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Chapter 2

Laser

Light Amplification by of Radiation

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Part I How does an object emit light or radiation?

Blackbody Radiation

• Solids heated to very high temperatures emit visible light (glow) – Incandescent Lamps (tungsten filament)

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Blackbody Radiation • The color changes with temperature – At high temperatures emission color is whitish, at lower temperatures color is more reddish, and finally disappear – Radiation is still present, but “invisible” – Can be detected as heat • Heaters; Night Vision Goggles

Electromagnetic Spectrum

visible light

1000 100 10 1 0.1 0.01

0.7 to 0.4 m

 (m)

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Electromagnetic Spectrum

visible light ultraviolet

1000 100 10 1 0.1 0.01

 (m)

Electromagnetic Spectrum

visible infrared light ultraviolet

1000 100 10 1 0.1 0.01

 (m)

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Electromagnetic Spectrum

visible infrared light ultraviolet

1000 100 10 1 0.1 0.01

THz Far IR Mid IR Near IR  (m)

Electromagnetic Spectrum

visible microwaves infrared light ultraviolet x-rays

1000 100 10 1 0.1 0.01

 (m)

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Electromagnetic Spectrum

visible microwaves infrared light ultraviolet x-rays

1000 100 10 1 0.1 0.01

Low High Energy Energy  (m)

Kirchoff’s Question (1859) Radiant Energy and Matter in Equilibrium What is the thermal radiation of a bodies that emit and absorb heat radiation, in an opaque enclosure or cavity, in equilibrium at temperature T?

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Observation

• All object at finite temperatures radiate electromagnetic waves (emit radiation) • Objects emit a spectrum of radiation depending on their temperature and composition • From classical point of view, thermal radiation originates from accelerated charged particles in the atoms near surface of the object

Ideal System to Study Thermal Radiation: Blackbody

– A blackbody is an object that absorbs all radiation incident upon it – Its emission is universal, i.e. independent of the nature of the object – Blackbodies radiate, but do not reflect and so are black

Blackbody Radiation is EM radiation emitted by blackbodies

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Blackbody Radiation • There are no absolutely blackbodies in nature – this is idealization • But some objects closely mimic blackbodies: – Carbon black or Soot (reflection is <<1%) • The closest objects to the ideal blackbody is a cavity with small hole (and the universe shortly after the big bang)

– Entering radiation has little chance of escaping, and mostly absorbed by the walls. Thus the hole does not reflect incident radiation and behaves like an ideal absorber, and “looks black”

Kirchoff's Law of Thermal Radiation (1859)

• Absorptivity αλ is the ratio of the energy absorbed by the wall to the energy incident on the wall, for a particular wavelength.

• The emissivity of the wall ελ is defined as the ratio of emitted energy to the amount that would be radiated if the wall were a perfect black body at that wavelength. • At thermal equilibrium, the emissivity of a body (or surface) equals its absorptivity

αλ = ελ • If this equality were not obeyed, an object could never reach thermal equilibrium. It would either be heating up or cooling down.

• For a blackbody ελ = 1 • Therefore, to keep your frank warm or your ice cream cold at a baseball game, wrap it in aluminum foil

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Blackbody Radiation Spectra

Blackbody Radiation Laws • Emission is continuous

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Blackbody Radiation Laws Stefan-Boltzmann Law

• The total emitted energy increases with temperature, and

represents, the total intensity (Itotal) – the energy per unit time per unit area or power per unit area – of the blackbody emission at given temperature, T.

4 Itotal  T

– σ = 5.670×10-8 W/m2-K4

• To get the emission power, multiply Intensity Itotal by area A

Blackbody Radiation Laws • The maximum shifts to shorter wavelengths with increasing temperature – the color of heated body changes from red to orange to yellow-white with increasing temperature

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Blackbody Radiation Laws Wien’s Displacement Law

• The wavelength of maximum intensity per unit wavelength is defined by the

max  T  b – b = 2.898×10-3 m/K is a constant • For, T ~ 6000 K,

2.898103    483 nm max 6000

Nobel 1911

Blackbody Radiation Spectra

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How to understand Blackbody radiation from fundamental physical principle?

The Birth of Quantum Mechanics

Classic Physics View

• Radiation is caused by EM wave radiation

• Consider a cavity at temperature T whose walls are considered as perfect reflectors

• The cavity supports many modes of oscillation of the EM field caused by accelerated charges in the cavity walls, resulting in the emission of EM waves at all wavelength

• They are considered to be a series of standing EM wave set up within the cavity

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Classic Physics View

• Radiation is caused by EM wave radiation • Average energy of a harmonic oscillator is

• Intensity of EM radiation emitted by classical harmonic oscillators at wavelength λ per unit wavelength: 2 I(,T)  E c 3 • Or per unit frequency ν: 2 2 I( ,T)  E c3

Classic Physics View

• In classical physics, the energy of an oscillator is continuous, so the average is calculated as: E    kBT  EP(E)dE  EP0e dE 0 0 E    E  kBT   P(E)dE kBT   P0e dE 0 0

E  kBT is the Boltzmann distribution P(E)  P0e

E  kBT

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Classic Physics View

• This gives the Rayleigh-Jeans Law

2 E 2 k T 2 2 2 2 I(,T)   B , I( ,T)  E  k T c  3 c  3 c3 c2 B

Agrees well with experiment long wavelength (low frequency) region

Classic Physics View

• Predicts infinite intensity at very short wavelengths (higher frequencies) – “Ultraviolet Catastrophe”

• Predicts diverging total emission by black bodies

No “fixes” could be found using classical physics

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Planck’s Hypothesis Max Planck postulated that A system undergoing simple harmonic motion with frequency ν can only have energies E  n  nh

where n = 1, 2, 3,… and h is Planck’s constant h = 6.63×10-34 J-s 1918 Nobel

Planck’s Theory E  nh E  (n 1)h  nh  h E is a quantum of energy

For  = 3kHz E  h E  6.631034 J  s 3000s1  21030 J

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Planck’s Theory • 2 2 As before: I (  , T )  E c3 • Now energy levels are discrete, En  nh  n   h

n  kBT P0e • So P( En )  n   k T B n P0e    k T n0 E P e B  n 0 n0  E  n   • Sum to obtain average energy:   k T k T P e B e B 1  0 n0

2 2  2 2 h Thus I (  , T )   c3  c3 h e kBT 1 e kBT 1

Blackbody Radiation Formula

2 2 h I( )  c2  h  exp  1 kBT 

c is the speed of light, kB is Boltzmann’s constant, h is Planck’s constant, and T is the temperature

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Blackbody Radiation from the Sun Plank’s curve Stefan-Boltzmann Law I  T4 λ BB max 4 IBB = T

Stefan-Boltzmann constant  =5.67×10-8 J/m2K4 More generally: I = T4  is the emissivity

Wien's Displacement Law -3 peak T = 2.898×10 m K

At T = 5778 K: -7 peak = 5.015×10 m = 5,015 A

• Cosmic microwave background (CMBR) as perfect black body radiation 1965, cosmic microwave background was first detected by Penzias and Wilson

Nobel Prize 1976

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The Nobel Prize in Physics 2006 • "for their discovery of the blackbody form and anisotropy of the cosmic microwave background radiation"

John C. George F. Mather Smoot

Part II

Stimulated Emission

How is light generated from an atomic point of view?

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Mechanisms of Light Emission

For atomic systems in thermal equilibrium with their surrounding, the emission of light is the result of:  Absorption

E2

E = hv

E1

Mechanisms of Light Emission

For atomic systems in thermal equilibrium with their surrounding, the emission of light is the result of:  Absorption  And subsequently, spontaneous emission of energy

E2 Phase and propagation direction of created photon is random.

E1

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Mechanisms of Light Emission For atomic systems in thermal equilibrium with their surrounding, the emission of light is the result of:  Absorption  And subsequently, spontaneous emission of energy  Stimulated emission

E Created photon 2 has the same phase, frequency, polarization, and propagation direction as the E 1 input photon.

Stimulated Emission

• It is pointed out by Einstein that: Atoms in an excited state can be stimulated to jump to a lower energy level when they are struck by a photon of incident light whose energy is the same as the energy-level difference involved in the jump. The electron thus emits a photon of the same wavelength as the incident photon. The incident and emitted photons travel away from the atom in phase. • This process is called stimulated emission.

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Population of Energy Levels

How many atoms are in the ground states? And how many are in the excited states?

E1 E2 Excited electron

Unexcited electron

Population of Energy Levels

Maxwell-Boltzmann distribution

Excited electron

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Rate Equation of Absorption and Emission

For absorbance, the # of E1 atoms decrease after absorption

absorption

h E

Rate Equation of Absorption and Emission

For emission, the # of E1 atoms increase

emission

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Rate Equation of Absorption and Emission

For stimulated, the # of E1 atoms increase after absorption

Stimulated emission

Rate Equation of Absorption and Emission

By considering all 3 processes, the change rate of # of E1 atoms becomes

absorption emission Stimulated emission

h E

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Rate Equation of Absorption and Emission

If the system is under equilibrium (blackbody), then

Rate Equation of Absorption and Emission

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Rate Equation of Absorption and Emission

I needs to approach to infinite when T approaches infinite, which implies

Rate Equation of Absorption and Emission

Compared to Plank’s formula,

For a visible light, v ~ 1014 Hz, A/B ~ 10-16

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Part III

The

Population Inversion

In order to obtain the coherent light from stimulated emission:

퐵푁2퐼 ≫ 퐵푁1퐼 + 퐴푁2

<<1

Thus:

푁2 ≫ 푁1

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Population Inversion In order to obtain the coherent light from stimulated emission, two conditions must be satisfied:

E 1. The atoms must be excited to the higher state. That is, an inverted population is needed, one in which more atoms are in the upper state than in the lower one, so that emission of photons will dominate over absorption.

Population Inversion In order to obtain the coherent light from stimulated emission, two conditions must be satisfied: 2. The higher state must be a metastable state – a state in which the electrons remain longer than usual so that the transition to the lower state occurs by stimulated emission rather than spontaneously.

E3 E3

Metastable state E2 E2 Incident photon

Photon of energyE 2  E1

E1 E1Emitted photon Metastable system Stimulated emission

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Four Key Elements of a LASER

- Gain medium (Active medium) - Pumping source relaxation - Cavity (Resonator) - pumping laser

relaxation

cavity (resonator)

gain medium Laser light

total output reflector coupler pumping source

Lasing Process

Population Inversion

Mirror Mirror

E f

Ei

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Lasing Process

Spontaneous emission Mirror Mirror

E f

Ei

Lasing Process

Stimulated emission Mirror Mirror

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Lasing Process

Feed-back by the cavity

Mirror Mirror

E f

Ei

Lasing Process

Stimulated emission Mirror Mirror

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Lasing Process

Feed-back by the cavity Mirror Mirror

E f

Ei

Lasing Process After several round trips/many pumps… Mirror Mirror

Laser beam Photons with: - same energy : Monochromatic - same direction of propagation : Spatial coherence - all in synchrony: Temporal coherence

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An Amplification and Cascade Process

During the entire process, the population must be kept inversed, i.e., the amplification media should be pumped all the time, either pulsed or continuously.

An Amplification and Cascade Process

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Laser Construction

Amplifying Medium

Laser Construction

• Atoms: - (HeNe) laser; heliumcadmium (HeCd) laser, copper vapor (CVL)

• Molecules: (CO2) laser, ArF and KrF excimer lasers, N2 laser

• Liquids: organic dye molecules dilutely dissolved in various solvent solutions

• Dielectric solids: neodymium atoms doped in YAG or glass to make the crystalline Nd:YAG or Nd:glass lasers

• Semiconductor materials: gallium arsenide, indium phosphide crystals.

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Homework

Please find out the principles of the following lasers from internet or books, and in your first lab report, i.e., “Lab #1” report, please add an “Appendix” section to describe the principle of one of the following lasers, with at least two figures, the construction of the laser and energy lever diagram, you have to describe these figures and the laser operation principle:

(1) Helium-neon (HeNe) laser (2) laser (3) (4) Semiconductor laser

Resonance Cavities and Longitudinal Modes

Since the wavelengths involved with lasers spread over small ranges, and are also absolutely small, most cavities will achieve lengthwise resonance

L = nλ/2 Plane Hemifocal parallel f resonator resonator c Concentric c Hemispheric resonator al resonator

f Confocal Unstable resonator resonator

c: center of curvature, f: focal point

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Resonance Cavities and Longitudinal Modes

Fabry-Perot boundary conditions

Multiple resonant frequencies

Resonance Cavities and Longitudinal Modes

node

antinode

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Resonance Cavities and Longitudinal Modes Multi-mode laser

Resonance Cavities and Transverse Modes

TEM 00 TEM 10 Gauss

TEM 01 TEM 11 - Hermite Moden

TEM 02 TEM 21

TEM 03 TEM 31

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Gaussian Beams • Zero order mode is Gaussian • Intensity profile: 2r 2 / w2 I  I0e

Gaussian Beams • intensity

• Beam waist: w 2 0 푤 = 푤0 1 + (푧/푧0)

2 • Confocal parameter 푘푤0 푧0 = (Rayleigh range): Z0 2

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Gaussian Beams 2푧 • Far from waist 푤 ≈ 푘푤0

• Divergence angle 푤 4 2휆  휃 ≈ 2 = =  0.637 푧 푘푤0 휋푛푤0 w0

Spread angle :

 / 2   /nw0

2w w 0 I 0 z0 z

Gaussian z  0 profile

Near field Far field (~ plane wave) (~ spherical wave)

Power Distribution in Gaussian

2r 2 / w2 • Intensity distribution: I  I0e • Experimentally to measure full width at half maximum (FWHM) diameter

• Relation is dFWHM = w 2 ln2 ~ 1.4 w • Define average intensity 2 Iavg = 4 P / (p d FWHM) • Overestimates peak:

I0 = Iavg/1.4

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Propagation of Gaussian Beam - ABCD law

Propagation of Gaussian Beam - ABCD law

Matrix method (Ray optics)

a o yo Optical Elements ai Optical axis yi

 y  A B y  푦표 = 퐴푦푖 + 퐵훼푖 o  i      훼 = 퐶푦 + 퐷훼 ao  C Dai  표 푖 푖

A B   : ray-transfer matrix C D

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Ray Transfer Matrices

Free space propagation 훼표

푦표 훼 푦푖 푖

(paraxial ray approximation)

푦표 = 푦푖 + 푑훼푖

훼표 = 훼푖

 yo  1 d   yi          ao  0 1  ai 

Ray Transfer Matrices Propagation through curved refracting surface

n1 yi yo n2

ai h ao

s R S’

푛1 푛2 푛2 − 푛1 푛1 푛1 푦푖 + = 훼표 = 훼푖 + (1 − ) 푦푖 = 푦표 = ℎ 푠 푠′ 푅 푛2 푛2 푅

 1 0   yo     yi      n1  n2 n1         ao  ai   n2R n2 

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Ray Transfer Matrices

Ray Transfer Matrices

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ABCD Law for Gaussian Beam

 yo  A B yi  yo  Ayi  Bai       ao  C Dai  ao  Cyi  Dai

yo Ayi  Bai Ro   ao Cyi  Dai

Ay /a  B  i i Cyi /ai  D

AR  B  i CRi  D

ABCD Law for Gaussian Beam

Ro (ray optics)  q (Gaussian optics)

optical system ABCD law for Gaussian beam :  A B    q  z  iz0   Aq1  B C D q  nw 2 2 z  0 Cq1  D 0  q1 q2

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ABCD Law for Gaussian Beam Focusing a Gaussian beam

w 01 w02 ? 1

z1 z2 ?

 A B  1 z2  1 01 z1         C D 0 1 1/ f 10 1 

1 z2 / f z1  z2  z1z2 / f      1/ f 1 z1 / f 

(1 z2 / f )q1  (z1  z2  z1z2 / f )  q2   q1 / f  (1 z1 / f )

ABCD Law for Gaussian Beam

2 2 1 1  z  1 w   1 1   01 2 2   2   w02 w01  f  f    f 2 (z  f ) z  f  1 ( f ) 2 2 2 2 (z1  f )  (w01 / ) f - If a strong positive lens is used ; w01  w02 => w02   f1 w01 2 f 2 f N : f-number => w02   , f N  f / d  (2w01)  ; The smaller the f# fo the lens, the smaller the beam waist at the focused spot.

2 2 - If w01 /   (z1  f ) => z2  f

Note) To satisfy this condition, the beam is expanded before being focused.

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