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Chloropicrin

Chloropicrin

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CAS Number: 76-06-2 DOT Number: UN 1580 (PIH) RTK Substance number: 0405 DOT Hazard Class: 6.1 () Date: April 1998 Revision: June 2005 ------

HAZARD SUMMARY * Chloropicrin can affect you when breathed in. * Exposure to hazardous substances should be routinely * Exposure can severely irritate the eyes causing intense evaluated. This may include collecting personal and area tearing. air samples. You can obtain copies of sampling results * Chloropicrin can irritate the skin causing a rash or from your employer. You have a legal right to this burning feeling on contact. information under OSHA 1910.1020. * Breathing Chloropicrin can irritate the nose, mouth and * If you think you are experiencing any work-related health throat. problems, see a doctor trained to recognize occupational * Chloropicrin can cause headache, nausea, vomiting and diseases. Take this Fact Sheet with you. diarrhea. * ODOR THRESHOLD = 1.1 ppm. * Breathing Chloropicrin can irritate the lungs causing * The range of accepted odor threshold values is quite coughing and/or shortness of breath. Higher exposures broad. Caution should be used in relying on odor alone as can cause a build-up of fluid in the lungs (pulmonary a warning of potentially hazardous exposures. edema), a medical emergency, with severe shortness of breath. WORKPLACE EXPOSURE LIMITS * Chloropicrin is a HIGHLY REACTIVE CHEMICAL and OSHA: The legal airborne permissible exposure limit a DANGEROUS EXPLOSION HAZARD. (PEL) is 0.1 ppm averaged over an 8-hour * Chloropicrin is a DOT Poison Inhalation Hazard (PIH). workshift.

IDENTIFICATION NIOSH: The recommended airborne exposure limit is Chloropicrin is a colorless, oily liquid with a sharp 0.1 ppm averaged over a 10-hour workshift. penetrating odor that causes tears. It is used as a fumigant, and fungicide, as tear , and in making dyes such ACGIH: The recommended airborne exposure limit is as Methyl Violet. 0.1 ppm averaged over an 8-hour workshift.

REASON FOR CITATION WAYS OF REDUCING EXPOSURE * Chloropicrin is on the Hazardous Substance List because * Where possible, enclose operations and use local exhaust it is regulated by OSHA and cited by ACGIH, DOT, ventilation at the site of chemical release. If local exhaust NIOSH, DEP, NFPA and EPA. ventilation or enclosure is not used, should be * This chemical is on the Special Health Hazard Substance worn. List because it is REACTIVE. * Wear protective work clothing. * Definitions are provided on page 5. * Wash thoroughly immediately after exposure to Chloropicrin and at the end of the workshift. HOW TO DETERMINE IF YOU ARE BEING * Post hazard and warning information in the work area. In EXPOSED addition, as part of an ongoing education and training effort, communicate all information on the health and The New Jersey Right to Know Act requires most employers safety hazards of Chloropicrin to potentially exposed to label chemicals in the workplace and requires public workers. employers to provide their employees with information and training concerning chemical hazards and controls. The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees.

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This Fact Sheet is a summary source of information of all Any evaluation should include a careful history of past and potential and most severe health hazards that may result from present symptoms with an exam. Medical tests that look for exposure. Duration of exposure, of the substance damage already done are not a substitute for controlling and other factors will affect your susceptibility to any of the exposure. potential effects described below. ------Request copies of your medical testing. You have a legal right to this information under OSHA 1910.1020. HEALTH HAZARD INFORMATION Mixed Exposures Acute Health Effects * Because smoking can cause heart disease, as well as lung The following acute (short-term) health effects may occur cancer, emphysema, and other respiratory problems, it may immediately or shortly after exposure to Chloropicrin: worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will * Exposure can severely irritate the eyes causing intense reduce your risk of developing health problems. tearing. * Chloropicrin can irritate the skin causing a rash or burning WORKPLACE CONTROLS AND PRACTICES feeling on contact. * Breathing Chloropicrin can irritate the nose, mouth and Unless a less toxic chemical can be substituted for a hazardous throat. substance, ENGINEERING CONTROLS are the most * Chloropicrin can cause headache, nausea, vomiting and effective way of reducing exposure. The best protection is to diarrhea. enclose operations and/or provide local exhaust ventilation at * Breathing Chloropicrin can irritate the lungs causing the site of chemical release. Isolating operations can also coughing and/or shortness of breath. Higher exposures can reduce exposure. Using respirators or protective equipment is cause a build-up of fluid in the lungs (pulmonary edema), a less effective than the controls mentioned above, but is medical emergency, with severe shortness of breath. sometimes necessary.

Chronic Health Effects In evaluating the controls present in your workplace, consider: The following chronic (long-term) health effects can occur at (1) how hazardous the substance is, (2) how much of the some time after exposure to Chloropicrin and can last for substance is released into the workplace and (3) whether months or years: harmful skin or eye contact could occur. Special controls should be in place for highly toxic chemicals or when Cancer Hazard significant skin, eye, or breathing exposures are possible. * While Chloropicrin has been tested, it is not classifiable as In addition, the following controls are recommended: to its potential to cause cancer.

Reproductive Hazard * Where possible, automatically pump liquid Chloropicrin from drums or other storage containers to process * According to the information presently available to the New containers. Jersey Department of Health and Senior Services, * Before entering a confined space where Chloropicrin may Chloropicrin has not been tested for its ability to affect be present, check to make sure that an explosive reproduction. concentration does not exist.

Other Long-Term Effects Good WORK PRACTICES can help to reduce hazardous * Chloropicrin can irritate the lungs. Repeated exposure exposures. The following work practices are recommended: may cause bronchitis to develop with cough, phlegm,

and/or shortness of breath. * Workers whose clothing has been contaminated by

Chloropicrin should change into clean clothing promptly. MEDICAL * Contaminated work clothes should be laundered by individuals who have been informed of the hazards of Medical Testing exposure to Chloropicrin. Before beginning employment and at regular times after that (at * Eye wash fountains should be provided in the immediate least annually), the following are recommended: work area for emergency use. * If there is the possibility of skin exposure, emergency * Lung function tests. shower facilities should be provided. * On skin contact with Chloropicrin, immediately wash or If symptoms develop or overexposure is suspected, the shower to remove the chemical. At the end of the following is recommended: workshift, wash any areas of the body that may have contacted Chloropicrin, whether or not known skin contact * Consider chest x-ray after acute overexposure. has occurred. * Do not eat, , or drink where Chloropicrin is handled, processed, or stored, since the chemical can be swallowed. CHLOROPICRIN page 3 of 6

Wash hands carefully before eating, drinking, smoking, or * If while wearing a filter or cartridge you can using the toilet. smell, taste, or otherwise detect Chloropicrin, or if while wearing particulate filters abnormal resistance to breathing PERSONAL PROTECTIVE EQUIPMENT is experienced, or eye irritation occurs while wearing a full facepiece respirator, leave the area immediately. Check to WORKPLACE CONTROLS ARE BETTER THAN make sure the respirator-to-face seal is still good. If it is, PERSONAL PROTECTIVE EQUIPMENT. However, for replace the filter or cartridge. If the seal is no longer good, some jobs (such as outside work, confined space entry, jobs you may need a new respirator. done only once in a while, or jobs done while workplace * Be sure to consider all potential exposures in your controls are being installed), personal protective equipment workplace. You may need a combination of filters, may be appropriate. prefilters or cartridges to protect against different forms of a chemical (such as vapor and mist) or against a mixture of OSHA 1910.132 requires employers to determine the chemicals. appropriate personal protective equipment for each hazard and * Where the potential for high exposure exists, use a to train employees on how and when to use protective MSHA/NIOSH approved supplied-air respirator with a full equipment. facepiece operated in a pressure-demand or other positive- pressure mode. For increased protection use in combination The following recommendations are only guidelines and may with an auxiliary self-contained breathing apparatus not apply to every situation. operated in a pressure-demand or other positive-pressure mode. Clothing * Exposure to 2 ppm is immediately dangerous to life and * Avoid skin contact with Chloropicrin. Wear protective health. If the possibility of exposure above 2 ppm exists, gloves and clothing. Safety equipment suppliers/ use a NIOSH approved self-contained breathing apparatus manufacturers can provide recommendations on the most with a full facepiece operated in a pressure-demand or other protective glove/clothing material for your operation. positive-pressure mode equipped with an emergency escape * Safety equipment manufacturers recommend Tychem air cylinder. Responder ® as a protective material. * All protective clothing (suits, gloves, footwear, headgear) HANDLING AND STORAGE should be clean, available each day, and put on before work. * Prior to working with Chloropicrin you should be trained on its proper handling and storage. * When Chloropicrin decomposes, or if it is contaminated, it Eye Protection may explode when exposed to HEAT, SHOCK or * Wear indirect-vent, impact and splash resistant goggles FRICTION. when working with liquids. * Chloropicrin must be stored to avoid contact with * Wear a face shield along with goggles when working with OXIDIZING AGENTS (such as , corrosive, highly irritating or toxic substances. PEROXIDES, PERMANGANATES, , * Contact lenses should not be worn when working with this NITRATES, , and ); substance. STRONG BASES (such as and HYDROXIDE); PROPARGYL BROMIDE; Respiratory Protection ANILINE; and POWDERED since violent IMPROPER USE OF RESPIRATORS IS DANGEROUS. reactions occur. Such equipment should only be used if the employer has a * Store in tightly closed containers in a cool, well-ventilated written program that takes into account workplace conditions, area away from METALS and COMBUSTIBLES. requirements for worker training, respirator fit testing and * DO NOT USE equipment made of , medical exams, as described in OSHA 1910.134. ALUMINUM or their ALLOYS when handling

Chloropicrin. * For field applications check with your supervisor and your * Wherever Chloropicrin is used, handled, manufactured, or safety equipment supplier regarding the appropriate respiratory equipment. stored, use explosion-proof electrical equipment and * Where the potential exists for exposure over 0.1 ppm, use a fittings. MSHA/NIOSH approved full facepiece respirator with an organic vapor cartridge. Increased protection is obtained QUESTIONS AND ANSWERS from full facepiece powered-air purifying respirators. Q: If I have acute health effects, will I later get chronic health effects? A: Not always. Most chronic (long-term) effects result from repeated exposures to a chemical.

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Q: Can I get long-term effects without ever having short------term effects? The following information is available from: A: Yes, because long-term effects can occur from repeated exposures to a chemical at levels not high enough to make New Jersey Department of Health and Senior Services you immediately sick. Occupational Health Service PO Box 360 Q: What are my chances of getting sick when I have been Trenton, NJ 08625-0360 exposed to chemicals? (609) 984-1863 A: The likelihood of becoming sick from chemicals is (609) 984-7407 (fax) increased as the amount of exposure increases. This is determined by the length of time and the amount of Web address: http://www.state.nj.us/health/eoh/odisweb/ material to which someone is exposed. Industrial Hygiene Information Q: When are higher exposures more likely? Industrial hygienists are available to answer your questions A: Conditions which increase risk of exposure include regarding the control of chemical exposures using exhaust physical and mechanical processes (heating, pouring, ventilation, special work practices, good housekeeping, good spraying, spills and evaporation from large surface areas hygiene practices, and personal protective equipment including respirators. In addition, they can help to interpret the results of such as open containers), and "confined space" exposures industrial hygiene survey data. (working inside vats, reactors, boilers, small rooms, etc.).

Medical Evaluation Q: Is the risk of getting sick higher for workers than for If you think you are becoming sick because of exposure to community residents? chemicals at your workplace, you may call personnel at the A: Yes. Exposures in the community, except possibly in Department of Health and Senior Services, Occupational cases of or spills, are usually much lower than those Health Service, who can help you find the information you found in the workplace. However, people in the need. community may be exposed to contaminated as well as to chemicals in the air over long periods. This Public Presentations may be a problem for children or people who are already Presentations and educational programs on occupational health ill. or the Right to Know Act can be organized for labor unions, trade associations and other groups.

Right to Know Information Resources The Right to Know Infoline (609) 984-2202 can answer questions about the identity and potential health effects of chemicals, list of educational materials in occupational health, references used to prepare the Fact Sheets, preparation of the Right to Know Survey, education and training programs, labeling requirements, and general information regarding the Right to Know Act. Violations of the law should be reported to (609) 984-2202. ------

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DEFINITIONS

ACGIH is the American Conference of Governmental NAERG is the North American Emergency Response Industrial Hygienists. It recommends upper limits (called Guidebook. It was jointly developed by Transport Canada, the TLVs) for exposure to workplace chemicals. United States Department of Transportation and the Secretariat of Communications and Transportation of Mexico. It is a A is a substance that causes cancer. guide for first responders to quickly identify the specific or generic hazards of material involved in a transportation The CAS number is assigned by the Chemical Abstracts incident, and to protect themselves and the general public Service to identify a specific chemical. during the initial response of the incident.

CFR is the Code of Federal Regulations, which consists of the NFPA is the National Protection Association. It classifies regulations of the United States government. substances according to their fire and explosion hazard.

A combustible substance is a , liquid or gas that will burn. NIOSH is the National Institute for Occupational Safety and Health. It tests equipment, evaluates and approves respirators, A is a gas, liquid or solid that causes conducts studies of workplace hazards, and proposes standards irreversible damage to human tissue or containers. to OSHA.

DEP is the New Jersey Department of Environmental NTP is the National Toxicology Program which tests Protection. chemicals and reviews evidence for cancer.

DOT is the Department of Transportation, the federal agency OSHA is the Occupational Safety and Health Administration, that regulates the transportation of chemicals. which adopts and enforces health and safety standards.

EPA is the Environmental Protection Agency, the federal PEL is the Permissible Exposure Limit which is enforceable by agency responsible for regulating environmental hazards. the Occupational Safety and Health Administration.

A fetus is an unborn human or animal. PIH is a DOT designation for chemicals which are Poison Inhalation Hazards. A flammable substance is a solid, liquid, vapor or gas that will ignite easily and burn rapidly. ppm means parts of a substance per million parts of air. It is a measure of concentration by volume in air. The flash point is the temperature at which a liquid or solid gives off vapor that can form a flammable mixture with air. A reactive substance is a solid, liquid or gas that releases energy under certain conditions. IARC is the International Agency for Research on Cancer, a scientific that classifies chemicals according to their STEL is a Short Term Exposure Limit which is usually a 15- cancer-causing potential. minute exposure that should not be exceeded at any time during a work day. IRIS is the Integrated Risk Information System database of the federal EPA. A teratogen is a substance that causes birth defects by damaging the fetus. A miscible substance is a liquid or gas that will evenly dissolve in another. TLV is the Threshold Limit Value, the workplace exposure limit recommended by ACGIH. mg/m3 means milligrams of a chemical in a cubic meter of air. It is a measure of concentration (weight/volume). The vapor pressure is a measure of how readily a liquid or a solid mixes with air at its surface. A higher vapor pressure A mutagen is a substance that causes mutations. A mutation is indicates a higher concentration of the substance in air and a change in the genetic material in a body cell. Mutations can therefore increases the likelihood of breathing it in. to birth defects, miscarriages, or cancer.

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Common Name: CHLOROPICRIN HANDLING AND STORAGE (See page 3) DOT Number: UN 1580 (PIH) DOT Hazard Class: 6.1 (Poison) FIRST AID NAERG Code: 154 CAS Number: 76-06-2 For POISON INFORMATION call 1-800-222-1222

Hazard rating NJDHSS NFPA Eye Contact FLAMMABILITY - 0 * Immediately flush with large amounts of water for at least REACTIVITY - 3 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. POISONOUS ARE PRODUCED IN FIRE

CONTAINERS MAY EXPLODE IN FIRE Skin Contact POISON INHALATION HAZARD * Quickly remove contaminated clothing. Immediately wash Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; area with large amounts of soap and water. Seek medical 3=serious; 4=severe attention immediately.

FIRE HAZARDS Breathing * Remove the person from exposure. * Extinguish fire using an agent suitable for type of * Begin rescue breathing (using universal precautions) if surrounding fire. Chloropicrin itself does not burn. breathing has stopped and CPR if heart action has stopped. * Water may not be effective in fighting fires. * Transfer promptly to a medical facility. * POISONOUS GASES ARE PRODUCED IN FIRE, * Medical observation is recommended for 24 to 48 hours including and Chlorine. after breathing overexposure, as pulmonary edema may be * CONTAINERS MAY EXPLODE IN FIRE. delayed. * Use water spray to keep fire-exposed containers cool. * If employees are expected to fight fires, they must be PHYSICAL DATA trained and equipped as stated in OSHA 1910.156. o o SPILLS AND EMERGENCIES Vapor Pressure: 20 mm Hg at 68 F (20 C) Water Solubility: Slightly soluble If Chloropicrin is spilled or leaked, take the following steps: OTHER COMMONLY USED NAMES * Evacuate persons not wearing protective equipment from area of spill or leak until clean-up is complete. Chemical Name: * Absorb liquids in vermiculite, dry sand, earth, soda or fly , Trichloronitro- ash, or cement powder and deposit in sealed Other Names: containers. Nitrotrichloromethane; Nitrochloroform; * Ventilate and wash area after clean-up is complete. Trichloronitromethane * Keep Chloropicrin out of a confined space, such as a sewer, because of the possibility of an explosion, unless the ------sewer is designed to prevent the build-up of explosive Not intended to be copied and sold for commercial . purposes. * It may be necessary to contain and dispose of Chloropicrin ------as a HAZARDOUS WASTE. Contact your state NEW JERSEY DEPARTMENT OF HEALTH AND Department of Environmental Protection (DEP) or your SENIOR SERVICES regional office of the federal Environmental Protection Right to Know Program Agency (EPA) for specific recommendations. PO Box 368, Trenton, NJ 08625-0368 * If employees are required to clean-up spills, they must be (609) 984-2202 properly trained and equipped. OSHA 1910.120(q) may be ------applicable. ======FOR LARGE SPILLS AND FIRES immediately call your fire department. You can request emergency information from the following:

CHEMTREC: (800) 424-9300 NJDEP HOTLINE: 1-877-WARN-DEP ======

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