Simple Model of Chromium Isotopic Abundance Evolution in Interstellar Dust
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Unit 1Moles and Equations
Cambridge University Press 978-1-107-61665-3 – Cambridge International AS and A Level Chemistry Judith Potter Peter Cann Excerpt More information Moles and equations Unit 1 Learning outcomes You should be able to: defi ne and use the terms empirical and molecular formulae and use experimental data defi ne and use relative masses based on the to fi nd them, 12C scale write and construct equations and use them in defi ne and use the mole and Avogadro’s performing mole calculations constant perform mole calculations involving solutions analyse simple mass spectra and use the data in and gases, relative atomic mass calculations This unit gathers together the basic chemistry relative isotopic mass = calculations. You may need to refer to it as you revise mass of one atom of the isotope other topics in later units. (1/12) of the mass of one atom of 12C Relative masses are a ratio of two masses and have 1.01 Relative masses no units. An atom is the smallest part of an element that can exist and still retain the identity of the element. A 1.02 The mole and the molecule is a group of atoms bonded together and the smallest portion of an element or compound that can Avogadro constant exist alone. A simple ion is an atom which has lost or To give an easy measurement of mass, a number of gained one or more electrons. Atoms, molecules and atoms is chosen so that their combined mass is equal to ions are so small that their masses are far too small the relative atomic mass in grams. -
Chromium Isotopes Detection in Their Ores with Minimal Errors
Open Access Annals of Advances in Chemistry Research Article Chromium Isotopes Detection in their Ores with Minimal Errors ISSN 2576-3768 Loai Aljerf1* and Nuha AlMasri2 1Department of Basic Sciences, Faculty of Dental Medicine, Damascus University, Mazzeh Highway, Almazzeh, Damascus, Syria 2Department of Chemistry, Faculty of Medicine, Syrian Private University, Damascus, Syria *Address for Correspondence: Loai Aljerf, De- Abstract partment of Basic Sciences, Faculty of Dental Medicine, Damascus University, Mazzeh High- The industrial production and use of chromium have grown considerably during the past way, Almazzeh, Damascus, Syria, Tel: +963-93 fi ve decades. Abundances of the chromium isotopes in terrestrial samples are identical to 34 46 993; Email: [email protected]; 0.01%. Among the dominant species of chromium, the trivalent form widely occurs in nature in [email protected] chromite ores which is extremely immobilized especially in water bodies. Samples were mixtures Submitted: 21 July 2018 of separated chromium isotopes and the calibration was made with the same species as those Approved: 03 September 2018 used in the measurements. The method had simplifi ed the conversion of the ores to chromyl Published: 04 September 2018 fl uoride since the element could be readily separated as lead chromate from the leaching of Copyright: 2018 Aljerf L, et al. This is an open chromite-sodium peroxide fusions. Isotope assay of chromyl fl uoride under certain conditions access article distributed under the Creative was measured and the measurements of chromium isotopic anomalies ratios and isotope Commons Attribution License, which permits abundance of the chromite ores have been assessed. These provided suffi cient quantitative mass unrestricted use, distribution, and reproduction spectrometric data, which were analyzed to calculate the abundance and the mean atomic mass in any medium, provided the original work is of the questioned isotopes. -
Determination of Picogram Quantities of Vanadium in Calcite And
+ + Anal. Chem. 1996, 68, 371-377 Determination of Picogram Quantities of Vanadium in Calcite and Seawater by Isotope Dilution Inductively Coupled Plasma Mass Spectrometry with Electrothermal Vaporization David W. Hastings* and Steven R. Emerson School of Oceanography, WB-10, University of Washington, Seattle, Washington 98195 Bruce K. Nelson Department of Geological Sciences, AJ-20, University of Washington, Seattle, Washington 98195 We developed a method to measure picogram quantities Recent interest in the geochemistry of vanadium has arisen of vanadium in calcite and seawater by isotope dilution from its unique redox behavior 9,10 and the observation of enriched (ID) inductively coupled plasma mass spectrometry using concentrations in anoxic sediments, black shale, and crude oil.11,12 electrothermal vaporization (ETV) to introduce the sample Because V deposition is redox sensitive, its concentration in into the plasma. A 50V isotope spike enriched to 44 atom seawater is most likely sensitive to the oxidation state of sedi- % was equilibrated with samples, followed by chemical ments. The calcitic shells of foraminifera accurately record purification by cation exchange chromatography. Samples seawater concentrations of V,13 so the V content of the fossil shells were introduced into the ETV unit with a Pd modifier and of these microscopic oceanic organisms potentially can serve as heated to 1000 °C. This quantitatively eliminates the an indicator of changes in past ocean anoxia.14 ClO+ isobaric interference with V at m/z 51 for solutions A typical 5 mg hand-picked sample of these microscopic shells up to 0.5 N HCl. The procedural blank was 0.27 pg of yields only 50-200 pg of vanadium. -
Chromium Isotope Behaviour in Natural Waters
UNIVERSITY OF SOUTHAMPTON FACULTY OF NATURAL AND ENVIRONMENTAL SCIENCES Ocean and Earth Sciences Chromium Isotope Behaviour in Natural Waters by Heather Jane Goring-Harford Thesis for the degree of Doctor of Philosophy June 2017 UNIVERSITY OF SOUTHAMPTON ABSTRACT FACULTY OF NATURAL AND ENVIRONMENTAL SCIENCES Ocean and Earth Sciences Doctor of Philosophy CHROMIUM ISOTOPE BEHAVIOUR IN NATURAL WATERS By Heather Jane Goring-Harford The isotopes of chromium (Cr) fractionate during terrestrial oxidation reactions that require the presence of oxygen. The main source of Cr to the oceans is via rivers, and thus Cr isotopic signatures (expressed as δ53Cr) preserved in authigenic sediments are increasingly being used to reconstruct the oxygen levels of ancient environments. However, Cr can undergo various reactions in natural waters that may fractionate Cr isotopes. The contribution of these reactions to authigenic sediment δ53Cr values is not well understood, and this limits the interpretation of δ53Cr values measured in ancient archives. This thesis describes the development of a method to accurately and precisely measure Cr isotopic signatures in natural waters with extremely low Cr concentrations, and evaluates the behaviour of Cr isotopes in water samples from a range of environmental settings. Seawater samples from the Atlantic Ocean Oxygen Minimum Zone (OMZ) were analysed to evaluate whether Cr isotopic fractionation was enhanced under depleted oxygen conditions. Results indicate that the Atlantic OMZ is not sufficiently depleted in oxygen to reduce and remove Cr from seawater, although δ53Cr values (1.08 – 1.72‰) were variable due to adsorption of Cr(III) to particles on the shelf, and hydrological mixing. Black Sea seawater samples that had dissolved oxygen concentrations close to zero were enriched in 52Cr, resulting in a δ53Cr that was 0.38‰ lower than the overlying fully oxygenated waters. -
ILPAC Unit S2: Atomic Structure
UNIT INDEPENDENT LEARNING PROJECT FOR ADVANCED CHEMISTRY Periodic Table of the Elements o 2 I He II ill] III IV V VI VIII 4.0 3 4 5 6 7 8 9 10 Li Be B C N 0 F Ne 6.9 9.0 10.8 12.0 14.0 16.0 19.0 20.2 11 12 13 14 15 16 17 18 Na Mg Al Si P S CI Ar 23.0 24.3 27.0 28.1 31.0 32.1 35.5 39.9 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 3! 36 K Ca Sc Ti V Cr Mn Fe Co Ni eu Zn Ga Ge As Se BrlKr 39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.9 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79 83.8 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 S4 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 85.5 87.6 88.9 91.2 92.9 95.9 99.0 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.91 ' 3 ' . 3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba La 4 Hf Ta W Re Os If Pt Au Hg Tl Pb Bi Po AtlRn 132.9 137.3 138.9 178.5 181.0 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 210.0 210.01222.0 87 88 89 Fr Ra Ac~ 223.0 226.0 227.0 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 "--- Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lw 232.0 231.0 238.1 (237) 239.1 (243) (241) (247) (251 ) (254) (253) (256) ( 254) (257) A value in brackets denotes the mass number of the most stable isotope. -
45024017.Pdf
Ain Shams University Faculty of Science Radiochemical Study on the Separation of Chromium-51 from the Irradiated Target by Using Commercial and/or Synthesized Ion Exchanger A thesis Submitted by Mohamed Ismail Mohamed Mohamed Aydia (M. Sc. Inorganic and Physical Chemistry 2007) Chemist\ Radioisotopes Production Facility Egyptian Second Research Reactor Atomic Energy Authority For the Degree of Doctor of Philosophy in Science (Chemistry). Department of Chemistry Faculty of Science Ain Shams University (2012) Ain Shams University Faculty of Science Approval Sheet The Thesis entitled Radiochemical Study on the Separation of Chromium-51 from the Irradiated Target by Using Commercial and/or Synthesized Ion Exchanger Submitted by/ Mohamed Ismail Mohamed Aydia (M. Sc. Inorganic and Physical Chemistry 2007) For the Degree of Doctor of Philosophy in Science (Chemistry). This thesis has been approved by supervisor committee SUPERVISORS • Prof. Dr. M.S. Abdel-Mottaleb ….……………… Professor of Inorganic Chemistry Faculty of Science-Ain Shams University • Prof. Dr. Salah Soliman ….……………… Ex-Chairman of Hot Labs Center Supervisor of Radioisotopes Production Facility Atomic Energy Authority • Prof. Dr. A. A. El-Mohty ….……………… Professor of Radiochemistry Radioactive Isotopes and Generator Dep. Atomic Energy Authority • Prof. K.M. El-Azony ….……………… Associate Professor of Radiochemistry Radioactive Isotopes and Generator Dep. Atomic Energy Authority. Prof. Dr. Maged Shafik Antonious Head of Chemistry Department Faculty of Science - Ain Shams University CHAPTER (I) INTRODUCTION CHAPTER (II) EXPERIMENTAL CHAPTER (III) RESULTS AND DISCUSSION REFERENCES ] SUMMARY ARABIC SUMMARY ACKNOWLEDGEMENT I would like to express my gratitude to Prof. Dr. Mohamed Sabry Abdel-Mottaleb, Professor of Inorganic Chemistry, Faculty of Science, Ain Shams University for his supervision and his sponsorship for this work. -
The Radiochemistry of Chromium COMMITTEE on NUCLEAR SCIENCE
546.7 P634v C95 National Academy of Sciences 1 National Research Council B I I NUCLEAR SCIENCE SERIES I 1 I I The Radiochemistry of Chromium COMMITTEE ON NUCLEAR SCIENCE L. F. CURTISS, Chairman ROBLEY D. EVANS, Vice Chairman NationalBureau ofStandards MassachusettsInstituteofTechnology J.A, DeJUREN, Secretary WestinghouseElectricCorporation H, J.CURTIS G. G. MANOV BrookhavenNationalLaboratory Tracerlab,Inc. SAMUEL EPSTEIN W. WAYNE MEINKE CaliforniaInstituteofTechnology UniversityofMichigan HERBERT GOLDSTEIN A. H. SNELL NuclearDevelopmentCorporationof Oak RidgeNationalLaboratory America E. A. UEHLING H. J.GOMBERG UniversityofWashington UniversityofMichigan D. M. VAN PATTER E. D. KLEMA BartolResearch Foundation NorthwesternUniversity ROBERT L. PLATZMAN Argonne NationalLaboratory LIAISON MEMBERS PAUL C .AEBERSOLD W. D. URRY Atomic Energy Commission U. S.Air Force J. HOWARD McMILLEN WILLIAM E. WRIGHT NationalScienceFoundation OfficeofNavalResearch SUBCOMMITTEE ON RADIOCHEMISTRY W. WAYNE MEINKE, Chairman EARL HYDE UniversityofMichigan UniversityofCalifornia(Berkeley) NATHAN BALLOU HAROLD KIRBY Navy RadiologicalDefenseLaboratory Mound Laboratory GREGORY R. CHOPPIN GEORGE LEDDICOTTE FloridaStateUniversity Oak RidgeNationalLaboratory GEORGE A. COWAN ELLIS P. STEINBERG Los AlarnosScientificLaboratory Argonne NationalLaboratory ARTHUR W. FAIRHALL PETER C. STEVENSON UniversityofWashington UniversityofCalifornia(Livermore) HARMON FINSTON LEO YAFFE BrookhavenNationalLaboratory McGillUniversity The Radiochemistry of Chromium By J.PIJCK Laboratory for