Iranian Dual-Use Lithium Related Research
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Recovery of Lithium from Spent Lithium Ion Batteries
Recovery of Lithium from Spent Lithium Ion Batteries Gabriel Chinyama Luzendu Chemical Engineering, masters level 2016 Luleå University of Technology Department of Engineering Sciences and Mathematics MASTER’S DEGREE PROJECT IN CHEMICAL ENGINEERING WITH SPECIALIZATION IN MINERALS AND METALLURGICAL ENGINEERING X7009K RECOVERY OF LITHIUM FROM SPENT LITHIUM ION BATTERIES Author: Gabriel Chinyama Luzendu Supervisors: Fredrik Engström & Jakob Kero Examiner: Caisa Samuelsson 31/08/2016 Division of Minerals and Metallurgical Engineering Department of Civil, Environmental & Natural Resource Engineering Luleå University of Technology Luleå, Sweden Declaration By submitting this thesis, I solemnly declare that the work contained therein is my own original work and that I am the sole author thereof and that it contains no material that has been accepted for the award of any other degree or diploma in any university. I also wish to declare that to the very best of my knowledge, it contains no material published previously or inscribed by another person, except where due reference is made in the text and that publication by Luleå University of Technology will not infringe any third party rights. Gabriel Chinyama Luzendu August, 2016 © Gabriel Chinyama Luzendu 2 Acknowledgement This thesis has been carried out at Luleå University of Technology, Division of Minerals and Metallurgical Research Laboratory. Further acknowledgement goes to the Swedish Institute for the financial support through the scholarship for my studies. I also wish to acknowledge my examiner Associate Professor Fredrik Engström and Jakob Kero for the knowledge, guidance and advice they shared with me during this thesis. Special thanks go to Professor Caisa Samuelsson for the opportunity to do the thesis in the department. -
Extraction of Lithium with Functionalized Lithium Ion-Sieves
See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/308339816 Extraction of lithium with functionalized lithium ion-sieves Article in Progress in Materials Science · September 2016 DOI: 10.1016/j.pmatsci.2016.09.004 CITATIONS READS 0 77 8 authors, including: Khaled Gasem Kaiying Wang University of Wyoming University of Wyoming 240 PUBLICATIONS 2,312 CITATIONS 1 PUBLICATION 0 CITATIONS SEE PROFILE SEE PROFILE Maohong Fan Univ. Wyoming and Georgia Tech 325 PUBLICATIONS 6,254 CITATIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: Mercury Removal View project Chemical-Looping Based CH4 Reforming View project All content following this page was uploaded by Kaiying Wang on 24 October 2016. The user has requested enhancement of the downloaded file. All in-text references underlined in blue are added to the original document and are linked to publications on ResearchGate, letting you access and read them immediately. Progress in Materials Science 84 (2016) 276–313 Contents lists available at ScienceDirect Progress in Materials Science journal homepage: www.elsevier.com/locate/pmatsci Extraction of lithium with functionalized lithium ion-sieves Xin Xu a,b, Yongmei Chen a, Pingyu Wan a, Khaled Gasem b, Kaiying Wang a,b, Ting He c, ⇑ Hertanto Adidharma b, Maohong Fan b,d,e, a National Fundamental Research Laboratory of New Hazardous Chemicals, Beijing University of Chemical Technology, Beijing 100029, China b Department of Chemical and Petroleum -
Federal LCA Commons Elementary Flow List: Background, Approach, Description and Recommendations for Use
EPA/600/R-19/092 | September 2019 | www.epa.gov/research The Federal LCA Commons Elementary Flow List: Background, Approach, Description and Recommendations for Use 0 Federal LCA Commons Elementary Flow List: Background, Approach, Description and Recommendations for Use by Ashley Edelen, Troy Hottle, Sarah Cashman Eastern Research Group Wesley Ingwersen U.S. EPA/National Risk Management Research Laboratory/ Land and Materials Management Division ii Notice/Disclaimer Although the U.S. Environmental Protection Agency, through its Office of Research and Development, funded and conducted the research described herein under an approved Quality Assurance Project Plan (Quality Assurance Identification Number G-LMMD-0031522-QP-1-0), with the support of Eastern Research Group, Inc. through EPA Contract Number EP-C-16-015, it does not necessarily reflect the views of the Agency, and no official endorsement should be inferred. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. iii Foreword The U.S. Environmental Protection Agency (U.S. EPA) is charged by Congress with protecting the Nation's land, air, and water resources. Under a mandate of national environmental laws, the Agency strives to formulate and implement actions leading to a compatible balance between human activities and the ability of natural systems to support and nurture life. To meet this mandate, U.S. EPA's research program is providing data and technical support for solving environmental problems today and building a science knowledge base necessary to manage our ecological resources wisely, understand how pollutants affect our health, and prevent or reduce environmental risks in the future. -
Www .Fancycn.Cn 6FN CYRESOURCE
FANCY RESOURCE www .fancycn.cn 6FN CYRESOURCE Company Introduction Fancy Mineral Resource Co, Ltd.(referred as “FR”) is As an energy conservation and environmental protection a manufacturing enterprise concentrated on converting enterprise, Fancy Resource, a hi-tech enterprise engaged in mineral resources into materials of industrial development and applications of mineral resources, has possessed applications, which dedicated itself to global resource mineral resources and strong Science and Technology Research & exploration & development, minerals application R&D, Development capabilities, specialized in scaled and refined production and end products sales for a long term, has a production of industrial mineral materials. After years’ continuous group of talented personnel and masters specialized high-speed development, Fancy Resource has achieved good mineral extraction technologies and R&D capabilities. results in terms of company size and operation profit. Envisioning For recent years, FR has specialized on the R&D of new the future, guided by national industrial policies and also according energy, new material , production process and the level to industry development and market demands, Fancy Resource will of industrialization development. As production bases continue to strengthen its efforts in the construction of New Energy both at home and abroad putting into operation in and New Materials Industry Chain, with mineral resources as its succession, Fancy will possess a broader extension guarantee and technological innovation -
The Structure of Alkali Silicate Glasses and Melts: a Multi-Spectroscopic Approach
The structure of alkali silicate glasses and melts: A multi-spectroscopic approach by Cedrick A. O'Shaughnessy A thesis submitted in conformity with the requirements for the degree of Doctor of Philosophy in Geology Graduate Department of Earth Sciences University of Toronto c Copyright 2019 by Cedrick A. O'Shaughnessy Abstract The structure of alkali silicate glasses and melts: A multi-spectroscopic approach Cedrick A. O'Shaughnessy Doctor of Philosophy in Geology Graduate Department of Earth Sciences University of Toronto 2019 The structure of alkali silicate glasses and melts is investigated using a multi-spectroscopic approach. Raman spectroscopy is used to characterize the local to intermediate range order within the glasses. We show that the distribution of rings varies as a function of composition, with 3-membered rings gaining importance with increasing alkali content. We apply a newly developed model for the fitting of the high n frequency envelope related to SiO4 symmetric stretch vibrations of Q species. These fits are interpreted using the idea of modifier bound bridging oxygen. The proportions of the different Qn species vary with alkali concentration with Q4 species breaking down to form lower order Qn species with increasing alkali 2 content. The Q peak appears at increasingly higher concentrations of M2O with increasing cation size. This leads us to believe that cations with a higher charge density cluster more readily than cations with a lower charge density. At the ∼20 mol. % composition we see a change in the silicate network, as shown by the absence of a Q4 peak and the proportion of 3-membered rings. -
Graphite and Lithium
www.oeko.de Environmental and socio-economic challenges in battery supply chains: graphite and lithium Short study prepared within the framework of the BMBF Darmstadt, joint project Fab4Lib - Research on measures to increase 29.07.2020 material and process efficiency in lithium-ion battery cell production along the entire value chain (FKZ 03XP0142E) Authors Geschäftsstelle Freiburg Postfach 17 71 79017 Freiburg Peter Dolega Hausadresse Dr. Matthias Buchert Merzhauser Straße 173 Dr. Johannes Betz 79100 Freiburg Telefon +49 761 45295-0 Oeko-Institut Büro Berlin Schicklerstraße 5-7 10179 Berlin Telefon +49 30 405085-0 Büro Darmstadt Rheinstraße 95 64295 Darmstadt Telefon +49 6151 8191-0 [email protected] www.oeko.de Fab4Lib Table of contents List of figures 4 List of abbreviations 5 1. Battery supply chains - towards sustainable cell manufacturing in the EU 7 2. Graphite 7 2.1. Natural graphite 8 2.2. Synthetic graphite 11 3. Lithium 12 3.1. Brines – Lithium triangle 13 3.2. Spodumene – Lithium from Australia 14 4. The future of battery supply chains 20 5. References 20 3 Fab4Lib List of figures Figure 2-1: Overview over the production process of natural graphite. 9 Figure 2-2: Overview over the production process of synthetic graphite. 11 Figure 3-1: Map of currently active lithium brines 13 Figure 3-2: Global lithium production from 2016 to 2018 by country 14 Figure 3-3: Map of Australian lithium mines 15 Figure 3-4: Location of Australian lithium mines in areas of critical habiat 18 Figure 3-5: Greenbushes and critical habitat in the surroundings -
Kalenga Tite Mwepu a Dissertation Submitted in Partial Fulfillment of The
LITHIUM EXTRACTION FROM ZIMBABWEAN PETALITE WITH AMMONIUM BIFLUORIDE DIGESTION Kalenga Tite Mwepu A dissertation submitted in partial fulfillment of the requirements for the degree Master of Science in Applied Science (Chemical Technology) in the Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology. Supervisor: Prof. Philip Crouse Co-supervisor: Dr Salmon Lubbe February 2020 Declaration I, Kalenga Tite Mwepu, student No. 15261043, do hereby declare that this research is my original work and that it has not previously, in its entirety or in part, been submitted and is not currently being submitted, either in whole or in part, at any other university for a degree or diploma, and that all references are acknowledged. SIGNED on this ________________________ day of_____12/02______________ 2020. __________________ Kalenga Tite Mwepu ii Synopsis Lithium carbonate is the precursor for most other lithium compounds. The market demand for lithium is increasing because it is used for many applications such as the preparation of electrode material and electrolyte for lithium-ion batteries, for treatment of manic depression, production of electronic grade crystals of lithium niobate and tantalite, and preparation of battery-grade lithium metal. Previously reported methods of lithium extraction require high temperature calcination for phase transformation from α-spodumene into β-spodumene, that is energy consuming and costly. This step is required because of the higher chemical reactivity of β-spodumene. The objectives of this research were to investigate the viability of ammonium bifluoride digestion of the petalite concentrate from the Bikita deposits without the initial thermal conversion to β- spodumene, in order to produce a high purity lithium carbonate in a cost efficient way, and optimising the remaining process parameters of the full process. -
Batteries for Electric and Hybrid Heavy Duty Vehicles
Notice This document is disseminated under the sponsorship of the U.S. Department of Transportation in the interest of information exchange. The United States Government assumes no liability for its contents or use thereof. The United States Government does not endorse products of manufacturers. Trade or manufacturers’ names appear herein solely because they are considered essential to the objective of this report. The mention of commercial products, their use in connection with material reported herein is not to be construed as actual or implied endorsement of such products by U.S. Department of Transportation or the contractor. For questions or copies please contact: CALSTART 48 S Chester Ave. Pasadena, CA 91106 Tel: (626) 744 5600 www.calstart.org Energy Storage Compendium: Batteries for Electric and Hybrid Heavy Duty Vehicles March 2010 CALSTART Prepared for: U.S. Department of Transportation Abstract The need for energy storage solutions and technologies is growing in support of the electrification in transportation and interest in hybrid‐electric and all electric heavy‐duty vehicles in transit and the commercial vehicles. The main purpose of this document is to provide an overview of advanced battery energy storage technologies available currently or in development for heavy‐duty, bus and truck, applications. The same set of parameters, such as energy density, power density, lifecycle and weight were used in review of the specific battery technology solution. The important performance requirements for energy storage solutions from the vehicle perspective were reviewed and the basic advantages of different cell chemistries for vehicle batteries were summarized. A list of current battery technologies available for automotive applications is provided. -
Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: a Review
resources Review Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: A Review Laurence Kavanagh * , Jerome Keohane, Guiomar Garcia Cabellos, Andrew Lloyd and John Cleary EnviroCORE, Department of Science and Health, Institute of Technology Carlow, Kilkenny, Road, Co., R93-V960 Carlow, Ireland; [email protected] (J.K.); [email protected] (G.G.C.); [email protected] (A.L.); [email protected] (J.C.) * Correspondence: [email protected] Received: 28 July 2018; Accepted: 11 September 2018; Published: 17 September 2018 Abstract: Lithium is a key component in green energy storage technologies and is rapidly becoming a metal of crucial importance to the European Union. The different industrial uses of lithium are discussed in this review along with a compilation of the locations of the main geological sources of lithium. An emphasis is placed on lithium’s use in lithium ion batteries and their use in the electric vehicle industry. The electric vehicle market is driving new demand for lithium resources. The expected scale-up in this sector will put pressure on current lithium supplies. The European Union has a burgeoning demand for lithium and is the second largest consumer of lithium resources. Currently, only 1–2% of worldwide lithium is produced in the European Union (Portugal). There are several lithium mineralisations scattered across Europe, the majority of which are currently undergoing mining feasibility studies. The increasing cost of lithium is driving a new global mining boom and should see many of Europe’s mineralisation’s becoming economic. The information given in this paper is a source of contextual information that can be used to support the European Union’s drive towards a low carbon economy and to develop the field of research. -
Fabrication of Glass Ceramic Fibres for High Temperature Applications
Fabrication of Glass Ceramic Fibres for High Temperature Applications by Zurina Shamsudin A thesis submitted for the degree of Doctor of Philosophy June 2013 Department of Mechanical Engineering Supervisor : Prof. Alma Hodzic 1 Abstract MgO-Al2O3-SiO2 (MAS) and LiO2-Al2O3-SiO2 (LAS) glass ceramic systems is a material which is reported to have very good mechanical properties and thermal stability. These properties are suitable not only for replacing the conventional materials but also embark new fields which can satisfy the technical demands especially in aerospace applications. However, this work is primarily focusing on the fabrication of glass ceramic matrix composites. Since these glass ceramics are reported to have good thermo-mechanical properties, the study embarked upon the fundamentals of processing of MAS and LAS glass ceramic fibres, in order to open a new avenue for advanced glass fibre composites in high temperature applications. The present work aims to develop fundamental information for fabrication of MAS and LAS glass ceramic fibres and development of the glass ceramic fibre reinforced polymer (GCFRP) composite. The thesis gradually evolves in the direction of this goal by developing suitable bulk glass ceramics, glass ceramic fibres and glass ceramic fibre reinforced polymer composites. In the first part, the bulk MAS and LAS glass ceramics were prepared using melting and casting process. This was followed by controlled heat treatments at different temperatures. The crystallisation behavior of both glass ceramics showed that the temperature increase enhanced the rigidity of the glass structure, thereby superior and reliable properties such as density, nanohardness and reduced Young's modulus were successfully derived in the MAS and LAS system prepared at different annealing and subsequent heat-treatment regimes. -
High Purity Inorganics
High Purity Inorganics www.alfa.com INCLUDING: • Puratronic® High Purity Inorganics • Ultra Dry Anhydrous Materials • REacton® Rare Earth Products www.alfa.com Where Science Meets Service High Purity Inorganics from Alfa Aesar Known worldwide as a leading manufacturer of high purity inorganic compounds, Alfa Aesar produces thousands of distinct materials to exacting standards for research, development and production applications. Custom production and packaging services are part of our regular offering. Our brands are recognized for purity and quality and are backed up by technical and sales teams dedicated to providing the best service. This catalog contains only a selection of our wide range of high purity inorganic materials. Many more products from our full range of over 46,000 items are available in our main catalog or online at www.alfa.com. APPLICATION FOR INORGANICS High Purity Products for Crystal Growth Typically, materials are manufactured to 99.995+% purity levels (metals basis). All materials are manufactured to have suitably low chloride, nitrate, sulfate and water content. Products include: • Lutetium(III) oxide • Niobium(V) oxide • Potassium carbonate • Sodium fluoride • Thulium(III) oxide • Tungsten(VI) oxide About Us GLOBAL INVENTORY The majority of our high purity inorganic compounds and related products are available in research and development quantities from stock. We also supply most products from stock in semi-bulk or bulk quantities. Many are in regular production and are available in bulk for next day shipment. Our experience in manufacturing, sourcing and handling a wide range of products enables us to respond quickly and efficiently to your needs. CUSTOM SYNTHESIS We offer flexible custom manufacturing services with the assurance of quality and confidentiality. -
Lithium Resources and Requirements by the Year 2000
Lithium Resources and Requirements by the Year 2000 GEOLOGICAL SURVEY PROFESSIONAL PAPER 1005 Lithium Resources and Requirements by the Year 2000 JAMES D. VINE, Editor GEOLOGICAL SURVEY PROFESSIONAL PAPER 1005 A collection of papers presented at a symposium held in Golden, Colorado, January 22-24, 1976 UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1976 UNITED STATES DEPARTMENT OF THE INTERIOR THOMAS S. KLEPPE, Secretary GEOLOGICAL SURVEY V. E. McKelvey, Director First printing 1976 Second printing 1977 Library of Congress Cataloging in Publication Data Vine, James David, 1921- Lithium resources and requirements by the year 2000. (Geological Survey Professional Paper 1005) 1. Lithium ores-United States-Congresses. 2. Lithium-Congresses. I. Vine, James David, 1921- II. Title. HI. Series: United States Geological Survey Professional Paper 1005. TN490.L5L57 553'.499 76-608206 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 Stock Number 024-001-02887-5 CONTENTS Page 1. Introduction, by James D. Vine, U.S. Geological Survey, Denver, Colo ______________-_______-_-- — ------- —— —— ——— ---- 1 2. Battery research sponsored by the U.S. Energy Research and Development Administration, by Albert Landgrebe, Energy Research and De velopment Administration, Washington, D.C., and Paul A. Nelson, Argonne National Laboratory, Argonne, Ill-__- —— -____.—————— 2 3. Battery systems for load-leveling and electric-vehicle application, near-term and advanced technology (abstract), by N. P. Yao and W. J. Walsh, Argonne National Laboratory, Argonne, 111___.__________________________________-___-_________ — ________ 5 4. Lithium requirements for high-energy lithium-aluminum/iron-sulfide batteries for load-leveling and electric-vehicle applications, by A.