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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Sugilite in Manganese Silicate Rocks from the Hoskins Mine and Woods Mine, New South Wales, Australia
Sugilite in manganese silicate rocks from the Hoskins mine and Woods mine, New South Wales, Australia Y. KAWACHI Geology Department, University of Otago, P.O.Box 56, Dunedin, New Zealand P. M. ASHLEY Department of Geology and Geophysics, University of New England, Armidale, NSW 2351, Australia D. VINCE 1A Ramsay Street, Essendon, Victoria 3040, Australia AND M. GOODWIN P.O.Bo• 314, Lightning Ridge, NSW 2834, Australia Abstract Sugilite relatively rich in manganese has been found at two new localities, the Hoskins and Woods mines in New South Wales, Australia. The occurrences are in manganese-rich silicate rocks of middle to upper greenschist facies (Hoskins mine) and hornblende hornfels facies (Woods mine). Coexisting minerals are members of the namansilite-aegirine and pectolite-serandite series, Mn-rich alkali amphiboles, alkali feldspar, braunite, rhodonite, tephroite, albite, microcline, norrishite, witherite, manganoan calcite, quartz, and several unidentified minerals. Woods mine sugilite is colour-zoned with pale mauve cores and colourless rims, whereas Hoskins mine sugilite is only weakly colour-zoned and pink to mauve. Within single samples, the chemical compositions of sugilite from both localities show wide ranges in A1 contents and less variable ranges of Fe and Mn, similar to trends in sugilite from other localities. The refractive indices and cell dimensions tend to show systematic increases progressing from Al-rich to Fe- Mn-rich. The formation of the sugilite is controlled by the high alkali (especially Li) and manganese contents of the country rock, reflected in the occurrences of coexisting high alkali- and manganese- bearing minerals, and by high fo2 conditions. KEYWORDS: sugilite, manganese silicate rocks, milarite group, New South Wales, Australia Introduction Na2K(Fe 3 +,Mn 3 +,Al)2Li3Sit2030. -
Zincite (Zn, Mn2+)O
Zincite (Zn, Mn2+)O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 6mm. Crystals rare, typically pyramidal, hemimorphic, with large {0001}, to 2.5 cm, rarely curved; in broad cleavages, foliated, granular, compact, massive. Twinning: On {0001}, with composition plane {0001}. Physical Properties: Cleavage: {1010}, perfect; parting on {0001}, commonly distinct. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 4 VHN = 205–221 (100 g load). D(meas.) = 5.66(2) D(calc.) = 5.6730 Rare pale yellow fluorescence under LW UV. Optical Properties: Translucent, transparent in thin fragments. Color: Yellow-orange to deep red, rarely yellow, green, colorless; deep red to yellow in transmitted light; light rose-brown in reflected light, with strong red to yellow internal reflections. Streak: Yellow-orange. Luster: Subadamantine to resinous. Optical Class: Uniaxial (+). ω = 2.013 = 2.029 R1–R2: (400) 13.0–13.6, (420) 12.8–13.2, (440) 12.6–12.8, (460) 12.3–12.6, (480) 12.1–12.4, (500) 12.0–12.2, (520) 11.8–12.1, (540) 11.8–12.0, (560) 11.7–11.9, (580) 11.6–11.8, (600) 11.4–11.7, (620) 11.3–11.6, (640) 11.2–11.5, (660) 11.1–11.4, (680) 11.0–11.2, (700) 11.0–11.2 Cell Data: Space Group: P 63mc (synthetic). a = 3.24992(5) c = 5.20658(8) Z = 2 X-ray Powder Pattern: Synthetic. 2.476 (100), 2.816 (71), 2.602 (56), 1.626 (40), 1.477 (35), 1.911 (29), 1.379 (28) Chemistry: (1) (2) SiO2 0.08 FeO 0.01 0.23 MnO 0.27 0.29 ZnO 99.63 98.88 Total 99.99 [99.40] (1) Sterling Hill, New Jersey, USA. -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
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American Mineralogist, Volume 70, pages 379-387, 1985 Ma_nganesehumites and leucophoenicitesfrom Franklin and Sterling- Hill' NewJersev: 'i"? andimplications ;ifi':il1,;;lfiil11"r's' Perr J. Dullx Department of Mineral Sciences Smithsonian lnstitution, Washington, D. C. 20560 Abstract The manganesehumites, (alleghanyite, manganhumite, and sonolite),together with some Mn-bearing samplesof the Mg-humites,and the related phasesleucophoenicite and jerry- gibbsite,from the orebodiesat Franklin and SterlingHill, New Jersey,are describedtogether with analytical data. Solid solution betweenhumite and manganhumiteis at least partially continuous. Expected Mn/Mg solid solutions between alleghanyiteand chondrodite, and betweensonolite and clinohumite, are discontinuous; they are interrupted by apparently orderedphases. In all cases,the possibleorderings involve Zn as well as Mn and Mg. There are no Mn end-membersof the manganesehumites at this locality. Manganeseis apparently restricted in leucophoenicite(5.42-6.63 Mn per 7 octahedral cations) and in jerrygibbsite (7.79-8.02Mn per 9 octahedralcations). Calcium is common to both leucophoeniciteand jerrygibbsite,but among the Mn-humites,only sonoliteaccepts appreciable Ca (0.65Ca per 9 octahedralcations). There is a "threshold" level ofzinc in all studiedsamples; this "threshold" levelis a constantfor leucophoenicite1-9.3 Znper 3 Si)and alleghanyite(-O.2Zn per 2 Si). No samplesof leucophoeniciteor jerrygibbsite were found to be Zn-ftee,suggesting either that Zn is required for their stability, or that these two phasesmight not be stable as end-members.Fluorine is present in all the Mn-humites and is proportional to the Mg- content,but is absentin leucophoeniciteand jerrygibbsite. Introduction humite speciesoccur there; the Mg-humites occur in the The magnesiumhumite species(norbergite, chondrodite, host Franklin Marble for the most part, and the Mn- humite, and clinohumite) have been well-studiedand re- humites in the orebodiesthemselves. -
The Seven Crystal Systems
Learning Series: Basic Rockhound Knowledge The Seven Crystal Systems The seven crystal systems are a method of classifying crystals according to their atomic lattice or structure. The atomic lattice is a three dimensional network of atoms that are arranged in a symmetrical pattern. The shape of the lattice determines not only which crystal system the stone belongs to, but all of its physical properties and appearance. In some crystal healing practices the axial symmetry of a crystal is believed to directly influence its metaphysical properties. For example crystals in the Cubic System are believed to be grounding, because the cube is a symbol of the element Earth. There are seven crystal systems or groups, each of which has a distinct atomic lattice. Here we have outlined the basic atomic structure of the seven systems, along with some common examples of each system. Cubic System Also known as the isometric system. All three axes are of equal length and intersect at right angles. Based on a square inner structure. Crystal shapes include: Cube (diamond, fluorite, pyrite) Octahedron (diamond, fluorite, magnetite) Rhombic dodecahedron (garnet, lapis lazuli rarely crystallises) Icosi-tetrahedron (pyrite, sphalerite) Hexacisochedron (pyrite) Common Cubic Crystals: Diamond Fluorite Garnet Spinel Gold Pyrite Silver Tetragonal System Two axes are of equal length and are in the same plane, the main axis is either longer or shorter, and all three intersect at right angles. Based on a rectangular inner structure. Crystal shapes include: Four-sided prisms and pyramids Trapezohedrons Eight-sided and double pyramids Icosi-tetrahedron (pyrite, sphalerite) Hexacisochedron (pyrite) Common Tetragonal Crystals: Anatase Apophyllite Chalcopyrite Rutile Scapolite Scheelite Wulfenite Zircon Hexagonal System Three out of the four axes are in one plane, of the same length, and intersect each other at angles of 60 degrees. -
Leucophoenicite Mn (Sio4)3(OH)2
2+ Leucophoenicite Mn7 (SiO4)3(OH)2 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals rare, typically slender, prismatic, elongated and striated [010], to 8 mm; in isolated grains or granular massive. Twinning: On k 001 , common, contact or interpenetrant twins, lamellar. f g Physical Properties: Cleavage: 001 , imperfect. Tenacity: Brittle. Hardness = 5.5{6 f g D(meas.) = 3.848 D(calc.) = [4.01] Optical Properties: Transparent to translucent. Color: Brown to light purple-red, raspberry-red, deep pink to light pink; rose-red to colorless in thin section. Luster: Vitreous. Optical Class: Biaxial ({). Pleochroism: Faint; rose-red 001 ; colorless 001 . Orientation: k f g ? f g X 001 cleavage. Dispersion: r > v; slight. ® = 1.751(3) ¯ = 1.771(3) ° = 1.782(3) ? f g 2V(meas.) = 74(5)± Cell Data: Space Group: P 21=a: a = 10.842(19) b = 4.826(6) c = 11.324(9) ¯ = 103:93(9)± Z = [2] X-ray Powder Pattern: Franklin, New Jersey, USA. 1.8063 (10), 2.877 (9), 2.684 (8), 4.36 (5), 3.612 (5), 2.365 (5), 2.620 (4) Chemistry: (1) (2) (3) (1) (2) (3) SiO2 26.36 26.7 26.7 CaO 5.67 2.4 2.8 FeO trace 0.3 0.3 Na2O 0.39 MnO 60.63 62.8 64.7 K2O 0.24 ZnO 3.87 0.0 0.0 H2O 2.64 [2.3] [2.8] MgO 0.21 5.5 2.7 Total 100.01 [100.0] [100.0] (1) Franklin, New Jersey, USA; composite of two analyses, corresponding to (Mn5:89Ca0:70Zn0:32 Na0:04Mg0:03K0:01)§=6:99(Si1:01O4)3(OH)2: (2) Kombat mine, Namibia; by electron microprobe, H2O by di®erence; corresponding to (Mn5:98Mg0:92Ca0:29Fe0:02)§=7:21(SiO4)3(OH)1:72: (3) Valsesia-Valtournanche area, Italy; by electron microprobe, H2O by di®erence; corresponding to (Mn6:16Mg0:45Ca0:34Fe0:03)§=6:98(SiO4)3(OH)2:10: Mineral Group: Leucophoenicite group. -
TEPHROITE from FRANKLIN, NEW JERSEY* Connbrrus S. Hunrsur
THE AMERICAN MINERALOGIST, VOL 46, MAY_JUNE, 1961 TEPHROITE FROM FRANKLIN, NEW JERSEY* ConNBrrus S. Hunrsur, Jn., Departmentof Mineralogy, Harvard, Uniaersity. Assrnlcr A study of tephroite specimens from Franklin and Sterling Hill, New Jersey showed in all of them the presence of thin sheets of willemite believed to be a product of exsolution. .fhese sheets are oriented parallel to the {100} and [010] planes of tephroite with the o and r axes of tephroite and willemite parallel. It is believed that Iittle zinc remains in the tephroite structure and that much of it reported in chemical analyses has been con- tributed by intergrown u'illemite. This conclusion is supported by experiments syn- thesizing tephroite. The indices of refraction and d spacing of {130} vary as would be expected with changes in amounts of MgO, FeO and CaO. INrnooucrroN 'fephroite, Mn2SiO4,a member of the olivine group, was describedas a new mineral from SterlingHill by Breithaupt in 1823.A chemicalanal- ysis of the original material was published by Brush (1864) together with severaladditional chemical analysesof tephroite made by others. These analysesreport ZnO in varying amounts which Brush attributed to invariably associatedzincite. Palache (1937) did not agree with Brush and stated " . that the molecularratios in someanalyses more nearly satisfy the orthosilicateformula when zinc is regardedas essen- tially a part of the mineral rather than as a constituent of mechanical inclusions." The present study was undertaken for the purpose of in- vestigatingthe variations in the propertiesof tephroite with changesin chemical composition, particularly the effect of zinc. Relationships were not expectedto be simplefor analysesshow, in addition to ZnO, variable amounts of MgO, FeO, and CaO. -
POUDRETTEITE, Knarb3si12o3e, a NEW MEMBER of the OSUMILITE GROUP from MONT SAINT-HILAIRE, OUEBEC, and ITS CRVSTAL STRUCTURE Assr
Canadian Mineralogist Vol. 25, pp.763-166(1987) POUDRETTEITE,KNarB3Si12O3e, A NEW MEMBEROF THE OSUMILITEGROUP FROM MONT SAINT-HILAIRE,OUEBEC, AND ITS CRVSTALSTRUCTURE JOEL D. GRICE, T. SCOTT ERCIT AND JERRY VAN VELTHUIZEN Mineral SciencesDivision, National Museumof Natural Sciences,Ottawa, Ontario KIA 0M8 PETE J. DUNN Departmentof Mineral Sciences,Smithsonian Institution, Washington,D.C, 20560,U,S.A. Assrnact positionC d coordinanceXII, le sodium,la position,4d unecoordinance VI, le bore,la position72 ir coordinance Poudretteiteis a newmineral species from the Poudrette IV, le silicium,la position71 i coordinanceIV, etla posi- quarry, Mont Saint-Hilaire,Quebec. It occursin a marble tion B estvacante. xenolith includedin nephelinesyenite, associated with pec- tolite, apophyllite, quartz and minor aegirine.It forms clear, Mots-clds: poudrettdite, nouvelle espbce min6rale, groupe colorlessto very pale pink, equidimensional,subhedral del'osumilite, mont Saint-Hilaire, borosilicate, affi ne. prismsup to 5 mm. It is brittle, H about 5, with a splin- mentde Ia structure. tery fracture;Dmetr. 2.51(l) g/cml, D"6".2.53 g/cm3. Uniaxialpositive, co 1.516(l), e 1.532(l).It is-hexagonal, spacegroup P6/ mcc, a I 0.239(l), c 13.485(3)A and,Z : 2. INTRoDUcTIoN The strongestten X-ray-diffractionlines in the powderpat- tern [d in A(r\(hkDl are: 6.74(30)(002),5.13 (100)(110), The optical and physical propertiesof members 4.07(30)(r 12), 3.70(30)(202), 3.3 6e(30)(004), 3.253 ( I 00) of the osumilite group are similar to those of com- (2r r), 2.9s6(40)(3 00), 2.8 I 5(60)(I I 4), 2.686(50)(213,204) mon mineralssuch as quartz and cordierite;for this and 2.013(30)(321).An analysisby electron microprobe reason, they are probably generally overlooked. -
Useful Primitive Radio Detector Minerals H.P
Sheet1 Useful Primitive Radio Detector Minerals H.P. Friedichs, AC7ZL Chemical Chemical Crystal PW Eccles Toricata Morgan Mineral Composition Formula Category Suitable Contacts (1925) (1928) (1910) (1913) Allemontite Arsenic antimonide AsSb Antimonide x Anatase Titanium dioxide TiO2 Oxide Metals and Zincite x x Antimony Element Sb Element Zincite, silicon, etc. x Argentite (silver glance) Silver sulfide Ag2S Sulfide Metals, graphite, tellurium x Arkansite See Anatase x Arsenic Element As Element Metals and Zincite x x x Arsenic pyrites See Mispickel x Bornite (peacock Sulfide of copper and ore) iron Cu5FeS4 Sulfide Zincite, silicon, etc. x x x x Boron Element B Element Zincite, tellurium x x Sulfide of antimony Boulangerite and lead Pb5Sb4S11 Sulfosalt x Sulfide of copper, Zincite, tellurium, Bourmonite antimony and lead PbCuSbS3 Sulfosalt antimony, bismuth x Brookite See Anatase x x Carborundum Silicon Carbide SiC Steel, zincite x Zincite (this combination is Sulfide of iron and the famous Perikon Chalcopyrite copper CuFeS2 Sulfide detector) x x x Cobaltite Cobalt arsenic sulfide CoAsS Zincite x x Cassiterite Tin Oxide SnO2 Oxide Metals x x Cerussite Lead Carbonate PbCo3 Carbonate ?x Chalcocite (copper glance) Copper sulfide Cu2S Sulfide Zincite, tellurium x x x Zincite (this combination is Sulfide of iron and the famous Perikon Copper pyrites copper CuFeS2 Sulfide detector) x x Corundum Aluminum oxidde Al2O3 Oxide Zincite, bornite x Page 1 Sheet1 Covellite Copper sulfide CuS Sulfide Zincite, etc x x Cuprite (Cuprous oxide) Copper oxide -
Guide to Healing Uses of Crystals & Minerals
Guide to Healing Uses of Crystals & Minerals Addiction- Iolite, amethyst, hematite, blue chalcedony, staurolite. Attraction – Lodestone, cinnabar, tangerine quartz, jasper, glass opal, silver topaz. Connection with Animals – Leopard skin Jasper, Dalmatian jasper, silver topaz, green tourmaline, stilbite, rainforest jasper. Calming – Aqua aura quartz, rose quartz, amazonite, blue lace agate, smokey quartz, snowflake obsidian, aqua blue obsidian, blue quartz, blizzard stone, blood stone, agate, amethyst, malachite, pink tourmaline, selenite, mangano calcite, aquamarine, blue kyanite, white howlite, magnesite, tiger eye, turquonite, tangerine quartz, jasper, bismuth, glass opal, blue onyx, larimar, charoite, leopard skin jasper, pink opal, lithium quartz, rutilated quartz, tiger iron. Career Success – Aqua aura quartz, ametrine, bloodstone, carnelian, chrysoprase, cinnabar, citrine, green aventurine, fuchsite, green tourmaline, glass opal, silver topaz, tiger iron. Communication – Apatite, aqua aura quartz, blizzard stone, blue calcite, blue kyanite, blue quartz, green quartz, larimar, moss agate, opalite, pink tourmaline, smokey quartz, silver topaz, septarian, rainforest jasper. www.celestialearthminerals.com Creativity – Ametrine, azurite, agatized coral, chiastolite, chrysocolla, black amethyst, carnelian, fluorite, green aventurine, fire agate, moonstone, celestite, black obsidian, sodalite, cat’s eye, larimar, rhodochrosite, magnesite, orange calcite, ruby, pink opal, blue chalcedony, abalone shell, silver topaz, green tourmaline, -
Mineral Index
Mineral Index Abhurite T.73, T.355 Anandite-Zlvl, T.116, T.455 Actinolite T.115, T.475 Anandite-20r T.116, T.45S Adamite T.73,T.405, T.60S Ancylite-(Ce) T.74,T.35S Adelite T.115, T.40S Andalusite (VoU, T.52,T.22S), T.27S, T.60S Aegirine T.73, T.30S Andesine (VoU, T.58, T.22S), T.41S Aenigmatite T.115, T.46S Andorite T.74, T.31S Aerugite (VoU, T.64, T.22S), T.34S Andradite T.74, T.36S Agrellite T.115, T.47S Andremeyerite T.116, T.41S Aikinite T.73,T.27S, T.60S Andrewsite T.116, T.465 Akatoreite T.73, T.54S, T.615 Angelellite T.74,T.59S Akermanite T.73, T.33S Ankerite T.74,T.305 Aktashite T.73, T.36S Annite T.146, T.44S Albite T.73,T.30S, T.60S Anorthite T.74,T.415 Aleksite T.73, T.35S Anorthoclase T.74,T.30S, T.60S Alforsite T.73, T.325 Anthoinite T.74, T.31S Allactite T.73, T.38S Anthophyllite T.74, T.47S, T.61S Allanite-(Ce) T.146, T.51S Antigorite T.74,T.375, 60S Allanite-(La) T.115, T.44S Antlerite T.74, T.32S, T.60S Allanite-(Y) T.146, T.51S Apatite T.75, T.32S, T.60S Alleghanyite T.73, T.36S Aphthitalite T.75,T.42S, T.60 Allophane T.115, T.59S Apuanite T.75,T.34S Alluaudite T.115, T.45S Archerite T.75,T.31S Almandine T.73, T.36S Arctite T.146, T.53S Alstonite T.73,T.315 Arcubisite T.75, T.31S Althausite T.73,T.40S Ardaite T.75,T.39S Alumino-barroisite T.166, T.57S Ardennite T.166, T.55S Alumino-ferra-hornblende T.166, T.57S Arfvedsonite T.146, T.55S, T.61S Alumino-katophorite T.166, T.57S Argentojarosite T.116, T.45S Alumino-magnesio-hornblende T.159,T.555 Argentotennantite T.75,T.47S Alumino-taramite T.166, T.57S Argyrodite (VoU,