2021 Chemical Selection Guide
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Safety Data Sheets (Sdss) Information and Glossary
Safety Data Sheets (SDSs) Information and Glossary 2408 Wanda Daley Drive Ames, Iowa 50011 (515) 294-5359 | www.ehs.iastate.edu Copyright© Reviewed 2018 Safety Data Sheets (SDSs) Information Safety Data Sheets (SDSs) are informational sheets required by the Occupational Safety and Health Administration (OSHA) for hazardous substances (chemicals). The OSHA Hazard Communication Standard (29 CFR 1910.1200) and the Iowa Hazardous Chemical Risks Right to Know Standard (Iowa Administrative Code Section 875, Chapters 110-140) requires SDSs be “readily accessible” for any hazardous chemical in the workplace. Employees must be made aware of the SDS content and chemical storage location. SDSs can be obtained from manufacturers and distributors at the time of initial shipment. Each university workplace must maintain an SDS for each hazardous chemical in its inventory. SDSs that are available electronically meet the “readily accessible” criteria, as long as computer access is available to all employees whenever work is being conducted. EH&S suggests that each workspace also maintain paper copies of commonly used hazardous chemicals for ease of access. OSHA requires specific information be included on an SDS, in a 16-section format as described in the UN Globally Harmonized System of Classification and Labeling of Chemicals (GHS). The SDS must be in English and must include at least the following information: Section 1: Identification includes product identifier; manufacturer or distributor name, address, phone number; emergency phone number; recommended use; restrictions on use. Section 2: Hazard(s) Identification includes all hazards regarding the chemical; required label elements. Section 3: Composition/Information on Ingredients includes information on chemical ingredients; trade secret claims. -
United States Patent ‘ Patented Mar
r 2,786,869 United States Patent ‘ Patented Mar. 26, 1957 l 2 tically, mixtures of tert-alkylamine such as are available on the market. Typical mixtures are those containing ‘ 2,786,869 C12H25NH2 to C15H31NH2 or C18H3'INH2 to C24H49NH2 N-TRIALKYLCARBINYL-N-(HYDROXYETHYL or C15H31- to C24H49NH2. These may be represented by POLYOXYETHYL) GLYCINES the formula Peter L. de Benneville and Homer J. Sims, Philadelphia, 31 Pa., assignors to Rohrn & Haas Company, Philadelphia, R’-—-C—NH2 Pa., a corporation of Delaware Rs No Drawing. Application June 16, 1954, 10 As catalysts in the ?rst step of the process of this Serial No. 437,273 invention, wherein the hydroxyethyl group is introduced, 9 Claims.‘ (or. 260-534) there may be used any of the strong acids, such as hy drochloric, hydrobromic, sulfuric, arylsulfonic, alkanesul fonic, or phosphoric. The preferred amount of this cat This invention relatesto-compounds of the structure 15 alyst is 10 to 30 mole percent of the amine. With R1 '(CH2CH2O),.H ‘ , amines from 12 carbon atoms upward it is exceedingly di?icult to introduce more than one hydroxyethyl group in a tert-alkylamine molecule. Such amines‘yicld ?nal 3 \CHrCOOH products which have the desired balance of properties. ' wherein R1, R2, and R3 are alkyl groups containing a 20 The ?rst reaction with ethylene oxide is effected by total of 11 to 23 carbon atoms and n is an integer having bringing together ethylene oxide and tert-alkylamine, a value from 5 to about 50 or more, preferably 5 to 25. usually by passing ethylene oxide into amine and catalyst, These compounds may be called N-(trialkylcarbinyl)-N at temperatures from 0° to 180° C. -
G.J. Chemical Company, Inc. Safety Data Sheet
G.J. CHEMICAL COMPANY, INC. SAFETY DATA SHEET . PRODUCT IDENTIFIER 1.1 PRODUCT NAME: ACETONE PRODUCT NUMBER(S):100100, 100101,100110, 100120, 100130, 100140,100150, 100160 & 100180 TRADE NAMES/SYNONYMS: 2-Propanone; Dimethylformaldehyde; Dimethyl Ketone; Beta-Ketopropane; Methyl Ketone; CAS-No: 67-74-1 CHEMICAL FAMILY: Ketone, Aliphatic 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST IDENTIFIED USES: 1. Manufacture, process and distribution of substances and mixtures * 2. Use in laboratories 3. Uses in coatings 4. Use as binders and release agents 5. Rubber production and processing 6. Polymer manufacturing 7. Polymer processing 8. Use in Cleaning Agents 9. Use in Oil and Gas Field drilling and production operations 10. Blowing agents 11. Mining chemicals USES ADVISED AGAINST: No information available 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Company: G.J. CHEMICAL CO., INC. Address: 40 VERONICA AVENUE SOMERSET, NJ 08873 Telephone: 1-973-589-1450 Fax: 1-973-589-3072 1.4 Emergency Telephone Number Emergency Phone: 1-800-424-9300 (CHEMTREC) . HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture GHS Classification in accordance with 29CFR 1910 (OSHA HCS) Flammable liquids (Category 2), H225 Eye irritation (Category 2A), H319 Specific target organ toxicity - single exposure (Category 3), Central Nervous system, H336 2.2 GHS Label elements, including precautionary statements Pictogram GHS02 GHS07 Signal word: DANGER Hazard statement(s) H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Precautionary statement(s) Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. -
Chapter Four – TRPA1 Channels: Chemical and Temperature Sensitivity
CHAPTER FOUR TRPA1 Channels: Chemical and Temperature Sensitivity Willem J. Laursen1,2, Sviatoslav N. Bagriantsev1,* and Elena O. Gracheva1,2,* 1Department of Cellular and Molecular Physiology, Yale University School of Medicine, New Haven, CT, USA 2Program in Cellular Neuroscience, Neurodegeneration and Repair, Yale University School of Medicine, New Haven, CT, USA *Corresponding author: E-mail: [email protected], [email protected] Contents 1. Introduction 90 2. Activation and Regulation of TRPA1 by Chemical Compounds 91 2.1 Chemical activation of TRPA1 by covalent modification 91 2.2 Noncovalent activation of TRPA1 97 2.3 Receptor-operated activation of TRPA1 99 3. Temperature Sensitivity of TRPA1 101 3.1 TRPA1 in mammals 101 3.2 TRPA1 in insects and worms 103 3.3 TRPA1 in fish, birds, reptiles, and amphibians 103 3.4 TRPA1: Molecular mechanism of temperature sensitivity 104 Acknowledgments 107 References 107 Abstract Transient receptor potential ankyrin 1 (TRPA1) is a polymodal excitatory ion channel found in sensory neurons of different organisms, ranging from worms to humans. Since its discovery as an uncharacterized transmembrane protein in human fibroblasts, TRPA1 has become one of the most intensively studied ion channels. Its function has been linked to regulation of heat and cold perception, mechanosensitivity, hearing, inflam- mation, pain, circadian rhythms, chemoreception, and other processes. Some of these proposed functions remain controversial, while others have gathered considerable experimental support. A truly polymodal ion channel, TRPA1 is activated by various stimuli, including electrophilic chemicals, oxygen, temperature, and mechanical force, yet the molecular mechanism of TRPA1 gating remains obscure. In this review, we discuss recent advances in the understanding of TRPA1 physiology, pharmacology, and molecular function. -
The Emerging Role of Transient Receptor Potential Channels in Chronic Lung Disease
BACK TO BASICS | TRANSIENT RECEPTOR POTENTIAL CHANNELS IN CHRONIC LUNG DISEASE The emerging role of transient receptor potential channels in chronic lung disease Maria G. Belvisi and Mark A. Birrell Affiliation: Respiratory Pharmacology Group, Airway Disease Section, National Heart and Lung Institute, Imperial College, London, UK. Correspondence: Maria G. Belvisi, Respiratory Pharmacology Group, Airway Disease Section, National Heart and Lung Institute, Imperial College, Exhibition Road, London SW7 2AZ, UK. E-mail: [email protected] @ERSpublications Transient receptor potential channels are emerging as novel targets for chronic lung diseases with a high unmet need http://ow.ly/GHeR30b3hIy Cite this article as: Belvisi MG, Birrell MA. The emerging role of transient receptor potential channels in chronic lung disease. Eur Respir J 2017; 50: 1601357 [https://doi.org/10.1183/13993003.01357-2016]. ABSTRACT Chronic lung diseases such as asthma, chronic obstructive pulmonary disease and idiopathic pulmonary fibrosis are a major and increasing global health burden with a high unmet need. Drug discovery efforts in this area have been largely disappointing and so new therapeutic targets are needed. Transient receptor potential ion channels are emerging as possible therapeutic targets, given their widespread expression in the lung, their role in the modulation of inflammatory and structural changes and in the production of respiratory symptoms, such as bronchospasm and cough, seen in chronic lung disease. Received: Jan 08 2017 | Accepted after revision: April 14 2017 Conflict of interest: Disclosures can be found alongside this article at erj.ersjournals.com Copyright ©ERS 2017 https://doi.org/10.1183/13993003.01357-2016 Eur Respir J 2017; 50: 1601357 TRANSIENT RECEPTOR POTENTIAL CHANNELS IN CHRONIC LUNG DISEASE | M.G. -
Breathing Protection 02
PRODUCT CATALOG US BREATHING PROTECTION 02 CONTENTS 4. SELECTING RESPIRATORY PROTECTION 28. CHOOSE A SUITABLE FACEPIECE 5. TWO TYPES OF RESPIRATORY PROTECTION 28. SR 520 - SR 530 6. SELECTING BREATHING PROTECTION ON 30. SR 570 THE BASIS OF LEVEL OF CONTAMINATION 34. SR 580 7. SELECTING BREATHING PROTECTION BASED 36. SR 580/SR 584 ON WORK DURATION AND WORKLOAD 38. SR 580/SR 587/SR 588-1 & SR 588-2 9. HALF MASKS AND FULL FACE MASKS 39. FILTER 10. HALF MASK SR 100 40. FILTER FOR HALF- AND FULL FACE MASK 12. HALF MASK SR 900 42. FILTER FOR FAN UNIT 14. REMOTE FILTER KIT OPTIONS 16. REMOTE FILTER HOLDER SR 905 43. CONTINUOUS FLOW AIR LINE RESPIRATORY PROTECTION EQUIPMENT 16. FULL FACE MASK SR 200 44. SR 200 AIRLINE 46. SR 307 19. READY-TO-GO KITS 19. FULL FACE MASK OPTIONS 47. COMPRESSED AIR FILTER 20. HALF MASK OPTIONS 47. SR 99-1 23. POWER ASSISTED FILTER PROTECTION POWERED AIR PURIFYING RESPIRATORS 48. COMPRESSED AIR HOSES 24. SR 500 48. SR 358 26. READY-TO-GO-KITS 48. SR 359 50. FILTER RECOMMENDATIONS 03 WORLD CLASS RESPIRATORY PROTECTION EQUIPMENT MADE IN SWEDEN SINCE 1926 Sundström Safety protects people from SUNDSTRÖMS FLEXIBLE SYSTEM contaminated air and is not content to MAKES WORK MORE COMFORTABLE, simply meet official requirements. SAFER AND MORE EFFICIENT Our aim is to always design and manu- facture the best and most comfortable The base for Sundström Safety's System is always the respiratory protection equipment actual respiratory protection over nose and mouth. on the market. -
Nerve Agent - Lntellipedia Page 1 Of9 Doc ID : 6637155 (U) Nerve Agent
This document is made available through the declassification efforts and research of John Greenewald, Jr., creator of: The Black Vault The Black Vault is the largest online Freedom of Information Act (FOIA) document clearinghouse in the world. The research efforts here are responsible for the declassification of MILLIONS of pages released by the U.S. Government & Military. Discover the Truth at: http://www.theblackvault.com Nerve Agent - lntellipedia Page 1 of9 Doc ID : 6637155 (U) Nerve Agent UNCLASSIFIED From lntellipedia Nerve Agents (also known as nerve gases, though these chemicals are liquid at room temperature) are a class of phosphorus-containing organic chemicals (organophosphates) that disrupt the mechanism by which nerves transfer messages to organs. The disruption is caused by blocking acetylcholinesterase, an enzyme that normally relaxes the activity of acetylcholine, a neurotransmitter. ...--------- --- -·---- - --- -·-- --- --- Contents • 1 Overview • 2 Biological Effects • 2.1 Mechanism of Action • 2.2 Antidotes • 3 Classes • 3.1 G-Series • 3.2 V-Series • 3.3 Novichok Agents • 3.4 Insecticides • 4 History • 4.1 The Discovery ofNerve Agents • 4.2 The Nazi Mass Production ofTabun • 4.3 Nerve Agents in Nazi Germany • 4.4 The Secret Gets Out • 4.5 Since World War II • 4.6 Ocean Disposal of Chemical Weapons • 5 Popular Culture • 6 References and External Links --------------- ----·-- - Overview As chemical weapons, they are classified as weapons of mass destruction by the United Nations according to UN Resolution 687, and their production and stockpiling was outlawed by the Chemical Weapons Convention of 1993; the Chemical Weapons Convention officially took effect on April 291997. Poisoning by a nerve agent leads to contraction of pupils, profuse salivation, convulsions, involuntary urination and defecation, and eventual death by asphyxiation as control is lost over respiratory muscles. -
Hydroxyacetonitrile (HOCH2CN) As a Precursor for Formylcyanide (CHOCN), Ketenimine (CH2CNH), and Cyanogen (NCCN) in Astrophysical Conditions
A&A 549, A93 (2013) Astronomy DOI: 10.1051/0004-6361/201219779 & c ESO 2013 Astrophysics Hydroxyacetonitrile (HOCH2CN) as a precursor for formylcyanide (CHOCN), ketenimine (CH2CNH), and cyanogen (NCCN) in astrophysical conditions G. Danger1, F. Duvernay1, P. Theulé1, F. Borget1, J.-C. Guillemin2, and T. Chiavassa1 1 Aix-Marseille Univ, CNRS, PIIM UMR 7345, 13397 Marseille, France e-mail: [email protected] 2 Institut des Sciences Chimiques de Rennes, École Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, Avenue du Général Leclerc, CS 50837, 35708 Rennes Cedex 7, France Received 8 June 2012 / Accepted 19 November 2012 ABSTRACT Context. The reactivity in astrophysical environments can be investigated in the laboratory through experimental simulations, which provide understanding of the formation of specific molecules detected in the solid phase or in the gas phase of these environments. In this context, the most complex molecules are generally suggested to form at the surface of interstellar grains and to be released into the gas phase through thermal or non-thermal desorption, where they can be detected through rotational spectroscopy. Here, we focus our experiments on the photochemistry of hydroxyacetonitrile (HOCH2CN), whose formation has been shown to compete with aminomethanol (NH2CH2OH), a glycine precursor, through the Strecker synthesis. Aims. We present the first experimental investigation of the ultraviolet (UV) photochemistry of hydroxyacetonitrile (HOCH2CN) as a pure solid or diluted in water ice. Methods. We used Fourier transform infrared (FT-IR) spectroscopy to characterize photoproducts of hydroxyacetonitrile (HOCH2CN) and to determine the different photodegradation pathways of this compound. To improve the photoproduct identifications, irradiations of hydroxyacetonitrile 14N and 15N isotopologues were performed, coupled with theoretical calculations. -
United States Patent (19) 11, 3,977,878 Roteman (45) Aug
United States Patent (19) 11, 3,977,878 Roteman (45) Aug. 31, 1976 54 EPOXY RESEN PHOTORESIST WITH 3,522, 194 7/1970 Hada et al........................ 260/47 A ODOFORMAND BISMUTH TRPHENYL 3,708,296 1 / 1973 Schlesinger........................ 96/115 P 3,711,391 lf 1973 Feinberg............................ 96/115 P 75 Inventor: Jerome Roteman, Solon, Ohio 3,720,634 3/1973 Statton ........................... 260/47 EC 73) Assignee: American Can Company, 3,721,617 3/1973 Watt ................................. 260/2 EP Greenwich, Conn. Primary Examiner-Jack P. Brammer 22 Filed: Feb. 26, 1975 Attorney, Agent, or Firm-Robert P. Auber; Ernestine (21) Appl. No.: 553,262 C. Bartlett; George P. Ziehmer Related U.S. Application Data 57 ABSTRACT 62 Division of Ser. No. 369,086, June 1 1, 1973, Pat. No. 3,895,954. Photopolymerizable compositions and processes for photopolymerizing such compositions are provided, 52 U.S. Cl................................ 96/86 P; 96/115 R; said process comprising admixing with said epoxides, 96/ 15 P; 204/159. 18; 204/159.23; photosensitive organohalogen compounds in combina 204/159.24; 96/85; 96/87 R tion with an organometallic compound and thereafter 51 Int. Cl.’....................... G03C 1/94; G03C 1/68 applying energy to the resulting mixture. The or 58 Field of Search............. 96/115 R, 1 15 P, 86 P, ganohalogens decompose to liberate an active catalyst 96/85, 87 R; 204/159.18, 159.23, 159.24; which then serves to initiate polymerization of the ep 260/2 EP, 2 EC, 47 A, 47 C; 427/43 oxide material. The organometallic compound func tions synergistically with the organohalogen to en 56) References Cited hance the film forming properties of the resulting pol UNITED STATES PATENTS ymer and or sensitivity of the polymerizable system. -
Naming Molecular Compounds General Instructions: Please Do the Activities for Each Day As Indicated
Teacher Name: Dwight Lillie Student Name: ________________________ Class: ELL Chemistry Period: Per 4 Assignment: Assignment week 2 Due: Friday, 5/8 Naming Molecular Compounds General Instructions: Please do the activities for each day as indicated. Any additional paper needed please attach. Submitted Work: 1) Completed packet. Questions: Please send email to your instructor and/or attend published virtual office hours. Schedule: Date Activity Monday (4/27) Read Sections 9.3, 9.5 in your textbook. Tuesday (4/28) Read and work through questions 1-9 Wednesday (4/29) Read and work through questions 10-14 Thursday (4/30) Read and work through questions 14-18 Friday (5/31) Read and work through questions 19-21 How are the chemical formula and name of a molecular compound related? Why? When you began chemistry class this year, you probably already knew that the chemical formula for carbon dioxide was CO2. Today you will find out why CO2 is named that way. Naming chemical compounds correctly is of paramount importance. The slight difference between the names carbon monoxide (CO, a poisonous, deadly gas) and carbon dioxide (CO2, a greenhouse gas that we exhale when we breathe out) can be the difference between life and death! In this activity you will learn the naming system for molecular compounds. Model 1 – Molecular Compounds Molecular Number of Atoms Number of Atoms in Name of Compound Formula of First Element Second Element ClF Chlorine monofluoride ClF5 1 5 Chlorine pentafluoride CO Carbon monoxide CO2 Carbon dioxide Cl2O Dichlorine monoxide PCl5 Phosphorus pentachloride N2O5 Dinitrogen pentoxide 1. Fill in the table to indicate the number of atoms of each type in the molecular formula. -
Chlorine Dioxide Gas Treatment of Cantaloupe and Residue Analysis Simran Kaur Purdue University
Purdue University Purdue e-Pubs Open Access Theses Theses and Dissertations 2013 Chlorine Dioxide Gas Treatment of Cantaloupe and Residue Analysis Simran Kaur Purdue University Follow this and additional works at: https://docs.lib.purdue.edu/open_access_theses Part of the Food Science Commons Recommended Citation Kaur, Simran, "Chlorine Dioxide Gas Treatment of Cantaloupe and Residue Analysis" (2013). Open Access Theses. 47. https://docs.lib.purdue.edu/open_access_theses/47 This document has been made available through Purdue e-Pubs, a service of the Purdue University Libraries. Please contact [email protected] for additional information. CHLORINE DIOXIDE GAS TREATMENT OF CANTALOUPE AND RESIDUE ANALYSIS A Thesis Submitted to the Faculty of Purdue University by Simran Kaur In Partial Fulfillment of the Requirements for the Degree of Master of Science December 2013 Purdue University West Lafayette, Indiana ii Two cantaloupes were in love. One said to the other, “Let’s run away together!” The other one said, “No. We cantelope.” iii ACKNOWLEDGEMENTS I would like to thank Dr. Mark Morgan for giving me the opportunity to work on this project. I truly appreciate his support, encouragement and guidance and have thoroughly enjoyed every moment. I would also like to thank my committee members, Dr. Mario Ferruzzi and Dr. Peter Hirst for their suggestions, feedback and comments. Thank you to Ben Paxson for his help with equipment and also to Dr. Applegate for the lab space to do my project. I am also thankful for the help and support from all my friends, old and new, close and far, for their support and companionship throughout my graduate studies, especially my dear friend Nadra Guizani. -
Health-Based Reassessment of Administrative Occupational Exposure Limits
Gezondheidsraad Voorzitter Health Council of the Netherlands Aan de Staatssecretaris van Sociale Zaken en Werkgelegenheid Onderwerp : Aanbieding adviezen herevaluatie bestuurlijke MAC-waarden Uw kenmerk : ARBO/AMIL/97/00648 Ons kenmerk : U 2204/CB/mj/563-B5 Bijlagen : 1 Datum : 13 november 2001 Mijnheer de staatssecretaris, Op verzoek van uw ambtsvoorganger bied ik u hierbij 12 adviezen aan van een reeks over de gezondheidskundige basis van uit het buitenland overgenomen grenswaarden voor beroepsmatige blootstelling aan stoffen. Het verzoek om deze adviezen is in algemene zin vervat in brief nr ARBO/AMIL/97/00648 en in latere stadia door uw departement toegespitst op afzonderlijke stoffen. De adviezen zijn opgesteld door een daartoe door mij geformeerde internationale commissie van de Gezondheidsraad en beoordeeld door de Beraadsgroep Gezondheid en Omgeving. De beoogde reeks van in het Engels gestelde adviezen zal losbladig worden gepubliceerd onder ons publicatienummer 2000/15OSH en, conform de aan de Gezondheidsraad voorgelegde toespitsingen van de adviesaanvraag, betrekking hebben op 168 stoffen. Het u thans aangeboden tweede pakket bestaat uit de adviezen genummerd 2000/15OSH/018 tot en met 2000/15OSH/029, respectievelijk betrekking hebbend op: bornanon-2 (kamfer, synthetisch), chloortrifluoride, o-chloorstyreen, cyclohexylamine, dizwaveldecafluoride, hexafluoroaceton, keteen, pentachloornaftaleen, perchlorylfluoride, m-ftalodinitril, thionylchloride en trichloornaftaleen. Bij afronding van de werkzaamheden van de hierboven bedoelde