derivatives by treatment with hydrobromic acid, or phosphorus tri- or penta-bromide, but in attempting to use this method in the preparation of bromo-derivatives for the purpose of ring synthesis unexpected difficulties were encountered. The hydroxy -groups in such polyhydric alcohols as glycerol, erythritol, mannitol, ckc., are usually only partially replaced by bromine when these alcohols are treated with hydrobroinic acid, and if, by employing higher temperatures and a large excess of the halogen acid, the attempt is made to complete the substitution, decomposition usually takes place with much charring, and the yield obtained is con- sequently very small. The same remarks apply to the use of the View Article Online 856 PERKIN AND SIMONSEN : bromides of phosphorus in such cases, the results obtained by the action of these reagents on the polyhydric alcohols being frequently most unsatisfactory." In investigating this matter, we found that a great improvement is achieved if the alcohol is first converted into the acetate and the latter is then heated with a solution of hydrogen bromide in glacial acetic acid (saturated at 0") at about 150'. -
Durham E-Theses
Durham E-Theses A spectroscopic study of some halogeno-complexes of tellurium (IV) Gorrell, Ian Barnes How to cite: Gorrell, Ian Barnes (1983) A spectroscopic study of some halogeno-complexes of tellurium (IV), Durham theses, Durham University. Available at Durham E-Theses Online: http://etheses.dur.ac.uk/7890/ Use policy The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that: • a full bibliographic reference is made to the original source • a link is made to the metadata record in Durham E-Theses • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. Please consult the full Durham E-Theses policy for further details. Academic Support Oce, Durham University, University Oce, Old Elvet, Durham DH1 3HP e-mail: [email protected] Tel: +44 0191 334 6107 http://etheses.dur.ac.uk A SPECTROSCOPIC STUDY OF SOME HALOGENO- COMPLEXES OF TELLURIUM (IV) by Ian Barnes Gorrell A thesis submitted in part fulfilment of the requirements for the degree of Master of Science in the University of Durham. The copyright of this thesis rests with the author. April 19 8 3 No quotation from it should be published without his prior written consent and information derived from it should be acknowledged. -5. OFC. 1983 TO MY MOTHER and MY FATHER1 S MEMORY' iii ACKNOWLEDGMENTS I wish to express my gratitude towards the late Professor T.C. -
High Purity Inorganics
High Purity Inorganics www.alfa.com INCLUDING: • Puratronic® High Purity Inorganics • Ultra Dry Anhydrous Materials • REacton® Rare Earth Products www.alfa.com Where Science Meets Service High Purity Inorganics from Alfa Aesar Known worldwide as a leading manufacturer of high purity inorganic compounds, Alfa Aesar produces thousands of distinct materials to exacting standards for research, development and production applications. Custom production and packaging services are part of our regular offering. Our brands are recognized for purity and quality and are backed up by technical and sales teams dedicated to providing the best service. This catalog contains only a selection of our wide range of high purity inorganic materials. Many more products from our full range of over 46,000 items are available in our main catalog or online at www.alfa.com. APPLICATION FOR INORGANICS High Purity Products for Crystal Growth Typically, materials are manufactured to 99.995+% purity levels (metals basis). All materials are manufactured to have suitably low chloride, nitrate, sulfate and water content. Products include: • Lutetium(III) oxide • Niobium(V) oxide • Potassium carbonate • Sodium fluoride • Thulium(III) oxide • Tungsten(VI) oxide About Us GLOBAL INVENTORY The majority of our high purity inorganic compounds and related products are available in research and development quantities from stock. We also supply most products from stock in semi-bulk or bulk quantities. Many are in regular production and are available in bulk for next day shipment. Our experience in manufacturing, sourcing and handling a wide range of products enables us to respond quickly and efficiently to your needs. CUSTOM SYNTHESIS We offer flexible custom manufacturing services with the assurance of quality and confidentiality. -
Durham E-Theses
Durham E-Theses A study of transition metal compounds in liquid hydrogen chloride Symon, David Allen How to cite: Symon, David Allen (1972) A study of transition metal compounds in liquid hydrogen chloride, Durham theses, Durham University. Available at Durham E-Theses Online: http://etheses.dur.ac.uk/9115/ Use policy The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that: • a full bibliographic reference is made to the original source • a link is made to the metadata record in Durham E-Theses • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. Please consult the full Durham E-Theses policy for further details. Academic Support Oce, Durham University, University Oce, Old Elvet, Durham DH1 3HP e-mail: [email protected] Tel: +44 0191 334 6107 http://etheses.dur.ac.uk To Tina INDEX PREFACE i ACKNOWLEDGEMENTS ii SUMMARY iii CHAPTER I INTRODUCTION 1 1.1.1 Non-Aqueous Solvents 1 1.1.2 History 2 1.1.3 Theory of the Solvent 9 1.2 Protonation of neutral transition metal complexes 14 1.2.1 History 14 CHAPTER 2 EXPERIMENTAL TECHNIQUES 18 2.1 The Vacuum System 18 2.2 Apparatus 23 2.3 Inert Atmosphere Glove Box Techniques 29 2.4 Determination of physical properties 30 2.4.1 Infrared spectra 30 2.4.2 '''H Nuclear Magnetic resonance studies 42 2.4.3 Ultra violet/visible spectra 45 2.4.4 -
Hazardous Materials Safety Administration 49 CFR Parts 171, 172, 173, Et Al
Vol. 80 Thursday, No. 5 January 8, 2015 Part II Department of Transportation Pipeline and Hazardous Materials Safety Administration 49 CFR Parts 171, 172, 173, et al. Hazardous Materials: Harmonization With International Standards (RRR); Final Rule VerDate Sep<11>2014 19:02 Jan 07, 2015 Jkt 235001 PO 00000 Frm 00001 Fmt 4717 Sfmt 4717 E:\FR\FM\08JAR2.SGM 08JAR2 mstockstill on DSK4VPTVN1PROD with RULES2 1076 Federal Register / Vol. 80, No. 5 / Thursday, January 8, 2015 / Rules and Regulations DEPARTMENT OF TRANSPORTATION III. Incorporation by Reference Discussion reduces regulatory compliance costs and Under 1 CFR Part 51 helps to avoid costly frustrations of Pipeline and Hazardous Materials IV. Comment Discussion international shipments. PHMSA’s Safety Administration V. Section-by-Section Review continued leadership in maintaining VI. Regulatory Analyses and Notices A. Statutory/Legal Authority for the consistency with international 49 CFR Parts 171, 172, 173, 175, 176, Rulemaking regulations enhances the hazardous 178 and 180 B. Executive Orders 12866 and 13563 and materials safety program and assists in DOT Regulatory Policies and Procedures maintaining a favorable trade balance. [Docket Nos. PHMSA–2013–0260 (HM– C. Executive Order 13132 215M)] D. Executive Order 13175 II. Background E. Regulatory Flexibility Act, Executive RIN 2137–AF05 PHMSA published a notice of Order 13272, and DOT Policies and proposed rulemaking (NPRM) under Procedures Docket HM–215M (79 FR 50741, August Hazardous Materials: Harmonization F. Paperwork Reduction Act With International Standards (RRR) G. Regulatory Identifier Number (RIN) 25, 2014) to incorporate various H. Unfunded Mandates Reform Act amendments to harmonize the HMR AGENCY: Pipeline and Hazardous I. -
Chemical Names and CAS Numbers Final
Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride -
2020 Emergency Response Guidebook
2020 A guidebook intended for use by first responders A guidebook intended for use by first responders during the initial phase of a transportation incident during the initial phase of a transportation incident involving hazardous materials/dangerous goods involving hazardous materials/dangerous goods EMERGENCY RESPONSE GUIDEBOOK THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE HAZARDOUS MATERIALS/ DANGEROUS GOODS REGULATIONS OR 2020 TO CREATE WORKER SAFETY DOCUMENTS EMERGENCY RESPONSE FOR SPECIFIC CHEMICALS GUIDEBOOK NOT FOR SALE This document is intended for distribution free of charge to Public Safety Organizations by the US Department of Transportation and Transport Canada. This copy may not be resold by commercial distributors. https://www.phmsa.dot.gov/hazmat https://www.tc.gc.ca/TDG http://www.sct.gob.mx SHIPPING PAPERS (DOCUMENTS) 24-HOUR EMERGENCY RESPONSE TELEPHONE NUMBERS For the purpose of this guidebook, shipping documents and shipping papers are synonymous. CANADA Shipping papers provide vital information regarding the hazardous materials/dangerous goods to 1. CANUTEC initiate protective actions. A consolidated version of the information found on shipping papers may 1-888-CANUTEC (226-8832) or 613-996-6666 * be found as follows: *666 (STAR 666) cellular (in Canada only) • Road – kept in the cab of a motor vehicle • Rail – kept in possession of a crew member UNITED STATES • Aviation – kept in possession of the pilot or aircraft employees • Marine – kept in a holder on the bridge of a vessel 1. CHEMTREC 1-800-424-9300 Information provided: (in the U.S., Canada and the U.S. Virgin Islands) • 4-digit identification number, UN or NA (go to yellow pages) For calls originating elsewhere: 703-527-3887 * • Proper shipping name (go to blue pages) • Hazard class or division number of material 2. -
Hazardous Substances (Chemicals) Transfer Notice 2006
16551655 OF THURSDAY, 22 JUNE 2006 WELLINGTON: WEDNESDAY, 28 JUNE 2006 — ISSUE NO. 72 ENVIRONMENTAL RISK MANAGEMENT AUTHORITY HAZARDOUS SUBSTANCES (CHEMICALS) TRANSFER NOTICE 2006 PURSUANT TO THE HAZARDOUS SUBSTANCES AND NEW ORGANISMS ACT 1996 1656 NEW ZEALAND GAZETTE, No. 72 28 JUNE 2006 Hazardous Substances and New Organisms Act 1996 Hazardous Substances (Chemicals) Transfer Notice 2006 Pursuant to section 160A of the Hazardous Substances and New Organisms Act 1996 (in this notice referred to as the Act), the Environmental Risk Management Authority gives the following notice. Contents 1 Title 2 Commencement 3 Interpretation 4 Deemed assessment and approval 5 Deemed hazard classification 6 Application of controls and changes to controls 7 Other obligations and restrictions 8 Exposure limits Schedule 1 List of substances to be transferred Schedule 2 Changes to controls Schedule 3 New controls Schedule 4 Transitional controls ______________________________ 1 Title This notice is the Hazardous Substances (Chemicals) Transfer Notice 2006. 2 Commencement This notice comes into force on 1 July 2006. 3 Interpretation In this notice, unless the context otherwise requires,— (a) words and phrases have the meanings given to them in the Act and in regulations made under the Act; and (b) the following words and phrases have the following meanings: 28 JUNE 2006 NEW ZEALAND GAZETTE, No. 72 1657 manufacture has the meaning given to it in the Act, and for the avoidance of doubt includes formulation of other hazardous substances pesticide includes but -
The Fluorosulfuric Acid Solvent System. VI. Solutions of Phosphorus, Arsenic, Bismuth, and Niobium Pentafluorides and Titanium Tetrafluoride
Vol. 8, No. 1, January 1969 THEFLUOROSVLFURIC ACIDSOLVENT SYSTEM 63 enzyme was not created. One particularly active cat- Acknowledgment.-This research was carried out alyst was tested, but the mode of catalysis is not yet under Grant GM 11989 from the National Institutes of understood. Health. CONTRIBUTIONFROM THE DEPARTMEKTOF CHEMISTRY, MCMASTERUNIVERSITY, HAMILTON, OKTARIO, CANADA The Fluorosulfuric Acid Solvent System. VI. Solutions of Phosphorus, Arsenic, Bismuth, and Niobium Pentafluorides and Titanium Tetrafluoride BY R. J. GILLESPIE, K. OUCHI, AND G. P. PEZ Received September 4, 1968 Conductivity measurements on solutions of PFs, AsF5, BiF5, NbF5, PFs-SOa, NbFj-SOa, and AsFg-S03 are reported. Con- ductometric titrations have been carried out on solutions of AsFj, BiF5, and AsF5.SOa. The results are compared with those obtained previously for SbF5 and SbF5-SO3. It is concluded that acid strength increases in the order: PFs - NbF5 < TiF4 - AsFr < BiF6 < AsFd(S03F) < SbF5 < AsFz(SO~F)~< SbFz(S03F)s. It was shown in part 111 of this series that antimony any of them are stronger acids than SbFS. The effect pentafluoride is a rather weak acid of the fluorosulfuric of sulfur trioxide on the acidity of some of the systems acid solvent system ionizing according to the equation was also studied. SbFj + 2HS03F +H[SbFj(SOsF)] + HSOsF Experimental Section HzS03F+ + SbF5(SOsF)- Niobium Pentafluoride.-Technical grade Ozark-Mahoning the acid H [SbF5(S03F)] having a dissociation constant material was purified by triple distillation under vacuum at 100-110”, mp 79-81’. K = 3.7 X 10-3 mol kg-l. Although antimony penta- Bismuth Pentafluoride.-Bismuth trifluoride was fluorinated in fluoride is not fully ionized, these solutions have an ex- a flow system at 500°.4 The crude BiFs was purified by sublima- tremely high acidity because of the rather high concen- tion under vacuum in an apparatus made entirely of Vycor glass tration of the fluorosulfuric acidium ion HzS03F+ and which is not attacked by BiF5 at -100”.