Silicone Rubber TECHNICAL INFORMATION
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5. Progress in Radiation Vulcanization of Natural Rubber Latex
JP0050691 JAERI-Conf 2000^003 5. Progress in Radiation Vulcanization of Natural Rubber Latex K. MAKUUCHI Takasaki Radiation Chemistry Research Establishment, JAERI 1233 Watanuki, Takasaki Gunma, 370-12 Japan 1. INTRODUCTION Radiation-induced crosslinking of natural rubber in latex can be accomplished by irradiating NR latex. The dose at which the maximum tensile strength (Tb) is found is called vulcanization dose (Dv). The Dv of NR latex is more than 250 kGy that is too high to be used in industry. The first RV accelerators proposed was carbon tetrachloride. Addition of 5 phr of carbon tetrachloride can reduce. The RVNRL was selected as one of the regional projects of the International Atomic Energy Agency (IAEA) known as the Regional Cooperative Agreement in the Asia and Pacific Region (RCA) in 1981. A pilot plant for the RVNRL was built in. Jakarta in 1983. The products from the pilot plant were tested and evaluated by several institutes in the region during 1983-1985, The results were as follows: Low tensile strength (less than 20MPa) Poor aging properties Inconsistent properties Not economic due to high dose requirement No advantages The results caused argument among the RCA member states and the IAEA whether the project should be continued or stopped. The preliminary R&D in the TRCRE on RVNRL indicated that the properties of RVNRL could be improved by proper selection of an accelerator. Finally, the IAEA decided to support the R&D on RVNRL at Takasaki. The following R&D were carried out in 1985 - 1989. Selection of NR latex to improve tensile strength Selection of accelerator to reduce required dose Selection of process factors to avoid inconsistency Selection of antioxidants to improve aging properties Biological safety test to find advantages of RVNRL As an accelerator n-butyl acrylate (n-BA) was selected by reason of its high accelerating efficiency, no residue in the final dipped products and tolerable price. -
Vulcanization & Accelerators
Vulcanization & Accelerators Vulcanization is a cross linking process in which individual molecules of rubber (polymer) are converted into a three dimensional network of interconnected (polymer) chains through chemical cross links(of sulfur). The vulcanization process was discovered in 1839 and the individuals responsible for this discovery were Charles Goodyear in USA and Thomas Hancock in England. Both discovered the use of Sulfur and White Lead as a vulcanization system for Natural Rubber. This discovery was a major technological breakthrough for the advancement of the world economy. Vulcanization of rubbers by sulfur alone is an extremely slow and inefficient process. The chemical reaction between sulfur and the Rubber Hydrocarbon occurs mainly at the C = C (double bonds) and each crosslink requires 40 to 55 sulphur atoms (in the absence of accelerator). The process takes around 6 hours at 140°C for completion, which is uneconomical by any production standards. The vulcanizates thus produced are extremely prone to oxidative degradation and do not possess adequate mechanical properties for practical rubber applications. These limitations were overcome through inventions of accelerators which subsequently became a part of rubber compounding formulations as well as subjects of further R&D. Following is the summary of events which led to the progress of ‘Accelerated Sulfur Vulcanization'. Event Year Progress - Discovery of Sulfur Vulcanization: Charles Goodyear. 1839 Vulcanizing Agent - Use of ammonia & aliphatic ammonium derivatives: Rowley. 1881 Acceleration need - Use of aniline as accelerator in USA & Germany: Oenslager. 1906 Accelerated Cure - Use of Piperidine accelerator- Germany. 1911 New Molecules - Use of aldehyde-amine & HMT as accelerators in USA & UK 1914-15 Amine Accelerators - Use of Zn-Alkyl Xanthates accelerators in Russia. -
Silicone Rubber Fluid Resistance Guide
Fluid Resistance Guide Performance Profiles for Silastic® brand Silicone and Fluorosilicone Rubber and XIAMETER® brand Silicone Rubber Contents Page Introduction noitcudortnI 2 This guide is intended to give you an idea of the performance profile of xednI sdiulF xednI 4 various classes of silicone rubbers when immersed in different fluids. ASTM and IRM Oils, Fuels, and Fluids 6 It's our hope that the information will save you the time and cost of MIL Specification Oils, Fuels, and Fluids 8 preliminary screening and feasibility tests. We recommend that you test Automotive Oils and Fluids 11 specific materials prior to use. Keep in mind that service conditions are Fuels 41 usually less severe than immersion tests. For instance, in actual service Hydraulic Fluids 51 the rubber is often only partly exposed or is subjected only to spills or Transformer and Instrument Oils 71 splashing. This means that a rubber that shows only fair results in a Specialty O ils, G reases, and Fluids 81 prolonged total immersion test will often perform quite adequately under Solvents 12 actual conditions. sdiulF enociliS sdiulF 32 Silicone Compounds and Greases 52 Types of Silastic and XIAMETER Food Products 62 Silicone Rubbers Water and Steam 82 Immersion test results refer to types of silicone rubber by Acids 29 their ASTM designation. The polymer classification described in Bases 30 ASTM D 1418 is based on the organic group side chains attached to the Salts 31 silicon-oxygen chain. If other groups are present, their initials are listed Other Chemicals 13 prior to the MQ designation: MQ indicates methyl groups, V indicates phenyl groups. -
Reinforcement of Styrene Butadiene Rubber Employing Poly(Isobornyl Methacrylate) (PIBOMA) As High Tg Thermoplastic Polymer
polymers Article Reinforcement of Styrene Butadiene Rubber Employing Poly(isobornyl methacrylate) (PIBOMA) as High Tg Thermoplastic Polymer Abdullah Gunaydin 1,2, Clément Mugemana 1 , Patrick Grysan 1, Carlos Eloy Federico 1 , Reiner Dieden 1 , Daniel F. Schmidt 1, Stephan Westermann 1, Marc Weydert 3 and Alexander S. Shaplov 1,* 1 Luxembourg Institute of Science and Technology (LIST), 5 Avenue des Hauts-Fourneaux, L-4362 Esch-sur-Alzette, Luxembourg; [email protected] (A.G.); [email protected] (C.M.); [email protected] (P.G.); [email protected] (C.E.F.); [email protected] (R.D.); [email protected] (D.F.S.); [email protected] (S.W.) 2 Department of Physics and Materials Science, University of Luxembourg, 2 Avenue de l’Université, L-4365 Esch-sur-Alzette, Luxembourg 3 Goodyear Innovation Center Luxembourg, L-7750 Colmar-Berg, Luxembourg; [email protected] * Correspondence: [email protected]; Tel.: +352-2758884579 Abstract: A set of poly(isobornyl methacrylate)s (PIBOMA) having molar mass in the range of 26,000–283,000 g mol−1 was prepared either via RAFT process or using free radical polymerization. ◦ These linear polymers demonstrated high glass transition temperatures (Tg up to 201 C) and thermal Citation: Gunaydin, A.; stability (T up to 230 ◦C). They were further applied as reinforcing agents in the preparation of the Mugemana, C.; Grysan, P.; onset Eloy Federico, C.; Dieden, R.; vulcanized rubber compositions based on poly(styrene butadiene rubber) (SBR). The influence of the Schmidt, D.F.; Westermann, S.; PIBOMA content and molar mass on the cure characteristics, rheological and mechanical properties of Weydert, M.; Shaplov, A.S. -
Tensile Properties of Pre-Vulcanised Natural Rubber Latex Films Via Hybrid Radiation and Peroxide Vulcanisations
ASM Sci. J., 11(2), 67-75 Tensile Properties of Pre-vulcanised Natural Rubber Latex Films via Hybrid Radiation and Peroxide Vulcanisations Sofian Ibrahim1;2∗, Chai Chee Keong1, Chantara Thevy Ratnam1 and Khairiah Badri2 1Malaysian Nuclear Agency, 43000 Kajang, Selangor, Malaysia 2School of Chemical Science and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia Radiation pre-vulcanised natural rubber latex (RVNRL) prepared by using gamma irradia- tion technique has many advantages over the conventionally prepared sulphur pre-vulcanised natural rubber latex (SPVL). Despite the fact that many potential latex dipped products can be made from RVNRL, little effort was made to fully commercialise the products because of the inferior strength of RVNRL products compared to SPVL products. An attempt was made to improve the tensile strength of RVNRL by combining both radiation and peroxide vulcanisation in order to ensure that the products will not tear or fail, and has sufficient stretch. Hexanediol diacrylate (HDDA) plays the main role as sensitizer during radiation vulcanisation and tert-butyl hydroperoxide (t-BHPO) as the co-sensitizer in peroxide vul- canisation. Pre-vulcanised natural rubber latex dipped films via hybrid radiation and perox- idation vulcanisations obtained showed tensile strength of 26.7 MPa, an increment of more than 15% compared to controlled film (22.5 MPa). Besides, the crosslink percentage of the rubber films also showed around 5% increment from 90.7% to 95.6%. Keywords: RVNRL, vulcanisation, irradiation, latex I. INTRODUCTION the expansion of this positive sales performance. One of the major contributors to Malaysia's national income is rubber and latex-based prod- ucts. -
Global Automotive Components and Suppliers Expo 16-18 June 2015 Stuttgart, Germany
GACS 2015 Report Global Automotive Components and Suppliers Expo 16-18 June 2015 Stuttgart, Germany 1.0 Introduction Global Automotive Components and Suppliers (GACS) Expo is the only show in Europe dedicated to showcasing automotive components and component suppliers for the OEM segment. Companies invited to exhibit at GACS 2015 comprised of automotive Tier 1, 2 and 3 suppliers. GACS 2015 was organized according to three main product categories namely Engine Expo, Automotive Interiors Expo and Automotive Testing Expo concurrently. These annual shows are organized by UKIP Media & Event Ltd. Global Automotive Components and Suppliers Expo (GACS2015) Date 16-18 June 2015 Venue Messe Stuttgart, Germany Organiser UKIP Media & Event Ltd Number of Malaysian Exhibitors 5 exhibitors with MREPC Exhibit Products Rubber Automotive Components – Gaskets, seals, O-rings, grommets, bushings, rubber metal bonded parts, weatherstrips, wiper blades, industrial gloves Table 1: Summary information of GACS 2015 Page | 1 GACS 2015 Report 2.0 Participation Info MREPC officers together with Malaysian manufacturers at MREPC Pavilion 2.1 Participation of MREPC in Exhibition MREPC participated in GACS 2015 for the first time with five rubber products manufacturers under MREPC Pavilion. MREPC and the Malaysian manufacturers promoted a wide range of rubber automotive components, including gaskets, O-rings, grommets, weatherstrips, wiper blades, rubber metal bonded parts such as engine mounts and exhaust hangers as well as industrial gloves. Companies Products 1. COOLTEC INDUSTRIES SDN BHD Rubber molded parts, O-rings, grommet, seals 2. KOSSAN RUBBER INDUSTRIES BHD Rubber automotive components 3. KUMPULAN JEBCO (M) SDN BHD Chasis & suspension parts – engine mounting system, bushes, dampers and strut mount suspension 4. -
Model Vulcanization Systems for Butyl Rubber and Halobutyl Rubber Manual
Exxon™ butyl and halobutyl rubber Model vulcanization systems for butyl rubber and halobutyl rubber manual Country name(s) 2 - Model vulcanization systems for butyl rubber and halobutyl rubber manual Model vulcanization systems for butyl rubber and halobutyl rubber manual - 3 Abstract The vulcanization of isobutylene-co-isoprene rubber (IIR), brominated isobutylene-co-isoprene rubber (BIIR), chlorinated isobutylene-co-isoprene rubber (CIIR), and brominated isobutylene-co-para-methylstyrene elastomer (BIMSM) differs from that of general-purpose rubbers (GPR). Butyl rubber has approximately 2% unsaturation in the backbone. Halobutyl rubber (BIIR and CIIR) incorporates the butyl backbone with either bromine or chlorine, which significantly increases the chemical reactivity of the isoprenyl units located in the butyl backbone. Similarly, in BIMSM the bromine atom is bonded to the para-methylstyrene (PMS) group, thus affording the completely saturated polymer backbone a site of chemical reactivity. Utilization of the unique attributes of butyl rubber and halobutyl rubbers with their minimal backbone unsaturation and of BIMSM elastomers with no backbone unsaturation is found in many areas of industry. These properties are excellent vapor impermeation, resistance to heat degradation, and improved chemical resistance as compared to general-purpose rubbers. However, this low amount of reactivity requires special consideration to vulcanize these isobutylene-based polymers. The type of vulcanization system selected is a function of the composite structure in which it is used, and the cured product performance requirements. Therefore, vulcanization systems vary and may include an accelerator package along with resins, zinc oxide, zinc oxide and sulfur, and quinoid systems. This review will discuss the types and selection of appropriate vulcanization systems for isobutylene-based elastomers. -
Silicone Materials for Automobiles
Silicone Materials for Automobiles CO NTENTS Silicone Fluids and Secondary Products for Automotive Applications P2 Silicone Elastomers for Automotive Applications P4 Silicone Elastomers for Automotive Applications — Application to Airbags — P6 Thermal Interface Materials for Automotive Applications P8 LIMS Materials for Automobiles P10 Silicone Materials for Automobiles Silicone Fluids and Secondary Products for Automotive Applications The auto industry has been unremitting in its pursuit of development of automotive technologies to improve safety, comfort, and fuel efficiency. Silicones have frequently been used as automotive materials, and Shin-Etsu has been using the latest technologies to develop products to meet evolving needs. In these pages we will present examples of some typical applications, mainly featuring silicone fluids and their secondary products. Introduction adding heat-resistance improvers to dimethyl tires wore out quickly and were therefore not In recent years, automakers have taken silicone fluid. They are used as fan coupling practical. Later, KBE-846 was developed by efforts to make safer vehicles that are more fluids and in other torque transmission researchers who realized that sulfide silane comfortable and eco-friendly by adding car applications, and as a heating medium in could be used to improve the wear life of room temperature it forms a uniform film navigation systems, sensors and other automobiles (Table 1). silica-compounded tires. with exceptional water repellency, oil features, while making vehicles lighter and repellency, release properties, and antifouling more fuel-efficient. In this article, we will 1-3. Modifier for synthetic leather seat materials 1-6. Plastic & rubber modifiers properties (Table 2). discuss some of the places where silicone Double end-capped carbinol-modified fluids Master pellets and acrylic silicone powders fluids and their secondary products Single end-capped diol-modified fluids Silicone master pellets are plastics compounded 2-2. -
Airfield Maintenance Activities at North Carolina Airports
STATE OF NORTH CAROLINA DEPARTMENT OF TRANSPORTATION PAT MCCRORY ANTHONY J. TATA GOVERNOR SECRETARY November 17, 2014 NOTICE TO PROSPECTIVE BIDDERS Subject: Invitation to attend a Mandatory Pre-Bid Conference Airfield Maintenance Activities at North Carolina Airports The North Carolina Department of Transportation – Division of Aviation is requesting bids for a purchase order contract involving airfield maintenance activities at North Carolina airports. The contract includes full depth asphalt patching, crack sealing, concrete and asphalt pavement repair, joint sealing, sealing/rejuvenation, rubber removal, airfield painting, marking removal, pressure washing, micro-surfacing, polyurethane foam systems, seeding and mulching, and other additional items. A Contract will be awarded to the three lowest responsible Bidders. The Contractor is to furnish labor, materials, equipment and traffic control and be available to perform work at any airport within North Carolina. A Mandatory Pre-Bid Conference will be held at the NCDOT – Division of Aviation building ( 1050 Meridian Drive, RDU Airport, NC ) in the second floor conference room on November 21, 2014 at 10:30 A.M. Contractors may call-in as an alternative to attending in-person. A call-in number and electronic copy of the Contract Proposal will be available at https://connect.ncdot.gov/letting/Pages/Aviation.aspx The NCDOT, in accordance with the provisions of Title VI of the Civil Rights of 1964 (78 Stat.252) and the Regulations of the Department of Transportation (49 C.F.R., Part 21), issued pursuant to such act, hereby notifies all bidders that it will affirmatively insure that the contract entered into pursuant to this notice will be awarded to the lowest responsible bidders without discrimination on the grounds of sex, race, color, or national origin. -
The Recycling of End-Of-Life Tyres. Technological Review(•)
rEvISTA dE METAlurGIA, 47 (3) invited review MAYO-JuNIO, 273-284, 2011 ISSN: 0034-8570 eISSN: 1988-4222 doi: 10.3989/revmetalm.1052 the recycling of end-of-life tyres. technological review(•) G. Ramos*, F. J. Alguacil* and F. A. López* Abstract In this review, a summary of current legislation applicable to End-of-Life Tyres (ELTs), management of that waste, both in Spain and Europe, and a compilation of existing technologies to enlarge the life of tyres and treatment technologies for material and energy recoveries, are provided. In recent years, there have been a number of studies in the field of treatment of ELTs, therefore applicable emerging technologies as more efficient, clean and cost- effective technologies, are discussed. Keywords End-of-Life Tyres (ELT); Retread; Material recovery; Energy recovery; Integrated Management System (IMS). reciclado de neumáticos fuera de uso. revisión tecnológica resumen En este trabajo, se realiza un resumen de la legislación actual aplicable a los Neumáticos Fuera de Uso (NFU), de la gestión de dicho residuo tanto en España como en Europa y una recopilación de las tecnologías existentes para la pro- longación de la vida útil de los neumáticos y de las tecnologías de tratamiento para su valorización material y ener- gética. En los últimos años, han sido numerosos los estudios realizados en el campo del tratamiento de los NFUs, por ello se ha realizado una búsqueda de las tecnologías emergentes, como posibles tecnologías más eficientes, limpias y económicas. Palabras clave Neumático Fuera de Uso (NFU); Recauchutado; Reciclaje material; Valorización energética. Sistema Integrado de Gestión (SIG). 1. -
The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber A
The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science By ROBERT J. WEHRLE B.S., Northern Kentucky University, 2012 Wright State University 2014 WRIGHT STATE UNIVERSITY GRADUATE SCHOOL August 29, 2014 I HEREBY RECOMMEND THAT THE THESIS PREPARED UNDER MY SUPERVISION BY Robert Joseph Wehrle ENTITLED The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber BE ACCEPTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE. Eric Fossum Ph.D. Thesis Director David A. Grossie, Ph.D. Chair, Department of Chemistry Committee on Final Examination Eric Fossum, Ph.D. William A. Feld, Ph.D. Steven B. Glancy, Ph.D. Kenneth Turnbull, Ph.D. Robert E. W. Fyffe, Ph.D. Vice President for Research and Dean of the Graduate School Abstract Wehrle, Robert J. M.S, Department of Chemistry, Wright State University, 2014. The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber. Ethylene‐propylene‐diene (EPDM) rubbers containing varying amounts of diene were cured with sulfur using either a moving die rheometer (MDR) or a rubber process analyzer (RPA). The effect of removing curatives and how the curing reaction changed was explored. Kinetic data was extracted from the rheology plots and reaction rate constants were determined by two separate ways: manually choosing points of interest or by a computer model. iii TABLE OF CONTENTS Page 1. Introduction 1 1.1 EPDM Overview 1 1.2 Preparation of EPDM 2 1.2.1 Ziegler‐Natta Catalysts 2 1.2.2 Metallocene Catalysts 4 1.3 Cross‐link Chemistry 5 1.3.1 Peroxide Cure 5 1.3.2 Sulfur Cure 6 1.3.3 Cross‐link Sites 8 1.3.3.1 Polymer Branching 9 1.3.4 Rubber Ingredients 10 1.3.4.1 Non‐curative Ingredients 10 1.3.4.2 Curative Ingredients 11 1.4 Kinetics 12 1.5 Instrumentation 13 2. -
Neoprene, Elastomer, Vulcanization, Radiation, Allyl, Sensitizer, Gel, Crosslinking, Dose, Crosslinks
American Journal of Polymer Science 2016, 6(3): 68-74 DOI: 10.5923/j.ajps.20160603.02 Radiation Crosslinking of Neoprene W with Diallyl Etherofmaleic Acid and Epoxy Resins Sh. M. Mammadov1,*, A. A. Asadova1, R. F. Khankishiyeva1, O. H. Akbarov2, G. Sh. Duruskari2, M. N. Maharramov2, J. M. Mamedov1, H. N. Akhundzada1 1Institute of Radiation Problems of ANAS, Azerbaijan 2Baku State University, Azerbaijan Abstract Discusses the use of technological aspects and radiation crosslinking Neoprene W in the presence of a diallyl ester of maleic acid (DAEMA) and epoxy resin (ED-5) in the presence of metal oxides. With the help of physico-chemical and spectral methods shows the variation in the molecular structure Neoprene W in the presence of DAEMA and ED-5 after irradiation with γ-rays of 500 kGr. With analysis method of Sol-gel for each test system determined the radiation-chemical yield (RCY) and the emergence of cross-linking of cross-links in the elastomer. The dependence of the crystallinity index of the degree of stretching for Neoprene W, irradiated at 500 kGy was defined. It was found that at the radiation vulcanization Neoprene W in the presence of a bifunctional bonds epoxy resin weakly has a decisive influence on the kinetics of the process and yield crosslinking. It is shown that above 1500 kGy irradiation in the filled Neoprene observed destruction in the elastomer chain, resulting in deterioration of physical and mechanical properties of the vulcanizates. Keywords Neoprene, Elastomer, Vulcanization, Radiation, Allyl, Sensitizer, Gel, Crosslinking, Dose, Crosslinks 1. Introduction wide range of substances. The high molecular Neoprene W is also irradiated with the Neoprene W (DuPont, France) is one of the most participation of low molecular weight organic sensitizers, promising elastomers for special purposes.