polymers Article Reinforcement of Styrene Butadiene Rubber Employing Poly(isobornyl methacrylate) (PIBOMA) as High Tg Thermoplastic Polymer Abdullah Gunaydin 1,2, Clément Mugemana 1 , Patrick Grysan 1, Carlos Eloy Federico 1 , Reiner Dieden 1 , Daniel F. Schmidt 1, Stephan Westermann 1, Marc Weydert 3 and Alexander S. Shaplov 1,* 1 Luxembourg Institute of Science and Technology (LIST), 5 Avenue des Hauts-Fourneaux, L-4362 Esch-sur-Alzette, Luxembourg;
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[email protected] (C.M.);
[email protected] (P.G.);
[email protected] (C.E.F.);
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[email protected] (S.W.) 2 Department of Physics and Materials Science, University of Luxembourg, 2 Avenue de l’Université, L-4365 Esch-sur-Alzette, Luxembourg 3 Goodyear Innovation Center Luxembourg, L-7750 Colmar-Berg, Luxembourg;
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[email protected]; Tel.: +352-2758884579 Abstract: A set of poly(isobornyl methacrylate)s (PIBOMA) having molar mass in the range of 26,000–283,000 g mol−1 was prepared either via RAFT process or using free radical polymerization. ◦ These linear polymers demonstrated high glass transition temperatures (Tg up to 201 C) and thermal Citation: Gunaydin, A.; stability (T up to 230 ◦C). They were further applied as reinforcing agents in the preparation of the Mugemana, C.; Grysan, P.; onset Eloy Federico, C.; Dieden, R.; vulcanized rubber compositions based on poly(styrene butadiene rubber) (SBR). The influence of the Schmidt, D.F.; Westermann, S.; PIBOMA content and molar mass on the cure characteristics, rheological and mechanical properties of Weydert, M.; Shaplov, A.S.